JPH0260559A - O/w-type emulsion composition - Google Patents
O/w-type emulsion compositionInfo
- Publication number
- JPH0260559A JPH0260559A JP63210196A JP21019688A JPH0260559A JP H0260559 A JPH0260559 A JP H0260559A JP 63210196 A JP63210196 A JP 63210196A JP 21019688 A JP21019688 A JP 21019688A JP H0260559 A JPH0260559 A JP H0260559A
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- fatty acid
- cream
- acid ester
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000000839 emulsion Substances 0.000 title claims abstract description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- 239000000194 fatty acid Substances 0.000 claims abstract description 20
- -1 fatty acid ester Chemical class 0.000 claims abstract description 19
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000007524 organic acids Chemical class 0.000 claims abstract description 10
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 5
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 5
- 235000013336 milk Nutrition 0.000 claims description 2
- 239000008267 milk Substances 0.000 claims description 2
- 210000004080 milk Anatomy 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 28
- 239000000843 powder Substances 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 abstract description 5
- 239000008101 lactose Substances 0.000 abstract description 5
- 235000020183 skimmed milk Nutrition 0.000 abstract description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract description 3
- 229920000223 polyglycerol Polymers 0.000 abstract description 3
- 235000002906 tartaric acid Nutrition 0.000 abstract description 3
- 239000011975 tartaric acid Substances 0.000 abstract description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract description 2
- 235000015155 buttermilk Nutrition 0.000 abstract description 2
- 235000015165 citric acid Nutrition 0.000 abstract description 2
- 239000001630 malic acid Substances 0.000 abstract description 2
- 235000011090 malic acid Nutrition 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 2
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 235000014593 oils and fats Nutrition 0.000 abstract 1
- 235000008476 powdered milk Nutrition 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000006071 cream Substances 0.000 description 21
- 230000014759 maintenance of location Effects 0.000 description 14
- 235000019640 taste Nutrition 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000003925 fat Substances 0.000 description 8
- 235000019197 fats Nutrition 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 6
- 235000009508 confectionery Nutrition 0.000 description 6
- 235000019484 Rapeseed oil Nutrition 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000005687 corn oil Nutrition 0.000 description 3
- 239000002285 corn oil Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008256 whipped cream Substances 0.000 description 3
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 235000013861 fat-free Nutrition 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000015243 ice cream Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- 235000021243 milk fat Nutrition 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000011850 desserts Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013410 fast food Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 235000019643 salty taste Nutrition 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000019614 sour taste Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Grain Derivatives (AREA)
- Edible Oils And Fats (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はO/W型エマルジョン組成物に関し、更に詳し
くは、特に洋菓子類等の製菓製パン等に使用されるホイ
ップ用クリーム用組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an O/W type emulsion composition, and more particularly to a composition for whipping cream used in confectionery and bread making such as Western confectionery. It is something.
本発明においてホイップクリームとは、たて型オープン
ミキサー等積々の方法で含気し、所定の硬さを有する含
気物を得た後、洋菓子(ケーキ、シュークリーム等)、
パン、その他調理、製菓に対しトッピング、フィリング
及びアイシング等として供されるO/W型エマルジョン
のクリームを総称する。In the present invention, whipped cream is aerated by a number of methods such as a vertical open mixer to obtain an aerated product having a predetermined hardness, and is then used to produce Western confectionery (cakes, cream puffs, etc.).
A general term for O/W emulsion creams that are used as toppings, fillings, icings, etc. for bread, other cooking, and confectionery.
上記の如きホイップ用クリームは脂肪分を45重量%以
上含有し、この脂肪分を0/W(水中油)型に水溶液中
に分散させている。またホイップと称する含気操作の結
果、分散する脂肪球は互いに作用し合って一定の保型性
が得られるが、この保型性を利用して製菓用にトッピン
グ、フィリング、アイシングとして使用される。The above-mentioned whipping cream contains a fat content of 45% by weight or more, and this fat content is dispersed in an aqueous solution in an 0/W (oil-in-water) type. In addition, as a result of the aeration process called whipping, the dispersed fat globules interact with each other to maintain a certain shape, and this shape retention is used to make toppings, fillings, and icings for confectionery. .
