JPH0285845A - Silver halide color photographic sensitive material - Google Patents
Silver halide color photographic sensitive materialInfo
- Publication number
- JPH0285845A JPH0285845A JP23802788A JP23802788A JPH0285845A JP H0285845 A JPH0285845 A JP H0285845A JP 23802788 A JP23802788 A JP 23802788A JP 23802788 A JP23802788 A JP 23802788A JP H0285845 A JPH0285845 A JP H0285845A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- silver
- silver halide
- yellow
- sample
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004332 silver Substances 0.000 title claims abstract description 33
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 33
- -1 Silver halide Chemical class 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 42
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000010521 absorption reaction Methods 0.000 claims abstract description 9
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021612 Silver iodide Inorganic materials 0.000 claims abstract description 5
- 229940045105 silver iodide Drugs 0.000 claims abstract description 5
- 239000000084 colloidal system Substances 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 68
- 108010010803 Gelatin Proteins 0.000 description 30
- 229920000159 gelatin Polymers 0.000 description 30
- 239000008273 gelatin Substances 0.000 description 30
- 235000019322 gelatine Nutrition 0.000 description 30
- 235000011852 gelatine desserts Nutrition 0.000 description 30
- 238000002360 preparation method Methods 0.000 description 16
- 239000002245 particle Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000009835 boiling Methods 0.000 description 13
- 239000003960 organic solvent Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 11
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 10
- 229910052740 iodine Inorganic materials 0.000 description 10
- 239000011630 iodine Substances 0.000 description 10
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 9
- 230000035945 sensitivity Effects 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000001235 sensitizing effect Effects 0.000 description 7
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- IYBUGHSUXJVLBQ-UHFFFAOYSA-L dipotassium;bromide;iodide Chemical compound [K+].[K+].[Br-].[I-] IYBUGHSUXJVLBQ-UHFFFAOYSA-L 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 208000010412 Glaucoma Diseases 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- LDOIXZDCORVNPZ-UHFFFAOYSA-O diazanium bromide nitrate Chemical compound [NH4+].[NH4+].[Br-].[O-][N+]([O-])=O LDOIXZDCORVNPZ-UHFFFAOYSA-O 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- FIMXAUNOQYLIGR-UHFFFAOYSA-M sodium hydrogen sulfate hydroxylamine sulfurous acid Chemical compound S(=O)(=O)([O-])O.S(=O)(O)O.NO.[Na+] FIMXAUNOQYLIGR-UHFFFAOYSA-M 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- QHFDHWJHIAVELW-UHFFFAOYSA-M sodium;4,6-dioxo-1h-1,3,5-triazin-2-olate Chemical compound [Na+].[O-]C1=NC(=O)NC(=O)N1 QHFDHWJHIAVELW-UHFFFAOYSA-M 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3022—Materials with specific emulsion characteristics, e.g. thickness of the layers, silver content, shape of AgX grains
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
Abstract
Description
【発明の詳細な説明】
ただし、本発明はこれらの実施例のみに限定されるもの
ではない。DETAILED DESCRIPTION OF THE INVENTION However, the present invention is not limited to these examples.
黄色コロイド銀Aの調製
40°Cの蒸留水にデキストリンを溶解し、N a O
Hでp H12,0に調整し、硝酸銀溶液を添加した後
、ゼラチンを添加し、脱塩を行ない、黄色コロイド恨A
を得た。Preparation of yellow colloidal silver A: Dissolve dextrin in distilled water at 40°C, add NaO
After adjusting the pH to 12.0 with H and adding silver nitrate solution, gelatin was added and desalted to obtain a yellow colloid.
I got it.
黄色コロイド銀Bの調製
N a OHT: p H12,0ニ調整した40″C
の水にデキストリンを溶解し、そこに過酸化水素水を添
加した後、硝酸銀溶液を添加する。更にゼラチンを添加
し、脱塩を行ない、黄色コロイド恨Bを得た。Preparation of yellow colloidal silver B N a OHT: pH adjusted to 12.0 at 40″C
Dissolve dextrin in water, add hydrogen peroxide solution, and then add silver nitrate solution. Furthermore, gelatin was added and desalted to obtain yellow colloid B.
黄色コロイド銀Cの調製
黄色コロイド銀Bの調製法の中で、水の温度を40°C
から60°Cに変更する以外黄色コロイド銀Bと同様に
して、黄色コロイド銀Cを調製した。Preparation of yellow colloidal silver C In the preparation method of yellow colloidal silver B, the water temperature is set to 40°C.
Yellow colloidal silver C was prepared in the same manner as yellow colloidal silver B except that the temperature was changed from to 60°C.
黄色コロイド銀りの調製
硝酸銀溶液をNaOHでpH11,0に調整し、そこに
ハイドロキノンとN a z S O3を添加する事で
黄色コロイド銀りを調製した。Preparation of yellow colloidal silver silver nitrate solution was adjusted to pH 11.0 with NaOH, and hydroquinone and Naz SO3 were added thereto to prepare yellow colloidal silver silver.
黄色コロイド銀A−Dの分光吸収
最大吸収波長(λ、□)
最大吸収値の2の吸収を与える長波側の波長(λD/4
)
実施例1
試料101の作製
下塗りを施した厚み127μの三酢酸セルロースフィル
ム支持体上に、下記のような組成の各層よりなる多層カ
ラー感光材料を作製し、試料101とした。Spectral absorption maximum absorption wavelength of yellow colloidal silver A-D (λ, □) Wavelength on the long wave side giving absorption of 2 of the maximum absorption value (λD/4
) Example 1 Preparation of Sample 101 A multilayer color photosensitive material consisting of each layer having the following composition was prepared on an undercoated cellulose triacetate film support having a thickness of 127 μm, and designated as Sample 101.
