JPH0316936A - Crystallized glass material having reinforcing back layer - Google Patents
Crystallized glass material having reinforcing back layerInfo
- Publication number
- JPH0316936A JPH0316936A JP14991789A JP14991789A JPH0316936A JP H0316936 A JPH0316936 A JP H0316936A JP 14991789 A JP14991789 A JP 14991789A JP 14991789 A JP14991789 A JP 14991789A JP H0316936 A JPH0316936 A JP H0316936A
- Authority
- JP
- Japan
- Prior art keywords
- crystallized glass
- glass material
- coupling agent
- layer
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 29
- 230000003014 reinforcing effect Effects 0.000 title claims abstract description 24
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 19
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 17
- 239000000057 synthetic resin Substances 0.000 claims abstract description 17
- 239000004566 building material Substances 0.000 abstract description 3
- 239000007822 coupling agent Substances 0.000 abstract description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 21
- 239000011347 resin Substances 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- 229910000077 silane Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 241000207199 Citrus Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- YTUPSNLWAAEFPL-UHFFFAOYSA-N ethenyl(ethoxy)silane Chemical compound CCO[SiH2]C=C YTUPSNLWAAEFPL-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、建材や壁材等として使用される結晶化ガラス
材に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a crystallized glass material used as a building material, wall material, etc.
（従来の技術）
近年、天然石材やガラス材とは質感や美感の異なる結晶
化ガラス材が内外装建材として多方面で使用されつつあ
る。(Prior Art) In recent years, crystallized glass materials, which have a different texture and aesthetic appearance than natural stone and glass materials, are being used in a wide variety of fields as interior and exterior building materials.
結晶化ガラス材は一般のガラス材よりも強靭ではあるが
、金属材と比べると耐衝撃性に劣り、衝撃力が加った場
合破損ずるおそれがある。建築物の壁面等を形威する板
状結晶化ガラス材では、高所で破損すると破片が四散し
著し《危険であるため、結晶化ガラス材の裏面に補強用
の合戒樹脂層が塗着されている。Although crystallized glass materials are stronger than general glass materials, they have poorer impact resistance than metal materials, and there is a risk of breakage when an impact force is applied. If plate-shaped crystallized glass materials, which form the walls of buildings, are damaged at high places, the pieces will scatter and become dangerous. It is worn.
前記合戒樹脂補強層としそは、主としてＦＲＰが使用さ
れており、基材となる合成樹脂には不飽和ポリエステル
やビニルエステルが使用されている。これらの樹脂は、
常温硬化が可能であり、硬化剤の配合により、硬化時間
を数分〜数十分に容易に調整することができ、作業性に
優れ、しかも低コストであるからである。FRP is mainly used for the above-mentioned joint resin reinforcing layer, and unsaturated polyester or vinyl ester is used as the base synthetic resin. These resins are
This is because it can be cured at room temperature, the curing time can be easily adjusted from several minutes to several tens of minutes by adding a curing agent, it has excellent workability, and it is low cost.
（発明が解決しようとする課題）
しかしながら、上記樹脂と結晶化ガラス材との接着性が
悪いため、塗布形或後に補強層が剥離し易いという問題
がある。(Problems to be Solved by the Invention) However, since the adhesiveness between the resin and the crystallized glass material is poor, there is a problem in that the reinforcing layer is likely to peel off after coating.
基材樹脂として接着力の強力な樹脂、例えばエポキシ系
樹脂の使用も考えられるが、常温硬化が困難で作業性に
劣り、又高コストであるという欠点がある。Although it is conceivable to use a resin with strong adhesive strength, such as an epoxy resin, as the base resin, it has drawbacks such as difficulty in curing at room temperature, poor workability, and high cost.
本発明はかかる問題点に鑑みなされたもので、基材樹脂
が結晶化ガラスとの接着性に劣るものであっても、合成
樹脂補強層が結晶化ガラス材６こ強固に塗着した裏面補
強層を有する結晶化ガラス制を提供することを目的とす
る。The present invention was made in view of this problem, and even if the base resin has poor adhesion to the crystallized glass, the synthetic resin reinforcing layer firmly adheres to the crystallized glass material to strengthen the back surface. The object is to provide a crystallized glass system having layers.
