JPH03213588A - Dyeing of yarn - Google Patents
Dyeing of yarnInfo
- Publication number
- JPH03213588A JPH03213588A JP2003144A JP314490A JPH03213588A JP H03213588 A JPH03213588 A JP H03213588A JP 2003144 A JP2003144 A JP 2003144A JP 314490 A JP314490 A JP 314490A JP H03213588 A JPH03213588 A JP H03213588A
- Authority
- JP
- Japan
- Prior art keywords
- dyeing
- dyed
- yarn
- solution
- anthocyanin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 26
- 229930002877 anthocyanin Natural products 0.000 claims abstract description 20
- 235000010208 anthocyanin Nutrition 0.000 claims abstract description 20
- 239000004410 anthocyanin Substances 0.000 claims abstract description 20
- 150000004636 anthocyanins Chemical class 0.000 claims abstract description 19
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 8
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 7
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 7
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 7
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000000835 fiber Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 3
- 102000004169 proteins and genes Human genes 0.000 abstract description 3
- 108090000623 proteins and genes Proteins 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 150000001455 metallic ions Chemical class 0.000 abstract 5
- ORTBMTXABUAMJS-VGEDXCMYSA-N Cyanidin 3-arabinoside Chemical compound [Cl-].O[C@H]1[C@H](O)[C@H](O)CO[C@H]1OC1=CC2=C(O)C=C(O)C=C2[O+]=C1C1=CC=C(O)C(O)=C1 ORTBMTXABUAMJS-VGEDXCMYSA-N 0.000 abstract 1
- KUCVMQMKRICXJC-FBVAEJEDSA-O Cyanidin 3-arabinoside Natural products O([C@H]1[C@@H](O)[C@@H](O)[C@H](O)CO1)c1c(-c2cc(O)c(O)cc2)[o+]c2c(c(O)cc(O)c2)c1 KUCVMQMKRICXJC-FBVAEJEDSA-O 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 25
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 239000004744 fabric Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- OBOSXEWFRARQPU-UHFFFAOYSA-N 2-n,2-n-dimethylpyridine-2,5-diamine Chemical compound CN(C)C1=CC=C(N)C=N1 OBOSXEWFRARQPU-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 7
- 210000002268 wool Anatomy 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 6
- VEVZSMAEJFVWIL-UHFFFAOYSA-O cyanidin cation Chemical compound [O+]=1C2=CC(O)=CC(O)=C2C=C(O)C=1C1=CC=C(O)C(O)=C1 VEVZSMAEJFVWIL-UHFFFAOYSA-O 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 210000004748 cultured cell Anatomy 0.000 description 5
- OKJMLYFJRFYBPS-UHFFFAOYSA-J tetraazanium;cerium(4+);tetrasulfate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OKJMLYFJRFYBPS-UHFFFAOYSA-J 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229940037003 alum Drugs 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical group [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 3
- 235000007336 cyanidin Nutrition 0.000 description 3
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical group [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- -1 anthocyanin compounds Chemical class 0.000 description 2
- PGJHGXFYDZHMAV-UHFFFAOYSA-K azanium;cerium(3+);disulfate Chemical compound [NH4+].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O PGJHGXFYDZHMAV-UHFFFAOYSA-K 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012192 staining solution Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- WEQHQGJDZLDFID-UHFFFAOYSA-J thorium(iv) chloride Chemical compound Cl[Th](Cl)(Cl)Cl WEQHQGJDZLDFID-UHFFFAOYSA-J 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、アントシアニンを含有する溶液で、繊維を染
色する方法の改良に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to an improvement in a method for dyeing fibers with a solution containing anthocyanins.
（従来の技術）
植物に含まれるアントシアニンを用いた繊維の染色は、
「草木染め」の１種として古来から知られているもので
ある。しかし、草木から抽出したアントシアニン染色液
に布を浸し染色させて得た染色布は、耐光堅牢度が劣り
、その市場価値が低い欠点を有していた。(Conventional technology) Dyeing of fibers using anthocyanins contained in plants is
It has been known since ancient times as a type of ``plant dyeing''. However, dyed fabrics obtained by soaking fabrics in an anthocyanin dyeing liquid extracted from plants have poor light fastness and have low market value.
そこで、染色液に、鉄、アルミニウム、スズ、アンチモ
ン、クロム塩を加えて、耐光堅牢度を向上させる試みが
されたけれども、市場価値のある耐光堅牢度のものは得
られなかった。また、紫外線吸収剤を染色液に加えて、
耐光堅牢度を向上させる試みがなされたが、これもよい
結果は得られなかった。Therefore, attempts were made to improve the light fastness by adding iron, aluminum, tin, antimony, and chromium salts to the dye solution, but no product with marketable light fastness could be obtained. Also, by adding a UV absorber to the dyeing solution,
Attempts have been made to improve light fastness, but these too have not yielded good results.
（発明が解決しようとする課題）
本発明はアントシアニンを用いて染色された繊維の耐光
堅牢度を高めることを目的とする。(Problems to be Solved by the Invention) An object of the present invention is to improve the light fastness of fibers dyed using anthocyanins.
（課題を解決するための手段）
即ち、本発明はアントシアニンを含有する染浴液中で繊
維を染色する前後に、パラジウム、セリウム、イツトリ
ウム、ビスマス、白金からなる群から少なくとも１個選
ばれた金属のイオンを含有する溶液中で媒染することを
特徴とする染色方法を提供する。(Means for Solving the Problems) That is, the present invention provides dyeing of at least one metal selected from the group consisting of palladium, cerium, yttrium, bismuth, and platinum before and after dyeing fibers in a dye bath containing anthocyanins. Provided is a dyeing method characterized by mordanting in a solution containing ions.
また、本発明はパラジウム、セリウム、イツトリウム、
ビスマス、白金からなる群から少なくとも１個選ばれた
金属のイオンと、アンドンアニンを含有した溶液中で繊
維を染色することを特徴とする染色方法を提供する。Furthermore, the present invention also provides palladium, cerium, yttrium,
To provide a dyeing method characterized in that fibers are dyed in a solution containing andonanine and at least one metal ion selected from the group consisting of bismuth and platinum.
本発明に使用されるアントシアニンは、通常、花弁や果
皮に含まれるアントシアニンでもいずれでもよいか、鮮
やかな色彩を得ようとする染織用途には、ただ一種の化
合物からなるアンドンアニンが望ましい。通常の生物組
織から採取されるアントシアニンは、複数のアントシア
ニン化合物からなることが知られており、本用途には、
ハナキリン培養細胞の生産するただ一種アンＩ・ンアニ
ンであるンアニジンー３−アラビノシトであることか望
ましい（特開昭５７−２６９７号公報参照）。The anthocyanin used in the present invention may be any anthocyanin normally contained in flower petals or pericarp, or andonanine, which consists of only one type of compound, is preferable for dyeing and weaving applications where bright colors are to be obtained. It is known that anthocyanins collected from normal biological tissues are composed of multiple anthocyanin compounds, and for this purpose,
It is preferable to use anidine-3-arabinosyto, which is the only type of annenin produced by Hanakirin cultured cells (see Japanese Patent Application Laid-Open No. 57-2697).
本発明に使用される繊維は、いずれでもよいが、タンパ
ク質由来の動物繊維である絹や羊毛が赤色染色性の」二
で望ましい結果か得られるか、ポリエステルやアクリル
等の合成繊維であってもよい。The fibers used in the present invention may be of any type, but protein-derived animal fibers such as silk and wool, which are dyeable in red, can yield the desired results, or synthetic fibers such as polyester and acrylic may be used. good.
本発明に使用されるアンドンアニンは、通常、花弁や果
皮に含まれるアントシアニンてもいずれでもよいか、鮮
やかな色彩を得ようとする染織用途には、ただ一種の化
合物からなるアントシアニンか望ましい。通常の生物組
織から採取されるアントシアニンは、複数のアンドンア
ニン化合物からなることが知られており、本用途には、
ノ＼ナキリン培養細胞の生産するただ一種アントシアニ
ンであるシアニジン−３−アラビノシトであることが望
ましい。The andonanine used in the present invention may be any anthocyanin normally contained in flower petals or pericarp, or preferably an anthocyanin consisting of only one type of compound for dyeing and weaving applications where bright colors are to be obtained. It is known that anthocyanins collected from ordinary biological tissues are composed of multiple andonanine compounds, and for this purpose,
It is desirable to use cyanidin-3-arabinocyto, which is the only anthocyanin produced by No\Nakirin cultured cells.
本発明に使用される繊維は、いずれてもよいか、タンパ
ク質由来の動物繊維である絹や羊毛がアントシアニンの
吸着性から望ましい結果が得られる。The fibers used in the present invention may be of any type, but desirable results can be obtained from protein-derived animal fibers such as silk and wool due to their adsorption properties for anthocyanins.
また、ポリエステルやアクリルよりもスルホン化された
ポリエステルやアクリルを用いる方か染色性の」−で望
ましい結果が得られる。In addition, preferable results can be obtained by using sulfonated polyester or acrylic rather than polyester or acrylic, or by using dyeable polyester or acrylic.
本発明に使用される染浴液は、上記アントシアニンの０
０１％（ｗ／ｖ）から１０％（ｗ／ｖ）の溶液（好まし
くは、水溶液）を塩酸等により好ましくはｐＨ４以下に
調整して用いられる。ｐＨが４を越えると耐光堅牢度の
向上が少ない。The dye bath liquid used in the present invention contains 0 of the above anthocyanins.
A solution (preferably an aqueous solution) of 0.01% (w/v) to 10% (w/v) is preferably adjusted to pH 4 or less with hydrochloric acid or the like before use. When the pH exceeds 4, there is little improvement in light fastness.
上記染浴を８０〜９５°Ｃに保ち、の染浴液中に上記繊
維の布あるいは糸を３０分〜２時間浸漬することによっ
て染色する。その後、十分な水洗により染色液を除去し
、風乾させる。更に、得られた染織布をパラジウム、セ
リウム、イツトリウム、ビスマス、白金からなる群から
少なくとも１個選ばれた金属のイオンを含有する溶液（
好ましくは、水溶液）に、２５°Ｃで５分〜２時間浸漬
し、媒染する。上記金属含有溶液は、通常の市販試薬、
例えば金属がパラ７ウムであれば、塩化パラジウム、セ
リウムであれば、硫酸セリウムアンモニウム、イアトリ
ウムであれば、塩化イツトリウム、ビスマスであれば塩
化ビスマス、白金てあれば、塩化白金酸カリウムを０．
１〜１０％（ｗ／ｖ）イオン交換水に溶解させて調整す
る。溶液のｐＨか７以上の場合、通常塩酸なとの酸を用
いてｐＨ７以下に調整する。アンドンアニンに対して上
記金属以外の金属を用いた場合、所望の耐光堅牢度は得
られない。The dyeing bath is maintained at 80 to 95° C., and the cloth or thread of the fiber is immersed in the dye bath solution for 30 minutes to 2 hours to dye. Thereafter, the dyeing solution is removed by thorough washing with water, and the material is air-dried. Furthermore, the obtained dyed and woven fabric is treated with a solution containing at least one metal ion selected from the group consisting of palladium, cerium, yttrium, bismuth, and platinum (
Preferably, it is immersed in an aqueous solution at 25° C. for 5 minutes to 2 hours to mordant. The above-mentioned metal-containing solution is a common commercially available reagent,
For example, if the metal is palladium, palladium chloride, cerium, cerium ammonium sulfate, yatrium, yttrium chloride, bismuth, bismuth chloride, and platinum, potassium chloroplatinate.