第1層:ハレーション防止層
黒色コロイド 0.25g/ボ紫外線
吸収剤 U−10,04g/ボ紫外線吸収剤 U−
20,1g/ボ
紫外線吸収剤 U−30,1g/M
高沸点有機溶媒 0−1 0.1 cc/rr
fを含むゼラチン層(乾燥膜W−2μ)
第2N二中間層
A−142,5mg/rrf
化合物H−10,05g/ボ
乳剤 A 銀量 0.05g/ボ高沸点
有機溶媒 0 2 0.05cc/rrfを含む
ゼラチン層(乾燥膜厚1μ)
第3層:第1赤感乳剤層
増感色素S−1(0,47mg/rrr)及びS−2(
0,02■/ホ)で分光増感された単分散沃臭化銀乳剤
銀量・・・・・・0.15g/ボ(ヨード含
量4モル%、平均粒子サイズ0.20μ、粒径に係る変
動係数(以下単に変動係数と略す)12%)
増感色素S−1(0,51■/ボ)及びS−2(0,0
3■/ホ)で分光増感された単分散性内部潜像型沃臭化
銀乳剤
銀量・・・・・・0.20g/ボ
(ヨード含量4モル%、平均粒子サイズ0.40μ、潜
像から粒子表面までの距離100人。1st layer: Anti-halation layer Black colloid 0.25g/Ultraviolet absorber U-10.04g/Ultraviolet absorber U-
20.1g/B Ultraviolet absorber U-30.1g/M High boiling point organic solvent 0-1 0.1 cc/rr
Gelatin layer containing f (dry film W-2μ) 2N second intermediate layer A-142.5mg/rrf Compound H-10.05g/emulsion A Silver amount 0.05g/bo High-boiling organic solvent 0 2 0.05cc Gelatin layer containing /rrf (dry film thickness 1μ) 3rd layer: 1st red-sensitive emulsion layer sensitizing dye S-1 (0.47mg/rrr) and S-2 (
Monodisperse silver iodobromide emulsion spectrally sensitized at 0.02 mol %/e) Silver amount: 0.15 g/e (iodine content 4 mol%, average grain size 0.20 μ, grain size The coefficient of variation (hereinafter simply referred to as coefficient of variation) 12%) Sensitizing dyes S-1 (0,51 cm/bo) and S-2 (0,0
Monodisperse internal latent image type silver iodobromide emulsion spectrally sensitized with 3■/E) Silver amount: 0.20 g/V (Iodine content: 4 mol%, average grain size: 0.40μ, The distance from the latent image to the particle surface is 100 people.
変動係数14%)
乳剤 B 銀量・・・・・・・・・0.05
g/醒A 1 0.60
mg/rrr化合物 H−60,01g/ボ
カプラー〇 −10,13g / rrrカプラーC2
0,033g / rrrカプラーC−100,1g/
M
高沸点有機溶媒0 2 0.08 cc/rr
rを含むゼラチン層(乾燥膜厚0.7μ)第4層:第2
赤惑乳剤層
増感色素S−1(1,1■/ボ)及びS−2(0,04
■/ホ)で分光増感された単分散沃臭化銀乳剤
銀量・・・・・・0.53g/ボ(ヨード含量3モル%
、平均粒子サイズ0.55μ、変動係数16%)
A−40,02■/ボ
カプラーC−10,40g/ボ
カブラーC−20,07g/腎
カプラーC−90−05g/ボ
高沸点有機溶媒0−2 0.22cc/イを含
むゼラチン層(乾燥膜厚1.7μ)第5層:第3赤感乳
剤層
増感色素s−1(1,1mg/rrr)及びS−2(0
,04■/rrr)で分光増感された単分散沃臭化銀乳
剤 銀量・・・・・・0.53 g/ボ(ヨー
ド含量2モル%、平均粒子サイズ0.07μ、変動係数
17%)
A−71,2u/m
カプラーC−60,35g/ボ
カブ’y−C−80,20g/n(
高沸点有機溶媒0−2 0.24cc/ボを含
むゼラチン層(乾燥膜厚1.8μ)第6層:中間層
A−1010mg/r+(
A−115mg/rr?
