JPH03143364A - Cream for whipping and preparation thereof - Google Patents
Cream for whipping and preparation thereofInfo
- Publication number
- JPH03143364A JPH03143364A JP1280428A JP28042889A JPH03143364A JP H03143364 A JPH03143364 A JP H03143364A JP 1280428 A JP1280428 A JP 1280428A JP 28042889 A JP28042889 A JP 28042889A JP H03143364 A JPH03143364 A JP H03143364A
- Authority
- JP
- Japan
- Prior art keywords
- cream
- chitosan
- emulsifier
- water
- whipping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006071 cream Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title description 2
- 229920001661 Chitosan Polymers 0.000 claims abstract description 28
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 238000001816 cooling Methods 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 239000008346 aqueous phase Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000012071 phase Substances 0.000 claims abstract description 5
- 230000001954 sterilising effect Effects 0.000 claims abstract description 5
- -1 glycerin fatty acid ester Chemical class 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 238000000265 homogenisation Methods 0.000 claims description 13
- 239000008256 whipped cream Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 239000000787 lecithin Substances 0.000 claims description 5
- 235000010445 lecithin Nutrition 0.000 claims description 5
- 229940067606 lecithin Drugs 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 230000006196 deacetylation Effects 0.000 claims description 3
- 238000003381 deacetylation reaction Methods 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 2
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000000839 emulsion Substances 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 230000035939 shock Effects 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 235000013336 milk Nutrition 0.000 description 6
- 239000008267 milk Substances 0.000 description 6
- 210000004080 milk Anatomy 0.000 description 6
- 239000003925 fat Substances 0.000 description 5
- 235000019197 fats Nutrition 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 241000951471 Citrus junos Species 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229920001503 Glucan Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 235000019737 Animal fat Nutrition 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 235000003301 Ceiba pentandra Nutrition 0.000 description 1
- 244000146553 Ceiba pentandra Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 102000000340 Glucosyltransferases Human genes 0.000 description 1
- 108010055629 Glucosyltransferases Proteins 0.000 description 1
- 235000014486 Hydrangea macrophylla Nutrition 0.000 description 1
- 241001091442 Hydrangeaceae Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- BBEAQIROQSPTKN-UHFFFAOYSA-N antipyrene Natural products C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000009928 pasteurization Methods 0.000 description 1
- 208000028169 periodontal disease Diseases 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 235000008476 powdered milk Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
Landscapes
- Grain Derivatives (AREA)
- Dairy Products (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、キI・ザン及び乳化剤を含有せしめたホイッ
プ用クリーム及びその製造法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a whipping cream containing KiI-Zan and an emulsifier, and a method for producing the same.
(従来の技術及び問題点)
現在、市場には、油溶性成分と水溶性成分とを乳化して
作られる合成りIJ−11、牛乳から分離された生クリ
ーム等多種多様のクリーム製品が市販されている。そし
て、これらの製品は、流通形態の複雑化、家庭用クリー
ムの伸上に伴って取扱方法が複雑になってきている。特
に、これらの製品のなかでホイップ用クリーム類は、温
度変化及び振動によって劣化するという特性をもってい
る。(Prior art and problems) Currently, there are a wide variety of cream products on the market, such as synthetic IJ-11 made by emulsifying oil-soluble components and water-soluble components, and fresh cream separated from milk. ing. The handling methods for these products are becoming more complicated as distribution formats become more complex and the popularity of household creams increases. In particular, among these products, whipping creams have the characteristic of deteriorating due to temperature changes and vibrations.
具体的には、ホイップ用クリームは長時間の振動あるい
はI易〆晶、冷却の繰り返しによりl曽オーiし固化す
る場合がある。特に、揚温し、冷却処理した場合、ホイ
ップしても終点でのシマリが激しく、オーバーランが低
く、硬くボッボッした糺織となり、その結果、口どけが
わるくフレーバーリリースもわるくなる。Specifically, whipping cream may become hardened and solidified due to long-term vibration, hardening, and repeated cooling. In particular, when fried and cooled, even after whipping, there is severe shimmering at the end of the process, low overrun, and a hard and fluffy paste, resulting in poor melt-in-the-mouth texture and poor flavor release.
