JPH0259714B2 - - Google Patents
Info
- Publication number
- JPH0259714B2 JPH0259714B2 JP7620586A JP7620586A JPH0259714B2 JP H0259714 B2 JPH0259714 B2 JP H0259714B2 JP 7620586 A JP7620586 A JP 7620586A JP 7620586 A JP7620586 A JP 7620586A JP H0259714 B2 JPH0259714 B2 JP H0259714B2
- Authority
- JP
- Japan
- Prior art keywords
- food
- water
- permeable
- direct dehydration
- semi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000013305 food Nutrition 0.000 claims description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 230000018044 dehydration Effects 0.000 claims description 21
- 238000006297 dehydration reaction Methods 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 239000012528 membrane Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 11
- 150000001413 amino acids Chemical class 0.000 claims description 10
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims description 7
- 102000002322 Egg Proteins Human genes 0.000 claims description 7
- 108010000912 Egg Proteins Proteins 0.000 claims description 7
- 102000016943 Muramidase Human genes 0.000 claims description 7
- 108010014251 Muramidase Proteins 0.000 claims description 7
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims description 7
- 235000014103 egg white Nutrition 0.000 claims description 7
- 210000000969 egg white Anatomy 0.000 claims description 7
- 239000004325 lysozyme Substances 0.000 claims description 7
- 235000010335 lysozyme Nutrition 0.000 claims description 7
- 229960000274 lysozyme Drugs 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000003204 osmotic effect Effects 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 235000005985 organic acids Nutrition 0.000 claims description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 13
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 12
- 235000001014 amino acid Nutrition 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000555825 Clupeidae Species 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000015278 beef Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229940093915 gynecological organic acid Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000019512 sardine Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229920002978 Vinylon Polymers 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 230000001420 bacteriolytic effect Effects 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000002727 hyperosmolar Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229940099690 malic acid Drugs 0.000 description 1
- LUEWUZLMQUOBSB-GFVSVBBRSA-N mannan Chemical class O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-GFVSVBBRSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Description
〔産業上の利用分野〕
本発明は、食品の食味を変えることなく、所望
の脱水率に脱水することを可能とし、しかも長期
にわたつて反復使用出来る食品の直接脱水液に関
する。
〔従来の技術〕
食品を変質させないで水分のみを除去すれば食
品の鮮度保持、冷凍破壊の防止、保形性の向上、
調理時の加熱エネルギーや加熱時間の減少など、
多くの利点があるため、種々研究が推進され、食
品を低温で浸透圧の差によつて脱水する方法が行
なわれるようになつた。この方法は、例えば特公
昭58−58124、USP−4383376などに記載されて
いるように、高浸透圧物質と、透水性半透膜(以
下、半透膜という)とを組合わせた特殊なシート
状物質を用い、これに食品を包んで脱水する方法
