JPH0253997A - Deodorizing paper - Google Patents
Deodorizing paperInfo
- Publication number
- JPH0253997A JPH0253997A JP20172388A JP20172388A JPH0253997A JP H0253997 A JPH0253997 A JP H0253997A JP 20172388 A JP20172388 A JP 20172388A JP 20172388 A JP20172388 A JP 20172388A JP H0253997 A JPH0253997 A JP H0253997A
- Authority
- JP
- Japan
- Prior art keywords
- deodorizing
- paper
- agent
- powder
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 49
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 4
- 150000004679 hydroxides Chemical class 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 6
- 239000013055 pulp slurry Substances 0.000 abstract description 3
- 239000002781 deodorant agent Substances 0.000 abstract 4
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野］
本発明は脱臭紙に関するものであり、特にパルプスラリ
ーに特殊な粉末脱臭剤を内添して製造した優れた脱臭能
力を有する脱臭紙に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to deodorizing paper, and particularly to deodorizing paper having excellent deodorizing ability produced by internally adding a special powder deodorizing agent to pulp slurry.
現在市販されている脱臭紙（消臭紙）は大別して次の三
種類に分類される。Deodorizing paper (deodorizing paper) currently on the market can be broadly classified into the following three types.
０紙に消臭液を含浸、担持させたもの。0 paper impregnated and supported with deodorizing liquid.
■紙の表面に粉末脱臭剤を塗布（コーティング）したも
の。■Paper surface coated with powder deodorizer.
■パルプスラリーに粉末脱臭剤を内添（フィリング）し
て製造したもの。■Manufactured by adding (filling) powdered deodorizer to pulp slurry.
ところで脱臭効果から見れば
■の消臭液含浸タイプの脱臭紙においては含浸させた消
臭液の量も少なく、又消臭液は元来脱臭能力は大きくな
いため、大きな脱臭効果は得られない。By the way, in terms of deodorizing effect, the amount of impregnated deodorizing liquid in the deodorizing paper impregnated with deodorizing liquid (■) is small, and the deodorizing liquid does not have a large deodorizing ability to begin with, so a large deodorizing effect cannot be obtained. .
■のコーティングタイプの脱臭紙においてはコーティン
グ時のバインダーにより粉末脱臭剤が被覆され、脱臭剤
としての本来の機能を十分発揮出来ないことが多い。In coating type deodorizing paper (2), the powder deodorizing agent is coated with the binder during coating, and is often unable to fully demonstrate its original function as a deodorizing agent.
■のフィリングタイプの脱臭紙の製造方法は■■の後加
工法とは異なり、脱臭紙の製造方法としては優れている
が、現在粉末脱臭剤として使用されている活性炭、天然
ゼオライト等は脱臭能力に関して言えば必ずしも満足出
来るものではない。The filling type deodorizing paper manufacturing method described in (■) is different from the post-processing method (■■) and is superior as a manufacturing method for deodorizing paper, but activated carbon, natural zeolite, etc. currently used as powder deodorizing agents have deodorizing ability. Regarding this, it is not always satisfactory.
本発明は従来のものがもつ以上の様な課題を解決し、優
れた脱臭能力を有する脱臭紙を提供することを目的とす
る。It is an object of the present invention to solve the above-mentioned problems of the conventional paper and to provide a deodorizing paper having excellent deodorizing ability.
上記課題解決のために本発明者は鋭意研究の結果、以下
に記する特殊な脱臭剤を■タイプの脱臭紙製造法におい
て内添することにより、従来の脱臭紙には見られない優
れた脱臭能力を有する脱臭紙の得られることを見出し、
本発明に到達したものである。In order to solve the above problem, the inventor of the present invention has conducted intensive research and has found that by internally adding the special deodorizing agent described below to the ■type deodorizing paper manufacturing method, the inventor has achieved excellent deodorization that cannot be found in conventional deodorizing paper. It was discovered that deodorizing paper with the ability to
This has led to the present invention.
即ち本発明の構成は脱臭剤有効成分としてＳｉ。That is, the structure of the present invention uses Si as the deodorizing agent active ingredient.
ＡＩ！、Ｍｇ、Ｎｉ、Ｚｎ、Ｍｏ、Ｆｅ、Ｔｉ。AI! , Mg, Ni, Zn, Mo, Fe, Ti.
Ｃａ、Ｎａ、Ｗ、にの酸化物、水酸化物、炭酸塩、錯塩
の一種以上を含有する脱臭紙である。This is a deodorizing paper containing one or more of Ca, Na, W, oxides, hydroxides, carbonates, and complex salts.
粉末脱臭剤の粒度は、脱臭紙の表面をなめらかにするた
めに粒度２５０メツシユ以下にするのが望ましい。The particle size of the powder deodorizing agent is preferably 250 mesh or less in order to smooth the surface of the deodorizing paper.
