JPH03131533A - Production of ruthenium nitrate solution - Google Patents
Production of ruthenium nitrate solutionInfo
- Publication number
- JPH03131533A JPH03131533A JP26791089A JP26791089A JPH03131533A JP H03131533 A JPH03131533 A JP H03131533A JP 26791089 A JP26791089 A JP 26791089A JP 26791089 A JP26791089 A JP 26791089A JP H03131533 A JPH03131533 A JP H03131533A
- Authority
- JP
- Japan
- Prior art keywords
- ruthenium
- solution
- hydroxide
- nitrate solution
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GTCKPGDAPXUISX-UHFFFAOYSA-N ruthenium(3+);trinitrate Chemical compound [Ru+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GTCKPGDAPXUISX-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- VDRDGQXTSLSKKY-UHFFFAOYSA-K ruthenium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ru+3] VDRDGQXTSLSKKY-UHFFFAOYSA-K 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 15
- 239000000460 chlorine Substances 0.000 claims abstract description 14
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 5
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 4
- -1 silver ions Chemical class 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 12
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 6
- 229910001923 silver oxide Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 9
- 239000003054 catalyst Substances 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 150000003304 ruthenium compounds Chemical class 0.000 abstract description 4
- 230000001376 precipitating effect Effects 0.000 abstract description 3
- 238000010908 decantation Methods 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 229910019891 RuCl3 Inorganic materials 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 13
- 229910021607 Silver chloride Inorganic materials 0.000 description 9
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- 229910052707 ruthenium Inorganic materials 0.000 description 7
- 239000006228 supernatant Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000004848 nephelometry Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ルテニウムの持つ特性を利用した触媒の原料
、あるいはルテニウム化合物の合成のための出発原料と
なる硝酸ルテニウム溶液の製造方法に関するものである
。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a method for producing a ruthenium nitrate solution that is a raw material for a catalyst or a starting material for the synthesis of a ruthenium compound using the properties of ruthenium. be.
（従来技術とその問題点）
従来ルテニウムの持つ特性を利用した触媒の原料、ある
いはルテニウム化合物の合成のための出発原料とては塩
化ルテニウムや塩化ルテニウム酸塩を用いていた。(Prior art and its problems) Conventionally, ruthenium chloride and ruthenate chloride have been used as raw materials for catalysts that utilize the properties of ruthenium, or as starting materials for the synthesis of ruthenium compounds.
しかし、最近の技術開発に伴い塩素イオンを含有するこ
とが触媒性能の障害となることや各種のルテニウム化合
物を合成する際の出発原料として硝酸ルテニウム溶液が
強く要望されていたが、該硝酸ルテニウム溶液の製造方
法がなくその開発が待たれていた。However, with recent technological developments, the inclusion of chlorine ions impedes catalyst performance, and a ruthenium nitrate solution has been strongly desired as a starting material for synthesizing various ruthenium compounds. There was no manufacturing method for this, so its development was awaited.
（発明の目的）
本発明は、上記の課題を解決するために成されたもので
、強く要望されている塩素イオンの含有量の少ない硝酸
ルテニウム溶液の製造方法を提供するものである。(Objective of the Invention) The present invention was accomplished in order to solve the above-mentioned problems, and provides a highly desired method for producing a ruthenium nitrate solution with a low content of chlorine ions.