化合物H10,1g/M
高沸点有機溶剤0−20.1cc/ボ
を含むゼラチンN(乾燥膜厚lμ)
第7層:第1緑惑乳剤層
増感色素S−3(2,2mg/rrr)及びS−4(1
,0■/rrf)で分光増感された単分散沃臭化銀乳剤
銀量・・・・・・0.5g/ボ(ヨード含
量3モル%、平均粒子サイズ0.35μ、変動係数19
%)
乳剤 B 銀量・・・・・・0.05g/
ボA−5 0.12■/ボ化合
物 H60,01g/rrr
化合物 H−50,005g/ボ
カプラーC−30.27g/ボ
高沸点有機溶媒0 2 0.17cc/ボを含
むゼラチン層(乾燥膜厚0.7μ)第8M:第2緑感乳
剤層
増悪色素S〜3(0,29g/ボ)及びS−4(0,3
■/ rrf )で分光増感された単分散性のの内部潜
像型沃臭化銀乳剤
銀量・・・・・・0.5 g/rrr(ヨード含量2
.5モル%、平均粒子サイズ0.5μ、変動係数18%
、潜像から粒子表面までの距離100人)
A−60,2■/ボ
化合物 H−60,01g/ボ
カプラーC−30,2g/ボ
高沸点有機溶媒0−2 0.13cc/ボを含
むゼラチン層(乾燥膜厚1.7μ)第9層:第3緑惑乳
剤層
増悪色素S−3(0,9g/ボ)及びS−4(0,3■
/ホ)で分光増感された平板状沃臭化銀乳剤
銀量・・・・・・0.5 g/ボ(ヨード含量2モ
ル%、直径/厚みの比が7以上の粒子が、全粒子の投影
面積の50%を占める。粒子の平均厚み0.10μ)
A−21,5■/ボ
カプラーC−40,2g/ボ
高沸点有機溶媒0−2 Q、03cc/r+
fを含むゼラチン層(乾燥膜厚1.7μ)第10層:中
間層
化合物 H−40,1g/イ
高沸点有機溶媒0−20.1cc/イ
を含むゼラチンN(乾燥膜厚0.05μ)第11層:黄
色フィルター層
黄色コロイドi艮 A !Jilffi 0.
12g/rrr化合吻 A−150,22g/rrr
化合物 H−10,02g/ボ
化合物 H−20,03g/M
高沸点有機溶媒 0−2 0.04cc/rr?
を含むゼラチン層(乾燥膜w−1μ)
第12層;第1青怒乳剤層
増感色素S−5(1,0g/%)で分光増感された平板
状沃臭化銀乳剤
i長屋・・・・・・0.6 g/rrf(ヨード
含量3モル%、直径/厚みの比が7以上の粒子が、全粒
子の投影面積の50%を占める。粒子の平均厚み0.1
0μ)
乳剤 A 銀量 o、ig/ボA −7
0,5■/ボ
カプラーC−50,5g/イ
高沸点有機溶媒0 2 0.1 cc/ボを
含むゼラチンN(乾燥膜厚1.5μ)第13層:第2青
惑乳剤層
増感色素S−5(2,0g/rrf)で分光増感された
平板状沃臭化銀乳剤
銀量・・・・・・1.tg/ボ
(ヨード含量2.5モル%、直径/厚みの比が7以上の
粒子が、全粒子の投影面積の50%を占める。粒子の平
均厚み0.15μ)
A−1210■/ボ
カプラー(、−71,2g/ボ
カプラーC−80,2g/ボ
高沸点有機溶媒0−2 0.23cc/ボを含
むゼラチン層(乾燥膜厚3μ)
第14層:第1保護層
A−130,10■/ボ
紫外線吸収剤 U−10,02g/ボ
紫外線吸収剤 U−20,03g/ボ
紫外線吸収剤 U−30,03g/ボ
紫外線吸収剤 U−40,29g/ボ
高沸点有機溶媒0−2 0.28cc/ n(
を含むゼラチン層(乾燥膜厚2μ)
第15層:第2保護層
表面をかぶらせた微粒子沃臭化銀乳剤
i艮tk−−−−0,1g/rrf
(ヨード含N1モル%、平均粒子サイズ0.06μ)A
−810■/ボ
ポリメチルメタクリレート粒子 0.1 g/m(平
均粒子1.5μ)
A−30,2g/ボ
A−91,0■/ボ
を含むゼラチン層(乾燥膜厚0.8μ)各層には上記組
成物の他に、カブ′り防止剤A−16、ゼラチン硬化剤
H−3、及び界面活性剤を添加した。Coefficient of variation 14%) Emulsion B Silver amount 0.05
g/Awakening A 1 0.60
mg/rrr compound H-60,01g/bo coupler -10,13g/rrr coupler C2
0,033g/rrr coupler C-100,1g/
M High boiling point organic solvent 0 2 0.08 cc/rr
Gelatin layer containing r (dry film thickness 0.7μ) 4th layer: 2nd layer
Red-light emulsion layer sensitizing dyes S-1 (1,1 cm/bo) and S-2 (0,04
Monodisperse silver iodobromide emulsion spectrally sensitized with ■/e)
Silver content: 0.53 g/bo (Iodine content: 3 mol%)
, average particle size 0.55μ, coefficient of variation 16%) Gelatin layer containing 0.22 cc/a (dry film thickness 1.7μ) 5th layer: 3rd red-sensitive emulsion layer containing sensitizing dyes s-1 (1.1 mg/rrr) and S-2 (0
Monodisperse silver iodobromide emulsion spectrally sensitized with silver content: 0.53 g/bo (iodine content: 2 mol%, average grain size: 0.07 μ, coefficient of variation: 17 %) A-71,2 u/m Coupler C-60, 35 g/Bokabu'y-C-80, 20 g/n (gelatin layer containing high boiling point organic solvent 0-2 0.24 cc/bo (dry film thickness 1. 8μ) 6th layer: Intermediate layer A-1010mg/r+ (A-115mg/rr? Compound H10, 1g/M Gelatin N containing high boiling point organic solvent 0-20.1cc/bo (dry film thickness lμ) 7th layer : First green emulsion layer sensitizing dye S-3 (2.2 mg/rrr) and S-4 (1
, 0 ■/rrf) Monodisperse silver iodobromide emulsion spectrally sensitized Silver amount: 0.5 g/rrf (Iodine content: 3 mol %, average grain size: 0.35 μ, coefficient of variation: 19
%) Emulsion B Silver amount...0.05g/
Bo A-5 0.12■/B Compound H60,01 g/rrr Compound H-50,005 g/Bo Coupler C-30.27 g/B High-boiling organic solvent 0 2 0.17 cc/Gelatin layer containing B (dry film thickness 0.7μ) 8th M: 2nd green-sensitive emulsion layer enhancing dye S-3 (0.29g/bo) and S-4 (0.3g/bo)
■ Monodisperse internal latent image type silver iodobromide emulsion spectrally sensitized with /rrf) Silver amount...0.5 g/rrr (iodine content 2
.. 5 mol%, average particle size 0.5μ, coefficient of variation 18%
