JPH03136662A - Deodorant and manufacture thereof - Google Patents

Deodorant and manufacture thereof

Info

Publication number
JPH03136662A
JPH03136662A JP1276369A JP27636989A JPH03136662A JP H03136662 A JPH03136662 A JP H03136662A JP 1276369 A JP1276369 A JP 1276369A JP 27636989 A JP27636989 A JP 27636989A JP H03136662 A JPH03136662 A JP H03136662A
Authority
JP
Japan
Prior art keywords
pulp
deodorizer
pulps
deodorizing
various
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1276369A
Other languages
Japanese (ja)
Inventor
Tatsuji Tauchi
田内 達治
Hirosuke Matsuoka
松岡 宏輔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON KOUDOSHI KOGYO KK
TAKEIZUMI SANGYO KK
Nippon Kodoshi Corp
Original Assignee
NIPPON KOUDOSHI KOGYO KK
TAKEIZUMI SANGYO KK
Nippon Kodoshi Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON KOUDOSHI KOGYO KK, TAKEIZUMI SANGYO KK, Nippon Kodoshi Corp filed Critical NIPPON KOUDOSHI KOGYO KK
Priority to JP1276369A priority Critical patent/JPH03136662A/en
Publication of JPH03136662A publication Critical patent/JPH03136662A/en
Pending legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

PURPOSE:To efficiently remove various malodors by molding various pulps of thick paper form into a determined form after dry distillation. CONSTITUTION:A deodorant is formed by using various pulps of thick paper form and pulp sludge as starting materials, and dry distilling the starting materials. An extremely powerful deodorizer utilizing the deodorizing force possessed by the pulp made porous can be obtained. In the manufacture, the strength and deodorizing force of the fiber itself can be determined by regulating steam pressure in autoclave, temperature, and dry distillation time. The pulps can be selected from craft pulp, Manila help pulp, ditch reed pulp, bamboo pulp, and sisal pulp. For example, various pulps of thick paper form are dry distilled in an autoclave having a steam pressure of 3-6 kg/cm<2> at a temperature of 120-160 deg.C for 30 minutes to 2 hours followed by drying.

Description

【発明の詳細な説明】 の 本発明は脱臭剤及びその製造方法にかかり、特に製紙工
場で使用される厚紙状の各種パルプ及び製紙工場から廃
棄されるパルプスラッジを乾留することにより得られる
脱臭剤とその製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a deodorizing agent and a method for producing the same, and in particular to a deodorizing agent obtained by carbonizing various cardboard-like pulps used in paper mills and pulp sludge discarded from paper mills. and its manufacturing method.

亥1ヱUえ監 一般に人間の生活には多種類の悪臭がつきまとうもので
あって、特に臭覚を強烈に刺激する悪臭、例えば養豚、
養鶏等の畜産農業、し尿やごみ処理等に起因する臭い、
或いは冷蔵庫内の臭い等日常生活における臭いは正常で
快適な市民生活を妨げるものである。更に近年では機械
、プラスチック、化学工場での製造過程で生じる廃棄臭
とか、有機溶剤系の臭気、食品工場とか酒造の過程で発
生する臭気、その他生理的な悪臭等が加わっている現状
にある。
亥1ヱEsupervised Human life in general is accompanied by many kinds of bad odors, and in particular, bad odors that strongly stimulate the sense of smell, such as pig farming,
Odors caused by livestock farming such as poultry farming, human waste, garbage disposal, etc.
Or, odors in daily life, such as the odors in refrigerators, disturb the normal and comfortable life of citizens. Furthermore, in recent years, waste odors generated in the manufacturing process of machinery, plastics, and chemical factories, organic solvent odors, odors generated in food factories and sake brewing processes, and other physiological odors have been added.

一方、これらの悪臭を取り除くための脱臭装置も種々考
えられており、中でも技術的に確立されている方式とし
て■燃焼脱臭方式、■活性炭、ゼオライト等の物理的吸
着剤を用いた方式、■アルカリ溶液その他の薬液を用い
た洗浄脱臭方式、■イオン交換樹脂その他の化学吸着剤
を用いた方式、■土壌脱臭法、活性汚泥等の生物脱臭方
式、■オゾンを利用した方式等が知られており、夫々脱
臭目的に応じて採用されている。
On the other hand, various deodorizing devices have been considered to remove these bad odors, and among them, the technically established methods are ■ combustion deodorization method, ■ method using physical adsorbents such as activated carbon and zeolite, and ■ alkali method. Known methods include cleaning and deodorizing methods using solutions and other chemicals, ■ methods using ion exchange resins and other chemical adsorbents, ■ soil deodorizing methods, biological deodorizing methods such as activated sludge, and ■ methods using ozone. , are adopted depending on the purpose of deodorization.

