JPH03104700A - Transfer print - Google Patents

Transfer print

Info

Publication number
JPH03104700A
JPH03104700A JP24160589A JP24160589A JPH03104700A JP H03104700 A JPH03104700 A JP H03104700A JP 24160589 A JP24160589 A JP 24160589A JP 24160589 A JP24160589 A JP 24160589A JP H03104700 A JPH03104700 A JP H03104700A
Authority
JP
Japan
Prior art keywords
layer
transfer
adhesives
resin
adhesive layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP24160589A
Other languages
Japanese (ja)
Other versions
JP2920952B2 (en
Inventor
Tsuruo Nakayama
鶴雄 中山
Hidetoshi Kodama
英俊 小玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentel Co Ltd
Original Assignee
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pentel Co Ltd filed Critical Pentel Co Ltd
Priority to JP24160589A priority Critical patent/JP2920952B2/en
Publication of JPH03104700A publication Critical patent/JPH03104700A/en
Application granted granted Critical
Publication of JP2920952B2 publication Critical patent/JP2920952B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE:To mount a transfer printed layer on an inorganic base with excellent adhesive properties by interposing a hot-melt adhesive layer between the inorganic base and the transfer printed layer. CONSTITUTION:A transfer print is manufactured by interposing a hot melt adhesive layer 2 among an inorganic base 1, in which a plated layer is formed onto a metal such as zinc, nickel, etc., or an alloy thereof, glass or a resin base, and transfer printed layers 3. The adhesive layer 2 is shaped by coating the surface of the base 1 with hot-melt group adhesives and heating and drying the adhesives. Adhesives containing a resin melted by heating is used as the adhesives, and an epoxy resin, etc., is cited as the kind. Adhesives including a crosslinking type resin having excellent solvent resistance and heat resistance is favorable among them. The printed layer 3 is formed by heating and contact- bonding a transfer sheet. A mold release layer, a printed layer employing printing ink including a thermoplastic resin and an adhesive layer are shaped successively onto a film fundamentally. The coating 4 of an ultraviolet curing or thermosetting resin, etc., can be executed in order to impart durability, gloss or the like onto the printed layers 3.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、無Ia基材に転写印刷層を設けてなる転写印
刷品に関する. (従来の技術とその課題) 従来、装飾性の向」二や商品の表示などのため、樹脂成
形品に転写印刷層を設けた転写印刷品が知られている。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a transfer printed product comprising a transfer printing layer provided on an Ia-free base material. (Prior Art and its Problems) Conventionally, transfer printing products are known in which a transfer printing layer is provided on a resin molded product for decorative purposes or product display.

しかし,これらの転写印刷層を無機基材へ設けようとす
ると、無機基材への転写印刷層の接着性が悪く,無機基
材へ転写印刷層を設けてなる転写印刷品は実用化されて
いない。
However, when trying to provide these transfer printing layers on an inorganic substrate, the adhesion of the transfer printing layer to the inorganic substrate is poor, and transfer printing products made by providing a transfer printing layer on an inorganic substrate have not been put into practical use. .

(課題を解決するための手段) 本発明は、無機基材に転写印刷層を設けてなる転写印刷
品において,無機基材と転写印刷層の間にホットメルト
接着剤層を介在させたことを特徴とする転写印刷品を要
旨とする。
(Means for Solving the Problems) The present invention is characterized in that, in a transfer printed product in which a transfer printing layer is provided on an inorganic base material, a hot melt adhesive layer is interposed between the inorganic base material and the transfer printing layer. The gist is the transfer print product.

以下、本発明を添付第1図を基にして詳述する。Hereinafter, the present invention will be explained in detail with reference to the attached FIG. 1.

無機基材lとして、具体的には、亜鉛、銅、鉄、ニッケ
ル等の金属又はその合金、ガラス、セラミック、或いは
、樹脂基村上にめっき層を設けたものなどが挙げられる
. ホットメルト接着剤層2は、ホントメルト系接着剤を基
材l表面に塗布して、加熱乾燥して形成する。ホットメ
ルト系接着剤は、加熱によりW4融する樹脂を含有する
もので、その種類は、エポキシ系、ポリエステル系、ウ
レタン系などが挙げられる.中でも、耐溶剤性、耐熱性
に優れているものが好ましく、この点では架橋型のm脂
を含イfしたものが好ましい。更に、このようなホット
メルト系接着剤は、市販されているものをそのまま使っ
ても良いが、溶剤に溶解させることにより、均一に塗付
かし易く、筆記具のクリップ、軸筒などという小さい部
品にはより効果が高い。
Specific examples of the inorganic base material include metals such as zinc, copper, iron, and nickel, or alloys thereof, glass, ceramics, and those having a plating layer provided on a resin base. The hot melt adhesive layer 2 is formed by applying a true melt adhesive to the surface of the base material 1 and drying it by heating. Hot-melt adhesives contain resins that undergo W4 melting when heated, and include epoxy, polyester, and urethane adhesives. Among these, those having excellent solvent resistance and heat resistance are preferred, and in this respect, those containing crosslinked m fat are preferred. Furthermore, such hot-melt adhesives can be used as they are on the market, but by dissolving them in a solvent, they are easier to apply evenly and are suitable for small parts such as writing instrument clips and barrels. is more effective.

