JPH03162575A - Stainless jig - Google Patents

Stainless jig

Info

Publication number
JPH03162575A
JPH03162575A JP30350289A JP30350289A JPH03162575A JP H03162575 A JPH03162575 A JP H03162575A JP 30350289 A JP30350289 A JP 30350289A JP 30350289 A JP30350289 A JP 30350289A JP H03162575 A JPH03162575 A JP H03162575A
Authority
JP
Japan
Prior art keywords
coating layer
jig
layer
sus
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30350289A
Other languages
Japanese (ja)
Inventor
Hiroyasu Satou
浩安 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tanaka Kikinzoku Kogyo KK
Original Assignee
Tanaka Kikinzoku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tanaka Kikinzoku Kogyo KK filed Critical Tanaka Kikinzoku Kogyo KK
Priority to JP30350289A priority Critical patent/JPH03162575A/en
Publication of JPH03162575A publication Critical patent/JPH03162575A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To easily remove a sticking metal, etc., from a stainless jig used in a device for forming a thin film and to make it possible to reuse the jig by successively forming an Au or Ni coating layer and an Ag or Cu coating layer on the surface of the jig to which an evaporated metal, etc., stick. CONSTITUTION:When a stainless jig is used in a device for forming a thin film by ion plating, sputtering, vacuum deposition or other method, an Au or Ni coating layer as a first layer and an Ag and/or Cu coating layer as a second layer are formed on the surface of the jig to which an evaporated metal, etc., stick. The first layer improves the adhesion of the second layer and facilitates the removal of a sticking metal and about >=0.1mum is sufficient for the thickness of the first layer. The second layer dissolves readily in nitric acid, etc., hardly corroding stainless steel and facilitates the removal of the sticking metal and the pref. thickness is about 0.2-20mum. The coating layers can be formed by electroplating, sputtering, ion plating or other method.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、電子工業界、電気機器材料等で使用されるイ
オンプレーティング、真空蒸着法、スパッタリングの薄
膜形或装置に用いる治具に関するものである。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a jig used for thin film type or equipment for ion plating, vacuum evaporation, and sputtering used in the electronic industry, electrical equipment materials, etc. It is.

(従来技術とその問題点) 近年、半導体、特にICの集積度が高くなり、その技術
は急速に伸びている。
(Prior art and its problems) In recent years, the degree of integration of semiconductors, especially ICs, has increased, and the technology thereof has been rapidly growing.

これらの集積度が高くなればなるほど、ICの回路幅、
回路の厚さ等がサブミクロンの領域になり、ファインパ
ターン形成するうえで超クリーンルームが必要条件にな
ってきている。
The higher the degree of integration, the wider the IC circuit width.
The thickness of circuits is now in the submicron range, and ultra-clean rooms are becoming a necessary condition for forming fine patterns.

一方、サブミクロンの回路ができれば、Siウエハーや
回路材料の材質により拡散が生じ、at1oyスパイク
を生じ特性上悪影響を発生させる。
On the other hand, if a submicron circuit is created, diffusion will occur due to the Si wafer or the material of the circuit material, causing an at1oy spike and causing an adverse effect on the characteristics.

このalloyスパイクを防止させるために、拡散防止
のバリャーが必要で、タングステン、チタンまたはこれ
らの合金が使用されている。 これらの金属は、大気中
では安定で薬品にも腐蝕しにくく、現在イオンプレーテ
ィング、真空蒸着法、スパッタリングの薄膜形成装置に
用いる治具に付着したタングステン、チタンまたはこれ
らの合金被膜は、機械的な処理方法として、ホーニング
やブラスト等で除去しているが、機械的な処理方法とし
て付着した被膜を除去した場合、治具のSUSベース材
料に食い込むことが多く、その後に洗浄しても取りきれ
ないという欠点があり、付着物を取りきれないまま、半
導体製造に使用すると、微細な付着物が治工具から落ち
、IC等の回路形成上パーティクル等の障害を生じてい
る。
To prevent this alloy spike, a diffusion barrier is required, and tungsten, titanium, or an alloy thereof is used. These metals are stable in the atmosphere and are not easily corroded by chemicals.Currently, tungsten, titanium, or their alloy coatings attached to jigs used in thin film forming equipment for ion plating, vacuum evaporation, and sputtering cannot be mechanically coated. As a treatment method, it is removed by honing, blasting, etc., but when removing the adhered film using a mechanical treatment method, it often digs into the SUS base material of the jig, and it cannot be removed even after cleaning. If it is used in semiconductor manufacturing without removing the deposits, the fine deposits will fall off the jigs and tools, causing problems such as particles in the formation of circuits such as ICs.

