JPH0295890A - Image receiving material for sublimation transfer - Google Patents
Image receiving material for sublimation transferInfo
- Publication number
- JPH0295890A JPH0295890A JP63247397A JP24739788A JPH0295890A JP H0295890 A JPH0295890 A JP H0295890A JP 63247397 A JP63247397 A JP 63247397A JP 24739788 A JP24739788 A JP 24739788A JP H0295890 A JPH0295890 A JP H0295890A
- Authority
- JP
- Japan
- Prior art keywords
- image
- receiving layer
- vinyl chloride
- polycaprolactone
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000859 sublimation Methods 0.000 title claims description 6
- 230000008022 sublimation Effects 0.000 title claims description 6
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 10
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 230000008018 melting Effects 0.000 abstract description 7
- 238000002844 melting Methods 0.000 abstract description 7
- 229920001225 polyester resin Polymers 0.000 abstract description 4
- 239000004645 polyester resin Substances 0.000 abstract description 4
- 238000007151 ring opening polymerisation reaction Methods 0.000 abstract description 2
- 239000010409 thin film Substances 0.000 abstract description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 13
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005670 poly(ethylene-vinyl chloride) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5272—Polyesters; Polycarbonates
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】 ［技術分野］ 本発明は、昇華転写用受像体に関する。[Detailed description of the invention] [Technical field] The present invention relates to an image receptor for sublimation transfer.
［従来技術］
従来の受像体は、基体（紙、合成紙、プラスチックフィ
ルムなど）の上に、昇華性染料を染着する染料受容層（
ポリエステル樹脂など）を形成してなるものである。[Prior Art] Conventional image receptors have a dye-receiving layer (dye-receiving layer) on which a sublimable dye is dyed on a substrate (paper, synthetic paper, plastic film, etc.).
Polyester resin, etc.).
しかし、従来の受像体では耐光性が悪く、保存中に画像
の劣化が起きていた。However, conventional image receptors have poor light resistance, and images deteriorate during storage.
［目 的］
本発明は、こうした事情に鑑み、転写された受像紙上で
の画像濃度が高く、保存後も低下のない昇華画像を形成
することができる受像体を提供することを目的とする。[Objective] In view of these circumstances, an object of the present invention is to provide an image receptor capable of forming a sublimated image that has a high image density on a transferred image-receiving paper and does not deteriorate even after storage.
［構 成］
本発明者は、上記課題を解決するため従来より研究を重
ねてきたが、受像体の染料受容層中に特定の化合物を含
有させることが有効であることを見出し、本発明に至っ
た。[Structure] The present inventor has conducted extensive research in order to solve the above problems, and has found that it is effective to include a specific compound in the dye-receiving layer of the image receptor, and has developed the present invention. It's arrived.
すなわち、本発明は基体上に昇華性染料が染着可能な染
料受容層を有する受像体において、前記受容層が塩化ビ
ニル系樹脂と下記−最大（式中ｎは単位ユニットの繰返
し数を示す）の繰返し構造をもった数平均分子ｆｉｔ
１．０００〜１００，０００の熱可塑性ポリカプロラク
トンを含有することを特徴とする。That is, the present invention provides an image receptor having a dye-receiving layer on a substrate to which a sublimable dye can be dyed, wherein the receptor layer is made of a vinyl chloride resin and the following - maximum (in the formula, n indicates the number of repeating units). A number-average molecule with a repeating structure of fit
It is characterized by containing 1.000 to 100,000 thermoplastic polycaprolactone.
本発明で用いるポリカプロラクトンは、強固な薄膜を形
成すると同時に、融点が４０〜７０℃（単位ユニットの
繰返し数によって決まる。）と熱転写記録における良好
な特性を有している。The polycaprolactone used in the present invention not only forms a strong thin film, but also has a melting point of 40 to 70° C. (determined by the number of repetitions of the unit), which has good properties in thermal transfer recording.
該ポリカプロラクトンは、ポリエステル樹脂であり、ε
−カプロラクトンの開環重合によって調製せしめられる
。いわゆるメチレン基とエステル基の単一ユニットの繰
返し構造を有するため、従来のポリエチレンテレフタレ
ート系のポリエステルに較べて、高重合度にもかかわら
ず融点を示し、６０〜７０℃位で平衡となる。第１表に
平均分子量と融点の関係を示した。The polycaprolactone is a polyester resin, and ε
- prepared by ring-opening polymerization of caprolactone. Because it has a repeating structure of a single unit of a so-called methylene group and an ester group, it exhibits a melting point despite a high degree of polymerization compared to conventional polyethylene terephthalate-based polyesters, and reaches equilibrium at about 60 to 70°C. Table 1 shows the relationship between average molecular weight and melting point.