従来、ホイップ用クリームの脂肪分の低下はクリームの
低カロリー化や食味、食感のライト化等の目的で試みら
れてきた。しかし乍ら、低脂肪化すると確かに低カロリ
ー化や食味、食感のライト化等の目的は達せられるもの
の、トッピング、フィリング、アイシングとしての所定
の保型性が得られず、これは低脂肪化することにより分
散する脂肪球の相互の作用が弱まり、保型性が得られな
いものと考えられていた。そこで一部の試みとして、W
10/W型エマルジョンを調整し脂肪分のみかけ容積率
を高め相互の作用を得て保型性を得る方法が開発された
が、この方法においても保型性は得られるものの、強力
なW10乳化が必要でポリグリセリン縮合リシノール酸
の如き強力な乳化剤を使用せねばならず、その結果とし
て口溶けの悪いしかも乳化剤の臭味のある製品しか得ら
れなかった。即ち、初期の目的を達成せんがあまり、食
品として本来持つべき「おいしさ」を損なうもので、到
底実用に供し得るものではなかった。Conventionally, attempts have been made to reduce the fat content of whipped cream for the purpose of making the cream lower in calories and lighter in taste and texture. However, although lowering the fat content certainly achieves the goals of lowering calories and lightening the taste and texture, it does not provide the required shape retention properties for toppings, fillings, and icings; It was thought that this would weaken the interaction between the dispersed fat globules, making it impossible to maintain shape. Therefore, as part of an attempt, W.
A method has been developed in which a 10/W type emulsion is adjusted to increase the apparent volume percentage of fat and obtain shape retention through mutual interaction.However, although shape retention can also be obtained with this method, the strong W10 emulsion This necessitates the use of a strong emulsifier such as polyglycerol-condensed ricinoleic acid, and as a result, only a product that does not melt in the mouth and has the odor of the emulsifier is obtained. That is, although the initial purpose was not achieved, the "tastiness" that a food should have was lost, and it could not be put to practical use at all.
また、ゼラチンや粘質多糖類の如き増粘剤の使用により
、脂肪球相互間の作用の低下を補填しようとの試みもあ
ったが、この方法により得られた製品はこれら増粘剤の
添加のため糊感のある食感の重たいものであった。There have also been attempts to compensate for the reduced interaction between fat globules by using thickening agents such as gelatin and viscous polysaccharides; It had a sticky texture and was heavy.
以上の様に、従来の試みはいずれも何等かの形で食品の
生命ともいうべき「おいしさ」を犠牲にして初めて保型
性を確保するものであり、従って「おいしさ」を頃なう
ことがなく保型性の良好なホイップ用クリームが待望さ
れている。As mentioned above, all of the conventional attempts have been to secure shape retention only by sacrificing the "tastiness", which is the lifeblood of the food, and therefore, the "tastiness" has been compromised. There is a long-awaited whipping cream that has good shape-retaining properties and is free from scratches.
本発明者らはかかる実情に鑑み、上記の如き問題を解決
するため鋭意研究の結果、脂肪分を低下させても優れた
保型性を備え、且つ食味、食感が軽快なO/W型エマル
ジョン組成物を得、本発明を完成したものである。In view of these circumstances, the present inventors have conducted intensive research to solve the above problems and have found an O/W type that has excellent shape retention even when the fat content is reduced and has a light taste and texture. An emulsion composition was obtained and the present invention was completed.
即ち、本発明は有機酸モノグリセラードを0.01〜0
.9重量%及び/又はポリグリセリン脂肪酸エステルを
0.01〜0.5重世%含有してなる0/W型工マルジ
ヨン組成物を内容とするものである。That is, in the present invention, the organic acid monoglyceride is
.. The composition contains an O/W type engineered multiplexion composition containing 9% by weight and/or 0.01 to 0.5% by weight of polyglycerin fatty acid ester.