（問題点を解決するための手段）
本発明は、硝酸ルテニウム溶液を製造する方法において
、塩化ルテニウム溶液にアンモニアを加えて中和し水酸
化ルテニウムを生成させ、次いで該水酸化ルテニウムを
傾斜法により分離して洗浄し、水酸化ルテニウムに硝酸
を加えて湯浴中で加熱溶解し、冷却した後、該溶液中の
塩素イオン濃度を測定し、該塩素イオン量に当量の銀イ
オンを加えて攪拌して静置し、濾過分離することを特徴
とする硝酸ルテニウム溶液の製造方法で、前記銀イオン
として加える化合物が硝酸銀または酸化銀であることを
特徴とする硝酸ルテニウム溶液の製造方法である。(Means for Solving the Problems) The present invention provides a method for producing a ruthenium nitrate solution, in which ammonia is added to a ruthenium chloride solution to neutralize it to produce ruthenium hydroxide, and then the ruthenium hydroxide is processed by a decanting method. Separate and wash, add nitric acid to ruthenium hydroxide, heat and dissolve in a hot water bath, cool, measure the chlorine ion concentration in the solution, add an equivalent amount of silver ions to the amount of chlorine ions, and stir. The method of producing a ruthenium nitrate solution is characterized in that the compound added as the silver ion is silver nitrate or silver oxide.
以下、本発明の製造方法について詳細に説明する。Hereinafter, the manufacturing method of the present invention will be explained in detail.
塩化ルテニウム溶液にアンモニア水を加えて中和し水酸
化ルテニウムを生成し、濾過分離して水酸化ルテニウム
を水で十分に洗浄する。Aqueous ammonia is added to the ruthenium chloride solution to neutralize it to produce ruthenium hydroxide, which is separated by filtration and the ruthenium hydroxide is thoroughly washed with water.
塩化ルテニウム溶液の濃度は５〜１００ｇ／Ｉ２であれ
ば良く、水酸化ルテニウムを生成させるのに、アンモニ
ア水を用いるのは他のアルカリ塩、例えば水酸化ナトリ
ウムや水酸化カリウムの水溶液を用いるとナトリウムや
カリウムのイオンが混入して分離が困難となるためで、
アンモニア水であれば加熱分離ができるためである。The concentration of the ruthenium chloride solution should be 5 to 100 g/I2, and to generate ruthenium hydroxide, aqueous ammonia is not suitable for other alkali salts, such as sodium hydroxide or potassium hydroxide. This is because ions such as potassium and potassium ions are mixed in, making separation difficult.
This is because ammonia water can be separated by heating.
また、生成させた水酸化ルテニウムの濾過分離、洗浄の
方法としては傾斜法により行うのが該水酸化ルテニウム
の洗浄に適し、洗浄は先ず、希アンモニア水（０，１％
程度）で２〜３回行い、次いで、純水で２〜３回洗浄す
ると塩素イオンの洗浄に効果があるものである。In addition, as a method for filtering, separating and washing the generated ruthenium hydroxide, a gradient method is suitable for washing the ruthenium hydroxide.
It is effective to wash chlorine ions by washing with pure water 2 to 3 times and then washing with pure water 2 to 3 times.
次いで、該水酸化ルテニウムに硝酸を加えて加熱溶解し
、冷却したのち該溶液中の塩素イオンを測定し、塩素イ
オン量を算出してその当量の銀イオンを加えて塩化銀を
生成させ一夜間室温で静置させたのち、塩化銀の沈澱と
硝酸に未溶解物を濾過分離して硝酸ルテニウム溶液を得
ることができる。Next, nitric acid was added to the ruthenium hydroxide and dissolved by heating, and after cooling, the chlorine ions in the solution were measured, the amount of chlorine ions was calculated, and the equivalent amount of silver ions was added to produce silver chloride, which was then dissolved overnight. After standing at room temperature, silver chloride precipitates and substances not dissolved in nitric acid are separated by filtration to obtain a ruthenium nitrate solution.
上記で用いる硝酸の濃度は特に限定されないが溶解速度
から６規定以上のものが良く、加熱溶解の方法としては
湯浴中で行うのが良い。The concentration of the nitric acid used above is not particularly limited, but it is preferably 6N or more in view of the dissolution rate, and the dissolution by heating is preferably carried out in a hot water bath.
その理由は、硝酸ルテニウムの収率を高めるためで、加
熱温度が高すぎると酸化物が生成しやすくなるからであ
る。The reason for this is to increase the yield of ruthenium nitrate, and if the heating temperature is too high, oxides are likely to be produced.
