JPH03182596A - Liquid detergent composition for floor - Google Patents
Liquid detergent composition for floorInfo
- Publication number
- JPH03182596A JPH03182596A JP32287889A JP32287889A JPH03182596A JP H03182596 A JPH03182596 A JP H03182596A JP 32287889 A JP32287889 A JP 32287889A JP 32287889 A JP32287889 A JP 32287889A JP H03182596 A JPH03182596 A JP H03182596A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- active agent
- surface active
- floor
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract description 18
- 239000007788 liquid Substances 0.000 title description 10
- 239000003599 detergent Substances 0.000 title description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims abstract description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 abstract description 22
- -1 polyoxyethylene lauryl ether Polymers 0.000 abstract description 8
- 239000004094 surface-active agent Substances 0.000 abstract description 5
- 125000000129 anionic group Chemical group 0.000 abstract description 3
- 239000004575 stone Substances 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はフロア−用液体洗浄剤組成物、更に詳しくは特
にテラゾー、大理石等の石型の床表面の汚れを洗浄する
のに適した液体洗浄剤組成物に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a liquid cleaning composition for floors, and more specifically, a liquid suitable for cleaning stains on stone-shaped floor surfaces such as terrazzo and marble. The present invention relates to a cleaning composition.
床表面の洗浄にはアニオン、ノニオン等の界面活性剤を
配合した中性液体洗浄剤或いはこれに溶剤類を配合した
洗浄剤が広く使われている。For cleaning floor surfaces, neutral liquid cleaning agents containing anionic and nonionic surfactants, or cleaning agents containing solvents are widely used.
これらの洗浄剤は木、ビニールタイル等の床の汚れの除
去に適している。しかし、近年普及しつつあるテラゾー
、大理石等の石型の床表面の汚れに対する洗浄性能は未
だ十分でない。These cleaning agents are suitable for removing stains from floors such as wood and vinyl tiles. However, cleaning performance for stains on stone-shaped floor surfaces such as terrazzo and marble, which have become popular in recent years, is still insufficient.
本発明者らは前記課題を解決すべく鋭意研究した結果、
ヒドロキシアルキルセルロースを配合した洗剤が石型表
面の汚れの除去効果に優れており、しかも洗浄後の表面
に好ましい仕上がり感（艶）を与え、べたつきも少ない
ことを見出し本発明を完成するに至った。As a result of intensive research by the present inventors to solve the above problems,
The inventors discovered that a detergent containing hydroxyalkyl cellulose has an excellent effect on removing dirt from the surface of stone molds, gives a desirable finish (gloss) to the surface after cleaning, and is less sticky, leading to the completion of the present invention. .
すなわち本発明は、
（ａ） アニオン界面活性剤 １〜５重量％Ｃ
ｂ）ノニオン界面活性剤 ２〜１０重量％（ｃ）
ヒドロキシアルキルセルロース０．１〜２重量％
（２） 低級アルコール １〜５重量％を
含有し、且つｐＨが９〜１２であることを特徴とするフ
ロア−用液体洗浄剤＆ｌ１ｔｃ物を提供するものである
。That is, the present invention provides: (a) anionic surfactant 1 to 5% by weight C
b) Nonionic surfactant 2-10% by weight (c)
To provide a liquid cleaning agent for floors containing 0.1 to 2% by weight of hydroxyalkylcellulose (2) 1 to 5% by weight of lower alcohol and having a pH of 9 to 12. be.
本発明に用いられる（ａ）成分のアニオン界面活性剤と
してはアルキルベンゼンスルホン酸塩、α−オレフィン
スルホン酸塩、アルキル硫酸塩、アルキルエーテル硫酸
塩、アルカンスルホン酸塩等が挙げられる。これらの中
でも洗浄性能、コスト等の面より炭素数９〜１４のアル
キルベンゼンスルホン酸塩が特に好ましい。アニオン界
面活性剤は組成物中に１〜５重量％配合される。Examples of the anionic surfactant as component (a) used in the present invention include alkylbenzene sulfonates, α-olefin sulfonates, alkyl sulfates, alkyl ether sulfates, alkanesulfonates, and the like. Among these, alkylbenzene sulfonates having 9 to 14 carbon atoms are particularly preferred in terms of cleaning performance, cost, and the like. The anionic surfactant is blended in the composition in an amount of 1 to 5% by weight.
