JPH028260A - Colored uv absorbing pigment - Google Patents
Colored uv absorbing pigmentInfo
- Publication number
- JPH028260A JPH028260A JP15962488A JP15962488A JPH028260A JP H028260 A JPH028260 A JP H028260A JP 15962488 A JP15962488 A JP 15962488A JP 15962488 A JP15962488 A JP 15962488A JP H028260 A JPH028260 A JP H028260A
- Authority
- JP
- Japan
- Prior art keywords
- colored
- fine particles
- cyano
- iron complex
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 21
- 239000010419 fine particle Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000004065 semiconductor Substances 0.000 claims abstract description 15
- LELDAEVDVCNEGF-UHFFFAOYSA-N [Fe]C#N Chemical compound [Fe]C#N LELDAEVDVCNEGF-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 14
- 125000004093 cyano group Chemical group *C#N 0.000 abstract description 3
- 150000004698 iron complex Chemical class 0.000 abstract description 3
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 abstract description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 2
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 7
- 229960003351 prussian blue Drugs 0.000 description 7
- 239000013225 prussian blue Substances 0.000 description 7
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000005340 laminated glass Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 osmium-cyanoiron complexes Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FSAYVKNORFJFQY-UHFFFAOYSA-N C(#N)[Ru].[Fe] Chemical class C(#N)[Ru].[Fe] FSAYVKNORFJFQY-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910003087 TiOx Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- PJFWJWMVURLZJF-UHFFFAOYSA-N [Fe].[Fe]C#N Chemical class [Fe].[Fe]C#N PJFWJWMVURLZJF-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- 238000000411 transmission spectrum Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は着色ＵＶ吸収顔料に関し、特に透明な着色紫外
線吸収フィルム等を作成するに適した微粒子状着色ＵＶ
＠収顔料に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to colored UV-absorbing pigments, and in particular to fine-particle colored UV-absorbing pigments suitable for producing transparent colored UV-absorbing films.
@ Regarding pigment collection materials.
従来、雲母鱗片上にＴｉ（ｈおよびプルシアンブルーを
順次被覆した着色顔料が知られている。（例えば特開昭
４９−１２８０２８）
該着色顔料は、例えば１０〜４０μｍの粒径。Conventionally, a colored pigment in which Ti(h) and Prussian blue are sequentially coated on mica scales is known. (For example, JP-A-49-128028) The colored pigment has a particle size of, for example, 10 to 40 μm.
約３．５ｒｄ／ｇの雲母粒子（約６８重量部）の表面に
Ｔｉ（ｈ被膜（２６，４重量部）およびプルシアンブル
ー被膜（５，６重量部）が設けられた形状をしている。It has a shape in which a Ti(h coating (26.4 parts by weight) and a Prussian blue coating (5.6 parts by weight) are provided on the surface of mica particles (about 68 parts by weight) of about 3.5 rd/g.
上記従来の無機材料を用いた着色顔料によれば、良好な
発色と良好な耐久性を存するものの、透明樹脂中に分散
させてフィルム状として使用しようとする場合には、光
が散乱されてしまい着色透明フィルムを作製できないと
いう問題点があった。Although the above-mentioned conventional colored pigments made from inorganic materials have good color development and good durability, when they are dispersed in a transparent resin and used in the form of a film, light is scattered. There was a problem that a colored transparent film could not be produced.
本発明は、良好な発色を与え、紫外光を吸収し、耐久性
が良好で、透明樹脂中に分散させても樹脂の透明性を失
なうことのない着色ＵＶ吸収顔料を提供することを目的
とする。The present invention aims to provide a colored UV-absorbing pigment that provides good color development, absorbs ultraviolet light, has good durability, and does not lose the transparency of the resin even when dispersed in a transparent resin. purpose.
本発明は、上記従来の問題点を解決するためになされた
ものであって、０．１μｍ以下の半導体微粒子の表面に
５〜３０ｎｍ厚のシアノ鉄錯体膜を設けた着色顔料であ
る。The present invention was made in order to solve the above conventional problems, and is a colored pigment in which a cyano iron complex film with a thickness of 5 to 30 nm is provided on the surface of semiconductor fine particles of 0.1 μm or less.
