JPH03180591A - Production of patterned paper and patterned paper produced thereby - Google Patents
Production of patterned paper and patterned paper produced therebyInfo
- Publication number
- JPH03180591A JPH03180591A JP31440589A JP31440589A JPH03180591A JP H03180591 A JPH03180591 A JP H03180591A JP 31440589 A JP31440589 A JP 31440589A JP 31440589 A JP31440589 A JP 31440589A JP H03180591 A JPH03180591 A JP H03180591A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- fibers
- raw material
- mixture
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000835 fiber Substances 0.000 claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 24
- 239000007864 aqueous solution Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 239000000975 dye Substances 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 9
- 239000002025 wood fiber Substances 0.000 claims abstract description 9
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 239000012266 salt solution Substances 0.000 claims description 10
- 238000007796 conventional method Methods 0.000 claims description 8
- 238000005054 agglomeration Methods 0.000 claims description 7
- 230000002776 aggregation Effects 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 6
- 238000005034 decoration Methods 0.000 abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000012209 synthetic fiber Substances 0.000 abstract description 3
- 229920002994 synthetic fiber Polymers 0.000 abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 abstract description 2
- 235000011126 aluminium potassium sulphate Nutrition 0.000 abstract description 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229940050271 potassium alum Drugs 0.000 abstract description 2
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 abstract description 2
- 230000015271 coagulation Effects 0.000 abstract 1
- 238000005345 coagulation Methods 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 15
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 15
- 239000000243 solution Substances 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000004513 sizing Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- NLMHXPDMNXMQBY-UHFFFAOYSA-L chembl260999 Chemical compound [Na+].[Na+].C1=CC(NC(=O)C)=CC=C1N=NC(C(=CC1=C2)S([O-])(=O)=O)=C(O)C1=CC=C2NC(=O)NC1=CC=C(C(O)=C(N=NC=2C=CC=CC=2)C(=C2)S([O-])(=O)=O)C2=C1 NLMHXPDMNXMQBY-UHFFFAOYSA-L 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野１
本発明は、外観及び風合いに優れた新規な柄を有する模
様紙を製造する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to a method for manufacturing patterned paper having a novel pattern with excellent appearance and texture.
別の観点に立てば本発明は、外観及び風合いに優れた新
規な柄を有する模様紙に関するものである。From another perspective, the present invention relates to patterned paper having a novel pattern that is excellent in appearance and texture.
したがって本発明は、その紙を利用する装飾、包装、印
刷等の産業及び製紙産業において利用できるものである
。Therefore, the present invention can be used in industries that utilize paper, such as decoration, packaging, and printing, as well as in the paper manufacturing industry.
［従来の技術］
従来、模様紙の製造方法としては、染色による方法、種
々の型付けによる方法、特殊な形状物又は着色物を折り
込む方法、特殊な抄紙技術を応用した方法など多くの方
法が知られている。また、種々の染色セルロース繊維を
晒しパルプに配合して製造した模様紙等も知られている
。[Prior Art] Conventionally, many methods have been known for producing patterned paper, including dyeing methods, methods using various types of molding, methods of folding objects of special shapes or colors, and methods that apply special paper-making techniques. It is being Furthermore, patterned papers made by blending various dyed cellulose fibers with bleached pulp are also known.
〔発明が解決しようとする問題点１
本発明の目的は、従来から知られている模様紙とは異な
った装飾用、包装用又は印刷用の新規な模様紙およびそ
°の製造方法を提供することにある。[Problem to be Solved by the Invention 1] An object of the present invention is to provide a new patterned paper for decoration, packaging, or printing, which is different from conventionally known patterned papers, and a method for producing the same. There is a particular thing.