そこで、薬品によるクリーニングで治具に付着したタン
グステン、チタンまたはこれらの合金被膜を除去し、し
かも該付着物を取り除いた後の治具を再使用させるに障
害のないものとしているが治具のSUSベース材料を腐
蝕させないで除去するには限られた種類の薬品を使用す
ることとなり治具に付着したタングステン、チタンまた
はこれらの合金被膜を完全に除去させるのに極めて多く
の労力を要している。
Therefore, we remove the tungsten, titanium, or these alloy coatings that have adhered to the jig by cleaning with chemicals, and after removing the adhesion, the jig is safe to reuse, but the SUS of the jig is A limited number of chemicals are used to remove the base material without corroding it, and it takes an extremely large amount of effort to completely remove the tungsten, titanium, or these alloy coatings that adhere to the jig. .

(発明の目的) 本発明は、前記従来法の欠点を解決するために或された
もので、薬品によるクリーニングで治具に付着したタン
グステン、チタンまたはこれらの合金被膜を除去し、し
かも該付着物を取り除いた後の治具が再使用させるに障
害のない治具を提供することを目的とする。
(Object of the Invention) The present invention was created to solve the drawbacks of the conventional method, and it is possible to remove tungsten, titanium, or their alloy coatings attached to a jig by cleaning with chemicals, and to remove the deposits. The purpose of the present invention is to provide a jig that can be reused after removal without any hindrance.

(問題点を解決するための手段) 本発明は、イオンプレーティング、スパッタリングおよ
び真空蒸着用ステンレス製治具において、該ステンレス
製治具の蒸着金属等が付着する面側に、第一の被覆層に
金またはニッケルの被覆層を形成し、第二の被覆層とし
て銀および/または銅の被覆層が形成されて成るステン
レス製治具である。
(Means for Solving the Problems) The present invention provides a stainless steel jig for ion plating, sputtering, and vacuum deposition, in which a first coating layer is provided on the side of the stainless steel jig to which vapor-deposited metal, etc. adheres. This is a stainless steel jig having a gold or nickel coating layer formed thereon, and a silver and/or copper coating layer formed as a second coating layer.

まず、ステンレス製治具を使用する前に予めタングステ
ン、チタンまたはこれらの合金被膜の付着する面側に第
一の被覆層として金またはニッケルの被覆層を形成し、
次いで、第二の被覆層として銀および/または銅の被覆
層を形成させる。
First, before using the stainless steel jig, a gold or nickel coating layer is formed as a first coating layer on the side to which the tungsten, titanium, or alloy coating of these is to be attached.
Next, a silver and/or copper coating layer is formed as a second coating layer.

前記第一の被覆層として金またはニッケルとするのはS
USベース材料と第二の被覆層である銀および/または
銅の被覆層の密着性を高める効果があるとともに、治具
に付着したタングステン、チタンまたはこれらの合金被
膜を除去するため薬品によるクリーニングの際に除去の
程度を目視で判断するに適するからであり、また、第二
の被覆層を形成している銀および/または銅の被覆層と
の対蘂品特性が異なるものであるからである。
The first coating layer is made of gold or nickel.
It has the effect of increasing the adhesion between the US base material and the second coating layer of silver and/or copper, and also uses chemical cleaning to remove tungsten, titanium, or their alloy coatings that adhere to the jig. This is because it is suitable for visually determining the extent of removal, and also because the anti-coating properties are different from those of the silver and/or copper coating layer forming the second coating layer. .

なお、金またはニッケルの被覆層の厚みは0. 1μm
以上であればよいものである。
Note that the thickness of the gold or nickel coating layer is 0. 1μm
Any above is sufficient.

前記第二の被覆層として銀および/または銅の被覆層と
するのは、SUSベース材料を腐蝕しにくい薬品として
硝酸、シアン等に容易に溶解するため治具に付着したタ
ングステン、チタンまたはこれらの合金被膜をはがし易
くなるという効果かある。
The second coating layer is made of silver and/or copper because it easily dissolves in nitric acid, cyanide, etc. as a chemical that does not easily corrode the SUS base material. This has the effect of making it easier to peel off the alloy coating.