本発明においては、０．１μｍ以下の半導体微粒子を基
材として使用しているが、粒径が０．１μｍより大きい
と例えば透明樹脂中に分散させた際に可視光の散乱によ
り透明性を失なうことになる。In the present invention, semiconductor fine particles with a diameter of 0.1 μm or less are used as a base material, but if the particle size is larger than 0.1 μm, transparency may be lost due to scattering of visible light when dispersed in a transparent resin. It will happen.
又該粒径は小さすぎると取扱いにくくなるので１０〜１
１００ｎとすることが好ましい。Also, if the particle size is too small, it will be difficult to handle, so the particle size should be 10 to 1.
It is preferable to set it to 100n.
該基材としては半導体微粒子を用いているが、半導体微
粒子を用いないと紫外線吸収特性が現われない。又半導
体微粒子は雲母微粒子と異なり０、１μｍ以下の粒径の
微粒子を調整しやすく、又シアノ鉄錯体を含むメツキ溶
液中に分散させた後紫外光を照射することによって、付
着性が良好で均一なシアノ鉄錯体膜を形成することがで
きる。Semiconductor fine particles are used as the base material, but unless semiconductor fine particles are used, ultraviolet absorption characteristics will not be exhibited. Furthermore, unlike mica particles, it is easy to prepare semiconductor particles with a particle size of 0.1 μm or less, and they can be dispersed in a plating solution containing a cyano iron complex and then irradiated with ultraviolet light, resulting in good and uniform adhesion. A cyano iron complex film can be formed.
該半導体としては、ＴｉＯｘ微粒子等の２．９ｅＶ以上
の禁止帯幅を有する半導体が、紫外線を良好に吸収する
ので好ましい。As the semiconductor, a semiconductor having a forbidden band width of 2.9 eV or more, such as TiOx fine particles, is preferable because it absorbs ultraviolet rays well.
該半導体微粒子上に被覆されるシアノ・鉄錯体膜は５〜
３０ｎｍ厚であるが、Ｓｎｍより薄いとシアノ鉄錯体に
基づく光の吸収作用が小さくなり着色顔料としての効果
が低下する。又３０ｎｍより厚くなると吸光特性は飽和
し、着色顔料の生産性が低下する。The cyano/iron complex film coated on the semiconductor fine particles has a thickness of 5 to 5.
Although the thickness is 30 nm, if it is thinner than S nm, the light absorption effect based on the cyano iron complex becomes small and the effect as a color pigment decreases. Moreover, when the thickness exceeds 30 nm, the light absorption characteristics become saturated and the productivity of colored pigments decreases.
半導体微粒子上に形成されるシアノ鉄錯体の種類は、必
要とされる色調等により調整することができる。例えば
鉄シアノ鉄錯体、ルテニウム・シアノ鉄錯体、オスニウ
ム・シアノ鉄錯体およびこれらの混合物等が例示できる
。The type of cyano iron complex formed on the semiconductor fine particles can be adjusted depending on the required color tone and the like. Examples include iron cyanoiron complexes, ruthenium-cyanoiron complexes, osmium-cyanoiron complexes, and mixtures thereof.
使用される半導体は、伝導帯（ｃｏｎｄｕｃｔｉｏｎ
ｂａｎｄ）のエネルギーレベルが高い（卑な電位）のも
ので、水に溶解しにくいものが好ましく 、ＴｔＯｚ＋
ＺｎＯ＋ＷＯ３＋、 ５ｒＴｉ０３ 、 ＣｄＳ ＋
Ｓｎｕｇ 、 ＣｄＳｅ等が例示できる。The semiconductors used are conduction band
It is preferable that the energy level of band) is high (base potential) and that it is difficult to dissolve in water.TtOz+
ZnO+WO3+, 5rTi03, CdS+
Examples include Snug, CdSe, etc.
