JPH03123692A - Method and apparatus for improving quality of water - Google Patents

Method and apparatus for improving quality of water

Info

Publication number
JPH03123692A
JPH03123692A JP26115689A JP26115689A JPH03123692A JP H03123692 A JPH03123692 A JP H03123692A JP 26115689 A JP26115689 A JP 26115689A JP 26115689 A JP26115689 A JP 26115689A JP H03123692 A JPH03123692 A JP H03123692A
Authority
JP
Japan
Prior art keywords
water
slaked lime
pumped
pumping
quality improvement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26115689A
Other languages
Japanese (ja)
Inventor
Masahiko Makino
正彦 牧野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaiyo Kogyo KK
Original Assignee
Kaiyo Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaiyo Kogyo KK filed Critical Kaiyo Kogyo KK
Priority to JP26115689A priority Critical patent/JPH03123692A/en
Priority to FI900048A priority patent/FI900048A/en
Priority to CA 2007615 priority patent/CA2007615A1/en
Priority to DK28490A priority patent/DK28490A/en
Priority to SE9001291A priority patent/SE9001291L/en
Publication of JPH03123692A publication Critical patent/JPH03123692A/en
Priority to US07/782,381 priority patent/US5227056A/en
Priority to US07/798,838 priority patent/US5256309A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To prevent eutrophication by adjusting pH and fixing phosphorus by a method wherein high concentration alkalified water is mixed with and diffused in water of a dam or the like by an intermittent air pumping-up apparatus. CONSTITUTION:A pump 4 is rotated and pumped-up water passes through slaked lime 2 to be transferred to a water suction cylinder 10a from a solution tank 7. The water pushed up by the compressed air of an intermittent air pumping-up apparatus 9 is blown off from the upper end of the water suction cylinder 10a to raise the surface 40 of the water like the protruding surface 40a of the water and the raised water successively falls to be diffused in a lateral direction. A part of mixed water falls on the way and the other part is diffused under the surface of water to reach the shore and falls to flow along the bottom part of the water and all of waters are perfectly mixed. Since high concentration alkalified water having slaked lime dissolved therein is diffused in an mixed with water to be treated, mixing is extremely easy and concn. rapidly becomes uniform and soluble phosphorus is markedly reduced and eutrophication is improved.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、上水用ダム、貯水池、池、堀、湖、沼、河
川などの水質改善を目的とした水質改善方法及び装置に
関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a water quality improvement method and apparatus for improving the water quality of water supply dams, reservoirs, ponds, moats, lakes, marshes, rivers, and the like.

(従来の技術) 従来、大量水の浄化については、出願人が先に提案した
間欠空気揚水装置(実公昭63−398号)が多大の成
果を上げ、国内各地で実用化されている。また、水道水
の消石灰によるPH調整や、カルシウムによる送水管の
腐蝕防止について提案されている。
(Prior Art) Conventionally, regarding the purification of large amounts of water, an intermittent air pumping device (Utility Model Publication No. 63-398) previously proposed by the applicant has achieved great results and has been put into practical use in various parts of the country. Furthermore, it has been proposed to adjust the pH of tap water using slaked lime and to prevent corrosion of water pipes due to calcium.

(発明により解決すべき課題) 前記間欠空気揚水装置によれば、ダム、湖沼、池、海等
の多量水の溶存酸素量を改善する点で、比較的少ないエ
ネルギーにより、多大の効果を上げると共に、10m以
上の水深があれば藻類の繁殖防止についても効果がある
ことが知られている。
(Problems to be Solved by the Invention) According to the intermittent air pumping device, in improving the amount of dissolved oxygen in large volumes of water such as dams, lakes, ponds, and the sea, it can achieve great effects with a relatively small amount of energy. It is known that water depths of 10 m or more are effective in preventing the growth of algae.

例えば、水量100万トンにつ祭直径50cm。For example, a festival with a water volume of 1 million tons has a diameter of 50 cm.

長さ10mの揚水筒を有する揚水装置1基に毎分約II
T?の加圧空気を送ることにより、約1週間て溶存酸素
量を改善できると共に、水深に関係なく、水温をほぼ一
定にできることが判明している。然し乍ら、水質が酸性
の場合に5.これをアルカリ性にすることは困難であり
、また酸素供給によって底質からの燐の溶出は抑えられ
るが、°水中の燐を除去することは困難であった。
Approximately II per minute per pumping device with a pumping tube 10m long
T? It has been found that by sending pressurized air into the water, the amount of dissolved oxygen can be improved over a period of about one week, and the water temperature can be kept almost constant regardless of the water depth. However, if the water quality is acidic, 5. It is difficult to make this alkaline, and although the elution of phosphorus from the bottom sediment can be suppressed by supplying oxygen, it has been difficult to remove phosphorus from the water.

(課題を解決する為の手段) 然るにこの発明は、消石灰を溶解した又はカセイソーダ
等により生成したアルカリ高濃度水を間欠空気揚水装置
により、ダム等に混合拡散させることにより、PR調整
及び燐を固定して、富栄養化を防止することに成功した
のである。
(Means for Solving the Problems) However, this invention adjusts PR and fixes phosphorus by mixing and diffusing highly concentrated alkaline water produced by dissolving slaked lime or using caustic soda into a dam etc. using an intermittent air pumping device. As a result, they succeeded in preventing eutrophication.

即ち方法の発明は、アルカリ高濃度水を間欠空気揚水装
置による揚水に注入し、該揚水の拡散循環に伴って大量
水のPHを調整することを特徴とした水質改善方法であ
る。
That is, the method invention is a water quality improvement method characterized by injecting highly concentrated alkaline water into water pumped by an intermittent air pumping device and adjusting the pH of a large amount of water as the pumped water diffuses and circulates.

また他の発明は消石灰を溶解させた水を間欠空気揚水装
置による揚水に注入し、該揚水の拡散循環に伴って処理
水中にカルシウム燐化合物を生成すると共に、PHを調
整することを特徴とした水質改善方法である。
Another invention is characterized in that water in which slaked lime is dissolved is injected into water pumped by an intermittent air pumping device, and as the pumped water diffuses and circulates, calcium phosphorus compounds are generated in the treated water and pH is adjusted. This is a method of improving water quality.