, distance from the latent image to the particle surface (100 persons) A-60,2■/Bo compound H-60,01g/Bocoupler C-30,2g/Bo High boiling point organic solvent 0-2 0.13cc/Gelatin containing Bo Layer (dry film thickness 1.7μ) 9th layer: 3rd glaucoma emulsion layer
/E) Tabular silver iodobromide emulsion spectrally sensitized with
Silver content: 0.5 g/bo (Iodine content: 2 mol%, particles with a diameter/thickness ratio of 7 or more occupy 50% of the projected area of all particles. Average thickness of particles: 0.5 g/bo). 10μ) A-21,5■/Bocoupler C-40,2g/Bo High boiling point organic solvent 0-2Q,03cc/r+
Gelatin layer containing f (dry film thickness 1.7 μ) 10th layer: Intermediate layer compound H-40, 1 g/a Gelatin N containing high boiling point organic solvent 0-20.1 cc/a (dry film thickness 0.05 μ) 11th layer: yellow filter layer yellow colloid i 艮 A! Jilffi 0.
12g/rrr Compound A-150,22g/rrr Compound H-10,02g/Bo compound H-20,03g/M High boiling point organic solvent 0-2 0.04cc/rr?
Gelatin layer containing (dry film w-1μ) 12th layer: 1st blue emulsion layer Tabular silver iodobromide emulsion i Nagaya spectrally sensitized with sensitizing dye S-5 (1.0 g/%) ...0.6 g/rrf (particles with an iodine content of 3 mol% and a diameter/thickness ratio of 7 or more occupy 50% of the projected area of all particles. Average thickness of particles 0.1
0μ) Emulsion A Silver amount o, ig/bo A -7
Gelatin N containing 0.5 cc/bo coupler C-50.5 g/a high-boiling organic solvent 0 2 0.1 cc/bo (dry film thickness 1.5 μ) 13th layer: 2nd blue emulsion layer sensitizing dye Silver amount of tabular silver iodobromide emulsion spectrally sensitized with S-5 (2.0 g/rrf)...1. tg/bo (particles with an iodine content of 2.5 mol% and a diameter/thickness ratio of 7 or more occupy 50% of the projected area of all particles. Average thickness of particles 0.15 μ) A-1210■/bo coupler ( , -71,2g/Bo Coupler C-80,2g/bo Gelatin layer containing high boiling point organic solvent 0-2 0.23cc/bo (dry film thickness 3μ) 14th layer: First protective layer A-130,10■ /B Ultraviolet absorber U-10,02g/B Ultraviolet absorber U-20,03g/B Ultraviolet absorber U-30,03g/B Ultraviolet absorber U-40,29g/B High-boiling organic solvent 0-2 0 .28cc/n(
gelatin layer (dry film thickness 2μ) 15th layer: Fine grain silver iodobromide emulsion covered with the surface of the second protective layer tk---0.1g/rrf (N1 mol% iodine content, average grain Size 0.06μ) A
-810■/bopolymethyl methacrylate particles 0.1 g/m (average particle 1.5μ) A-30,2g/bo A-91,0■/gelatin layer containing (dry film thickness 0.8μ) each layer In addition to the above composition, an antifoggant A-16, a gelatin hardener H-3, and a surfactant were added.
試料を作るのに用いた化合物を後掲の第3表に示す。The compounds used to prepare the samples are shown in Table 3 below.
乳剤A、Bの調製
コンドロールド・ダブルジェット法により、平均粒子サ
イズ0115μの臭化銀立方体乳剤を調製し、ヒドラジ
ンおよび全錯塩を用いて低pAg下でかぶらせた(乳剤
Aとする)。Preparation of Emulsions A and B A silver bromide cubic emulsion with an average grain size of 0115 μm was prepared by the Chondrald double jet method and fogged with hydrazine and a total complex salt under low pAg (referred to as emulsion A).
このように調製した乳剤Aの表面に臭化銀を250人の
厚みでシェル付をしたものを乳剤Bとする。Emulsion B was obtained by shelling silver bromide to a thickness of 250 mm on the surface of emulsion A thus prepared.
試料102の作製
試料101の感光性ハロゲン化銀乳剤の沃化銀含量をす
べて5モル%にする以外試料101と全く同様にして試
料101/4を作製した。Preparation of Sample 102 Sample 101/4 was prepared in exactly the same manner as Sample 101 except that the silver iodide content of the photosensitive silver halide emulsion of Sample 101 was all set to 5 mol %.
試料103の炸裂
試料101の第117Iの黄色フィルター層にヨウ化カ
リウムを0.6 X 10−2g/rrf添加する以外
、試料101と全く同様にして試料103を作製した。Explosion of Sample 103 Sample 103 was prepared in exactly the same manner as Sample 101 except that potassium iodide was added to the 117I yellow filter layer of Sample 101 at a rate of 0.6 x 10-2 g/rrf.
試料104の作製
試料102の第111Jのコロイド銀Aの代りにコロイ
ド銀Bを使用する以外試料102と全く同様にして試料
104を作製した。Preparation of Sample 104 Sample 104 was prepared in exactly the same manner as Sample 102 except that colloidal silver B was used instead of colloidal silver A in the 111J of sample 102.
試料105〜107の作製
試料101の第11層のコロイド銀Aの代わりに第1表
のコロイド銀を使用する以外試料101と全(同様にし
て試料105〜107を作製した。Preparation of Samples 105 to 107 Samples 105 to 107 were prepared in the same manner as Sample 101 except that colloidal silver shown in Table 1 was used in place of Colloidal Silver A in the 11th layer of Sample 101.
試料108の作製
試料105の第11層に臭化カリウムを0.6×10−
”g/rrr添加する以外試料105と全く同様にして
試料108を作製した。Preparation of sample 108 Add potassium bromide to the 11th layer of sample 105 at 0.6 x 10-
Sample 108 was prepared in exactly the same manner as Sample 105 except that ``g/rrr was added.
この様に作製した試料101〜108を、白色光で、連
続ウェッジを通して露光し、下記現像処理を行ない、そ
れぞれのシアン、マゼンタ、イエローの濃度を測定し、
シアン、マゼンタ、イエローの濃度1.0の相対感度と
、最高濃度(D□X)を求めた。又、最低濃度部分の残
存銀量を測定し、脱銀速度の比較を行なった。Samples 101 to 108 prepared in this way were exposed to white light through a continuous wedge, subjected to the following development process, and the respective cyan, magenta, and yellow densities were measured.
The relative sensitivity of cyan, magenta, and yellow at a density of 1.0 and the maximum density (D□X) were determined. In addition, the amount of residual silver in the lowest density portion was measured and the desilvering speeds were compared.
カラー反転感光材料の場合D waxが高い程カブリが
低いといえる。In the case of color reversal photosensitive materials, it can be said that the higher the D wax, the lower the fog.
本発明のインターイメージ効果の測定方法を下記に示す
。The method for measuring the interimage effect of the present invention is shown below.
試料101〜108について各々一部を赤色ウェッジ露
光し、又、他の一部に白色ウェッジ露光(赤+緑+青色
光)を与えた。白色露光時の赤色露光間と、赤色露光時
の露光量は同等であった。For each of Samples 101 to 108, a portion was subjected to red wedge exposure, and another portion was subjected to white wedge exposure (red+green+blue light). The exposure amount during red exposure during white exposure and during red exposure was equivalent.
これらの露光した試料を下記現像処理した。赤色露光の
シアンと白色露光のシアンを比較し、濃度1.0の所の
露光量差Δlog Eが大きい程、赤感性乳剤層へのイ
ンターイメージ効果が大きいといえる。These exposed samples were subjected to the following development treatment. Comparing cyan exposed to red and cyan exposed to white, it can be said that the greater the exposure amount difference Δlog E at a density of 1.0, the greater the interimage effect on the red-sensitive emulsion layer.
又、緑怒性乳剤層へのインターイメージ効果も同様にし
て求めた。In addition, the interimage effect on the green emulsion layer was determined in the same manner.
以上の結果を第1表に示す。The above results are shown in Table 1.
上記のように露光した試料101〜108の現像処理は
、以下のようにして行なった。Samples 101 to 108 exposed as described above were developed as follows.
処理工程 時間 温度 各処理液の組成は、以下のとおりであった。Processing process time temperature The composition of each treatment liquid was as follows.
亜硫酸カリウム チオシアン酸カリウム 炭酸カリウム ノ 臭化カリウム ヨウ化カリウム 水を加えて H 30,0g 30.0 g 1.2g 1.2g 35.0g 35.0g 0°、5g 5.0mg 1000 n/! 100100 O,60 9,70 pHは、塩酸又は水酸化カリウムで調整した。potassium sulfite potassium thiocyanate potassium carbonate of potassium bromide potassium iodide add water H 30.0g 30.0g 1.2g 1.2g 35.0g 35.0g 0°, 5g 5.0mg 1000n/! 100100 O,60 9,70 pH was adjusted with hydrochloric acid or potassium hydroxide.
に水迭丘
母液 補充液
エチレンジアミン 10.0mj2 12.
0 mlリン酸2ナトリウム 5.0g水
を加えて 1000++1p H7,
00
pHは、塩酸又は水酸化カリウムで調整した。Nisui Takaoka Mother Liquor Replenisher Ethylenediamine 10.0mj2 12.
Add 0 ml disodium phosphate 5.0 g water to 1000++1p H7,
00 pH was adjusted with hydrochloric acid or potassium hydroxide.
ヱヱ已(l
ベンジルアルコール
ジエチレングリコール
母液
15、Onl
補充液
18.0mj!
12、On/! 14.0 mj!臭化カリウム
0.5gヨウ化カリウム
1.0’mg水を加えて 1000
n/! 1000 mlp H10,6011,00
pHは、塩酸又は水酸化カリウムで調整した。12, On/! 14.0 mj! Potassium bromide 0.5 g Potassium iodide
Add 1.0'mg water to 1000
n/! 1000 mlp H10,6011,00 pH was adjusted with hydrochloric acid or potassium hydroxide.