［問題点を解決するための手段］
（製造方法）
ここに提案される模様紙の製造方法のひとつは、ナトリ
ウムカルボキシメチルセルロース（以下の記述において
は、これをｒＣＭＣＪと略記する。）水溶液に染料、顔
料、填料、木材繊維、化学繊維からなる集団のなかから
選択された１種類または数種類の物質を入れ、それらの
混合物をかきまぜながら、その混合物に金属塩水溶液を
添加して凝集させ、その凝集物を抄紙原料である繊維に
添加し、こうして得られた調整ずみ抄紙原料を通常の方
法によって抄造することを特徴とする模様紙の製造方法
である。[Means for solving the problem] (Manufacturing method) One of the methods for manufacturing patterned paper proposed here is to add a dye to an aqueous solution of sodium carboxymethyl cellulose (in the following description, this will be abbreviated as rCMCJ). One or more substances selected from the group consisting of pigments, fillers, wood fibers, and chemical fibers are added, and while the mixture is stirred, an aqueous metal salt solution is added to the mixture to cause agglomeration. This is a method for producing patterned paper, which is characterized by adding the above-mentioned fibers to fibers, which are raw materials for paper making, and making paper from the thus obtained adjusted raw material for paper making using a conventional method.
また、ここに提案される模様紙の製造方法の第２番目の
ものは、部分的に透明化された模様紙の製造方法であっ
て、それは、ＣＭＣ水溶液に染料、顔料、填料、木材繊
維、化学繊維および熱によって透明化する物質からなる
集団のなかから選択された１種類または数種類の物質を
入れ、それらの混合物をかきまぜながら、その混合物に
金属塩水溶液を添加して凝集させ、その凝集物を抄紙原
料である繊維に添加し、こうして得られた調整ずみ抄紙
原料を通常の方法によって抄造したのち、得られた紙を
加熱することを特徴とする部分透明化模様紙の製造方法
である。The second method for producing patterned paper proposed herein is a method for producing partially transparent patterned paper, which involves adding dyes, pigments, fillers, wood fibers, etc. to a CMC aqueous solution. One or several types of substances selected from the group consisting of chemical fibers and substances that become transparent by heat are added, and while stirring the mixture, an aqueous metal salt solution is added to the mixture to cause agglomeration. This is a method for producing partially transparent patterned paper, which is characterized by adding the above-mentioned fibers to fibers, which are raw materials for papermaking, making paper from the thus obtained adjusted raw materials for papermaking by a conventional method, and then heating the obtained paper.
（模様紙）
ここに提案される模様紙のひとつは、ＣＭＣ水溶液に染
料、顔料、填料、木材繊維、化学繊維からなる集団のな
かから選択された１種類または数種類の物質を入れ、そ
れらの混合物をかきまぜながら、その混合物に金属塩水
溶液を添加して凝集させ、その凝集物を抄紙原料である
繊維に添加し、こうして得られた調整ずみ抄紙原料を通
常の方法によって抄造したことを特徴とする模様紙であ
る。(Patterned paper) One of the patterned papers proposed here is a CMC aqueous solution containing one or more substances selected from the group consisting of dyes, pigments, fillers, wood fibers, and chemical fibers, and a mixture thereof. While stirring, an aqueous metal salt solution is added to the mixture to cause agglomeration, the agglomerate is added to fibers that are a raw material for papermaking, and the thus obtained adjusted raw material for papermaking is made into paper by a conventional method. It is patterned paper.
また、ここに提案される第２番目の模様紙は、部分的に
透明化された模様紙であって、それは、ＣＭＣ水溶液に
染料、顔料、填料、木材繊維、化学繊維および熱によっ
て透明化する物質からなる集団のなかから選択された１
種類または数種類の物質を入れ、それらの混合物をかき
まぜながら、その混合物に金属塩水溶液を添加して凝集
させ、その凝集物を抄紙原料である繊維に添加し、こう
して得られた調整ずみ抄紙原料を通常の方法によって抄
造したのち、得られた紙を加熱することによって得られ
る部分透明化模様紙である。The second patterned paper proposed here is a partially transparent patterned paper, which is made transparent by adding dyes, pigments, fillers, wood fibers, chemical fibers, and heat to a CMC aqueous solution. 1 selected from a group of substances
Add one or several kinds of substances, stir the mixture, add an aqueous metal salt solution to the mixture to cause agglomeration, add the aggregate to the fibers that are the raw material for papermaking, and use the adjusted raw material for papermaking thus obtained. This is a partially transparent patterned paper obtained by heating the paper after forming it using a conventional method.
