JPH03104700A - Transfer print - Google Patents
Transfer printInfo
- Publication number
- JPH03104700A JPH03104700A JP24160589A JP24160589A JPH03104700A JP H03104700 A JPH03104700 A JP H03104700A JP 24160589 A JP24160589 A JP 24160589A JP 24160589 A JP24160589 A JP 24160589A JP H03104700 A JPH03104700 A JP H03104700A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- transfer
- adhesives
- resin
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 37
- 239000004831 Hot glue Substances 0.000 claims abstract description 13
- 150000007529 inorganic bases Chemical class 0.000 claims abstract description 10
- 238000010023 transfer printing Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 10
- 229920005989 resin Polymers 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 10
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000012790 adhesive layer Substances 0.000 abstract description 6
- 229910052759 nickel Inorganic materials 0.000 abstract description 5
- 238000007639 printing Methods 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 229920005992 thermoplastic resin Polymers 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 2
- 239000000956 alloy Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- -1 etc. Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000012943 hotmelt Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000002585 base Substances 0.000 description 6
- 238000007747 plating Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 229920000298 Cellophane Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Decoration By Transfer Pictures (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、無Ｉａ基材に転写印刷層を設けてなる転写印
刷品に関する．
（従来の技術とその課題）
従来、装飾性の向」二や商品の表示などのため、樹脂成
形品に転写印刷層を設けた転写印刷品が知られている。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a transfer printed product comprising a transfer printing layer provided on an Ia-free base material. (Prior Art and its Problems) Conventionally, transfer printing products are known in which a transfer printing layer is provided on a resin molded product for decorative purposes or product display.
しかし，これらの転写印刷層を無機基材へ設けようとす
ると、無機基材への転写印刷層の接着性が悪く，無機基
材へ転写印刷層を設けてなる転写印刷品は実用化されて
いない。However, when trying to provide these transfer printing layers on an inorganic substrate, the adhesion of the transfer printing layer to the inorganic substrate is poor, and transfer printing products made by providing a transfer printing layer on an inorganic substrate have not been put into practical use. .
（課題を解決するための手段）
本発明は、無機基材に転写印刷層を設けてなる転写印刷
品において，無機基材と転写印刷層の間にホットメルト
接着剤層を介在させたことを特徴とする転写印刷品を要
旨とする。(Means for Solving the Problems) The present invention is characterized in that, in a transfer printed product in which a transfer printing layer is provided on an inorganic base material, a hot melt adhesive layer is interposed between the inorganic base material and the transfer printing layer. The gist is the transfer print product.
以下、本発明を添付第１図を基にして詳述する。Hereinafter, the present invention will be explained in detail with reference to the attached FIG. 1.
無機基材ｌとして、具体的には、亜鉛、銅、鉄、ニッケ
ル等の金属又はその合金、ガラス、セラミック、或いは
、樹脂基村上にめっき層を設けたものなどが挙げられる
．
ホットメルト接着剤層２は、ホントメルト系接着剤を基
材ｌ表面に塗布して、加熱乾燥して形成する。ホットメ
ルト系接着剤は、加熱によりＷ４融する樹脂を含有する
もので、その種類は、エポキシ系、ポリエステル系、ウ
レタン系などが挙げられる．中でも、耐溶剤性、耐熱性
に優れているものが好ましく、この点では架橋型のｍ脂
を含イｆしたものが好ましい。更に、このようなホット
メルト系接着剤は、市販されているものをそのまま使っ
ても良いが、溶剤に溶解させることにより、均一に塗付
かし易く、筆記具のクリップ、軸筒などという小さい部
品にはより効果が高い。Specific examples of the inorganic base material include metals such as zinc, copper, iron, and nickel, or alloys thereof, glass, ceramics, and those having a plating layer provided on a resin base. The hot melt adhesive layer 2 is formed by applying a true melt adhesive to the surface of the base material 1 and drying it by heating. Hot-melt adhesives contain resins that undergo W4 melting when heated, and include epoxy, polyester, and urethane adhesives. Among these, those having excellent solvent resistance and heat resistance are preferred, and in this respect, those containing crosslinked m fat are preferred. Furthermore, such hot-melt adhesives can be used as they are on the market, but by dissolving them in a solvent, they are easier to apply evenly and are suitable for small parts such as writing instrument clips and barrels. is more effective.
