JPH02504275A - Herbicidal sulfonamides - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention] name of invention Grass sulfonamides Cross-reference to Seki applications This application is part of U.S. Application No. 078.191 filed on July 27, 1987. This is a continuation application.

Lord Niri Ω! ! The following documents contain substantially all disclosures related to the sulfonamides of the present invention. A herbicidal sulfonylurea containing a characteristic sulfonylurea residue is disclosed. Ru. However, these documents do not imply the invention, but rather It has enough characteristics to be useful as a background for understanding: US Patent No. 4.370.480 European Patent No. 79.772 US Patent No. 4.435.206 European Patent Original No. 87,780 U.S. Patent No. 4.4 No. 81.029 European Patent Application No. 95.925 U.S. Patent No. 4.549.8 No. 98 European Patent Application No. 126.711 U.S. Patent No. 4.618.363 European Patent Application No. 203.825 US Patent No. 4.638.004 Loppa Patent Application No. 245.058 US Patent No. 4.659.366 South African Patent No. 85/2603 South African Patent No. 83/3850 Ari Ω! Accomplish The present invention includes agriculturally suitable salts! R In the formula, J is E is a single bond or -〇H,-; Q' is -C (T-N-0-A 1 k"C'; T1 is CN, F, CI, B rt　5CNs　Ns, C, ~C, Cloxy, C, -C, thioalkyl, NH (C, ~C, C2furkylN(C, -c.

Re; Alk is optionally CN%0CHs, 5CHs or halogen-substituted 01-C, a and CH2CH=CH2; Q'' is -C(Tri-N-0-A 1k; T2 is H: optionally substituted with CN, 0CHs, SCH, or halogen; C, -C, alkyl; cyclopropyl; F; C1; Br; CN; SCN; N 3; C+~C, alkoxy; C1~C, thioalkyl; NH(C, -C2 fulky ); N (C, ~C, C2 full-kyl; N (OCH5) R1 is H, C, -C, alkyl, C8~C, haloalkyl, halogen, CN, nitro, C, ~C , Clkoxy, C3-C, haloalkoxy, C1-C, alkylthio, C8-C , alkylsulfinyl, C8-C.

Alkylsulfonyl, S CF z H-N Hx, N HCHs%N (CHs ) or one C8-C, alkoxy, C8-C, haloalkoxy, S)I.

selected from C3-C, alkyl substituted with SCH, CN or OH; R"　c)I%F　s　C1%B　r　s　C1-C27k'r　, C1~c , H1C1 or C, -C, alkoxy; Rs is H1C1 ~Cs alkyl, CI#c, haloalkyl, Cs ~C4 flukenyl, C3~C Substituted with 4 alkynyl, CH, CN, phenyl and FlCl, CHs or OCH, selected from phenyl: n is 0 or l; R is H or CH; W is 0 or S; A is X is H%C8-C, alkyl%C1-C, alkoxy, c, ~C, haloalfoxy C, C, ~C4 haloalkyl, Cl-C4 haloalkylthio, 01~C, alkyl ruthio, halogen%C, ~C, alkoxyalkyl, C1~C, alkoxyal koxy, amino, c, ~C,C2furkylamino(01~C,alkyl)amino or selected from C1-C, cycloalkyl; Y is HlC, -C67/L-kyl, C1-C4 alkoxy, c, ~C, /%0F Rukoxy, 01-C4 haloalkylthio, c, ~C, C2 furkylthio 5-C, Alkoxyalkyl, C2-C, alkoxyalkoxy, amino, Cl-03a Lucylamino, diCCl-Cs alkyl)amino, 08-C4 alkenyloxy , CX-C4 alkynyloxy %C, ~C.

Alkylthioalkyl% C1-C, haloalkyl% C, ~C, C2 Furukyldide , cyano, C1-C, alkylsulfinylalkyl, and N(OCHs)CH selected from l; m is 2 or 3; Ll and R are independently 0 or S; Ra is H or C8-C, alkyl; ; Rb and Rc are independently C3-C, alkyl; 2 is CH or N; 2 is CH or N: Y, is 0 or CH! And; X, is CH,,0CHI,QC,H, or OCF! H; X, is CH,,C , Hs or CH, CF, and: Y is 0CHs, 0CxHs, 5cHs, S Cx H*, CH, or CH.

CH, is; X is CH, or 0CHs: Y3 is H or CH3; X is CH, 0CH1, QC, H, , CH20CH, or CI; and Y is CH3, OCH,, OC, H, or Cg; provided that i) x is CQ, F, When Br or l, 2 is CH and Y is OCH,,QC,H,,N(OCH ,)CM,,NHCH,,N(CHs)z or OCF,H: Li) when X or Y is C1 haloalkoxy, 2 is CH; 1ii) X, and BiY and CI at the same time? 'No; tv) When W is S, R is H and A is A-1. Yes, and Y is CH,,0CH1,OCs H*,CH,OCH,,C! H *, CF,, 5C) Il, OCHx CI (-CH2, OCH, CICH, OC H.

CM, 0CR3, CH(OCHs)z or 1.3-geo+7? It is n-2-il. the law of nature: v) When the total number of carbon atoms in X and Y is greater than 4, the number of carbon atoms in Ql or Q is equal to 4. Squid or less: vi) When J is J-6, J-7, J-8 or J-9 and A is A-7 , 2. is CH; and vi) is J-6, J-7, J-8 or J-9; A is A-1, and X and Y are haloalkoxy or haloalkyl'J- Toki, T2 is F%C1%Br, CNs SCN%Nl, C, -c, Fluco xy, CI~C, thioalkyl, NH(C, ~C2 alkyl), or] compounds, herbicide compositions containing the compounds, and pre-emergence herbicides and post-emergence herbicides thereof , for use as a post-emergent herbicide and/or plant growth regulator. For simplification The compounds are described and claimed with respect to Formula I, including all It should be understood that salts of .

In the above definition, "alkyl" used alone or in compound words, e.g. in the latter case “Alkyl” in “alkylthio” or “haloalkyl” can be straight chain or branched. branched alkyl, such as methyl, ethyl, n-propyl, improvil or different Butyl and pentyl isomers are shown.

Alkoxy includes methoxy, ethoxy, n-probyloxy, improbyloxy and This shows the butyl isomer.

Alkenyl is a straight or branched chain alkene such as l-propenyl, 2-propenyl, 3-propenyl and the different butenyl and pentenyl isomers.

Alkynyl is a straight or branched alkaine such as ethynyl, l-propynyl, 2- Propynyl and different butynyl and pentynyl isomers are shown.

Alkylsulfonyl is methylsulfonyl, ethylsulfonyl and different propyl Indicates the sulfonyl isomer.

A preferred compound A is E is a single bond; and W is 0, A compound of formula l.

A preferred compound B is E is CM, or J is J-6: and W is 0, A compound of formula I.

A preferred compound C is R1 is H, Fs C11Br%C) IICN% CH3,0CHs, 5CHs or is OCF! selected from H; R” is selected from Hs F% C1% Br or CMS; R3 is H% C3~C , alkyl, phenyl, CHICF! and CH, CH-CH,; X is C, ~C*alkyl, C, ~C, alkoxy, C11F, Br% l5OC F! H%CH! F-CFs, QCHICHJ, 0CHsCHF! ,OCH,CF , , CHICI and CH, Br; Y is H%08~C, alkyl, c I~C! Alkoxy, CM, QC)i,,CH*OCH! CHs, NHCH s, N(OCHs)CHs, N(CHs)s, CFs%5CI(s, OCHsC H-C) 11, OCH* Cif CH, OCHsCH, OCH,, CH20C H,, OCF, H% 0CF2Br, scp! )1. Cyclopropyl, CmiCH or C =CCH1; and Rh and Re are C, -C, alkyl; This is compound A.

A suitable compound is A is A-1; n is 0; X is selected from CH,,0CHI,0CHICH3,CI or OCF *H ;and Y is CH,,OCR,,C,H,,CH,OCH,,NHCH,,CH(OCH Compound C is selected from s)* and cyclopropyl.

A preferred compound E is R is H: TI is selected from CN%C1 and C, &-C, alkoxy; and T! is H% C1~C, alkyl, cyclopropyl, 01%CN and C1~C, alkoxy? selected from It is a compound.

Other suitable compounds are Compound E, where J is J-1-J-5 and J-7 to J-13.

Particularly suitable compounds are: 2-[[[[(4-chloro-6-medoxy-2-pyrimidinyl)amino]carbo Nyl]amino]sulfonyl]-N-methoxybenzenecarboximidoylchlora ido (compound 28), 2-[(cyano)(methoxyimino)methyl]-N-[ [(4-methoxy-6-methyl-2-pyrimidinyl)amino]carbonyl]ben Zensulfonamide (Compound 2), and N-methoxy-2-[[[[(4-methoxy-6-methyl-1,3,5-tria din-2-yl)amino]carbonyl]amino]sulfonylbenzenecarboxy Midoyl chloride (compound 29).

Details of the invention formula! The compounds are prepared by the method shown in Equations 1.2.3 and 4 below. However, how In the equation, J%W, A and R are as defined above.

It will be clear to those skilled in the art how to select individual compounds of Formula 1.

Equation l is the tertiary amine base of the sulfonamide, e.g. 1,8-diazabisic The suitability of nim in the presence of b[5,4,0]undec-7-ene (DBU) Examples of reactions of suitable carbamic acids or thiocarbamic acids with phenol esters Ru. A similar coupling method is described in European Patent Application No. 70.804. Ru.

The reaction of Equation l can be performed in an inert solvent such as dioxane or acetonitrile. for 1 to 24 hours, optionally under an insoluble atmosphere and in the presence of equimolar amounts of DBU, about - Works best at 5-25°C. The desired product of formula I can be obtained by converting the reaction solution into aqueous hydrochloric acid or can be conveniently separated by acidifying with acetic acid and filtering.