本発明の着色ＵＶ吸収顔料は、透明樹脂中に分散させる
ことによって透明着色フィルムを作製できるが、該フィ
ルムを例えば板ガラスの片側膜あるいは中間膜として使
用する場合には、該透明樹脂としてポリビニルブチラー
ル、酢酸ビニル、ポリウレタン、ポリアクリレート等を
使用することが好ましい。本発明の着色顔料を該透明樹
脂中に１〜２０−ｔ％程度添加・分散することにより透
明着色フィルムを作製することができる。The colored UV-absorbing pigment of the present invention can be dispersed in a transparent resin to produce a transparent colored film, but when the film is used, for example, as one side film or an intermediate film of a plate glass, the transparent resin may be polyvinyl butyral, Preferably, vinyl acetate, polyurethane, polyacrylate, etc. are used. A transparent colored film can be produced by adding and dispersing about 1 to 20-t% of the colored pigment of the present invention in the transparent resin.
従来の雲母微粒子の表面に半導体膜およびプルシアンブ
ルー膜を被膜した形状の着色顔料においては、雲母微粒
子の粉砕が困難なため、０．１μｍ以下の粒径とするこ
とが難かしく、そのため樹脂中に分散させた場合に可視
光の散乱により、透明性を得ることができなかった。In conventional colored pigments in which the surface of mica particles is coated with a semiconductor film and a Prussian blue film, it is difficult to grind the mica particles to a particle size of 0.1 μm or less. Transparency could not be obtained due to scattering of visible light when dispersed.
本発明においては、微粒子として半導体材料を用いてい
るため０．１μｍ以下の微粒子を容易に得ることができ
るために透明着色フィルム作製用着色顔料を実現できた
。In the present invention, since a semiconductor material is used as the fine particles, fine particles having a size of 0.1 μm or less can be easily obtained, thereby realizing a colored pigment for producing a transparent colored film.
〔実施例１〕
０、０２ ｍｏｌｄｍ−３の塩化第２鉄と、同じ濃度の
フェリシアン化カリウムの水溶液を各５ ｍｌずつ混合
し、更に平均粒径３６ｎｍのチタニア微粒子１００■を
加えて、懸濁液を作成した。この溶液に１５分間Ａｒを
通気することによって溶存酸素を除去した後にダブルキ
ャップで密封した。次に、４００Ｗの高圧水銀灯を光源
に用いて１時間光照射を行なうことによってチタニア微
粒子上にプルシアンブルーを析出させた。[Example 1] 0,02 moldm-3 of ferric chloride and an aqueous solution of potassium ferricyanide of the same concentration were mixed in an amount of 5 ml each, and 100 μm of titania fine particles with an average particle size of 36 nm were added to form a suspension. It was created. Dissolved oxygen was removed by bubbling Ar through the solution for 15 minutes and then sealed with a double cap. Next, Prussian blue was precipitated on the titania fine particles by irradiating the titania particles with light for 1 hour using a 400 W high-pressure mercury lamp as a light source.
遠心分離により、該処理後の微粒子を回収し、蒸留水で
洗浄した後に乾燥させた。得られた鮮やかな青色に着色
した微粒子と約５０μｍのビーズ状スペーサを光硬化性
モノマー中に分散させてから０．７ ｍｍの２枚のソー
ダライムガラス基板に挟んだ後に、光照射により硬化さ
せて第２図に示す様な合せガラスを作製した。The treated fine particles were collected by centrifugation, washed with distilled water, and then dried. The resulting bright blue colored fine particles and approximately 50 μm bead-like spacers were dispersed in a photocurable monomer, sandwiched between two 0.7 mm soda lime glass substrates, and then cured by light irradiation. A laminated glass as shown in FIG. 2 was manufactured using the following steps.
第１図は、光硬化性モノマーに対して微粒子の含有量・
を変化させた試料の透過スペクトルを示している。図中
１は光硬化性モノマーのみ、２はチタニア微粒子４．８
ｗｔ％、３，４．５は上記被覆微粒子が各々２．４ｗｔ
％、４．８圓ｔ％、１１．９譬ｔ％の試料である。第１
図よりプルシアンブルーで被覆した微粒子がチタニア微
粒子と同様にＵＶ光を吸収し、微粒子濃度が１１．９ｗ
ｔ％では、約４０Ｏｎ＋ｎ以下の波長の光はほとんど完
全に吸収されることを表わしている。Figure 1 shows the fine particle content and
It shows the transmission spectra of samples with different values. In the figure, 1 is only the photocurable monomer, 2 is titania fine particles 4.8
wt%, 3 and 4.5 are each 2.4wt of the above coated fine particles.
