JPH025807B2 - - Google Patents
Info
- Publication number
- JPH025807B2 JPH025807B2 JP57148552A JP14855282A JPH025807B2 JP H025807 B2 JPH025807 B2 JP H025807B2 JP 57148552 A JP57148552 A JP 57148552A JP 14855282 A JP14855282 A JP 14855282A JP H025807 B2 JPH025807 B2 JP H025807B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- electrical contact
- resistance
- antimony
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 25
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 229910052787 antimony Inorganic materials 0.000 claims description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 9
- 229910052797 bismuth Inorganic materials 0.000 claims description 9
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 9
- 229910052738 indium Inorganic materials 0.000 claims description 9
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 238000003466 welding Methods 0.000 description 6
- 229910000410 antimony oxide Inorganic materials 0.000 description 5
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- MVPWCKPKSBBVTC-UHFFFAOYSA-N antimony;oxosilver Chemical compound [Sb].[Ag]=O MVPWCKPKSBBVTC-UHFFFAOYSA-N 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
Landscapes
- Manufacture Of Switches (AREA)
- Contacts (AREA)
Description
本発明は、電気接点材料に関するものである。
従来より内部酸化法により製作した電気接点材
料の一つとして銀−酸化アンチモンが用いられて
きた。銀−酸化アンチモンは、接触抵抗の安定
性、耐溶着性の優れた接点性能を有するが、アー
クによる消耗が大きく耐電圧、耐絶縁性に劣るも
のである。
そこで本発明者は、この電気接点材料よりもア
ークに対する耐消耗性に優れた接点特性を有する
電気接点材料を開発すべく鋭意考究の結果、満足
できる電気接点材料を見い出したものである。
本発明の電気接点材料の一つは、ビスマス0.1
〜５重量％、インジウム１〜10重量％、亜鉛１〜
10重量％、アンチモン１〜10重量％、残部銀から
成る材料であつて、且つ内部酸化されているもの
である。
本発明の電気接点材料の他の一つは、ビスマス
0.1〜５重量％、インジウム１〜10重量％、亜鉛
１〜10重量％、アンチモン１〜10重量％、鉄、ニ
ツケル、コバルト、ジルコニウムの少なくとも一
種0.01〜0.5重量％、残部銀から成る材料であつ
て、且つ内部酸化されているものである。
本発明の電気接点材料に於いて、ビスマス0.1
〜５重量％、インジウム１〜10重量％、亜鉛１〜
10重量％、アンチモン１〜10重量％とした理由
は、ビスマス0.1重量％未満では酸化アンチモン
の粒状析出を抑えて組織を均一にする効果がな
く、インジウム１重量％未満では耐溶着性を改善
する効果がなく、亜鉛１重量％未満では耐消耗性
向上の効果がなく、アンチモン１重量％未満では
耐溶着性に関しては良好な結果が得られず、また
ビスマス５重量％を越えると、合金の融点が下が
りすぎ高温での内部酸化が困難となり、インジウ
ム10重量％を越えると接点開閉時に酸化インジウ
ムが堆積して接触抵抗が上昇し、亜鉛10重量％を
越えると酸化亜鉛が層状に析出して接触抵抗が増
大し、アンチモン10重量％を越えると酸化物の粒
界析出が著しくなつて耐消耗性を劣化させるの
で、ビスマス0.1〜５重量％、インジウム１〜10
重量％、亜鉛１〜10重量％、アンチモン１〜10重
量％範囲内では、耐溶着性、耐消耗性、接触抵抗
特性の充分満足できる電気接点材料が得られるも
のである。
さらに本発明の電気接点材料の他の一つに於い
て、ビスマス0.1〜５重量％、インジウム１〜10
重量％、亜鉛１〜10重量％、アンチモン１〜10重
量％以外に鉄、ニツケル、コバルト、ジルコニウ
ムの少なくとも一種合計で0.01〜0.5重量％添加
する理由は、これを電気接点材料に分散させた場
合、これにより得られる酸化ビスマス、酸化イン
ジウム、酸化亜鉛及び酸化アンチモンの均一微細
な分散によつて、放電による消耗が一層減少する
からであつて、0.01重量％未満では酸化ビスマ
ス、酸化インジウム、酸化亜鉛及び酸化アンチモ
ンが均一微細な分散せず、0.5重量％を越えると
それ自体の偏析が増加するからである。
次に本発明による電気接点材料の効果を明瞭な
らしめる為に、具体的な実施例と従来例について
説明する。
下記の表の左欄に示す実施例１〜10の成分組成
の材料を溶解し、アトマイズ粉となした後、600
℃、９気圧、２日間内部酸化し、この酸化アトマ
イズ粉を圧縮焼結し、これを押出、引抜加工した
後切断してヘツダ−加工し、頭部径５mm、頭高１
mm、脚部径2.5mm、脚長2.5mmの固定接点と頭部径
４mm、頭高1.1mm、脚部径2.8mm、脚長1.6mm、頭部
球状5Rの可動接点を得た。
然してこれら実施例１〜10の電気接点材料にて
作つたリベツト型電気接点と、下記の表の左欄に
示す従来例の成分組成の材料を実施例１、２と同
じ方法で作つた同一寸法のリベツト型電気接点を
ヒンジ型リレーに組み込み下記の試験条件にて開
閉試験を行つた処、下記の表の右欄に示すような
結果を得た。
試験条件
電圧：AC100V 50Hz
電流：投入40A、定常10A
負荷：抵抗
開閉頻度：20回／分
開閉回数：溶着発生迄
接触力：40ｇ
開離力：45ｇ
The present invention relates to electrical contact materials. Silver-antimony oxide has conventionally been used as one of the electrical contact materials manufactured by internal oxidation. Silver-antimony oxide has excellent contact properties such as stable contact resistance and welding resistance, but is subject to large wear due to arcing and is inferior in voltage resistance and insulation resistance. Therefore, the inventor of the present invention has conducted extensive research to develop an electrical contact material that has contact properties that are more resistant to arc wear than this electrical contact material, and as a result has found a satisfactory electrical contact material. One of the electrical contact materials of the present invention is bismuth 0.1