Adjust by dissolving 1-10% (w/v) in ion-exchanged water. If the pH of the solution is 7 or higher, it is usually adjusted to 7 or lower using an acid such as hydrochloric acid. If a metal other than the above metals is used for andonanine, the desired light fastness cannot be obtained.
上記金属イオンによる媒染は染色の前に行っても同し結
果が得られる。また、アント／アニン染色液中に上記金
属イオンか同量存在しても同じ結果が得られる。The same results can be obtained even if mordanting with the metal ions is carried out before dyeing. Furthermore, the same results can be obtained even if the same amount of the above metal ions is present in the ant/anine staining solution.
得られた染織布あるいは染織糸について、ＪＪ−ポンア
ーク燈による耐光試験（ＪＩＳ−Ｌ−８４２）を行い、
耐光堅牢度を確認する。The obtained dyed and woven fabric or dyed and woven thread was subjected to a light resistance test (JIS-L-842) using a JJ-Pon arc lamp.
Check light fastness.
（発明の効果）
本発明の方法により、アントシアニン染色繊維の耐光堅
牢度が、従来１級以下から３級へ向上が見られ、市場価
値が高まった。(Effects of the Invention) By the method of the present invention, the light fastness of anthocyanin-dyed fibers was improved from the conventional grade 1 or lower to grade 3, and the market value increased.
（実施例）
本発明を実施例により更に詳細に説明する。本発明はこ
れら実施例に限定されない。(Example) The present invention will be explained in more detail with reference to Examples. The invention is not limited to these examples.
実施例１
ｐＨ２の塩酸酸性水溶液１０００ｆｆＣに乾燥ノ＼ナキ
リン培養細胞２０９を浸漬し、濾過して得られたＯ用％
シアニジン３−アラビノシト水溶液１０００ｙｔρに、
塩化すトリウム１ｇを添加して塩酸て染浴液をｐ＋−＋
２に調整した。１０００屑ρカラスビーカーに染浴液を
移し、９５°Ｃに保温した。染浴液中に５ｃｍ四方の絹
布あるいは羊毛布各５枚を１時間浸漬し染色した。染織
布を取り出し流水中に浸して十分に染色液を除いた後、
風乾して水分を除去した。塩化パラジウト、硫酸セリウ
ムアンモニウム、塩化イツトリウム、塩化ビスマス、塩
化白金酸カリウムそれぞれ１ｇを各１００ｍＱのイオン
交換水に溶解させ、その２５°Ｃ溶液に得られたアント
シアニン染色絹布あるいは羊毛布を１時間浸漬した。染
色布を取り出し流水中に浸して十分に媒染液を除いた後
、風乾して水分を除去した。Example 1 % O obtained by immersing dried Nakyrin cultured cells 209 in 1000 ffC of an acidic aqueous solution of hydrochloric acid at pH 2 and filtering it.
Cyanidin 3-arabinosite aqueous solution 1000ytρ,
Add 1g of thorium chloride to make the dye bath solution p+-+ with hydrochloric acid.
Adjusted to 2. The dye bath solution was transferred to a 1000 ml glass beaker and kept at 95°C. Five pieces of silk cloth or wool cloth each measuring 5 cm square were immersed in the dye bath solution for 1 hour and dyed. After taking out the dyed fabric and soaking it in running water to thoroughly remove the dyeing solution,
Water was removed by air drying. 1 g each of palladium chloride, cerium ammonium sulfate, yttrium chloride, bismuth chloride, and potassium chloroplatinate was dissolved in 100 mQ of ion-exchanged water, and the resulting anthocyanin-dyed silk or wool cloth was immersed in the 25°C solution for 1 hour. . The dyed cloth was taken out and soaked in running water to thoroughly remove the mordant, and then air-dried to remove moisture.
染色性と耐光性を観察した。結果を表−１に示す。The dyeability and light fastness were observed. The results are shown in Table-1.