Alternatively, the aqueous layer may be extracted with a solvent such as methylene chloride. Drying and evaporation of solvent Explosion gives the desired product.

The phenyl carbamate and phenylthiocarbamate intermediates of formula I The method described in National Patent Application No. 8215671 and No. 8215045 or can be produced by obvious modifications thereof.

Equation 2 is the sulfonylisocyanate and sulfonyl inthiocyanate of formula ■ , with a suitable heterocyclic amine of formula V.

Equation 2 %formula% The reaction in Equation 2 can be performed using methylene chloride, tetrahydrofuran, toluene or acetonyl chloride. It is best carried out in an inert solvent such as tolyl at a temperature of about 0 to 80°C. It will be done. Catalytic amount of 1,4-diazabicyclo[2,2,2]octane (DABCO) may be used to accelerate the reaction. If the product is insoluble in the reaction solvent, It can be isolated by simple filtration. Soluble products are removed by evaporation of the solvent and the residue mastication with a solvent such as l-chlorobutane, diethyl ether or ethyl acetate. , and can be isolated by filtration.

Sulfonylisocyanate ■ (w-o) is the most recent study by Ulrich et al. Organic chemical synthesis methods (New Methods of Preparative) Organic Chemistry), Volume ■, pp. 223-241, Akade Mitsuku Press (Academic Press).

New York and London), edited by W. Foerst. can be prepared directly from the corresponding sulfonamide according to the method described. Wear.

According to this two-step process, the sulfonamide is an isolable n-butylsulfonylurea. This can be further reacted with phosgene and a tertiary amine catalyst to form a sulfonyl nitride. Manufacture socyanate. A similar one-step method is described in U.S. Pat. No. 4,238,621. It may be carried out according to the method described in .

In addition, sulfonamides can be produced by reaction with thionyl chloride to form the intermediate N-sulfinyl sulfone. An amide is prepared and exposed to phosgene in the presence of a catalytic amount of pyridine to sulfonate it. It can also be nylisocyanate. For more details, see Ulrich et al., J. See Lug Chew, 3200-3202 (1969). About.

Sulfonyl inthiocyanate (rV, W-5) from the corresponding sulfonamide , reaction with carbon disulfide and potassium hydroxide, followed by phosgeation of the resulting dipotassium salt. Manufactured by processing in a container. Such a method is based on the Arc-7 arm (Arc K, Pharm, ), 299.174 (1966).

Equation 3 is a suitable complex of the sulfonyl carbamate or thiocarbamate of formula The reaction with ring group amine V is illustrated.

The reaction of Equation 3 is approximately 20 to 1 in an inert solvent such as p-dioxane. It is carried out at 00°C for 0.5 to 24 hours. Common for producing sulfonylureas Further details regarding the coupling reaction can be found in European Patent Application No. 44.807. It has been described. The product is isolated by evaporation of the reaction solvent and this residue is Masturbate with a solvent such as 1-chlorobutane or ethyl ether and filter. or by chromatographic methods using silica gel.

Phenylcarbamates and phenylthiocarbamates of formula ■ are disclosed in U.S. Patent No. 4.4. 43.243, European Patent Application No. 44.808 or South African Patent Application No. 82 No. 15042 or obvious variations thereof.

Equation 4 shows that a sulfonamide of formula Ia can be prepared by reaction of a sulfonamide of formula Ia with a suitable salt or amine. The preparation of the corresponding sulfonamide of 1b is illustrated.

A, Alk, R and R8 are as described above; M is Na" or K"; Ta is CN%S　CN-N　s, Cs~Cs alkoxy, C,~C, thioalkyl Le or F; Tb is NH(C+~C, alkyl), N(C+~C, alkyl)2, Tc is Ta nu is Tb].

The reaction of Equation 4 is performed by converting Ia into an inert solvent such as acetone, methyl ethyl ketone, Tetrahydrofuran, dioxane, methanol, dimethylformamide (DMF ), a small amount of salt M-Ta in dimethylsulfone or dimethylsulfoxide 1 molar equivalent (at least 2 mol when Ta is an alkoxide or mercaptide) equivalent amount). The reaction takes place for 1 to 24 hours, and The process is carried out at about 20 DEG to 140 DEG C. in the presence of a phase transfer catalyst such as an ether. Living Compound 1b (Tc is Ta) is obtained by adding water, if Ta is an alkoxide or a mercaptide. It is isolated by acidification and filtration. Other aqueous suspensions such as methylene chloride Crude 1b can be produced by extraction with a similar solvent, drying, and evaporation of the solvent.

Product 1b can be obtained using a solvent such as l-chlorobutane, ethyl acetate or diethyl ether. by mastication with medium and filtration or chromatography on silica gel It can be further purified by methods. Similarly, product 1b (Tc is Tb) converts Ia into an inactive Solvents such as tetrahydrofuran, p-dioxane, methanol, methylene chloride or is preferably reacted with about 2 to 20 molar equivalent excess of amine H-Tb in DMF. It can be manufactured by This reaction is carried out at approximately 0-100°C for 1-24 hours. be exposed. The processing is as described above.

Similarly, by using the method described in Equation 4, J becomes J.

~J13 and Ql or Q2 is C(C1)NOAIk From the corresponding compound, the formula! Other compounds can also be produced.

As illustrated in equation 5, the intermediate sulfonamide of formula Crossley et al., J. Am, Chem, S. oc, ) 60.2223-2224 (193B); Baylor , Monatsh, Dan, 667-683 (1961); and U.S. Pat. No. 4.511.392, the corresponding sulfonyl chloro by amination of the ride with anhydrous ammonia or aqueous ammonium hydroxide. Manufactured by

As shown in Equation 6, the sulfonamide of formula It can also be produced by deprotonation of mido.

For convenience, the reaction in Equation 6 is based on Catt et al. Chew, ), 39, 566-568 (1974). in fluoroacetic acid (TFA) or Lomardino, J. Polyphosphoric acid according to the method of Org Chem, 36.1843-1845 (1971) This is done using In addition, t-butylsulfonamide, toluene or xylene reflux in a solvent such as 1 to 24 hours catalytic amount of p-toluenesulfonic acid (p - TSA) may be used to produce (2).

The intermediate sulfonyl chloride of formula ■a is preferably of formula ■a as shown in equation 7. is prepared by oxychlorination of the appropriate thioether.

In formula 1, J is as described above, E is a single bond, and R4 is C! ~C,A benzyl or benzyl].

The reaction of Equation 7 involves the suspension of a thioether in a solvent such as acetic acid or propionic acid. the solution in the presence of at least 2.5 equivalents of water at about -20 to 30°C for 0.2 to 5 hours. This is done by contacting with 3.0 equivalents of chlorine.

The reaction mixture is poured into ice-water and the product is filtered or purified with a solvent such as methylene chloride. Isolate by extraction with The extraction product is optionally neutralized or slightly Wash with aqueous sodium bicarbonate until basic, then dry and evaporate the solvent. to obtain a sufficiently pure product that can be used directly in the next step.

In addition, a hypochlorite solution of a thioether ■ in which R is benzyl or hydrogen, i.e., Na0 Reaction with C2 can give the sulfonyl chloride ■a. More details See similar reactions in South African Patent Nos. 84/8845 and 84/88449. Also, mercaptans or thioethers are chlorine and potassium hydrogen difluorides. It is transformed into sulfonyl fluoride by the reaction of Alternatively, it can be reacted with ammonium hydroxide to form a sulfonamide; e.g. Brown et al., J-Chem, Soc, Burki 1,522 = 527 (1 972).

Sulfonyl chloride ■a can be obtained by diazotization reaction as illustrated in equation 8. May be manufactured.

Amine hydrochloride is treated with nitrite in an organic solvent such as acetonitrile or acetone. and the resulting diazonium salt with sulfur dioxide and sulfur chloride. ①a is produced by reacting with copper. Doyle, J., Org. 2, 2426-2431 and 2431-2436 (1977), similar reactions It describes an incident against. In addition, sulfonium chloride ■a is aqueous diazotization European Patent Application No. 83,975 See No. 85.476. Aromatic amines of formula X can be reduced using various known reduction methods, e.g. For example, synthetic organic chemistry stry), 4th edition, pp. 557-563, John Wiley & Sump ( John Wiley and 5oz, New York, Lo (ed.), Hilgetag et al., and European Patent Application No. 07.894 from the corresponding nitro compounds.

The sulfonyl chloride of formula (b) is shown in equation 9 and described in U.S. Pat. No. 4,420. 325 from compounds of formula (1).

In formula 1, J is as described above, and [X] is a suitable halogen or other agent, such as N- bromosuccinimide].

The thioether of formula (I) is an important intermediate for preparing the compounds of the present invention; They can be manufactured by a variety of common methods known in the art. some such people The method is described in Equation lO~15 below.

Equation 10 is for a thioether of formula ffa containing a σ-chloroxime residue, of formula Production from carboxylic acid is illustrated. Continuation <IIa, suitable salt M-Ta or amine Reaction with H-Tb gives the thioether of formula 1b.

[wherein R,, R4, Al2, M%Ta%Tb and Tc are as described above; and [X] is as defined later].

In Equation 10a, the carbon axI is converted to the acid chloride, which in turn is It is converted to the N-alkoxyamide, which can be isolated by known methods.

