JPH0313992B2 - - Google Patents
Info
- Publication number
- JPH0313992B2 JPH0313992B2 JP57191882A JP19188282A JPH0313992B2 JP H0313992 B2 JPH0313992 B2 JP H0313992B2 JP 57191882 A JP57191882 A JP 57191882A JP 19188282 A JP19188282 A JP 19188282A JP H0313992 B2 JPH0313992 B2 JP H0313992B2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- layer
- wax
- thermal transfer
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002844 melting Methods 0.000 claims description 17
- 230000008018 melting Effects 0.000 claims description 13
- 239000003086 colorant Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000007740 vapor deposition Methods 0.000 claims description 3
- 239000001993 wax Substances 0.000 description 16
- -1 polyethylene Polymers 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 235000012343 cottonseed oil Nutrition 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 235000010187 litholrubine BK Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 210000001685 thyroid gland Anatomy 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
Description
【発明の詳細な説明】
本発明は多色感熱転写リボンに関する。従来、
ベースフイルムに融点の異なる感熱転写インク層
を融点の高い順に設け、且つ、各感熱転写インク
層の間に、融点がそれらの中間にあたるワツクス
層を設けていた。しかし、ワツクスでは剥離効果
は十分ではなく、転写による色も均一でなく、そ
のため塗布量を厚くする必要があつた。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to multicolor thermal transfer ribbons. Conventionally,
Heat-sensitive transfer ink layers having different melting points were provided on the base film in descending order of melting point, and a wax layer having a melting point intermediate between the heat-sensitive transfer ink layers was provided between each heat-sensitive transfer ink layer. However, wax does not have a sufficient peeling effect and the transferred color is not uniform, so it is necessary to apply a thick coating amount.
本発明はこれら従来技術の欠点を改良したもの
であつて、剥離効果が良好で、且つ、下の色を隠
蔽できるのでインクの塗布量を少くし、感度が高
く、且つ、伝熱もよい。 The present invention improves these drawbacks of the prior art, and has a good peeling effect, can hide the underlying color, reduces the amount of ink applied, has high sensitivity, and has good heat transfer.
感熱転写方式は現在、ワードプロセツサー、
TSS端末、発券機に用いられ、今后フアクシミ
リ、金融端末機、電卓、タイプライターなど多く
の用途が考えられ、本発明の多色感熱転写リボン
はこれらの目的に有効に使用し得るものである。 The thermal transfer method is currently used in word processors,
It is used in TSS terminals, ticket issuing machines, and can be used in many other applications such as facsimile machines, financial terminals, calculators, and typewriters, and the multicolor thermal transfer ribbon of the present invention can be effectively used for these purposes.
本発明の多色感熱転写リボンは、ベース上に、
色及び融点の異なる感熱転写インク層を融点の高
い順に設け、且つ各感熱転写インク層の間に金属
蒸着層を設けて成ることを特徴とするものであ
る。 The multicolor thermal transfer ribbon of the present invention has, on the base,
It is characterized in that heat-sensitive transfer ink layers having different colors and melting points are provided in order of increasing melting point, and a metal vapor deposition layer is provided between each heat-sensitive transfer ink layer.
このベースとしては、セロフアン、ポリエステ
ル、ナイロン、コンデンサ紙、グラシンなどを用
いることができる。 As this base, cellophane, polyester, nylon, capacitor paper, glassine, etc. can be used.
感熱転写インク層の材料としては、ワツクス、
着色材から成るものを用いるが、他に、体質顔料
や柔軟剤を必要に応じて加えてもよい。これらの
成分の混合割合は好適には次のごとくである。 Materials for the thermal transfer ink layer include wax,
Although a coloring material is used, extender pigments and softeners may be added as necessary. The mixing ratio of these components is preferably as follows.
ワツクス 30−60重量％
顔 料（着色剤及び体質顔料） 15−40重量％
柔軟剤 10−30重量％
各感熱転写インク層の厚さは、例えば1.0−
3.0μのオーダーである。Wax 30-60% by weight Pigment (colorant and extender) 15-40% by weight Softener 10-30% by weight The thickness of each thermal transfer ink layer is, for example, 1.0-40% by weight.
It is on the order of 3.0μ.
使用するワツクスの例を挙げると次の様であ
る。 Examples of waxes used are as follows.
融点 40℃前后：脂肪酸、例えば、綿実脂肪酸
融点 60℃前后：パラフインワツクス、ポリエチ
レングリコール
融点 80℃前后：モタン、カルナバ、カスターな
どの各ワツクス
融点100℃前后：酸化ポリエチレン、部分ケン化
エステルワツクス
着色剤としては、例えば、次のようなものを用
いることができる。Melting point: Before and after 40℃: Fatty acids, e.g., cottonseed fatty acids Melting point: Before and after 60℃: Paraffin wax, polyethylene glycol Melting point: Before and after 80℃: Various waxes such as Motan, Carnauba, and Castor Melting point: Before and after 100℃: Oxidized polyethylene, partially saponified ester wax As the coloring agent, for example, the following can be used.