尚、適宜、必要に応じ、無機基材１とホシトメルト系接
着剤層２の間には、アクリル，メラミン、エポキシ、ポ
リエステル、ウレタン系のラジカル重合型の塗膜を形成
してもよい。In addition, if necessary, a radical polymerization type coating film of acrylic, melamine, epoxy, polyester, or urethane type may be formed between the inorganic base material 1 and the photomelt adhesive layer 2.
転写印刷層３は、転写シートを加熱圧着して形成する。The transfer printing layer 3 is formed by heat-pressing a transfer sheet.
転写シー１〜は，基本的には，、フィルム」二に、離形
層、熱可塑性の樹脂を含む印刷インキを用いスクリーン
印刷、オフセット印刷により印刷した印刷層，接着層が
順次形威されてなる。尚，転写印刷Ｎ３Ｊ−．に、耐久
性或いは光沢などを付与するため、紫外線硬化型或いは
熱硬化型樹脂などよりなるコーティング４を実施できる
。Basically, the transfer sheets 1 to 1 are formed by sequentially forming a release layer, a printing layer printed by screen printing or offset printing using a printing ink containing a thermoplastic resin, and an adhesive layer on a film 2. Become. In addition, transfer printing N3J-. In order to impart durability or gloss, a coating 4 made of ultraviolet curing or thermosetting resin can be applied.
（実施例）
大美可±
基材として真鍮板上に光沢ニッケルめっきを１０μｍ、
光沢ニッケルめっき上にクロムめっきを０．２μｍ形或
し、乾燥後，エポキシ系ホットメルト系接着剤（Ｓ−１
０、東亜合或（株）！２）をスプレーにて５μｍ塗布し
て，１３０度℃、５分間乾燥して、ホットメルト系接着
剤層を設けた。(Example) 10 μm bright nickel plating on a brass plate as a base material.
Apply 0.2 μm chromium plating on bright nickel plating or after drying, apply epoxy hot melt adhesive (S-1
0, Toa Goor Co., Ltd.! 2) was applied by spraying to a thickness of 5 μm and dried at 130° C. for 5 minutes to provide a hot melt adhesive layer.
次に、ポリエステルフィルム上に、離形層、スクリーン
印刷により形成した熱可塑性樹脂よりなる印刷層，接着
層を順次形成してなる転写シートを、ホットメルト接薯
剤が塗布された基村上に置き２４０度℃加熱したプレー
トによりシリコンゴムを介して圧着を３秒聞行ない、フ
ィルムを剥離して転写印刷層を形或した．次に、紫外線
硬化型樹脂よりなるコーティングを施して真鍮基材に転
写印刷層を設けてなる転写印刷品を得た。Next, a transfer sheet, which is made by sequentially forming a release layer, a printing layer made of thermoplastic resin formed by screen printing, and an adhesive layer on a polyester film, is placed on the base layer coated with hot melt adhesive. The silicone rubber was pressed with a plate heated to 240°C for 3 seconds, and the film was peeled off to form a transfer printing layer. Next, a transfer print product was obtained in which a transfer print layer was provided on a brass base material by applying a coating made of an ultraviolet curable resin.
こうして得たものの密着性について、基盤面にカッター
にて１ｍｍ間隔にカットし、セロハンテーブを接着し、
その後，セロハンテーブを剥離することにより評価した
ところ、極めて良好な結果を示した。To check the adhesion of the obtained product, cut it with a cutter at 1 mm intervals on the base surface, glue cellophane tape,
Thereafter, an evaluation was made by peeling off the cellophane tape, and very good results were shown.
大奥Ｎ要
実施例１と同様の金属基村上に、ニッケルめっきを１０
μｍ形威し、乾燥後、アクリル系塗料（マジクロンＭＧ
ＩＯＯＯ．関西ペイント（株）製）を塗布し、１３０度
℃、３０分間乾燥した。次に、ウレタン系ホットメルト
系接着剤（ＰＶ８１００、東亜合！Ｉｊ．（株）製）を
キシレンとメチルエチルケトンの１＝１溶剤で３倍に希
釈した希釈液を、スプレーにて基村上に２〜３μｍ塗布
し、１３０度℃、５分間乾燥した。次に、ポリエステル
フィルム上に、離形層，オフセット印刷により形成した
熱可塑性樹脂よりなる印刷層、接着層を順次形成してな
る転写シートを、ホットメルト接着剤が塗布された基村
上に置き、２４０度℃加熱したプレートによりシリコン
ゴムを介して圧着を２秒間行ない、フィルムを剥離して
転写印刷磨を形威した。次に、紫外線硬化型樹脂よりな
るコーティングを施して真鍮基材に転写印刷層を設けて
なる転写印刷品を得た。Nickel plating is applied to the same metal substrate Murakami as in Example 1.
