JPH03127711A - Impressing material for dental use - Google Patents

Impressing material for dental use

Info

Publication number
JPH03127711A
JPH03127711A JP1266989A JP26698989A JPH03127711A JP H03127711 A JPH03127711 A JP H03127711A JP 1266989 A JP1266989 A JP 1266989A JP 26698989 A JP26698989 A JP 26698989A JP H03127711 A JPH03127711 A JP H03127711A
Authority
JP
Japan
Prior art keywords
impression
impressing
weight
chlorinated paraffin
impressing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1266989A
Other languages
Japanese (ja)
Inventor
Takashi Chinuki
千貫 高志
Hiroshi Ishida
博士 石田
Tatsuo Goto
達男 後藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IBUKI KK
Sumitomo Chemical Co Ltd
Original Assignee
IBUKI KK
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IBUKI KK, Sumitomo Chemical Co Ltd filed Critical IBUKI KK
Priority to JP1266989A priority Critical patent/JPH03127711A/en
Publication of JPH03127711A publication Critical patent/JPH03127711A/en
Pending legal-status Critical Current

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  • Dental Preparations (AREA)

Abstract

PURPOSE:To obtain the subject impressing material easily flowable in the collection of impression, sufficiently keeping the shape at about the body temperature and solidifiable in an elastic state by uniformly mixing an ethylene-vinyl acetate copolymer with a specific amount of a chlorinated paraffin. CONSTITUTION:The objective dental impressing material can be produced by uniformly mixing 10-70wt.% of an ethylene-vinyl acetate copolymer with 90-30wt.% of a chlorinated paraffin. The impressing material can be easily used simply by squeezing out of a tube without necessitating skilled labor. It does not adhere to the oral mucosa and exhibits high reproducibility. An impression having undercut part can be collected and the impression is free from dimensional change with time at normal temperature. The material can be applied without giving pain to the patient caused by odor, heat, etc. Even if the first collection of the impression is failed, the impressing operation can be repeated by applying the impressing material to the first impressing material. The material has the merits of an agar impressing material and those of a silicone rubber impressing material.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は歯科用に用いられる印象材に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to impression materials used in dentistry.

〔従来の技術〕[Conventional technology]

従来、歯科用印象材として、非弾性印象材たる石膏印象
材、亜鉛華ニーシノール印象材、モデリングコンパウン
ド及び弾性印象材たる寒天印象材、アルジネート印象材
、ポリサルファイドラバー印象材、シリコーンラバー印
象材、ポリエーテルラバー印象材が知られている。この
中で主に親水性系の寒天印象材とアルジネート印象材、
疎水性系のシリコーンラバー印象材が使用されている。
Traditionally, dental impression materials have been used as non-elastic impression materials such as gypsum impression materials, zinc oxide Nishinol impression materials, modeling compounds, and elastic impression materials such as agar impression materials, alginate impression materials, polysulfide rubber impression materials, silicone rubber impression materials, and polyether. Rubber impression materials are known. Among these, mainly hydrophilic agar impression materials and alginate impression materials,
A hydrophobic silicone rubber impression material is used.

そして、この寒天印象材及びシリコーンラバー印象材は
アンダーカットのある印象採得に適当であるとともに、
寒天印象材は、安価でかつ口腔粘膜面に対し親和性を有
する利点を有し、一方、シリコーンラバー印象材は口腔
内組繊細部の再現性の精度が高くかつシャープさを有す
ると共に口腔内浸出液による影響がないという利点を有
している。
This agar impression material and silicone rubber impression material are suitable for taking impressions with undercuts, and
Agar impression materials have the advantages of being inexpensive and having an affinity for the oral mucosal surface, while silicone rubber impression materials have high precision and sharpness in the reproducibility of delicate parts of the oral cavity, and are effective against intraoral exudates. It has the advantage of not being affected by

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記親水性系印象材は、上記利点を有するものの離液現
象を起こし、精度が低くシャープさに欠け、口腔内浸出
液により印象寸法に誤差を生じるという問題があり、ま
たシリコーンラバー印象材は、高価でかつ口腔粘膜面に
対し親和性に欠けるという問題があった。
Although the above-mentioned hydrophilic impression materials have the above-mentioned advantages, they suffer from problems such as syneresis, low precision, lack of sharpness, and errors in impression dimensions caused by intraoral exudate, and silicone rubber impression materials are expensive. There were problems in that it was large and lacked affinity for the oral mucosal surface.

そこで本発明は、アンダーカットのある印象採得に適し
、口腔粘膜面に対して親和性があり、かつ口腔内組繊細
部の再現性の精度が高くかつシャープさを有すると共に
口腔内浸出液による影響がないという利点をも兼備した
印象材を提供することを目的とする。
Therefore, the present invention is suitable for taking impressions with undercuts, has an affinity for the oral mucosal surface, has high precision and sharpness in reproducibility of delicate parts of the oral cavity, and is not affected by intraoral exudates. The purpose of the present invention is to provide an impression material that also has the advantage of being free of scratches.

[課題を解決するための手段] 本発明は、無毒で弾性強度を有し、かつ軟化温度を自由
に選択できるエチレン−酢酸ビニル共重合体(以下EV
A樹脂という)の性質に着目してなされたものである。
[Means for Solving the Problems] The present invention utilizes an ethylene-vinyl acetate copolymer (hereinafter referred to as EV) which is non-toxic, has elastic strength, and can freely select the softening temperature.
This was developed by focusing on the properties of resin A).

EVA樹脂単独では未だ軟化温度が高く、少し高温であ
っても粘りのある鳥もち状でしかないため印象材として
は好ましくない。本発明者らは鋭意研究の結果、EVA
樹脂に適当量の塩素化パラフィンを均一に混合すること
により、印象採得時の60〜70°Cでは容易に流動し
、かつ体温近傍では、形状が十分保持でき、さらに弾性
体として固化する特性を有する印象材として有効な組成
物を見出し本発明を充放させたものである。
EVA resin alone is not preferable as an impression material because its softening temperature is still high, and even at a slightly high temperature, it remains sticky and sticky. As a result of intensive research, the inventors found that EVA
By uniformly mixing an appropriate amount of chlorinated paraffin with the resin, it has the properties of being able to flow easily at 60 to 70°C at the time of impression taking, retain its shape well near body temperature, and solidify as an elastic body. The present invention has been developed by discovering a composition that is effective as an impression material and has the following properties.

すなわち本発明は、エチレン−酢酸ビニル共重合体10
〜70重量%と塩素化パラフィン90〜30重量%とか
らなる歯科用印象材である。
That is, the present invention provides ethylene-vinyl acetate copolymer 10
It is a dental impression material consisting of ~70% by weight and 90-30% by weight of chlorinated paraffin.

本発明で使用するEVA樹脂は、下記の反復単位〔A〕
と〔B〕とを有する共重合体であって、酢酸ビニル含有
量が20〜50重量%のものが塩素化パラフィンの均一
混合性の点から好ましい。
The EVA resin used in the present invention has the following repeating unit [A]
A copolymer having and [B] having a vinyl acetate content of 20 to 50% by weight is preferred from the viewpoint of uniform miscibility of the chlorinated paraffin.

(CH2C142)−(A) (CH2−CH)。(CH2C142)-(A) (CH2-CH).

○        (B) CH3−C,○ また、EVA樹脂として酢酸ビニル含有量が特定の一種
のEVA樹脂を用いてもよく、あるいは酢酸ビニル含有
量が異なる複数種のEVA樹脂を組み合わせて用いても
よい。
○ (B) CH3-C, ○ In addition, a type of EVA resin with a specific vinyl acetate content may be used as the EVA resin, or a combination of multiple types of EVA resins with different vinyl acetate contents may be used. .

本発明で使用する塩素化パラフィンとは、炭素数10〜
30のn−パラフィンの塩素化物又はワックスの塩素化
物で、塩素含有量が40〜70%のものである。特に、
塩素含有量が40〜50%のものが粘度等の点から好ま
しい。
The chlorinated paraffin used in the present invention has 10 or more carbon atoms.
A chlorinated product of No. 30 n-paraffin or a chlorinated wax with a chlorine content of 40 to 70%. especially,
Those having a chlorine content of 40 to 50% are preferred from the viewpoint of viscosity and the like.

EVA樹脂と塩素化パラフィンの組成物中の塩素化パラ
フィン量は、90〜30重量%であり、90重量%以上
では、可塑剤のブリードアウトが大きく、また30重量
%以下では、60〜70°Cで適度の流動性を示さない
ので好ましくない。
The amount of chlorinated paraffin in the composition of EVA resin and chlorinated paraffin is 90 to 30% by weight, and if it is more than 90% by weight, the bleed out of the plasticizer will be large, and if it is less than 30% by weight, it will be 60 to 70°. C is not preferred because it does not exhibit adequate fluidity.

本発明の歯科用印象材として使用されるEVA樹脂と可
塑剤からなる組成物には、更に、増量剤としであるいは
固体弾性、溶融粘度の調整剤等として各種添加剤を添加
することができる。これらの添加剤としては、パラフィ
ン等のワックス類、ベントナイト、炭酸カルシウム、ク
ルジ、ウオラストナイト、二酸化ケイ素、二酸化ケイ素
エアロゲル、酸化チタン、珪藻土、珪酸カルシウム、ガ
ラス、ガラスピーズ、ガラスバルーン等の無機充填剤、
並びにポリエチレン粉末、スチレンビーズ酢酸ビニル樹
脂などの有機充填剤などが好ましい。
The composition of the EVA resin and plasticizer used as the dental impression material of the present invention may further contain various additives such as fillers, solid elasticity and melt viscosity regulators, and the like. These additives include waxes such as paraffin, bentonite, calcium carbonate, cruzi, wollastonite, silicon dioxide, silicon dioxide airgel, titanium oxide, diatomaceous earth, calcium silicate, glass, glass peas, glass balloons, and other inorganic fillers. agent,
Also preferred are organic fillers such as polyethylene powder, styrene beads and vinyl acetate resin.

これらの他に、顔料染料による着色、賦香剤、甘味剤、
酸化防止剤、防腐剤、防菌・殺菌剤などの添加も必要に
応じ適宜行うことができる。
In addition to these, coloring with pigment dyes, flavoring agents, sweeteners,
Antioxidants, preservatives, antibacterial/sterilizing agents, and the like can also be added as appropriate.

〔実施例〕〔Example〕

以下に本発明を具体的に説明するために実施例を示すが
、本発明は必ずしもこれらの例により限定されるもので
はない。
Examples are shown below to specifically explain the present invention, but the present invention is not necessarily limited to these examples.

(実施例1) EVA樹脂(住友化学工業■製、エバテート■に301
0)15重量部、塩素化パラフィン(味の素■製、エン
バラ■40)85重量部、パラフィンワックス(半井化
学製試薬、融点52〜54°C)5重量部および珪藻土
(昭和化学■製、ラジオライト)5重量部を150°C
にて均一に混合し、これをチューブ状容器に充填して保
存した。使用時に、これを60〜70°Cに加温し、チ
ューブから押し出してトレーに盛り口腔内にセット、2
〜3分間で固化させ、これに石膏(面至歯科工業製、プ
ラストーンL)100gを水26gで練和しEVA印象
型に注入して型を成形した。得られた印象材は、口腔内
の再現性に優れたものであった。
(Example 1) EVA resin (manufactured by Sumitomo Chemical, Evatate 301)
0) 15 parts by weight, 85 parts by weight of chlorinated paraffin (manufactured by Ajinomoto ■, Enbara ■40), 5 parts by weight of paraffin wax (reagent manufactured by Hanui Chemical, melting point 52-54°C), and diatomaceous earth (manufactured by Showa Kagaku ■, Radiolight) ) 5 parts by weight at 150°C
The mixture was mixed uniformly in a tube, and the mixture was filled into a tube-shaped container and stored. When using, warm this to 60-70°C, push it out of the tube, place it on a tray, and set it in the oral cavity.
After solidifying for ~3 minutes, 100 g of plaster (Plastone L, manufactured by Menshi Dental Industry Co., Ltd.) was mixed with 26 g of water and poured into an EVA impression mold to form a mold. The obtained impression material had excellent intraoral reproducibility.