しかも、ホイップクリーノ、類には、液状状態で安定で
あり、かつ、ホイップ時には速かに解乳化し適度の硬さ
とオーバーランとを有するホイップが得られなければな
らないという相反する2面の特性が要求される。これら
の特性を満足さセるために、従来は、乳化剤の1!1!
類を選択し、それを組合せ、それによって柚脂の特性を
調整してこの問題解決の糸口を探索してきた。Moreover, whip creamers and similar products have two contradictory characteristics: they must be stable in a liquid state, and quickly demulsify during whipping to provide a whip with appropriate hardness and overrun. is required. In order to satisfy these characteristics, conventionally, emulsifiers of 1!1!
We have been searching for ways to solve this problem by selecting different types, combining them, and adjusting the properties of yuzu oil.
しかし、種々の試みにもかかわらす決定的な解決にはい
まだ到っていない。特に、液状状態での安定性に関して
は程度の差はあるもののいずれのクリームでも揚湯、冷
却後に増粘、固化が発生ずる。However, despite various attempts, a definitive solution has not yet been reached. In particular, in terms of stability in a liquid state, all creams tend to thicken and solidify after being fried and cooled, although there are varying degrees of stability.
即ち、流通時に揚湯、冷却状態に置かれると液状状態で
の脂肪球凝集が起こり安定性が劣化し増粘する。このよ
うな処理を受けたクリームは、ホイップ時にはオーバー
ランの低下、硬さの顕著な増加1口どけの劣化がみられ
る。過去にはこれらの現象を解決するために種々の乳化
剤の組み合わせにより揚湯、冷却耐外を付写していた。That is, if the product is heated and cooled during distribution, fat globules agglomerate in the liquid state, resulting in decreased stability and increased viscosity. Creams that have undergone such treatment show a decrease in overrun, a noticeable increase in hardness, and a deterioration in melt-in-the-mouth consistency during whipping. In the past, in order to solve these phenomena, various combinations of emulsifiers were used to improve hot water heating and cooling resistance.
具体的には、特開昭551.4117.i号公報の合成
ホイップ用クリームの製造方法では、レシチン、ソルビ
タン脂肪酸エステル及びグリセリン脂肪酸エステルを、
また特開昭56−.15171号公報の合成ホイップ用
クリームではグリセリン脂肪酸エステル、ソルビタン脂
肪酸エステル、沃素価約80〜100のクリセリン不飽
和脂肪酸エステル、1−(L B 1〜2の蔗糖脂肪酸
エステル及びレシチンを特定の比率で用いており、これ
らの先行技術にみられるように特定の乳化剤を特定の比
率で組合せて使用することによって耐輸送性及び耐熱性
を改良している。Specifically, Japanese Patent Application Laid-Open No. 551.4117. In the method for producing synthetic whipped cream disclosed in Publication No. I, lecithin, sorbitan fatty acid ester, and glycerin fatty acid ester are
Also, JP-A-56-. The synthetic whipping cream of Publication No. 15171 uses glycerin fatty acid ester, sorbitan fatty acid ester, chrycerin unsaturated fatty acid ester with an iodine value of about 80 to 100, sucrose fatty acid ester with 1-(LB 1 to 2), and lecithin in a specific ratio. As seen in these prior art techniques, transport resistance and heat resistance are improved by using specific emulsifiers in combination in specific ratios.
しかし、安定剤による改良例はない。従来の本発明者等
のデスI・結果によれば一般的な安定剤ば全て粘度を高
くする作用があるだけでなく楊温、冷却耐性に欠けてい
た。However, there are no examples of improvements using stabilizers. According to the conventional results obtained by the inventors of the present invention, all common stabilizers not only have the effect of increasing viscosity, but also lack heat resistance and cooling resistance.
(問題点を解決するための手段)
本発明は、このような事情に鑑みなされたものであって
、乳化剤ばかりでなく、安定剤を選択することによって
、従来の安定剤を使用した場合のように、クリームが揚
湯、冷却耐性に欠け、その結果ホイップクリでのシマリ
が激しく、オーバーランが低く硬いボッボッした組織と
なることを肪止し、揚湯、冷却後も適正な液状状態を保
ち、粘度の増加しないホイップクリ−11を/j)よう
とするものである。(Means for Solving the Problems) The present invention has been made in view of the above circumstances, and by selecting not only an emulsifier but also a stabilizer, it is possible to eliminate the problem by selecting a stabilizer instead of an emulsifier. In addition, the cream lacks resistance to frying and cooling, resulting in severe shimmering when whipped, and a hard, lumpy structure with low overrun. The purpose is to create a whipped cream 11 whose viscosity does not increase.
