JPH03199433A - Ring for spinning frame - Google Patents
Ring for spinning frameInfo
- Publication number
- JPH03199433A JPH03199433A JP33756389A JP33756389A JPH03199433A JP H03199433 A JPH03199433 A JP H03199433A JP 33756389 A JP33756389 A JP 33756389A JP 33756389 A JP33756389 A JP 33756389A JP H03199433 A JPH03199433 A JP H03199433A
- Authority
- JP
- Japan
- Prior art keywords
- ring
- surface layer
- traveler
- layer
- carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 24
- 239000002344 surface layer Substances 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000007747 plating Methods 0.000 claims abstract description 12
- 229910001096 P alloy Inorganic materials 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims abstract description 10
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011651 chromium Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 4
- 150000001247 metal acetylides Chemical class 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 8
- 229910045601 alloy Inorganic materials 0.000 abstract description 6
- 239000000956 alloy Substances 0.000 abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052742 iron Inorganic materials 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 238000005255 carburizing Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- FXNGWBDIVIGISM-UHFFFAOYSA-N methylidynechromium Chemical group [Cr]#[C] FXNGWBDIVIGISM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は高速精紡に於いて優れた性能を発揮する紡機用
リングに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a ring for a spinning machine that exhibits excellent performance in high-speed spinning.
〔従来の技術及び発明が解決しようとする課題〕従来の
紡機用リングは、一般に低炭素鋼が用いられ、表面硬化
処理として浸炭焼入れ処理が行なわれている。しかし、
上記リングでは、スピンドル回転数が20.000 r
、p、m以上(現在の高速回転は、17.000 r、
p、m、−18,000r、p、m、)では、リングと
トラベラの摩擦抵抗の増大と摩擦熱の急激な上昇のため
、トラベラが早期に焼付き飛散し、連続運転が出来ない
という欠点があった。[Prior Art and Problems to be Solved by the Invention] Conventional rings for spinning machines are generally made of low carbon steel, and are subjected to carburizing and quenching as a surface hardening process. but,
In the above ring, the spindle rotation speed is 20.000 r
, p, m or more (current high speed rotation is 17,000 r,
p, m, -18,000r, p, m,), due to the increase in frictional resistance between the ring and the traveler and the rapid rise in frictional heat, the traveler seizes up early and scatters, making continuous operation impossible. was there.
この為、クロムを含む合金鋼に焼入れ処理、または浸炭
焼入れ処理か行なわれているが、上記問題点を解決する
には至っていない。For this reason, alloy steels containing chromium are subjected to quenching or carburizing, but this has not yet solved the above problems.
本発明は上記問題点を解決し、高速回転における耐摩耗
性を向上し、連続運転の可能な紡機用リングを得ること
を目的とするものである。The object of the present invention is to solve the above-mentioned problems and provide a ring for a spinning machine that has improved wear resistance during high-speed rotation and is capable of continuous operation.
本発明は、クロムを0.9〜26%含む合金鋼を用いて
所定のリング形状に形成し、少なくともトラベラの摺動
面に、浸炭焼入れにより炭素量が1.5〜5%を有し、
球状化した炭化物か表面に突出した表層を設け、上記表
層に続き順次炭素量が減少する層を形成し、さらに上記
表層の表面に被膜硬度がHv800〜1100を有する
ニッケル・リン合金メンキ層を形成した紡機用リングを
提供するものであり、上記紡機用リングの表層の球状化
した炭化物の量が面積率で30〜90%とし、またはト
ラベラ摺動面の中心線平均粗さRaが0.25.m以下
、あるいはニッケル・リン合金メンキ層の厚さが2〜l
Q4とした紡機用リングを提供するものである。The present invention uses alloy steel containing 0.9 to 26% chromium to form a predetermined ring shape, and at least the sliding surface of the traveler has a carbon content of 1.5 to 5% by carburizing and quenching.