である。しかし、この方法は機械によつて自動化
することは困難で、人手を要し、大量生産には不
適当であつた。
そのため、本発明者等は、先に食品を半透膜に
包装し、これを高浸透圧物質の直接脱水液に所定
時間浸漬し、食品を所望の脱水率に脱水するとと
もに、水分等を吸収した直接脱水液を減圧して、
これらを除去し、反復使用する方法により上記の
問題を解決した。
しかし、上記直接脱水液は、一般菌の増殖速度
が早くて腐敗し易く、長期の使用に耐えない欠点
があつた。
〔従来技術とその問題点〕
本発明は上記の事情に鑑み、腐敗することな
く、比較的長期間にわたつて使用出来る直接脱水
液を提供することを目的とする。
〔問題点を解決するための手段〕
本発明は上記の目的を達成するためになされた
もので、その要旨は、透水性半透膜に包装された
食品に、上記透水性半透膜を介して接触させ、食
品中の水分を透水性半透膜を通して吸収除去する
食品の直接脱水液であつて、液状高浸透圧物質、
エタノール、およびアミノ酸またはその塩から選
ばれた少なくとも一種類よりなる食品の直接脱水
液、或いは、液状高浸透圧物質、エタノール、ア
ミノ酸またはその塩より選ばれた少なくとも一種
類と、有機酸またはその塩、卵白リゾチームより
選ばれた一種類以上を含む食品の直接脱水液にあ
る。
〔発明の具体的構成および作用〕
以下、本発明を詳しく説明する。
本発明において対象とする食品は、生の魚介
類、肉等の生鮮動物性食品、野菜、果物などの植
物性食品で、特に脱水することによつて保存性が
増す食品、冷凍耐性が向上する食品、食味がよく
なる食品、調理性が改善される食品等である。
また、半透膜は、水および水分子とほぼ同じ大
きさの分子は通すが高分子物を通さず、食品に直
接接触しても安全なものが用いられる。例えば、
低延伸性ビニロンフイルム、普通セロハン、コロ
ジオン膜、エチレン酢酸ビニール共重合体フイル
ム等が好適である。これらフイルムは、水および
食品中の不要成分であるアンモニア、トリメチル
アミン、ジメチルアミン、ホルムアルデヒド、食
塩などは透過するが、有効成分である蛋白質、糖
類、ミネラル、ビタミン類などはほとんど透過し
ない。
また、本発明に係る直接脱水液の主成分となる
液状高浸透圧物質は、上記半透膜を実質的に通さ
ないものでなければならないが、完全にその透過
を阻止することは出来ないので、食品、食品添加
物、食品加工材として使用が許可されたものが用
いられる。例えば、水あめ、シヨ糖等の糖類の濃
厚水溶液、マンナン質、アルギン酸ソーダ、カラ
ギーナン、アラビヤゴム等の天然高分子、メチル
セルローズ類、ポリアクリル酸ソーダ、グリセリ
ン、プロピレングリコールなどの合成高分子物あ
るいは合成物が好適である。
また、上記液状高浸透圧物質に添加されるもの
のうち、エタノールは、カビの発生を抑制するた
めのもので、その量は、直接脱水液中の濃度とし
て0.5〜5wt%が好ましい。この量が0.5wt%未満
では、カビの発生を抑制する効果がなく、5%を
越えると不経済であるばかりでなく、食品にアル
コール臭がつき、アミノ酸の溶解量が減少する。
アミノ酸またはその塩は、一般菌の増殖を抑制す
るもので、例えば、グリシン、グルタミン酸、ア
ラニン、またはそれらの塩等が用いられ、その量
は0.5〜2wt%が好ましく、量が0.5wt%未満では、
一般菌に対する抑制効果がなく、2wt%を越える
と、結晶が析出し易くなつたり、食品に味、或い
は色がつくことがある。
上記エタノール、アミノ酸またはその塩の添加
により、直接脱水液の腐敗は大幅に遅延される
が、有機酸またはその塩、卵白リゾチーム、プロ
ピレングリコールを添加すると、種々な効果が発
揮され、腐敗はさらに遅延される。すなわち、有
機酸またはその塩は発生するNH3、アミン等を
中和してPHを下げる効果があり、例えばリンゴ
酸、クエン酸、酢酸、アルスコルビン酸、ソルビ
ン酸または、その塩などが用いられ、その量は、
0.1〜1wt%が好ましく、量が0.1wt%未満ではPH
を下げる効果がなく、1wt%を越えると、設備材
料が高価につき、さらに、食品に臭いがついた
り、食味が変化したりすることがある。卵白リゾ
チームは溶菌作用があり、その量は、0.01〜
0.05wt%が好ましい。添加量が0.01wt%未満で
は、上記効果が発揮されず、0.05wt%を越える
と、高価なものであるため、経済性を失う。
この他、必要に応じて添加されるものとしてプ
ロピレングリコールがある。これはエタノールの
蒸気圧を低下させ、一般菌の増殖を抑制するが、
液状高浸透圧物質がプロピレングリコールの場合
には当然のことながら使用されない。使用される
場合の量は、1〜3wt%が好ましい。量が1wt%
未満では、上記効果がなく、3wt%を越えると直
接脱水液の粘度が上り、エネルギーコストが高く
なり、またアミノ酸の溶解量が低下する。
このように、液状高浸透圧物質にエタノール、
アミノ酸またはその塩より選ばれた少なくとも一
種類を配合した直接脱水液、或いは上記直接脱水
液にさらに有機酸またはその塩、卵白リゾチーム
より選ばれた一種以上および必要に応じてプロピ
レングリコールを配合した直接脱水液は、カビが
発生しにくく、一般菌の増殖も遅く、腐敗が遅延
され、食品の直接脱水液としての使用を長期にわ
たつて可能とする。
〔実施例〕
次に実施例、比較例を示して本発明を説明す
る。
実施例 1
厚さ18μmのビニロンシート(東京セロハン紙
株式会社製、LH−18)を用いて、新鮮ないわ
し、ステーキ用牛肉それぞれ100gを別個に真空
包装し、これらを2℃に保持したエタノール
0.5wt%、グリシン0.5wt%を含む別個の濃度
50wt%のシヨ糖水溶液に、それぞれ24時間浸漬
した。
これを繰返して、いわし、牛肉それぞれ300g
を浸漬処理した。これら、いわし、牛肉をそれぞ
れ処理した液のはいつた容器の上部を開き、20℃
の室内に5時間放置した後密閉して、経時的一般
菌数、カビ発生の有無、臭いを調べた。結果を第
1表に示す。
[Industrial Field of Application] The present invention relates to a direct dehydration solution for foods that can be dehydrated to a desired dehydration rate without changing the taste of the food, and can be used repeatedly over a long period of time. [Conventional technology] If only water is removed without altering the quality of the food, food can be kept fresh, prevented from freezing, and improved in shape retention.