〔発明の作用１
本発明の製造方法によれば、染色凝集物が出来る際に液
がかきまぜれているから、凝集物の大きさは、かきまぜ
の強弱により、大きくしたり、小さくしたりすることが
できる。[Effect of the invention 1] According to the production method of the present invention, since the liquid is stirred when dyeing aggregates are formed, the size of the aggregates can be increased or decreased depending on the strength of stirring. I can do it.
また、本発明の製造方法によれば、種々の特性を持った
添加用凝集物を作ることができる。例えば高白色度、高
不透明度の添加物を望む場合には、製紙用の填料である
高白色度、高不透明度の酸化チタンをＣＭＣと金属塩水
溶液で凝集させ、大きい酸化チタン凝集物を作ることが
できる。更に大きい凝集物を作る時には、つなぎとして
バルブ等をも添加することが望ましい。Furthermore, according to the production method of the present invention, additive aggregates having various properties can be produced. For example, if an additive with high whiteness and high opacity is desired, titanium oxide with high whiteness and high opacity, which is a filler for paper manufacturing, is aggregated with CMC and an aqueous metal salt solution to form large titanium oxide aggregates. be able to. When making even larger aggregates, it is desirable to add a valve or the like as a binder.
さらにまた、部分的に透明化した柄を望む場合には、熱
によって透明化する物質（例えばポリエチレン製の合成
バルブ）をＣＭＣと金属塩水溶液で固めて凝集物を作り
、それを紙に抄きこんだあとで熱処理して、部分透明化
紙を得ることができる。Furthermore, if a partially transparent pattern is desired, a material that becomes transparent when heated (for example, a polyethylene synthetic bulb) is solidified with CMC and an aqueous metal salt solution to form an aggregate, which is then made into paper. After it is hardened, it can be heat-treated to obtain partially transparent paper.
このようにＣＭＣと金属塩水溶液で凝集を起こす際の添
加材料を変えることによって、凝集物の性質が異なるた
め、意匠性に冨んだ柄となる。In this way, by changing the additive materials when aggregating CMC and a metal salt aqueous solution, the properties of the agglomerates differ, resulting in a pattern rich in design.
本発明の構成要素について以下に詳説する。Components of the present invention will be explained in detail below.
（ＣＭＣ水溶液） ＣＭＣ水溶液は、ＣＭＣを水で溶解させたものである。(CMC aqueous solution) The CMC aqueous solution is one in which CMC is dissolved in water.
溶解濃度はＣＭＣの種類により異なるが、かきまぜによ
る流動性があり、かつ、金属塩水溶液を添加した際にゲ
ル化が起こる濃度であることが必要である。そのような
濃度としては、０．５重量％ないし２重量％が好ましい
。Although the dissolved concentration differs depending on the type of CMC, it is necessary that it has fluidity when stirred and is at a concentration that causes gelation when an aqueous metal salt solution is added. Such a concentration is preferably from 0.5% to 2% by weight.
（金属塩）
金属塩水溶液をつくるための金属塩としては、カリミョ
ウバン、硫酸アルミニウム、酢酸アルミニウム、水酸化
カルシウム、硫酸第一鉄、塩化第二鉄、硫酸亜鉛、塩化
バリウム、硝酸クロム、硝酸銀、塩化スズ、塩化第二銅
、酢酸鉛があげられる。(Metal salts) Metal salts for making metal salt aqueous solutions include potassium alum, aluminum sulfate, aluminum acetate, calcium hydroxide, ferrous sulfate, ferric chloride, zinc sulfate, barium chloride, chromium nitrate, silver nitrate, Examples include tin chloride, cupric chloride, and lead acetate.
（染料、顔料）
染料としては、各種の直接染料、塩基性染料、酸性染料
、分散染料、カチオン染料等を使用することができる。(Dye, Pigment) As the dye, various direct dyes, basic dyes, acid dyes, disperse dyes, cationic dyes, etc. can be used.