が  しよ”  る しかしながら、このような従来の各種脱臭方式もしくは
脱臭剤を用いた場合、前記した各種の悪臭を効率的に除
去することは困難であって、単に悪臭の発散を押えて外
部に放散されることを防止するか、もしくは物理的、化
学的吸着剤を用いて悪臭の一部を吸着し、生活上耐え得
る程度まで悪臭の低下をはかっているにすぎない。特に
日常生活には前記各種の悪臭が複合される場合が多いの
で、これらの悪臭に有効に作用する脱臭装置を得ること
は極めて困難である。
However, when using various conventional deodorizing methods or deodorizing agents, it is difficult to efficiently remove the various types of odors mentioned above. The only way to reduce the odor is to prevent it from being emitted, or to adsorb part of the odor using physical or chemical adsorbents, and to reduce the odor to a level that is tolerable in daily life. Since the various types of malodors mentioned above are often combined, it is extremely difficult to obtain a deodorizing device that effectively eliminates these malodors.

また、前記した物理的、化学的吸着剤を用いた場合には
、悪臭除去後の廃材を処理する手段が難しく、処理方法
によっては二次公害を引き起こす惧れがある。
Furthermore, when using the above-mentioned physical or chemical adsorbents, it is difficult to dispose of the waste material after the odor has been removed, and depending on the processing method, there is a risk of causing secondary pollution.

特に将来にわたっての生活環境問題を考慮すると、前記
脱臭剤に用いられる原料としては、物理的、化学的吸着
剤を用いない材料を用いることが公害防止の観点からも
望ましい。
Particularly in consideration of future living environment problems, it is desirable to use materials that do not use physical or chemical adsorbents as raw materials for the deodorizer from the viewpoint of pollution prevention.

そこで本発明はこのような従来の各種の脱臭剤が有して
いる問題点を解消して、各種のパルプ及びパルプスラッ
ジを原料とする脱臭剤及びその製造方法を提供するこ七
を目的とするものである。
Therefore, it is an object of the present invention to solve the problems of various conventional deodorizing agents and to provide a deodorizing agent using various pulps and pulp sludge as raw materials and a method for producing the same. It is something.

る めの 本発明は上記目的を達成するために、厚紙状の各種パル
プ並びにパルプスラッジを乾留して製造した脱臭剤を基
本とするものである。
In order to achieve the above object, the present invention is based on a deodorizing agent produced by carbonizing various pulps in the form of cardboard and pulp sludge.

上記のパルプとしてはクラフトパルプ、マニラ麻パルプ
、葦パルプ、竹パルプ、サイザル麻パルプの中から選択
して利用することができる、また、本発明では厚紙状の
各種パルプを高圧釜内で蒸気圧3〜6kg/Cm2、温
度120〜160℃で30分〜2時間乾留した後、乾燥
して製作する脱臭剤の製造方法と、パルプスラッジを、
含有する有する水分が20%から30%になるまで乾燥
させ、その後高圧釜内で蒸気圧3〜6 kg / cm
2、温度120〜160℃で30分〜2時間乾留した後
、乾燥して製作する脱臭剤の製造方法を提供する。
The above-mentioned pulp can be selected from kraft pulp, manila hemp pulp, reed pulp, bamboo pulp, and sisal pulp. In addition, in the present invention, various pulps in the form of cardboard are heated in a high-pressure cooker at a vapor pressure of 3. A method for producing a deodorizer by drying and drying pulp sludge after carbonization at ~6 kg/Cm2 and a temperature of 120 to 160°C for 30 minutes to 2 hours,
Dry until the moisture content is 20% to 30%, then heat in a high-pressure cooker to a vapor pressure of 3 to 6 kg/cm
2. To provide a method for producing a deodorizing agent, which is produced by drying the deodorizer after drying it at a temperature of 120 to 160° C. for 30 minutes to 2 hours.

生貝 かかる脱臭剤及びその製造方法によれば、各種パルプを
乾留して多孔性を持つ物質に変換したことにより、脱臭
力を持たせることができる。得られた脱臭剤は化学的物
質を原料としていないので、二次公害が発生する惧れか
ない。
According to the raw shellfish deodorizing agent and its manufacturing method, various pulps are carbonized and converted into a porous substance, so that the deodorizing power can be imparted. Since the obtained deodorizer is not made from chemical substances, there is no risk of secondary pollution occurring.