~5% by weight, indium 1~10% by weight, zinc 1~
The material consists of 10% by weight, 1-10% by weight of antimony, and the balance is silver, and is internally oxidized. Another electrical contact material of the present invention is bismuth
A material consisting of 0.1 to 5% by weight, indium 1 to 10% by weight, zinc 1 to 10% by weight, antimony 1 to 10% by weight, 0.01 to 0.5% by weight of at least one of iron, nickel, cobalt, and zirconium, and the balance being silver. and is internally oxidized. In the electrical contact material of the present invention, bismuth 0.1
~5% by weight, indium 1~10% by weight, zinc 1~
The reason for setting 10% by weight of bismuth and 1 to 10% by weight of antimony is that less than 0.1% by weight of bismuth does not have the effect of suppressing granular precipitation of antimony oxide and making the structure uniform, while less than 1% by weight of indium improves welding resistance. Zinc has no effect, less than 1% by weight of zinc has no effect on improving wear resistance, less than 1% by weight of antimony does not give good results in terms of welding resistance, and more than 5% by weight of bismuth lowers the melting point of the alloy. If the indium content is too low, internal oxidation at high temperatures becomes difficult, and if the indium content exceeds 10% by weight, indium oxide will accumulate during contact opening and closing, increasing contact resistance, and if the zinc content exceeds 10% by weight, a layer of zinc oxide will precipitate and the contact resistance will increase. The resistance increases, and if antimony exceeds 10% by weight, grain boundary precipitation of oxides becomes significant and wear resistance deteriorates.
Within the range of 1 to 10% by weight of zinc and 1 to 10% by weight of antimony, an electrical contact material with sufficiently satisfactory welding resistance, wear resistance, and contact resistance properties can be obtained. Furthermore, in another electrical contact material of the present invention, bismuth 0.1-5% by weight, indium 1-10%
The reason why at least one of iron, nickel, cobalt, and zirconium is added in a total of 0.01 to 0.5% by weight in addition to 1 to 10% by weight of zinc and 1 to 10% by weight of antimony is that when dispersed in the electrical contact material. This is because the resulting uniform and fine dispersion of bismuth oxide, indium oxide, zinc oxide and antimony oxide further reduces consumption due to discharge. This is because antimony oxide and antimony oxide are not uniformly and finely dispersed, and if the amount exceeds 0.5% by weight, segregation of the antimony oxide itself increases. Next, in order to clarify the effects of the electrical contact material according to the present invention, specific examples and conventional examples will be described. After melting the materials having the compositions of Examples 1 to 10 shown in the left column of the table below and making them into atomized powder, 600
℃, 9 atmospheres for 2 days, the oxidized atomized powder was compressed and sintered, extruded and drawn, then cut and processed into headers, with a head diameter of 5 mm and a head height of 1.