漂−」[−辰 母液 補充液 亜硫酸ナトリウム ヒドロキシルアミン硫酸塩 2.0g 3.0g 2.5g 3.6g 臭化アンモニウム 硝酸アンモニウム 水を加えて pH 00g 0 g 000m1 6.30 pHは、酢酸又はアンモニア水で調整した。Drifting-” [-Tatsuna] Mother liquor Replenisher sodium sulfite hydroxylamine sulfate 2.0g 3.0g 2.5g 3.6g ammonium bromide ammonium nitrate add water pH 00g 0 g 000m1 6.30 The pH was adjusted with acetic acid or aqueous ammonia.
還頁足l丘
母液 補充液
を3mg/l以下に処理し、続いて二塩化イソシアヌー
ル酸ナトリウム20mg/fと硫酸ナトリウム1.5g
/fを添加した。この液のpHは7.5の範囲にある。Replenishment solution was treated to below 3 mg/l, followed by 20 mg/f of sodium isocyanurate dichloride and 1.5 g of sodium sulfate.
/f was added. The pH of this liquid is in the range of 7.5.
6.5〜
亜硫酸ナトリウム
15.0g
水を加えて 1000 m1pH6,
50
pHは、酢酸又はアンモニア水で調整した。6.5~ Sodium sulfite 15.0g Add water 1000ml pH6,
50 pH was adjusted with acetic acid or aqueous ammonia.
第二水IL 母液、補充液とも水道水をH型強
酸性カチオン交換樹脂(ロームアンドハース社製アンバ
ーライト IR−120B)と、OH型アニオン交換樹
脂(同アンバーライ) I R−400)を充填した
混床式カラムに通水してカルシウム及びマグネシウムイ
オン濃度第1表の結果より、本発明は比較例に比べて、
インターイメージ効果の低下、感度低下、脱銀性の悪化
を伴なう事なくカプリが低い(Doつが高い)事が明白
である。Second water IL Both mother liquor and replenisher are filled with tap water and H-type strongly acidic cation exchange resin (Amberlite IR-120B manufactured by Rohm and Haas) and OH-type anion exchange resin (Amberlite IR-400) From the results of calcium and magnesium ion concentration in Table 1 when water was passed through the mixed bed column, the present invention showed that compared to the comparative example,
It is clear that Capri is low (Do is high) without any deterioration in interimage effect, sensitivity or desilvering properties.
実施例2
ポリエチレンで両面ラミネートした紙支持体に、次の第
−層から第十二層を重層塗布した試料201を作成した
。ポリエチレンの第−層塗布側にはチタンホワイトを白
色顔料として、また微量の群青を青味染料として含む。Example 2 Sample 201 was prepared by applying the following 1st to 12th layers on a paper support laminated on both sides with polyethylene. The polyethylene coating side of the first layer contains titanium white as a white pigment and a trace amount of ultramarine as a bluish dye.
(感光層組成) 以下に成分とg/rrr単位で示した塗布量を示す。(Photosensitive layer composition) The components and coating amounts in g/rrr are shown below.
なおハロゲン化銀及びコロイド銀については銀換算の塗
布量を示す。For silver halide and colloidal silver, coating amounts are shown in terms of silver.
第1N(ゼラチンN)
ゼラチン ・・・ 1.30第2層(
アンチハレーションN)
黒色コロイド銀 ・・・ 0.10ゼラチ
ン ・・・ 0.70第3層(低感度
赤感光層)
ゼラチン
シアンカラー(*3)
シアンカラー(*4)
・ ・ ・ 1.00
・ ・ ・ 0.14
・ ・ ・ 0.07
カプラー溶媒【*8と*9)・・・
第4層(高感度赤感層)
0.06
ゼラチン
シアンカラー(*3)
シアンカラー(*4)
・ ・ ・ 1.00
・ ・ ・ 0.20
・ ・ ・ 0.10
カプラー溶媒(*8と*9)・
第5層(中間層)
黒色コロイド銀
0.10
0.02
ゼラチン
混色防止剤(*lO)
ポリマーラテックス(*13) ・・第6層(低感度
緑感層)
ゼラチン
マゼンタカプラー(*15)
退色防止剤(*16)
スティン防止剤(*17)
スティン防止剤(*18)
0.02
0.08
0.10
0.80
0.10
0.10
0.01
0.001
退色防止剤(*16) ・・・ 0.10ステ
イン防止剤(*17) ・・・ 0.01ステイン
防止剤(*18) ・・・ 0.001第875(
イエローフィルター層)
黄色コロイド銀 A ・・・ 0.20ゼラチン
・・・ 1.00混色防止剤(*1
0) ・・・ 0.06ボリマーラテツクス(
*13) ・・第9層(低怒度青感層)
0.10
第7層(高感度緑感層)
ゼラチン ・・・ 0.80マゼンタ
カプラー(*15)・・・ 0.10ゼラチン
イエローカプラー(*21)
スティン防止剤(*18)
カプラー溶媒(*9)
0.50
0.20
0、00 1
0.05
第10層(高域度青惑層)
ゼラチン
イエローカプラー(*21)
スティン防止剤(*18)
カプラー溶媒(*9)
第11層(紫外線吸収N)
ゼラチン
1.00
0.40
0、 OO2
0,10
1,50
混色防止剤(*23)
混色防止剤溶媒(*9)
0.06
0.15
第12層(保護層)
*8
*9
*lO
*11
*12
ジ(2−エチルヘキシル)フタレート
トリノニルホスフェート
2.5−ジーも一オクチルハイドロキノントリクレジル
ホスフエート
ジブチルフタレート
*13
ポリエチルアクリレート
*23
2.5
一ジー5ec
−オクチルハイ
ドロキノン
*19
トリオクチルホスフェート
トフエクン
試料202の作製
試料201の全感光性ハロゲン化銀乳剤の沃化銀含量を
、5モル%にする以外試料201と全く同様にして試料
201/4を作製した。1st N (gelatin N) Gelatin... 1.30 2nd layer (