A protruding surface layer of spheroidal carbide is provided on the surface, a layer in which the amount of carbon decreases sequentially is formed following the surface layer, and a nickel-phosphorus alloy coating layer having a coating hardness of Hv800 to 1100 is further formed on the surface of the surface layer. The present invention provides a ring for a spinning machine, in which the amount of spheroidized carbide on the surface layer of the ring for a spinning machine is 30 to 90% in terms of area ratio, or the center line average roughness Ra of the traveler sliding surface is 0.25. .. m or less, or the thickness of the nickel-phosphorus alloy coating layer is 2 to 1
The present invention provides a spinning machine ring of Q4.
以下本発明の一実施例を図面に基づいて説明する。 An embodiment of the present invention will be described below based on the drawings.
Cr:1.5%、C:1%を含む高炭素クロム軸受w4
(SUJ−2)を切削し、所定のリング形状に形成した
後、ガス浸炭を8800cx15時間行ない、850°
Cより油中で焼入れした後、−50°Cでサブゼロ処理
を行ない、その後200 ’Cで3時間焼戻しを行なう
。次いで、濃度20%の塩酸に浸漬して表層部の鉄素地
を侵蝕させ、第1図に示すように鉄素地(1)の表面に
炭、化物(2)を突出させた後、ニッケル・リン合金メ
ンキを行ない、表面にニッケル・リン合金メッキ層(3
)を形成する。High carbon chromium bearing w4 containing Cr: 1.5%, C: 1%
After cutting (SUJ-2) and forming it into a predetermined ring shape, gas carburization was performed at 8800 cx for 15 hours, and 850°
After quenching in oil at temperature C, subzero treatment is performed at -50°C, and then tempering is performed at 200'C for 3 hours. Next, the surface layer of the iron substrate is eroded by immersion in 20% hydrochloric acid to cause carbon and compounds (2) to protrude from the surface of the iron substrate (1) as shown in Figure 1, and then nickel and phosphorus are added. Alloy coating is performed, and the surface is coated with a nickel-phosphorus alloy plating layer (3
) to form.
次いで、熱処理炉において約400℃で約1時間加熱処
理して表面の被膜硬度がHv800〜1100を有する
紡機用リングを形成する。Next, the ring is heat-treated at about 400° C. for about 1 hour in a heat-treating furnace to form a spinning machine ring having a surface coating hardness of 800 to 1100 Hv.
更に好ましくは、トラベラが接触、摺動するフランジ表
面を研磨加工し、中心線平均粗さか0.257J以下の
平滑な表面で、かつ炭化物とニッケル・リン合金メッキ
の共存する紡機用リングを形成する3゜
又、上記実施例において、ニッケル・リン合金メンキ層
(3)の厚さは2〜IO/R1とするのが好ましいもの
である。More preferably, the flange surface on which the traveler contacts and slides is polished to form a ring for a spinning machine that has a smooth surface with a center line average roughness of 0.257 J or less and has carbide and nickel-phosphorus alloy plating coexisting. 3. In the above embodiment, the thickness of the nickel-phosphorus alloy coating layer (3) is preferably 2 to IO/R1.
なお、上記サブゼロ処理のかわりに840°Cより二次
焼入れを行なってもよい。また、浸炭温度は930°C
以下が望ましく、930℃より高いと、素地が粗大化し
、粒界に沿って塊状の大きな炭化物が析出し、トラベラ
の走行中にクラックを発生し、摩耗が生じ易くなる。Note that, instead of the above-mentioned sub-zero treatment, secondary hardening may be performed at 840°C. In addition, the carburizing temperature is 930°C
The temperature below is desirable. If the temperature is higher than 930°C, the base material will become coarse and large lumpy carbides will precipitate along the grain boundaries, causing cracks to occur while the traveler is running, making it easy to wear.
本発明の紡機用リングは第2図に示すように少なくとも
0.05mmの表層は炭素量が1.5〜5°6で表層に
引続き順次炭素量が減少している。As shown in FIG. 2, the ring for spinning machines of the present invention has a carbon content of 1.5 to 5°6 in the surface layer of at least 0.05 mm, and the carbon content decreases successively from the surface layer.
また、表面居は球状の炭化物が分散したマルテフザイト
組織となる。In addition, the surface structure is a maltefuzite structure in which spherical carbides are dispersed.
