JPH0259022A - Reaction apparatus of waste gas smokestack - Google Patents

Reaction apparatus of waste gas smokestack

Info

Publication number
JPH0259022A
JPH0259022A JP63210099A JP21009988A JPH0259022A JP H0259022 A JPH0259022 A JP H0259022A JP 63210099 A JP63210099 A JP 63210099A JP 21009988 A JP21009988 A JP 21009988A JP H0259022 A JPH0259022 A JP H0259022A
Authority
JP
Japan
Prior art keywords
inner cylinder
reducing agent
flue
exhaust gas
smokestack
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63210099A
Other languages
Japanese (ja)
Other versions
JP2690751B2 (en
Inventor
Meiji Ito
明治 伊東
Masahiro Nitta
昌弘 新田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Power Ltd
Original Assignee
Babcock Hitachi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Hitachi KK filed Critical Babcock Hitachi KK
Priority to JP63210099A priority Critical patent/JP2690751B2/en
Publication of JPH0259022A publication Critical patent/JPH0259022A/en
Application granted granted Critical
Publication of JP2690751B2 publication Critical patent/JP2690751B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)

Abstract

PURPOSE:To prevent adhesion of scales and lowering the strength of the walls of a smokestack due to thermal impact by dividing the flow of the waste gas by installing an inner cylinder in the smokestack, and setting a reducing agent spraying nozzle to spray a reaction material in the inside of the inner cylinder. CONSTITUTION:A waste gas flows in a smokestack pipe 4 from down side to up side and is divided by an inner cylinder 2 to inside and outside of the inner cylinder, and an aqueous solution containing a reducing agent is sprayed with rotation through a reducing agent spraying nozzle 6 to the flow in the inside of the inner cylinder. Because water-drops from the reducing agent spraying nozzle 6 collide against the inner walls of the inner cylinder 2 and even though the situation is different depending on the size of the water drops, sprayed condition, and the gas flow, the inner cylinder 2 is possibly cooled to water boiling temperature, 100 deg.C, locally. However, since the inner cylinder 2 is heated by a gas flowing outside, the wall temperature is not decreased as compared to the case of no gas flow outside, and as a result, scale adhesion and thermal impact is lessened. The smokestack pipe 4 is protected from a sprayed material by the inner cylinder 2.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は排ガス煙道の反応装置に係り、特に排ガス脱硝
用の還元剤を水溶液の噴霧で添加する場合の煙道保護に
好適な排ガス煙道の反応装置に関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a reaction device for an exhaust gas flue, and in particular to an exhaust gas smoke suitable for flue protection when a reducing agent for exhaust gas denitrification is added as an aqueous solution spray. Regarding the road reactor.

〔従来の技術〕[Conventional technology]

石炭、石油などの化石燃料を用いる燃焼装置から発生す
る窒素酸化物(NOx)は有害であり、排出を極力少な
くする努力がなされている。窒素酸化物の低減はまず発
生を押さえ、次いで発生したものはアンモニア等の還元
剤を添加して反応させ、無害化する方法が一般的である
。例えば火力発電所の大型ボイラでは、まず低NOx燃
焼によってNOx発生を押さえ、次いで排ガスにアンモ
ニアを添加し、脱硝反応器でNOxを処理した後に大気
中に放出している。都市部における暖房用の小型ボイラ
等では、単機光たりの排ガス放出量が少なく法規制が緩
やかなこともあり、排ガス中の窒素酸化物処理までは実
施されていなかった。
Nitrogen oxides (NOx) generated from combustion equipment that uses fossil fuels such as coal and oil are harmful, and efforts are being made to reduce emissions as much as possible. A common method for reducing nitrogen oxides is to first suppress their generation, and then add a reducing agent such as ammonia to react with the generated nitrogen oxides to render them harmless. For example, in a large boiler at a thermal power plant, NOx generation is first suppressed by low NOx combustion, then ammonia is added to the exhaust gas, and the NOx is treated in a denitrification reactor before being released into the atmosphere. For small boilers used for heating in urban areas, the amount of exhaust gas emitted per unit is small and laws and regulations are lenient, so treatment of nitrogen oxides in the exhaust gas has not been carried out.