また他の方法の発明は、消石灰を入れた溶解槽に水を注
入し、溶解槽からカルシウムを溶解したアルカリ水を取
り出し、このアルカリ水を揚水筒の揚水中に注入するこ
とにより大量水のPHを調整することを特徴としたもの
である。
Another invention of the method is to inject water into a dissolution tank containing slaked lime, take out alkaline water in which calcium is dissolved from the dissolution tank, and inject this alkaline water into the pumping water of a water pump to improve the pH of a large amount of water. It is characterized by adjusting the

また、消石灰を溶解させた水を多段の間欠空気揚水装置
による揚水中に注入し、該揚水の拡散循環に伴って大量
水の全部又は一部のPHを調整することを特徴とした水
質改善方法である。
Further, a water quality improvement method characterized by injecting water in which slaked lime has been dissolved into water pumped by a multi-stage intermittent air pumping device, and adjusting the pH of all or part of the large amount of water as the pumped water diffuses and circulates. It is.

更に大量水は、浅層・深層の何れか一方又は両方のPH
を調整することを特徴としたものである。
Furthermore, large amounts of water have a pH of either shallow or deep, or both.
It is characterized by adjusting the

更に他の方法としては、間欠空気揚水装置による揚水噴
出域内へ消石灰を配置し、前記揚水の流動時に、前記消
石灰を溶解した消石灰高濃度水を前記揚水の拡散循環に
伴って大量水に混入することを特徴とした水質改善方法
である。
Still another method is to arrange slaked lime in a pumping and spouting area by an intermittent air pumping device, and when the pumped water flows, slaked lime high concentration water in which the slaked lime is dissolved is mixed into a large amount of water as the pumped water diffuses and circulates. This is a water quality improvement method characterized by:

次に装置の発明は、消石灰を入れる溶解槽の下部に、給
水管の先端側を連結し、溶解槽の上部に送水管の基端側
を連結し、前記送水管の先端側を間欠空気揚水装置の吸
水筒に連結したことを特徴とする水質改善装置である。
Next, the invention of the device connects the tip side of the water supply pipe to the lower part of the dissolution tank containing slaked lime, connects the base end side of the water supply pipe to the upper part of the dissolution tank, and connects the distal end side of the water supply pipe to the intermittent air pumping. This is a water quality improvement device characterized by being connected to a water absorption cylinder of the device.

次に他の装置の発明は、消石灰を入れる溶解槽の下部に
給水管の先端側を連結し、溶解槽の上部に送水管の基端
を連結し、前記送水管の先端を多段間欠揚水装置の揚水
筒の全部又は一部に接続開口させたことを特徴とした水
質改善装置である。
Next, the invention of another device connects the tip side of a water supply pipe to the lower part of a dissolution tank containing slaked lime, connects the base end of the water supply pipe to the upper part of the dissolution tank, and connects the tip of the water supply pipe to a multistage intermittent water pumping device. This is a water quality improvement device characterized by having a connecting opening in all or part of the water pumping cylinder.

また他の装置の発明は、揚水筒の下部に、空気室を設置
した間欠空気揚水装置の揚水筒の上部であって、揚水拡
散通路4q消石灰の通水性容器を設けたことを特徴とす
る水質改善装置である。
Another invention of the device is for improving water quality, characterized in that the upper part of the water pumping pipe of an intermittent air pumping device in which an air chamber is installed in the lower part of the water pumping pipe is provided with a water-permeable container for pumping diffusion passage 4q and slaked lime. It is an improvement device.

前記において、消石灰の溶解度は20℃の場合に160
0a+g/Ω (0、16%)であるから、溶解槽に多
量の消石灰を入れ、又は多量の消石灰塊を通水容器に収
容しておいても、一定量宛溶解するので、支障を生じる
おそれなく、管理が容易である。
In the above, the solubility of slaked lime is 160 at 20°C.
0a+g/Ω (0.16%), so even if a large amount of slaked lime is placed in the dissolution tank or a large amount of slaked lime block is stored in a water container, it will dissolve to a certain amount, which may cause problems. Easy to manage.

例えば、溶解槽又は通水容器に多量の消石灰を入れてお
いて通水すれば、逐次カルシウムを溶出し、その状態は
、前記消石灰がなくなるまでほぼ同一条件で続くことに
なるので、自動制御の必要なく、順調に作動する。通常
上水に使用されるダム等の水質によれば、PH調整の為
に10〜30mg / 1の消石灰を必要とするので、
1600mg/Ωの高濃度水のほぼ160倍〜50倍の
水量の水質を改善することができる。また水中の燐の除
去については、50〜100mg/Rの消石灰を必要と
するので、1600mg/lの高濃度水のほぼ32倍〜
16倍の水量の水質を改善することができる。
For example, if a large amount of slaked lime is placed in a dissolution tank or a water-flowing container and water is passed through it, calcium will be eluted successively and this state will continue under almost the same conditions until the slaked lime runs out. It works fine without any need for it. According to the water quality of dams etc. normally used for drinking water, 10 to 30 mg/1 of slaked lime is required to adjust the pH.
It is possible to improve water quality by approximately 160 to 50 times the amount of water with a high concentration of 1600 mg/Ω. In addition, to remove phosphorus from water, 50 to 100 mg/R of slaked lime is required, which is approximately 32 times more concentrated than water with a high concentration of 1600 mg/L.
The water quality can be improved by 16 times the amount of water.

この発明の方法中、予め消石灰を溶解した高濃度水を作
る場合には、前記処理水量に応じた高濃度水(例えば、
処理水100万トンに対し1万トン)必要となるが、そ
の溶解槽へは処理対象のダム等の水を給水すればよいの
で、円滑に確実に実施できる。
In the method of this invention, when preparing highly concentrated water with slaked lime dissolved in advance, the highly concentrated water according to the amount of treated water (for example,
(10,000 tons per 1 million tons of treated water) is required, but since water from a dam, etc. to be treated can be supplied to the dissolution tank, the process can be carried out smoothly and reliably.

また、揚水装置の上部の揚水拡散域に消石灰を収容する
通水容器を配置すればよいので、管理は一層簡単になる
Moreover, since it is sufficient to arrange a water passage container containing slaked lime in the pumped water diffusion area at the upper part of the water pumping device, management becomes easier.