顔料としては無機顔料でも有機顔料でも使用することが
できる。As the pigment, both inorganic pigments and organic pigments can be used.
（填料）
カオリン、けいそう土、クレー、タルク、炭酸カルシウ
ム、硫酸カルシウム、硫酸バリウム、酸化チタンなど、
通常の製紙のために用いられる物質を使用することがで
きる。(Fillers) Kaolin, diatomaceous earth, clay, talc, calcium carbonate, calcium sulfate, barium sulfate, titanium oxide, etc.
Materials used for conventional paper making can be used.
（繊維）
通常の木材バルブ、リンクバルブなどの植物繊維バルブ
、合成バルブのほかに各種の合成繊維、無機繊維などの
化学繊維が使用できる。(Fiber) In addition to regular wood valves, plant fiber valves such as link valves, and synthetic valves, various synthetic fibers and chemical fibers such as inorganic fibers can be used.
“（配合バルブ）
凝集物を添加する原料バルブとしては、製紙用として普
通に使用されるバルブはいずれも使用できる。木材バル
ブのほかに、リンターパルプ、植物繊維バルブの何れも
使用でき、そのほかに合成バルブ、合成繊維等も適宜使
用できる。(Blending valve) As a raw material valve for adding aggregates, any valve commonly used for papermaking can be used.In addition to wood valves, linter pulp and vegetable fiber valves can also be used. Synthetic valves, synthetic fibers, etc. can also be used as appropriate.
また、バルブは未晒しバルブでも晒しバルブでも目的に
応じて使いわけられる。Also, the bulb can be used as either an unbleached bulb or a bleached bulb depending on the purpose.
次に実施例を挙げて説明するが、本発明が下記の実施例
だけに限定されないことはいうまでもない。各実施例に
おける「％」は、とくに指示しないかぎりはすべて重量
％を意味する。Next, an explanation will be given with reference to examples, but it goes without saying that the present invention is not limited to the following examples. All "%" in each example means % by weight unless otherwise specified.
実施例１
水１．５リットルにＣＭＣ（ダイセル化学工業■の製品
ｒＣＭＣダイセル１１５ｏ」）１５ｇを溶解して１重量
％濃度のＣＭＣ水溶液を作った。Example 1 A CMC aqueous solution having a concentration of 1% by weight was prepared by dissolving 15 g of CMC (rCMC Daicel 115o, a product of Daicel Chemical Industries, Ltd.) in 1.5 liters of water.
この液を２リツトル容積のタッピバルブ離解機に入れた
。更に染料液（直接染料シリアスイエロー１％液５３ｃ
ｃ、スカーレット４ＢＳレッド１％液７ｃｃ）を添加し
た。離解機のプロペラシャフトを回転させ、液をかきま
ぜながら硫酸バンド（アルミニウムをアルミナに換算し
た濃度は８重量％）を添加し、着色凝集物を作った。This liquid was placed in a 2 liter volume Tappi valve disintegrator. Furthermore, dye liquid (direct dye Serious Yellow 1% liquid 53c
c, 7 cc of Scarlet 4BS Red 1% liquid) was added. The propeller shaft of the disintegrator was rotated to stir the solution while adding sulfuric acid (concentration of aluminum to alumina: 8% by weight) to form a colored aggregate.
ＮＢＫＰ／ＬＢＫＰ＝２０／８０１’７リーネス４００
ｍｍβのバルブ１００ｇにサイズバインＥを０．７％、
硫酸バンド液を１．５％、上記の凝集物液６５ｍ４を入
れて、手抄き抄紙機で米坪１００ｇ／ｍ”になるように
凝集模様入りの紙を抄造した。NBKP/LBKP=20/801'7 Leeness 400
Add 0.7% of Sizevine E to 100g of mmβ bulb.
A 1.5% sulfuric acid solution and 65 m4 of the above-mentioned agglomerate solution were added to make paper with an agglomerate pattern to a weight of 100 g/m'' using a hand paper machine.
サイズ液として、酸化チン１フフ
を使用して、表面サイジングを行った。得られた模様紙
の一例が見本（１）である。Surface sizing was performed using 1 fufu of tin oxide as a sizing liquid. Sample (1) is an example of the patterned paper obtained.
実施例２
１％ＣＭＣ水溶液４００ｃｃに二酸化チタンＲ−８５０
（６原産業■の製品）５ｇ、木材バルブ５ｇを入れて
よくかきまぜ、均一な分散烏を作った。１℃のビーカー
に液を移し、市販の実験用アジテータ−で３５０ｒｐｍ
の速度で液をかきまぜておいて、そこに硫酸バンド１５
ｍｎを添加して凝集物を作った。Example 2 Titanium dioxide R-850 in 400cc of 1% CMC aqueous solution
(Product of 6 Hara Sangyo ■) and 5 g of wood bulb were added and stirred well to make a uniformly dispersed mixture. Transfer the liquid to a beaker at 1℃ and stir at 350 rpm using a commercially available experimental agitator.
Stir the solution at a speed of
mn was added to form an agglomerate.
ＮＢＫＰ／ＬＢＫＰ＝２０／８０でフリーネス４００ｍ
ｍ１２のバルブ１００ｇにサイズバインＥを０．７％、
硫酸バンド液（アルミニウムをアルミナに換算した濃度
は８重量％）を１．５％、上記の凝集物液６０ｍβを入
れて、手抄き抄紙機で米坪１００ ｇ／ｒｎ’になるよ
うに凝集模様入りの紙を抄造した。サイズ液として、酸
化デンプン７％濃度のものを使用して、表面サイジング
を行った。得られた模様紙の一例が見本（２）である。Freeness 400m with NBKP/LBKP=20/80
Add 0.7% Sizevine E to 100g of m12 valve.
Add 1.5% sulfuric acid band solution (concentration of aluminum to alumina: 8% by weight) and 60 mβ of the above aggregate solution, and aggregate to 100 g/rn' on a hand paper machine. I made paper with a pattern. Surface sizing was performed using an oxidized starch solution with a concentration of 7% as a sizing solution. Sample (2) is an example of the patterned paper obtained.
実施例３
１％ＣＭＣ水溶液４００ｃｃに離解した５ＷＰ−Ｅ５０
０ （三井石油化学工業■製のポリエチレン製合成バル
ブの商品名）を固形換算５ｇ添加し、よくかきまぜて均
一な分散液を作った。ＩＪ２のビーカーに液を移し、市
販の実験用アジテータ−で３５Ｏｒｐｍの速度で液をか
きまぜておいて、そこに硫酸バンド（アルミニウムをア
ルミナに換算した濃度は８重量％）１５ｍｊ２を添加し
て凝集物を作った。Example 3 5WP-E50 disintegrated into 400cc of 1% CMC aqueous solution
0 (trade name of a polyethylene synthetic valve manufactured by Mitsui Petrochemical Industries ■) was added in an amount of 5 g in solid terms and stirred well to prepare a uniform dispersion. Transfer the liquid to an IJ2 beaker, stir the liquid at a speed of 35 rpm using a commercially available experimental agitator, and add 15mj2 of sulfuric acid band (concentration of aluminum to alumina: 8% by weight) to form aggregates. made.
ＮＢＫＰ／ＬＢＫＰ＝２０／８０でフリーネス４００ｍ
ｍＪ２のバルブ１００ｇにサイズパインＥを０．７％、
硫酸バンド液１．５％を上記の凝集物液４００ｍβを入
れて、手抄き抄紙機で米坪１００ｇ／ｍ″になるように
凝集模様入りの紙を抄造した。サイズ液として、酸化デ
ンプン７％濃度のものを使用して、表面サイジングを行
った。更に熱カレンダー処理して、凝集物のあった部分
が透明化した模様紙を得た。得られた模様紙の一例が見
本（３）である。Freeness 400m with NBKP/LBKP=20/80
0.7% size pine E to 100g of mJ2 valve,
1.5% of the sulfuric acid band solution was added to 400 mβ of the above aggregate solution, and paper with an aggregate pattern was made using a hand paper machine to a weight of 100 g/m''. Oxidized starch 7 was used as the sizing solution. % concentration was used for surface sizing.Furthermore, a thermal calendar treatment was performed to obtain a patterned paper in which the areas where the aggregates were made transparent.An example of the obtained patterned paper is sample (3) It is.
模様の大きさは、反応する時の液のかきまぜ速度に影響
があって、より早い回転では凝集物は小さくなる。大き
な形状の凝集物を作る場合は、実施例２のようにつなぎ
としての繊維質を入れることが必要である。The size of the pattern affects the rate at which the liquid is stirred during the reaction, with faster rotation resulting in smaller aggregates. When making a large-sized aggregate, it is necessary to add fibers as a binder as in Example 2.
凝集物の色は染料を変えることによって各種の色調に変
えることができる。The color of the agglomerates can be changed to various shades by changing the dye.
抄紙原料に添加する凝集物の量を増減すれば、このみの
模様を表現することができる。By increasing or decreasing the amount of aggregates added to the papermaking raw material, it is possible to create a pattern like this.
［発明の効果］
本発明によって、従来は例を見ない新規な柄を有する模
様紙が得られる。本発明の模様紙は水溶性高分子（すな
わちＣＭＣ）を使用しているため、紙シートから凝集物
の離脱が無く、オフセット印刷適性も良好であった。従
って、本発明の模様紙は、装飾、包装、出版用などに有
効に利用される。[Effects of the Invention] According to the present invention, patterned paper having a novel pattern never seen before can be obtained. Since the patterned paper of the present invention uses a water-soluble polymer (ie, CMC), there was no separation of aggregates from the paper sheet, and it had good suitability for offset printing. Therefore, the patterned paper of the present invention can be effectively used for decoration, packaging, publishing, etc.
Claims (4)
染料、顔料、填料、木材繊維、化学繊維からなる集団の
なかから選択された１種類または数種類の物質を入れ、
それらの混合物をかきまぜながら、その混合物に金属塩
水溶液を添加して凝集させ、その凝集物を抄紙原料であ
る繊維に添加し、こうして得られた調整ずみ抄紙原料を
通常の方法によって抄造することを特徴とする模様紙の
製造方法。(1) Adding one or more substances selected from the group consisting of dyes, pigments, fillers, wood fibers, and chemical fibers to a sodium carboxymethyl cellulose aqueous solution,
While stirring the mixture, an aqueous metal salt solution is added to the mixture to cause agglomeration, and the agglomerate is added to fibers, which are the raw material for papermaking, and the thus obtained adjusted raw material for papermaking is made into paper using a conventional method. A distinctive method for producing patterned paper.
染料、顔料、填料、木材繊維、化学繊維および熱によっ
て透明化する物質からなる集団のなかから選択された１
種類または数種類の物質を入れ、それらの混合物をかき
まぜながら、その混合物に金属塩水溶液を添加して凝集
させ、その凝集物を抄紙原料である繊維に添加し、こう
して得られた調整ずみ抄紙原料を通常の方法によって抄
造したのち、得られた紙を加熱することを特徴とする部
分透明化模様紙の製造方法。(2) 1 selected from the group consisting of dyes, pigments, fillers, wood fibers, chemical fibers, and substances that become transparent by heat in an aqueous solution of sodium carboxymethyl cellulose.
Add one or several kinds of substances, stir the mixture, add an aqueous metal salt solution to the mixture to cause agglomeration, add the aggregate to the fibers that are the raw material for papermaking, and use the adjusted raw material for papermaking thus obtained. A method for producing partially transparent patterned paper, which comprises forming the paper by a conventional method and then heating the obtained paper.