ところが最近、都市大気の排ガスによる汚染が進み、都
市部の小規模の排ガス発生源も法規制が厳しくなり、よ
り小型の排ガス脱硝装置が付設され、窒素酸化物が処理
される傾向にある。一般にこのような化学装置を小規模
にする場合、単に縮小させるだけでは不具合が生じ熱、
物質および運動量の移動を加味した機械的な再検討が必
要である。
Recently, however, pollution of urban air by exhaust gas has increased, and laws and regulations have become stricter for small-scale exhaust gas generating sources in urban areas, and there is a trend for smaller exhaust gas denitration equipment to be installed to treat nitrogen oxides. Generally, when making such chemical equipment small-scale, simply scaling it down will cause problems and generate heat and heat.
A mechanical reexamination that takes into account the transfer of mass and momentum is necessary.

大型の脱硝装置では、人が通行できるような巨大な煙道
断面に数多くの還元剤噴射口を設けて排ガスに希釈した
アンモニアガスを噴射しており、噴射したアンモニアガ
スの壁面への影響は無視できる。しかし、装置が小型に
なるほど煙道の径が小さくなり、単位量のガスと接触す
る煙道壁面の面積が広くなり、添加した還元剤が均一に
ならないまま壁面に接触する機会が増す。これは、排ガ
スより通常かなり低温である還元剤が局在化したまま壁
面に接触するので、部分的に壁面が冷却される機会が増
すことになる。
In large denitrification equipment, ammonia gas diluted with exhaust gas is injected by installing many reducing agent injection ports in a huge flue cross section that people can pass through, and the effect of the injected ammonia gas on the wall is ignored. can. However, as the device becomes smaller, the diameter of the flue becomes smaller and the area of the flue wall that comes into contact with a unit amount of gas becomes larger, increasing the chances that the added reducing agent will come into contact with the wall surface without being uniform. This increases the chance that the wall surface will be partially cooled, since the reducing agent, which is usually much cooler than the exhaust gas, contacts the wall surface in a localized manner.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記従来技術では、排ガスより温度が低く、通常大気温
度に等しい還元剤を排ガスに混合すると、小口径の煙道
はど煙道壁面に局所的な冷却が生じ、その部分に排ガス
中のタール、硫安等のスケールが付着する危険性が増す
問題がある。この問題は、還元剤としてアンモニア等の
ガスを用いる場合にはそれほど障害とはならない。しか
し、脱硝反応には脱硝触媒の種類により反応に通した温
度があり、排ガスの温度をその温度まで下げるために還
元剤としてアンモニア、尿素等の水溶液を用いる場合が
あり、この場合に大きな問題となる。すなわち、水溶液
では噴霧して微少な水滴としても、ガスと混合して蒸発
する前に煙道壁面に衝突したものは集合して液膜を作り
易く、気化時に蒸発潜熱を吸収するため壁面の温度が低
下し、局所的な温度低下が大きいと熱衝撃により壁面の
強度が次第に低下するという問題が生じる。また、還元
剤が尿素の場合にはさらに還元剤そのものがスケールと
して壁面にM積される欠点が生じる。
In the above-mentioned conventional technology, when a reducing agent whose temperature is lower than that of the exhaust gas and is normally equal to the atmospheric temperature is mixed with the exhaust gas, local cooling occurs on the flue wall surface of the small-diameter flue, and the tar in the exhaust gas, There is a problem that the risk of adhesion of scales such as ammonium sulfate increases. This problem is less of a problem when a gas such as ammonia is used as the reducing agent. However, the temperature required for the denitration reaction depends on the type of denitration catalyst, and in order to lower the temperature of the exhaust gas to that temperature, an aqueous solution of ammonia, urea, etc. may be used as a reducing agent, which poses a major problem. Become. In other words, even if an aqueous solution is sprayed into minute water droplets, those that collide with the flue wall before mixing with gas and evaporating tend to aggregate and form a liquid film, and the temperature of the wall surface increases as it absorbs the latent heat of vaporization during vaporization. If the local temperature drop is large, a problem arises in that the strength of the wall surface gradually decreases due to thermal shock. Furthermore, when the reducing agent is urea, there is a further drawback that the reducing agent itself is deposited as scale on the wall surface.

