JPH0250766B2 - - Google Patents
Info
- Publication number
- JPH0250766B2 JPH0250766B2 JP59051517A JP5151784A JPH0250766B2 JP H0250766 B2 JPH0250766 B2 JP H0250766B2 JP 59051517 A JP59051517 A JP 59051517A JP 5151784 A JP5151784 A JP 5151784A JP H0250766 B2 JPH0250766 B2 JP H0250766B2
- Authority
- JP
- Japan
- Prior art keywords
- ozone
- oil
- linalool
- treatment agent
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 44
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 15
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 15
- 229930007744 linalool Natural products 0.000 claims description 15
- -1 linalool ester Chemical class 0.000 claims description 10
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 8
- 229940043350 citral Drugs 0.000 claims description 8
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000341 volatile oil Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 230000000694 effects Effects 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000012717 electrostatic precipitator Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000001941 cymbopogon citratus dc and cymbopogon flexuosus oil Substances 0.000 description 3
- 239000010636 coriander oil Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 238000006385 ozonation reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 244000018436 Coriandrum sativum Species 0.000 description 1
- 235000002787 Coriandrum sativum Nutrition 0.000 description 1
- 244000179970 Monarda didyma Species 0.000 description 1
- 235000010672 Monarda didyma Nutrition 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N butyl alcohol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000001469 lavandula hydrida abrial herb oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
Landscapes
- Control Or Security For Electrophotography (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明は電気集塵機およびイオン風空気清浄
器、復写機など高電圧を利用する機器周辺に生ず
るオゾンを処理するオゾン処理剤に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to an ozone treatment agent for treating ozone generated around equipment that uses high voltage, such as electrostatic precipitators, ionic air cleaners, and copying machines.
従来例の構成とその問題点
従来電気集塵機および復写機などでは高電圧下
に於て放電現象を利用して集塵および帯電して各
機能を働かしているが、放電現象に於て同時に発
生するオゾンに対して活性炭および触媒などを使
用してオゾン濃度の低減を計つていた。又イオン
風空気清浄機に於ては単に集塵だけでなく風を発
生させる為オゾン濃度は一段と高くなる問題があ
り、活性炭フイルターなどを使用すると風速が大
巾に低下して実用に供さないと云う欠点があつ
た。又一般的なテルペン系香料である森林浴香料
を使用した場合ある程度オゾン処理効果が見られ
るが、オゾンを低減させる為には相当高濃度で使
用しないと効果が見られない為、むしろ香料の臭
気がきつくなり使用に耐えない問題があつた。Conventional configurations and their problems Conventional electrostatic precipitators and copying machines use discharge phenomena under high voltage to collect dust and charge electricity to operate each function, but when the discharge phenomenon occurs at the same time, Attempts were made to reduce the ozone concentration by using activated carbon and catalysts. In addition, ion air air purifiers do not only collect dust but also generate wind, so there is a problem that the ozone concentration becomes even higher, and if activated carbon filters are used, the wind speed decreases significantly, making it unusable. There was a drawback. In addition, when using forest bathing fragrances, which are common terpene fragrances, some degree of ozone treatment effect can be seen, but in order to reduce ozone, the effect is not seen unless it is used at a fairly high concentration, so the odor of the fragrance is rather There was a problem that it became too tight to withstand use.
発明の目的
本発明は上記のような欠点を解消する為のもの
で、低濃度で臭気が薄い状態でオゾン処理効果の
高いオゾン処理剤を電気的、物理的に種々研究実
験して数多いテルペン化合物の中からオゾン処理
剤として効果的な物質を見出したものである。Purpose of the Invention The present invention is intended to eliminate the above-mentioned drawbacks, and has conducted various electrical and physical research experiments to develop an ozone treatment agent that has a high ozone treatment effect at low concentration and low odor, and has been developed using a large number of terpene compounds. Among these, we have discovered a substance that is effective as an ozone treatment agent.
発明の構成
本発明のオゾン処理剤は、リナロール、リナロ
ールエステル、シトラールのうち単独もしくはこ
れ等の成分のうち少なくとも１種を含有してなる
オゾン処理剤としたもので、数多くのテルペン化
合物の中からオゾンに対して少量でオゾン濃度を
低下し、かつ香料特有の臭気の少ないオゾン処理
剤を見つけ出したものである。Structure of the Invention The ozonation agent of the present invention is an ozonation agent containing linalool, linalool ester, citral alone or at least one of these components, and is selected from among many terpene compounds. We have discovered an ozone treatment agent that reduces ozone concentration in a small amount relative to ozone and has less odor peculiar to fragrances.