染料、顔料、填料、木材繊維、化学繊維のなかから選択
された１種類または数種類の物質を入れ、それらの混合
物をかきまぜながら、その混合物に金属塩水溶液を添加
して凝集させ、その凝集物を抄紙原料である繊維に添加
し、こうして得られた調整ずみ抄紙原料を通常の方法に
よって抄造したことを特徴とする模様紙。(3) Add one or more substances selected from dyes, pigments, fillers, wood fibers, and chemical fibers to a sodium carboxymethylcellulose aqueous solution, and add a metal salt aqueous solution to the mixture while stirring the mixture. A patterned paper characterized in that the agglomerated product is added to fibers as a raw material for papermaking, and the thus obtained adjusted raw material for papermaking is made by a conventional method.
染料、顔料、填料、木材繊維、化学繊維および熱によっ
て透明化する物質からなる集団のなかから選択された１
種類または数種類の物質を入れ、それらの混合物をかき
まぜながら、その混合物に金属塩水溶液を添加して凝集
させ、その凝集物を抄紙原料である繊維に添加し、こう
して得られた調整ずみ抄紙原料を通常の方法によって抄
造したのち、得られた紙を加熱したことを特徴とする部
分透明化模様紙。(4) 1 selected from the group consisting of dyes, pigments, fillers, wood fibers, chemical fibers, and substances that become transparent by heat in a sodium carboxymethyl cellulose aqueous solution.
Add one or several kinds of substances, stir the mixture, add an aqueous metal salt solution to the mixture to cause agglomeration, add the aggregate to the fibers that are the raw material for papermaking, and use the adjusted raw material for papermaking thus obtained. A partially transparent patterned paper characterized by being made by a conventional method and then heating the resulting paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1314405A JP2649851B2 (en) | 1989-12-05 | 1989-12-05 | Patterned paper manufacturing method and patterned paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1314405A JP2649851B2 (en) | 1989-12-05 | 1989-12-05 | Patterned paper manufacturing method and patterned paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03180591A true JPH03180591A (en) | 1991-08-06 |
| JP2649851B2 JP2649851B2 (en) | 1997-09-03 |
Family
ID=18052953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1314405A Expired - Lifetime JP2649851B2 (en) | 1989-12-05 | 1989-12-05 | Patterned paper manufacturing method and patterned paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2649851B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07279100A (en) * | 1994-04-08 | 1995-10-24 | Tokushu Paper Mfg Co Ltd | Pattern-dyed paper and its production |
| WO2001005796A3 (en) * | 1999-07-20 | 2001-08-23 | Munksjo Paper Decor Inc | Aluminum compounds and process of making the same |
| JP2011094253A (en) * | 2009-10-28 | 2011-05-12 | Hokuetsu Kishu Paper Co Ltd | Aggregate for patterned paper, patterned paper using the same and method for producing them |
| JP2012012728A (en) * | 2010-06-30 | 2012-01-19 | Hokuetsu Kishu Paper Co Ltd | Patterned paper and method for producing the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63219698A (en) * | 1987-03-05 | 1988-09-13 | 東海パルプ株式会社 | Special paper additive and patterned special paper using the same |
| JPH01162898A (en) * | 1987-12-17 | 1989-06-27 | Abekawa Seishi Kk | Pattern paper |
-
1989
- 1989-12-05 JP JP1314405A patent/JP2649851B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63219698A (en) * | 1987-03-05 | 1988-09-13 | 東海パルプ株式会社 | Special paper additive and patterned special paper using the same |
| JPH01162898A (en) * | 1987-12-17 | 1989-06-27 | Abekawa Seishi Kk | Pattern paper |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07279100A (en) * | 1994-04-08 | 1995-10-24 | Tokushu Paper Mfg Co Ltd | Pattern-dyed paper and its production |
| WO2001005796A3 (en) * | 1999-07-20 | 2001-08-23 | Munksjo Paper Decor Inc | Aluminum compounds and process of making the same |
| JP2011094253A (en) * | 2009-10-28 | 2011-05-12 | Hokuetsu Kishu Paper Co Ltd | Aggregate for patterned paper, patterned paper using the same and method for producing them |
| JP2012012728A (en) * | 2010-06-30 | 2012-01-19 | Hokuetsu Kishu Paper Co Ltd | Patterned paper and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2649851B2 (en) | 1997-09-03 |
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