また、該第二の被覆層の厚みは0,2〜20μmでよい
もので、0.2μm以下では第二の被覆層からはがれに
くく、20μm以上では経済的に不利となるからである
Further, the thickness of the second coating layer may be 0.2 to 20 μm; if it is less than 0.2 μm, it will be difficult to peel off from the second coating layer, and if it is more than 20 μm, it will be economically disadvantageous.

なお、前記第一の披覆層および第二の被覆層を形成させ
る方法としては、電気メッキ法、スパッタリング、また
はイオンプレーチイングにより選んで行うことが良く、
SUSベース材料を痛めることなく、被覆層の厚みを調
節し易く、緻密で密着性のよい被覆層が得られるからで
ある。
The method for forming the first covering layer and the second covering layer may be selected from electroplating, sputtering, or ion plating.
This is because the thickness of the coating layer can be easily adjusted without damaging the SUS base material, and a dense coating layer with good adhesion can be obtained.

以下、本発明に係わる実施例を記載するが、該実施例は
本発明を限定するものではない。
Examples related to the present invention will be described below, but the examples are not intended to limit the present invention.

(実施例l) 治具であるSUS製のプラネタリドーム(直径480n
+m)に予め第一の被覆層として金を0.  2μm電
気メッキしたのち、次いで第二の被覆層として銀を0.
2μm電気メッキしたのちスパッタリング装置内にセッ
トしてチタンの薄膜を形成させる操作をした。
(Example 1) A planetary dome made of SUS (diameter 480n) was used as a jig.
+m) in advance with 0.0% gold as a first coating layer. After 2 μm electroplating, a second coating layer of 0.0 μm silver was applied.
After electroplating to a thickness of 2 μm, the sample was placed in a sputtering device to form a thin titanium film.

上記第一の被覆層に金を第二の被覆層に銀をメッキした
SUS製のプラネタリドームに付着したチタン被膜(膜
厚500〜1000μm)を、純水で十分に洗浄した後
、SUS製の容器に入れ希硝酸(硝酸1容量:水l容量
)に過酸化水素を滴下しながら加えて加熱して液温65
°Cにし、反応させたところ、第二の被覆層の銀が溶解
しチタン被膜が浮き上がりはがれて除去され金色の第一
の被覆層か目視で確認されたところでSUS製のプラネ
タリドームを取り出した。
After thoroughly washing the titanium film (film thickness 500 to 1000 μm) attached to the SUS planetary dome with gold plating on the first coating layer and silver plating on the second coating layer with pure water, Add hydrogen peroxide dropwise to dilute nitric acid (1 volume of nitric acid: 1 volume of water) in a container and heat until the liquid temperature reaches 65.
℃ and allowed to react, the silver in the second coating layer was dissolved and the titanium coating was lifted up and peeled off. When the gold-colored first coating layer was visually confirmed, the SUS planetary dome was taken out.

次いで、純水で洗浄したのち、70℃の温純水で十分に
洗浄した。
Next, it was washed with pure water, and then thoroughly washed with warm pure water at 70°C.

また、SUS製のプラネタリドームの腐蝕状況を拡大し
て観察したところ、何ら変化はみられなかった。
Further, when the corrosion status of the SUS planetary dome was observed under magnification, no change was observed.

(実施例2) SUS製のホルダと防着板(幅300mmX長さ450
mm)に予め第一の被覆層として金を0.1μm電気メ
ッキしたのち、次いで第二の被覆層として銅を5.0μ
m電気メッキしたのちスパッタリング装置内にセットし
てタングステンの薄膜を形成させる操作をした。
(Example 2) SUS holder and anti-adhesion plate (width 300mm x length 450mm)
mm) was electroplated in advance with 0.1 μm of gold as a first coating layer, and then with 5.0 μm of copper as a second coating layer.
After electroplating, the sample was placed in a sputtering device to form a thin tungsten film.

上記第一の被覆層に金を第二の被覆層に銅をメッキした
SUS製のホルダと防着板に付着したタングステン被膜
(膜厚500〜1000μm)を、純水で十分に洗浄し
た後、SUS製の容器に入れ希硝酸(硝酸1容量:水【
0容量)に過酸化水素を滴下しながら加えて加熱して液
温65℃にし、反応させたところ、第二の被覆層の銅が
溶解しタングステン被膜が浮き上がりはがれて除去され
金色の第一の被覆層が目視で確認されたところでSUS
製のホルダと防着板を取り出した。
After thoroughly washing the tungsten coating (film thickness 500 to 1000 μm) attached to the SUS holder and the anti-adhesion plate in which the first coating layer is plated with gold and the second coating layer is plated with copper, with pure water, Place dilute nitric acid (1 volume of nitric acid: water) in a SUS container.
When hydrogen peroxide was added dropwise to the solution (0 volume) and heated to a temperature of 65°C to cause a reaction, the copper in the second coating layer was dissolved and the tungsten coating was lifted up and peeled off, leaving the gold-colored first coating. When the coating layer is visually confirmed, the SUS
I took out the manufactured holder and anti-adhesion plate.

次いで、純水で洗浄したのち、70℃の温純水で十分に
洗浄した。
Next, it was washed with pure water, and then thoroughly washed with warm pure water at 70°C.

また、SUS製のプラネタリドームの腐蝕状況を拡大し
て観察したところ、何ら変化はみられなかった。
Further, when the corrosion status of the SUS planetary dome was observed under magnification, no change was observed.

(実施例3) SUS製のプラネタリドーム(直径300mm)に予め
ニッケルを0.2μm電気メッキしたのち、次いで銅を
1.  0μm電気メッキし、スパッタリング装置内に
セットしてタングステンとチタンの薄膜を形成させる操
作をした。
(Example 3) A SUS planetary dome (diameter 300 mm) was electroplated with nickel to a thickness of 0.2 μm, and then copper was plated to a thickness of 1.5 μm. It was electroplated to a thickness of 0 μm and placed in a sputtering device to form a thin film of tungsten and titanium.

上記第一の被覆層にニッケルを第二の被覆層に銅をメッ
キしたSUS製のプラネタリドームに付着したタングス
テンとチタンの層状の被膜(膜厚500〜1000μm
)を、純水で十分に洗浄した後、SUS製の容器に入れ
シアン系の銅エッチング液(シアン化カリウム5 0 
g/l.、水酸化カリウム7.5g/A、剥離剤(商品
名Nソルト)13g/I!.)を、P. V.  C槽
に建浴し、40〜50℃に加温してから、前記ブラネタ
リドームを一昼夜浸漬した。
A layered coating of tungsten and titanium (film thickness 500 to 1000 μm) adhered to the SUS planetary dome in which the first coating layer is plated with nickel and the second coating layer is plated with copper.
) with pure water, put it in a SUS container and add a cyanide-based copper etching solution (potassium cyanide 50
g/l. , potassium hydroxide 7.5g/A, stripping agent (trade name N Salt) 13g/I! .. ), P. V. A bath was prepared in Tank C, heated to 40 to 50°C, and then the Blanetari dome was immersed for one day and night.

第二の披覆層の銅が溶解しタングステンとチタンの層状
の被膜が浮き上がりはがれて除去されニッケル色の第一
の被覆層が目視で確認されたところでSUS製のプラネ
タリドームを取り出した。
The SUS planetary dome was taken out when the copper of the second coating layer was dissolved, the layered coating of tungsten and titanium was lifted up, peeled off, and removed, and the nickel-colored first coating layer was visually confirmed.

次いで、純水で洗浄したのち、70°Cの温純水で十分
に洗浄した。
Next, it was washed with pure water, and then thoroughly washed with warm pure water at 70°C.

また、SUS製のプラネタリドームの腐蝕状況を拡大し
て観察したところ、何ら変化はみられなかった。
Further, when the corrosion status of the SUS planetary dome was observed under magnification, no change was observed.

(実施例4) SUS製のプラネタリドーム(直径480mm)に予め
第一の被覆層として金を0.2μm電気メッキしたのち
、次いで第二の被覆層として銅を2.0μm電気メッキ
したのち、さらに銀を0.5μm電気メッキし、スパッ
タリング装置内にセットしてチタンの薄膜を形成させる
操作をした。
(Example 4) A SUS planetary dome (diameter 480 mm) was electroplated with gold to a thickness of 0.2 μm as a first coating layer, then copper was electroplated to a thickness of 2.0 μm as a second coating layer, and then Silver was electroplated to a thickness of 0.5 μm, and the plate was placed in a sputtering device to form a thin titanium film.

上記第一の被覆層に金を第二の被覆層に銅と銀をメッキ
したSUS製のプラネタリドームに付着したチタン被膜
(膜厚300〜500μm)を、純水で十分に洗浄した
後、SUS製の容器に入れ希6Cj酸(稍酸2容量:水
IO容m)に過酸化水素を滴下しながら加えて加熱して
液温65℃にし、反応させたところ、第二の被覆層の銀
と銅が溶解しチタンが浮き上がりはがれて除去され金色
の第一の被覆層が目視で確認されたところでSUS製の
プラネタリドームを取り出した。
The titanium film (thickness: 300 to 500 μm) attached to the SUS planetary dome, in which the first coating layer is plated with gold and the second coating layer is plated with copper and silver, is thoroughly washed with pure water, and then the SUS Hydrogen peroxide was added dropwise to dilute 6Cj acid (2 volumes of chloric acid: IO volume of water in m) in a plastic container, heated to a liquid temperature of 65°C, and reacted. When the copper was dissolved and the titanium was lifted up and peeled off, and the golden first coating layer was visually confirmed, the SUS planetary dome was taken out.

次いで、純水で洗浄したのち、70℃の温純水で十分に
洗浄した。
Next, it was washed with pure water, and then thoroughly washed with warm pure water at 70°C.

また、SUS製のプラネタリドームの腐蝕状況を拡大し
て観察したところ、何ら変化はみられなかった。
Further, when the corrosion status of the SUS planetary dome was observed under magnification, no change was observed.

(発明の効果) 以一ヒのように、本発明の予め治具に第一の被覆層とし
て金またはニッケルの被覆を形成させ、第二の被覆層と
して銀および/または銅の被覆層を形成しておき、スパ
ッタリングや真空蒸着を行った際に付着するタングステ
ンやチタン等の被膜を薬品で処理することでタングステ
ンやチタン等を剥がして除去することができ、従来法の
欠点となる治具に食い込むことのある付着物等がなく、
しかもSUSのベース材を腐蝕することもなく処理がで
き、 該治工具を再利用することができ極めて効果大なるもの
である。
(Effects of the Invention) As described above, a gold or nickel coating is formed as a first coating layer on the jig of the present invention, and a silver and/or copper coating layer is formed as a second coating layer. By treating the coating of tungsten, titanium, etc. that adheres during sputtering or vacuum evaporation with chemicals, the tungsten, titanium, etc. can be peeled off and removed. There are no deposits that could dig in,
Moreover, the process can be performed without corroding the SUS base material, and the jigs and tools can be reused, which is extremely effective.

Claims (1)

【特許請求の範囲】[Claims] (1)イオンプレーティング、スパッタリングおよび真
空蒸着用ステンレス製治具において、該ステンレス製治
具の蒸着金属等が付着する面側に、第一の被覆層として
金またはニッケルの被覆層を形成し、第二の被覆層とし
て銀および/または銅の被覆層が形成されて成るステン
レス製治具。
(1) In a stainless steel jig for ion plating, sputtering, and vacuum evaporation, a gold or nickel coating layer is formed as a first coating layer on the side of the stainless steel jig to which evaporated metal, etc. is attached, A stainless steel jig in which a silver and/or copper coating layer is formed as a second coating layer.
JP30350289A 1989-11-22 1989-11-22 Stainless jig Pending JPH03162575A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30350289A JPH03162575A (en) 1989-11-22 1989-11-22 Stainless jig

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30350289A JPH03162575A (en) 1989-11-22 1989-11-22 Stainless jig

Publications (1)

Publication Number Publication Date
JPH03162575A true JPH03162575A (en) 1991-07-12

Family

ID=17921744

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30350289A Pending JPH03162575A (en) 1989-11-22 1989-11-22 Stainless jig

Country Status (1)

Country Link
JP (1) JPH03162575A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020040702A (en) * 2002-03-05 2002-05-30 김경수 Jig Material for Hot-dip Galranized Metal Plate
JP2014141709A (en) * 2013-01-23 2014-08-07 Sumitomo Metal Mining Co Ltd Deposition preventing member and film deposition apparatus comprising the same and maintenance method of deposition preventing member

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020040702A (en) * 2002-03-05 2002-05-30 김경수 Jig Material for Hot-dip Galranized Metal Plate
JP2014141709A (en) * 2013-01-23 2014-08-07 Sumitomo Metal Mining Co Ltd Deposition preventing member and film deposition apparatus comprising the same and maintenance method of deposition preventing member

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