After applying μm shape and drying, apply acrylic paint (Magicron MG).
IOOO. Kansai Paint Co., Ltd.) was applied and dried at 130 degrees Celsius for 30 minutes. Next, a diluted solution of urethane hot melt adhesive (PV8100, manufactured by Toago Ij. Co., Ltd.) diluted 3 times with a 1=1 solvent of xylene and methyl ethyl ketone was sprayed onto Motomura's upper surface. It was applied to a thickness of 3 μm and dried at 130° C. for 5 minutes. Next, a transfer sheet formed by sequentially forming a release layer, a printing layer made of a thermoplastic resin formed by offset printing, and an adhesive layer on a polyester film is placed on the base plate coated with hot melt adhesive, Pressure bonding was performed for 2 seconds through the silicone rubber using a plate heated to 240 degrees Celsius, and the film was peeled off to form a transfer printing polish. Next, a transfer print product was obtained in which a transfer print layer was provided on a brass base material by applying a coating made of an ultraviolet curable resin.
こうして得たものについて密着性の評価をしたところ、
実施例１同様に極めて良好な結果を示した。When we evaluated the adhesion of the product obtained in this way,
Similar to Example 1, very good results were shown.
（発明の効果）
以上のように、本発明によれば、無機基材に接着性が優
れた転写印刷層を設けてなる転写印刷品たり得る．(Effects of the Invention) As described above, according to the present invention, a transfer printed product can be obtained in which a transfer printing layer with excellent adhesiveness is provided on an inorganic base material.
第１図は本発明の一例を示す要部断面図。
１・・・基材、２・・・ホットメルト接着剤層、３ 転
写印刷Ｊｌ．４・・・コーティング。FIG. 1 is a sectional view of a main part showing an example of the present invention. 1...Base material, 2...Hot melt adhesive layer, 3 Transfer printing Jl. 4...Coating.
Claims (1)
て、無機基材と転写印刷層の間にホットメルト接着剤層
を介在させたことを特徴とする転写印刷品。A transfer printed product comprising a transfer printing layer provided on an inorganic base material, characterized in that a hot melt adhesive layer is interposed between the inorganic base material and the transfer printing layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24160589A JP2920952B2 (en) | 1989-09-18 | 1989-09-18 | Transfer printing products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24160589A JP2920952B2 (en) | 1989-09-18 | 1989-09-18 | Transfer printing products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03104700A true JPH03104700A (en) | 1991-05-01 |
| JP2920952B2 JP2920952B2 (en) | 1999-07-19 |
Family
ID=17076804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24160589A Expired - Lifetime JP2920952B2 (en) | 1989-09-18 | 1989-09-18 | Transfer printing products |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2920952B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294888A (en) * | 1994-11-08 | 1996-05-15 | Swee Siong Lee | Epoxy-coated substrates |
| US6836046B2 (en) | 2002-06-25 | 2004-12-28 | Denso Corporation | Stator coil including sequentially-connected conductor segments for an electric rotary machine |
| JP2007326266A (en) * | 2006-05-08 | 2007-12-20 | Marumiya:Kk | Manufacturing method of printed matter, and printed matter |
| CN103419524A (en) * | 2012-05-17 | 2013-12-04 | 上海纳尔数码喷印材料股份有限公司 | Three-layer unidirectional perspective film printing material and manufacturing method thereof |
-
1989
- 1989-09-18 JP JP24160589A patent/JP2920952B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294888A (en) * | 1994-11-08 | 1996-05-15 | Swee Siong Lee | Epoxy-coated substrates |
| GB2294888B (en) * | 1994-11-08 | 1998-07-22 | Swee Siong Lee | Coated substrates |
| US6836046B2 (en) | 2002-06-25 | 2004-12-28 | Denso Corporation | Stator coil including sequentially-connected conductor segments for an electric rotary machine |
| JP2007326266A (en) * | 2006-05-08 | 2007-12-20 | Marumiya:Kk | Manufacturing method of printed matter, and printed matter |
| CN103419524A (en) * | 2012-05-17 | 2013-12-04 | 上海纳尔数码喷印材料股份有限公司 | Three-layer unidirectional perspective film printing material and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2920952B2 (en) | 1999-07-19 |
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