また、チューブ状容器に充填して保存した組成物を同様
にチューブから押し出し、金型上で、55mmx20m
m、3mm厚みの平板を作り、湿度100%の室温条件
で24時間放置した試料について、放置前後の辺の長さ
を測定し、寸法変化率を下記式により求めた。
In addition, the composition filled and stored in a tube-shaped container was similarly extruded from the tube, and placed on a mold in a size of 55 mm x 20 m.
A flat plate with a thickness of 3 mm was prepared and the sample was left at room temperature with 100% humidity for 24 hours.The lengths of the sides before and after being left were measured, and the dimensional change rate was determined using the following formula.

表1に示す通り、寸法変化はきわめてわずかであり、良
好な結果を示した。
As shown in Table 1, the dimensional change was extremely small, indicating good results.

(実施例2) EVA樹脂(住良化学工業■製エバテート■H3O11
)5重量部、EVA樹脂(住良化学工業(2)製エバテ
ート8に4010)15重量部、塩素化パラフィン(味
の素■製エンバラ@40)80重量部およびパラフィン
ワックス(牛丼化学製試薬、融点52〜54°C)5重
量部を使用した以外は実施例1と同様の試験を行った。
(Example 2) EVA resin (Evatate H3O11 manufactured by Sumira Chemical Co., Ltd.)
), 15 parts by weight of EVA resin (Evatate 8 to 4010 manufactured by Sumira Chemical Co., Ltd. (2)), 80 parts by weight of chlorinated paraffin (Enbara@40 manufactured by Ajinomoto ■), and paraffin wax (reagent manufactured by Gyudon Kagaku, melting point The same test as in Example 1 was conducted except that 5 parts by weight (52-54°C) was used.

(実施例3) EVA樹脂(住良化学工業■製エバテート■H3O11
)10重量部、EVA樹脂(住良化学工業■製エバテー
ト■に4010)15重量部、塩素化パラフィン(味の
素■製エンパラ■40)75重量部を使用した以外は実
施例1と同様の試験を行った。
(Example 3) EVA resin (Evatate H3O11 manufactured by Sumira Chemical Co., Ltd.)
), 15 parts by weight of EVA resin (Evatate 4010 manufactured by Sumira Chemical Co., Ltd.), and 75 parts by weight of chlorinated paraffin (Empara 40 manufactured by Ajinomoto) were used. went.

(実施例4) EVA樹脂(住良化学工業■製エバテート@に4010
)15重量部、EVA樹脂(住良化学工業■製エバテー
ト■R5011)35重量部、塩素化パラフィン(味の
素■製エンパラ@40)50重量部および珪藻土(昭和
化学■製、ラジオライト)20重量部を使用した以外は
実施例1と同様の試験を行った。
(Example 4) EVA resin (Evatate@4010 manufactured by Sumira Chemical Co., Ltd.)
) 15 parts by weight, EVA resin (Evatate R5011 manufactured by Sumira Chemical Co., Ltd.) 35 parts by weight, chlorinated paraffin (Empara@40 manufactured by Ajinomoto ■) 50 parts by weight, and diatomaceous earth (manufactured by Showa Chemical ■, Radiolite) 20 parts by weight The same test as in Example 1 was conducted except that .

(実施例5) EVA樹脂(住良化学工業■製エバテート@に4010
)10重量部、EVA樹脂(住良化学工業■製エバテー
ト@M5011)15重量部、EVA樹脂(住良化学工
業■製エバテート■R5011)40重量部塩素化パラ
フィン(味の素■製エンパラ@40)35重量部および
珪藻土(昭和化学■製、ラジオライト)50重量部を使
用した以外は実施例1と同様の試験を行った。
(Example 5) EVA resin (Evatate@4010 manufactured by Sumira Chemical Co., Ltd.)
) 10 parts by weight, EVA resin (Evatate@M5011 manufactured by Sumira Chemical Co., Ltd.) 15 parts by weight, EVA resin (Evatate R5011 manufactured by Sumira Chemical Co., Ltd.) 40 parts by weight Chlorinated paraffin (Empara@40 manufactured by Ajinomoto ■) 35 The same test as in Example 1 was conducted except that 50 parts by weight of diatomaceous earth (Radiolite, manufactured by Showa Kagaku ■) were used.