本発明に用いられる（口）成分のノニオン界面活性剤と
してはポリオキシエチレンアルキルエーテル、ポリオキ
シエチレンアルキルフェニルエーテル等が特に有用であ
る。ノニオン界面活性剤はＨＬＢが９以上、好ましくは
１１〜１３の範囲にあるものが洗浄性能の面で望ましい
。ノニオン界面活性剤は組成物中に２〜１０重量％配合
される。Particularly useful nonionic surfactants as the (oral) component used in the present invention are polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, and the like. The nonionic surfactant preferably has an HLB of 9 or more, preferably in the range of 11 to 13, from the viewpoint of cleaning performance. The nonionic surfactant is blended in the composition in an amount of 2 to 10% by weight.
上記界面活性剤は（ａ）／ （ｂ）重量比で１／１〜１
／８の範囲で使用するのが洗浄性能、起泡性能の面で最
も好ましい。The above surfactant has a (a)/(b) weight ratio of 1/1 to 1.
It is most preferable to use it within the range of /8 in terms of cleaning performance and foaming performance.
本発明に用いられる（ｃ）成分のヒドロキシアルキルセ
ルロースとしてはヒドロキシメチルセルロース、ヒドロ
キシエチルセルロース等カ挙ケられる。ヒドロキシアル
キルセルロースは２５℃、１％濃度の水溶液が約１００
〜５０００センチボイズの粘度を有し、アルキル置換度
（ＤＳ）が０．８〜１．５の範囲にあるものが好適に用
いられる。これらヒドロキシアルキルセルロースは洗浄
性［向上させ、石型の床表面に艶を与える効果を有する
。かかるヒドロキシアルキルセルロースは組成物中に０
．１〜２重量％配合される。The hydroxyalkylcellulose used as component (c) in the present invention includes hydroxymethylcellulose, hydroxyethylcellulose, and the like. Hydroxyalkyl cellulose has a 1% concentration aqueous solution at 25°C.
Those having a viscosity of ~5000 centivoise and a degree of alkyl substitution (DS) in the range of 0.8 to 1.5 are preferably used. These hydroxyalkylcelluloses have the effect of improving cleaning properties and giving gloss to stone-shaped floor surfaces. No such hydroxyalkyl cellulose is present in the composition.
．． It is blended in an amount of 1 to 2% by weight.
本発明に用いられる（２）成分の低級アルコールとして
はエタノール、イソプロパツール等が挙げられる。これ
ら低級アルコールは可溶化剤として使用されるものであ
るが、殺菌効果を付与し、衛生感を高めるためにはエタ
ノールの使用が望ましい、低級アルコールは組成物中に
１〜５重量％配合される。Examples of the lower alcohol as component (2) used in the present invention include ethanol, isopropanol, and the like. These lower alcohols are used as solubilizers, but it is preferable to use ethanol in order to impart a bactericidal effect and improve hygiene. Lower alcohols are blended in the composition in an amount of 1 to 5% by weight. .
本発明の組成物のｐＨは９〜１２に調整される。The pH of the composition of the invention is adjusted to 9-12.
ｐＨはモノエタノールアミン、ジェタノールアミン、ト
リエタノールアミン等のアルカノールアミンで調整する
のがよい。The pH is preferably adjusted with alkanolamines such as monoethanolamine, jetanolamine, and triethanolamine.
本発明のフロア−用液体洗浄剤組成物を高硬度の洗浄水
で使用する際にはニトリロ三酢酸塩、エチレンシアミン
四酢酸塩等のアミノカルボン酸塩キレート剤を組成物に
０．０５〜１重量％添加するのが好ましい。When using the liquid floor cleaning composition of the present invention with high-hardness cleaning water, an aminocarboxylate chelating agent such as nitrilotriacetate or ethylenecyaminetetraacetate is added to the composition in an amount of 0.05 to It is preferable to add 1% by weight.
本発明のフロア−用液体洗浄剤組成物には必要に応じて
その他香料、色素、にごり剤等を配合することができる
。The liquid floor cleaning composition of the present invention may contain other fragrances, pigments, clouding agents, etc., if necessary.