（課題を解決するための手段）
上記目的を達或するためになされた本発明の結晶化ガラ
ス材は、結晶化ガラス材の裏面にシランカップリング剤
層を介して合成樹脂補強層を塗着するものであり、また
、基材合成樹脂にシランカップリング剤を含有した合成
樹脂補強層を結晶化ガラス材の裏面に直接塗着するもの
である。(Means for Solving the Problems) The crystallized glass material of the present invention, which has been made to achieve the above object, has a synthetic resin reinforcing layer coated on the back surface of the crystallized glass material via a silane coupling agent layer. In addition, a synthetic resin reinforcing layer containing a silane coupling agent in a base synthetic resin is directly applied to the back surface of the crystallized glass material.
（作 用）
結晶化ガラス材と合成摺脂補強層との間に介在するシラ
ンカップリング剤層や合成樹脂補強層中に含有したシラ
ンカップリング剤は、一方で結晶化ガラス材と反応し、
他方で補強層中の合成樹脂と反応し、両者に亘って強い
化学結合を形或して、合成樹脂補強層の接着力を向上さ
せることができる。(Function) The silane coupling agent layer interposed between the crystallized glass material and the synthetic resin reinforcing layer or the silane coupling agent contained in the synthetic resin reinforcing layer reacts with the crystallized glass material,
On the other hand, it can react with the synthetic resin in the reinforcing layer and form a strong chemical bond between them, thereby improving the adhesive strength of the synthetic resin reinforcing layer.
（実施例）
本発明において使用されるシランカ／プリング剤は、一
般式が（Ｒｏｔ）Ｓ＋Ｒ’ で表わされ、ＲＯ基は加水
分解して１１０基となり、更に無機物表面と反応しエー
テル結合をつくり、一方Ｒ′基は樹脂との親和力の強い
基で構成される。本発明では、例えば、Ｔ−クロロプロ
ビル１・リメトキシシラン、ビニル１・リクロロシラン
、ビニルＩ・リエトキシシラン、Ｔ−メタクリ口キシプ
口ピルトリメ｛・キシシランを使用することができる。(Example) The silanka/pulling agent used in the present invention has the general formula (Rot)S+R', and the RO group is hydrolyzed to 110 groups, which further reacts with the surface of an inorganic substance to form an ether bond. On the other hand, the R' group is composed of a group having a strong affinity with the resin. In the present invention, for example, T-chloroprobyl-limethoxysilane, vinyl-1-lichlorosilane, vinyl-I-ethoxysilane, and T-methacrylate-trimethoxysilane can be used.
基材樹脂としてビニルエステルを使用ずる場合ば、特に
Ｔ−メタクリロキシブロビルトリメ１・キシシランが好
適である。When a vinyl ester is used as the base resin, T-methacryloxybrobyltrimethoxysilane is particularly suitable.
尚、シランカンブリング剤のほか、有機クロム化合物も
同様の作用をなすものであり、シランカ・ンプリング剤
の代用として利用可能である。In addition to the silane combing agent, an organic chromium compound also has a similar effect and can be used as a substitute for the silane cumbling agent.
シランカンプリング剤は、原液のまま、あるいは適宜の
有機溶剤で希釈して結晶化ガラス材の表面に塗布され、
半乾燥ないし乾燥後、その上に液状のＦＲＰが塗着され
て合成樹脂補強層が形成される。この場合、シランカツ
プリング剤層の厚さは、薄くても一向に差し支えなく、
理論的にはシランカップリング剤の分子厚さで足りる。The silane camping agent is applied to the surface of the crystallized glass material as it is or diluted with an appropriate organic solvent.
After semi-drying or drying, liquid FRP is applied thereon to form a synthetic resin reinforcing layer. In this case, there is no problem with the thickness of the silane coupling agent layer, even if it is thin.
Theoretically, the molecular thickness of the silane coupling agent is sufficient.
作業性を考慮すると、通常、カップリング剤量でｔＯ〜
３０ｇ／ｒｒＴ程度とされる。塗布手段は、刷毛塗り、
スプレー塗布等の適宜の手段を適用すればよい。Considering workability, the amount of coupling agent is usually tO ~
It is estimated to be about 30g/rrT. The application method is brush painting,
Appropriate means such as spray coating may be applied.