さらに、分散した炭化物の量は表層より深さ0.05m
m までの部分で面積率で炭化物が30〜90%を占め
、望ましくは40〜70%程度となるこが良く、少ない
と耐摩耗性の効果が少なく、多いと靭性が悪くなり、剥
離やクラックの原因となり易い。Furthermore, the amount of dispersed carbide is 0.05 m below the surface layer.
The area ratio of carbides in the area up to m2 should be 30 to 90%, preferably about 40 to 70%.If the amount is too low, the wear resistance effect will be small, and if the amount is too high, the toughness will deteriorate, resulting in peeling and cracking. It is easy to cause this.
また、表層0.05mm程度までの層の炭素含有量は1
.5〜5%が適当であり、望ましくは2〜4%が最も良
い範囲となる。なお、1.5%未満では炭化物の量が少
なく、耐摩耗性や耐疲労性の効果が少ない。また、炭素
含有量が多いと、炭化物の析出が多くなり過ぎて靭性が
劣る様になる。In addition, the carbon content of the surface layer up to about 0.05 mm is 1
.. A suitable range is 5 to 5%, preferably 2 to 4%. Note that if it is less than 1.5%, the amount of carbide is small and the effects on wear resistance and fatigue resistance are small. Moreover, if the carbon content is high, carbide precipitation will be too large, resulting in poor toughness.
また、素材のCr量は0.9〜26%が望ましく、0.
9%未満では炭化物が球状化し難く、網状に析出し、耐
摩耗性、耐疲労性が悪くなり、26%以上では浸炭に時
間がかかり、また素材コストの面でも高価なものとなる
。Further, the Cr content of the material is preferably 0.9 to 26%, and 0.9% to 26%.
If it is less than 9%, it is difficult for the carbide to become spheroidized and precipitate in a network shape, resulting in poor wear resistance and fatigue resistance. If it is more than 26%, carburizing takes time and the material cost becomes expensive.
炭化物を突出させる方法としては、本発明の実施例に用
いたような化学的方法が有効であるか、ジョンドブラス
ト加工のような機械的な方法でもよい。As a method for protruding the carbide, a chemical method such as that used in the embodiments of the present invention is effective, or a mechanical method such as John deblasting may be used.
合金メンキ層の厚さは、5〜10μmとしたが、5序よ
り小さい場合には、合金メッキの効果が十分に発揮され
ず、トラベラの早期摩耗、焼付きの原因となり、10/
Jlを超える場合には表面の荒れ、メンキの剥離の原因
となる。The thickness of the alloy plating layer was set to 5 to 10 μm, but if it is smaller than 5 μm, the effect of the alloy plating will not be fully exhibited, causing early wear and seizure of the traveler, and the thickness will be 10/10 μm.
If it exceeds Jl, it will cause surface roughness and peeling of the coating.
また、本発明の紡機用リングのトラベラ接触部の表面粗
さを研磨により中心線平均粗さRaを0.25un以下
にすると、第3図に示すようにトラベラの摩耗が減少し
、高速条件でもトラベラの寿命が長く、安定した紡出が
長時間持続される。Furthermore, when the surface roughness of the traveler contacting part of the ring for a spinning machine of the present invention is polished to a center line average roughness Ra of 0.25 un or less, the wear of the traveler is reduced as shown in Fig. 3, even under high-speed conditions. The life of the traveler is long and stable spinning can be maintained for a long time.
なお、中心線平均粗さの測定条件は先端R=2/@の触
針を用い、カントオフ値λc−0,25mm 、測定長
さL=0.8mm、 ドライブスピード0.1mm/
Sとしたものである。The conditions for measuring the center line average roughness are as follows: using a stylus with tip R = 2/@, cant-off value λc - 0.25 mm, measurement length L = 0.8 mm, drive speed 0.1 mm/
It is designated as S.
次に上記本発明の紡機用リング(4)と従来のクロムを
含む合金鋼に浸炭焼入れを行なった紡機用リング(B)
を用いて、次の条件にて比較テストを行なった。Next, the spinning machine ring (4) of the present invention and the conventional spinning machine ring (B) obtained by carburizing and quenching alloy steel containing chromium.