更に製造に際して、高圧釜内の蒸気圧、@度及び乾留時
間によって脱臭剤の強度と脱臭力が決定されるという作
用がある。
Furthermore, during production, the strength and deodorizing power of the deodorizing agent are determined by the steam pressure in the high-pressure cooker, temperature and carbonization time.

Xl1 以下本発明にかかる脱臭剤及びその製造方法の各実施例
を詳述する。
Xl1 Examples of the deodorizing agent and the method for producing the same according to the present invention will be described in detail below.

本発明で用いられる原料は、製紙工場で用いられる各種
パルプ及び製紙工場から廃棄されるパルプスラッジであ
り、上記パルプとしてはクラフトパルプ、マニラ麻パル
プ、葦パルプ、竹パルプ。
The raw materials used in the present invention are various pulps used in paper mills and pulp sludge discarded from paper mills, and the pulps include kraft pulp, Manila hemp pulp, reed pulp, and bamboo pulp.

サイザル麻パルプが利用可能である。Sisal pulp is available.

本発明ではこれらの各種パルプの中から選択して利用す
ることができる。
In the present invention, it is possible to select and use these various pulps.

これらのパルプを脱臭剤として使用するに際し、該パル
プを乾留することによって多孔性を持たせたことが特徴
となっている。
When these pulps are used as deodorizing agents, they are characterized by being made porous by carbonizing the pulps.

即ち、これらのパルプを高圧釜内で蒸気圧3〜6kg/
cm2、温度120〜160°Cで30分〜2時間乾留
した後、乾燥して脱臭剤とする。
That is, these pulps are heated in a high-pressure cooker at a steam pressure of 3 to 6 kg/
cm2, and carbonized at a temperature of 120 to 160°C for 30 minutes to 2 hours, and then dried to obtain a deodorizing agent.

上記の乾留処理とは、空気を遮断した状態でパルプを強
く加熱することによって熱分解を行わせる手段であって
、パルプ自体の多孔性が高められ、脱臭剤としての機能
が付与される。
The above-mentioned carbonization treatment is a means of thermally decomposing the pulp by strongly heating it in a state where air is shut off, thereby increasing the porosity of the pulp itself and imparting a function as a deodorizing agent.

また、前記高圧釜内の蒸気圧及び温度が低く、かつ、乾
留時間が短いほどパルプ自体は強靭であり、前記蒸気圧
及び温度が高く、かつ、乾留時間が長いほど脱臭力が高
まる反面でパルプ自体の強度が低下するので、利用目的
に応じてこれらの条件を決定すれば良い。
In addition, the lower the vapor pressure and temperature in the high-pressure cooker and the shorter the carbonization time, the stronger the pulp itself.The higher the vapor pressure and temperature and the longer the carbonization time, the stronger the deodorizing power, Since the strength of the material itself decreases, these conditions should be determined depending on the purpose of use.

得られた脱臭剤は厚紙状を呈しているので、用途に応じ
て適当な大きさ及び形状にカットして、例えば果物とか
野菜類を出荷する際のダンボール箱の中に入れるとか、
梱包内に封入する等の使用形態が可能である。
The obtained deodorizer has a cardboard-like shape, so it can be cut into an appropriate size and shape depending on the purpose and placed in a cardboard box for shipping fruits and vegetables, for example.
It is possible to use it in a manner such as enclosing it in a package.

一方、工場廃棄物であるパルプスラッジを乾留したもの
はそのままでも使用することができるが、更に小さく粉
砕して形状を揃えるとか、ペレット状、フィルター状も
しくは適宜な形状に成形することによって脱臭剤として
の利用の道が拡大する。
On the other hand, pulp sludge, which is a factory waste product, can be used as it is, but it can be used as a deodorizing agent by grinding it into smaller pieces and making it into a uniform shape, or by molding it into pellets, filters, or other suitable shapes. The ways in which it can be used will expand.

特にフィルター状に成形することによって、バキューム
カーの排気用フィルターとか、更には工場。
In particular, by molding it into a filter shape, it can be used for vacuum car exhaust filters, and even factories.

し尿処理場等の排気装置等に利用することができる。It can be used as an exhaust system for human waste treatment plants, etc.

上記パルプスラッジは本来産業廃棄物として処理に苦慮
していたものであって、そのまま廃棄すると公害源とな
ってしまうため、製紙工場等において専門の処理業者に
委託している現状にあり、このような産業廃棄物を脱臭
剤として利用可能とした意義が大きいものと考えられる
The above-mentioned pulp sludge was originally difficult to dispose of as industrial waste, and if disposed of as is, it would become a source of pollution. It is considered to be of great significance that industrial waste can be used as a deodorizing agent.

次に上記の乾留条件を種々変えた本発明にかかる脱臭剤
の各種実施例と既存の脱臭剤である比較例との脱臭力を
測定した結果を示す。
Next, the results of measuring the deodorizing power of various examples of the deodorizing agent according to the present invention and a comparative example of an existing deodorizing agent in which the above-mentioned carbonization conditions were variously changed are shown.

(測定方法) 各実施例及び比較例を1812のデシケータに試薬特級
アンモニア水の10倍希釈液0.4mQとともに密閉し
た後、乾燥器内で105℃、13分間放置し、アンモニ
ア氷を完全に蒸発させ、乾燥器から取り出した後、15
分、25分、35分。
(Measurement method) Each example and comparative example was sealed in a 1812 desiccator with 0.4 mQ of a 10-fold diluted reagent grade ammonia water, and then left in a dryer at 105°C for 13 minutes to completely evaporate the ammonia ice. 15 minutes after removing from the dryer.
Minutes, 25 minutes, 35 minutes.

50分経過した後の残存するアンモニアの濃度を検知管
法によって測定した結果を示す。
The results of measuring the concentration of remaining ammonia after 50 minutes by the detection tube method are shown.

尚、ブランクテストによるアンモニア濃度は510pp
mであった。
In addition, the ammonia concentration in the blank test was 510pp.
It was m.

(実施例1) 実施例1はクラフトパルプ100gを原料として、この
原料を蒸気圧5〜6kg/ cm2. 160℃で2時
間乾留した後、乾燥して脱臭剤とした。
(Example 1) In Example 1, 100 g of kraft pulp was used as a raw material, and this raw material was heated to a vapor pressure of 5 to 6 kg/cm2. After carbonizing at 160° C. for 2 hours, it was dried to obtain a deodorizing agent.

(実施例2) 実施例2はマニラ麻100gを原料として、実施例1と
同一の条件で乾留した後、乾燥して脱臭剤とした。
(Example 2) In Example 2, 100 g of Manila hemp was carbonized under the same conditions as in Example 1, and then dried to obtain a deodorizing agent.

(実施例3) 実施例3は葦パルプ100gを原料として実施例1と同
一の条件で乾留した後、乾燥して脱臭剤とした。
(Example 3) In Example 3, 100 g of reed pulp was carbonized under the same conditions as Example 1 using 100 g of reed pulp as a raw material, and then dried to obtain a deodorizing agent.

(実施例4) 実施例4はパルプスラッジを原料として、この原料を水
分含有量が20〜30%になるまで乾燥させ、その後蒸
気圧5〜6kg/cm2,160℃で2時間乾留した後
、乾燥して脱臭剤とした。
(Example 4) In Example 4, pulp sludge was used as a raw material. This raw material was dried until the moisture content became 20 to 30%, and then carbonized at a vapor pressure of 5 to 6 kg/cm2 at 160°C for 2 hours. It was dried and used as a deodorizer.

(比較例1.2) 活性炭を主体とする市販の冷蔵庫用脱臭剤を使用した。(Comparative example 1.2) A commercially available refrigerator deodorizer containing activated carbon as a main ingredient was used.

即ち上記表1の測定結果に示すとおり、従来の脱臭剤に
対して1本発明にかかる脱臭剤の脱臭能力が極めて高い
ことが理解される。
That is, as shown in the measurement results in Table 1 above, it is understood that the deodorizing ability of the deodorizing agent according to the present invention is extremely high compared to conventional deodorizing agents.

又里五漿求 以上詳細に説明したように、本発明にかかる脱臭剤及び
その製造方法によれば、厚紙状の各種パルプ並びにパル
プスラッジを原料として利用して、この原料を乾留して
成る脱臭剤及びその製造方法を提供するものであり、多
孔質となったパルプの持つ脱臭力を利用した極めて強力
な脱臭剤を得ることができる。また、製造に際して高圧
釜内の蒸気圧、温度及び乾留時間を調整することによっ
て繊維自体の強度と脱臭力が決定されるという効果があ
る。
As explained in detail above, according to the deodorizing agent and the method for producing the same according to the present invention, various types of cardboard-like pulp and pulp sludge are used as raw materials, and the deodorizing agent is produced by carbonizing these raw materials. The present invention provides an extremely strong deodorizing agent that utilizes the deodorizing power of porous pulp. Furthermore, the strength and deodorizing power of the fibers themselves are determined by adjusting the steam pressure, temperature, and carbonization time in the high-pressure cooker during production.

特に一般の日常生活には各種の悪臭が複合される場合が
多く、本脱臭剤はこれらの悪臭に対しても有効である。
In particular, in general daily life, various types of bad odors are often compounded, and the present deodorizer is effective against these bad odors as well.

更に従来の物理的、化学的吸着剤を用いた脱臭剤では、
廃材を処理する手段が難しく、かつ、処理方法によって
は二次公害を引き起こす惧れがあるが、本発明にかかる
脱臭剤は原料が自然界に存在する多孔質の植物であるた
め、公害防止の観点からも望ましいという利点を有して
いる。
Furthermore, with conventional deodorizers that use physical or chemical adsorbents,
It is difficult to dispose of waste materials, and there is a risk of secondary pollution depending on the processing method, but since the deodorizer of the present invention is made from porous plants that exist in nature, it is effective from the perspective of preventing pollution. It has the advantage of being highly desirable.

Claims (1)

【特許請求の範囲】 (1)厚紙状の各種パルプを乾留した後、所定の形状に
成形して成る脱臭剤。 (2)前記パルプがクラフトパルプ、マニラ麻パルプ、
葦パルプ、竹パルプ、サイザル麻パルプの中から選択さ
れた1種もしくは2種以上の複合品である請求項1記載
の脱臭剤。(3)製紙工場から廃棄されるパルプスラッ
ジを乾燥させて乾留した後、所定の形状に成形して成る
脱臭剤。 (4)厚紙状の各種パルプを高圧釜内で蒸気圧3〜6k
g/cm^2、温度120〜160℃で30分〜2時間
乾留した後、乾燥して製作することを特徴とする脱臭剤
の製造方法。 (5)前記パルプがクラフトパルプ、マニラ麻パルプ、
葦パルプ、竹パルプ、サイザル麻パルプである請求項4
記載の脱臭剤の製造方法。 (6)製紙工場から廃棄されるパルプスラッジを含有す
る水分が20%から30%になるまで乾燥させ、その後
高圧釜内で蒸気圧3〜6kg/cm^2、温度120〜
160℃で30分〜2時間乾留した後、乾燥して製作す
ることを特徴とする脱臭剤の製造方法。
[Scope of Claims] (1) A deodorizer made by carbonizing various cardboard-like pulps and then molding them into a predetermined shape. (2) the pulp is kraft pulp, Manila hemp pulp,
The deodorizer according to claim 1, which is a composite product of one or more selected from reed pulp, bamboo pulp, and sisal pulp. (3) A deodorizer made by drying and carbonizing pulp sludge discarded from a paper mill and then molding it into a predetermined shape. (4) Various types of pulp in the form of cardboard are heated to a steam pressure of 3 to 6 k in a high-pressure pot.
g/cm^2 and a temperature of 120 to 160°C for 30 minutes to 2 hours, followed by drying. (5) The pulp is kraft pulp, Manila hemp pulp,
Claim 4: Reed pulp, bamboo pulp, sisal pulp
A method for producing the deodorizing agent described. (6) Pulp sludge discarded from paper mills is dried until the moisture content is reduced from 20% to 30%, and then heated in a high-pressure cooker at a steam pressure of 3 to 6 kg/cm^2 and a temperature of 120 to 30%.
A method for producing a deodorizer, which comprises carbonizing the deodorizer at 160°C for 30 minutes to 2 hours and then drying it.
JP1276369A 1989-10-24 1989-10-24 Deodorant and manufacture thereof Pending JPH03136662A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1276369A JPH03136662A (en) 1989-10-24 1989-10-24 Deodorant and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1276369A JPH03136662A (en) 1989-10-24 1989-10-24 Deodorant and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH03136662A true JPH03136662A (en) 1991-06-11

Family

ID=17568473

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1276369A Pending JPH03136662A (en) 1989-10-24 1989-10-24 Deodorant and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH03136662A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06296667A (en) * 1993-04-14 1994-10-25 Tomoegawa Paper Co Ltd Deodorant pellet and its production
JP3034641U (en) * 1996-06-25 1997-02-25 日本エスコ株式会社 Packaging containers
CN103866601A (en) * 2014-03-19 2014-06-18 苏州吉臣日用品有限公司 Mixed pulp compound papermaking pulp substrate as well as preparation method and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06296667A (en) * 1993-04-14 1994-10-25 Tomoegawa Paper Co Ltd Deodorant pellet and its production
JP3034641U (en) * 1996-06-25 1997-02-25 日本エスコ株式会社 Packaging containers
CN103866601A (en) * 2014-03-19 2014-06-18 苏州吉臣日用品有限公司 Mixed pulp compound papermaking pulp substrate as well as preparation method and application thereof
CN103866601B (en) * 2014-03-19 2016-05-18 苏州吉臣日用品有限公司 Compound pulp substrate, the preparation method and its usage of manufacturing paper with pulp of mixed slurry

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