表−１：平均分子量（１ｍＷ）と融点（ｒａｐ）の関係
ｍＷ ｍｐ（’Ｃ）
３０００ ４Ｂ−５８
４０００４ｇ−５８
１００００８０−８３，５
４００００〜６００００ ６１−６４７００
００〜１００．０００ ８３−７１該ポリカプロ
ラクトンは受容層の染着性樹脂に対して ５〜３０重量
％が好ましい。Table-1: Relationship between average molecular weight (1 mW) and melting point (rap) mW mp ('C) 3000 4B-58 40004g-58 1000080-83,5 40000-60000 61-64700
00-100.000 83-71 The amount of the polycaprolactone is preferably 5-30% by weight based on the dyeable resin of the receptor layer.
塩化ビニル系の樹脂としてはポリ塩化ビニル、塩化ビニ
ル−酢酸ビニル共重合体、エチレン−塩化ビニル共重合
体、塩化ビニル−プロピオン酸ビニル共重合体などがあ
る。Examples of vinyl chloride-based resins include polyvinyl chloride, vinyl chloride-vinyl acetate copolymers, ethylene-vinyl chloride copolymers, and vinyl chloride-vinyl propionate copolymers.
基体上への染料受容層の塗布量は固形分含量で０．１〜
２０ｇ／ｃＩｌ’がよい。The coating amount of the dye-receiving layer on the substrate is from 0.1 to 0.1 in terms of solid content.
20g/cIl' is good.
また本発明においては、染料受容層中にアミノ変性シリ
コーン、エポキシ変性シリコーン、アルキッド変性シリ
コーン等の離型剤を含有させることができる。これらシ
リコーン類の使用により、転写媒体との熱融百防止効果
が更に向上する。しかし、シリコーン含有量が多くなる
と、前記したように記録後の保存性が低下するので、そ
の含有量は染料受容層の樹脂量に対して、１０重量％以
下であることが望ましい。Further, in the present invention, a release agent such as amino-modified silicone, epoxy-modified silicone, alkyd-modified silicone, etc. can be contained in the dye-receiving layer. Use of these silicones further improves the effect of preventing thermal melting with the transfer medium. However, as the silicone content increases, the storage stability after recording deteriorates as described above, so the silicone content is desirably 10% by weight or less based on the amount of resin in the dye-receiving layer.
なお、染料受容層中には、充填剤を含有させることもで
きる。充填剤としては、シリカ、酸化チタン、炭酸カル
シウム等の白色顔料が挙げられ、その添加量は、該受容
層の樹脂量に対して、５〜６０重二％が好ましい。その
他、染料受容層には、界面活性剤、紫外線吸収剤、酸化
防止剤等を適宜含有させてもよい。Incidentally, a filler can also be contained in the dye-receiving layer. Examples of fillers include white pigments such as silica, titanium oxide, and calcium carbonate, and the amount added thereof is preferably 5 to 60% by weight based on the amount of resin in the receiving layer. In addition, the dye-receiving layer may contain a surfactant, an ultraviolet absorber, an antioxidant, etc. as appropriate.
受像基体としては、合成紙、上質紙、アート紙、コート
紙、セルロース繊維紙、プラスチックフィルム等が単独
であるいはこれらの積層体として使用される。As the image-receiving substrate, synthetic paper, high-quality paper, art paper, coated paper, cellulose fiber paper, plastic film, etc. are used alone or as a laminate of these.
次に実施例を挙げ、本発明をさらに詳細に説明する。EXAMPLES Next, the present invention will be explained in more detail with reference to Examples.
実施例１
塩化ビニル−酢酸ビニル共重合体；
ＶｙＨＨ（ユニオン・カーバイド社） １５部ポリカプ
ロラクトン；プラクセル２１０Ｓ（ダイセル化学社）
２部アミノ変性シリコーンオイル、
Ｓ Ｆ ８４１７（トーレシリコーン社）
１部トルエン ４０部
メチルエチルケトン ４０部上記上記液を
ワイヤーバーを用いて厚さ約１５０μの合成紙（ユボＦ
ＰＧ−１５０、玉子油化合成紙）上に塗布し、乾燥温度
７５℃で１分間乾燥して、厚さ約５μの染着層を形成し
、本発明の受像媒体が作成された。Example 1 Vinyl chloride-vinyl acetate copolymer; VyHH (Union Carbide) 15 parts polycaprolactone; Plaxel 210S (Daicel Chemical)
2-part amino-modified silicone oil,
SF 8417 (Torre Silicone Co., Ltd.)