A comparative test was conducted using the following conditions:
糸 : エステル/綿 45′S
リング : 3.2mmF 41mmuX57.5
mm$mmへラ: ys−2/hrl110 にッ
ケルメンキ品)スピンドル回転数: 16,000r、
p、m−30,00Or、p、m第4図に上記紡出条件
での各スピンドル回転数でのトラベラとリングの摩擦抵
抗指数を示す。Thread: Ester/cotton 45'S Ring: 3.2mmF 41mmuX57.5
mm$mm spatula: ys-2/hrl110 Nikkermenki product) Spindle rotation speed: 16,000r,
p, m - 30,00 Or, p, m Figure 4 shows the frictional resistance index of the traveler and ring at each spindle rotation speed under the above spinning conditions.
スピンドル回転が16.000r、p、m −18。Spindle rotation is 16.000r, p, m -18.
000 r、p、mまでは、本発明リング(4)と従来
リング(I3)には大きな差はなく、摩擦抵抗指数の著
しい上昇も認められない。000 r, p, and m, there is no significant difference between the ring of the present invention (4) and the conventional ring (I3), and no significant increase in the frictional resistance index is observed.
スピンドル回転数がl 8.00 Or、p、mを超え
ると、従来リング[F])の摩擦抵抗指数は上昇し始め
るが、本発明のリング(4)は緩やかである。さらに2
0.000 r、p、m以上になると従来リングの摩擦
抵抗指数は急激に上昇し始め、24.OQ Q r、p
、m以上では、トラベラの焼付き、摩耗が進行し、連続
紡出が不可能となる。When the spindle rotation speed exceeds l 8.00 Or, p, m, the frictional resistance index of the conventional ring [F]) begins to rise, but the ring (4) of the present invention does so gradually. 2 more
At 0.000 r, p, m or more, the frictional resistance index of the conventional ring begins to rise rapidly. OQ Q r,p
, m or more, seizure and wear of the traveler progress, making continuous spinning impossible.
これに対し本発明のリング(4)は、スピンドル回転数
が24.000r、p、m 30.000r、p、m
の高速域に於いても急激な上昇は見られず、安定した低
い摩擦抵抗指数を示し、24.000r、p、m −3
0、000r、p−mでもトラベラの摩耗も殆どなく、
連続紡出が可能となった。On the other hand, the ring (4) of the present invention has a spindle rotation speed of 24.000 r, p, m and 30.000 r, p, m.
No sudden increase was observed even in the high speed range of
There is almost no wear on the traveler even at 0,000 r/pm.
Continuous spinning became possible.
本発明は上記の如く、炭化物とニッケル・リン合金メッ
キの共存体を形成すると共に、合金メンキの硬度をHv
80(1〜1100とし、更に表面の粗さをR・で0.
25低以下に形成してし・るので、スピンドル回転数2
4.00 Or、p、m以上の超高速域においてもなじ
みがよく、安定した連続運転が可能となり、トラベラ焼
けが発生せず、トラベラ寿命も延長することができる。As described above, the present invention forms a coexistence of carbide and nickel-phosphorus alloy plating, and also increases the hardness of the alloy plating by Hv.
80 (1 to 1100, and further the surface roughness is R・0.
Since it is formed to be less than 25, the spindle rotation speed is 2.
It has good adaptability even at ultra-high speeds of 4.00 Or, p, m or higher, enables stable continuous operation, prevents traveler burn, and extends the life of the traveler.
また、研磨加工をすることにより、トラベラとの接触表
面に硬質微粒子を露出させているのでリングの耐摩耗性
も向上し、リングの寿命を延長する。Furthermore, by polishing, hard particles are exposed on the surface that contacts the traveler, which improves the wear resistance of the ring and extends its lifespan.
更にメッキ処理後、熱処理を施しているので、メッキ層
の剥離もない等の優れた効果を有する発明である。Furthermore, since heat treatment is performed after plating, this invention has excellent effects such as no peeling of the plating layer.