これ等の物質の含まれる混合物又は天然精油を
高電圧下に於ける放電現象に於て発生するオゾン
の近傍に配置することにより、気化したこれ等の
混合物又は天然精油とオゾンが接触反応してオゾ
ン濃度を低減させるものである。 By placing a mixture containing these substances or natural essential oil in the vicinity of ozone generated during a discharge phenomenon under high voltage, the vaporized mixture or natural essential oil and ozone will come into contact and react. It reduces ozone concentration.
実施例の説明
本発明はリナロール、リナロールエステル、シ
トラールのうち単独もしくはこれ等の成分のうち
少なくとも一種を含有する混合物又は天然精油か
ら成るもので、天然精油としてベルガモツト、ボ
アデローズ、コリアンダー、ジヤスミン、ラベン
ダー油（ラバンヂン油も含む）、リナロエ油、プ
リグレン油、メロリ油、レモングラス油、オレン
ジ油等である。これ等の天然精油はいずれもリナ
ロール、リナロールエステル、シトラールのいず
れかを含有しており揮発したガスはいずれもオゾ
ンと強力に反応してオゾン濃度を低減させること
が出来る。リナロールエステルとオゾンの反応は
次の通りである。Description of Examples The present invention consists of linalool, linalool ester, citral alone or a mixture containing at least one of these components, or natural essential oil, and the natural essential oils include bergamot, boa de rose, coriander, diasmine, and lavender oil. (including lavandin oil), linaloe oil, puriglen oil, melori oil, lemongrass oil, orange oil, etc. All of these natural essential oils contain linalool, linalool ester, or citral, and the volatilized gases react strongly with ozone and can reduce the ozone concentration. The reaction between linalool ester and ozone is as follows.
又シトラールとオゾンの反応は次の通りであ
る。 The reaction between citral and ozone is as follows.
又混合打としては、主にアルコールが適してお
り揮発量によりアルコールの種類を変えて混合す
ることにより所要の揮発量が得られる。尚アルコ
ールには、メチルアルコール、エチルアルコー
ル、ブチルアルコール、アミルアルコール、プロ
ピレングリコール、エチレングリコール等が使用
出来る。 Alcohol is mainly suitable for mixing, and the desired amount of volatilization can be obtained by changing the type of alcohol and mixing it depending on the amount of volatilization. As the alcohol, methyl alcohol, ethyl alcohol, butyl alcohol, amyl alcohol, propylene glycol, ethylene glycol, etc. can be used.
実施例 １
リナロール 60％
アルコール 40％
上記組成のものを約６畳の部屋にて、空気清浄
器より発生するオゾンに対して供給した結果、発
生場所で400ppbが室内で230ppbとなつていたも
のが、0.3ｇ／ｈの供給により室内60ppbに低下し
た。尚室内のオゾン濃度を変えて、上記混合物を
一定量0.3ｇ／供給したときのオゾン濃度は第
１図に示す通りで約1/3〜1/4に減じる効果を示し
た。Example 1 Linalool 60% Alcohol 40% As a result of supplying the above composition to the ozone generated by an air purifier in a room of about 6 tatami mats, the ozone was 400 ppb at the place of generation, but 230 ppb indoors. , it decreased to 60 ppb indoors by supplying 0.3 g/h. When the ozone concentration in the room was changed and a constant amount of 0.3 g/g of the above mixture was supplied, the ozone concentration was reduced to about 1/3 to 1/4 as shown in FIG.
実施例 ２
リナロールエステル 80％
アルコール 20％
実施例 ３
シトラール 70％
アルコール 30％
実施例 ４
ラベンダー油 50％
レモングラス油 30％
アルコール 20％
実施例 ５
レモングラス油 10％
ベルガモツト油 80％
アルコール 10％
実施例 ６
ボアデローズ油 40％
コリアンダー油 40％
アルコール 20％
実施例 ７
コリアンダー油 30％
リナロエ油 70％
実施例２から７では揮発量によつて多少のオゾ
ン減少能力は異なるものの、いずれも0.2ｇ／ｈ
の揮発量で1/2〜1/5にオゾン濃度を減少する効果
を示した。これ等の反応を等モル拡散、接触反応
によつて反応するだけに、オゾンに対して完全に
接触すべく配置すれば理論上は、一定量の揮発量
で一定のオゾンを完全に反応させることが出来る
はずであるが、空気清浄器の排気口全体の面積は
広く実際に排気全体にオゾン処理剤を配置するこ
とはむずかしいもので、ほゞ中央の一ケ所に配置
して実験したものである。Example 2 Linalool ester 80% Alcohol 20% Example 3 Citral 70% Alcohol 30% Example 4 Lavender oil 50% Lemongrass oil 30% Alcohol 20% Example 5 Lemongrass oil 10% Bergamot oil 80% Alcohol 10% Implementation Example 6 Boa de rose oil 40% Coriander oil 40% Alcohol 20% Example 7 Coriander oil 30% Linaloe oil 70% In Examples 2 to 7, the ozone reduction ability differs depending on the amount of volatilization, but in all cases it is 0.2 g/h
showed the effect of reducing ozone concentration by 1/2 to 1/5 with the amount of volatilization. Since these reactions occur through equimolar diffusion and catalytic reactions, if they are placed in complete contact with ozone, it is theoretically possible to completely react a certain amount of ozone with a certain amount of volatilization. However, the area of the entire exhaust port of an air purifier is large and it is difficult to actually place the ozone treatment agent over the entire exhaust, so we experimented by placing the ozone treatment agent in one place roughly in the center. .