尚、適宜、必要に応じ、無機基材1とホシトメルト系接
着剤層2の間には、アクリル,メラミン、エポキシ、ポ
リエステル、ウレタン系のラジカル重合型の塗膜を形成
してもよい。
In addition, if necessary, a radical polymerization type coating film of acrylic, melamine, epoxy, polyester, or urethane type may be formed between the inorganic base material 1 and the photomelt adhesive layer 2.

転写印刷層3は、転写シートを加熱圧着して形成する。The transfer printing layer 3 is formed by heat-pressing a transfer sheet.

転写シー1〜は,基本的には,、フィルム」二に、離形
層、熱可塑性の樹脂を含む印刷インキを用いスクリーン
印刷、オフセット印刷により印刷した印刷層,接着層が
順次形威されてなる。尚,転写印刷N3J−.に、耐久
性或いは光沢などを付与するため、紫外線硬化型或いは
熱硬化型樹脂などよりなるコーティング4を実施できる
Basically, the transfer sheets 1 to 1 are formed by sequentially forming a release layer, a printing layer printed by screen printing or offset printing using a printing ink containing a thermoplastic resin, and an adhesive layer on a film 2. Become. In addition, transfer printing N3J-. In order to impart durability or gloss, a coating 4 made of ultraviolet curing or thermosetting resin can be applied.

(実施例) 大美可± 基材として真鍮板上に光沢ニッケルめっきを10μm、
光沢ニッケルめっき上にクロムめっきを0.2μm形或
し、乾燥後,エポキシ系ホットメルト系接着剤(S−1
0、東亜合或(株)!2)をスプレーにて5μm塗布し
て,130度℃、5分間乾燥して、ホットメルト系接着
剤層を設けた。
(Example) 10 μm bright nickel plating on a brass plate as a base material.
Apply 0.2 μm chromium plating on bright nickel plating or after drying, apply epoxy hot melt adhesive (S-1
0, Toa Goor Co., Ltd.! 2) was applied by spraying to a thickness of 5 μm and dried at 130° C. for 5 minutes to provide a hot melt adhesive layer.

次に、ポリエステルフィルム上に、離形層、スクリーン
印刷により形成した熱可塑性樹脂よりなる印刷層,接着
層を順次形成してなる転写シートを、ホットメルト接薯
剤が塗布された基村上に置き240度℃加熱したプレー
トによりシリコンゴムを介して圧着を3秒聞行ない、フ
ィルムを剥離して転写印刷層を形或した.次に、紫外線
硬化型樹脂よりなるコーティングを施して真鍮基材に転
写印刷層を設けてなる転写印刷品を得た。
Next, a transfer sheet, which is made by sequentially forming a release layer, a printing layer made of thermoplastic resin formed by screen printing, and an adhesive layer on a polyester film, is placed on the base layer coated with hot melt adhesive. The silicone rubber was pressed with a plate heated to 240°C for 3 seconds, and the film was peeled off to form a transfer printing layer. Next, a transfer print product was obtained in which a transfer print layer was provided on a brass base material by applying a coating made of an ultraviolet curable resin.

こうして得たものの密着性について、基盤面にカッター
にて1mm間隔にカットし、セロハンテーブを接着し、
その後,セロハンテーブを剥離することにより評価した
ところ、極めて良好な結果を示した。
To check the adhesion of the obtained product, cut it with a cutter at 1 mm intervals on the base surface, glue cellophane tape,
Thereafter, an evaluation was made by peeling off the cellophane tape, and very good results were shown.

大奥N要 実施例1と同様の金属基村上に、ニッケルめっきを10
μm形威し、乾燥後、アクリル系塗料(マジクロンMG
IOOO.関西ペイント(株)製)を塗布し、130度
℃、30分間乾燥した。次に、ウレタン系ホットメルト
系接着剤(PV8100、東亜合!Ij.(株)製)を
キシレンとメチルエチルケトンの1=1溶剤で3倍に希
釈した希釈液を、スプレーにて基村上に2〜3μm塗布
し、130度℃、5分間乾燥した。次に、ポリエステル
フィルム上に、離形層,オフセット印刷により形成した
熱可塑性樹脂よりなる印刷層、接着層を順次形成してな
る転写シートを、ホットメルト接着剤が塗布された基村
上に置き、240度℃加熱したプレートによりシリコン
ゴムを介して圧着を2秒間行ない、フィルムを剥離して
転写印刷磨を形威した。次に、紫外線硬化型樹脂よりな
るコーティングを施して真鍮基材に転写印刷層を設けて
なる転写印刷品を得た。
Nickel plating is applied to the same metal substrate Murakami as in Example 1.
After applying μm shape and drying, apply acrylic paint (Magicron MG).
IOOO. Kansai Paint Co., Ltd.) was applied and dried at 130 degrees Celsius for 30 minutes. Next, a diluted solution of urethane hot melt adhesive (PV8100, manufactured by Toago Ij. Co., Ltd.) diluted 3 times with a 1=1 solvent of xylene and methyl ethyl ketone was sprayed onto Motomura's upper surface. It was applied to a thickness of 3 μm and dried at 130° C. for 5 minutes. Next, a transfer sheet formed by sequentially forming a release layer, a printing layer made of a thermoplastic resin formed by offset printing, and an adhesive layer on a polyester film is placed on the base plate coated with hot melt adhesive, Pressure bonding was performed for 2 seconds through the silicone rubber using a plate heated to 240 degrees Celsius, and the film was peeled off to form a transfer printing polish. Next, a transfer print product was obtained in which a transfer print layer was provided on a brass base material by applying a coating made of an ultraviolet curable resin.

こうして得たものについて密着性の評価をしたところ、
実施例1同様に極めて良好な結果を示した。
When we evaluated the adhesion of the product obtained in this way,
Similar to Example 1, very good results were shown.

(発明の効果) 以上のように、本発明によれば、無機基材に接着性が優
れた転写印刷層を設けてなる転写印刷品たり得る.
(Effects of the Invention) As described above, according to the present invention, a transfer printed product can be obtained in which a transfer printing layer with excellent adhesiveness is provided on an inorganic base material.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一例を示す要部断面図。 1・・・基材、2・・・ホットメルト接着剤層、3 転
写印刷Jl.4・・・コーティング。
FIG. 1 is a sectional view of a main part showing an example of the present invention. 1...Base material, 2...Hot melt adhesive layer, 3 Transfer printing Jl. 4...Coating.

Claims (1)

【特許請求の範囲】[Claims]  無機基材に転写印刷層を設けてなる転写印刷品におい
て、無機基材と転写印刷層の間にホットメルト接着剤層
を介在させたことを特徴とする転写印刷品。
A transfer printed product comprising a transfer printing layer provided on an inorganic base material, characterized in that a hot melt adhesive layer is interposed between the inorganic base material and the transfer printing layer.
JP24160589A 1989-09-18 1989-09-18 Transfer printing products Expired - Lifetime JP2920952B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24160589A JP2920952B2 (en) 1989-09-18 1989-09-18 Transfer printing products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24160589A JP2920952B2 (en) 1989-09-18 1989-09-18 Transfer printing products

Publications (2)

Publication Number Publication Date
JPH03104700A true JPH03104700A (en) 1991-05-01
JP2920952B2 JP2920952B2 (en) 1999-07-19

Family

ID=17076804

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24160589A Expired - Lifetime JP2920952B2 (en) 1989-09-18 1989-09-18 Transfer printing products

Country Status (1)

Country Link
JP (1) JP2920952B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2294888A (en) * 1994-11-08 1996-05-15 Swee Siong Lee Epoxy-coated substrates
US6836046B2 (en) 2002-06-25 2004-12-28 Denso Corporation Stator coil including sequentially-connected conductor segments for an electric rotary machine
JP2007326266A (en) * 2006-05-08 2007-12-20 Marumiya:Kk Manufacturing method of printed matter, and printed matter
CN103419524A (en) * 2012-05-17 2013-12-04 上海纳尔数码喷印材料股份有限公司 Three-layer unidirectional perspective film printing material and manufacturing method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2294888A (en) * 1994-11-08 1996-05-15 Swee Siong Lee Epoxy-coated substrates
GB2294888B (en) * 1994-11-08 1998-07-22 Swee Siong Lee Coated substrates
US6836046B2 (en) 2002-06-25 2004-12-28 Denso Corporation Stator coil including sequentially-connected conductor segments for an electric rotary machine
JP2007326266A (en) * 2006-05-08 2007-12-20 Marumiya:Kk Manufacturing method of printed matter, and printed matter
CN103419524A (en) * 2012-05-17 2013-12-04 上海纳尔数码喷印材料股份有限公司 Three-layer unidirectional perspective film printing material and manufacturing method thereof

Also Published As

Publication number Publication date
JP2920952B2 (en) 1999-07-19

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