Reaction of the leading amide with a suitable halogenating agent [X] gives a compound of formula IIa. Ru. Suitable halogenating agents include inert solvents such as benzene or chloroform. , phosphorus pentachloride or phosphorus pentabromide at about 5-40°C ζl for 24 hours; or methyl chloride in an inert solvent such as chlorobenzene, benzene or chlorobenzene, from about lO to 130°C. , preferably phosgene or thionyl chloride and a catalytic amount of DMF; or more preferably in an inert solvent such as acetonitrile, about 0 Equimolar amounts of triphenylphosphine and tetrachloride at ~80°C for 1-24 hours Contains carbon (or carbon tetrabromide). The compound of formula IIa is prepared by evaporation of the reaction medium under vacuum. isolated by and optionally treated with water followed by chromatography on silica gel. It can be purified by

The reaction of Equation 10b is performed in the general manner described in Equation 4.

Formula 11 is a formula I containing a σ-cyanoxime residue! of formula X of the thioether of c The preparation of ll+ from the corresponding aldehyde is shown.

Equation 11 1) NaBH,, C2H, 0H125℃; CH30H ,H,O.

X111 5) M-Ark, base [in the formula, R8, R 6, M and AΩ are as described above].

Reactions 1) to 4) in Equation 11 are performed by generally known methods, and when Al2k is H and Provides an unmasked oxime of formula IIc. This masking oxime, a suitable base and reagents in an inert solvent by generally known methods. Subsequent reaction with M-AI2 gives the masked oxime IIc. Appropriate The base and solvent were potassium tert-butoxide in DMF or sodium tert-butoxide in methanol. Contains lium methoxide. Reactions 4 and 5 of Equation 11 are further illustrated in Example 7. shown.

Analogously to the reactions described in Equations 10 and 11, the appropriate corresponding carboxylic acid or is another formula ■ in which J is J, ~Jll, by performing a reaction with an aldehyde. Thioethers can be produced.

Equation 12 illustrates the preparation of aldoximes and ketoximes of formula IId.

[In the formula, R1, R and lk are as described above; Td is OCHs or S C3-C, alkyl substituted with CH3: or cyclopropyl; Td' is Td or CF, CF　s　CF　s, CF3CF*CF, or H can be; Te is Td' or CO,H: and Te' is Td'].

In Equation 12a, 2-fluoropyridine XIV is r) et al., J. Organomet, chem, 215 % 139-150 (1981) metallization with acid chloride (LDA), followed by acid chloride or N,N-di Treatment with methylamide (or carbon dioxide and H,O) to produce the corresponding ketone or alkali Produce dehyde (or carboxylic acid). In equation 12b, halopyridine Reaction of V with a suitable mercaptide in a solvent such as DMF produces the corresponding thioether. give ru. This is obtained by the formula TXd upon reaction with an alkoxyamine by known methods. produce compounds. U.S. Pat. No. 4,456,469 discloses a similar halopyridine-method Discloses the lucaptide reaction.

Also, by known methods, the aldo or keto-thioether of equation 12b can be by reaction with roxylamine followed by a suitable base and alkylating agent M-AQk , masked t; can produce oxime IId. suitable base and The solvent is as described in Equation 11. trifluoromethylketone, hydro Details regarding the reaction with xylamine can be found, for example, in Rosenfeld. U.S. Pat. No. 3,748.361 to R.L. Vador et al., J.

See Med, Chem, ■, 646-650 (1972). thing.

Oximes of formula Ifd where Te' is CH2CN can be prepared using generally known methods. and a suitable 2-benzylthio-3-pyridyl-carboxylate ester. It can be manufactured using a two-step method. i.e. the ester in an inert solvent such as tetra Reaction with a suitable base such as sodium hydride and acetonitrile in hydrofuran gives the corresponding 3-ketoacetonitrile, which is followed by the appropriate alkoxyamine or more preferably its hydrochloride in an inert solvent such as methanol or DMF. The reaction in gives ffd (Te' is CH, CN).

The pyridyl alkyl ketones described in Equations 12a and 12b are the appropriate pyridyl They can also be prepared by reaction of acid chlorides with alkyl Grignard reagents. For more information For example, see Japanese Patent Publication No. 60-253.531.

Marsais et al., J. Augmet Chem 2, supra 6.　139～ 147 (1981) of 3-chloropyridine and its tetrahydrofuran. For reaction with butyl lithium in medium lithium dialkylamide or diethyl nityl describes the preparation of 3, 4 and 2,3-disubstituted pyridines according to the present invention. such a rich The reaction of the intermediate with the reagent described in Equation 12a, as well as the reaction of Equation 12b, By reaction, the corresponding 3,4- and 2,3-isomers of IId can be obtained.

For further details regarding the synthesis of pyridines, see Beritmeyer. Tetrahedron, 26.5907 (1970); Blank et al., J. Met. Chem. Hill, 1065-1. 071 (1974); Mallet et al., Tetrahedron, Earthworks, 3 433 (1985), and Delarge et al. Annales Pham, France, 36,369 (1978), and R,L, Salvader et al., Tetrahedron, ■, 1221- 1226 (1971), pyridine of the formula ■, where J is J-6 to J-9. N-oxidation of sulponamides follows known methods for oxidation of pyridine compounds. It is done.

Equations 13 and 14 illustrate the preparation of thio7ene carboxylic acids of formulas IIe and Iff do. This acid is an intermediate for the preparation of compounds similar to those described in Equation 1o. It can be used as Also, the reduction of the ester or its ester is written in Equation 11. Methyl alcohols for similar reactions described can be given: Equation 13 In equations 13 and 14, metal-halogen exchange or diacid by known methods Metallization with carbon or disulfide is carbon DI! Give e and f. 3. Starting with 4-dibromo-thiophene and carrying out the reaction of Equation 13, the acid The 3,4-substituted isomer of is formed. Regarding production of thiophene and treatment of functional groups Further details can be found in U.S. Patent No. 4.481.029 and Knight See et al., J., Kem. T., Parkin Trans. 1, 791-794 (1983). Served.

Equation 15 illustrates the preparation of several pyrazole thioethers of Formula IIg. child This is followed by subsequent reactions similar to those described in Equations 10111 and 12. .

[In the formula, Tf is H1 optionally OCH,, SCH, or C, -C substituted with halogen , alkyl; cyclopropyl, oH or OCR, and R, , R, and and R4 are as described above.

The compound of formula XVI in equation 15 is known or prepared by known methods. For example, Kviko et al., Zurnar Oru 0-1754 ( 1972) and Japanese Patent Publication No. 57-228261.

t-Butylsulfonamides of formula XIX% XXI and XXIII are compounds of the invention It is a useful intermediate for manufacturing products and can be prepared by known methods or simple variations thereof. It can be manufactured using Some such methods are Equations 16.17 and 1 8 is exemplified.

[In the formula, Tf is as described above].

The preparation of intermediates such as bromide XVIII is described in European Patent Application No. 95.925. It can be seen in the number. Exposure of bromide XVIII to BuLi, suitable acid solution Treatment with loride, DMF or carbon dioxide gives XIX.

In Equation 17, the isomeric 5-keto-4-sulfonamide is prepared as outlined. while in equation 18 the isomeric 4-keto-3-sulfonamide is outlined as Manufactured to suit.

Intermediateization of Formulas XIX%XXI and XXII+ in Equations 16.17 and 18 The compound undergoes subsequent reactions similar to those described in Equations 1O112 and 12. Can be done.

Further details regarding the synthesis of pyrazoles can be found, for example, in European patent application no. 7.780, South African Patent Application No. 833.350, European Patent Application No. 95.9 No. 25, and Jacobs, “Heterocyclic Compounds,” Elderfie. Elderf 1eld II, Volume 5, pp. 45-161, Wiley Publishing ( Wiley, New York), 1957.

Various reactions described throughout this specification with respect to J%R1-R3, Ql and Q, Chemical compatibility of reactants and reaction conditions must be evaluated and judicious choices made. do not have. Based on this discussion, peers will be able to accept such evaluations and selections without undue difficulty. It could be done easily. Furthermore, in some cases, as is clear to peers , incompatibilities can be easily resolved by appropriate selection of protecting groups. . As a collection of references describing a variety of such protecting groups, see Green ( Greene et al., “Protecting Groups in Organic Synthesis”, John Wiley &amp; See Sands, Inc., 1981.

The heterocyclic amine of formula V in Equation 2 above may be a or by a simple modification thereof. For example, European Patent Application No. 84.22 No. 4 and Braker et al., J. Chem, Soc. ), 69.3072 (1947), among others, dialkoxymethyl or 1,3-di Preparation of aminopyridines and triazines substituted by oxolan-2-yl describes the law. Also, South African Patent Application Nos. 8215045 and 8215671 The number is a haloalkyl or haloalkylthio group such as 0CHxCH2F10CH* CFs, S　CF　xH- and 0CF2H-substituted aminopyrimidines and Describes the method for producing riazine. South African Patent Application No. 83/7434 is haloalkyl, alkoxy, haloalkoxy, alkylamino, dialkyl Cyclopropylpyrimidine substituted with groups such as amino or alkoxyalkyl This paper describes the synthesis of triazines and triazines.

5.6-cyhydrofuro [2,3-dl pyrimidin-2-amine, cyclopene Ta[dco]pyrimidine-2-ami7 (V, A is A2), and 6,7-dihy Toro 5H-pyrano [2,3-dl pyrimidin-2-amine (V, A is A -3) may be manufactured as described in European Patent Application No. 15.683. I can do it. 7o [2,3-a] Pyvmidine-2-7mine (V, A is A- 4) is described in European Patent Application No. 46.677. A is A-7 Compounds of formula V are described in European Patent No. 125.864.

Compounds of formula V where A is A-5 are described in European Patent Application No. 73,562. Ru. Compounds of formula V, where A is A-6, are described in European Patent Application No. 94.260. Ru.

Additionally, for general methods for producing aminopyrimidines and triazines, please refer to the following publications: "Chemistry of Heterocyclic Compounds", Interscience Publishing (In terscience Pufl, New York.