本発明者らは、脂肪分45重量%の起泡性クリームの脂
肪分を低下させていった場合の、そのエマルジョン特性
とホイツプ性について研究を重ねたところ、単に従来の
クリーム組成物では、系中に分散する脂肪球の絶対量の
減少によりホイップしないか、またはホイップしてもオ
ーバーラン(比容積)が高くなりすぎ、製菓用トッピン
グとして使用に耐えないものであった。The present inventors conducted repeated research on the emulsion characteristics and whipping properties of foaming cream with a fat content of 45% by weight when the fat content was lowered. Due to a decrease in the absolute amount of fat globules dispersed therein, the product was not whipped, or even if it was whipped, the overrun (specific volume) was too high, making it unsuitable for use as a confectionery topping.
そこで、本発明者らは引き続いて鋭意研究の結果、有機
酸モノグリセラードを0.01〜0.9重量%及び/又
はポリグリセリン脂肪酸エステルを0゜01〜0.5重
量%使用することによりホイツプ性が向上するとともに
、クリームの粘度及び可塑化に対しても安定なO/W型
エマルジョン組成物が得られること、また、上記エマル
ジョン組成物にクエン酸等の有機酸を添加してpHを4
.5〜6.5の範囲に調整することにより、−層保型性
の向上したものが得られ、従来のクリームではこの様な
低pifになるとクリームの粘度が増加したり、可塑化
し易くなり、クリームの安定性が著しく低下するのに、
本発明の場合には全く安定であること、更にまた、蛋白
質含量を0.5重世%以上とすることにより、しっかり
した保型性を有し、保存中の離水現象の殆どない安定な
りリームが得られることを知見した。しかも、得られた
組成物は従来の脂肪分45重量%クリームと同等以上の
ホイップ物性を持ち、且つ食味、食感の非常に優れた軽
快さを持つものであった。Therefore, as a result of continuous research, the present inventors found that by using 0.01 to 0.9% by weight of organic acid monoglyceride and/or 0.01 to 0.5% by weight of polyglycerin fatty acid ester, It is possible to obtain an O/W emulsion composition that improves whipping properties and is stable against cream viscosity and plasticization. 4
.. By adjusting the pif in the range of 5 to 6.5, a product with improved layer shape retention can be obtained, and in conventional creams, when the pif is as low as this, the viscosity of the cream increases and it becomes easy to plasticize. Although the stability of the cream is significantly reduced,
In the case of the present invention, it is completely stable, and furthermore, by setting the protein content to 0.5% or more, it has a stable shape retention property and has almost no syneresis phenomenon during storage. We found that it is possible to obtain In addition, the resulting composition had whipped physical properties equivalent to or better than conventional creams with a fat content of 45% by weight, and had an extremely light taste and texture.
本発明に使用される油脂としては、菜種油、トウモロコ
シ油、ヤシ油、パーム油、乳脂肪等の動植物油が例示で
き、これらは単独または混合物で使用され、また各種油
脂を硬化、分別等の処理を施したものも使用できる。1
0℃のS、F、1. (固体脂含量)が30〜50.2
0℃のS、F、1.が15〜25.30℃のS、F、1
.が5〜10の範囲の油脂が好ましいが、油脂自体のS
、F、1.が多少変化しても、出来たクリームの食味、
食感、その作業性に影響を与えることは少ない。Examples of the fats and oils used in the present invention include animal and vegetable oils such as rapeseed oil, corn oil, coconut oil, palm oil, and milk fat. You can also use the ones that have been given. 1
0°C S, F, 1. (Solid fat content) is 30 to 50.2
0°C S, F, 1. is 15 to 25.30℃ S, F, 1
.. is preferably in the range of 5 to 10, but the S of the fat itself
,F,1. Even if there is a slight change in the taste of the resulting cream,
It has little effect on texture and workability.