以上の実施例1〜5の印象材はいずれも口腔内の再現性
および寸法安定性共に優れたものであった。
The impression materials of Examples 1 to 5 above were all excellent in both intraoral reproducibility and dimensional stability.

(比較例1) アルジネート印象材として、日本歯研工業製のパナコー
ルSEを、JIS  T6505に従い、水と混和し、
実施例1と同様のテストを行ったが寸法安定性に欠ける
ものであった。
(Comparative Example 1) As an alginate impression material, Panacol SE manufactured by Nippon Kiken Kogyo was mixed with water according to JIS T6505,
The same test as in Example 1 was conducted, but the dimensional stability was found to be lacking.

ホホホホホ \\\\\ l:I  口 OOロ ト か ♂ さ ♂ コ  二  ュ  ユ  二 ス、 \ ^、 “ス、 ′ス、 よよ♂と と 特開平 127711(4) 〔発明の効果〕 本発明の印象材は、例えばチューブから押し出すだけで
簡単に使用でき熟練した技術を必要としない。また口腔
内組織に粘着せず、再現性に優れ、かつアンダーカット
部を含む印象ができ常温における経時変化によって寸法
変化がないという特徴を有するものである。また臭さ、
熱さ等によって患者に苦痛を与えることがなく、オレン
ジ油、ハツカ油、香料を使用することによって患者に良
悪を与えることができる。さらに1回目の印象が失敗し
てもその上に印象材を追加して再度印象することができ
る。また辺縁等の印象の場合、盛り足し可能であり、辺
縁のみを温水で温め機能印象を採得できる。またティッ
シュコンディショナー、弾性裏装剤としても適用可能で
ある。
Hohohohoho\\\\\ l:I 口 OOLOTO ka ♂ sa ♂ Ko Niyu Nisu, \ ^, “Su, 'su, yoyo♂to” and JP-A-127711 (4) [Effects of the Invention] The present invention This impression material is easy to use, for example, by simply pushing it out of a tube, and does not require skilled techniques.It also does not stick to oral tissues, has excellent reproducibility, can create impressions that include undercuts, and shows no change over time at room temperature. It has the characteristic that there is no dimensional change due to
The heat does not cause pain to the patient, and the use of orange oil, peppermint oil, and fragrance can make the patient feel good and bad. Furthermore, even if the first impression fails, an impression material can be added on top of it and another impression can be made. In addition, in the case of an impression such as a margin, it is possible to add more, and a functional impression can be obtained by heating only the margin with warm water. It can also be used as a tissue conditioner and elastic lining agent.

本発明はエチレン−酢酸ビニル共重合体に塩素化パラフ
ィンを加えてなり、寒天印象材とシリコーンラバー印象
材の利点を兼備した印象材を提供できる。
The present invention is made by adding chlorinated paraffin to an ethylene-vinyl acetate copolymer, and can provide an impression material that has both the advantages of an agar impression material and a silicone rubber impression material.

11(艷)11 (艷)

Claims (1)

【特許請求の範囲】[Claims]  エチレン−酢酸ビニル共重合体10〜70重量%と塩
素化パラフィン90〜30重量%とからなる歯科用印象
材。
A dental impression material comprising 10 to 70% by weight of an ethylene-vinyl acetate copolymer and 90 to 30% by weight of chlorinated paraffin.
JP1266989A 1989-10-13 1989-10-13 Impressing material for dental use Pending JPH03127711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1266989A JPH03127711A (en) 1989-10-13 1989-10-13 Impressing material for dental use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1266989A JPH03127711A (en) 1989-10-13 1989-10-13 Impressing material for dental use

Publications (1)

Publication Number Publication Date
JPH03127711A true JPH03127711A (en) 1991-05-30

Family

ID=17438518

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1266989A Pending JPH03127711A (en) 1989-10-13 1989-10-13 Impressing material for dental use

Country Status (1)

Country Link
JP (1) JPH03127711A (en)

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