Series of books published by London; Brown, “Pyrimidine”; Volume 14 of the same series; Smo I n et al., “S-triazine and Derivatives'', Volume 13 of the same series; U.S. Pat. No. 3,154,547: and Huffman et al., J. Org., describes the synthesis of riazine. ・Chem (Org, Ch em,), 28% 1812-1816 (1963) .

Agriculturally suitable salts of compounds of formula It can be manufactured by the method. For example, metal salts may be used to protect compounds of formula I from sufficiently basic alkyl salts. Aluminum containing ions (e.g. hydroxide, alkoxide, or carbonate) Can be produced by contacting with solutions of potash or alkaline earth metal salts. Wear. Quaternary amine salts can also be made using similar techniques.

Salts of compounds of formula I may be prepared by mutual exchange of certain cations. Click The exchange of ions can be carried out using an aqueous solution of a salt (e.g. an alkali or quaternary amine salt) of a compound of formula 1. This can be done by directly contacting the cation with the solution containing the cation to be exchanged. Wear. This method ensures that the desired salt containing the exchanged cation is insoluble in water and cannot be filtered. Therefore, it is most effective when it can be separated.

The exchange involves replacing an aqueous solution of a salt (e.g. an alkali metal or quaternary amine salt) of a compound of formula I with in a column packed with a cation exchange resin containing the cations to be exchanged in place of the original salt. This can be done by passing the column through the column and allowing the desired product to flow out of the column. can. This method allows the desired salt to be water soluble such as potassium, sodium or calcium. It is particularly useful when it is a mu salt.

Acid addition salts useful in this invention include compounds of formula I prepared by adding a suitable acid such as p-toluenesulfonate. It can be produced by reacting with phosphoric acid, trichloroacetic acid, etc.

The following specific examples further illustrate the preparation of compounds of the invention. Light and temperature that won't turn you down is Mr. Serra.

Example 1 N-methoxy-2-[(phenylmethyl)thiobenzamidobenzene 800- 2-[(phenylmethyl)thio]-benzoic acid 100 g and thionyl chloride 97. 6 g of the suspension was refluxed for about 3 hours and then evaporated to dryness under vacuum. This residue 2-[(phenylmethyl)thiamine with a melting point of 113-116 101.2 g of benzoyl chloride was obtained.

Cooled to below 5°C by external cooling; 500% water and 200% methylene chloride. - 48.2 g of methoxylamine hydrochloride is added to a suspension of 80.2 g of potassium acid the above acid dissolved in 700 mg of methylene chloride after about 10 minutes. Chloride I OIg was added dropwise. After stirring the suspension for 1 hour at 0°C, Stir for 2 hours without cooling, separate the organic layer and dry (MgSO4). It was then evaporated to dryness under vacuum. The residue was recrystallized from 1-chlorobutane to give a melting point of 1 79 g of the title compound were obtained at 00-105°C.

Example 2 N-methoxy-2(phenylmethylthiobenzenecarboximidoylchloride) de In benzene 1500i under N, atmosphere cooled to 20-30℃ by external cooling. Illustrative Example 1 To a suspension of 79 g of product was added portionwise 60.2 g of phosphorus pentachloride. 2 After stirring at 5°C for about 24 hours, the suspension was warmed to 40°C for about 4 hours and then to 25°C. Cooled and filtered. The filtrate was evaporated under vacuum below 40°C and the residue was dissolved in methylene chloride. The subject compound 47 was subjected to chromatography on silica gel with g was obtained as a crude yellow oil: NMR (CDC(is): ppm 4:15 (m-3 8-0CHs), 4.6 (s, 2H, CH,), 7.4 (m, 9H, Ar).

Example 3 2-(Chlorsulfonyl)-N-methoxybenzenecarboximidoylchloride workman Product of Example 2 in glacial acetic acid 125+nQ cooled to about 13° C. with external cooling. 8.6++ff of chlorine was added dropwise to a solution of 1.9 g of water and 1.9 g of water. at 10-15℃ After stirring for 1 hour, the suspension was poured into excess ice-water and the mixture was dissolved in 1-chlorobutane. Extracted with. This extract was washed twice with water and then with saturated aqueous sodium bicarbonate. washed again with water, dried (MgSO,) and evaporated under vacuum at 40 °C. The title compound was obtained as a crude oil.

Example 4 2-(Aminosulfonyl)-N-methoxybenzene-carboximidoylchloride Engineering Cooled to -30°C by external cooling; carried out in 100ml of tetrahydrofuran. To the solution of the crude oil of Example 3, 1.7 i of ammonia was added dropwise. Stir at -30℃ for about 15 minutes. After stirring, the suspension was purged with N, to remove excess ammonia, and then removed under vacuum. It was evaporated at below 30°C. After adding ice-water to this residue, the suspension was dissolved in methyl chloride. Extracted with 100 ml of olefin, dried (MgSO4) and evaporated under vacuum. child The residue was masticated with hexane to give 2.5 g of the title compound, melting point 155-158°C. It was obtained as a rough surface.

NMR (CDCQ3+DMSO): ppm4.2 (s, 3H, 0CHs), 6 °6 (bS, 2H, NH2), 7.8 (m, 48% Ar).

Example 5 2-(4-methoxy-6-methyl-2-pyrimidinylaminocarpoille,.

Aminosulfonyl -N-methoxybenzene 0.4 g of the product of Example 4 and phenyl (4- Suspension of 0.46 g of methoxy-6-methylpyrimidin-2-yl)carbamate 25g of DBUo was added to it. This suspension was stirred at room temperature for about 2 hours and then diluted with excess water and filtered. The filtrate was acidified with concentrated hydrochloric acid to obtain a precipitate. After filtration , the residue was washed with excess water and dried with suction to give the subject compound, melting point 178-179°C. 0.35g was obtained.

IR (Nujol): 1700cm-' (C-0); NMR (CDCffs) : ppm2.4(s, 31(,CHs), 3.9(s13H.

0CHs), 3.95 (s, 3H, N0CHs), 6.3 (s% IH, py- H), 7.3 (m% IH%NH), 7.5 (m% IH, Ar), 7.7 (m% , 2H.

Ar), 8.4 (m% IH, Ar), 13.2 (bs, IH, NH).

Example 6 N-methoxy-2-[(4-methoxy-6-methyl-1,35-)riazine-2 -yl)amine carbonyl amino sulfonyl benzenecarboximido Luchloride.

! l! By the method of Example 5, 0.4 g of the product of Example 4 was converted to phenyl (4-methoxy). 0.46 g of C-6-methyl-1,3,54 riazin-2-yl)carbamate and and DBUo, 25 g. The resulting suspension was added to concentrated hydrochloric acid without filtration. and filtered. The residue was washed with excess water and dried with suction to a melting point of 182. Obtained 0.45 g of the title compound at ~184<0>C.

IR (Nujol): 1700cm-' (C-0) NMR (CDCffx) : ppm2.6 (ss 3H, CHs), 3.95 (s, 3H.

N0CH, ), 4.1 (s, 3H, 0CHs), 7.4 (bsl 1H, NH) , 7.5 (m, 1) 1. Ar), 7.7 (m, 2H, Ar), 8.4 (m, IH .

Ar), 12.4 (bs, IH, NH).

Example 7 a-(methoxyimino)-2-[(phenylmethyl)thio]benzeneacetoni begging 2-[(phenylmethyl)thio]benzeneacetonitrile in methanol 350- A suspension of 41 g and 9.4 g of sodium methoxide was stirred under N at 25°C for 1 hour. Stir and then reflux for 1 hour and cool to 10°C. n-Butylnitrile (17 , 7 g) was added dropwise and the suspension was stirred for 16 hours at about 25°C and then evaporated under vacuum. I set it. Excess water was added to this residue, the emulsion was washed with methylene chloride, and the three-phase water - A mixture of oil and methylene monochloride was obtained.

The oil layer was separated and acidified with concentrated hydrochloric acid in water. Extract the suspension with methylene chloride The crude σ-(hydroxy imino)-2-[(phenylmethyl)thio]benzeneacetonitrile 26.9g was obtained as an oil.

To 15 g of the above crude oil in DMF 125+a12 was added potassium ter 6.6 g of t-butoxide was added. After stirring for 1 hour, the suspension was heated to 50°C for 1 hour. The mixture was heated for a while, and 7.1 g of dimethyl sulfide was added dropwise at 40°C. This suspension was heated at 25°C overnight. diluted with excess water, extracted with diethyl ether, and the extract was dried (M gS　O4) and evaporated under vacuum. Silicage the residue using methylene chloride Chromatography on a column gave the title compound as an oil.

NMR (CDCffs): ppm4.0-4.2 (m-5H%0CHs, CH ), 7.4 (m, 9H, Ar).

Example 8 2-Cyano(methoxyiminomethylbenzenesulfonamide 5! Example 3) According to the method, 11 g of the product of Example 7 were dissolved in 2.2 g of water and salt in 125 m4 of glacial acetic acid. It was reacted with element 9,9rr+(l.After treatment, 2-[cyano(methoxyimino) ) Methyl]benzenesulfonyl chloride was obtained as a crude oil.

By the method of Example 4, all of the above crude oil was dissolved in 100 mβ of tetrahydrofuran. It was reacted with 1.7 ml of ammonia. After treatment, the residue was masticated with hexane, Recrystallization from 1-chlorobutane gave 2 g of the title compound, melting point 82-90°C. .

NMR (CDC4g): P pm4.3 (s-3H,0CHs), 5.4 (b s, 2H, NH,), 7.7 (m, 3HSAr), 8.2 (m, IH, Ar).