本発明に用いられる乳化剤はクエン酸モノグリセラード
、乳酸モノグリセラード、酢酸モノグリセラード等の有
機酸モノグリセラード及び/又はポリグリセリン脂肪酸
エステルで、その使用量は有機酸モノグリセラードはエ
マルジョン全体に対して0.01〜0.0重量%、好ま
しくは0.05〜0゜5重量%、ポリグリセリン脂肪酸
エステルは0.01〜0.5重量%、好ましくは0.0
5〜0.3重量%である。有機酸モノグリセラードが0
.9重量%またはポリグリセリン脂肪酸エステルが0.
5重量%をそれぞれ越えると、風味上不快感があり、ま
た各々0.01%未満では乳化効果が十分でなく、エマ
ルジョンの乳化が不安定になるか、保型性が低下する。The emulsifier used in the present invention is an organic acid monoglyceride and/or polyglycerin fatty acid ester such as citric acid monoglyceride, lactic acid monoglyceride, and acetic acid monoglyceride, and the amount of organic acid monoglyceride used is determined throughout the emulsion. 0.01 to 0.0% by weight, preferably 0.05 to 0.5% by weight, and 0.01 to 0.5% by weight of polyglycerin fatty acid ester, preferably 0.0% by weight.
It is 5 to 0.3% by weight. Organic acid monoglyceride is 0
.. 9% by weight or 0.0% polyglycerin fatty acid ester.
If the content exceeds 5% by weight, the flavor will be unpleasant, and if the content is less than 0.01%, the emulsification effect will be insufficient, resulting in unstable emulsification or poor shape retention.
エマルジョンのpHを4.5〜6.5の範囲に調整する
にはクエン酸、酒石酸、リンゴ酸等の有機酸、低級脂肪
酸、及びナトリウム、カリウム等の塩化物等が例示でき
るが、あまり極度に酸味、塩味を惑じる物は本発明の特
徴を阻害するため好ましくない。pHが4.5未満では
エマルジョンのボテ現象が発生しやすく、またpo6.
sを越えるとホイップ時の保型性の低下及びその後の保
存性の低下が現れる。To adjust the pH of the emulsion to a range of 4.5 to 6.5, organic acids such as citric acid, tartaric acid, and malic acid, lower fatty acids, and chlorides such as sodium and potassium can be used, but they should not be too extreme. Substances that give off a sour or salty taste are not preferred because they interfere with the characteristics of the present invention. If the pH is less than 4.5, the emulsion tends to become brittle, and if the pH is less than 4.5, the emulsion tends to become brittle.
If it exceeds s, the shape retention during whipping and the subsequent storage stability will decrease.
更に、本発明に用いられる蛋白質としては乳を原料とす
るものが好ましく、例えば脱脂粉乳、全粉乳、バターミ
ルク、カゼイン、ナトリウム等が例示でき、これらは単
独または混合物で用いられ、エマルジョン全体の0.5
重量%以上使用するのが望ましい、0.5重量%未満で
はオーバーランが高くなったり、保型性、耐熱保存性等
が不十分となる場合があるが、ホイップ後に直ちに食す
る用途、例えばアイスクリームのデコレーション等外食
レストランやファーストフード店等で使用される場合に
は、むしろ口溶けが良く、好ましい場合もある。上記乳
蛋白質以外の蛋白質を用いて本発明の0/W型工マルジ
ヨン組成物を作ることはできるが、その蛋白質の持つ本
来の臭味が出て、本発明のクリームの持つ特徴が弱めら
れる。Furthermore, the protein used in the present invention is preferably one made from milk, such as skim milk powder, whole milk powder, buttermilk, casein, sodium, etc., which can be used alone or in a mixture, and can be used to reduce the total weight of the emulsion. .5
It is desirable to use more than 0.5% by weight. If it is less than 0.5% by weight, overrun may be high or the shape retention and heat-resistant storage properties may be insufficient. When used in restaurants, fast food restaurants, etc., such as in cream decorations, it may be preferable because it melts in the mouth rather well. Although it is possible to prepare the O/W-type engineered multilayer composition of the present invention using proteins other than the above-mentioned milk proteins, the original odor and taste of the protein will come out, and the characteristics of the cream of the present invention will be weakened.