実施例２
塩化パラジウム、硫酸セリウムアンモニウム、塩化イッ
トリウｔ・、塩化ビスマス、塩化白金酸カノウムそれぞ
れ１ｇを各１００１Ｃのイオン交換水に溶解させ、その
２５°Ｃ溶液に５ｃｍ四方絹布あるいは羊毛布を１時間
浸漬した。染色布を取り出し流水中に浸して上針に媒染
液を除いた後、風乾して水分を除去した。ｐＨ２の塩酸
酸性水溶液１００（ＪＪｔｔｒＱに乾燥ハナキリン培養
細胞２０ｇを浸漬し、濾過して得られた０、１％シアニ
ジン３−アラビノシト水ｍ液］ ０００ ｍＱに、塩化
ナトリウム１ｇを添加して塩酸で染浴液をｐＨ４に調整
した。各２００１１Ｑガラスビーカーに染浴液を移し、
９５°Ｃに保温した。染浴液中に媒染済みの絹布あるい
は羊毛布各５枚を１時間浸漬し染色した。染織布を取り
出し流水中に浸して十分に染色液を除いた後、風乾して
水分を除去した。染色性と耐光性を観察した。結果を表
−１に示す。Example 2 1 g each of palladium chloride, cerium ammonium sulfate, yttrium chloride, bismuth chloride, and kanium chloroplatinate was dissolved in 1001C ion-exchanged water, and a 5cm square piece of silk or wool cloth was placed in the 25°C solution for 1 hour. Soaked. The dyed cloth was taken out and immersed in running water to remove the mordant on the top needle, and then air-dried to remove moisture. Add 1 g of sodium chloride to 100 m of an acidic hydrochloric acid solution at pH 2 (0.1% cyanidin 3-arabinocyto aqueous solution obtained by immersing 20 g of dried Hanakirin cultured cells in JJttrQ and filtering it), and dye with hydrochloric acid. The bath solution was adjusted to pH 4. Transfer the dye bath solution to each 20011Q glass beaker,
The temperature was kept at 95°C. Five pieces of mordanted silk or wool cloth were immersed in the dye bath solution for one hour and dyed. The dyed fabric was taken out and soaked in running water to thoroughly remove the dyeing solution, and then air-dried to remove water. The dyeability and light fastness were observed. The results are shown in Table-1.
実施例３
ｐＨ２の塩酸酸性水溶液１’０ＯＯＩＷ１２に乾燥ハナ
キリン培養細胞２０ｇを浸漬し、濾過して得られた０
１％シアニジン３−アラビノシト水溶液１０００ｘｆ２
に、塩化ナトリウム１ｇを添加し、更に、２０ＯＩＣづ
つビーカーに分け、塩化パラジウム、硫酸セリウムアン
モニウム、塩化イツトリウム、塩化ビスマス、塩化白金
酸カリウムそれぞれ１ｇを溶解させ、塩酸でｐＨ４に調
整した。その各９５°Ｃ溶液に５ｃｍ四方絹布あるいは
羊毛布を１時間浸漬した。染色布を取り出し流水中に浸
して十分に染色液を除いた後、風乾して水分を除去した
。Example 3 20 g of dried Hanakirin cultured cells were immersed in a pH 2 hydrochloric acid acidic aqueous solution 1'0OOIW12 and filtered.
1% cyanidin 3-arabinosite aqueous solution 1000xf2
To the solution, 1 g of sodium chloride was added, and 20 OIC was divided into beakers, and 1 g each of palladium chloride, ammonium cerium sulfate, yttrium chloride, bismuth chloride, and potassium chloroplatinate were dissolved therein, and the pH was adjusted to 4 with hydrochloric acid. A 5 cm square piece of silk or wool cloth was immersed in each of the 95°C solutions for 1 hour. The dyed fabric was taken out and soaked in running water to remove the dyeing solution sufficiently, and then air-dried to remove water.
染色性と耐光性を観察した。結果を表−１に示す。The dyeability and light fastness were observed. The results are shown in Table-1.