1 part toluene 40 parts methyl ethyl ketone 40 parts The above solution was coated with synthetic paper approximately 150μ thick (YUBO F) using a wire bar.
The image-receiving medium of the present invention was prepared by applying the dye to PG-150 (egg-oiled synthetic paper) and drying it for 1 minute at a drying temperature of 75° C. to form a dyed layer with a thickness of about 5 μm.
一方、昇華転写シートとしては、下記処方のインク層を
、バック層としてシリコーン硬化樹脂膜約１μを設けた
６μ厚のＰＥＴフィルム上に約２μ塗布して転写媒体を
得た。On the other hand, as a sublimation transfer sheet, a transfer medium was obtained by applying approximately 2 μm of an ink layer having the following formulation onto a 6 μm thick PET film provided with a silicone cured resin film of approximately 1 μm as a back layer.
ポリビニルブチラール樹脂
（ＢＸ−１／積水化学製＞ １０部シア
ン用昇華分散染料（カヤセット ７１４／日本化薬製）
６部溶斉、 ＭＥＫ
４５部トルエン
４５部
こうして得られた転写媒体のインク層が、受像媒体の染
着層と、対面するように重ね合せ、転写媒体の裏面から
サーマルヘッドで加熱エネルギーを変えて画像記録を行
った。サーマルヘッドの記録密度は６ドツト／ｆｆ１Ｉ
１１であり、記録出力は０．４２Ｗ／ドツトであった。Polyvinyl butyral resin (BX-1/Sekisui Chemical>10 parts sublimation disperse dye for cyan (Kayaset 714/Nippon Kayaku)
6 parts melting, MEK
45 parts toluene
45 copies The ink layer of the transfer medium thus obtained was superimposed on the dyed layer of the image receiving medium so as to face each other, and an image was recorded from the back side of the transfer medium using a thermal head while changing the heating energy. The recording density of the thermal head is 6 dots/ff1I
11, and the recording output was 0.42 W/dot.
以下同様に受像体を作製し印字を行った。Thereafter, image receptors were prepared and printed in the same manner.
［実施例２］
塩化ビニル−酢酸ビニル共重合体；
ＶｙＮＳ （ユニオン・カーバイド社） １５部ポリカ
プロラクトン；プラクセル２２０（ダイセル化学社）
２部アミノ変性シリコーン：５Ｆ８４
１７
（トーレシリコーン社） １部トルエン
４０部メチルエチルケトン
４０部［比較例１］
ポリエステル樹脂；バイロン２００
（東洋紡） １５部
アミノ変性シリコーン、 Ｓ Ｆ ８４１７（トーレシ
リコーン） ２部トルエン
４０部メチルエチルケトン
４０部［比較例２］
塩化ビニル−酢酸ビニル共重合体；
ＶＹ）ＩＨ１５部
アミノ変性シリコーン、 Ｓ Ｆ ８４１７ ２部トル
エン ４０部メチルエチル
ケトン ４０部上記各実施例、比較例で得
られた印字画像をキセノン・フェードメータで２４ｈｒ
露光後の画像濃度の褪色率を測定した。[Example 2] Vinyl chloride-vinyl acetate copolymer; VyNS (Union Carbide) 15 parts polycaprolactone; Plaxel 220 (Daicel Chemical)
Two-part amino-modified silicone: 5F84
17 (Toray Silicone Co., Ltd.) 1 part toluene
40 parts methyl ethyl ketone
40 parts [Comparative Example 1] Polyester resin; Vylon 200 (Toyobo) 15 parts amino-modified silicone, SF 8417 (Toray Silicone) 2 parts toluene
40 parts methyl ethyl ketone
40 parts [Comparative Example 2] Vinyl chloride-vinyl acetate copolymer; VY) IH 15 parts Amino-modified silicone, SF 8417 2 parts Toluene 40 parts Methyl ethyl ketone 40 parts The printed images obtained in each of the above Examples and Comparative Examples were treated with xenon.・24hr with fade meter
The fading rate of image density after exposure was measured.