A fixed contact with a leg diameter of 2.5 mm, a leg length of 2.5 mm, and a movable contact with a head diameter of 4 mm, a head height of 1.1 mm, a leg diameter of 2.8 mm, a leg length of 1.6 mm, and a spherical head shape of 5R were obtained. However, the rivet-type electrical contacts made from the electrical contact materials of Examples 1 to 10 and the same dimensions made from the materials of the conventional examples shown in the left column of the table below by the same method as Examples 1 and 2. When the rivet-type electrical contact was assembled into a hinge-type relay and an opening/closing test was conducted under the test conditions below, the results shown in the right column of the table below were obtained. Test conditions Voltage: AC100V 50Hz Current: 40A, steady 10A Load: Resistance Switching frequency: 20 times/min Number of switching: Contact force until welding occurs: 40g Breaking force: 45g
【表】
尚、耐電圧については接点間AC1200V、10秒
印加し、リーク電流が10mA未満の場合合格
10mA以上の場合不合格とした。
上記の表で明らかなように実施例１〜10の電気
接点材料で作つたリベツト型電気接点は、従来例
の電気接点材料で作つたリベツト型電気接点に比
し、耐電圧性、耐消耗性に優れ、耐溶着性につい
ては略同等に優れていることが判る。
以上詳記した通り本発明の電気接点材料は、従
来の電気接点材料よりも耐電圧性、耐消耗性に優
れた接点特性を有するので、従来の電気接点材料
にとつて代わることのできる画期的なものと云え
る。[Table] Regarding the withstand voltage, apply 1200V AC between contacts for 10 seconds, and pass if the leakage current is less than 10mA.
If it was 10mA or more, it was considered a failure. As is clear from the table above, the rivet-type electrical contacts made with the electrical contact materials of Examples 1 to 10 have higher voltage resistance and wear resistance than the rivet-type electrical contacts made with the conventional electrical contact materials. It can be seen that the welding resistance is almost equally excellent. As detailed above, the electrical contact material of the present invention has contact characteristics that are superior to conventional electrical contact materials in terms of voltage resistance and wear resistance, so it is a revolutionary product that can replace conventional electrical contact materials. It can be said that it is something like that.
Claims (1)
重量％、亜鉛１〜10重量％、アンチモン１〜10重
量％、残部銀から成る材料であつて、且つ内部酸
化されている電気接点材料。 ２ ビスマス0.1〜５重量％、インジウム１〜10
重量％、亜鉛１〜10重量％、アンチモン１〜10重
量％、鉄、ニツケル、コバルト、ジルコニウムの
少なくとも一種0.01〜0.5重量％、残部銀から成
る材料であつて、且つ内部酸化されている電気接
点材料。[Claims] 1. Bismuth 0.1-5% by weight, Indium 1-10
An electrical contact material consisting of 1 to 10% by weight of zinc, 1 to 10% by weight of antimony, and the balance being silver, and which is internally oxidized. 2 Bismuth 0.1-5% by weight, Indium 1-10
An electrical contact that is internally oxidized and is made of a material consisting of 1 to 10% by weight of zinc, 1 to 10% by weight of antimony, 0.01 to 0.5% by weight of at least one of iron, nickel, cobalt, and zirconium, and the balance silver. material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57148552A JPS5938344A (en) | 1982-08-27 | 1982-08-27 | Electrical contact material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57148552A JPS5938344A (en) | 1982-08-27 | 1982-08-27 | Electrical contact material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5938344A JPS5938344A (en) | 1984-03-02 |
| JPH025807B2 true JPH025807B2 (en) | 1990-02-06 |
Family
ID=15455308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57148552A Granted JPS5938344A (en) | 1982-08-27 | 1982-08-27 | Electrical contact material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5938344A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0644953B2 (en) * | 1986-02-20 | 1994-06-15 | 蛇の目ミシン工業株式会社 | Sewing data creation device for embroidery sewing machine and method for creating sewing data for embroidery sewing machine |
| JPH0679634B2 (en) * | 1987-02-23 | 1994-10-12 | ブラザー工業株式会社 | Sewing data creation device for automatic sewing machine |
| JP2992203B2 (en) | 1994-07-27 | 1999-12-20 | 川崎製鉄株式会社 | Method of manufacturing cold rolled stainless steel strip |
| JP4764444B2 (en) * | 2008-03-17 | 2011-09-07 | 善夫 鈴木 | Separator structure |
| CN115216665B (en) * | 2022-06-29 | 2023-11-17 | 重庆科技学院 | Crystal oscillator alloy electrode and process |
-
1982
- 1982-08-27 JP JP57148552A patent/JPS5938344A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5938344A (en) | 1984-03-02 |
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