本発明者は、このようなりリームを得る目的のために多
数の安定剤について検討し、その結果キトサンがこのよ
うな目的に使用され得るものであり、キトサンと乳化剤
とを併用することによって揚湯2冷却後も適正な液状状
態を保ち、粘度の増加しないホイップクリームを得るこ
とができるという知見を得て本発明を完成するに至った
ものである。The present inventor has studied a number of stabilizers for the purpose of obtaining such reams, and as a result, chitosan can be used for this purpose, and by using chitosan and an emulsifier together, it is possible to The present invention was completed based on the knowledge that it is possible to obtain whipped cream that maintains a proper liquid state even after cooling and does not increase in viscosity.
すなわち、本発明は、
(1)キトサンと乳化剤とを含有せしめたホイップ用ク
リ−Jl、
及び
(2) ?rh溶性成分よりなる油相と水溶性成分よ
りなる水相とを乳化剤の存在下に混合し、加熱し、均質
化し、殺菌または滅菌し、冷却を行ってホイップ用クリ
ームを製造するに当り、均質化後の工程において、キト
サンを添加することよりなるホイップ用クリームの製造
法
に関する。That is, the present invention provides (1) whipping cream Jl containing chitosan and an emulsifier, and (2) ? When producing whipped cream by mixing an oil phase consisting of rh-soluble components and an aqueous phase consisting of water-soluble components in the presence of an emulsifier, heating, homogenizing, pasteurizing or sterilizing, and cooling, The present invention relates to a method for producing whipped cream, which comprises adding chitosan in a step after fermentation.
従来、キチンから誘導とれる水溶性化合物を飲食品に配
合することば知られている(特開昭61216648号
公報)。この水溶性化合物はキトサンの1種と考えられ
、ここでは脱アセチル化度が40〜60%のものが使用
されているが、ここで前記水溶性化合物を飲食品に添加
する目的は、ストレプトコッカス・ミュータンスがショ
糖を基質としてグルコシルトランスフェラーゼの作用に
よって非水溶性菌体外グルカンを産生ずること及び該グ
ルカンか歯牙表面に強固に41着することを防IJIシ
、それによってう触子Iυj効果、「」皇子11)j効
果、歯周病予防効果を達成しよ・うとするものであり、
本発明の目的と相違する。しかも、飲食品もドロップ、
クツキー、セリー等シーI糖を多晴に含有ずろ飲食品が
示されており、ホイップ用クリームについては全く述べ
られていない。BACKGROUND ART Conventionally, it has been known to incorporate water-soluble compounds derived from chitin into foods and drinks (Japanese Patent Application Laid-Open No. 61216648). This water-soluble compound is considered to be a type of chitosan, and the one used here has a degree of deacetylation of 40 to 60%. This prevents the production of water-insoluble extracellular glucan by Glucosyltransferase using sucrose as a substrate and the firm adhesion of the glucan to the tooth surface, thereby preventing the caries Iυj effect. ``Prince 11) It aims to achieve the effect of preventing periodontal disease,
This is different from the purpose of the present invention. Moreover, food and drinks are also dropped,
Foods and beverages containing a large amount of Sea I sugar, such as kutsky and celery, are disclosed, and whipping cream is not mentioned at all.
本発明では、このような公知例とは相違し、前記したよ
うにキトサンと乳化剤とをホイップ用クリームに含有さ
せるごとによって、クリ−J、が揚湯、冷却処理しても
安定で適正な物性イ直をもつ液状状態を保ち、オーバー
ランの現象が少なく、過度に硬くならず口どけ良好なホ
イップクリ−1、を得ることができるようにしようとす
るものである。In the present invention, unlike such known examples, by incorporating chitosan and an emulsifier into the whipping cream as described above, Cree-J has stable and appropriate physical properties even when hot water is heated and cooled. It is an object of the present invention to provide whipped cream 1 that maintains a liquid state with smoothness, has little overrun phenomenon, does not become excessively hard, and melts well in the mouth.
このようなりリームは合成りリームでもよいし、また牛
乳から分離した生クリームでもよい。Such ream may be synthetic ream or fresh cream separated from milk.