本発明において、更に無脂固形分、その他を使用するこ
とができる。無脂固形分としては、乳糖゛をはじめとす
るtI!類や、カラギーナン、ローガストビンガム等の
ガム質、リン酸塩等が例示できる。In the present invention, non-fat solids and others may also be used. Non-fat solids include tI!, including lactose. Examples include carrageenan, gummy substances such as rogust Bing gum, and phosphates.
しかし、これらは本発明の特徴を損なう場合があるので
、使用するか否かについては十分な考慮を要する。However, since these may impair the features of the present invention, sufficient consideration must be given to whether or not to use them.
以下に実施例及び比較例を示し、本発明を更に詳細に説
明するが、これらによって何ら限定されるものではない
。EXAMPLES The present invention will be explained in more detail with reference to Examples and Comparative Examples below, but the present invention is not limited thereto.
実施例1
全重量に対して25%(重量%、以下間し)の硬化菜種
油と10%のトウモロコシ油を65℃に加温溶解し、ク
エン酸モノグリセラード0.3%と酢酸モノグリセラー
ド0.1%及びポリグリセリン脂肪酸エステル0.05
%を混合し油相部を作製した。他方、脱脂粉乳8%及び
乳糖2.4%を55℃の温水54%に分散させ、更にク
エン酸0.1%を加えて十分に攪拌混合し、油相部と混
合した。次に65℃で均質化機にて50kg/cn処理
し、140℃で2秒間直接殺菌した後、更に均質化機に
て100 kg/c4処理し、急冷してO/W型エマル
ジョン組成物を得た。得られた組成物のpHは6.3、
蛋白質含量は2.1%であった。このO/W型エマルジ
ョン組成物を5℃冷蔵庫にて2日間エーシングさせ、ホ
バートミキサーにてホイップさせたところ、4分50秒
で最適な状態のクリームになった。このクリームの口溶
けは非常に軽快で、油脂骨45%含有するクリームに比
べて著しい差が認められた。更に室温く25℃)に30
分間放置しても、クリームの肌荒れ、シマリ (硬くな
る現象)はなく、20℃で24時間放置しても離水現象
、ダレ現象は全く認められなかった。Example 1 Hydrogenated rapeseed oil and 10% corn oil, based on the total weight, were heated and dissolved at 65°C, and 0.3% citric acid monoglyceride and acetic acid monoglyceride were dissolved. 0.1% and polyglycerin fatty acid ester 0.05
% was mixed to prepare an oil phase. On the other hand, 8% of skim milk powder and 2.4% of lactose were dispersed in 54% of warm water at 55°C, and 0.1% of citric acid was added thereto, thoroughly stirred and mixed, and mixed with the oil phase. Next, it was treated at 50 kg/cn with a homogenizer at 65°C, and directly sterilized at 140°C for 2 seconds, then further processed with a homogenizer at 100 kg/c4, and rapidly cooled to obtain an O/W emulsion composition. Obtained. The pH of the resulting composition was 6.3,
Protein content was 2.1%. When this O/W type emulsion composition was aged in a 5°C refrigerator for 2 days and whipped with a Hobart mixer, it became an optimal cream in 4 minutes and 50 seconds. This cream melted in the mouth very easily, and a marked difference was observed compared to the cream containing 45% fat and oil. Further, lower the temperature to room temperature (25°C) to 30°C.
There was no skin roughness or shimmering (hardening phenomenon) of the cream even after it was left for a minute, and no syneresis or sagging phenomenon was observed even after it was left at 20°C for 24 hours.