また、合戒柑脂補強層の接着性を向上させるには、上記
のようにシランカップリング剤層を形成する他、シラン
カップリング剤を基材樹脂中に予め練り込んでおいても
よい。この場合、配合量は基材樹脂１００重量部に対し
て０．５〜１０重量部程度とするのがよい。０．５重量
部未満では接着性改善効果が少なく、一方、１０重量部
を越えると基拐樹脂の耐衝撃性が劣化する。In addition to forming a silane coupling agent layer as described above, a silane coupling agent may be kneaded into the base resin in advance to improve the adhesion of the citrus resin reinforcing layer. In this case, the blending amount is preferably about 0.5 to 10 parts by weight per 100 parts by weight of the base resin. If it is less than 0.5 parts by weight, the effect of improving adhesion will be small, while if it exceeds 10 parts by weight, the impact resistance of the base resin will deteriorate.
次に具体的実施例を掲げて説明する。Next, specific examples will be listed and explained.
（１）下記主戒分の結晶化ガラス板材にγ−メタクリ口
キシプロビル１・リメ１・キシシランを刷毛で塗布し、
５２時間常温放置後、半乾燥状態のシランカップリング
剤層の上にガラス繊維を？ｎ太したビニルエステル樹脂
を塗布し、１５分間常温放置して乾燥硬化した。硬化し
た合戒樹脂補強層の界面剥離状態を調べたところ、剥離
箇所は皆無であった。(1) Apply γ-methacrylate xyprovir 1, lime 1, and xysilane to the crystallized glass plate material of the following main precepts with a brush,
After leaving it at room temperature for 52 hours, put glass fiber on top of the semi-dry silane coupling agent layer. A thick vinyl ester resin was applied and left to stand at room temperature for 15 minutes to dry and harden. When the state of interfacial peeling of the cured Gokai resin reinforcing layer was examined, there was no peeling location.
０結晶化ガラス利の主威分組ｅ．（ｗｔ％）ＳｉＯ。二
６２％ Ａｌ２０−Ｊ ： １６％ＮａｚＯ二１１
％ＣａＯ：６％
尚、シランカノブリング剤層の形成を除くほか、同条件
で合成樹脂補強層を塗着したもの（従来例）では、界面
剥離面積は６５％であった。0 main force of crystallized glass resin e. (wt%) SiO. 262% Al20-J: 16% NazO211
%CaO: 6% In addition, in the case where the synthetic resin reinforcing layer was applied under the same conditions except for the formation of the silane canobling agent layer (conventional example), the interfacial peeling area was 65%.
（２） （＋）と同しシランカンブリング剤をシンナ
ーで１０倍に希釈したものを刷毛で塗布し、乾燥後に（
１）と同し液状のＦＲＰを塗着した。乾燥硬化後に界面
剥離状態を調べたところ、皆無であった。(2) Apply the same silane cambling agent as (+) diluted 10 times with thinner with a brush, and after drying (
Same as 1), liquid FRP was applied. When the state of interfacial peeling was examined after drying and curing, there was no interfacial peeling.
（３） ビニルエステル樹脂１００重量部に対して、
（１）と同しシランカップリング剤を３重量部および１
重量ｆ＜１１配合した液状Ｆ Ｒ Ｐを調製した。この
液状Ｆ Ｒ Ｐを（１）と同し結晶化ガラス材に直接塗
布して、■５分間常温放置して乾燥硬化した。硬化後の
界面剥離面積を測定したところ、３重量部の場合が１０
％、１重量部の場合が３５％であった。シランカップリ
ング剤の１重量部の配合でも、（１）に記載した無配合
の従来例に比べて約２倍の接着力の向上が認められた。(3) For 100 parts by weight of vinyl ester resin,
Same as (1), 3 parts by weight of silane coupling agent and 1 part by weight.
A liquid FRP containing a weight f<11 was prepared. This liquid FRP was applied directly to the same crystallized glass material as in (1) and left to dry and harden for 5 minutes at room temperature. When the interfacial peeling area after curing was measured, it was 10 parts by weight in the case of 3 parts by weight.
%, 1 part by weight was 35%. Even when 1 part by weight of the silane coupling agent was added, the adhesive strength was improved by about twice as much as the conventional example described in (1) without the addition.