本発明の目的は、上記従来技術の欠点をなくし、還元剤
混合部における煙道壁面へのスケールの付着、および熱
衝撃による煙道壁面の強度低下を防止することができる
排ガス煙道の反応装置を提供することにある。
An object of the present invention is to provide a reactor for an exhaust gas flue, which can eliminate the drawbacks of the prior art described above and prevent scale from adhering to the flue wall in the reducing agent mixing section and from reducing the strength of the flue wall due to thermal shock. Our goal is to provide the following.

〔課題を解決するための手段〕[Means to solve the problem]

上記目的は、燃焼排ガス煙道に排ガス中の特定成分と反
応する物質を添加し、下流の煙道または反応器で反応さ
せ排ガスを浄化するものにおいて、前記煙道に内筒を設
けて排ガスの流れを内筒の内と外に分割し、内筒の内側
に反応物質を噴射する還元剤噴射ノズルを配置したこと
を特徴とする排ガス煙道の反応装置により達成される。
The above purpose is to purify the exhaust gas by adding a substance that reacts with a specific component in the exhaust gas to the flue gas flue and causing the reaction to occur in the downstream flue or reactor. This is achieved by an exhaust gas flue reactor characterized in that the flow is divided into the inside and outside of the inner cylinder, and a reducing agent injection nozzle for injecting the reactant is arranged inside the inner cylinder.

本発明においては、内筒の内壁および/または外壁に羽
根を設け、これに傾斜をもたせて排ガスを旋回させるこ
とが好ましい。
In the present invention, it is preferable that blades be provided on the inner wall and/or the outer wall of the inner cylinder, and the blades be inclined to swirl the exhaust gas.

〔作用〕[Effect]

還元剤噴射ノズルより排ガス中に噴射された低温で高濃
度の還元剤は、内筒に妨げられて煙道壁面には接触せず
、内筒内で充分に排ガスと混合され、希釈されて内筒か
ら出た後に煙道壁面と接触する。一方、内筒壁面は噴射
された還元剤で局所的に冷却されるが、煙道壁面と異な
り外側を流れる排ガスによって加熱されているので内筒
壁面の温度低下が少なく、したがってスケールの付着も
少ない。また、内筒に熱衝撃が加わり強度低下が生じる
ことがあっても、内筒は煙道壁面と異なり外部から荷重
が加わることもないので問題となることはない。
The low-temperature, high-concentration reducing agent injected into the exhaust gas from the reducing agent injection nozzle is blocked by the inner cylinder and does not come into contact with the flue wall, but is sufficiently mixed with the exhaust gas in the inner cylinder, diluted, and released into the exhaust gas. After coming out of the tube, it comes into contact with the flue wall. On the other hand, the inner cylinder wall surface is locally cooled by the injected reducing agent, but unlike the flue wall surface, it is heated by the exhaust gas flowing outside, so the temperature drop on the inner cylinder wall surface is small, and therefore there is less scale adhesion. . Further, even if a thermal shock is applied to the inner cylinder, causing a decrease in its strength, this will not be a problem because unlike the flue wall, no load is applied to the inner cylinder from the outside.

〔実施例〕〔Example〕

以下、本発明を実施例を用いて詳細に説明する。 Hereinafter, the present invention will be explained in detail using examples.