また、塩素イオンを測定するのは水酸化ルテニウムを洗
浄した際のバラツキが生ずるためと、該塩素イオンを除
くために加える銀イオンが過剰となることをさけるため
であり、測定方法は銀イオンによる比濁法でよい。In addition, the reason for measuring chlorine ions is to avoid variations that occur when ruthenium hydroxide is washed, and to avoid excessive silver ions being added to remove the chlorine ions.The measurement method is based on silver ions. Nephelometry is sufficient.
加える銀イオンはＯ０ｌ規定前後の硝酸銀溶液を用いる
と良く、他に酸化銀を加えても硝酸銀と同様の結果を得
ることができるものである。It is preferable to use a silver nitrate solution with a concentration of around O0l as the silver ions to be added, and even if silver oxide is added, the same results as with silver nitrate can be obtained.
なお、−夜間静置させるのは塩化銀の沈澱を熟成させる
効果があり濾過分離しやすくするためである。The reason why the silver chloride is allowed to stand overnight is that it has the effect of ripening the silver chloride precipitate and makes it easier to separate it by filtration.
塩化銀の沈澱と硝酸に未溶解物を濾過分離する方法は特
に限定するものではないが、パルプノ々ウダや活性炭粉
末を加えて濾過分離することは微量の塩化銀の沈澱と硝
酸に未溶解物を濾過分離するのに効果的であることは言
うまでもない。The method of filtering and separating silver chloride precipitates and undissolved substances in nitric acid is not particularly limited, but adding pulp powder or activated carbon powder and separating by filtration is a method that can remove a trace amount of silver chloride precipitates and undissolved substances in nitric acid. Needless to say, it is effective for filtering and separating.
以下、本発明に係わる実施例を記載するが、該実施例は
本発明を限定するものではない。Examples related to the present invention will be described below, but the examples are not intended to limit the present invention.
（実施例１）
塩化ルテニウム溶液（Ｒｕとして２０ｇ／１）１１を攪
拌しながら１４％アンモニア水を加えてＰＨ７まで中和
して水酸化ルテニウムを生成させる。(Example 1) While stirring a ruthenium chloride solution (20 g/1 as Ru) 11, 14% ammonia water is added to neutralize the solution to pH 7 to produce ruthenium hydroxide.
次いで、静置して水酸化ルテニウムを沈降させ上澄み液
を傾斜法により分離し、０．１％アンモニア水を１００
０ｍ１ｌ’加えて攪拌して静置し、水酸化ルテニウムを
沈降させ上澄み液を傾斜法で分離する操作を３回行った
後、純水をｉ ｏ ｏ ｏｒｎｌ加えて攪拌して静置し
、水酸化ルテニウムを沈降させ上澄み液を傾斜法で分離
する操作を３回行った後、６２％硝酸３００ｍｌを加え
て１００℃の湯浴中で攪拌下で８時間加熱溶解し、次い
で冷却したのち該溶液中の塩素イオン濃度を測定したと
ころ８０ｍ ｇ ／ １２で塩素イオン量を液量から算
出し、当量の０． １規定の硝酸銀溶液を加え攪拌して
一夜間室温で静置したのち、塩化銀の沈澱と硝酸に未溶
解物をメンブランフィルタを用いて濾過分離して硝酸ル
テニウム溶液２５０ｒｎｌを得た。Next, the ruthenium hydroxide was allowed to settle, and the supernatant liquid was separated by a decanting method.
Add 0 ml of pure water, stir and let stand, precipitate the ruthenium hydroxide, and separate the supernatant liquid by decanting method three times, then add io o ornl of pure water, stir and let stand, After precipitating the ruthenium oxide and separating the supernatant liquid by decanting method three times, 300 ml of 62% nitric acid was added and dissolved by heating in a 100°C water bath with stirring for 8 hours, then after cooling, the solution was dissolved. When the chlorine ion concentration in the liquid was measured, it was 80 mg/12.The chlorine ion amount was calculated from the liquid volume, and the equivalent amount was 0. A 1N silver nitrate solution was added, stirred, and allowed to stand overnight at room temperature. Silver chloride precipitates and substances undissolved in nitric acid were separated by filtration using a membrane filter to obtain 250 rnl of a ruthenium nitrate solution.
該硝「１ｉルテニウム溶液中のルテニウムの濃度を化学
分析したところ７０ ｇ／Ａで、塩素イオンは２０ｍｇ
／ｆｆであった。Chemical analysis of the concentration of ruthenium in the 1I ruthenium solution showed that it was 70 g/A, and the chloride ion was 20 mg.
/ff.
（実施例２）
塩化ルテニウム溶液（Ｒｕとして２０ｇ／ｊ７）１βを
攪拌しながら１４％アンモニア水を加えてＰＨ７まで中
和して水酸化ルテニウムを生成させる。(Example 2) While stirring a ruthenium chloride solution (20 g/j7 as Ru) 1β, 14% ammonia water is added to neutralize the solution to pH 7 to produce ruthenium hydroxide.
次いで、静置して水酸化ルテニウムを沈降させ上澄み液
を傾斜法により分離し、０．１％アンモニア水を１００
０ｄ加えて攪拌して静置し、水酸化ルテニウムを沈降さ
せ」−澄み液を傾斜法で分離する操作を３回行った後、
純水を１０００ｍｌ加えて攪拌して静置し、水酸化ルテ
ニウムを沈降させ上澄み液を傾斜法で分離する操作を４
回行った後、６２％硝酸３００ｍｌを加えて１００°Ｃ
の湯浴中で攪拌下で８時間加熱溶解し、次いで冷却した
のち該溶液中の塩素イオン濃度を測定したところ６０ｍ
ｇ ／ ｌ！で塩素イオン量を液量から算出し、当量
の酸化銀を加え攪拌して一夜間室温で静置したのち、パ
ルプパウダを３ｇ加え攪拌したのち、塩化銀の沈澱と硝
酸に未溶解物をグラスフィルタを用いて濾過分離して硝
酸ルテニウム溶液２５０Ｊを得た。Next, the ruthenium hydroxide was allowed to settle, and the supernatant liquid was separated by a decanting method.
0d, stirred and allowed to stand still to precipitate the ruthenium hydroxide.'' After performing the operation of separating the clear liquid by decanting method three times,
Add 1000 ml of pure water, stir and let stand, precipitate the ruthenium hydroxide, and separate the supernatant liquid using the decanting method.
After several times, add 300ml of 62% nitric acid and heat to 100°C.
The concentration of chlorine ions in the solution was measured after heating and dissolving in a hot water bath for 8 hours with stirring, and after cooling, it was found to be 60 m
g/l! Calculate the amount of chlorine ions from the liquid volume, add an equivalent amount of silver oxide, stir, and let stand at room temperature overnight. Add 3 g of pulp powder and stir. Precipitate silver chloride and remove the undissolved matter in nitric acid through a glass filter. The ruthenium nitrate solution was separated by filtration to obtain 250 J of a ruthenium nitrate solution.
該硝酸ルテニウム溶液中のルテニウムの濃度を化学分析
したところ７０ｇ／ｌで、塩素イオンは２０ｍｇ／ｌで
あった。Chemical analysis of the concentration of ruthenium in the ruthenium nitrate solution revealed that it was 70 g/l, and the concentration of chloride ions was 20 mg/l.
なお、実施例２のパルプパウダのかわりに活性炭粉末を
用いたところ同様の結果が得られた。Note that when activated carbon powder was used in place of the pulp powder in Example 2, similar results were obtained.
（実施例３）
塩化ルテニウム溶液（Ｒｕとして２０ｇ／Ｅ）１１を攪
拌しながら１４％アンモニア水を加えてＰＨ７まで中和
して水酸化ルテニウムを生成させる。(Example 3) While stirring a ruthenium chloride solution (20 g/E as Ru) 11, 14% ammonia water is added to neutralize the solution to pH 7 to produce ruthenium hydroxide.