粉末脱臭剤の配合割合はパルプに対して１：１程度にす
るのが望ましい。It is desirable that the blending ratio of the powder deodorizer to the pulp is about 1:1.
以下実施例により本発明を説明するが本発明はこれに限
定されるものではない。The present invention will be explained below with reference to Examples, but the present invention is not limited thereto.
実施例１〜４および比較例１〜２
下記の使用原料、製紙条件、原料配合割合、粉末脱臭剤
の種類に従って脱臭紙を製造し、その脱臭紙を使用して
臭気成分ガスの脱臭効果を試験した結果を表１および第
１図、第２図に示した。Examples 1 to 4 and Comparative Examples 1 to 2 Deodorizing paper was manufactured according to the following raw materials used, paper manufacturing conditions, raw material blending ratio, and type of powder deodorizing agent, and the deodorizing paper was used to test the deodorizing effect on odor component gas. The results are shown in Table 1 and FIGS. 1 and 2.
なお脱臭効果の試験は、２０２容の角型ポリ製タンクに
１０１０Ｘ１１に切った脱臭紙を吊り下げ、臭気成分ガ
スを所定濃度になる様に注入し、経過時間毎に試料採取
口より採取した試料臭気の濃度を測定することにより行
った。In the deodorizing effect test, deodorizing paper cut into 1010 x 11 pieces was suspended in a 202 volume rectangular polyester tank, odor component gas was injected to a predetermined concentration, and samples were collected from the sampling port at each elapsed time. This was done by measuring the odor concentration.
「使用原料」
パルプー−−一−−−−−−−−−−−−−−−−−−
−−−−−十分叩解したパルプドライ紙力強化剤−−−
一−−−アクリルアミド系樹脂凝集剤−−−−一−−−
−−−−−−−−−−−−−−−一硫酸ハン土すイズ剤
−〜−−−一一一一一−−一−−−−−−−−−ロジン
系すイズ剤ザイズ剤固定化剤−エピクロルヒドリン系樹
脂ウェット紙力強化剤−ボリアミドアミン樹脂粉末脱臭
剤−−−−−一−−−−−−−−−本発明によるもの（
粒度２５０メツシユ以下）従
来の粉末脱臭剤
「製紙条件」
乾燥条件 １００°Ｃで２分間
「原料配合割合」 重量部
パルプ １００部
ドライ紙力強化剤 ３
凝集剤 ３
サイズ剤 ３
サイズ剤固定化剤 ０．３ウ工ツト紙力強
化剤 ０．３粉末脱臭剤 １
００
「粉末脱臭剤の種類」
（実施例−１）
重量部
、’１２０． １５
ＳｉＯｚ ６Ｏ
ＮａｚＣＯ，、５
ＺｎＯ８
Ｍ ｏ Ｏｘ １０
ＮｉＣＯｈ −一文
（実施例−２）
ＡＩ２２０゜
ＳｉＯ□
に２ＣＯ３
ＺｎＯ
Ｍｏｂ。"Raw materials used" Pulp - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Raw materials used
−−−−Sufficiently beaten pulp dry paper strength strengthener−−−
1---Acrylamide resin flocculant---1---
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−1−−−−−1−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− agent fixing agent - epichlorohydrin resin wet paper strength strengthening agent - polyamide amine resin powder deodorizing agent - - - - - According to the present invention (
Particle size: 250 mesh or less) Conventional powder deodorizer ``Paper manufacturing conditions'' Drying conditions 100°C for 2 minutes ``Raw material blending ratio'' Part by weight Pulp 100 parts Dry paper strength strengthener 3 Coagulant 3 Sizing agent 3 Sizing agent fixing agent 0 .3 Paper strength strengthener 0.3 Powder deodorizer 1
00 "Type of powder deodorizer" (Example-1) Parts by weight, '120. 15 SiOz 6O NazCO,, 5 ZnO8 Mo Ox 10 NiCOh - One sentence (Example-2) 2CO3 ZnO Mob in AI220°SiO□.
ａＣＯ３ １ｅ２ （実施例−３） ｇＯ ＡＩ！、、Ｏ。aCO3 1e2 (Example-3) gO AI! ,,O.
ＳｉＯ□ Ｎ ａ ｚ ＣＯ３ ＦｅｚＣ）：ｔ Ｆ ｅ （ＯＨ）ｚ ＺｎＣＯ。SiO□ N az CO3 FezC):t F e (OH)z ZnCO.
（実施例−４） Ａ／４．０３ ＳｉＯ□ ＷＯ８ Ｃａ Ｈ４Ｐ２Ｏ７ Ｆ ｅ （ＯＨ）２ ｅｚＯｓ 〔比較例−１〕 〔比較例−２〕 −じし渇 天然ゼオライ１〜 粉末活性炭 （以下余白、 次頁へつづく） 上段 タンク内濃度（ｐｐｍ） 下段 残存 率Ｃ／Ｃ。(Example-4) A/4.03 SiO□ WO8 Ca H4P2O7 F e (OH)2 ezOs [Comparative example-1] [Comparative example-2] - thirst Natural zeolite 1~ powdered activated carbon (Margin below, (continued on next page) Upper stage: Concentration in tank (ppm) Lower row: Survival rate C/C.
Ｕ脱臭試験結果」
表
以上の結果から明らかな様に、本発明による脱臭紙は従
来のものに比較して短時間で急速に顕著な脱臭効果を示
し、しかも時間経過に伴い臭気ガス残存率が著しく小さ
くなり、優れた脱臭能力を有するものである。As is clear from the results above, the deodorizing paper of the present invention exhibits a rapid and remarkable deodorizing effect in a short period of time compared to conventional paper, and moreover, the residual rate of odor gas decreases over time. It is extremely small and has excellent deodorizing ability.
本発明による脱臭紙は短時間で急速に顕著な脱臭効果を
示し、しかも時間経過に伴い臭気ガス残存率が著しく小
になる優れた脱臭能力を有する。The deodorizing paper according to the present invention rapidly exhibits a remarkable deodorizing effect in a short period of time, and has an excellent deodorizing ability in which the residual rate of odor gas decreases significantly over time.
第１図および第２図は、それぞれアンモニアガスおよび
硫化水素ガスに対して本発明の粉末脱臭剤（実施例３お
よび４）および従来の粉末脱臭剤（比較例１および２）
を内添して製造した脱臭紙の脱臭試験効果を示すグラフ
である。Figures 1 and 2 show the powder deodorizer of the present invention (Examples 3 and 4) and the conventional powder deodorizer (Comparative Examples 1 and 2) for ammonia gas and hydrogen sulfide gas, respectively.
It is a graph showing the deodorizing test effect of deodorizing paper manufactured by internally adding .
Claims (1)
Ｍｏ、Ｆｅ、Ｔｉ、Ｃａ、Ｎａ、Ｗ、Ｋの酸化物、水酸
化物、炭酸塩、錯塩の一種以上を含有する脱臭紙。Deodorizer active ingredients include Si, Al, Mg, Ni, Zn,
A deodorizing paper containing one or more of oxides, hydroxides, carbonates, and complex salts of Mo, Fe, Ti, Ca, Na, W, and K.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20172388A JPH0253997A (en) | 1988-08-11 | 1988-08-11 | Deodorizing paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20172388A JPH0253997A (en) | 1988-08-11 | 1988-08-11 | Deodorizing paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0253997A true JPH0253997A (en) | 1990-02-22 |
Family
ID=16445864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20172388A Pending JPH0253997A (en) | 1988-08-11 | 1988-08-11 | Deodorizing paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0253997A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05247895A (en) * | 1992-03-06 | 1993-09-24 | Shikishima Boseki Kk | Cellulosic fiber-containing paper |
| JPH067634A (en) * | 1992-06-24 | 1994-01-18 | Nippondenso Co Ltd | Deodorant and its production |
| JPH06154136A (en) * | 1992-11-19 | 1994-06-03 | Matsushita Electric Ind Co Ltd | Vacuum cleaner |
| JPH09253186A (en) * | 1996-03-22 | 1997-09-30 | Yoshinari Hasegawa | Deodorizing antibacterial material |
| US6824619B1 (en) | 1999-03-08 | 2004-11-30 | Asm International N.V. | Method and device for rotating a wafer |
| JP2018083995A (en) * | 2016-11-22 | 2018-05-31 | 花王株式会社 | Method for producing deodorized paper |
-
1988
- 1988-08-11 JP JP20172388A patent/JPH0253997A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05247895A (en) * | 1992-03-06 | 1993-09-24 | Shikishima Boseki Kk | Cellulosic fiber-containing paper |
| JPH067634A (en) * | 1992-06-24 | 1994-01-18 | Nippondenso Co Ltd | Deodorant and its production |
| JPH06154136A (en) * | 1992-11-19 | 1994-06-03 | Matsushita Electric Ind Co Ltd | Vacuum cleaner |
| JPH09253186A (en) * | 1996-03-22 | 1997-09-30 | Yoshinari Hasegawa | Deodorizing antibacterial material |
| US6824619B1 (en) | 1999-03-08 | 2004-11-30 | Asm International N.V. | Method and device for rotating a wafer |
| US7351293B2 (en) | 1999-03-08 | 2008-04-01 | Asm International N.V. | Method and device for rotating a wafer |
| JP2018083995A (en) * | 2016-11-22 | 2018-05-31 | 花王株式会社 | Method for producing deodorized paper |
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