第1図は、本発明による排ガス煙道の反応装置をディー
ゼルエンジンの排ガス脱硝に適用した場合の装置系統図
である。本発明の特徴である内筒2は、煙道配管4内に
配置され、還元剤噴射ノズル6の下流に配置される。デ
ィーゼルエンジン11で発生した排ガスは、煙道配管4
内を通り内筒2により内筒内側と外側に分割されて流れ
、内側の流れに還元剤噴射ノズル6より還元剤が噴射さ
れた後、それぞれ脱硝反応器12に送られ、脱硝触媒上
で排ガス中の窒素酸化物と還元剤が反応して浄化された
後、熱交換器13で廃熱が回収され、消音器14を通っ
て煙突15より排出される。
FIG. 1 is an apparatus system diagram when the exhaust gas flue reaction apparatus according to the present invention is applied to exhaust gas denitrification of a diesel engine. The inner cylinder 2, which is a feature of the present invention, is disposed within the flue pipe 4 and downstream of the reducing agent injection nozzle 6. The exhaust gas generated by the diesel engine 11 is transferred to the flue pipe 4.
The flow is divided into the inside and outside of the inner cylinder by the inner cylinder 2, and after the reducing agent is injected into the inner flow from the reducing agent injection nozzle 6, it is sent to the denitrification reactor 12, and the exhaust gas is treated on the denitrification catalyst. After the nitrogen oxides and reducing agent inside react and are purified, the waste heat is recovered in the heat exchanger 13, passes through the muffler 14, and is discharged from the chimney 15.

ディーゼルエンジン11で発生する排ガスの温度は、運
転状態によって異なるが、通常450〜600℃である
。一方、例えばチタン系の脱硝触媒を充填した脱硝反応
器12に適した温度は350〜500℃である。通常、
還元剤の添加だけでは排ガス温度は低下しても5℃まで
であることから、排ガス温度を約100℃低下させるた
め、還元剤とともに水が噴霧される。
The temperature of the exhaust gas generated by the diesel engine 11 varies depending on the operating condition, but is usually 450 to 600°C. On the other hand, a suitable temperature for the denitrification reactor 12 filled with, for example, a titanium-based denitrification catalyst is 350 to 500°C. usually,
If only the reducing agent is added, the exhaust gas temperature decreases by 5° C., so water is sprayed together with the reducing agent in order to lower the exhaust gas temperature by about 100° C.

第2図は、本発明の煙道の反応装置の一実施例を示す断
面図、第3図は、第2図のm−m線に、沿った矢視方向
断面図である。この装置は、煙道配管4と、その内側に
設けられた還元剤噴射ノズル6と、該噴射ノズル6の噴
射口を囲み、ガス流れ方向に配置された内筒2と、この
内筒2の下流側の内壁および外壁に設けられた羽根1お
よび羽根3とから主に構成される。内筒内壁の羽根1は
、内筒内のガスの流れを旋回させるために傾斜をもたせ
て螺旋状に設けられ、さらに内筒外壁の羽根3は、外側
のガスを内側のガスと逆に旋回させるために内側と逆の
角度で傾斜をもたせて設けられている。
FIG. 2 is a cross-sectional view showing one embodiment of the flue reactor of the present invention, and FIG. 3 is a cross-sectional view taken along the line mm in FIG. 2 in the direction of the arrows. This device includes a flue pipe 4, a reducing agent injection nozzle 6 provided inside the flue pipe, an inner cylinder 2 surrounding the injection nozzle of the injection nozzle 6 and arranged in the gas flow direction, and an inner cylinder 2 arranged in the gas flow direction. It is mainly composed of blades 1 and 3 provided on the inner and outer walls of the downstream side. The blades 1 on the inner wall of the inner cylinder are provided in a spiral shape with an inclination to swirl the flow of gas in the inner cylinder, and the blades 3 on the outer wall of the inner cylinder swirl the gas on the outside in the opposite direction to the gas inside. It is provided with an inclination at the opposite angle to the inside to make it easier to move.

上記構成において、排ガスは煙道配管4内を下から上へ
流れ(第2図)、内筒2により内筒内側と外側に二分さ
れ、内側の流れには還元剤噴射ノズル6より還元剤水溶
液が旋回して噴霧される。
In the above configuration, the exhaust gas flows from the bottom to the top in the flue pipe 4 (Fig. 2), and is divided into two by the inner cylinder 2 into the inner side and the outside of the inner cylinder, and the inner flow is injected with a reducing agent aqueous solution from the reducing agent injection nozzle 6. swirls and is sprayed.