Example 9 2-(cyano(methoxyimino)methyl-N-(4,6-cymethoxy1) ．． 3.5-) Riazin-2-ylamino carbonyl benzenesulfone L earthwork By the method of Example 5, 0.4 g of the product of Example 8 was added to 10 g of dry acetonitrile. - medium phenyl(4,6-simethoxy1.3.5-triazin-2-yl)car React with 0.51m (Bame) and 28g of DBUo, melting point 191-194℃ 0.6 g of the subject compound was obtained.

IR (Nujol): 1710cm-' (C-0) NMR (CDCj2a) = 1) pm4.1 (s, 6H, 0CHI), 4.2 (s, 3H.

N OCH3), 7.4 (bs, IH, NH), 7.6 (ml 1H%Ar), 7゜8 (m, 2H, Ar), 8.5 (+f+, IH, Ar), 12.3 (b s , l　H.

NH).

Using the method described in Equation 1-18 and Examples 5.6 and 9, or simple variations thereof, The following compounds in Tables 1 to 9 were prepared using the following methods.

General formulas in Tables 1 to 9 Table 1 (continued) J(-HHCI CHs 0CHsCHxCFs 0CR sJ-1-HHCI　　　　CHz　　ocHzCHF2　CH sJ (-HHCI CHs 0CHzCFs CHsJ -1-HHCI CHa CI QC! 88J- 1-HII C1cps oc, us NHC) Is J-1-HHCI CHs 0CHs CH25C HsJ(-HHCI CHs-0CFJ CHxJ(-HHCI 　　　　CHs　　　　CI　　　　　　0CFJJ(Cut　HHC I CHx 0CRs 0CHsJ (CHI H HCN　　　CHs　　　　　　　　　　　　　　　　　　　　0CHsJ-1-HH CI C, Hl OCH3ocnsJ-1-HHC1c, a ,　　　　　CH, ocaxJ(-HHCI　　　C2H5CH3CHl J(-HHCI CIHs CI 0CRsJ- 1-HHCI CJs Br 0CHsJ (-H HCI　　　CJs　　　CHs　　　　HJ(-HHCI) CIHI OCH3HJ-1-HII CI CIHI 0CHs CHxOCJsJ(-HHCI C5Hi 0CFJ 0CHsJ (-HHCI CJi 0CHs CH(OCHs)*J(-HHCI CJs C11s 0CJsJ-1-HHCI CxHs CHa CHxOCHs Table 1 (continued) J-1-HHCI C, H, 0CHs CH, QCH.

J-1-HHCI C! H!　　　　　　　　　　　　　　　　　　CJsJ -1-HHCI CzHs 0CxHs 0C1b J-1-HHCI CJs 0CHxCFs 0CHs J-1-H’A CI CJs CFs 0CRsJ-1-HHC1c, H, CH2F 0CHIJ-1-H HCI C2HI CH2Cl C) CHlJ-1- HHCI C2H8CHJr 0CRsJ-1-HHCI ClH8F 0CHsJ-1-HHCI CIII 　　　　　I　　　　　　0CHsJ-1-HHC1c,a, 0CH2t&F 0CHsJ-1-HHC1c, n, OCR , CH2CF2 C1゜J-1-HHCI CxHs 0CHaCHFa CHaJ(-HHCI CxHs 0CToCFs CHsJ-1-HHCI CJs C,) I I oc, a, NHCH3J (-HHCI C lH80CH1CHsSCHsJ-1-HHCI C2H50CFJ CHlJ-1-HHC1c, H, CI 0CFIHJ-1 -HHCI　　　　n-C5Hy　　　OCH30CHsJ(-HHC1 n-C5Ht CHs 0CTIsJ-1-HHC1n-C 5Ht　　　　CHs　　　CHa Table 1 (Standard) J(-HHC1n-C5Hy CI OC’AsJ-1-H HCl n-C5H= Br 0CRsJ-1-H 11C1n-Cs1lt CHs HJ-1-B HC1 n-C5Ht 0CHs HJ(-HHC1n-Cant 　　　　　　　　　　CHzOCJsJ(-HHC1n-C5Ht) 0CFJ 0CHsJ (-HHC1n-C5Hy OCH3C 1 (OCHs) *J-1-HHC1n-C5Hr CHs 0 CtHsJ-1-H11CI n-C, HI Cl, CHxOCHaJ(-HHC1n-C5Ht 0CRs C l! QC) IsJ-1-B HC1n-C5Ht OCH3CIH IJ-1-HHC1n-Cant OC*Hs 0CRsJ(- HHC1fl-C3Ht 0C4CFs 0CRsJ-1-HB C1n-CJy CFs 0CRsJ-1-HHC1 n-C5Hy CHJ 0CHsJ (-HHC1n-C5H t CHICI 0CHsJ(-HHCI n-C5H y CHJr 0CTi@J-1-HHC1n-Cant 　F　　　　　α].

J(-II II C1n-CJy 1 0CR sJ-1-HHCI n-C5Ht 0CHzCHJ 0 CRsJ-1-II HC1n-CJy OCH, CH, CF, O C.R.

J-1-B HC1n-C5Ht OCH*CHF5 CHa Table 1 (continued) JERR'/R'/T' Alk X YJ-1-HHC1 n-C3Hy 0CHICFs CHsJ(-11HC1n-C3 H7CI　　　　　　0CzHsJ　-1-HHC1n-C3Hy　　　o c, u, NHCHsJ-1-HHC1n-C3Hy 0CHs 　　　　CHxSCHsJ(-HHC1n-C5Ht　　　　　0CF2HC HlJ-1-HHC1n-C, It CI 0CFJJ(- HHCI C0(CHs)t 0CHs 0CRsJ- 1-HHCI CH (CHs) * CHs 0CHsJ -1-HHCI CB(CHx)* CHs CHnJ -1-HHCI C1 (CHn) * CI 0CRs J-1-HHCI CH(CHs)t Br 0CR sJ-1-HHCI CH (CH3)!　　　　CHs　　　HJ -1-HHCI　　　　C1(CHI)!　　　　　　　　　　　　HJ- 1-HHCI CH (CHi) x 0CRs CH25 CHsJ(-HHCI　　　　CH(CHs)＊　　　　　0CFJ　　　0 CRsJ-1-HHCI　　　　CB(CHI)!　　　　0CR1CB(O CRs) *J-1-HHCI C1(CHs) x CHs 0CtHsJ-1-HHCI CHCCHs)RCHI CHxOCHaJ(-11II CI C1(CHs)x 0CRs CH*0C11aJ(-HHCI CB(CH s) * 0CHs CJsJ(-HHCI C1(CH s) s OC*Hs 0CHsJ(-II HCI CH(CHs)s 0CHICFI OCH8J-1-HHCI CH(CHx)x CFs 0CHxJ-1-HHCI CH (CH3)!　　　CHzF　　　OCHiJ-1-HHC I CH(CHs) x CHzCl ocusJ(-HH CI CH (CHs) * CHJr ocn.

J(-HB CI CH(CHa)x F 0CHaJ(-HHCI C)l(CH3)z I I 0CHsJ(-HHCI CH(CHs)t OCH*CHJ 0CRsJ-1-HHCI CH (CH3)!　　　　0CHz CHzCFsOCHsJ(-HHCI　　　　CH(CH3)! 　　　0C 1bCHFx CHsJ(-HHCI) CH(CHs)z 0CHzCFs CHaJ(-HHCI CH(CHs)t CI 0CJsJ(-HHCI CH(CH3)2 0CJa　　　NHCHsJ(-HHCI　　　　CH(CHs)20CH s CHxSCHsJ(-HHCI CH(CHs)g 0CFJ CHsJ(-HHCI CH(CHs)* CI 0CFJJ-1-HHCN CHl OC H30CHsJ-1-)I HCN CH, CH30CH3J-1 -HHCN　　　　C)ISCH,CHaJ(-HHCN　　　　C)Is 　　　　　　CI　　　　　0CHsJ(-HHCN　　-CH3Br　 　　　　　　　　　　　　　　　　　　　CHs HJ-1-HHCN cHs OCH,) 1 table 1 (To) J-1-HHCN CH,OCH3CHl0CR)IIJ-1-HHCN 　　　　CH,0CFJ　　　0CH3J-1-HHCN　　　CHs 　　　　　　　　　　　CH(OCHs)zJ-1-HHCN　　cH ,CH,oc,H.

J(-HHCN CHs CHs CHzOCHsJ- 1-HHCN CH30CH!　　　CHaOCHxJ-1-1(HC N CH30CH, C, HBJ-1-HHCN CH, QC2H8 QC) IsJ-1-HHCN CHs 0CHzCFx 0CHsJ-1-HHCN CHs CF3 0CH3 J-1-HHCN CHI CH2F 0CJJ- 1-HHCN　　　　CHs　　　CHzCl　　　　0CHsJ-1 -HHCN CHs CHxBr 0CHsJ-1-H HCN CJ F F 0CHsJ-1-1 (HCN 　　　　CH,I　　　　　0CH3J(-HHCN　　　　CHs　 0CHsCHJ 0CHsJ-1-HHCN CHI 0CHsCHzCFs 0CHsJ(-HHCN CHs 0CHzCHFz CHlJ-1-HHCN CHs OCH, CF3 CH.

J(-HHCN CHl CI 0CJiJ-1-H HCN CHs 0CJs NHCHs Table 1 (Unified) J E RR’/R”T’/T”Alk X Y J-1-HHCN CHs 0CHs CHsSCHs J-1-HHCN cps 0CF2HCHsJ-1-HHC N C13CI OCF, HJ(-HH0CHs CHs 　　　　　　　　　　　　　　　　　　　　0CR3J-1-HH0CHs　　　CHl　 　　CHs　　　　0CRsJ(-HH0CHs　　CHs　　　 CHs　　　　C)IsJ(-HHOCH3CHs　　　　　CI 0CHsJ-1-HH0CRs CHs Br 0C RsJ-1-HB 0CRs CHs CH= HJ-1-HH0CHs CHI OCHi H J-1-HH0CRs CHs 0CHs CHzOCJ sJ-1-HH0CHs CHs 0CFJ 0CHsJ (-HH0CRs CHs 0CHs CH(OCTo) xJ-1-HHoca, CH3CL QC, H.

J-1-HHOCH, cHn CH, CHlOCR.

J(-[I B 0CRs CHs 0CRs CHaOCHxJ(-HH0CRs CHs 0CHs CxH*J-1-B Hoca, cHx oc, n, 　OCH.

J-1-HH0CRs CHs 0CHxCFs 0CRs J(-HH0CHs CHs -CFs 0CH3J-1- 11HOCHi CHs CHzF 0CHsJ-1-HH 0CR3CH, CH, CI OCR.

Table 1 (Unified) ±　　　　RR1/R　71　/’r　!　　　　　　　　　　　X　　　 YJ(-HH0CHs CHs CHJr 0CHsJ -1-HH0CHs CH3F QC)IsJ(-HH0CH s CHs I 0CHIJ-1-HH0CHs 　　CHs　　　　　　　CHzCHJ　　　0CHsJ-1-HHQC)l , CH,OCH,CH,CF30CH$J-1-HHOCH,CHI 　　　　　0CHzCHF＊　　CH.

J(-HH0CHa CHs 0CHzCFx CHsJ -1-HHOCHi CH, CI QC, HaJ-1-HHO CH, CM, 0CJs, NHCH.

J-1-1 (H0CHs cH, OCH3C) 1.5CHIJ (-HHO CH3CHI OCF! HCHsJ-1-HHQC)Is　　C Hs　　　　　CI　　　　OCF, HJ(-HHN(CHs)s　C Hs　　　　　　　　　　　　　　　　0CHsJ-1-HHN(CHI)!　　 CHs　　　　CHs　　　　　0CRsJ(-HHN(CHl)!　C HI GHs CHaJ-1-HHN(CHs) CH s CI 0CHsJ-1-HHN(CHs)s CH s Br 0CHaJ-1-HHN(CHs) x CH s CHs HJ(-HHN(CH3)! CHI OCH3HJ(-HHN(CHI)! CHs 0CRs 　　　CHzOCtH*J(-HHN(CHs)*　CHs　　　　0 CFJ 0CHsJ-1-HHN(CHs)* CHi 0 CHs CM (OCHi) *Table 1 (猖) 上上lord□□Alk　X　Y J(-HHN(CL)g CHs CHs 0CdbJ- 1-HHN(CHs)s CHs CHa cn, oca .

J-1-HHN(CHI)! CH30CHI CHzOCHsJ- 1-HB N(CHs)z CHs 0CHs CxHsJ(-HHN(CHI)! CH30CJs 0CRsJ-1 -HHN(CHI)! CI, ocntcFs 0CRsJ -1-B HN(CHi)t CHx CFs 0C RsJ(-B HN(CHI)! CHs CHJ 0CIbJ-1-HHN(CHa)* CHs CHxCl 0CHaJ(-HHN(CHs)* CHlCHJr OCHmJ( -HHN(CL)z CHs F 0CHsJ(-HH N(CL)z CHs I 0CHsJ-1-HHN ( CHI)!　can　　　　0CIbCHJ　　ocu.

J-1-HHN(CHs) x CHs 0CHiCHxCFs 0CRsJ(-B HN(CHx) x CHs 0CR1CH F!　　　CHIJ(-HHN(CHs)z　CHs　　　　　0CHxC Fs CHsJ-1-B HN(CHs)*CHs C I QC! HeJ(-HHN(CHx)t CHs Q ClHI　　　NHCHsJ(-HHN(CHi)z　CHs　　　 0CRs　　　　CHtSCHsJ(-HHN(CH3)!　CHs　 OCF! HCHIJ(-11HN(CHi)* CHx C I OCF! 11J(-HHCN　　　CJi　　　　　0C Hs　　　OCH3 Table 1 (Standard) J-1-HB CN CN CxHs CHs 0C HsJ-1-HHCN C2Hi CH, Cl.

J-1-HHCN　　　　　C, H8C1ocusJ(-HHCN　　　　n -cn)! ?　　　　　　　　　　　　　　　　0CRsJ(-B　　HCN　 n-CJt CHs 0CHsJ(-HHCN n- C5Ht CHs CHsJ-1-HHCN n-C5H y CI 0CH3J(-HHCN CH(CHi)* 0CRs 0CRsJ(-HH’ CN CH(CH3 )! CHs 0CRsJ-1-HHCN CH (CHs) z CHI CH.

J-1-HHCN CM (CHs)s CI 0C RsJ-1-HHoca, C2H50CHs ocasJ(- HH0CHs CJi CHs 0CHsJ-1-H HOCH3C2H@ co, co.

J-1-HH0CHs caHs CI 0CH8 J(-HH0CHs n-C5Ht 0CHs 0CH sJ(-HH0CHs n-C5Hr CHs 0CH sJ(-)I H0CHa n-C3Hy CHs CHsJ-1-HH0CHs n-C5Ht 'CI' 0CHsJ-1-HHOCH3CH(CH3)!　　　　　　　　　　　　　　　　0CHs 0CRsJ-1-HH0CHs CH(CHm)* CHs 0CRsJ-1-HH0CR1C1(CHs)* CHI Cu11 table 1 (union) J-1-HH0CHs CM (CHi)z CI 0C HIJ(-HH0C2Hs CHs 0CHs 0CR sJ-1-HHoc, o, CHl can 0CHs J-1-HHoc, u, CHI can cusJ- 1-HHQC, H, CB, CI OCR.

J-1-HH0CJi CJs 0CHs 0CHsJ -1-HHQC, Hl c, u, CHI OCR.

J(-HH0CJs CJs CHs CHsJ(-H B 0CJs CJs 0CRsJ- 1-HH0C2H, n-C3Hy 0CH8OCH.

J-1-HH0CIH@ n-C5Ht CHl OCH @J(-HH0CHs n-C5Hy CHs CHs J(-II H0CRs n-C5Ht CI 0CRsJ-1-HHocans CH(CHi)z 0CRs 　　OCR.

J-1-HHQClHI C1 (CHs) * CHs 0C RsJ-1-HHQClHI CH (CHs) * Cl, CHIJ-1-HII QClHI C11 (CHI)!　　　 CI　　　　　　0CHIJ　-1-HH5CHs　　　CHs　　　　 0CRs 0CHsJ(-HII SCBs CHa 　　　　CHs　　　　0CRsJ(-HH5CHs　　　CHs　 CHs CHsJ (-HH5CHs Cl1s CI OCHmJ-1-II Hsc, as CHI α1s CI.

! -L] Wow J-1-HH5CJs CHs CHs 0CHsJ -1-HH5cans CHI cas CHIJ- 1-HHSC! II CHs CI 0CHsJ ( -HHSCN CHs 0CHs 0CHsJ (-H HBr CHs 0CRs 0CRsJ-1-HH Ns　　　　CHs　　　　　　　　　　　　　　　　0CHsJ(-HIf NHCHs CHs 0CHs 0CRsJ -1-B HNHC! Hs CHs 0CHs 0 CRsJ-1-HHN (CHI) CIHsCH, 0CRs 0CHIJ (-E HN(CJs)s CHs 0CHs 0C RsJ-1-HHN (OCRs) CHsCHs 0CRs 0CRsJ-1-HHN (OCRs) CHsCHs CHs 0CRsJ-1-HHN(OCH8)CHlCH,CBs CHIJ (-HHN(OCRs)CHsCHi CI 0CRsJ -1-HHNCCHris CHs 0CRs 0CRs J-1-HHN(CBs)i CHs 0CHa oC RsJ-7-HHHC11s CHa 0CRs (n=0) J-7-HHHCHs CHs (n=0) ! −L]Ω J E RR’/R” Tl□ Alk X YJ-7-HH, HCJs 　　　　　　　　　　0CHa (n=0) J-7-HHHn-C5Ht 0CHs 0CHs (n□0) J-7-HHCHI CHs 0CHs 0CHs (n □0) J-7-HHCJa CHs 0CHs 0CHs (n =0) J-7-HHn-C3H7CHs 0CHs 0CHs (n□ 0) J-7-HH Schiff e7 CHI 0CRs 0CH3 ( n=o) Propyl J-7-HH Schiffel CH, cox 0CH3 (n=0) P. Pi,.

J-7-HH Schiff OCHs CI 0CHs (nl=o) Propyl Table 1 (Unit) J4 - HHN (CHI)!　　　CHI　　　　　　　　CR1oCHs (n□0) J-7-HHN (CHri 2 CHs 0CEs (n・o) Table 1 (Unified) J-7-HHC1cHg 0CRs 0CR1 (n□1) J-7-HHHCH30CHI QC)Is(n-1) J-2-HHCI CHs OCH30CRsJ-2-HH CI CHs CHI 0CHsJ-2-HHCI CH3CHI CHsJ-2-HB CI CHs CI CI 0CHsJ-2-HB CN CHa 0CRs 0CRsJ-2-HHCN CHI CHs 0CHsJ-2-HHCN CH s CHs CHsJ-2-HHCN cH, CI 0CHsJ-2-HH0CHs 0CHsJ-2-HH0CHs CHs CHs 0CHsJ-2-HH0CHs CHs CHs CHsJ-2-HH0CRs CHs CI 0C HsJ-2-HHN (CHs) * CHs 0CRs 0C HsJ-2-HHN(CHs)z CHs CHs 0CR sJ-2-HHN(CH3)! CH3CHs CHsJ-2-HH N(CJ) x CHs CI 0CHsJ-3-HHCI CH30CH30CHIJ-3-HHCI CHs C Hs 0CRsJ-3-HHCI CHI caw 　　　　CHI sac-'' (Hi J-3-HHCI CHs CI 0CHsJ- 3-HHCN CHs 0CRs 0CRsJ-3 -)I HCN CHs CHs 0CHsJ -3-HHCN CHs CHs CHsJ-3- HHCN　　　　CH, C1ocusJ-3-HH0CHI　　　CHI 　　　　　　　　　　　　　　0CHsJ-3-HH0CHs　　　　CHs CHs 0CHsJ-3-HHOCH3CB, C H, CHIJ-3-HHOCHm CHx CI 0CHsJ-3-HHN(CHs) x CHs 0CHs 0CHsJ-3-HHN(CHs)t CHs CHs 0CRsJ-3-)I HN(CHs)* CHs CHs CHsJ-3-HHN(CHs)x CHx CI 0CHxJ-4-HHCI CHs 0CH s 0CHsJ-4-HHCN CH, 0CR30CR3J- 4-HHocHs CHI 0CH8OCR.