さらに、クリーム製造は、一般には、水溶IIL成分の
溶液と油溶性成分を溶解した溶液との各々の水系、油脂
を混合、均質化する方法を採用している。キトザンを水
溶性成分として水系に加えると乳蛋白と反応して凝集物
を形成するおそれがある。Furthermore, cream production generally employs a method in which a solution of a water-soluble IIL component and a solution of an oil-soluble component are mixed and homogenized. When chitosan is added as a water-soluble component to an aqueous system, it may react with milk proteins and form aggregates.
この結果、クリームが適正な物性値をもつ液状状態は保
てるものの、乳化、均質化−[稈において、均質機内で
バルブ、ピストンに凝集物が付着し、運転性能が低下す
ることがあるので、このような点を考慮し、ギトザンの
クリームへの添加は、クリームの均質化処理後の工程に
おいて行うことが望ましい。As a result, although the cream can maintain a liquid state with appropriate physical properties, emulsification and homogenization (in the culm, aggregates may adhere to the valves and pistons in the homogenizer, reducing operational performance. Considering these points, it is desirable that Gitosan be added to the cream in a step after the cream is homogenized.
キトサンは脱アセチル化度70%以」―、好適には75
〜85%のものを0.01〜0.5%、好ましくは0.
01〜0,2%添加し、乳化剤は、レシチン、グリセリ
ン脂肪酸エステル、蔗糖脂肪酸エステル、ソルビタン脂
肪酸エステル及びブIIピレングリコール脂肪酸エステ
ルよりなるZ(fから選択されるものを0.03〜1.
0%添方力11ることか望ましい。Chitosan has a degree of deacetylation of 70% or more, preferably 75%.
~85% of 0.01 to 0.5%, preferably 0.
The emulsifier is selected from Z (f) consisting of lecithin, glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and BuII pyrene glycol fatty acid ester, and the emulsifier is 0.03 to 1.
It is desirable to have a 0% bias force of 11.
このような配合割合、特にキトサンは0.01%以下で
は効果の発現が弱く、また0、5%以上となると乳成分
中の蛋白とキI・サンとが反応して凝集物を生し、粘度
が増加し、保存性がわるくなる。If the blending ratio is less than 0.01%, especially chitosan, the effect will be weak, and if it is more than 0.5%, the protein in the milk component will react with chitosan to form aggregates. Viscosity increases and storage stability deteriorates.
本発明では油溶性成分には、ナタネ油、トウモロコシ柚
、綿実油、カポック油、大豆油、米柚、バーム浦等の植
物浦、牛脂等の動物脂肪、あるいはこれらに分別、水素
添加、エステル交換等を行って得られる油脂が単独また
は混合して使用される。また、これらに脂溶性乳化剤、
脂溶性ビタミンその他の脂溶性食品添加物を添加しても
よい。In the present invention, the oil-soluble components include rapeseed oil, corn yuzu, cottonseed oil, kapok oil, soybean oil, rice yuzu, vegetable ura such as barm ura, animal fat such as beef tallow, or fractionation, hydrogenation, transesterification, etc. The fats and oils obtained by this process can be used alone or in combination. In addition, fat-soluble emulsifiers,
Fat-soluble vitamins and other fat-soluble food additives may also be added.
また水溶(11成分には、全乳、粉乳、脱脂粉乳等の乳
成分が単独でまたは混合して用いられる。In addition, milk components such as whole milk, powdered milk, skim milk powder, etc. are used alone or in combination as the water-soluble (11 components).