実施例2
実施例1において、クエン酸モノグリセラード0.3%
、酢酸モノグリセラード0.1%及びポリグリセリン脂
肪酸エステル0.05%に代えて、乳酸モノグリセラー
ド0.4%と酢酸モノグリセラード0.25%を用いた
他は実施例1と同様にして実施したところ、実施例1と
ほぼ同様の結果を得た。Example 2 In Example 1, citric acid monoglyceride 0.3%
, Same as Example 1 except that 0.4% of lactic acid monoglyceride and 0.25% of acetic acid monoglyceride were used instead of 0.1% of acetic acid monoglyceride and 0.05% of polyglycerin fatty acid ester. As a result, almost the same results as in Example 1 were obtained.
実施例3
実施例1において、クエン酸モノグリセラード0.3%
、酢酸モノグリセラード0.1%及びポリグリセリン脂
肪酸エステル0.05%に代えて、ポリグリセリン脂肪
酸エステル0.35%と、水層部にポリグリセリンネ飽
和脂肪酸エステル0.1%添加した他は実施例1と同様
の操作を行った。実施例1とほぼ同様の結果が得られた
。Example 3 In Example 1, citric acid monoglyceride 0.3%
, except that instead of 0.1% acetic acid monoglyceride and 0.05% polyglycerin fatty acid ester, 0.35% polyglycerin fatty acid ester and 0.1% polyglycerin saturated fatty acid ester were added to the water layer. The same operation as in Example 1 was performed. Almost the same results as in Example 1 were obtained.
実施例4
実施例1において、クエン酸に代えて酒石酸を用いた他
は実施例1と同様に操作して0/W型工マルジョンを作
製した。得られた○/W型エマルジョン組成物のpHは
5.8、蛋白質含量は2.1%で、ホイップクリームと
して十分なる機能を持ち、口溶けもすこぶる良好であっ
た。Example 4 An O/W type emulsion was prepared in the same manner as in Example 1 except that tartaric acid was used instead of citric acid. The obtained O/W type emulsion composition had a pH of 5.8 and a protein content of 2.1%, had a sufficient function as a whipped cream, and melted in the mouth very well.
実施例5
全重量に対して硬化菜種油17.5%と硬化ヤシ油2.
5%及び乳脂肪15%を65℃に加温溶解し、クエン酸
モノグリセラード0.25%及びポリグリセリン脂肪酸
エステル0.08%を混合し、油相部を作製した。他方
、脱脂粉乳7.5%及び乳糖3.0%を55℃の温水5
4%に分散させ、更にクエン酸0.1%を加えて十分に
撹拌混合し、油相部と混合し、実施例4と同様に処理し
O/W型エマルジョン組成物を得た。このO/W型エマ
ルジョン組成物のpHは6.0、蛋白質含量は1.9%
で、最適ホイップ時間は4分15秒、オーバーラン12
5%で、従来のクリームと比較して格段に優れた食味、
食感を有し、作業性、保存性についても十分優れたもの
であった。Example 5 Hydrogenated rapeseed oil 17.5% and hydrogenated coconut oil 2.
5% and milk fat 15% were heated and dissolved at 65°C, and 0.25% of citric acid monoglyceride and 0.08% of polyglycerin fatty acid ester were mixed to prepare an oil phase. On the other hand, 7.5% skim milk powder and 3.0% lactose were added to 55°C warm water.
4%, further added 0.1% citric acid, stirred and mixed thoroughly, mixed with the oil phase, and treated in the same manner as in Example 4 to obtain an O/W emulsion composition. The pH of this O/W emulsion composition is 6.0, and the protein content is 1.9%.
So, the optimal whipping time is 4 minutes 15 seconds, overrun 12
At 5%, it has a much superior taste compared to conventional cream.
It had a good texture and was excellent in workability and storage stability.