以下実施例にて本発明を説明するが、本発明はこれらの
実施例に限定されるものではない。The present invention will be explained below with reference to Examples, but the present invention is not limited to these Examples.
表１に示す組成のフロア−用液体洗浄剤組成物を調製し
、以下の方法により洗浄力及び実用性の評価を行なった
。Liquid floor cleaning compositions having the compositions shown in Table 1 were prepared, and their cleaning power and practicality were evaluated by the following methods.
く洗浄力評価方法〉
ナタネ油に油溶性色素スダン■を微量加えたちの０．５
ｇを３０Ｘ３０ｃｍのテラゾー片にハケで薄く塗布した
。このテラゾー片に表１に示す＆Ｉｌ或のフロア−用液
体洗浄剤組成物の０．３％水溶液をｌ〇−滴下し、テラ
ゾー片表面を布でこすり、洗浄力を肉眼で判定する。Cleaning power evaluation method: A trace amount of oil-soluble pigment Sudan ■ is added to rapeseed oil.
A thin layer of g was applied to a 30 x 30 cm piece of terrazzo with a brush. One drop of a 0.3% aqueous solution of a liquid floor cleaning composition shown in Table 1 was dropped onto the terrazzo piece, the surface of the terrazzo piece was rubbed with a cloth, and the cleaning power was visually judged.
この時の判定基準は以下の通りである。The judgment criteria at this time are as follows.
Ｏ：きれいに落ちている
Δ：少しピンク色が残っている
×：ピンク色がまだらに残る
表 １
注）
＊１：Ｎｏ、２及び３は比較品
本２ＬＡＳ：直鎖アルキルベンゼンスルホン酸塩＊３Ｈ
ＥＣ：ヒドロキシエチルセルロース＊４Ｂ：バランス量
の略
〈実用性評価方法〉
テラゾー製の床のある家庭４０軒で表１に示す組成のフ
ロア−用液体洗浄剤組成物を使用してもらい、洗浄時の
汚れの落ちやすさ、洗浄後のテラゾー面の光沢及び洗浄
後のテラゾー面に素足で乗った時のべたつき感を評価し
てもらった。O: Cleanly removed Δ: A little pink color remains ×: Pink color remains mottled Table 1 Note) *1: No, 2 and 3 are comparative products 2LAS: Linear alkylbenzene sulfonate *3H
EC: Hydroxyethyl cellulose *4B: Abbreviation for balance amount <Practical evaluation method> We asked 40 households with terrazzo floors to use a liquid floor cleaning composition with the composition shown in Table 1. Participants were asked to evaluate the ease of removing dirt, the gloss of the terrazzo surface after cleaning, and the sticky feeling when stepping on the terrazzo surface with bare feet after cleaning.
これらの評価結果を表２に示す。These evaluation results are shown in Table 2.
表 ２ 実用性評価Table 2 Practicality evaluation
Claims (1)
オン界面活性剤２〜１０重量％ （ｃ）ヒドロキシアルキルセルロース ０．１〜２重量％ （２）低級アルコール１〜５重量％ を含有し、且つｐＨが９〜１２であることを特徴とする
フロアー用液体洗浄剤組成物。[Scope of Claims] 1 (a) 1 to 5% by weight of anionic surfactant (b) 2 to 10% by weight of nonionic surfactant (c) 0.1 to 2% by weight of hydroxyalkylcellulose (2) Lower alcohol 1 5% by weight, and has a pH of 9 to 12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1322878A JP2602562B2 (en) | 1989-12-12 | 1989-12-12 | Liquid detergent composition for floors |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1322878A JP2602562B2 (en) | 1989-12-12 | 1989-12-12 | Liquid detergent composition for floors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03182596A true JPH03182596A (en) | 1991-08-08 |
| JP2602562B2 JP2602562B2 (en) | 1997-04-23 |
Family
ID=18148624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1322878A Expired - Fee Related JP2602562B2 (en) | 1989-12-12 | 1989-12-12 | Liquid detergent composition for floors |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2602562B2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51142007A (en) * | 1975-04-02 | 1976-12-07 | Procter & Gamble | Detergent composition |
-
1989
- 1989-12-12 JP JP1322878A patent/JP2602562B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51142007A (en) * | 1975-04-02 | 1976-12-07 | Procter & Gamble | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2602562B2 (en) | 1997-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
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