噴霧された還元剤水溶液および排ガスは、さらに下流の
内筒内壁の羽根1で旋回が強められ、内筒2の外に送ら
れる。一方、内筒2の外側を流れる排ガスは、内筒2お
よび内筒外壁の羽根3を加熱し、同時に羽根3のねじれ
によって旋回され、内筒2の出口で内側のガスと逆方向
の旋回により内側のガスおよび還元剤と衝突し混合され
る。内筒2の内壁には還元剤噴射ノズル6からの水滴が
衝突するため、水滴の大きさ、噴射状態、ガス流れによ
って異なるものの、内筒2は局所的に水の沸点である温
度100℃まで低下する危険性がある。
The atomized reducing agent aqueous solution and exhaust gas are further swirled by the blades 1 on the inner wall of the inner cylinder downstream, and are sent out of the inner cylinder 2. On the other hand, the exhaust gas flowing outside the inner cylinder 2 heats the inner cylinder 2 and the blades 3 on the outer wall of the inner cylinder, is simultaneously swirled by the twist of the blades 3, and at the outlet of the inner cylinder 2 is swirled in the opposite direction to the inner gas. It collides with and mixes with the gas and reducing agent inside. Since the water droplets from the reducing agent injection nozzle 6 collide with the inner wall of the inner cylinder 2, the temperature of the inner cylinder 2 locally reaches up to 100°C, which is the boiling point of water, although it varies depending on the size of the water droplets, the injection condition, and the gas flow. There is a risk of decline.

しかし、内筒2は外側のガスによって加熱されているの
で、外側をガスが流れない場合に較べて壁面温度が冷却
されず、したがってスケール付着とか熱衝撃は少なくな
る。煙道配管4は内筒2によって噴射物から保護される
。なお、内筒2は煙道配管4によって周囲の荷重から保
護されるので強度を必要としない。
However, since the inner cylinder 2 is heated by the gas outside, the wall surface temperature is not cooled as much as when no gas flows outside, and therefore scale adhesion and thermal shock are reduced. The flue pipe 4 is protected from propellants by the inner cylinder 2. Note that the inner cylinder 2 is protected from surrounding loads by the flue pipe 4, and therefore does not require strength.

第4図は、内筒2の他の実施例を示す側面図、第5図は
、第4図の底面図である。内筒の強度を必要としないの
で単に薄板を折り曲げただけの構造でも充分に使用でき
る。
FIG. 4 is a side view showing another embodiment of the inner cylinder 2, and FIG. 5 is a bottom view of FIG. 4. Since the strength of the inner cylinder is not required, a structure made by simply bending a thin plate can be used satisfactorily.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、煙道壁面が添加した還元剤によって冷
却されることがないので、スケール付着の危険性が少な
くなるとともに、局所的な冷却、加熱の繰返しによる熱
衝撃により煙道配管の強度低下もない。
According to the present invention, since the flue wall surface is not cooled by the added reducing agent, the risk of scale adhesion is reduced, and the flue piping is strengthened by thermal shock caused by repeated local cooling and heating. There is no decline.