Antihalation N) Black colloidal silver ... 0.10 Gelatin ... 0.70 3rd layer (low-sensitivity red-sensitive layer) Gelatin cyan color (*3) Cyan color (*4) ・ ・ ・ 1.00 ・・ ・ 0.14 ・ ・ ・ 0.07 Coupler solvent [*8 and *9)... 4th layer (highly sensitive red sensitive layer) 0.06 Gelatin cyan color (*3) Cyan color (*4) ・・ ・ 1.00 ・ ・ ・ 0.20 ・ ・ ・ 0.10 Coupler solvent (*8 and *9) ・ 5th layer (intermediate layer) Black colloidal silver 0.10 0.02 Gelatin color mixing inhibitor (*lO ) Polymer latex (*13) 6th layer (low sensitivity green sensitive layer) Gelatin magenta coupler (*15) Anti-fading agent (*16) Anti-stain agent (*17) Anti-stain agent (*18) 0.02 0.08 0.10 0.80 0.10 0.10 0.01 0.001 Anti-fading agent (*16) ... 0.10 anti-stain agent (*17) ... 0.01 anti-stain agent (*18) ... 0.001 No. 875 (
Yellow filter layer) Yellow colloidal silver A ... 0.20 Gelatin ... 1.00 Color mixing prevention agent (*1
0) ... 0.06 bolimar latex (
*13) 9th layer (low sensitivity blue sensitivity layer) 0.10 7th layer (high sensitivity green sensitivity layer) Gelatin 0.80 magenta coupler (*15) 0.10 gelatin yellow Coupler (*21) Stain inhibitor (*18) Coupler solvent (*9) 0.50 0.20 0,00 1 0.05 10th layer (high-frequency blue layer) Gelatin yellow coupler (*21) Stain Inhibitor (*18) Coupler solvent (*9) 11th layer (UV absorption N) Gelatin 1.00 0.40 0, OO2 0.10 1,50 Color mixing inhibitor (*23) Color mixing inhibitor solvent (*9 ) 0.06 0.15 12th layer (protective layer) *8 *9 *lO *11 *12 Di(2-ethylhexyl) phthalate trinonyl phosphate 2.5-di-octylhydroquinone tricresyl phosphate dibutyl phthalate *13 Polyethyl acrylate *23 2.5 -5ec-octylhydroquinone *19 Preparation of trioctyl phosphate tofecne sample 202 Other than setting the silver iodide content of the total photosensitive silver halide emulsion of sample 201 to 5 mol% Sample 201/4 was prepared in exactly the same manner as sample 201.
試料203の作製
試料201の第8Nに沃化カリウムを0.7×10−”
g/m”添加する以外試料201と全く同様にして、試
料203を作製した。Preparation of sample 203 Add 0.7 x 10-" potassium iodide to the 8th N of sample 201.
Sample 203 was prepared in exactly the same manner as Sample 201 except that "g/m" was added.
試料204の作製
試料202の第8層のコロイド銀Aの代りにコロイドj
lBを使用する以外試料202と全く同様にして試料1
04を作製した。Preparation of sample 204 Colloid j was used instead of colloid silver A in the eighth layer of sample 202.
Sample 1 was prepared in exactly the same manner as sample 202 except that 1B was used.
04 was produced.
試料205〜207の作製
試料201の第8Nの黄色コロイド銀Aと第2表に示す
黄色コロイド銀に変更する以外試料201と全く同様に
して、試料205〜207を作製した。Preparation of Samples 205 to 207 Samples 205 to 207 were prepared in exactly the same manner as Sample 201 except that the 8N yellow colloidal silver A of Sample 201 was changed to the yellow colloidal silver shown in Table 2.
試料208の作製
試料204の第8層に臭化カリウムを0.7 Xl0−
’g/m”添加する以外試料204と全く同様にして試
料208を作製した。Preparation of sample 208 Potassium bromide was added to the 8th layer of sample 204 at a concentration of 0.7
Sample 208 was prepared in exactly the same manner as sample 204 except that 'g/m' was added.
この様にして作製した試料201〜208について、実
施例1の様に相対感度、D#111X、残存銀量、イン
ターイメージ効果を求めた。Regarding Samples 201 to 208 prepared in this manner, relative sensitivity, D#111X, residual silver amount, and interimage effect were determined as in Example 1.
但し、この場合の現像処理は下記の様に行なった。However, the development process in this case was performed as follows.
