JPH0255694A - Brazing filler metal for ti - Google Patents
Brazing filler metal for tiInfo
- Publication number
- JPH0255694A JPH0255694A JP20674788A JP20674788A JPH0255694A JP H0255694 A JPH0255694 A JP H0255694A JP 20674788 A JP20674788 A JP 20674788A JP 20674788 A JP20674788 A JP 20674788A JP H0255694 A JPH0255694 A JP H0255694A
- Authority
- JP
- Japan
- Prior art keywords
- brazing
- alloy
- filler metal
- core material
- brazing filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005219 brazing Methods 0.000 title claims abstract description 58
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 30
- 239000000945 filler Substances 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 56
- 239000011162 core material Substances 0.000 claims abstract description 29
- 238000007747 plating Methods 0.000 claims abstract description 24
- 229910000990 Ni alloy Inorganic materials 0.000 claims abstract description 15
- 230000002093 peripheral effect Effects 0.000 claims abstract description 11
- 239000000956 alloy Substances 0.000 abstract description 13
- 229910052759 nickel Inorganic materials 0.000 abstract description 5
- 239000013078 crystal Substances 0.000 abstract description 3
- 230000007423 decrease Effects 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 13
- 229910045601 alloy Inorganic materials 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 229910018054 Ni-Cu Inorganic materials 0.000 description 6
- 229910018481 Ni—Cu Inorganic materials 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 229910002482 Cu–Ni Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
利用産業分野
この発明は、Ｔｉ用ろう材、特に、Ｔｉ製メガネフレー
ムのろう付けに最適で作業性にすぐれ高い接着強度が得
られるＴｉ用ろう材に係り、Ｔｉ芯材にＮｉ合金外皮材
を設け、さらに最外層にＡｇめっき層を設けた複合線材
あるいは前記Ｎｉ合金を芯材として最外層にＡｇめっき
層を設けることにより、低温度で能率よく接合できるＴ
ｉ用ろう材に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Application This invention relates to a brazing filler metal for Ti, and in particular to a brazing filler metal for Ti that is suitable for brazing Ti eyeglass frames, has excellent workability, and provides high adhesive strength. By providing a composite wire material with a Ni alloy outer skin material and further providing an Ag plating layer on the outermost layer, or using the Ni alloy as a core material and providing an Ag plating layer on the outermost layer, T can be efficiently joined at low temperatures.
Regarding brazing filler metal for i.
背景技術
一般に、メガネフレーム材には、すぐれた耐食性並びに
軽量でばね性に富み、さらに光沢性等の美観にすぐれて
いることが要望されている。BACKGROUND ART In general, eyeglass frame materials are required to have excellent corrosion resistance, be lightweight, have high spring properties, and have excellent aesthetic appearance such as gloss.
かかる要求を満足する材料として、近年、Ｔｉがメガネ
フレーム材として使用されるようになった。In recent years, Ti has come to be used as a material for eyeglass frames as a material that satisfies such requirements.
しカル、Ｔｉには多くの利点はあるが、ろう付は性に問
題があり、製造性が悪くコストが高し１問題があった。Although Ti has many advantages, it has problems with brazing properties, poor manufacturability, and high cost.
このためＴｉ用ろう材として、Ｔｉを用いた合金材が提
案されているが、充分なろう付は性が得られず、メガネ
フレーム材のコスト上昇を招来しており、コスト低減が
要望されている。For this reason, an alloy material using Ti has been proposed as a brazing filler metal for Ti, but sufficient brazing properties cannot be obtained and the cost of eyeglass frame materials increases, and cost reduction is desired. There is.
発明の目的
この発明は、Ｔｉメガネフレーム材へのろう付は性にす
ぐれ、ろう付は後の機械的強度の向上が得られるＴｉ用
ろう材の提供を目的としている。OBJECT OF THE INVENTION The object of the present invention is to provide a brazing filler metal for Ti that has excellent properties when brazed to a Ti eyeglass frame material and improves mechanical strength after brazing.
発明の概要
発明者らは、Ｔｉメガネフレームのコスト低Ｍ化を計る
ため、Ｔｉメガネフレーム材へのろう付は性にすぐれた
ろう材を種々検討した結果、芯材にＴｉ材を、外皮材に
Ｎｉ材またはＮｉ合金を用い、さらに外皮材の外周面、
すなわち、最外層にＡｇめっき層を形成した複合線材が
、Ｔｉ材をメガネフレームに加工する際のろう材として
、すぐれたろう付は性を発揮すること、特に、最外層に
Ａｇめっき層を設けることにより、該ろう材の融点を低
下させ、短時間に効率よくろう付けを完了させることが
できるため、Ｔｉメガネフレーム本体のろう付は後の結
晶粒の粗大化が防止でき、機械的強度の向上を図ること
ができることを知見した。Summary of the Invention In order to reduce the cost of Ti eyeglass frames, the inventors investigated various brazing materials with excellent properties for brazing to Ti eyeglass frame materials, and as a result, they decided to use Ti for the core material and for the outer skin material. Using Ni material or Ni alloy, the outer peripheral surface of the outer skin material,
In other words, a composite wire with an Ag plating layer formed on the outermost layer exhibits excellent brazing properties as a brazing material when processing Ti material into eyeglass frames, and in particular, providing an Ag plating layer on the outermost layer. By lowering the melting point of the brazing filler metal, it is possible to complete brazing efficiently in a short time, which prevents the crystal grains from becoming coarser after brazing the Ti glasses frame body, and improves mechanical strength. We found that it is possible to achieve this goal.
すなわち、この発明は、
Ｔｉ材を芯材とし、該芯材の外周面に外皮材としてＮｉ
またはＣｕ ８０％以下含有のＮｉ合金を被覆するとと
もに、さらに外皮材の外周面にＡｇめっき層を形成した
ことを特徴とするＴｉ用ろう材であり、さらに、
ＮｉまたはＣｕ ８０％以下含有のＮｉ合金を芯材とし
、該芯材の外周面にＡｇめっき層を形成したことを特徴
とするＴｉ用ろう材である。That is, the present invention uses a Ti material as a core material, and a Ni material as an outer skin material on the outer peripheral surface of the core material.
Or a brazing filler metal for Ti characterized by being coated with a Ni alloy containing 80% or less of Cu and further forming an Ag plating layer on the outer peripheral surface of the outer skin material, and further comprising Ni or Ni alloy containing 80% or less of Cu. This brazing material for Ti is characterized by using an alloy as a core material and forming an Ag plating layer on the outer peripheral surface of the core material.
発明の好ましい実施態様
この発明において、複合線材の芯材にＴｉを用いるのは
、ろう付は時の被溶接材たるＴｉの溶融量を極力低減さ
せ、機械的強度だけでなく、接合部形状等の点において
もすぐれたろう付けができるためであり、特に、接合部
における接着強度の向上とともに耐食性を付与するのに
有効である。Preferred Embodiments of the Invention In this invention, the reason why Ti is used as the core material of the composite wire is to minimize the amount of melted Ti, which is the material to be welded, during brazing, and improve not only mechanical strength but also the shape of the joint. This is because excellent brazing can be achieved in terms of the above, and it is particularly effective in improving adhesive strength and imparting corrosion resistance at joints.
この発明のろう材において、外皮材のＮｉまたはＣｕ−
Ｎｉ合金は、Ｔｉの融点を低下させる効果を有するため
、Ｔｉメガネフレーム本体等の被溶接材のＴｉの接合部
でＴｉとすぐ反応し、特に、Ｃｕを含有するＮｉ合金は
、最外層のＡｇめっき層との反応によって一層融点が低
くなるため、被溶接材の結晶粒の粗大化を防止し、すぐ
れたろう付は性を発揮することができる。In the brazing material of this invention, Ni or Cu-
Since Ni alloy has the effect of lowering the melting point of Ti, it reacts immediately with Ti at the Ti joint of the material to be welded, such as the main body of Ti eyeglass frames. Since the melting point is further lowered by the reaction with the plating layer, coarsening of the crystal grains of the welded material is prevented, and excellent brazing properties can be achieved.
また、外皮材は、このろう材を製造する際に行なう熱処
理時に、芯材のＴｉへのガス雰囲気の影響を避ける効果
を有する。Further, the outer skin material has the effect of avoiding the influence of the gas atmosphere on the Ti of the core material during the heat treatment performed when manufacturing this brazing material.