黄色系：オイルイエロー、黄鉛
赤色系：カーミン6B、レツドSM
青色系：シニアンブルー、群青、紺青
黒色系：カーボンブラツク、黒酸化鉄、黒鉛
体質顔料としては、例えば、アエロジル、サイ
ロイドなどのホワイトカーボン、クレー、タル
ク、アルミナ、硫酸バリウム、炭酸カルシウム、
炭酸マグネシウムなどを用いることができる。Yellow: oil yellow, yellow lead Red: Carmine 6B, Red SM Blue: senior blue, ultramarine, navy blue Black: carbon black, black iron oxide, graphite Extender pigments include white carbon such as Aerosil and Thyroid. , clay, talc, alumina, barium sulfate, calcium carbonate,
Magnesium carbonate or the like can be used.
柔軟剤としてはオイル、例えば、植物油綿実
油、カストル油、落花生油など）及び鉱油（モー
ターオイル、流動パラフイン、マシン油、タービ
ン油など）や界面活性剤、例えば、ポリエチレン
系界面活性剤を用いることができる。 As softeners, oils such as vegetable oils (cottonseed oil, castor oil, peanut oil, etc.) and mineral oils (motor oil, liquid paraffin, machine oil, turbine oil, etc.) and surfactants such as polyethylene surfactants can be used. .
金属蒸着層材料としてはアルミニウム、銅、
鉛、錫、亜鉛等を用いることがきるが、アルミニ
ウムが好適である。 Metal vapor deposition layer materials include aluminum, copper,
Although lead, tin, zinc, etc. can be used, aluminum is preferred.
金属蒸着層の厚みは通常300〜1000Å、好まし
くは600〜100Åである。 The thickness of the metal vapor deposited layer is usually 300 to 1000 Å, preferably 600 to 100 Å.
感熱転写インク層の塗工は常法で適宜行うこと
ができ、例えば、一般のカーボン印刷機を用いて
塗工することができる。 Coating of the heat-sensitive transfer ink layer can be carried out appropriately by a conventional method, for example, by using a general carbon printing machine.
金属蒸着層を感熱転写インク層上に設けるのに
は常法による金属蒸着方法を用いることができ
る。例えば、真空中で所望の金属を加熱溶融し
て、これを蒸発させ、その周囲に被塗物、即ち、
感熱転写インク層を蒸発源に面して置くと、その
面は蒸発物の金属膜で被覆される。装置として
は、例えば、絶対圧力が10-5〜10-6mmHgまで減
圧できる排気系統、真空室、蒸着金属をその蒸発
温度まで熱する設備、金属蒸着層をつけようとす
る感熱転写インク層を固定保持できる設備を有す
るものを用いることができる。 A conventional metal deposition method can be used to provide the metal deposition layer on the thermal transfer ink layer. For example, a desired metal is heated and melted in a vacuum, evaporated, and the object to be coated is placed around it, i.e.,
When the thermal transfer ink layer is placed facing the evaporation source, its surface is coated with a metal film of the evaporator. The equipment includes, for example, an exhaust system that can reduce the absolute pressure to 10 -5 to 10 -6 mmHg, a vacuum chamber, equipment that heats the deposited metal to its evaporation temperature, and a thermal transfer ink layer to which the metal deposition layer is applied. It is possible to use a device that has equipment that allows it to be fixedly held.
実施例 １
ベースフイルムに6μのポリエチレンフイルム
を用い、下記の組成の青色の熱溶融インクをロー
ルコータにて、130℃で2.0μの厚さになるように
塗工した。Example 1 A 6μ polyethylene film was used as the base film, and a blue hot-melt ink having the following composition was coated with a roll coater at 130°C to a thickness of 2.0μ.
OPワツクス（部分ケン化エステルワツクス）
60重量部
シニアンブルー ５ 〃
炭酸カルシウム 15 〃
鉱 油 30 〃
そして上記塗布面にアルミニウムを厚さ600Å
になるように蒸着させた。OP wax (partially saponified ester wax)
60 parts by weight Shinian Blue 5 Calcium carbonate 15 Mineral oil 30 Then apply aluminum to the above coating surface to a thickness of 600Å.
It was deposited so that
次に、下記の組成の赤色の熱溶融インクをロー
ルコータにて100℃で2.0μの厚さに塗工した。 Next, a red heat-melting ink having the composition shown below was applied to a thickness of 2.0 μm at 100° C. using a roll coater.
酸化ワツクス 30重量部
ポリエチレングリコール 30 〃
カーミン6B 20 〃
ポリエチレン界面活性剤 30 〃
上記塗布面にアルミニウムを600Åになるよう
に蒸着させた。Oxidized wax 30 parts by weight Polyethylene glycol 30 Carmine 6B 20 Polyethylene surfactant 30 Aluminum was deposited on the above coating surface to a thickness of 600 Å.
更に、下記組成の黄色の熱溶融インクをロール
コータで、70℃で、厚さ2.0μになる様に塗工し
た。 Further, a yellow heat-melting ink having the composition shown below was coated using a roll coater at 70°C to a thickness of 2.0 μm.
パラフインワツクス 30重量部
綿実脂肪酸 30 〃
黄 鉛 20 〃
植物油 30 〃
このようにしてつくつた多色感熱転写リボンは
感熱複写機で複写に用いた所、各温度により、そ
れぞれ異つた色の鮮明な記憶が得られた。Parafine wax 30 parts by weight Cottonseed fatty acid 30 〃 Yellow lead 20 〃 Vegetable oil 30 〃 When the multicolored thermal transfer ribbon made in this way is used for copying with a thermal copying machine, it produces vivid colors of different colors depending on the temperature. I got a memory.
しかし、アルミニウムによる蒸着層を設けず
に、融点がそれらの中間にあたるワツクス層をそ
れぞれ設けて作成した多色感熱転写リボンは色が
まじり合い、鮮明な記録が得られなかつた。 However, in the case of a multicolor thermal transfer ribbon produced by providing wax layers with melting points between these layers without providing an aluminum vapor-deposited layer, the colors mixed together and clear recording could not be obtained.
実施例 ２
ベースフイルムに16μの厚さのセロフアンを用
い、下記の組成の黒色の熱溶融インクをロールコ
ータで、130℃で厚さ2.0μになるように塗工した。Example 2 Cellophane with a thickness of 16 μm was used as a base film, and a black heat-melting ink having the following composition was coated with a roll coater at 130° C. to a thickness of 2.0 μm.
カルバナワツクス 30重量部
エステルワツクス 30重量部
カーボンブラツク 20重量部
鉱 油 30重量部
そして、上記塗布面にアルミニウムを厚さ600
Åになる様に蒸着させた。Carvana wax 30 parts by weight Ester wax 30 parts by weight Carbon black 20 parts by weight Mineral oil 30 parts by weight Then, coat the above coated surface with aluminum to a thickness of 600 mm.
It was deposited to give a thickness of Å.
次いで、下記組成の赤色の熱溶融インクをロー
ルコータにて、100℃で2.0μになる様に塗工した。 Next, a red heat-melting ink having the following composition was applied using a roll coater at 100°C to a thickness of 2.0μ.
酸化ワツクス 30重量部
ポリエチレングリコール 30 〃
カーミン6B 20 〃
ポリエチレン系界面活性剤 30 〃
このようにしてつくられた多色感熱転写リボン
は感熱複写機で複写に用いた所、各温度により、
それぞれ異なつた色の鮮明な記録が得られた。Oxidized wax 30 parts by weight Polyethylene glycol 30 〃 Carmine 6B 20 〃 Polyethylene surfactant 30 〃 When the multicolor thermal transfer ribbon thus produced was used for copying with a thermal copying machine, it changed depending on the temperature.
Clear records of different colors were obtained.
しかし、アルミニウムによる蒸着層を設けず
に、融点がそれらの中間に当るワツクス層をそれ
ぞれ設けて作成した多色感熱転写リボンは色がま
じり合い、鮮明な記録が得られなかつた。 However, in the case of a multicolor thermal transfer ribbon prepared by providing wax layers having a melting point between these layers without providing an aluminum vapor-deposited layer, the colors mixed together and clear recording could not be obtained.
Claims (1)
インク層を融点の高い順に設け、且つ各感熱転写
インク層の間に金属蒸着層を設けたことを特徴と
する多色感熱転写リボン。 ２ 特許請求の範囲第１項において、金属蒸着層
がアルミニウム蒸着層であることを特徴とする多
色感熱転写リボン。[Scope of Claims] 1. A multicolor effect characterized by providing heat-sensitive transfer ink layers of different colors and melting points on a base in order of increasing melting point, and providing a metal vapor deposition layer between each heat-sensitive transfer ink layer. Heat transfer ribbon. 2. The multicolor thermal transfer ribbon according to claim 1, wherein the metal vapor-deposited layer is an aluminum vapor-deposited layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57191882A JPS5981185A (en) | 1982-11-02 | 1982-11-02 | Multicolor heat-sensitive transfer ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57191882A JPS5981185A (en) | 1982-11-02 | 1982-11-02 | Multicolor heat-sensitive transfer ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5981185A JPS5981185A (en) | 1984-05-10 |
| JPH0313992B2 true JPH0313992B2 (en) | 1991-02-25 |
Family
ID=16282025
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57191882A Granted JPS5981185A (en) | 1982-11-02 | 1982-11-02 | Multicolor heat-sensitive transfer ribbon |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5981185A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07121601B2 (en) * | 1985-01-31 | 1995-12-25 | 株式会社東芝 | Thermal transfer recorder |
| US5120383A (en) * | 1986-12-29 | 1992-06-09 | Seiko Epson Corporation | Thermal transfer ink sheet and method of printing |
-
1982
- 1982-11-02 JP JP57191882A patent/JPS5981185A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5981185A (en) | 1984-05-10 |
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