Reduced heating energy and heating time during cooking, etc.
Due to its many advantages, various research efforts have been conducted to dehydrate foods at low temperatures using osmotic pressure differences. This method uses a special sheet that combines a high osmotic pressure substance and a water-permeable semipermeable membrane (hereinafter referred to as semipermeable membrane), as described in Japanese Patent Publication No. 58-58124, USP-4383376, etc. This is a method of dehydrating food by wrapping it in a substance like this. However, this method is difficult to automate with a machine, requires manpower, and is unsuitable for mass production. Therefore, the present inventors first packaged food in a semi-permeable membrane and immersed it in a direct dehydration solution of a high osmotic substance for a predetermined period of time to dehydrate the food to the desired dehydration rate and absorb water etc. The directly dehydrated liquid is depressurized and
The above problem was solved by removing these and repeatedly using them. However, the above-mentioned direct dehydration solution has the disadvantage that the growth rate of common bacteria is fast and it is easily putrefied, making it unsustainable for long-term use. [Prior art and its problems] In view of the above circumstances, the present invention aims to provide a direct dehydration solution that does not spoil and can be used for a relatively long period of time. [Means for Solving the Problems] The present invention has been made to achieve the above object, and its gist is that food packaged in a water-permeable semi-permeable membrane is packaged through the water-permeable semi-permeable membrane. A direct dehydration solution for food that absorbs and removes moisture in the food through a water-permeable semipermeable membrane;
A direct dehydration solution of food consisting of ethanol and at least one selected from amino acids or salts thereof, or a liquid hyperosmotic substance, ethanol, at least one selected from amino acids or salts thereof, and an organic acid or salt thereof. , in the direct dehydration of foods containing one or more selected types of egg white lysozyme. [Specific structure and operation of the invention] The present invention will be explained in detail below. Foods targeted by the present invention include fresh animal foods such as raw seafood and meat, and plant foods such as vegetables and fruits, and in particular foods whose preservability is increased by dehydration and whose freeze resistance is improved. Foods, foods with improved taste, foods with improved cooking properties, etc. In addition, the semipermeable membrane used is one that allows water and molecules approximately the same size as water to pass through, but does not allow polymeric materials to pass through, and is safe even when it comes into direct contact with food. for example,
Low-stretchability vinylon film, ordinary cellophane, collodion film, ethylene vinyl acetate copolymer film, etc. are suitable. These films allow water and unnecessary components in food, such as ammonia, trimethylamine, dimethylamine, formaldehyde, and salt, to pass through, but they hardly allow active ingredients such as proteins, sugars, minerals, and vitamins to pass through. Furthermore, the liquid high osmotic pressure substance that is the main component of the direct dehydration solution according to the present invention must be one that does not substantially pass through the semipermeable membrane, but it is not possible to completely prevent its permeation. , those approved for use as foods, food additives, and food processing materials are used. For example, concentrated aqueous solutions of sugars such as starch syrup and sucrose, natural polymers such as mannans, sodium alginate, carrageenan, and gum arabic, synthetic polymers or compounds such as methylcellulose, sodium polyacrylate, glycerin, and propylene glycol. is suitable. Further, among the substances added to the liquid high osmotic pressure substance, ethanol is used to suppress the growth of mold, and the amount thereof is preferably 0.5 to 5 wt% in terms of the concentration in the direct dehydration liquid. If this amount is less than 0.5 wt%, there is no effect of suppressing the growth of mold, and if it exceeds 5%, it is not only uneconomical, but also gives the food an alcohol odor and reduces the amount of dissolved amino acids.