この発明において、ろう材の最外層に形成するＡｇめっ
き層は、後述するいずれの構成のろう材においても、構
成組成と反応し、ろう材の融点を低下させる効果を有す
るため被着する。In the present invention, the Ag plating layer formed on the outermost layer of the brazing filler metal reacts with the constituent composition of any of the brazing filler metals described below and adheres thereto because it has the effect of lowering the melting point of the brazing filler metal.
かかる効果を有するＡｇ層は、ろう材の製造効率、経済
性等を合せて考慮するに、めっきにより、１〜１０νｍ
の層厚さで各複合線材の最外層に設けることが望ましい
。Considering the production efficiency and economic efficiency of the brazing material, the Ag layer having such an effect can be formed by plating with a thickness of 1 to 10 νm.
It is desirable to provide the outermost layer of each composite wire with a layer thickness of .
この発明において、特に、Ｔｉ製メガネフレーム本体等
の被溶接材を少量のろう材にてろう付けをする場合、あ
るいは小面積での接合、さらに点接合する等の場合には
、芯材のＴｉ量を下記の断面積比より大幅に少なくして
も、すぐれたろう付は性を発揮することができ、さらに
は、Ｔｉを用いることなく、前記外皮材のＮｉまたはＣ
ｕ８０％以下含有のＮｉ合金を芯材として、外周面にＡ
ｇめっき層を設けた構成のろう材が、ろう付は作業性や
接合強度にすぐれている。In this invention, in particular, when brazing materials to be welded such as Ti eyeglass frame bodies with a small amount of brazing metal, or when joining in a small area or point joining, it is necessary to Even if the amount is significantly lower than the cross-sectional area ratio shown below, excellent brazing performance can be achieved.
A Ni alloy containing u80% or less is used as the core material, and A on the outer peripheral surface.
A brazing filler metal with a plating layer has excellent workability and bonding strength.
また、この発明のＣｕ−Ｎｉ合金において、Ｃｕが８０
ｗｔ％を超えると、Ｔｉの融点を低下させる効果がなく
、かつ耐食性を劣化させるので好ましくない。該合金の
好ましい組成範囲は、Ｃｕは３０〜７５ｗｔ％、Ｎｉは
２５〜７０ｗｔ％である。Further, in the Cu-Ni alloy of the present invention, Cu is 80
If it exceeds wt%, it is not preferable because it has no effect of lowering the melting point of Ti and deteriorates corrosion resistance. The preferable composition range of the alloy is 30 to 75 wt% of Cu and 25 to 70 wt% of Ni.
さらに、この発明による複合線ろう材において、Ｔｉ芯
材と該複合線材の断面積比、すなわち、最外層に形成す
るＡｇめっき層を除く複合線材の断面積に占めるＴｉ芯
材の断面積比は６５％以下が好ましく、６５％を超える
場合は、外皮材のＮｉ量またはＣｕ８０ｗｔ％以下含有
のＮｉ合全全量少なくなって、Ｔｉの融点の低下に十分
な効果が得られないため、前記断面積比を６５％以下に
限定する。特に、Ｔｉの効果を得るためには、前記断面
積比を２５％以上にするのが好ましい。Furthermore, in the composite wire brazing material according to the present invention, the cross-sectional area ratio of the Ti core material to the composite wire material, that is, the cross-sectional area ratio of the Ti core material to the cross-sectional area of the composite wire material excluding the Ag plating layer formed as the outermost layer is 65% or less is preferable, and if it exceeds 65%, the amount of Ni in the outer skin material or the total amount of Ni containing 80 wt% or less of Cu decreases, and a sufficient effect in lowering the melting point of Ti cannot be obtained. Limit the area ratio to 65% or less. In particular, in order to obtain the effect of Ti, it is preferable that the cross-sectional area ratio be 25% or more.
この発明によるろう材は、例えば、以下の製造方法にて
得られる。The brazing material according to the present invention can be obtained, for example, by the following manufacturing method.
Ｔｉ芯材を用いる場合は、種々の製造方法が考えられる
が、特に、造管ミルを用いた製造方法が工業的規模にお
いて、生産性良くこの発明のろう材を得ることができる
。When using a Ti core material, various manufacturing methods can be considered, but in particular, a manufacturing method using a tube mill can yield the brazing filler metal of the present invention with good productivity on an industrial scale.
コイル状Ｎｉ板またはＣｕ８０ｗｔ％以下含有のＮｉ合
金板を巻戻し、これを成形ロールにて走行中に管状に成
形するが、外皮材の上方より同走行方向にコイル状Ｔｉ
線を巻戻しながら、管状への成形途上の外皮材中に挿入
しながら成形し、管状体の突合せ端部をプラズマアーク
等により溶接する。この際、Ｔｉ芯材と該複合線材の直
径比を４１５以下にすると、前記の断面積比となる。A coiled Ni plate or a Ni alloy plate containing 80 wt% or less of Cu is unwound and formed into a tubular shape while running with forming rolls.
The wire is unwound and inserted into the shell material that is being formed into a tubular shape, and the butt ends of the tubular body are welded by plasma arc or the like. At this time, when the diameter ratio of the Ti core material and the composite wire is set to 415 or less, the above-mentioned cross-sectional area ratio is achieved.
さらに、伸管加工して、芯材のＴｉ材と外皮材のＮｉ材
またはＣｕ８０ｗｔ％以下含有のＮｉ合金材を圧着し、
所要線径に線引加工し、例えば、その断面形状が平角状
になる如く、平角圧延して、連続Ａｇめっきを施すこと
によって、所要形状、寸法のろう材を得ることができる
。Furthermore, by pipe drawing processing, the core material Ti material and the outer skin material Ni material or Ni alloy material containing 80 wt% or less of Cu are bonded together,
A brazing filler metal of a desired shape and size can be obtained by drawing the wire to a desired wire diameter, rolling it into a rectangular shape so that its cross-sectional shape becomes rectangular, and then applying continuous Ag plating.
また、Ｔｉ芯材を用いない場合は、芯材となるＮｉまた
はＣｕ−Ｎｉ合金からなり断面形状が円形、長方形等か
らなる線材に、連続Ａｇめっきを施すことによって容易
に製造することができる。When a Ti core material is not used, it can be easily manufactured by continuously plating a wire rod made of Ni or a Cu-Ni alloy and having a circular or rectangular cross-sectional shape as the core material.
実施例
実施例１
板厚０．２ｍｍ、板幅１２．８ｍｍの３０％Ｎｉ−７０
％Ｃｕ合金帯を巻戻しながら、走行中に成形ロールによ
り管状に成形するに際し、前記Ｎｉ−Ｃｕ合金帯材上方
より、径１．２ｍｍのＴｉ線を巻戻しながら、前記Ｎｉ
−Ｃｕ合金帯の成形途上の管状体中に挿入し、さらに、
前記Ｎｉ−Ｃｕ管状体の突合せ端部を、溶接電流５０Ａ
、速度ＩＵｍ／ｍｉｎの条件のプラズマアークにて溶接
して複合材となした。Examples Example 1 30% Ni-70 with a plate thickness of 0.2 mm and a plate width of 12.8 mm.
% Cu alloy strip is unwound and formed into a tubular shape by forming rolls while running, a Ti wire with a diameter of 1.2 mm is unwound from above the Ni-Cu alloy strip material while the Ni-Cu alloy strip is being rolled back.
- Insert the Cu alloy strip into the tubular body that is in the process of being formed, and further,
The abutting ends of the Ni-Cu tubular body were welded with a welding current of 50 A.
A composite material was obtained by welding using a plasma arc at a speed of IUm/min.
さらに、伸管加工して、芯材のＴｉ材と外皮材のＮｉ−
Ｃｕ合会合材圧着し、ついで伸線加工した後、連続Ａｇ
めっき処理を施し、第１図ａに示す如く、芯材（２〉の
Ｔｉが０．０８ｍｍ、外皮材（３）のＮｉ−Ｃｕ合合金
炉０．０１ｍｍ、最外層のＡｇめっき層（４）厚が５ｐ
ｍからなる厚み０．１１ｍｍの平角複合線材のろう材（
１）を得た。Furthermore, by pipe drawing, the core material of Ti material and the outer skin material of Ni-
After crimping the Cu aggregation material and then wire drawing, continuous Ag
After plating, as shown in Figure 1a, the core material (2) has a Ti of 0.08 mm, the outer skin material (3) has a Ni-Cu alloy furnace of 0.01 mm, and the outermost Ag plating layer (4). Thickness is 5p
Brazing filler metal of rectangular composite wire with a thickness of 0.11 mm consisting of m (
1) was obtained.
前記複合線材より面積２０ｍｍ２のろう材試験片（５）
を採取し、長さ１００皿×幅２０ｍｍ寸法の２枚のＴｉ
板（６）Ｃ６）を重ねてその間に、前記ろう材試験片（
５）を介在し、アルゴンガス雰囲気中にて、９３０℃、
ＩＨｒの加熱を施して接着した後、第２図に示す如く、
２枚のＴｉ板（６）（６）を各々反対方向に引っ張る条
件にて剪断強度試験を行った。その結果を第１表に表す
。Brazing metal test piece (5) with an area of 20 mm2 from the composite wire rod
2 Ti plates with dimensions of 100 plates in length x 20 mm in width.
Stack the plates (6) C6) and place the brazing metal test piece (
5) in an argon gas atmosphere at 930°C,
After applying IHr heating and bonding, as shown in Figure 2,
A shear strength test was conducted under the condition that the two Ti plates (6) (6) were pulled in opposite directions. The results are shown in Table 1.
また、比較のために、ろう材としてＡｇろうを用い、Ｔ
ｉ板同志を９８０”ＣにＩＨｒ加熱した場合と、ろう材
としてＡｇ−Ａ１合金を用いて、９００℃にＩＨｒ加熱
した場合の剪断強度試験を同一条件にて行った。その試
験結果を第１表に表す。For comparison, Ag solder was used as the filler metal, and T
Shear strength tests were conducted under the same conditions when the i-plates were heated by IHr to 980"C and when they were heated by IHr to 900"C using Ag-A1 alloy as a brazing material. Express in a table.
実施例２
径０．４ｍｍのＮｉ−Ｃｕ合金線を巻戻しながら、成形
ロールにより厚み０．１ｍｍの平角線材に成形し、さら
に、連続Ａｇめっき処理を施し、第１図すに示す如く、
芯材（１１）のＮｉ−Ｃｕ合金が０．１ｍｍ、最外層の
Ａｇめっき層（１２）厚が５ｐｍからなる厚み０．１１
ｍｍの平角複合線材のろう材（１ｏ）を得た。Example 2 A Ni-Cu alloy wire with a diameter of 0.4 mm was unwound and formed into a rectangular wire with a thickness of 0.1 mm using forming rolls, and then subjected to continuous Ag plating treatment, as shown in Figure 1.
The core material (11) has a Ni-Cu alloy of 0.1 mm, and the outermost Ag plating layer (12) has a thickness of 5 pm.Thickness: 0.11
A brazing material (1o) of rectangular composite wire of mm was obtained.
前記複合線材より面積２０ｍｍ２のろう材試験片を採取
し、長さ１００ｍｍＸ幅２軸皿寸法の２枚のＴｉ平板を
重ねて、その間に前記ろう材試験片を介在し、アルゴン
ガス雰囲気中にて、９３０ ’Ｃ１ＩＨｒの加熱ヲ施し
て接着した後、実施例１と同様に２枚のＴｉ平板を各々
反対方向に引っ張る条件にて剪断強度試験を行った。そ
の結果を第１表に表す。A brazing metal test piece with an area of 20 mm2 was taken from the composite wire rod, two Ti flat plates with a length of 100 mm and a width of a biaxial plate were stacked, the brazing metal test piece was interposed between them, and the brazing metal test piece was placed in an argon gas atmosphere. , 930'C1IHr for adhesion, and then a shear strength test was conducted under the condition that the two Ti flat plates were pulled in opposite directions in the same manner as in Example 1. The results are shown in Table 1.
第１表
発明の効果
実施例より明らかな如く、加熱温度が９５０″Ｃ以下と
低く、ろう付は作業性にすぐれ、高い接着強度が得られ
、Ｔｉ製メガネフレームのろう付けに最適なＴｉ用ろう
材であることが分かる。As is clear from the Examples of Effects of the Invention in Table 1, the heating temperature is as low as 950''C or less, the brazing workability is excellent, high adhesive strength is obtained, and Ti is ideal for brazing Ti eyeglass frames. It can be seen that it is a brazing material.
説明図である。It is an explanatory diagram.
第２図は剪断強度試験条件を示すＴｉ板の説明図である
１、１０・・・ろう材、２，１１・・・芯材、３・・・
外皮材、４．１２・・・Ａｇめっき層、５・・・ろう材
試験片、６・・・Ｔｉ板。FIG. 2 is an explanatory diagram of a Ti plate showing shear strength test conditions. 1, 10... brazing metal, 2, 11... core material, 3...
Outer skin material, 4.12...Ag plating layer, 5...Brazing metal test piece, 6...Ti plate.
Claims (1)
またはＣｕ８０％以下含有のＮｉ合金を被覆するととも
に、さらに外皮材の外周面にＡｇめっき層を形成したこ
とを特徴とするＴｉ用ろう材。 ２ ＮｉまたはＣｕ８０％以下含有のＮｉ合金を芯材とし、
該芯材の外周面にＡｇめっき層を形成したことを特徴と
するＴｉ用ろう材。[Claims] 1. Ti material is used as a core material, and Ni material is used as an outer skin material on the outer peripheral surface of the core material.
Alternatively, a brazing filler metal for Ti, which is coated with a Ni alloy containing 80% or less of Cu, and further has an Ag plating layer formed on the outer peripheral surface of the outer skin material. 2 Using Ni or a Ni alloy containing 80% or less of Cu as a core material,
A brazing filler metal for Ti, characterized in that an Ag plating layer is formed on the outer peripheral surface of the core material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20674788A JPH0255694A (en) | 1988-08-19 | 1988-08-19 | Brazing filler metal for ti |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20674788A JPH0255694A (en) | 1988-08-19 | 1988-08-19 | Brazing filler metal for ti |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0255694A true JPH0255694A (en) | 1990-02-26 |
Family
ID=16528430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20674788A Pending JPH0255694A (en) | 1988-08-19 | 1988-08-19 | Brazing filler metal for ti |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0255694A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003092325A1 (en) * | 2002-04-26 | 2003-11-06 | Tayca Corporation | Composite piezoelectric vibrator |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61269997A (en) * | 1985-05-25 | 1986-11-29 | Nippon Gakki Seizo Kk | Brazing material for titanium material |
| JPS62187592A (en) * | 1986-02-12 | 1987-08-15 | Tanaka Kikinzoku Kogyo Kk | Clad solder |
-
1988
- 1988-08-19 JP JP20674788A patent/JPH0255694A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61269997A (en) * | 1985-05-25 | 1986-11-29 | Nippon Gakki Seizo Kk | Brazing material for titanium material |
| JPS62187592A (en) * | 1986-02-12 | 1987-08-15 | Tanaka Kikinzoku Kogyo Kk | Clad solder |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003092325A1 (en) * | 2002-04-26 | 2003-11-06 | Tayca Corporation | Composite piezoelectric vibrator |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6722002B1 (en) | Method of producing Ti brazing strips or foils | |
| CN107695559A (en) | A kind of silver-based composite soldering foil and preparation method thereof | |
| US3664816A (en) | Steel-to-aluminum transition piece | |
| JPS5919088A (en) | Copper composite material and its manufacture | |
| JPH0255694A (en) | Brazing filler metal for ti | |
| JPH11284111A (en) | Heat sink member, manufacture thereof and semiconductor package using the hear sink member | |
| JPS6013424B2 (en) | Manufacturing method for eyeglass frame materials | |
| JP3355199B2 (en) | Arc spraying wire | |
| JPS63169348A (en) | Amorphous alloy foil for jointing ceramics | |
| JPH0324317B2 (en) | ||
| JPS6182996A (en) | Production of composite brazing filler metal | |
| JPH0543070Y2 (en) | ||
| JP3020649B2 (en) | Manufacturing method of clad steel | |
| JP2019039043A (en) | Production method of coated coil | |
| JPS59110492A (en) | Laminate of brazing material for simultaneous carburizing and brazing and its production | |
| JP2761963B2 (en) | Manufacturing method of aluminum clad steel sheet with excellent workability | |
| JPS5952643A (en) | Composite material | |
| JP2957306B2 (en) | Arc spraying wire | |
| JPH0543071Y2 (en) | ||
| JPS60238093A (en) | Production of composite aluminum-stainless steel material | |
| JPH0220673A (en) | Manufacture of ni-copper alloy clad plate | |
| JPH05220587A (en) | Manufacture of clad steel | |
| JP2663811B2 (en) | Manufacturing method of aluminum clad steel sheet | |
| JPH046175A (en) | Composite foil brazing material for joining ceramics | |
| JPH01150489A (en) | Manufacture of thin stainless steel clad sheet |