J-4-HHN (CHs) * CHs 0CRs 0CH sJ-s -HHCI CHs 0CRs 0CH sJ-5-HHCI CHs CHs 0CHaJ -5-HHCI CHm CHs CHsJ-5- HHCI CHs CI 0CHIJ-5-HHC N CHs 0CB3 ocas table 1 (un) Top E RR”/R” T’/T-in-law Alk X YJ-5-H HCN CHS CHS 0CRSJ -S - HHCN CHs CHs CHsJ-5-HHC N CH, CI OCR.

J-5-B H0CRs CHs 0CRs 0 CRsJ-5-HHN(CHs)s CHs 0CIis 0CHa Table 1 (Unified) J(2-HHHCHs 0CHs 0CRs(R,-Cls ) J-13-HHHcH, ocus ocus (R1g CHs) J-12-HCHI　　　HCHs　　　　　　0CH80CH8(Rx<z Hs) J-11-HHHCHs　　　　　0CRs　　　　ocus(Rs<H( CHs)z J-10-HH Cyclo CHI ocas OCH.

(Rs-In-CsHy) Prohil J-11-HHC HI Fx) J-12-HHHcu, 0CRs ocus(R3CH zCH<Hz) J-1-HHCI CHs Nib 0CHaJ- 1-HHCI　　　　CHs　　　n-CJt　　　　0CHsJ(- HHCI CHs NHCHs 0CHsJ-1-H HCN CHI ocns sco.

J-1-HHCI CHs 0CRs 5CFJJ -1-HHCI CHs 0CRs OCH*Ct CH! -Lμri Upper master i□bi Alk　X　Y J-1-HHCI CHs 0CHa 0CH sCII<HaJ-1-HHCI　　　　CHa　　　　　OCR,C Tomo CHJ-1-HII CI CJs 0CR s N (CBs) *J-1-B II CI CHs 0CRs NH! J(-HII C I CHs 0CRs CFsJ-1-H1 1CI　　　　　CHs　　　　　　0CHs　　　　　　　0CHxCHt OC) IsJ-1-HHCI CHs 0CRs 　CHsSCHsJ(-HHCI　　　　CHs　　　　　　0CHB Cl0J(-HHCN) CHI 0CR1ω Cl.

J-1-HHCI CHs 0CRs CH( SCHs) OCsHsJ-1-II B CR s　　　　　　　0CRs　　　　C(CHxXSCHs)xJ(-HHCI Color CHS 0chs C (SCJS) Color -L Rainbow J E RR’/R” T’/T” Alk X YJ (-II HCI CHs 0CHs N (OCToXCBs)J(-IIHCNCHsOCHsCfukiCCH.

J-1-HHCI CHs 0CRs C5 BsJ-1-HHCI CHs 0CRs 0ChBrJ-7-H6-F HCHs 0CRs 0CRs (n□0) J-1-115-F CI C11s 0CR s 0CRsJ(-H6-CI CI CHs 0CRs 0CRsJ-2-H4-CI CI CHs 0CRs 0CHsJ-7-H6-Br II CBs 0CHs 0CHs (H of a J-1-H5-Br CI CHs 0CRs 0CHsJ-3-II 4-Ctls CI CR s　　　　　　　　　　　　　　　　　　　CC’FIsJ(2-H3-CIls) HC11s 0CRs 0CHs (Rs-CL) J-1-B 5-CHsCN CI CHs 0 CHs 0CRsJ-1-H5-α', is CI C Hs　　　　　　0CHs　　　　α】.

J-1-H5-5cHs CL C1’s 0CR s　　　　OCRs! -L11 J　E　RR’/R”　T’/T”　Alk　X　YJ(2-H3-CHs 　　　　HCHsCHs　　　　　CHs (Rs ~ cps) J-1-H5-OCFJ CI CHs 0CRs 0CHsJ(-CHs HCI 0 CHs　　　　　0CHsJ(-CHsHCI　　　　CHs　　　　 　CHs　　　　　0CHsJ(-CHsHCN　　　　CHm　 0CRs C1゜J(-CHs HCN Hs　　　　　　　CHI　　　　　　0CH3J-2-CHI　HCI　 CH3QC)Is 0CHsJ-3-CHs HCI 　　　CHs　　　　　　　　　　　　　　　　　0CI(sJ-1-H6- CI CN CN CHI 0CR80CH8J-1- H6-CI CN CN cH, CHm OCI’1sJ -1-H6-CI CN CN CHI CHI CHIJ (-H6-CI CN CN CHs CI　　　　　　0CRsJ-7-HHCF3　　　　　　CH,CH,can( nlIO)′″ Table 1 (min) Table 1 (Unified) J E RR’/R” T’/T” Alk X YJ-7-HHCFI CIhCHs CHs 0CHs (n・0) J-7-HHCFs CH2CH2CHI CH3 (n・o) J-7-HHCFs　　　n-C5H7CHs　　　c)! .

(n・0) J-7-HHCFs CH(CHs)z 0CHs 0 CHs (n=0) J-7-HI'l CF, CH (CHI: h C) I S 0CRs (n=0) J-7-HHCFa C) I(CH3)z CHs C Hs(n-IO) -to 1 \Chiakeno J E RR’/R” T’/T” Alk X YJ-7-HHCFs CHsCN 0CHs 0CHsf+-^A J　E　RR’/R”　T’/T2　Alk　X　Y!TwoL”υ J E E RR’/R” TI/T! Alk X YJ-7-HII CHs CHHi 　　　CTl5　　　　0CHs(nll's J-7-HHCHs CxHs CHI C Bs(nIIO) J-7-HII CHs CaHs CI 　　　　　　0CRs(n・o) J-7-HHCBi n-C5Ht α:II, O CI! .

(n・0) (n□0) J-7-HHCHs n-C5Bt ct 0C Rs(n-O) J-7-HB CHs CH(CHs)z 0CRs 　　　　0CHs(nlIO) J-7-HB　　　　CHs　　　　CH(CHs)s　　　CHs oCHs (n deception 0) (nI=o) J-1-HHF CM, QC) 1.　　　　　0C R1J-1-HHF C) Is CHI 0CII.

J-1-HHF C) 13 CH3CH.

J-1-III F CHs CI 　　　　0CII Table 1 (绖) J-1-HHCN CHtCN 0CHs 0CH sJ-1-HHCN CHaOCHs 0CHs 0 CHsJ-7-HHCHs CHiCH*CN 0CHa 0CRs (n±0) J-7-HHCHs CBsCHxOCHs 0CHs 0CRs (n・0) J-7-HHCHI CHa (CH ICN 0CH80CH3(n ・0) (n・o) J-7-CHs HCHs CHs 0CHs OCHs (Hg J-7-CHs HCHs CHs 0 CHs(n-O) J-7-CH, HCH, CH, CHs CHs (n□o) (n□o) J-7-B HCHzCN CHs CHs C HI(n-no Table 2 Top E RR1/R" T'/T" Alk X YJ-1 -HB C1cps CHa 0CHaJ (-II HCI CHs 0CRs 0CRsJ-1-HB CI CHs 0CxHs NHCHsJ-1-II HCI CHi 0CRs N(OCBsXCHs) J-1-II HCI C) Is 0CRs N(CHs)sJ(-HHCI CaHs CHs 0CHs J(-HB CI CHL 0CRs 0CRsJ-1-II HC1c, a, oc, a, NHCBsJ-1-HII CI CJs 0CRs N(OCHsXCHs)J(-HHCICH Ha 0CHs N(CHs) *J-1-HHC1n-C5Ht CT o 0CHxJ-1-HHC1n-C5Hy 0CRs 0CRsJ- 1-II H, C1n-CJy 0CsBs NHCHsJ(-HB C1n(:5lly 0CRs N(OCBsXCHs)J-1-HHC1 n-C5Ht　0CHs　N(CHs)*J-1-HHCI　　CH(C 1la)s CBs 0CRsJ(-HHCI CH(CHs)* 0CHs OCT.