The amino acid or its salt suppresses the growth of general bacteria, and for example, glycine, glutamic acid, alanine, or salts thereof are used, and the amount thereof is preferably 0.5 to 2 wt%, and if the amount is less than 0.5 wt%, ,
It has no inhibitory effect on general bacteria, and if it exceeds 2wt%, crystals may be more likely to precipitate or food may taste or color. Addition of the above-mentioned ethanol, amino acids or their salts greatly retards the spoilage of the directly dehydrated liquid, but adding organic acids or their salts, egg white lysozyme, and propylene glycol exerts various effects and further delays the spoilage. be done. In other words, organic acids or their salts have the effect of neutralizing generated NH 3 , amines, etc. and lowering the pH. For example, malic acid, citric acid, acetic acid, ascorbic acid, sorbic acid, or their salts are used. , the amount is
0.1-1wt% is preferable, and if the amount is less than 0.1wt%, the PH
If it exceeds 1wt%, the equipment and materials become expensive, and the food may develop an odor or change in taste. Egg white lysozyme has a bacteriolytic effect, and its amount ranges from 0.01 to
0.05wt% is preferred. If the amount added is less than 0.01 wt%, the above effect will not be exhibited, and if it exceeds 0.05 wt%, it will be expensive and lose economic efficiency. In addition, propylene glycol is added as necessary. This lowers the vapor pressure of ethanol and suppresses the growth of general bacteria, but
Naturally, it is not used when the liquid hyperosmolar substance is propylene glycol. When used, the amount is preferably 1 to 3 wt%. The amount is 1wt%
If it is less than 3 wt%, the above effect will not be obtained, and if it exceeds 3 wt%, the viscosity of the direct dehydration solution will increase, energy cost will increase, and the amount of dissolved amino acids will decrease. In this way, ethanol, liquid hyperosmotic substance,
A direct dehydration solution containing at least one selected from amino acids or their salts, or a direct dehydration solution containing at least one selected from amino acids or salts thereof, or organic acids or salts thereof, one or more selected from egg white lysozyme, and propylene glycol as necessary. The dehydrating liquid is resistant to the growth of mold, the growth of common bacteria is slow, and spoilage is delayed, making it possible to use it as a direct dehydrating liquid for foods over a long period of time. [Example] Next, the present invention will be explained with reference to Examples and Comparative Examples. Example 1 100g each of fresh sardines and steak beef were vacuum-packed separately using 18μm-thick vinylon sheets (manufactured by Tokyo Cellophane Paper Co., Ltd., LH-18), and the ethanol was kept at 2°C.
0.5wt%, separate concentrations containing 0.5wt% glycine
Each sample was immersed in a 50wt% sucrose aqueous solution for 24 hours. Repeat this and add 30g each of sardines and beef.
was immersed. Open the top of the container containing the liquid from which sardines and beef were processed, and heat it to 20°C.
After being left in a room for 5 hours, it was sealed and the general bacterial count, presence of mold growth, and odor were examined over time. The results are shown in Table 1.
【表】
比較例 1
エタノール、グリシンを含まない脱水液を用い
た他は、実施例1と全く同じにして、経時的一般
菌数、カビ発生の有無、臭いを調べた。結果を第
2表に示す。[Table] Comparative Example 1 The same procedure as in Example 1 was used except that a dehydrated solution containing no ethanol or glycine was used, and the general bacterial count over time, presence or absence of mold growth, and odor were examined. The results are shown in Table 2.
【表】【table】
【表】
第1表および第2表より、アルコール、グリシ
ンを含まない脱水液は、一般菌の増加、カビおよ
び腐敗臭の発生が早く、短期間に変質することが
わかる。
実施例 2
脱水液として、エタノール5wt%、グリシン
2wt%、dl−リンゴ酸1wt%、卵白リゾチーム
0.05wt%、プロピレングリコール3wt%を含む
30wt%の水あめ水溶液1を用い、容器開放時
の室温を25℃とした他は実施例1と同じ操作、条
件で経時的な一般菌数、カビの発生の有無、臭い
を調べた。結果を第3表に示す。[Table] From Tables 1 and 2, it can be seen that the dehydrated liquid that does not contain alcohol or glycine increases the number of general bacteria, generates mold and putrid odor quickly, and deteriorates in a short period of time. Example 2 As dehydrating liquid, 5 wt% ethanol and glycine
2wt%, dl-malic acid 1wt%, egg white lysozyme
Contains 0.05wt%, propylene glycol 3wt%
Using 30 wt% starch syrup aqueous solution 1 and using the same procedures and conditions as in Example 1, except that the room temperature at the time of opening the container was 25° C., the general bacterial count, presence or absence of mold growth, and odor were examined over time. The results are shown in Table 3.
【表】
比較例 2
エタノール、グリシン、dl−リンゴ酸、卵白リ
ゾチーム、プロピレングリコールを含まない脱水
液を用いた他は、実施例2と全く同じ操作、条件
で、経時的な一般菌数、カビの発生有無、臭いを
調べた。結果を第4表に示す。[Table] Comparative Example 2 The general bacterial count and mold count over time were determined using the same operations and conditions as in Example 2, except that a dehydrated solution containing no ethanol, glycine, dl-malic acid, egg white lysozyme, or propylene glycol was used. The presence or absence of odor was investigated. The results are shown in Table 4.
以上述べたように、本発明に係る食品の直接脱
水液は、経時的な変質が少なく、吸収した水分を
減圧除去すれば、反復使用することが可能で、極
めて効率的な食品の直接脱水が出来る。
As mentioned above, the direct dehydration solution for food according to the present invention has little deterioration over time, and can be used repeatedly by removing absorbed water under reduced pressure, making it extremely efficient for direct dehydration of food. I can do it.
Claims (1)
性半透膜を介して接触させ、食品中の水分を透水
性半透膜を通して吸収除去する食品の直接脱水液
であつて、液状高浸透圧物質、エタノール、およ
びアミノ酸またはその塩から選ばれた少なくとも
一種類よりなることを特徴とする食品の直接脱水
液。 2 透水性半透膜に包装された食品に、上記透水
性半透膜を介して接触させ、食品中の水分を透水
性半透膜を通して吸収除去する食品の直接脱水液
であつて、液状高浸透圧物質、エタノール、およ
びアミノ酸またはその塩より選ばれた少なくとも
一種類と、有機酸またはその塩、卵白リゾチーム
より選ばれた一種類以上を含むことを特徴とする
食品の直接脱水液。[Scope of Claims] 1. A direct dehydration solution for food, which is brought into contact with food packaged in a water-permeable semi-permeable membrane through the water-permeable semi-permeable membrane, and absorbs and removes moisture in the food through the water-permeable semi-permeable membrane. 1. A direct dehydration solution for food, which comprises at least one selected from a liquid hyperosmotic substance, ethanol, and an amino acid or a salt thereof. 2 A direct dehydration liquid for food that is brought into contact with food packaged in a water-permeable semi-permeable membrane through the water-permeable semi-permeable membrane, and absorbs and removes water in the food through the water-permeable semi-permeable membrane. A direct dehydration solution for food, characterized by containing at least one selected from osmotic substances, ethanol, and amino acids or salts thereof, and at least one selected from organic acids or salts thereof, and egg white lysozyme.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7620586A JPS62232366A (en) | 1986-04-02 | 1986-04-02 | Solution for dehydrating food directly |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7620586A JPS62232366A (en) | 1986-04-02 | 1986-04-02 | Solution for dehydrating food directly |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62232366A JPS62232366A (en) | 1987-10-12 |
JPH0259714B2 true JPH0259714B2 (en) | 1990-12-13 |
Family
ID=13598656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7620586A Granted JPS62232366A (en) | 1986-04-02 | 1986-04-02 | Solution for dehydrating food directly |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62232366A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0728711B2 (en) * | 1986-11-27 | 1995-04-05 | 株式会社リブ・インタ−ナシヨナル | How to dehydrate food |
-
1986
- 1986-04-02 JP JP7620586A patent/JPS62232366A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS62232366A (en) | 1987-10-12 |
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