第1図は本発明の紡機用リングの一実施例を示すトラベ
ラとの摺動面における要部断面図、第2図はリング表面
からの深さと炭素濃度の関係を示す曲線図、第3図はト
ラベラ摩耗量と表面粗さとの関係を示す曲線図、第4図
はスピンドル回転数と摩擦抵抗指数との関係を示す曲線
図である。
(1)・・・・・・鉄素地 (2)・・・・・
・炭化物(3)・・・・・・ニンケル・リン合金メンキ
層第
1
図
第
図
0、J O,20,30,40,50,6表面カゝらの
;渠さ (用J叱)
第
図
O3l
z
3
中+15’碌平均組−v(Rαμ加)
第
図
スピンドル
( r.p 、…〕Fig. 1 is a cross-sectional view of the main part of a ring for a spinning machine according to an embodiment of the present invention on the sliding surface with a traveler, Fig. 2 is a curve diagram showing the relationship between depth from the ring surface and carbon concentration, Fig. 3 4 is a curve diagram showing the relationship between traveler wear amount and surface roughness, and FIG. 4 is a curve diagram showing the relationship between spindle rotation speed and frictional resistance index. (1)・・・Iron base (2)・・・・・・
・Carbide (3)・・・Ninkel-phosphorus alloy coating layer 1 Figure 0, J O, 20, 30, 40, 50, 6 surface areas; Figure O3l z 3 Medium+15' average group -v (Rαμ added) Figure spindle (r.p,...]
Claims (4)
定のリング形状に形成し、少なくともトラベラの摺動面
に、浸炭焼入れにより炭素量が1.5〜5%を有し、球
状化した炭化物が表面に突出した表層を設け、上記表層
に続き順次炭素量が減少する層を形成し、さらに上記表
層の表面に被膜硬度がHv800〜1100を有するニ
ッケル・リン合金メッキ層を形成してなることを特徴と
する紡機用リング。(1) A predetermined ring shape is formed using alloy steel containing 0.9 to 26% chromium, and at least the sliding surface of the traveler is carburized and quenched to have a carbon content of 1.5 to 5%, and a spherical shape is formed. A surface layer in which the carbonized carbide protrudes on the surface is provided, a layer in which the amount of carbon gradually decreases is formed following the surface layer, and a nickel-phosphorus alloy plating layer having a coating hardness of Hv800 to 1100 is further formed on the surface of the surface layer. A ring for spinning machines that is characterized by its shape.
0〜90%である請求項1記載の紡機用リング。(2) The amount of spheroidized carbides in the surface layer is 3 in terms of area ratio.
The ring for a spinning machine according to claim 1, which has a content of 0 to 90%.
5μm以下である請求項1または2記載の紡機用リング
。(3) Center line average roughness Ra of traveler sliding surface is 0.2
The ring for a spinning machine according to claim 1 or 2, which has a diameter of 5 μm or less.
μmである請求項1,2または3記載の紡機用リング。(4) The thickness of the nickel-phosphorus alloy plating layer is 2 to 10
The ring for a spinning machine according to claim 1, 2 or 3, which has a diameter of μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33756389A JPH03199433A (en) | 1989-12-26 | 1989-12-26 | Ring for spinning frame |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33756389A JPH03199433A (en) | 1989-12-26 | 1989-12-26 | Ring for spinning frame |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03199433A true JPH03199433A (en) | 1991-08-30 |
Family
ID=18309823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP33756389A Pending JPH03199433A (en) | 1989-12-26 | 1989-12-26 | Ring for spinning frame |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03199433A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016117935A (en) * | 2014-12-22 | 2016-06-30 | 株式会社不二製作所 | Surface treatment method for sliding member, and sliding member |
KR20160101015A (en) * | 2013-12-19 | 2016-08-24 | 그로츠-베케르트 카게 | Tool for textiles and production method for same |
-
1989
- 1989-12-26 JP JP33756389A patent/JPH03199433A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160101015A (en) * | 2013-12-19 | 2016-08-24 | 그로츠-베케르트 카게 | Tool for textiles and production method for same |
US20160319472A1 (en) * | 2013-12-19 | 2016-11-03 | Groz-Beckert Kg | Tool For Textiles and Production Method for Same |
US10487429B2 (en) * | 2013-12-19 | 2019-11-26 | Groz-Beckert Kg | Tool for textiles and production method for same |
JP2016117935A (en) * | 2014-12-22 | 2016-06-30 | 株式会社不二製作所 | Surface treatment method for sliding member, and sliding member |
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