%, 4.8 mm t%, and 11.9 mm t%. 1st
From the figure, the fine particles coated with Prussian blue absorb UV light in the same way as the titania fine particles, and the fine particle concentration is 11.9w.
t% indicates that light with a wavelength of about 40On+n or less is almost completely absorbed.
また、約７２０〜７４０ｎｍの吸収は、被覆物であるプ
ルシアンブルーの原子酒量移動吸収によるものである。Moreover, the absorption in the range of about 720 to 740 nm is due to the atomic volume transfer absorption of Prussian blue, which is the coating.
以上のことから、プルシアンブルーで被覆されたチタニ
ア微粒子が、着色ＵＶ吸収顔料として有用であることが
わかる。From the above, it can be seen that titania fine particles coated with Prussian blue are useful as colored UV-absorbing pigments.
上記実施例において作製された合せガラスは、良好な透
明性を有し、あざやかな色調、良好な耐久性、良好な紫
外線吸収を示す合せガラスであった。The laminated glass produced in the above examples had good transparency, bright color tone, good durability, and good ultraviolet absorption.
本発明の着色Ｕｖ＠収顔粗顔料実施例からもあきらかな
とうり樹脂等に分散させることによって透明体を作製で
きる。It is clear from the colored Uv@facial coarse pigment examples of the present invention that a transparent body can be produced by dispersing it in a resin or the like.
第１図は実施例にて作製した着色顔料を用いた合せガラ
スの透過率を示す図、第２図は実施例で作成した着色合
せガラスの概略を示す斜視図である。
長／ｍｍFIG. 1 is a diagram showing the transmittance of the laminated glass using the colored pigment produced in the example, and FIG. 2 is a perspective view schematically showing the colored laminated glass produced in the example. Length/mm
Claims (1)
〜３０ｎｍ厚のシアノ・鉄錯体膜を設けた着色ＵＶ吸収
顔料。(1) 5 on the surface of semiconductor fine particles with a particle size of 0.1 μm or less
A colored UV-absorbing pigment with a ~30nm thick cyano-iron complex film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15962488A JPH028260A (en) | 1988-06-28 | 1988-06-28 | Colored uv absorbing pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15962488A JPH028260A (en) | 1988-06-28 | 1988-06-28 | Colored uv absorbing pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH028260A true JPH028260A (en) | 1990-01-11 |
Family
ID=15697787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15962488A Pending JPH028260A (en) | 1988-06-28 | 1988-06-28 | Colored uv absorbing pigment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH028260A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5243823A (en) * | 1992-10-26 | 1993-09-14 | Allied-Signal Inc. | Master cylinder with non-threaded end cap retention |
| WO2002031060A1 (en) * | 2000-10-09 | 2002-04-18 | Bayer Aktiengesellschaft | Composite particles |
| JP2006010589A (en) * | 2004-06-28 | 2006-01-12 | Techno Network Shikoku Co Ltd | Radiochromic material |
| JP2013209511A (en) * | 2012-03-30 | 2013-10-10 | Dainichiseika Color & Chem Mfg Co Ltd | Iron blue composition |
-
1988
- 1988-06-28 JP JP15962488A patent/JPH028260A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5243823A (en) * | 1992-10-26 | 1993-09-14 | Allied-Signal Inc. | Master cylinder with non-threaded end cap retention |
| WO2002031060A1 (en) * | 2000-10-09 | 2002-04-18 | Bayer Aktiengesellschaft | Composite particles |
| US6565973B2 (en) | 2000-10-09 | 2003-05-20 | Bayer Aktiengesellschaft | Composite particles |
| JP2006010589A (en) * | 2004-06-28 | 2006-01-12 | Techno Network Shikoku Co Ltd | Radiochromic material |
| JP4586191B2 (en) * | 2004-06-28 | 2010-11-24 | 株式会社テクノネットワーク四国 | Use of radiation-sensitive dye composition containing silica particles for measurement of radiation at a low dose of 10 Gy or less |
| JP2013209511A (en) * | 2012-03-30 | 2013-10-10 | Dainichiseika Color & Chem Mfg Co Ltd | Iron blue composition |
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