（効 果）
以上説明した通り、本発明の結晶化ガラス材は、結晶化
ガラス材の裏面にシランカップリング剤層を介して合威
樹脂補強層を塗着形威し、あるいは合戒樹脂補強層の基
材樹脂にシランカップリング剤を配合したので、シラン
カップリング剤による化学結合によって合成樹脂補強層
を結晶化ガラス材の裏面に強固に接着することができる
。この結合は、基材樹脂の如何に拘らず形成されるので
、基材樹脂とピて安価な、又常温硬化可能な適宜の樹脂
を使うことができる利点がある。(Effects) As explained above, the crystallized glass material of the present invention can be obtained by coating the back surface of the crystallized glass material with a resin reinforcing layer via a silane coupling agent layer, or by applying a resin reinforcing layer to the back surface of the crystallized glass material via a silane coupling agent layer. Since a silane coupling agent is blended into the base resin of the layer, the synthetic resin reinforcing layer can be firmly adhered to the back surface of the crystallized glass material by chemical bonding caused by the silane coupling agent. Since this bond is formed regardless of the base resin, there is an advantage that an appropriate resin can be used which is inexpensive compared to the base resin and can be cured at room temperature.
Claims (2)
を介して合成樹脂補強層が塗着されていることを特徴と
する裏面補強層を有する結晶化ガラス材。(1) A crystallized glass material having a back surface reinforcing layer, characterized in that a synthetic resin reinforcing layer is applied to the back surface of the crystallized glass material via a silane coupling agent layer.
含有した合成樹脂補強層が塗着されていることを特徴と
する裏面補強層を有する結晶化ガラス材。(2) A crystallized glass material having a back surface reinforcing layer, characterized in that a synthetic resin reinforcing layer containing a silane coupling agent is applied to the back surface of the crystallized glass material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14991789A JPH0316936A (en) | 1989-06-12 | 1989-06-12 | Crystallized glass material having reinforcing back layer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14991789A JPH0316936A (en) | 1989-06-12 | 1989-06-12 | Crystallized glass material having reinforcing back layer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0316936A true JPH0316936A (en) | 1991-01-24 |
Family
ID=15485413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14991789A Pending JPH0316936A (en) | 1989-06-12 | 1989-06-12 | Crystallized glass material having reinforcing back layer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0316936A (en) |
-
1989
- 1989-06-12 JP JP14991789A patent/JPH0316936A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4832990A (en) | Process for coating metal surfaces with polyolefins | |
| EP1391289A3 (en) | Low shrink low density laminate formulation | |
| KR0172617B1 (en) | Silane primer composition | |
| WO2003033255A1 (en) | Composite molding with adhesive composition layer comprising conjugated diene polymer having cyclic structure, and coating material | |
| CA2348300A1 (en) | Adhesive bonding process for aluminium and/or aluminium alloy | |
| JPH0316936A (en) | Crystallized glass material having reinforcing back layer | |
| JPH01139252A (en) | Easy adhesion type decorative sheet for wall | |
| CA2227005A1 (en) | Adhesion-promoting composition for bonds between plastic and other materials | |
| JPS59177177A (en) | Finishing method for rust preventive lining | |
| CN217580924U (en) | Based on structure of plastering a surface of carbon fiber structure processing decorative layer | |
| KR101418863B1 (en) | MMA resin coating structure | |
| JPH0762317A (en) | Adhesive for building material | |
| JPS60137957A (en) | Epoxy cement composition rapidly curable-in-water | |
| JP2863051B2 (en) | Manufacturing method of decorative building materials | |
| JP2630797B2 (en) | Primer composition for painting | |
| JPH03273084A (en) | Waterproofing and sealing using modified silicone-based puttying material | |
| JPH01113471A (en) | Primer | |
| JPH06264044A (en) | Adhesive for building material | |
| JPS6086185A (en) | Adhesive for spray application | |
| JP2514511B2 (en) | Adhesive composition for patterned floor | |
| JPS615149A (en) | Water-proof construction method | |
| JP2663663B2 (en) | Backside treatment method for natural stone | |
| JPH01234377A (en) | Formation of coating film on concrete product | |
| JP3059902U (en) | Antifouling fiber reinforced plastic waterproof structure | |
| CN110303745A (en) | A kind of composite metal plate and preparation method thereof with antibacterial functions |