尚復写機等に対して空気清浄器と同じ方法で、
オゾン処理剤を配置することにより、オゾンを減
少させることが出来る。 In addition, use the same method as for air purifiers for copying machines, etc.
By arranging an ozone treatment agent, ozone can be reduced.
発明の効果
以上のように本発明は、リナロール、リナロー
ルエステル、シトラールのうち単独もしくはこれ
等の成分のうち少なくとも一種を含有する混合物
又は天然精油から成るオゾン処理剤を、電気集塵
器等で発生するオゾンの近くに配置して、オゾン
処理剤の揮発ガスをオゾンに接触させることによ
り、オゾンを消滅もしくは低減せしめるものであ
る。しかも本発明のオゾン処理剤は、香りが薄く
かつ少量でオゾンと効率良く反応する特徴があ
る。Effects of the Invention As described above, the present invention provides an ozone treatment agent consisting of linalool, linalool ester, citral alone or a mixture containing at least one of these components, or a natural essential oil, which is generated using an electrostatic precipitator or the like. The ozone treatment agent is placed near the ozone, and the volatile gas of the ozone treatment agent is brought into contact with the ozone, thereby eliminating or reducing the ozone. Furthermore, the ozone treatment agent of the present invention has a light scent and is characterized by reacting efficiently with ozone in a small amount.
ちなみに、図は電気集塵機に本発明のオゾン処
理剤を設けたものＡと、オゾン処理剤を設けなか
つたものＢと、リナロール、リナロールエステ
ル、シトラール以外のテルペン系綱領を用いたも
のＣとのオゾンの空気吹出部での濃度と室内濃度
の比較を示し、これから、本オゾン処理剤の効果
が明白である。 By the way, the diagram shows the ozone of electrostatic precipitators A equipped with the ozonating agent of the present invention, B not equipped with an ozonating agent, and C using a terpene system other than linalool, linalool ester, and citral. A comparison between the concentration at the air outlet and the indoor concentration is shown, and the effect of this ozone treatment agent is clear.
図は空気清浄機に対してオゾン処理剤を設けた
場合と、設けなかつた場合との空気吹出部のオゾ
ン濃度比較線図である。
The figure is a comparison diagram of ozone concentration in the air blowing section of an air purifier with and without an ozone treatment agent.
Claims (1)
ルのうち単独もしくはこれらの成分のうち少なく
とも１種を含有する混合物又は天然精油からなる
オゾン処理剤。1. An ozone treatment agent consisting of linalool, linalool ester, citral alone or a mixture containing at least one of these components, or a natural essential oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59051517A JPS60197222A (en) | 1984-03-16 | 1984-03-16 | Ozone treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59051517A JPS60197222A (en) | 1984-03-16 | 1984-03-16 | Ozone treating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60197222A JPS60197222A (en) | 1985-10-05 |
| JPH0250766B2 true JPH0250766B2 (en) | 1990-11-05 |
Family
ID=12889198
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59051517A Granted JPS60197222A (en) | 1984-03-16 | 1984-03-16 | Ozone treating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60197222A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6164315A (en) * | 1984-09-05 | 1986-04-02 | Ricoh Co Ltd | Ozone removing agent for electrostatic image forming apparatus |
| JPH0687890B2 (en) * | 1988-02-29 | 1994-11-09 | 東海興業株式会社 | Sterilizer / deodorizer |
| GB2351665B (en) * | 1999-06-09 | 2003-09-03 | Atmospheric Solutions Ltd | Reduction of ozone in an enclosed enviroment |
| KR20070090237A (en) * | 2004-12-07 | 2007-09-05 | 액세스 비지니스 그룹 인터내셔날 엘엘씨 | Methods for scavenging oxidizing nitrogen and oxygen species with fragrances having antioxidative properties |
-
1984
- 1984-03-16 JP JP59051517A patent/JPS60197222A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60197222A (en) | 1985-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |