JPH03116660A - Cooling device of seat for monitor inside fuel reformer - Google Patents

Cooling device of seat for monitor inside fuel reformer

Info

Publication number
JPH03116660A
JPH03116660A JP1252117A JP25211789A JPH03116660A JP H03116660 A JPH03116660 A JP H03116660A JP 1252117 A JP1252117 A JP 1252117A JP 25211789 A JP25211789 A JP 25211789A JP H03116660 A JPH03116660 A JP H03116660A
Authority
JP
Japan
Prior art keywords
reformer
air
seat
cooling
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1252117A
Other languages
Japanese (ja)
Inventor
Kazuyuki Matsuzawa
松沢 和幸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP1252117A priority Critical patent/JPH03116660A/en
Publication of JPH03116660A publication Critical patent/JPH03116660A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

PURPOSE:To cool a seat for monitor inside the reformer by means of low operation cost and an equipment of a simple construction by supplying air of each system being supplied to a fuel battery generation device, or a part of exhaust gas from the fuel battery and a reformer burner, to the seat for the inside monitor through a cooler. CONSTITUTION:Air 9a for cooling a seat 17 for an inside monitor is branched in the middle of a pipeline of air 9 for a reformer burner. On the pipe line of air 9a for cooling, a cooler 29 which cools air 9 for the reformer burner having a high temperature to the temperature appropriate for cooling the seat 17 for the inside monitor, and a mist separator 20 for removing moisture which condenses accompanying a drop of air temperature, are provided. A pipe line of nitrogen gas 18 for cooling as a backup is also connected, together with a pipe line of this cooling air 9a, to the seat 17 for the inside monitor. A part of the air 9 for the reformer burner therefore can be used for cooling the seat 17 for the inside, thus remarkably reducing the nitrogen gas 18 amount to be used for cooling.

Description

【発明の詳細な説明】 [発明の目的] (産業上の利用分野) 本発明は燃料電池発電装置の燃料改質系に設置される燃
料改質器内部監視用座の冷却装置に関するものである。
[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) The present invention relates to a cooling device for a monitoring seat inside a fuel reformer installed in a fuel reforming system of a fuel cell power generation device. .

(、従来の技術) 近年、実用化が進んでいる燃料電池発電装置は、水素等
の燃料の有しているエネルギーを、燃料電池内で生じる
電気化学反応により、直接電気エネルギーに変換するも
のであり、上記燃料と空気等の酸化剤が燃料電池に供給
されている限り、高い変換効率で電気エネルギーを取り
出すことができるものである。
(, Prior Art) Fuel cell power generation devices, which have been put into practical use in recent years, directly convert the energy contained in fuels such as hydrogen into electrical energy through an electrochemical reaction that occurs within the fuel cell. As long as the fuel and the oxidizing agent such as air are supplied to the fuel cell, electrical energy can be extracted with high conversion efficiency.

また、この種の燃料電池発電装置においては、メタン等
の原料ガスを水蒸気改質することによって、燃料電池用
の燃料としての水素ガスを得るために、燃料改質系を備
えることが多い。この様な燃料改質系の改質器において
は、内部に改質反応触媒層が設けられた改質反応管の内
側に、原料ガスライン及び水蒸気ラインを通して供給さ
れるメタン等の原料ガス及び水蒸気の混合ガスを導入し
、且つ、」二記改質反応管の外側に燃焼室での燃焼で得
られた高温の加熱ガスを通過させることにより、上記原
料ガスを水素リッチな改質ガスに改質し、さらに、−酸
化炭素変成器を経て、より水素濃度の高い改質ガスとし
た上で、負荷としての燃料電池へ供給するようにしてい
る。
Further, this type of fuel cell power generation device is often equipped with a fuel reforming system in order to obtain hydrogen gas as a fuel for the fuel cell by steam reforming a raw material gas such as methane. In such a fuel reforming system reformer, raw material gas such as methane and steam are supplied through a raw material gas line and a steam line to the inside of a reforming reaction tube in which a reforming reaction catalyst layer is provided. The raw material gas is reformed into a hydrogen-rich reformed gas by introducing a mixed gas of The reformed gas is then passed through a -carbon oxide shift converter to form a reformed gas with a higher hydrogen concentration, which is then supplied to a fuel cell as a load.

ところで、上記のような燃料電池発電装置の一例を第3
図により説明する。即ち、燃料改質器1内には、ここに
供給された炭化水素系燃料2を、水蒸気改質反応によっ
て水素リッチな改質ガス3とするための触媒を充填した
改質管4が設けれている。この改質管4は、燃料電池1
3に内蔵された燃料電池燃料極5に送られて発電に利用
され、その残留水素6は燃料電池13から改質器バーナ
10に送られ燃料として使用される。一方、燃料電池1
3で発電に必要とされる酸素は、外気をターボコンプレ
ッサ7で昇圧して、燃料電池13の空気極15に供給さ
れる。残留酸素を含む空気極15からの出口ガス16は
、改質器バーナ10の燃焼空気として利用される。また
、ターボコンプレッサ7で昇圧された空気の一部は、燃
料電池13側へ伸びる配管から分岐され、改質器バーナ
用空気つとして改質器バーナ10に送られる。この改質
器バーナ10の燃焼ガスの一部は、ブロア12により昇
圧されて燃料電池13に送られ、電池容器14のパージ
ガスとして用いられる。
By the way, an example of the above-mentioned fuel cell power generation device is shown in the third example.
This will be explained using figures. That is, in the fuel reformer 1, there is provided a reforming tube 4 filled with a catalyst for converting the hydrocarbon fuel 2 supplied therein into a hydrogen-rich reformed gas 3 through a steam reforming reaction. ing. This reforming pipe 4 is connected to the fuel cell 1
The remaining hydrogen 6 is sent to the fuel electrode 5 of the fuel cell built in the fuel cell 13 and used for power generation, and the residual hydrogen 6 is sent from the fuel cell 13 to the reformer burner 10 and used as fuel. On the other hand, fuel cell 1
In step 3, oxygen required for power generation is supplied to the air electrode 15 of the fuel cell 13 by boosting the pressure of outside air using the turbo compressor 7. The outlet gas 16 from the air electrode 15 containing residual oxygen is utilized as combustion air for the reformer burner 10. Further, a part of the air pressurized by the turbo compressor 7 is branched from a pipe extending toward the fuel cell 13 side, and is sent to the reformer burner 10 as reformer burner air. A part of the combustion gas from the reformer burner 10 is pressurized by the blower 12 and sent to the fuel cell 13, where it is used as purge gas for the cell container 14.

この燃料改質器1には、燃焼状態監視用およびガス分析
用の座17が数冊設置されているが、運転中および停止
過程中に高温に晒されるため、計器および座の保護のた
め座17を冷却する必要がある。この座17の冷却手段
として、従来の装置では、別途用意した窒素ガス18を
座17部分に供給していた。
This fuel reformer 1 is equipped with several seats 17 for combustion status monitoring and gas analysis, but since they are exposed to high temperatures during operation and shutdown, the seats 17 are used to protect the instruments and seats. 17 needs to be cooled down. As a cooling means for the seat 17, in the conventional device, nitrogen gas 18 prepared separately was supplied to the seat 17 portion.

(発明が解決しようとする課題) 」二記のように従来の燃料改質器の内部監視用座の冷却
装置は、冷却用ガスとして空気や燃焼排ガスに比べると
入手が困難な窒素ガスを単独で使用していたため、運転
コストが高いという欠点があった。特に、燃料電池発電
装置の大容量化に伴い窒素ガスの使用量も多くなり、I
OMW級の装置では200〜500 K g / hに
も達し、運転コストが非常に高くなる」二に、窒素ガス
供給設備が大型する問題もあった。
(Problems to be Solved by the Invention) As mentioned in Section 2, the conventional cooling device for the internal monitoring seat of a fuel reformer uses nitrogen gas, which is difficult to obtain compared to air or combustion exhaust gas, as a cooling gas. The disadvantage was that the operating costs were high. In particular, as the capacity of fuel cell power generation equipment increases, the amount of nitrogen gas used increases,
OMW class equipment reaches 200 to 500 Kg/h, making the operating cost extremely high.''Secondly, there was also the problem of the large size of the nitrogen gas supply equipment.

本発明は、上記のような従来技術の問題点を解決し、簡
単な構成で、運転コストが低く、しかも窒素ガスを単独
で使用した場合と同様な信頼性にも優れた燃料改質器内
部監視用座の冷却装置を提供することを目的とする。
The present invention solves the problems of the prior art as described above, and provides a fuel reformer internal structure that has a simple configuration, low operating costs, and has excellent reliability comparable to when nitrogen gas is used alone. The object of the present invention is to provide a cooling device for a monitoring seat.

[発明の構成コ (課題を解決するための手段) 上記の目的を達成するために、本発明の燃料改質器内部
監視用座の冷却装置は、燃料電池発電装置に供給されて
いる各系統の空気、あるいは燃料電池装置や改質器バー
ナからの排ガスの一部を、冷却器を介して内部監視用座
に供給し、これを冷却するように構成したものである。
[Configuration of the Invention (Means for Solving the Problems)] In order to achieve the above object, the cooling device for the internal monitoring seat of the fuel reformer of the present invention has the following features: The system is configured to supply the air or a part of the exhaust gas from the fuel cell device or the reformer burner to the internal monitoring seat via a cooler to cool it.

(作用) 上記のような構成を有する本発明においては、空気や排
ガスのように入手が容易か、あるいは廃棄されていた低
コストのガスを利用して内部監視用座を冷却することが
できる。また、専用の冷却ガス供給設備を設けることな
く、燃料電池発電装置に必要とされる空気あるいは排ガ
ス用の配管を分岐し、これを内部監視用座に送込むだけ
で良いので、冷却装置の構造も単純化される。
(Function) In the present invention having the above-described configuration, the internal monitoring seat can be cooled using easily available or discarded low-cost gas such as air or exhaust gas. In addition, there is no need to install dedicated cooling gas supply equipment, and the structure of the cooling system can be improved by simply branching off the air or exhaust gas piping required for the fuel cell power generation system and sending it to the internal monitoring seat. is also simplified.

(実施例) 以下、本発明の一実施例を第1図及び第2図に従って具
体的に説明する。なお、第3図の従来技術と同一の部材
については、同一の符号を付し、説明は省略する。
(Example) Hereinafter, an example of the present invention will be specifically described with reference to FIGS. 1 and 2. Note that the same members as those in the prior art shown in FIG. 3 are designated by the same reference numerals, and explanations thereof will be omitted.

第1図において、ターボコンプレッサ7によって昇圧さ
れた空気8の一部は、燃料電池13側の配管の途中から
分岐され、改質器バーナ用空気9として改質器バーナ1
0に送られている。この改質器バーナ用空気9の配管の
途中から内部監視月産17の冷却用空気9aが分岐され
ている。この冷却用空気9aの配管上には、温度の高い
改質器バーナ用空気9を内部監視月産17を冷却するの
に適した温度にまで冷却する冷却器19と、空気温度低
下に伴って凝縮する水分を除去するためのミストセパレ
ータ20とが設けられている。また、内部監視月産17
には、この冷却空気9aの配管と共に、バックアップ用
として冷却用の窒素ガス18の配管も接続されてる。
In FIG. 1, a part of the air 8 pressurized by the turbo compressor 7 is branched from the middle of the pipe on the fuel cell 13 side, and is used as reformer burner air 9 for the reformer burner 1.
It is being sent to 0. Cooling air 9a for internal monitoring monthly production 17 is branched off from the middle of the piping for this reformer burner air 9. On the piping of this cooling air 9a, there is a cooler 19 that cools the high-temperature reformer burner air 9 to a temperature suitable for cooling the internal monitoring unit 17, and a cooler 19 that cools the high-temperature reformer burner air 9 to a temperature suitable for cooling the internal monitoring unit 17. A mist separator 20 is provided to remove condensed moisture. In addition, internal monitoring monthly production of 17
In addition to the cooling air 9a piping, a cooling nitrogen gas 18 piping is also connected as a backup.

この様な構成を有する本実施例においては、外気を昇圧
して成る改質器バーナ用空気の一部を内部監視月産の冷
却用として使用し、高価な窒素ガス18はバックアップ
用として使用されるだけであり、窒素ガス単独で内部監
視月産を冷却する場合に比較して、冷却のために使用す
る窒素ガス量を格段に低減することができる。特に、元
になる外気は無尽蔵であり、燃料電池発電装置が大容量
化し冷却能力の増大が望まれる場合であっても、ターボ
コンプレッサの能力や配管の送風容量を増大させるだけ
で容易に対応でき、窒素ガスの様にガス供給設備の大型
化の必要もない。
In this embodiment having such a configuration, a part of the reformer burner air made by pressurizing the outside air is used for cooling the internal monitoring monthly production, and the expensive nitrogen gas 18 is used for backup. Compared to the case where the internally monitored monthly production is cooled using nitrogen gas alone, the amount of nitrogen gas used for cooling can be significantly reduced. In particular, the source of outside air is inexhaustible, so even if the capacity of a fuel cell power generation device increases and an increase in cooling capacity is desired, this can be easily achieved by simply increasing the capacity of the turbo compressor or the air blowing capacity of the piping. Unlike nitrogen gas, there is no need to increase the size of gas supply equipment.

(他の実施例) 本発明は、上記の実施例に限定されるものではなく、内
部監視月産冷却用空気としては、改質器バーナ用空気の
一部を分岐する以外に、燃料電池発電装置に使用される
他の空気系統、例えば計装制御用の空気の一部を利用す
ることも可能である。
(Other Embodiments) The present invention is not limited to the above-mentioned embodiments.In addition to branching off a part of the air for the reformer burner, the air for internally monitored monthly cooling may be used for fuel cell power generation. It is also possible to utilize other air systems used in the device, for example a portion of the air for instrumentation control.

また、第2図の様に空気以外に、改質器バーナ燃焼ガス
の様な排ガスを使用することもできる。
Moreover, as shown in FIG. 2, exhaust gas such as reformer burner combustion gas can also be used in addition to air.

即ち、第2図の実施例においては、燃料改質器1から排
出され電池容器13のパージガスとして使用される改質
器バーナ燃焼ガス11の配管を、ブロア12の後段で分
岐して冷却用ガスllaを取り出し、これを冷却器19
およびミストセパレータ20を介して改質器内部監視用
座17に送り込んでいる。この実施例においては、前記
実施例の空気と同様に排ガスとして廃棄される安価なガ
スを使用して改質器内部監視用座17の冷却を行うこと
ができるので、窒素ガスを使用した従来の冷却装置に比
較して運転コストを大幅に低減できる。
That is, in the embodiment shown in FIG. 2, the piping for the reformer burner combustion gas 11 discharged from the fuel reformer 1 and used as purge gas for the battery container 13 is branched after the blower 12 to supply the cooling gas. Take out the lla and put it in the cooler 19.
It is then fed into the reformer internal monitoring seat 17 via the mist separator 20. In this embodiment, the reformer internal monitoring seat 17 can be cooled using an inexpensive gas that is discarded as exhaust gas, similar to the air in the previous embodiment, so that it is possible to cool the reformer internal monitoring seat 17 instead of the conventional Operating costs can be significantly reduced compared to cooling equipment.

また、大型の窒素ガス供給設備も不要であり、冷却用に
分岐する配管や冷却器19などの簡単な装置を付加する
だけで良いので、設備的にも優れている。さらに、本実
施例では、外気に比べて酸素濃度が低い燃焼ガスの一部
を冷却用に使用するので、窒素ガスを使用した場合と同
様に高い安全性を確保できる利点もある。
In addition, there is no need for large nitrogen gas supply equipment, and it is sufficient to add simple devices such as branch piping and a cooler 19 for cooling, which is excellent in terms of equipment. Furthermore, in this embodiment, since a part of the combustion gas having a lower oxygen concentration than the outside air is used for cooling, there is an advantage that high safety can be ensured as in the case where nitrogen gas is used.

また、図示の実施例のように窒素ガスによるバックアッ
プ系統を併設した場合には、運転時の信頼性もより向上
される利点がある。
Further, when a backup system using nitrogen gas is provided as in the illustrated embodiment, there is an advantage that reliability during operation is further improved.

[発明の効果] 以上説明したとおり、本発明によれば、燃料電池発電装
置に使用される各系統の空気あるいは排ガスを使用して
改質器内部監視用座を冷却するようにしたので、紙庫な
運転コストと簡単な構造の設備で、改質器内部監視用座
の冷却を行うことのできる冷却装置を提供することがで
きる。
[Effects of the Invention] As explained above, according to the present invention, since the reformer internal monitoring seat is cooled using the air or exhaust gas from each system used in the fuel cell power generation device, the paper It is possible to provide a cooling device that can cool a monitoring seat inside a reformer with low operating costs and equipment with a simple structure.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の改質器内部監視用座の冷却装置の第1
実施例を備えた燃料電池発電装置の構成を示すシステム
系統図、第2図は本発明の第2実施例を示すシステム系
統図、第3図は従来の燃料電池発電装置における冷却装
置の構成を示すシステム系統図である。 1・・・燃料改質器、2・・・炭化水素系燃料、3・・
・改質ガス、4・・・改質管、5・・・燃料電池燃料極
、6・・・燃料極出口ガス、7・・・ターボコンプレッ
サ、8・・・昇圧空気、9・・・改質器バーナ用空気、
9a・・・冷却用空気、10・・・改質器バーナ、11
・・・改質器バーナ燃焼ガス、11a・・・冷却用ガス
、12・・・ブロア、13・・・燃料電池、14・・・
電池容器、15・・・燃料電池空気極、16・・・空気
極出口ガス、17・・・改質器内部監視用座、18・・
・窒素ガス、19・・・冷却器、20・・・ミストセパ
レータ。
FIG. 1 shows the first cooling device for the monitoring seat inside the reformer of the present invention.
FIG. 2 is a system diagram showing the configuration of a fuel cell power generation device equipped with an embodiment. FIG. 2 is a system diagram showing a second embodiment of the present invention. FIG. 3 is a system diagram showing the configuration of a cooling device in a conventional fuel cell power generation device FIG. 1...Fuel reformer, 2...Hydrocarbon fuel, 3...
- Reformed gas, 4... Reforming tube, 5... Fuel cell fuel electrode, 6... Fuel electrode outlet gas, 7... Turbo compressor, 8... Boosting air, 9... Reforming Air for quality equipment burner,
9a... Cooling air, 10... Reformer burner, 11
...Reformer burner combustion gas, 11a... Cooling gas, 12... Blower, 13... Fuel cell, 14...
Battery container, 15...Fuel cell air electrode, 16...Air electrode outlet gas, 17...Reformer internal monitoring seat, 18...
・Nitrogen gas, 19... Cooler, 20... Mist separator.

Claims (2)

【特許請求の範囲】[Claims] (1)燃料電池と、この燃料電池に水素リッチな改質ガ
スを供給する燃料改質器とを有し、 前記燃料改質器には、炭化水素燃料を水蒸気改質反応に
よって水素リッチな改質ガスとする触媒を内部に充填し
た改質管と、改質管の周囲に水蒸気改質反応に必要とな
る反応熱を供給するための改質器バーナと、この燃焼室
内の状況を監視するための座が設けられ、 前記改質器バーナには昇圧された空気が改質器バーナ用
空気として供給されると共に、改質器からの燃焼排ガス
を燃料電池容器のパージガスとして使用して成る燃料電
池発電装置において、燃料電池発電装置に供給されてい
る各系統の空気、あるいは燃料電池や改質器バーナから
の排ガスの一部を、冷却器を介して内部監視用座に供給
し、これを冷却するように構成したことを特徴とする燃
料改質器内部監視用座の冷却装置。
(1) It has a fuel cell and a fuel reformer that supplies a hydrogen-rich reformed gas to the fuel cell, and the fuel reformer includes a hydrogen-rich reformer that converts hydrocarbon fuel into a hydrogen-rich reformed gas through a steam reforming reaction. The system monitors the reformer tube, which is filled with a catalyst to produce a quality gas, the reformer burner, which supplies the reaction heat necessary for the steam reforming reaction around the reformer tube, and the situation inside this combustion chamber. A seat is provided for the reformer burner, pressurized air is supplied to the reformer burner as air for the reformer burner, and combustion exhaust gas from the reformer is used as a purge gas for the fuel cell container. In a battery power generation system, air from each system supplied to the fuel cell power generation system, or a portion of the exhaust gas from the fuel cell or reformer burner, is supplied to the internal monitoring seat via a cooler. A cooling device for a monitoring seat inside a fuel reformer, characterized in that it is configured to cool the inside of a fuel reformer.
(2)内部監視用座に、バックアップ用の窒素ガスが供
給されている請求項第1項記載の燃料改質器内部監視用
座の冷却装置。
(2) A cooling device for an internal monitoring seat of a fuel reformer according to claim 1, wherein nitrogen gas for backup is supplied to the internal monitoring seat.
JP1252117A 1989-09-29 1989-09-29 Cooling device of seat for monitor inside fuel reformer Pending JPH03116660A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1252117A JPH03116660A (en) 1989-09-29 1989-09-29 Cooling device of seat for monitor inside fuel reformer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1252117A JPH03116660A (en) 1989-09-29 1989-09-29 Cooling device of seat for monitor inside fuel reformer

Publications (1)

Publication Number Publication Date
JPH03116660A true JPH03116660A (en) 1991-05-17

Family

ID=17232711

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1252117A Pending JPH03116660A (en) 1989-09-29 1989-09-29 Cooling device of seat for monitor inside fuel reformer

Country Status (1)

Country Link
JP (1) JPH03116660A (en)

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