参考例１
実施例１中の塩化パラジウム、硫酸セリウムアンモニウ
ム、塩化イツトリウム、塩化ビスマス、塩化白金酸カリ
ウムを酢酸鉄、酢酸銅、クロムミョウバン、アルミミョ
ウバンに変更スル。Reference Example 1 Palladium chloride, cerium ammonium sulfate, yttrium chloride, bismuth chloride, and potassium chloroplatinate in Example 1 were replaced with iron acetate, copper acetate, chromium alum, and aluminum alum.
参考例２
実施例２中の塩化パラジウム、硫酸セリウムアンモニウ
ム、塩化イツトリウム、塩化ヒスマス、塩化白金酸カリ
ウムを酢酸鉄、酢酸銅、クロムミョウバン、アルミミョ
ウバンに変更スル。Reference Example 2 Palladium chloride, cerium ammonium sulfate, yttrium chloride, hismuth chloride, and potassium chloroplatinate in Example 2 were replaced with iron acetate, copper acetate, chromium alum, and aluminum alum.
参考例３
実施例３中の塩化パラジウム、硫酸セリウムアンモニウ
ム、塩化イツトリウム、塩化ビスマス、塩化白金酸カリ
ウムを酢酸鉄、酢酸銅、クロムミョウバン、アルミミョ
ウバンに変更する。Reference Example 3 Palladium chloride, ammonium cerium sulfate, yttrium chloride, bismuth chloride, and potassium chloroplatinate in Example 3 were replaced with iron acetate, copper acetate, chromium alum, and aluminum alum.
Claims (1)
る前後に、パラジウム、セリウム、イットリウム、ビス
マス、白金からなる群から少なくとも１個選ばれた金属
のイオンを含有する溶液中で媒染することを特徴とする
染色方法。 ２、パラジウム、セリウム、イットリウム、ビスマス、
白金からなる群から少なくとも１個選ばれた金属のイオ
ンと、アントシアニンを含有した溶液中で繊維を染色す
ることを特徴とする染色方法。[Claims] 1. A solution containing ions of at least one metal selected from the group consisting of palladium, cerium, yttrium, bismuth, and platinum before and after dyeing fibers in a dye bath containing anthocyanins. A dyeing method characterized by mordanting. 2. Palladium, cerium, yttrium, bismuth,
A dyeing method comprising dyeing fibers in a solution containing anthocyanin and at least one metal ion selected from the group consisting of platinum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003144A JPH03213588A (en) | 1990-01-10 | 1990-01-10 | Dyeing of yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003144A JPH03213588A (en) | 1990-01-10 | 1990-01-10 | Dyeing of yarn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03213588A true JPH03213588A (en) | 1991-09-18 |
Family
ID=11549160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003144A Pending JPH03213588A (en) | 1990-01-10 | 1990-01-10 | Dyeing of yarn |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03213588A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281479A (en) * | 2004-03-30 | 2005-10-13 | Kakuyokai | Dye solution containing anthocyanin pigment and dyeing process using the same |
| CN108978078A (en) * | 2018-07-13 | 2018-12-11 | 杨传平 | A kind of textile cloth dyeing apparatus of recoverable dyestuff |
-
1990
- 1990-01-10 JP JP2003144A patent/JPH03213588A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281479A (en) * | 2004-03-30 | 2005-10-13 | Kakuyokai | Dye solution containing anthocyanin pigment and dyeing process using the same |
| JP4526846B2 (en) * | 2004-03-30 | 2010-08-18 | 財団法人覚誉会 | Dye solution containing anthocyanin pigment and dyeing method using the same |
| CN108978078A (en) * | 2018-07-13 | 2018-12-11 | 杨传平 | A kind of textile cloth dyeing apparatus of recoverable dyestuff |
| CN108978078B (en) * | 2018-07-13 | 2021-08-27 | 浙江银梭织染股份有限公司 | Textile fabric dyeing device capable of recycling dye |
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