然して、−風水質を改善した後は、流入水量の水質を改
善すればよいわけであるから、ランニングコストは原則
的に流入水量に対応することになる。然して、富栄養化
により生じる幾多の問題点も解決されることになり、正
に一石二鳥である。
However, after improving the feng shui quality, it is only necessary to improve the quality of the amount of inflow water, so the running cost basically corresponds to the amount of inflow water. As a result, many of the problems caused by eutrophication will be solved, truly killing two birds with one stone.

次に間欠空気揚水装置の能力は、水量、ダム等の断面形
状及び流入・流出形態により異なるけれども、大凡前記
のように水量100万トンに対し、直径50cmの揚水
筒1基位である。
Next, although the capacity of an intermittent air pumping device varies depending on the amount of water, the cross-sectional shape of the dam, etc., and the form of inflow and outflow, it is approximately one pumping tube with a diameter of 50 cm per 1 million tons of water as described above.

然して実験の結果によれば、ダムの平面形状が多少の複
雑であったり、又は設置位置から岸が遠い(1000m
、又はそれ以上)場合であっても、はぼ均等に拡散循環
することが認められている。
However, according to the results of experiments, the planar shape of the dam is somewhat complicated, or the shore is far from the installation location (1000 m).
, or more), it has been observed that the diffusion circulation is more or less uniform.

従って、この拡散循環により消石灰の溶解水は拡散し、
全体の水質を改善することができる。
Therefore, due to this diffusion circulation, the dissolved water of slaked lime is diffused,
Overall water quality can be improved.

尚、前記においては消石灰を溶解してアルカリ高濃度水
を生成したが、他のアルカリ性剤を用いてアルカリ高濃
度水を生成することを妨げない。
In the above description, slaked lime was dissolved to produce highly alkaline water, but this does not preclude the use of other alkaline agents to produce highly alkaline water.

(作  用) 即ちこの発明の方法によれば、消石灰の溶解水を間欠空
気揚水装置による揚水の拡散によって大量水に混入する
ので、容易均等に拡散できる。
(Function) That is, according to the method of the present invention, the dissolved water of slaked lime is mixed into a large amount of water by diffusion of the water pumped by the intermittent air pumping device, so that it can be easily and evenly spread.

また、消石灰は通水路に介装するのみで、可溶2宛溶液
となって拡散するので、溶解量に対する管理の必要性が
ない。
In addition, the slaked lime is simply inserted into the water passage and becomes a soluble solution and diffuses, so there is no need to control the amount of dissolved lime.

また消石灰の溶解によって水中に溶解している燐と、カ
ルシウムとが結合して燐化合物を生成し、燐を不溶性に
固定する。
In addition, phosphorus dissolved in water due to the dissolution of slaked lime combines with calcium to form a phosphorus compound, fixing the phosphorus insoluble.

この発明の装置によれば、揚水を有効に拡散循環できる
ので、揚水に混入した消石灰の溶解水も同様に均一拡散
させることができる。
According to the device of the present invention, since the pumped water can be effectively diffused and circulated, the dissolved water of slaked lime mixed in the pumped water can also be uniformly diffused.

(実施例1) 次に、この発明の実施例を第1図乃至第3図について説
明する。
(Example 1) Next, an example of the present invention will be described with reference to FIGS. 1 to 3.

溶解槽1の下部に消石灰2を充填(例えば通水容器に入
れて適宜積み上げる)すると共に、溶解槽1の下部へ給
水管3を連結する。給水管3にはポンプ4と、バルブ5
を介装する。また、溶解槽1の上部に移送管6の基端を
連結し、移送管6の先端に溶液タンク7を連結し、溶液
タンク7にポンプ11を介装した送水管8の基端を連結
し、送水管8の先端を間欠空気揚水装置9の吸水筒10
aに連結開口させる。前記において、ポンプ4を回転し
、その吸入管14により、例えばダムより汲み上げた水
を矢示12のように溶解槽1に送ると、この水は消石灰
2を通過して溶解槽1に溜る。
The lower part of the dissolving tank 1 is filled with slaked lime 2 (for example, placed in a water-flowing container and piled up appropriately), and the water supply pipe 3 is connected to the lower part of the dissolving tank 1. The water supply pipe 3 has a pump 4 and a valve 5.
Interpose. Further, the base end of a transfer pipe 6 is connected to the upper part of the dissolution tank 1, the solution tank 7 is connected to the tip of the transfer pipe 6, and the base end of a water supply pipe 8 in which a pump 11 is interposed is connected to the solution tank 7. , the tip of the water pipe 8 is connected to the water suction tube 10 of the intermittent air pumping device 9.
Make a connection opening in a. In the above, when the pump 4 is rotated and water pumped up from a dam, for example, is sent to the dissolution tank 1 as indicated by the arrow 12 through its suction pipe 14, this water passes through the slaked lime 2 and accumulates in the dissolution tank 1.

そこで上澄水を移送管6で矢示13のように取り出す。Then, the supernatant water is taken out through the transfer pipe 6 as shown by the arrow 13.

この場合に上澄水であって水位が高いので、溶液タンク
7の位置が低ければ、移送ポンプを要しない。尤も、溶
解槽1を密封方式にすれば、ポンプ4からの給水によっ
て、移送管6へ自動的に移送される。そこで、溶液タン
ク7内の水をポンプ11により矢示15のように吸水筒
10aへ移送する。
In this case, since it is supernatant water and the water level is high, if the position of the solution tank 7 is low, a transfer pump is not required. However, if the dissolution tank 1 is sealed, the water will be automatically transferred to the transfer pipe 6 by the water supplied from the pump 4. Therefore, the water in the solution tank 7 is transferred to the water suction cylinder 10a as indicated by the arrow 15 by the pump 11.

前記間欠空気揚水装置9の揚水筒18は(第2図、第3
図)、4本の筒体18a、18b、18C,18dを一
体的に束ねた複合筒1oと、その下方に連結した一本の
吸水筒10aとよりなり、前記送水管8は吸水筒10a
に連結しである。前記間欠空気揚水装置9は、吸水筒1
0aの下部外側に空気室20を嵌挿し、吸水筒10aの
上部外側に浮室32を嵌装して構成されている。前記空
気室20は、吸水筒10aの外側へ所定間隔をおいて遊
嵌した内筒21と、その外側へ所定間隔をおいて遊嵌し
た外筒22と、内筒21と外筒22の間に嵌挿した仕切
筒23とよりなり、吸水筒】Oaと内筒21との間隙部
24、内筒21と仕切筒23の間隙部25、仕切筒23
と外筒22の間隙部26の上部は何れも頂板27で覆わ
れ、前記間隙部24.25の下部は底板28で閉塞され
ている。
The pumping cylinder 18 of the intermittent air pumping device 9 is shown in FIGS. 2 and 3.
), the water pipe 8 consists of a composite pipe 1o, which is made by integrally bundling four cylinders 18a, 18b, 18C, and 18d, and one water absorption pipe 10a connected below the composite pipe 1o.
It is connected to. The intermittent air pumping device 9 includes a water absorption cylinder 1
The air chamber 20 is fitted into the outside of the lower part of the water absorption cylinder 10a, and the floating chamber 32 is fitted into the outside of the upper part of the water absorption tube 10a. The air chamber 20 includes an inner cylinder 21 that is loosely fitted to the outside of the water absorption cylinder 10a at a predetermined interval, an outer cylinder 22 that is loosely fitted to the outside of the water absorption cylinder 10a at a predetermined interval, and a space between the inner cylinder 21 and the outer cylinder 22. A gap 24 between the water absorption tube Oa and the inner tube 21, a gap 25 between the inner tube 21 and the partition tube 23, and a gap 25 between the inner tube 21 and the partition tube 23;
The upper part of the gap 26 of the outer cylinder 22 is covered with a top plate 27, and the lower part of the gap 24, 25 is closed with a bottom plate 28.

前記仕切筒23の上部及び内筒21の下部には間隙24
.25.26を夫々連通ずる連通孔2つ、30が穿設さ
れ、間隙24と吸水筒10内とは連通孔31で連通され
ている。図中16は加圧空気の給気管、17は揚水筒1
8の下部と連索55.56で連結した重錘、19は覆板
、57は標識である(第4図)。
A gap 24 is provided between the upper part of the partition cylinder 23 and the lower part of the inner cylinder 21.
.. Two communication holes 30 are drilled through which the holes 25 and 26 are communicated with each other, and the gap 24 and the inside of the water absorption cylinder 10 are communicated with each other through the communication holes 31. In the figure, 16 is the pressurized air supply pipe, 17 is the water pump 1
A weight is connected to the lower part of 8 by cables 55 and 56, 19 is a cover plate, and 57 is a marker (Fig. 4).

前記間欠空気揚水装置9は、複合筒10の上部外側に固
定した浮室32の浮力によって吊り上げられ、重錘17
によって引き下げられているので、自由状態では常時垂
直状態で浮遊している(第4図)。
The intermittent air pumping device 9 is lifted by the buoyancy of a floating chamber 32 fixed to the outside of the upper part of the composite cylinder 10, and
Since it is pulled down by

前記実施例において、第2図のように加圧空気を空気室
20へ矢示33のように供給すると、加圧空気は空気室
20の上部内側より逐次溜り、その水位を矢示34のよ
うに下降させる。このようにして水位が連通孔30に達
すると、空気室20内の加圧空気は、矢示35.36.
37のように各連通孔29.30.31を通過して吸水
筒10a内へ入り、大きな気泡58となって上昇し、つ
いで4本の筒体18a、18b、:1.8c、18dに
分割された気泡38となって上昇する。この場合に気泡
38の下方の水は、気泡58.38の浮力によって引き
上げられ、気泡58.38の上方の水は浮力で押し上げ
られる。このようにして押し上げられた水は複合筒10
の上端から矢示39のように吹き出しく第4図)、水面
40を凸水面40aのように持ち上げた後、重力により
逐次矢示41のように下降して、矢示42のように横方
向へ拡散する。この場合において、前記吸水筒10a内
に供給された消石灰によるアルカリ高濃度水は、揚水中
に混入して矢示43のように揚水筒18内を上昇し、揚
水筒18の上端と水面との間の水に巻き込まれれて急速
に混合水となり、凸水面40aまで押し上げられ、つい
で矢示41のように拡散することになる。
In the above embodiment, when pressurized air is supplied to the air chamber 20 as shown by the arrow 33 as shown in FIG. lower to. When the water level reaches the communication hole 30 in this way, the pressurized air in the air chamber 20 moves as indicated by arrows 35, 36.
37, it passes through each communication hole 29, 30, 31 and enters the water absorption cylinder 10a, becomes a large bubble 58 and rises, and is then divided into four cylinders 18a, 18b, 1.8c, 18d. The air becomes bubbles 38 and rises. In this case, the water below the bubble 38 is pulled up by the buoyancy of the bubble 58.38, and the water above the bubble 58.38 is pushed up by the buoyancy. The water pushed up in this way is transferred to the composite tube 10.
After the water surface 40 is raised as a convex water surface 40a, it gradually descends as shown by the arrow 41 due to gravity, and then flows laterally as shown by the arrow 42. spread to. In this case, the highly concentrated alkaline water produced by the slaked lime supplied into the water absorption tube 10a mixes into the pumped water and rises inside the water pumping tube 18 as shown by the arrow 43, causing a contact between the upper end of the water pumping tube 18 and the water surface. It is caught in the water between the two, rapidly becomes mixed water, is pushed up to the convex water surface 40a, and then spreads out as shown by the arrow 41.

然して混合水の一部は途中から下降することになり、他
部は水面下(例えば1m〜3mの間)を拡散して岸に至
り、矢示45のように下降して水底部を矢示44のよう
に流動し、以下同様の循環を繰り返して余水が完全に混
合することになる。
As a result, part of the mixed water will descend from the middle, and the other part will spread below the water surface (for example, between 1 m and 3 m) and reach the shore, descending as shown by arrow 45 and moving down to the bottom of the water as shown by the arrow. 44, and the same circulation is repeated thereafter until the remaining water is completely mixed.

前記において、揚水は水面付近の水と混合水となること
により、温度差が殆んどなくなるので、比重差も殆んど
なくなり、沈降することなく矢示42のように横方向へ
拡散することになる。
In the above, the pumped water becomes mixed water with the water near the water surface, so there is almost no temperature difference, so there is almost no difference in specific gravity, and it spreads laterally as shown by arrow 42 without settling. become.

(実施例2) 第5図の実施例は、間欠空気揚水装置9の上方へ浮子4
6で保持した通水性の容器47を設置し、容器47の中
へ消石灰を収容する。この状態で間欠空気揚水装置9の
空気室20に加圧空気を送ると、前記実施例1で説明し
たように矢示48のように吹き上げられた水が水面付近
の水と混合し乍ら、容器47内を通過し、この間に消石
灰を溶解して、アルカリ高濃度水となり、矢示50.5
1のように拡散し、ついで矢示52のように下降した後
、水底部を矢示53のように移訪して、再び矢示54の
ように上昇するので、前記実施例1と同様に消石灰の高
濃度溶解水を急速に拡散混合することができる。
(Embodiment 2) In the embodiment shown in FIG. 5, the float 4 is
A water-permeable container 47 held by a container 6 is installed, and slaked lime is stored in the container 47. When pressurized air is sent to the air chamber 20 of the intermittent air pumping device 9 in this state, the water blown up as shown by the arrow 48 mixes with the water near the water surface as explained in the first embodiment. The water passes through the container 47, during which time the slaked lime is dissolved to become highly concentrated alkaline water, and the water becomes as indicated by the arrow 50.5.
It diffuses as shown in 1, then descends as shown by arrow 52, moves around the bottom of the water as shown by arrow 53, and rises again as shown by arrow 54, so it is the same as in Example 1. Water with a high concentration of slaked lime can be rapidly diffused and mixed.

前記実施例においては、容器47内を混合水が通過する
ことによって、アルカリ高濃度水が生成されるので、実
施例1の溶解槽のように濃度調整はできない。そして、
多量の水が通過すれば、必然的に濃度は低下するが、水
量が多いので効率低下のおそれはない。
In the embodiment described above, highly concentrated alkaline water is generated by passing the mixed water through the container 47, so the concentration cannot be adjusted as in the dissolution tank of the first embodiment. and,
If a large amount of water passes through, the concentration will inevitably decrease, but since the amount of water is large, there is no risk of a decrease in efficiency.

(実施例3) 次に第6図乃至第10図の実施例は、ダム、湖、沼など
の浅層と深層を上下別々に処理するものである。
(Embodiment 3) Next, in the embodiment shown in FIGS. 6 to 10, the upper and lower shallow layers and deep layers of a dam, lake, swamp, etc. are treated separately.

即ち、下部の間欠空気揚水装置59と、上部の間欠空気
揚水装置60とを分離装置61を介して連結したもので
ある。前記間欠空気揚水装置59は、揚水筒62の下部
に空気室20を嵌装して構成され、前記間欠空気揚水装
置60は、揚水筒63の下部に空気室20aを嵌装して
構成されている。前記各空気室20.20aは、実施例
1の空気室20と実質的に同一であるから、各対応部の
符号は同一とする。
That is, a lower intermittent air pumping device 59 and an upper intermittent air pumping device 60 are connected via a separation device 61. The intermittent air pumping device 59 is configured by fitting an air chamber 20 into the lower part of a water pumping tube 62, and the intermittent air pumping device 60 is configured by fitting an air chamber 20a into the bottom of a pumping tube 63. There is. Since each of the air chambers 20.20a is substantially the same as the air chamber 20 of the first embodiment, the corresponding parts are given the same reference numerals.

前記分離装置61は、揚水筒62の上端外側に、環状板
64aを嵌装固定し、前記環状板64a上には、第10
図中、截頭円錐状の分離材65a165bを所定間隔で
上下に遊嵌し、分離材65a165bの上端を空気室2
0aの外筒22と仕切筒23の間隙26と連通させる。
The separation device 61 has an annular plate 64a fitted and fixed on the outside of the upper end of the water pumping cylinder 62, and a tenth
In the figure, frustoconical separation members 65a165b are loosely fitted vertically at predetermined intervals, and the upper end of the separation members 65a165b is connected to the air chamber 2.
It communicates with the gap 26 between the outer cylinder 22 and the partition cylinder 23 of 0a.

また、分離材65bの上部は外筒22の下部と連結し、
連結部外側には環状板64bを嵌装固着しである。
Further, the upper part of the separating member 65b is connected to the lower part of the outer cylinder 22,
An annular plate 64b is fitted and fixed on the outside of the connecting portion.

次に第9図中、前記空気室20は、揚水筒62の下部に
連結した補助揚水筒62aの外側へ所定間隔をおいて遊
嵌した内筒21と、その外側へ所定間隔をおいて遊嵌し
た外筒22と、内筒21と外筒22との間に嵌装した仕
切筒23とよりなり、補助揚水筒62aと内筒21との
間隙部24、内筒21と仕切筒23との間隙部25、仕
切筒23と外筒22との間隙部26の上部は何れも頂板
27で覆われ、前記間隙部24.25の下部は底板28
で閉塞されている。 前記仕切筒23の上部及び内筒2
1の下部には、間隙24.25.26を夫々連通する連
通孔29.30が穿設され、間隙24と補助揚水筒62
a内とは連通孔31で連通されている。図中16は加圧
空気の給気管、17は給液筒67の下部と連索55で連
結した重錘、87は吸水管、88は揚水筒の下部に連結
した給液管である。
Next, in FIG. 9, the air chamber 20 includes an inner cylinder 21 that is loosely fitted to the outside of the auxiliary water pump 62a connected to the lower part of the water pump 62 at a predetermined interval, and an inner cylinder 21 that is loosely fitted to the outside of the auxiliary water pump 62a at a predetermined interval. It consists of the fitted outer cylinder 22 and the partition cylinder 23 fitted between the inner cylinder 21 and the outer cylinder 22. The upper part of the gap 25 and the gap 26 between the partition tube 23 and the outer tube 22 are all covered with a top plate 27, and the lower part of the gap 24.25 is covered with a bottom plate 28.
is blocked by. The upper part of the partition tube 23 and the inner tube 2
Communication holes 29 and 30 that communicate the gaps 24, 25, and 26, respectively, are bored in the lower part of the tank 1, and the gaps 24 and the auxiliary water pump 62 are connected to each other.
It communicates with the inside of a through a communication hole 31. In the figure, 16 is a pressurized air supply pipe, 17 is a weight connected to the lower part of the liquid supply cylinder 67 by a continuous line 55, 87 is a water suction pipe, and 88 is a liquid supply pipe connected to the lower part of the water pump cylinder.

前記空気室20aは、揚水筒63の下部外側に所定間隔
をおいて遊嵌した内筒21と、その外側へ所定間隔をお
いて遊嵌した外筒22と、内筒21と外筒22との間に
嵌装した仕切筒23とよりなり、揚水筒63と内筒21
との間隙部24、内筒21と仕切筒23との間隙部25
、仕切筒23と外筒22との間隙部26の上部は何れも
頂板27で覆われ、前記間隙部24.25の下部は底板
28で閉塞されている。
The air chamber 20a includes an inner cylinder 21 that is loosely fitted to the outside of the lower part of the water pumping cylinder 63 at a predetermined interval, an outer cylinder 22 that is loosely fitted to the outside of the lower part at a predetermined interval, and an inner cylinder 21 and an outer cylinder 22. It consists of a partition tube 23 fitted between the water pumping tube 63 and the inner tube 21.
a gap 24 between the inner tube 21 and the partition tube 23; a gap 25 between the inner tube 21 and the partition tube 23;
The upper part of the gap 26 between the partition tube 23 and the outer cylinder 22 is covered with a top plate 27, and the lower part of the gap 24, 25 is closed with a bottom plate 28.

前記仕切筒23の上部及び内筒21の下部には、間隙2
4.25.26を夫々連通する連通孔29.30が穿設
され、間隙24と揚水筒63内とは連通孔31で連通さ
れている。前記間欠空気揚水装置59.60は揚水筒6
3の上部外側に固定した浮体66と、揚水筒62の下部
に吊下さた重錘17とによって第6図々示のように水中
へ垂直に保たれる。
A gap 2 is provided at the upper part of the partition cylinder 23 and the lower part of the inner cylinder 21.
Communication holes 29 and 30 are bored to communicate with each other, and the gap 24 and the inside of the water pumping cylinder 63 are communicated with each other through a communication hole 31. The intermittent air pumping device 59,60 is a pumping cylinder 6.
The floating body 66 fixed to the outside of the upper part of the water pump 3 and the weight 17 suspended from the lower part of the water lifting tube 62 keep it vertically underwater as shown in FIG.

前記補助揚水筒62aの下端には、給液筒67が連結さ
れ、給液筒67の下部外側に給液環68が設置され、該
給液環68は多数の給液孔69により給液筒67内と連
通している。従って給液環68へ送水管8により矢示7
0のように送られたアルカリ高濃度水は第9図中、矢示
71のように給液筒67内に入り、矢示80のように吸
入される揚水と共に上昇する。
A liquid supply cylinder 67 is connected to the lower end of the auxiliary water pump 62a, and a liquid supply ring 68 is installed on the outside of the lower part of the liquid supply cylinder 67. It communicates with 67. Therefore, the water supply pipe 8 is connected to the liquid supply ring 68 as shown by the arrow 7.
The highly concentrated alkaline water sent as shown in FIG. 9 enters the liquid supply cylinder 67 as shown by arrow 71 in FIG.

前記実施例において、第9図の給気管16から矢示33
のように加圧空気を空気室20に供給すると、加圧空気
は空気室20の上部内側より逐次溜り、その水位が鎖線
72のように連通孔30に達すると、空気室20内の加
圧空気は、矢示35.36.37のように各連通孔29
.30.31を通過して補助揚水筒62a内へ入り、気
泡38となって矢示43のように上昇する。この気泡3
8は揚水筒63の下端閉塞板73に衝突し、分離材65
a、65bによって気水分離し、空気は第10図中矢示
74のように上昇して、空気室20aの頂部に溜り、つ
いで逐次水位を押し下げる。このようにして水位が鎖線
75のように連通孔3゜に達すると、空気室内の空気は
矢示35.36.37のように各連通孔29.30.3
1を通過して揚水筒63内に入り、気泡38aとなって
、矢示76のように上昇し、揚水筒63の上方へ吹き出
され、上方の水と混合した後、矢示77.78.79.
80のように循環流動する。
In the embodiment, from the air supply pipe 16 to the arrow 33 in FIG.
When pressurized air is supplied to the air chamber 20 as shown in FIG. Air flows through each communication hole 29 as shown by arrows 35, 36, and 37.
.. 30.31 and enters the auxiliary pumping cylinder 62a, becomes a bubble 38, and rises as shown by an arrow 43. This bubble 3
8 collides with the lower end closing plate 73 of the water pump 63, and the separating member 65
A and 65b separate air and water, and the air rises as indicated by the arrow 74 in FIG. 10, accumulates at the top of the air chamber 20a, and then gradually lowers the water level. In this way, when the water level reaches 3 degrees of the communication hole as shown by the chain line 75, the air in the air chamber flows through each communication hole 29, 30, 3 as shown by the arrows 35, 36, 37.
1, enters the water pumping tube 63, becomes bubbles 38a, rises as shown by the arrow 76, is blown out above the water pumping tube 63, mixes with the water above, and then becomes a bubble 38a as shown by the arrows 77, 78. 79.
Circulating flow like 80.

一方、分離材65a、65bで分離された水は、その近
辺の水と混合し、矢示81.82.83.84のように
分離材61付近から水底にかけて循環流動することにな
る。
On the other hand, the water separated by the separation materials 65a and 65b mixes with water in the vicinity and circulates from the vicinity of the separation material 61 to the bottom of the water as shown by arrows 81, 82, 83, and 84.

前記実施例によれば、間欠空気揚水装置59によって深
層の水質を改善1−1間欠空気揚水装置60によって浅
層の水質を改善することができる。
According to the embodiment, the intermittent air pumping device 59 can improve the water quality in the deep layer 1-1 The intermittent air pumping device 60 can improve the water quality in the shallow layer.