次いで、静置して水酸化ルテニウムを沈降させに澄み液
を傾斜法により分離し、０．１％アンモニア水を１００
ＯＪ加えて攪拌して静置し、水酸化ルテニウムを沈降さ
せ」二澄み液を傾斜法で分離する操作を３回行った後、
純水をｌ ＯＯ０１ｎｌ加えて攪拌して静置し、水酸化
ルテニウムを沈降させ上澄み液を傾斜法で分離する操作
を３回行った後、６２％硝酸３００ｄを加えて１００°
Ｃの湯浴中で攪拌下で８時間加熱溶解し、次いで純水を
３００ｄ加えて冷却したのち該溶液中の塩素イオン濃度
を測定したところ５０ｍｇ／ｆｆで塩素イオン量を液量
から算出し、当量の０．１規定の硝酸銀溶液を加え攪拌
して一夜間室温で静置したのち、塩化銀の沈澱と硝酸に
未溶解物をメンブランフィルタを用いて濾過分離し、濾
過した溶液を１００°Ｃ湯浴中で加熱濃縮して硝酸ルテ
ニウム溶液２５０ｍ７！を得た。Next, the clear liquid was separated by a decanting method to allow the ruthenium hydroxide to settle, and 100% of 0.1% ammonia water was added.
After adding OJ and stirring and allowing to stand still to precipitate the ruthenium hydroxide, the liquid was separated using a decanting method three times.
After adding 1 001 nl of pure water, stirring and standing, precipitating the ruthenium hydroxide and separating the supernatant liquid by decanting method three times, add 300 d of 62% nitric acid and boil at 100°.
The solution was heated and dissolved in a hot water bath of C for 8 hours with stirring, and then 300 d of pure water was added and cooled. The chlorine ion concentration in the solution was measured at 50 mg/ff, and the amount of chlorine ions was calculated from the liquid volume. An equivalent amount of 0.1N silver nitrate solution was added, stirred, and allowed to stand overnight at room temperature. Silver chloride precipitates and substances undissolved in nitric acid were separated by filtration using a membrane filter, and the filtered solution was heated at 100°C. Heat and concentrate in a hot water bath to make 250m7 of ruthenium nitrate solution! I got it.
該硝酸ルテニウム溶液中のルテニウムの濃度を化学分析
したところ７０ ｇ／ｌで、塩素イオンは１０ｍｇ／Ａ
であった。Chemical analysis of the concentration of ruthenium in the ruthenium nitrate solution revealed that it was 70 g/l, and the chlorine ion was 10 mg/A.
Met.
（発明の効果）
以上のように本発明の製造方法により塩素イオンの少な
い硝酸ルテニウム溶液を製造することが可能となり、ル
テニウムの持つ特性を利用した触媒などへの開発がさら
に広まることが期待され技術発展に大いに貢献するもの
である。(Effects of the Invention) As described above, the production method of the present invention makes it possible to produce a ruthenium nitrate solution containing few chlorine ions, and it is expected that the development of catalysts that utilize the properties of ruthenium will further spread. This will greatly contribute to development.
Claims (2)
化ルテニウム溶液にアンモニアを加えて中和し水酸化ル
テニウムを生成させ、次いで該水酸化ルテニウムを傾斜
法により分離して洗浄し、水酸化ルテニウムに硝酸を加
えて湯浴中で加熱溶解し、冷却した後、該溶液中の塩素
イオン濃度を測定し、該塩素イオン量に当量の銀イオン
を加えて攪拌して静置し、濾過分離することを特徴とす
る硝酸ルテニウム溶液の製造方法。(1) In the method of producing a ruthenium nitrate solution, ammonia is added to a ruthenium chloride solution to neutralize it to produce ruthenium hydroxide, and then the ruthenium hydroxide is separated and washed by a decanting method, and the ruthenium hydroxide is added with nitric acid. After heating and dissolving in a hot water bath and cooling, measure the chlorine ion concentration in the solution, add an equivalent amount of silver ions to the amount of chlorine ions, stir, let stand, and separate by filtration. Characteristic method for producing ruthenium nitrate solution.
酸化銀であることを特徴とする請求項１に記載の硝酸ル
テニウム溶液の製造方法。(2) The method for producing a ruthenium nitrate solution according to claim 1, wherein the compound added as the silver ion is silver nitrate or silver oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26791089A JP2774329B2 (en) | 1989-10-14 | 1989-10-14 | Method for producing ruthenium nitrate solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26791089A JP2774329B2 (en) | 1989-10-14 | 1989-10-14 | Method for producing ruthenium nitrate solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03131533A true JPH03131533A (en) | 1991-06-05 |
| JP2774329B2 JP2774329B2 (en) | 1998-07-09 |
Family
ID=17451320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26791089A Expired - Lifetime JP2774329B2 (en) | 1989-10-14 | 1989-10-14 | Method for producing ruthenium nitrate solution |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2774329B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0698586A1 (en) | 1994-07-29 | 1996-02-28 | BASF Aktiengesellschaft | Inorganic building materials containing modifying polymer and additional polyether derivatives |
| US5906469A (en) * | 1995-11-22 | 1999-05-25 | Dainippon Screen Mfg. Co., Ltd. | Apparatus and method for detecting and conveying substrates in cassette |
| WO2011004006A2 (en) | 2009-07-10 | 2011-01-13 | Basf Se | Microcapsules having polyvinyl monomers as cross-linking agents |
| US8449981B2 (en) | 2006-12-13 | 2013-05-28 | Basf Se | Microcapsules |
| CN109574097A (en) * | 2019-02-01 | 2019-04-05 | 江苏欣诺科催化剂有限公司 | The preparation method of six ammino ruthenium of trichlorine |
| CN114378298A (en) * | 2021-12-21 | 2022-04-22 | 上海铂生金属材料有限公司 | Preparation method of superfine platinum powder |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107619938B (en) * | 2017-10-11 | 2019-02-19 | 昆明理工大学 | A method of silver-colored ruthenium being purified in ruthenium compound tail washings from preparing |
-
1989
- 1989-10-14 JP JP26791089A patent/JP2774329B2/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0698586A1 (en) | 1994-07-29 | 1996-02-28 | BASF Aktiengesellschaft | Inorganic building materials containing modifying polymer and additional polyether derivatives |
| US5906469A (en) * | 1995-11-22 | 1999-05-25 | Dainippon Screen Mfg. Co., Ltd. | Apparatus and method for detecting and conveying substrates in cassette |
| US8449981B2 (en) | 2006-12-13 | 2013-05-28 | Basf Se | Microcapsules |
| US9217080B2 (en) | 2006-12-13 | 2015-12-22 | Basf Se | Microcapsules |
| WO2011004006A2 (en) | 2009-07-10 | 2011-01-13 | Basf Se | Microcapsules having polyvinyl monomers as cross-linking agents |
| CN109574097A (en) * | 2019-02-01 | 2019-04-05 | 江苏欣诺科催化剂有限公司 | The preparation method of six ammino ruthenium of trichlorine |
| CN109574097B (en) * | 2019-02-01 | 2021-11-16 | 江苏欣诺科催化剂有限公司 | Preparation method of trichloro-hexa-amino ruthenium |
| CN114378298A (en) * | 2021-12-21 | 2022-04-22 | 上海铂生金属材料有限公司 | Preparation method of superfine platinum powder |
| CN114378298B (en) * | 2021-12-21 | 2024-04-02 | 上海铂生金属材料有限公司 | Preparation method of superfine platinum powder |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2774329B2 (en) | 1998-07-09 |
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