また、本発明により内筒の内と外を流れるガス流れ方向
を変えた場合には、内筒出口のガス合流時にガスが撹乱
され、排ガスと還元剤との混合をより促進する効果があ
る。
Furthermore, when the flow direction of the gas flowing inside and outside the inner cylinder is changed according to the present invention, the gas is disturbed when the gases merge at the outlet of the inner cylinder, which has the effect of further promoting the mixing of the exhaust gas and the reducing agent.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明による排ガス煙道の反応装置を用いた
ディーゼル排ガス処理装置の系統図、第2図は、本発明
による反応装置の一実施例を示す断面図、第3図は、第
2図のm−m線に沿った矢視方向断面図、第4図は、本
発明に用いる内筒の他の実施例を示す側面図、第5図は
、第4図の底面図である。 1・・・内筒内壁の羽根、2・・・内筒、3・・・内筒
外壁の羽根、4・・・煙道配管、5・・・保温材、6・
・・還元剤噴射ノズル、7・・・還元剤導管、8・・・
噴射用空気導管、9・・・圧縮空気、10・・・還元剤
。 代理人 弁理士 川 北 武 長 内筒 煙道配管 還元剤噴射ノズル 還元剤導管 ディーゼルエンジン 脱硝反応器 熱交換器 消音器 煙突 第 第
FIG. 1 is a system diagram of a diesel exhaust gas treatment device using an exhaust gas flue reactor according to the present invention, FIG. 2 is a sectional view showing an embodiment of the reactor according to the present invention, and FIG. 2 is a sectional view taken along the line m-m in FIG. 2, FIG. 4 is a side view showing another embodiment of the inner cylinder used in the present invention, and FIG. 5 is a bottom view of FIG. 4. . DESCRIPTION OF SYMBOLS 1... Blades on the inner wall of the inner cylinder, 2... Inner cylinder, 3... Blades on the outer wall of the inner cylinder, 4... Flue piping, 5... Heat insulating material, 6...
...Reducing agent injection nozzle, 7... Reducing agent conduit, 8...
Air conduit for injection, 9... Compressed air, 10... Reducing agent. Agent Patent Attorney Takeshi Kawakita Osanai cylinder Flue piping Reducing agent injection nozzle Reducing agent conduit Diesel engine denitrification reactor Heat exchanger Silencer Chimney No.

Claims (2)

【特許請求の範囲】[Claims] (1)燃焼排ガス煙道に排ガス中の特定成分と反応する
物質を添加し、下流の煙道または反応器で反応させ排ガ
スを浄化するものにおいて、前記煙道に内筒を設けて排
ガスの流れを内筒の内と外に分割し、内筒の内側に反応
物質を噴射する還元剤噴射ノズルを配置したことを特徴
とする排ガス煙道の反応装置。
(1) In a combustion exhaust gas flue in which a substance that reacts with a specific component in the exhaust gas is added and the flue gas is reacted in a downstream flue or reactor to purify the flue gas, an inner tube is provided in the flue to direct the flow of the flue gas. 1. A reactor for an exhaust gas flue, characterized in that an inner cylinder is divided into an inside and an outside part, and a reducing agent injection nozzle for injecting a reactant is arranged inside the inner cylinder.
(2)内筒の内壁および/または外壁に羽根を設けたこ
とを特徴とする請求項(1)記載の排ガス煙道の反応装
置。
(2) The reactor for an exhaust gas flue according to claim (1), characterized in that vanes are provided on the inner wall and/or outer wall of the inner cylinder.
JP63210099A 1988-08-24 1988-08-24 Exhaust gas flue reactor Expired - Fee Related JP2690751B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63210099A JP2690751B2 (en) 1988-08-24 1988-08-24 Exhaust gas flue reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63210099A JP2690751B2 (en) 1988-08-24 1988-08-24 Exhaust gas flue reactor

Publications (2)

Publication Number Publication Date
JPH0259022A true JPH0259022A (en) 1990-02-28
JP2690751B2 JP2690751B2 (en) 1997-12-17

Family

ID=16583800

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63210099A Expired - Fee Related JP2690751B2 (en) 1988-08-24 1988-08-24 Exhaust gas flue reactor

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Country Link
JP (1) JP2690751B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007275838A (en) * 2006-04-11 2007-10-25 Babcock Hitachi Kk Exhaust gas denitration apparatus and its operation method
JP2013160224A (en) * 2012-02-03 2013-08-19 Man Diesel & Turbo Filial Af Man Diesel & Turbo Se Tyskland Turbo supercharging type large-sized two-stroke diesel engine with exhaust gas emission control function

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007275838A (en) * 2006-04-11 2007-10-25 Babcock Hitachi Kk Exhaust gas denitration apparatus and its operation method
JP4716325B2 (en) * 2006-04-11 2011-07-06 バブコック日立株式会社 Flue gas denitration device and operation method thereof
JP2013160224A (en) * 2012-02-03 2013-08-19 Man Diesel & Turbo Filial Af Man Diesel & Turbo Se Tyskland Turbo supercharging type large-sized two-stroke diesel engine with exhaust gas emission control function

Also Published As

Publication number Publication date
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