通常水深の大きいダム、湖、沼等においては、深層と浅
層の水量が著しく異なるので、アルカリ高濃度水の供給
に際し、水量に応じ浅層側を多くし、深層側を少なくす
れば、合理的かつ早急に水質を改善することができる。
Normally, in dams, lakes, ponds, etc. with large water depths, the amount of water in the deep and shallow layers is significantly different, so when supplying highly concentrated alkaline water, it would be reasonable to increase the amount of water in the shallow layer and decrease the amount in the deep layer depending on the amount of water. Water quality can be improved quickly and efficiently.

(実施例4) 第11図に示す実施例は、上下の間欠空気揚水装置59
.60を夫々独立した空気室から加圧空気を放出できる
ようにしたものである。
(Embodiment 4) The embodiment shown in FIG.
.. 60 is configured such that pressurized air can be released from independent air chambers.

即ち、下部の揚水筒62と上部の揚水筒63との夫々の
下方に同一構造の空気室20,20を設置し、下部の揚
水筒62の上端に複数の支杆79を介し案内板85を支
持し、案内板85の上部へ脚杆86を立設して上部の揚
水筒63の下端に連設した給液筒67を支承したもので
ある。従って上下の対流は案内板85を境として行われ
るが、混合水の拡散循環は総て実施例3と同一であるか
ら、これについての説明を省略した。各部の符号中、実
施例3と同一構造のものは同一符号とした。
That is, air chambers 20, 20 of the same structure are installed below the lower water pumping tube 62 and the upper water pumping tube 63, respectively, and the guide plate 85 is connected to the upper end of the lower water pumping tube 62 via a plurality of support rods 79. A leg rod 86 is erected on the upper part of the guide plate 85 to support a liquid supply cylinder 67 connected to the lower end of the upper water pump cylinder 63. Therefore, the vertical convection is performed using the guide plate 85 as a boundary, but the diffusion and circulation of the mixed water is all the same as in Example 3, so the explanation thereof is omitted. Among the reference numerals of each part, those having the same structure as those in Example 3 are given the same reference numerals.

前記実施例3.4は何れも単一揚水筒よりなる間欠空気
揚水装置を用いたが、実施例1のように複合揚水筒にす
ることもできる。また、二段以上四段位の多段にするこ
ともできる。
In Examples 3 and 4, an intermittent air pumping device consisting of a single pumping tube was used, but it is also possible to use a composite pumping tube as in Example 1. It is also possible to have multiple stages of two to four stages.

(発明の効果) この発明は消石灰を水に溶解し、又は揚水の拡散時に消
石灰を溶解して高濃度としたものを被処理水に拡散混合
するので、混合がきわめて容易であって、急速に均一濃
度(例えばPH7前後)になる効果がある。このように
消石灰によるPH調整により、上水における鉄管などの
腐蝕を防止する効果がある。
(Effect of the invention) This invention dissolves slaked lime in water, or diffuses and mixes slaked lime in high concentration during the diffusion of pumped water into the water to be treated, so mixing is extremely easy and rapid. It has the effect of achieving a uniform concentration (for example, around pH 7). In this way, pH adjustment using slaked lime has the effect of preventing corrosion of iron pipes and the like in tap water.

また、溶解したカルシウムは、溶存燐などと結合して不
溶性となり沈澱するので、可溶性燐が著しく減少し、富
栄養化を改善する効果がある。
Furthermore, dissolved calcium combines with dissolved phosphorus and the like to become insoluble and precipitate, resulting in a significant decrease in soluble phosphorus, which has the effect of improving eutrophication.

更に、酸性雨などによって、魚類の生息困難な池、湖沼
等の水質を改善することもできる効果がある。
Furthermore, it has the effect of improving the water quality of ponds, lakes, and marshes where it is difficult for fish to live due to acid rain.

また、水深の大きいダム、湖等にあっては、上層のみ、
或いは上層と深層を個別処理することにより、水質改善
効率を向上し、合理化することができる効果がある。
In addition, in dams, lakes, etc. with large water depths, only the upper layer
Alternatively, by treating the upper layer and the deeper layer separately, the water quality improvement efficiency can be improved and streamlined.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明の実施例のフロー図、第2図は同じく
間欠空気揚水装置の一部を切断した拡大正面図、第3図
は同じく平面図、第4図は同じく設置状態の図、第5図
は同じく他の実施例の設置状態の図、第6図は他の実施
例の設置状態を示す図、第7図は同じく二段式間欠空気
揚水装置の一部を省略した一部断面した拡大図、第8図
は同じく上下連結部の一部断面拡大図、第9図は同じく
下部の空気室の断面拡大図、第10図は同じく上部の空
気室の断面拡大図、第11図は他の実施例の一部を省略
した拡大図である。 1・・・溶解槽  2・・・消石灰  3・・・給水管
4・・・ポンプ  5・・・バルブ  6・・・移送管
7・・・溶液タンク    8・・・送水管9・・・間
欠空気揚水装置 10・・・吸水筒11・・・ポンプ 
12.13.14.15・・・矢示17・・・重!  
 18・・・揚水筒  19・・・覆板20・・・空気
室 21・・・内筒   22・・・外筒23・・・仕
切筒 24.25.26・・・間隙部27・・・頂板 
 28・・・底板
FIG. 1 is a flow diagram of an embodiment of the present invention, FIG. 2 is an enlarged front view with a part of the intermittent air pumping device cut away, FIG. 3 is a plan view, and FIG. 4 is a diagram of the installed state. FIG. 5 is a diagram showing the installation state of another embodiment, FIG. 6 is a diagram showing the installation state of another embodiment, and FIG. 7 is a partially omitted part of the two-stage intermittent air pumping device. 8 is an enlarged partial cross-sectional view of the upper and lower connecting portions, FIG. 9 is an enlarged cross-sectional view of the lower air chamber, FIG. 10 is an enlarged cross-sectional view of the upper air chamber, and FIG. 11 is an enlarged cross-sectional view of the upper air chamber. The figure is an enlarged view of another embodiment with some parts omitted. 1...Dissolution tank 2...Slaked lime 3...Water supply pipe 4...Pump 5...Valve 6...Transfer pipe 7...Solution tank 8...Water pipe 9...Intermittent Air pumping device 10... Water suction tube 11... Pump
12.13.14.15...Arrow 17...Heavy!
18... Lifting tube 19... Cover plate 20... Air chamber 21... Inner tube 22... Outer tube 23... Partition tube 24.25.26... Gap portion 27... top plate
28...Bottom plate

Claims (1)

【特許請求の範囲】 1 アルカリ高濃度水を間欠空気揚水装置による揚水に
注入し、該揚水の拡散循環に伴って大量水のPHを調整
することを特徴とした水質改善方法 2 消石灰を溶解させたアルカリ高濃度水を間欠空気揚
水装置による揚水に注入し、該揚水の拡散循環に伴って
処理水中にカルシウム燐化合物を生成すると共に、PH
を調整することを特徴とした水質改善方法 3 消石灰を入れた溶解槽に水を注入し、溶解槽からカ
ルシウムを溶解したアルカリ水を取り出し、このアルカ
リ水を揚水筒の揚水中に注入することにより大量水のP
Hを調整することを特徴とした請求項1又は2記載の水
質改善方法 4 消石灰を溶解させた水を多段の間欠空気揚水装置に
よる揚水中に注入し、該揚水の拡散循環に伴って大量水
の全部又は一部のPHを調整することを特徴とした水質
改善方法 5 大量水は、浅層・深層の何れか一方又は両方のPH
を調整することを特徴とした請求項4記載の水質改善方
法 6 間欠空気揚水装置による揚水噴出域内へ消石灰を配
置し、前記揚水の流動時に、前記消石灰を溶解してこの
水を、前記揚水の拡散循環に伴って拡散させ大量水のP
Hを調整することを特徴とした水質改善方法 7 消石灰を入れる溶解槽の下部に、給水管の先端側を
連結し、溶解槽の上部に送水管の基端側を連結し、前記
送水管の先端側を間欠空気揚水装置の吸水筒に連結した
ことを特徴とする水質改善装置 8 消石灰を入れる溶解槽の下部に給水管の先端側を連
結し、溶解槽の上部に送水管の基端を連結し、前記送水
管の先端を多段間欠揚水装置の揚水筒の全部又は一部に
接続開口させたことを特徴とした水質改善装置 9 揚水筒の下部に、空気室を設置した間欠空気揚水装
置の揚水筒の上部であって、揚水拡散通路に消石灰を収
容する通水性容器を設けたことを特徴とする水質改善装
[Claims] 1. A water quality improvement method characterized by injecting highly concentrated alkaline water into water pumped by an intermittent air pumping device and adjusting the pH of a large amount of water as the pumped water diffuses and circulates. 2. Dissolving slaked lime. Highly concentrated alkaline water is injected into the water pumped by an intermittent air pumping device, and as the pumped water diffuses and circulates, calcium phosphorus compounds are generated in the treated water, and PH
Water quality improvement method 3 characterized by adjusting water quality. By injecting water into a dissolution tank containing slaked lime, taking out alkaline water in which calcium is dissolved from the dissolution tank, and injecting this alkaline water into the pumping water of the water pump. P of large amount of water
4. Water quality improvement method according to claim 1 or 2, characterized in that water in which slaked lime is dissolved is injected into the water pumped by a multi-stage intermittent air pumping device, and a large amount of water is produced as the pumped water diffuses and circulates. Water quality improvement method 5 characterized by adjusting the PH of all or part of a large amount of water.
6. Water quality improvement method according to claim 4, characterized in that slaked lime is arranged in a pumping water spouting area by an intermittent air pumping device, and when the pumped water flows, the slaked lime is dissolved and this water is added to the pumped water. A large amount of water P is diffused through diffusion circulation.
Water quality improvement method 7 characterized by adjusting H The tip side of the water supply pipe is connected to the lower part of the dissolution tank containing slaked lime, the base end side of the water supply pipe is connected to the upper part of the dissolution tank, and the water supply pipe is Water quality improvement device 8, characterized in that the tip side is connected to the water suction tube of an intermittent air pumping device. Water quality improvement device 9, characterized in that the tips of the water pipes are connected and opened to all or part of the water pumping tube of the multistage intermittent water pumping device.Intermittent air pumping device in which an air chamber is installed in the lower part of the water pumping tube. A water quality improvement device characterized in that a water-permeable container for accommodating slaked lime is provided in the upper part of the water pumping cylinder in the pumping water diffusion passage.
JP26115689A 1989-08-03 1989-10-05 Method and apparatus for improving quality of water Pending JPH03123692A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP26115689A JPH03123692A (en) 1989-10-05 1989-10-05 Method and apparatus for improving quality of water
FI900048A FI900048A (en) 1989-08-03 1990-01-04 FOERFARANDE FOER FAERBAETTRING AV VATTENBESKAFFENHET.
CA 2007615 CA2007615A1 (en) 1989-08-03 1990-01-11 Method of improving the quality of large amount of water and the quantity of dissolved oxygen therein, and apparatus for said improvement
DK28490A DK28490A (en) 1989-08-03 1990-02-02 PROCEDURE FOR IMPROVING THE QUALITY OF LARGE WATER QUANTITY AND THE QUANTITY OF DISSOLVED OXYGEN THEREOF AND APPARATUS FOR USE
SE9001291A SE9001291L (en) 1989-08-03 1990-04-09 PROCEDURE AND DEVICE FOR IMPROVING THE QUALITY OF A HIGH QUANTITY OF WATER AND QUANTITY OF LOST ACID THEREOF
US07/782,381 US5227056A (en) 1989-08-03 1991-10-24 Apparatus for improving the quality of a large amount of water and the quantity of dissolved oxygen therein
US07/798,838 US5256309A (en) 1989-08-03 1991-11-25 Method of improving the quality of large amount of water, and quantity of dissolved oxygen therein

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26115689A JPH03123692A (en) 1989-10-05 1989-10-05 Method and apparatus for improving quality of water

Publications (1)

Publication Number Publication Date
JPH03123692A true JPH03123692A (en) 1991-05-27

Family

ID=17357888

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26115689A Pending JPH03123692A (en) 1989-08-03 1989-10-05 Method and apparatus for improving quality of water

Country Status (1)

Country Link
JP (1) JPH03123692A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010042982A1 (en) * 2008-10-14 2010-04-22 Armtech Holdings Pty Ltd Treatment of water containing dissolved mineral species

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010042982A1 (en) * 2008-10-14 2010-04-22 Armtech Holdings Pty Ltd Treatment of water containing dissolved mineral species

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