Ｎｏ、 褪色率（％）
実施例１ １０
〃 ２ １２
比較例１ ５０
〃 ２ ２０
［発明の効果］
以上説明したように、本発明の構成による昇華転写用受
像媒体は、画像濃度が高く、保存後の劣化のないすぐれ
た画１象を得ることができる。No. Fading rate (%) Example 1 10 〃 2 12 Comparative example 1 50 〃 2 20 [Effects of the invention] As explained above, the image receiving medium for sublimation transfer according to the structure of the present invention has a high image density and is easy to store. An excellent image without subsequent deterioration can be obtained.
Claims (1)
像体において、前記受容層が塩化ビニル系樹脂と下記一
般式（ I ） ▲数式、化学式、表等があります▼…（ I ） （式中ｎは単位ユニットの繰返し数を示す）の繰返し構
造をもった数平均分子量１，０００〜１００，０００の
熱可塑性ポリカプロラクトンを含有することを特徴とす
る昇華転写用受像体。[Claims] An image receptor having a dye-receiving layer on a substrate to which a sublimable dye can be dyed, wherein the receptor layer is made of a vinyl chloride resin and has the following general formula (I) ▲ Numerical formula, chemical formula, table, etc. ▼…(I) For sublimation transfer, characterized by containing thermoplastic polycaprolactone having a repeating structure of (in the formula, n indicates the number of repeating units) and a number average molecular weight of 1,000 to 100,000. Image receptor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63247397A JPH0295890A (en) | 1988-10-03 | 1988-10-03 | Image receiving material for sublimation transfer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63247397A JPH0295890A (en) | 1988-10-03 | 1988-10-03 | Image receiving material for sublimation transfer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0295890A true JPH0295890A (en) | 1990-04-06 |
Family
ID=17162823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63247397A Pending JPH0295890A (en) | 1988-10-03 | 1988-10-03 | Image receiving material for sublimation transfer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0295890A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02184494A (en) * | 1989-01-11 | 1990-07-18 | Ricoh Co Ltd | Sublimable heat transfer image receiving medium |
| JPH02184493A (en) * | 1989-01-11 | 1990-07-18 | Ricoh Co Ltd | Sublimable heat transfer image receiving medium |
| EP0588065A2 (en) * | 1992-08-19 | 1994-03-23 | The Goodyear Tire & Rubber Company | Package for compounding rubber, compounded rubber and method of compounding rubber |
| EP0613787A1 (en) * | 1993-03-05 | 1994-09-07 | Toyo Ink Manufacturing Co., Ltd. | Image receptor sheet for thermal transfer |
| EP0781664A3 (en) * | 1995-12-28 | 1997-07-30 | Dai Nippon Printing Co., Ltd. | Thermal transfer image-receiving sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6478882A (en) * | 1987-06-16 | 1989-03-24 | Eastman Kodak Co | Top coat for dye image receiving layer used for heat transfer |
-
1988
- 1988-10-03 JP JP63247397A patent/JPH0295890A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6478882A (en) * | 1987-06-16 | 1989-03-24 | Eastman Kodak Co | Top coat for dye image receiving layer used for heat transfer |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02184494A (en) * | 1989-01-11 | 1990-07-18 | Ricoh Co Ltd | Sublimable heat transfer image receiving medium |
| JPH02184493A (en) * | 1989-01-11 | 1990-07-18 | Ricoh Co Ltd | Sublimable heat transfer image receiving medium |
| EP0588065A2 (en) * | 1992-08-19 | 1994-03-23 | The Goodyear Tire & Rubber Company | Package for compounding rubber, compounded rubber and method of compounding rubber |
| EP0588065A3 (en) * | 1992-08-19 | 1994-05-11 | Goodyear Tire & Rubber | Package for compounding rubber and compounded rubber |
| TR27759A (en) * | 1992-08-19 | 1995-07-14 | Goodyear Tire & Rubber | Packaging and compound rubber for rubber compounding. |
| EP0613787A1 (en) * | 1993-03-05 | 1994-09-07 | Toyo Ink Manufacturing Co., Ltd. | Image receptor sheet for thermal transfer |
| EP0781664A3 (en) * | 1995-12-28 | 1997-07-30 | Dai Nippon Printing Co., Ltd. | Thermal transfer image-receiving sheet |
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