[処理工程]
第一現像(黒白現像)38°C1’15”水 洗
38°C1’30”反転露光
100Lux以上 1°以上カラー現像 3
8°C2° 15”水 洗 38
℃ 45パ漂白定着 38°C
2’OO″水 洗 38°C2°
15′′〔処理液組成〕
亜硫酸カリウム
30、0 g
チオシアン酸カリウム
炭酸カリウム
ジエチレングリコール
1、2 g
35、0 g
15.0mf
臭化カリウム
ヨウ化カリウム
水を加えて
臭化カリウム
ヨウ化カリウム
水を加えて
2左う:ゴ旧象丞。[Processing process] First development (black and white development) 38°C 1'15" water washing
38°C1'30" inversion exposure
100 Lux or more 1° or more color development 3
8°C2° 15”Wash 38
℃ 45pa bleach fixing 38℃
2'OO''Wash 38°C2°
15'' [Treatment liquid composition] Potassium sulfite 30.0 g Potassium thiocyanate Potassium carbonate Diethylene glycol 1.2 g 35.0 g 15.0 mf Add potassium bromide potassium iodide water, add potassium bromide potassium iodide water te 2 left: Go old elephant jo.
ベンジルアルコール ジエチレングリコール 0.5g 5、0■ (pH9,70) 15.0mff1 12.001A 亜硫酸ナトリウム 氷酢酸 水を加えて 亜硫酸ナトリウム 炭酸カリウム ヒドロキシルアミン硫酸塩 2.0g 25、0 g 3.0g 0.5g 1.0■ (p H10,40) 15、0 g 5.0mj2 (pH6゜50) 第2表の結果より、 本発明は比較例に比べて、 第 表 インターイメージ効果の低下、 感度低下、 脱銀性 の悪化を伴なう事なくカブリが低い (D 、、。benzyl alcohol diethylene glycol 0.5g 5,0■ (pH9,70) 15.0mff1 12.001A sodium sulfite glacial acetic acid add water sodium sulfite potassium carbonate hydroxylamine sulfate 2.0g 25.0g 3.0g 0.5g 1.0 ■ (p H10,40) 15.0g 5.0mj2 (pH 6°50) From the results in Table 2, Compared to the comparative example, the present invention has No. table Decrease in interimage effect, decreased sensitivity, Desilvering property Low fog without any deterioration (D...
が高 い) 事が明白である。is high stomach) The thing is clear.
0■ 十C)Iz C→了3−一土CHz CH+π丁H \ tcsH。0 ■ 10C) Iz C → 3-1 earth CHz CH + π ding H \ tcsH.
H
1’l)l
t−CJ、+
I
H
C1l□:CHSO□CH□C0NHCtlzC)I、
=CH3O□CHzCONHCHzUt+
H
0■
I
H
H
H
S’2
2H5
C!H。H 1'l)l t-CJ, + I H C1l□:CHSO□CH□C0NHCtlzC)I,
=CH3O□CHzCONHCHzUt+ H 0■ I H H H S'2 2H5 C! H.
CHzCH=CI(z CsF+tSOtNCHzCOOK C3H。CHzCH=CI(z CsF+tSOtNCHzCOOK C3H.
A−9 A−10 alls C,H5 明細書の浄書(内容に変更なし) υiA-9 A-10 alls C, H5 Engraving of the statement (no changes to the contents) υi
Claims (1)
乳剤層、緑感性ハロゲン化銀乳剤層、青感性ハロゲン化
銀乳剤層、及び黄色コロイド銀含有イエローフィルター
層を有するハロゲン化銀カラー写真感光材料において、
該少なくとも1の乳剤層に含まれるハロゲン化銀乳剤の
平均沃化銀含有量が4モル%以下であり、さらに前記黄
色コロイド銀の親水性コロイド層における最大吸収波長
が430〜450nmにあり、かつ該最大吸収値の1/
4を与える長波側波長が500〜560nmにあること
を特徴とするハロゲン化銀カラー写真感光材料。A silver halide color photographic light-sensitive material having on a support at least one red-sensitive silver halide emulsion layer, one green-sensitive silver halide emulsion layer, one blue-sensitive silver halide emulsion layer, and a yellow filter layer containing yellow colloidal silver. ,
The average silver iodide content of the silver halide emulsion contained in the at least one emulsion layer is 4 mol% or less, and the maximum absorption wavelength of the yellow colloidal silver in the hydrophilic colloid layer is in the range of 430 to 450 nm, and 1/ of the maximum absorption value
A silver halide color photographic light-sensitive material characterized in that the long wavelength side giving a wavelength of 4 is in the range of 500 to 560 nm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23802788A JPH0285845A (en) | 1988-09-22 | 1988-09-22 | Silver halide color photographic sensitive material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23802788A JPH0285845A (en) | 1988-09-22 | 1988-09-22 | Silver halide color photographic sensitive material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0285845A true JPH0285845A (en) | 1990-03-27 |
Family
ID=17024078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23802788A Pending JPH0285845A (en) | 1988-09-22 | 1988-09-22 | Silver halide color photographic sensitive material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0285845A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8627652B2 (en) | 2006-06-13 | 2014-01-14 | Isuzu Motors Limited | Control method of exhaust gas purification system and exhaust gas purification system |
US8973350B2 (en) | 2006-06-13 | 2015-03-10 | Isuzu Motors Limited | Control method of exhaust gas purification system and exhaust gas purification system |
-
1988
- 1988-09-22 JP JP23802788A patent/JPH0285845A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8627652B2 (en) | 2006-06-13 | 2014-01-14 | Isuzu Motors Limited | Control method of exhaust gas purification system and exhaust gas purification system |
US8973350B2 (en) | 2006-06-13 | 2015-03-10 | Isuzu Motors Limited | Control method of exhaust gas purification system and exhaust gas purification system |
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