そして、これらに、水溶性ビタミン、リン酸塩、水溶性
カルシウム塩、水溶性ヒタごン等の水溶性食品添加物を
配合し、水に溶解して使用してもよい。リン酸塩につい
ては、一般にその水素イオン濃度緩衝作用、金属イオン
封鎖作用が知られている。これを合成りリーム、?Lク
リームに使用した場合、粘度の低下、エマルジョンの安
定性、楊温冷却耐性付与に効果を示すことから必要に応
して適宜添加する。このようなリン酸塩としては、第1
リン酸ナトリウム、第2リン酸す1ヘリウム、第3リン
酸すI〜ゾリウムメタリン酸すl・リウム、ヘキサメタ
リン酸すl−リウム、ポリリン酸すトリウムを例示でき
、これらの1種または21fi以上の使用が有効である
。リン酸塩は、クリームに対して0.05〜0.5重量
%添加することが好ましい。These may be mixed with water-soluble food additives such as water-soluble vitamins, phosphates, water-soluble calcium salts, and water-soluble hydrangeas, and dissolved in water for use. Phosphates are generally known for their hydrogen ion concentration buffering and metal ion sequestering effects. Synthesize this, Riream? When used in L cream, it is effective in reducing viscosity, emulsion stability, and imparting cooling resistance, so it is added as necessary. As such phosphates, the first
Examples include sodium phosphate, monohelium dibasic phosphate, sodium tertiary phosphate to zolium metaphosphate, sulfurium hexametaphosphate, and thorium polyphosphate, and one of these or 21fi or more is effective. It is preferable to add 0.05 to 0.5% by weight of phosphate to the cream.
本発明にお1.Jるホイップ用クリームの製造法では、
油脂を加温下で単独または数種混合溶解し、これに乳化
剤を加え、溶解する。一方、わ(乳等の水溶性成分を温
水に溶解し、この油相と水相とを加温下でホモミキサー
で撹拌する。必要な場合、この容量を水で調整し、均質
機で均質処理し、殺菌または滅菌し、冷却を行って製品
を得る。The present invention includes 1. In the manufacturing method of Juru whipping cream,
Fats and oils are dissolved singly or in combination under heating, and an emulsifier is added and dissolved. On the other hand, dissolve water-soluble ingredients such as milk in warm water, and stir the oil phase and aqueous phase with a homomixer under heating. If necessary, adjust the volume with water and homogenize with a homogenizer. Processing, pasteurization or sterilization, and cooling to obtain the product.
キトサンは所要量を水を加えて膨潤させ、これに乳酸等
の有機酸を加えて水溶液とし製造工程の適宜の段階で添
加するが、特に前述したように均質化処理後の工程で添
加すると乳蛋白質と反応して凝集物を生成することがな
く、添加されている乳化剤の作用と相まって良好な乳化
物を得ることができ、均質機の運転性能を低下させるこ
とがl〔い。これば、水溶性成分を均質化した後生トザ
ンを添加すると、均質化処理によって水溶液中の蛋白質
が脂肪球皮膜中に吸収されるためキトリ・ンと反応しな
くなるものと推定される。Chitosan is swollen by adding the required amount of water, and then an organic acid such as lactic acid is added to make an aqueous solution, which is then added at an appropriate stage of the manufacturing process.In particular, as mentioned above, if it is added after the homogenization process, milk It does not react with proteins to form aggregates, and together with the action of the added emulsifier, a good emulsion can be obtained, and the operating performance of the homogenizer will not be degraded. It is presumed that if fresh tozan is added after homogenizing the water-soluble components, the proteins in the aqueous solution will be absorbed into the fat globule membrane by the homogenization process and will not react with chitrilin.
次に、本発明の実施例を示し、本発明をより上1体的に
説明する。Next, examples of the present invention will be shown to explain the present invention in a more comprehensive manner.
実施例1
加温した配合油脂4.00kgにレシチン20f!グリ
セリン脂肪酸エステル10g、ポリグリセリン脂肪酸エ
ステル30 gを添加し混合、溶解した。ついで脱脂粉
乳400g、リン酸塩10 gを5.50kgの温水に
添加・混合し、これを60°Cに加温した。この水相に
70°Cに加温した前記浦和を添加しながらホモミキザ
ーで10分撹拌した。撹拌後、全量をlo、ookgに
加水調整した。第1表に各番号の試料の原料配合割合及
びキI・ザンの添加時期を、第1図にクリーム製造工程
を示す。番号#1は、加水調整後にキトサン水溶液の代
りに水溶液を添加し、番号#2〜#4ば、加水調整後に
別途調製した−1−トリーン水溶液を添加し、その後均
質機で100kg/CrfIで均質処理し華気吹き込み
式直接滅菌機にて140°C,4秒の条件で滅菌しその
後10°Cまでプレートクーラーにて急速冷却した。ま
た、番号#5〜#7は、加水調整後に均質機で100k
g/CrNで均質処理し、その後別途調製したキトサン
水溶液を添加し混合したのち華気吹き込み式直接滅菌機
にて140°C,4秒の条件で滅菌しその後10°Cま
でプレーI・クーラーにて急速冷却した。得られたホイ
ップクリームは、5°Cにて7日間エージングしたのら
、粘度測定・顕微鏡観察・ホイップテスト及びヒートシ
ョックテスI・に供した。Example 1 20 f lecithin in 4.00 kg of warmed blended oil and fat! 10 g of glycerin fatty acid ester and 30 g of polyglycerin fatty acid ester were added, mixed, and dissolved. Next, 400 g of skim milk powder and 10 g of phosphate were added to and mixed with 5.50 kg of warm water, and the mixture was heated to 60°C. The above-mentioned Urawa heated to 70°C was added to this aqueous phase while stirring for 10 minutes using a homomixer. After stirring, the total amount was adjusted to lo, ookg with water. Table 1 shows the mixing ratio of raw materials and the time of addition of KiI-Zan for each numbered sample, and FIG. 1 shows the cream manufacturing process. For number #1, an aqueous solution was added instead of the chitosan aqueous solution after the water adjustment, and for numbers #2 to #4, a separately prepared -1-thrine aqueous solution was added after the water adjustment, and then homogenized with a homogenizer at 100 kg/CrfI. It was treated and sterilized using a direct sterilizer using a flower blowing type direct sterilizer at 140°C for 4 seconds, and then rapidly cooled to 10°C using a plate cooler. In addition, numbers #5 to #7 are 100k in a homogenizer after water adjustment.
After homogenizing with g/CrN, a chitosan aqueous solution prepared separately was added and mixed, and then sterilized in a direct sterilizer using a direct sterilizer at 140°C for 4 seconds, and then placed in a play I cooler until 10°C. and rapidly cooled. The obtained whipped cream was aged at 5°C for 7 days and then subjected to viscosity measurement, microscopic observation, whipping test, and heat shock test I.
均質時の均質機の運転状態及びクリーム調製後の乳化状
態を第2表に示した。均質機の運転状態は、#2.#3
.#4がそれぞれやや不良となった。クリーム運転後の
乳化状態ば、#1. ;#5#6.#7が良好であり、
#2は、#1. #5#6.#7と比較するとやや劣る
状態であった。Table 2 shows the operating state of the homogenizer during homogenization and the emulsification state after cream preparation. The operating state of the homogenizer is #2. #3
.. #4 was slightly defective. If the emulsification state after cream operation is #1. ;#5#6. #7 is good,
#2 is #1. #5 #6. The condition was slightly inferior compared to #7.
この結果、キトサンを添加する場合は均質後にしたほう
が良いことか判った。As a result, it was found that it is better to add chitosan after homogenization.
調製したホイップクリームの粘度を第3表に示した。キ
トサンを均質後に添加した系の方がヒートショック(H
3)後の粘度増加が少なく良好であった。The viscosity of the whipped cream prepared is shown in Table 3. The system in which chitosan was added after homogenization had better heat shock (H
3) There was little increase in viscosity after that, which was good.
ill製したホイップクリームのホイップテスト結果を
第4表に示した。キトサンを均質後に添加した系はホイ
ップ時間が短くホイツプ性に優れていた。また、ヒート
ショック後のオーバーラン減少が少なくヒートショック
耐性に優れ°ζいた。ホイップクリームをしぼり型に入
れてしぼり出したときの造花時の組織についてもキトサ
ンを均質後に添加した系の方が良好であった。離水に関
しては、ヒートショック後にその差が現れ、キトサンを
均質後に添加した系の方が離水が少な(良好であった。Table 4 shows the results of the whipping test for the whipped cream made by ill. The system in which chitosan was added after homogenization had short whipping time and excellent whipping properties. In addition, the overrun reduction after heat shock was small and the heat shock resistance was excellent. The structure of artificial flowers when whipped cream was put into a squeeze mold and squeezed out was also better in the system in which chitosan was added after homogenization. Regarding water syneresis, the difference appeared after heat shock, and the system in which chitosan was added after homogenization had less water syneresis (better).
口どけに関してもヒートショック後にその差が現れ、キ
トサンを均質後に添加した系の方が口どけが良好であっ
た。Differences in melting in the mouth also appeared after heat shock, with the system in which chitosan was added after homogenization having better melting in the mouth.
以上のように、キトザン添加は、ホイップクリームの物
性を改良する効果を有し、特にヒートショック耐性の向
上が顕著である。また、キトサンの添加にあたっては、
ごれを、均質後に添加することによりその効果を充分に
発揮することが出来る。As described above, the addition of chitozan has the effect of improving the physical properties of whipped cream, and in particular, the improvement in heat shock resistance is remarkable. In addition, when adding chitosan,
By adding dirt after homogenization, its effect can be fully exhibited.
以下余白
7
■
(発明の効果)
本発明ではホイップ用クリーム製造のさい、乳化剤とキ
トサンとを添加するので揚湯7冷却処理耐性を有し、安
定で適正な物性をもつホイップ用クリームを得ることが
できる。特に、キトサンをホイップ用クリームの均質化
後に加えると乳化均質のさいに均質機内でバルブ、ピス
トンへの凝集物の付着を防止することによって、運転性
能の低下を防止することができる。そして得られたクリ
ームは揚湯、冷却処理に対し、−層目性を有し、かつ安
定で良好な物性を示すものとなる。Margin below 7 ■ (Effects of the invention) In the present invention, when producing whipping cream, emulsifiers and chitosan are added, so that it is possible to obtain whipping cream that is resistant to boiling and cooling treatment and has stable and appropriate physical properties. Can be done. In particular, when chitosan is added after homogenizing whipping cream, it can prevent deterioration in operational performance by preventing aggregates from adhering to valves and pistons in the homogenizer during emulsification homogenization. The resulting cream has a layered texture, is stable, and exhibits good physical properties when subjected to frying and cooling treatments.
第1図は、本発明のホイップ用クリーム製造の工程を示
す工程図である。FIG. 1 is a process chart showing the process of producing whipped cream according to the present invention.
Claims (4)
リーム(1) Whipping cream containing chitosan and emulsifier
って、これを0.01〜0.5%含有せしめたものであ
る請求項(1)のホイップ用クリーム(2) The whipping cream according to claim (1), wherein the chitosan has a degree of deacetylation of 70% or more and contains 0.01 to 0.5% of chitosan.
、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル及び
プロピレングリコール脂肪酸エステルよりなる群から選
択される1種または2種以上のものであって、これを0
.03〜1.0%含有せしめたものである請求項(1)
または(2)のホイップ用クリーム(3) The emulsifier is one or more selected from the group consisting of lecithin, glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and propylene glycol fatty acid ester, and
.. Claim (1)
Or (2) whipping cream
相とを乳化剤の存在下に混合し、加熱し、均質化し、殺
菌または滅菌し、冷却を行ってホイップ用クリームを製
造するに当り、均質化後の工程において、キトサンを添
加することを特徴とするホイップ用クリームの製造法(4) To produce whipped cream by mixing an oil phase consisting of oil-soluble components and an aqueous phase consisting of water-soluble components in the presence of an emulsifier, heating, homogenizing, pasteurizing or sterilizing, and cooling. A method for producing whipping cream characterized by adding chitosan in the process after homogenization.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1280428A JP2844537B2 (en) | 1989-10-27 | 1989-10-27 | Whipping cream and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1280428A JP2844537B2 (en) | 1989-10-27 | 1989-10-27 | Whipping cream and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03143364A true JPH03143364A (en) | 1991-06-18 |
JP2844537B2 JP2844537B2 (en) | 1999-01-06 |
Family
ID=17624917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1280428A Expired - Lifetime JP2844537B2 (en) | 1989-10-27 | 1989-10-27 | Whipping cream and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2844537B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998037775A3 (en) * | 1997-02-28 | 1998-12-10 | Nestle Sa | Gelled emulsion products containing chitosan |
-
1989
- 1989-10-27 JP JP1280428A patent/JP2844537B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998037775A3 (en) * | 1997-02-28 | 1998-12-10 | Nestle Sa | Gelled emulsion products containing chitosan |
US6238720B1 (en) | 1997-02-28 | 2001-05-29 | Nestec S.A. | Gelled emulsion products containing chitosan |
EP1295532A3 (en) * | 1997-02-28 | 2003-06-18 | Société des Produits Nestlé S.A. | Gelled emulsion products containing chitosan |
Also Published As
Publication number | Publication date |
---|---|
JP2844537B2 (en) | 1999-01-06 |
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