実施例6
実施例1において、クエン酸を使用しない他は実施例1
と同様にしてO/W型エマルジョン組成物を作製した。Example 6 Same as Example 1 except that citric acid is not used.
An O/W type emulsion composition was prepared in the same manner as above.
得られたエマルジョン組成物のpHは6.8で、実施例
1の組成物に比しホイップ後の保型性においてやや劣り
、またその後の保存性においても僅かな離水を生じた。The pH of the obtained emulsion composition was 6.8, which was slightly inferior to the composition of Example 1 in shape retention after whipping, and slight syneresis occurred in subsequent storage.
しかし乍ら、実施例1の組成物よりも食味は軽快で、ホ
イップ後すぐに食する用途では問題のないものであった
。However, the taste was lighter than that of the composition of Example 1, and there were no problems when it was eaten immediately after whipping.
実施例7
全重量に対して25%の硬化菜種油と10%のトウモロ
コシ油を65℃に加温溶解し、クエン酸モノグリセラー
ド0.3%、酢酸モノグリセラード0.1%及びポリグ
リセリン脂肪酸エステル0.05%を混合し、油相部を
作製した。また脱脂粉乳0゜3%と乳糖5%を55℃の
温水59.1%に分散させ、更にクエン酸0.1%を加
えて十分に攪拌し油相部と混合しO/W型エマルジョン
組成物を実施例1と同様に作製した。得られた組成物の
pHは6゜2、蛋白質含量は0.08%で、実施例1〜
5で得られた組成物に比し、ややフワフワした保型性の
クリームであったが、アイスクリームやチョコレートサ
ンデー等の如くアイスクリームにデコレーションしたデ
ザート類としては、むしろ実施例1〜5の組成物よりも
更に口溶けの軽快なものであった。Example 7 25% of hydrogenated rapeseed oil and 10% of corn oil based on the total weight were heated and dissolved at 65°C, and 0.3% of citric acid monoglyceride, 0.1% of acetic acid monoglyceride and polyglycerol fatty acid were dissolved. An oil phase was prepared by mixing 0.05% of ester. In addition, 0.3% skim milk powder and 5% lactose were dispersed in 59.1% warm water at 55°C, and 0.1% citric acid was added, thoroughly stirred, and mixed with the oil phase to form an O/W emulsion. A product was prepared in the same manner as in Example 1. The pH of the obtained composition was 6°2, the protein content was 0.08%, and the composition was as follows:
Compared to the composition obtained in Example 5, the cream had a slightly fluffier shape retention property, but the compositions of Examples 1 to 5 were more suitable for desserts decorated with ice cream, such as ice cream and chocolate sundaes. It was lighter and melted in the mouth even more than the original.
比較例1
実施例5において、クエン酸モノグリセラード0.25
%とポリグリセリン脂肪酸エステル0.08%の代わり
に、シヨ糖脂肪酸エステル0.25%とレシチン0.0
8%を使用した他は、実施例5と同様の操作を行った。Comparative Example 1 In Example 5, citric acid monoglyceride 0.25
% and polyglycerin fatty acid ester 0.08%, sucrose fatty acid ester 0.25% and lecithin 0.0
The same operation as in Example 5 was performed except that 8% was used.
得られたエマルジョン組成物はエマルジョン調製直後か
ら1200cpと高い粘度を示し、オーバーランも35
%と非常に含気性の悪いものであった。The obtained emulsion composition showed a high viscosity of 1200 cp immediately after emulsion preparation, and an overrun of 35 cp.
%, and had very poor air permeability.
比較例2
比較例1において、ショ糖脂肪酸エステルの代わりにモ
ノグリセリン脂肪酸エステルを0.05.0.10.0
.15.0.20.0.25.0.30及び0゜35%
それぞれ使用した他は比較例1と同様の操作を行った。Comparative Example 2 In Comparative Example 1, 0.05.0.10.0 monoglycerin fatty acid ester was used instead of sucrose fatty acid ester.
.. 15.0.20.0.25.0.30 and 0°35%
The same operation as in Comparative Example 1 was performed except that each was used.
得られたエマルジョン組成物はいずれもホイップ操作を
続けても全く保型性の得られないものであった。All of the emulsion compositions obtained could not retain their shape at all even if the whipping operation was continued.
比較例3
比較例1において、レシチンの代わりに不飽和モノグリ
セリン脂肪酸エステルを0.02.0.04.0.06
.0.08及び0.10%それぞれ使用した他は比較例
1と同様の操作を行った。得られたエマルジョン組成物
はいずれもホイップ中にチャーニング状態となり、分離
状態となった。Comparative Example 3 In Comparative Example 1, 0.02.0.04.0.06 unsaturated monoglycerin fatty acid ester was used instead of lecithin.
.. The same operation as in Comparative Example 1 was performed except that 0.08% and 0.10% were used, respectively. All of the obtained emulsion compositions became a churning state during whipping and became a separated state.
軟土の通り、本発明によればホイツプ性、保型性及び保
存性に優れ、且つ食味、食感の軽快な0/W型工マルジ
ヨン組成物を提供することができる。As mentioned above, according to the present invention, it is possible to provide an O/W-type engineered multi-mulsion composition that has excellent whipping properties, shape retention properties, and preservability, and has a light taste and texture.
Claims (1)
及び/又はポリグリセリン脂肪酸エステルを0.01〜
0.5重量%含有してなるO/W型エマルジョン組成物
。 2、pHが4.5〜6.5の範囲にある請求項1記載の
組成物。 3、乳を原料とする蛋白質を0.5重量%以上含有する
請求項1又は2記載の組成物。[Claims] 1. 0.01 to 0.9% by weight of organic acid monoglyceride
and/or polyglycerin fatty acid ester from 0.01 to
An O/W type emulsion composition containing 0.5% by weight. 2. The composition according to claim 1, which has a pH in the range of 4.5 to 6.5. 3. The composition according to claim 1 or 2, which contains 0.5% by weight or more of milk-based protein.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63210196A JPH0260559A (en) | 1988-08-24 | 1988-08-24 | O/w-type emulsion composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63210196A JPH0260559A (en) | 1988-08-24 | 1988-08-24 | O/w-type emulsion composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0260559A true JPH0260559A (en) | 1990-03-01 |
Family
ID=16585376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63210196A Pending JPH0260559A (en) | 1988-08-24 | 1988-08-24 | O/w-type emulsion composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0260559A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5393554A (en) * | 1991-05-29 | 1995-02-28 | Fuji Oil Company, Limited | Cream composition |
JP2007289116A (en) * | 2006-04-27 | 2007-11-08 | Miyoshi Oil & Fat Co Ltd | Powdered oil and fat |
WO2016208605A1 (en) * | 2015-06-22 | 2016-12-29 | クラシエフーズ株式会社 | Powder for no-heat just-add-water cream foodstuff |
JP2020080811A (en) * | 2018-11-30 | 2020-06-04 | 株式会社カネカ | Novel whipped cream, and production method of the same |
-
1988
- 1988-08-24 JP JP63210196A patent/JPH0260559A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5393554A (en) * | 1991-05-29 | 1995-02-28 | Fuji Oil Company, Limited | Cream composition |
JP2007289116A (en) * | 2006-04-27 | 2007-11-08 | Miyoshi Oil & Fat Co Ltd | Powdered oil and fat |
JP4627513B2 (en) * | 2006-04-27 | 2011-02-09 | ミヨシ油脂株式会社 | Powdered oil |
WO2016208605A1 (en) * | 2015-06-22 | 2016-12-29 | クラシエフーズ株式会社 | Powder for no-heat just-add-water cream foodstuff |
JP2020080811A (en) * | 2018-11-30 | 2020-06-04 | 株式会社カネカ | Novel whipped cream, and production method of the same |
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