J(-B HCI C11 (CHs) * QC! 88 NHCII Hatake J (-HHCI CB(CHs)s 0C Rs N(OCHsXCili) J(-1111CI CI(CHs) Proverbs 0CRs N(CHs) *J-I CHm 11 II CI CH s 0CHs CHa! -L”YuuΣ ”2 ER and Shikupieshiro 2 Δ几 CI　　　　CHs　　　　　　　　　　　　　　　　　　　　　J-1-CHs　 HCI CHs 0CHs 0CRsJ-1-H HCN CBs CHs C1゜J(-HHCN 　　　　CHs　　　　　　　　　　　　　　　　　0CRsJ(-HB) CN　　　　CHm　　　　　QC! HI NBCHIJ-1-B 11 CN CN CHI 0CH1N (OCHsX CIIm) J(-HPi CN CN CHx 0CRs N(CHs)sJ(-II HCN CHII CHs C1゜J-1-HHCN CJs 0C Rs　　　　0CRsJ(-HHCN　　　　Ca1ls　　　OC *Hs NIICHsJ-1-B HON C5Hi 0CRs N (OCBsXCHs) J-1-HHCN CJs　　　　　0CHs　　　NCCHs’)zJ(-HHCN　　　 n-C5Hy CHs 0CRsJ (-II HC N n-C5Ht 0CHs 0CRsJ (-II HCM n-C5Ht 0CJs NHCHs J(-HHCM　　　　n-C5Ht　　　0CRs　　　　N(OCI IsXCHs) J-1-11BCN n-CIIIv α:H s　　　　N(C1s)sJ-1-II PI CN 　　　C H (CHs) * C1 (s αI.

J(-HII CM CB(CHm)* 0CRs 0CRsJ-1-HII CN C1(CHs)s 0CJs) JHCHsJ-1-HII CN I J(CHs)g oco, N(OCH3XCBs)J(-HHCN CH(CHs)s OCHs N(CHs) x Table 2 ( ) J E RR’/R” T’/T” Alk X YJ (CHI HHCN CHI 0CRs CHs J-1-CHs HCN CHs OCI’13 0CH3J-1-CH3) I CN CM, OC I'l, CI(lJ-1-HHN(CHI)! CH, CB, 0CR3J-1-HHN (CHs) * cH, 0CHs ocasJ-1-HHN(CHs) x CH, QC, H, NHC)l.

J-1-H) I N (CH,), CH, 0C11a N (QC)ISXCH3)J(-HHN(CH3)! C)In 0CRs　　　　N(CHx)sJ-1-HHN(CHs)z　　C2H@ CH30CHsJ(-HHN(CH3)! CJs 0CRs 0CRsJ(-HHN(CHs)* CJs OCJ* NHCHsJ(-B HN(CHs)* CIHI 　　　　　0CHs　　　N(OCHsXCHn)J-1-HHN(CHs ) x c, H, ocH, N (CHs) iJ-1-HHN (CHs) * n-C5Hy CHs 0CHsJ-1-HHN(CHs)* n-C5Hy 0CHs 0CRsJ-1-HHN (C Hs) * n-C5Hy QC, HI NHC) IsJ-1 -) I HN (CHI)! n-C3H? QC)1.　　　 N(OCHsXCHs)J-1-)I HN(CHs)z n-C ,H,OCH,N(CHs)zJ-1-HHN(CBs)*C)I(C) Is)* CI(s 0CHsJ-1-HHN(CHs)* CH(CHs)x 0CT3s 0CH3J-1-HHN(CH 3)! CH(C1(3)! 0CJs NHCHxJ-1- HHN(CHI)!　　　CH(CHs) x 0CHsN(OCHsXC Hs) Table 2 (Tong) J E RR’/R” T’/T” Alk X YJ-1-HHN (CH ,), CH(CHs), OCH,N(CFI,).

J(CHI H) I N(CHI)! CHa 0C Hs　　　CBsJ-1-CH2ON(CHri!　cH,0CH80C HsJ-1-CHs HN (CHs) * CHs 0CHs CHsJ-1-)I HQC)lI C)1.　　　　　 cas 0CHsJ-1-HH0CHI CHs 0CHI 0CHsJ-1-HHOCH3CH,OC,H,NHC)I .

J-1-H)l OCH,CH,0CRs N(OCHmXC Hs) J-1-HH0CHI cL QC) 1.　　　　 N(CH,)IJ-1-H)I 0CHs CI)1.　　　 CH, QC) ISJ-1-HI OCH, C, H, OCH, 0CR sJ-1-HHOCR, C, HI QC, H, NHCH.

J-1-HH0CHs CJs 0CHs N(O CHsXCHm)J-] -HH0CHs CJs 0C Hs　　　　NCHsJ-1-HH0CHs　　　n-C3H7CHs 0CHsJ-1-HHOCR, n-C, Hy OCR, OCH.

J-1-HH0CHs n-CJt 0CsH* NHC H3J-1-HHoca, n-C3H7ocH,N(OCHxXCHs )J-1-HH0CHI n-C5Hy 0CHs N (CHs)gJ-1-HHocHs CH(CH,), CH3Q C) ISJ(-HH0CRs C)l(CHs:h 0CHs 0CHsJ-1-HH0CHs CH(CHI)2 0CJi NHCHs! 2 (#!Σ Engineering E RR’/R” T’/T” Required x y J-1-11H0CRs CH(CHs) x 0CHs N( OCHsXCHs) J-1-HH0CRs CD(CHs)* 0C Hs　　　　N(CHs)zJ-1CHx　HH0CRs　　CHs 0CFis CamJ-1-CBsHOCH,CHs OCR, OCH.

J-1-CHsH0CRs cHs ocas CHI J(-HH0CJs CHs 0CHs CHsJ(-H H0CJs CHs OC’FIs 0CRsJ (-HH 0CJs CJs 0CHs 0C1bJ-1-HHOC! Hs CJs 0CRs CHmJ-1-HHBr CHs OCR.

J-1-il HSCN CHs CHa 0CI (sJ-1-HH5cas cHt ocas C) I mJ(-HH5CHI C) Is 0CRs OCTl mJ(-B H5cans CHs 0CHs CHs J(-HHNHCHs CHs QC) Is CHsJ- 1-HHNHC! B1 CHI 0CHs CHsJ-1 -HII N(CHs) CJsCHs 0CRs C HsJ(-HHN(CJs)* CTi5 0CRs CHs J(-if HN(OCHsXCBi)CL 0CHs CH sJ-1-II HN (OCHsXCHm) CHs 0CHs 0CHsJ-1-HHN(CBs)s CHx CBs 0CRsJ(-HHN(CHri4 CHI CHs 0C Hs table 2 (union) J E RR’/R”Q Alk X YJ-1-HHNI CH s 0CHs CHsJ-2-HHCI CM, OCR, CHIJ-2-HHCI CHs 0C Hs 0CHsJ-2-HHCN CHs 0CH s 0CHsJ-2-HHCN Cl, ocaa CH.

J-2-HH0CHs CHs 0CHs CBsJ- 2-HH0CHs CHs 0CHs 0CRsJ-2 -HHN(CBs)a CHa 0CRs CHsJ- 2-HHN(C1)Is) * CHs 0CRs 0C RsJ4 - HHCI CHs 0CHs CL table 2 (string) ” 2 ER and 2 ΔR X YJ-3-II 　　　! 1 CI CHs 0CRs 0 CRsJ-3-HHCN CHs Ocaa OCH mJ-3-HHCN CHs 0CRs CHsJ -3-HH0CHs CHs 0CRs CHsJ- 3-B H0CHs CHs 0CHs 0CH aJ-3-RB N (CHs) * CHs 0CHs 　　　　CHsJ-3-HHN(CHs)*　　CHs　　　　　　0CHs 0CRsJ-4-)] HHCI CHs 0CRs CHsJ-4-HHCI CHs 0C Rs　　　　0CRsJ(-HHCN　　　　CHs　　　　　0CRs 0CRsJ-4-HHCN CHs CHIJ-4-HH0CHs CHs 0CRs CHsJ-4-11H0CHs CHs 0CRs 0CRsJ-4-HHN(CHx)x CHs 0CHs CHxJ-4-B HN(CHs)x C) Is 0CHs 0CHsJ-5-B HCI CHs 0CHs CHsJ-5-1 (HCI CHs OCRs 0CHsJ-5-HHCN C) Is 0CRs 0CRsJ-5-HHCN CHs 0 CRs　　　CBsJ-5-HH0CHI　　　CH,QC)II　　 CH.

J-5-HH0CI(s CHs 0CHs 0CRs J-5-HHN(CHs) x CHs 0CRs CB s-sac-λ-cargo and Upper ER□□赳　x　y (n111) J-7C) It H13HCHs 0CRs CHs(n =1) J-7-HHCN CHs 0CRs CHs(n =0) 1-7 - HHCN CHs 0CRs 　0CRs(n・o) Table 2 (Unified) J-12-H3-CHs HCHs CHs 0CRs (R3 San CJi) J(-II 5-F CI CHs CHs 0CEsJ-1-E 6-CI CI CHs ocas CHsJ-2-H4-CI CI CH, OCR , OCR.

J-1-H5-Br CI CH, CM, OCR.

J-3-II 4-CHs CI CHs CHs 0CFIsJ-1-H5-CBICN CI CHs 0CHs 0CHsJ-1-H5-OCR3CI CHI 　　　　　　CHI　　　　0CIIIJ-1-H5-5CHs　　CI C11s CHs 0CI5! -L”! Σ J E RR’/R” T’/T” Alk X YJ-1-H5-OCF sHCI C1l, CHs OCHmJ- 1-II 6-CI CN CN CHs 　　　　　0CRsJ(-H6-CI　　　CN　　　　CHs 0CHs 0CHsJ-1-H6-CI CN CBs 0CJs NHCll5J-1-HHCI 　　　　Cl45　　　　　0CHsCI1. FCBsJ-1-HHC1, CHs　　　　　　0CToCHxF　　　0CRsJ(-B　　HCI　 CH30CH1CF3 actsJ-1-B HCI 　　　CHi　　　　　　　　CHsCFs　　　　0CRsJ(-HHCI 　　　　CHs　　　　　　0CIl＊CHsCI　CHsJ-1-HH CI　　　　　CHs　　　　　CH*C10CHsJ(-HHCN 　　　CHs　　　　CBJr　　　　　0CRsJ-1-1(HCI CH8ocas BJ-1-HHC1at, α:H, SCI! .

J(-HHCI CHs 0CIltCHFt C HsJ(-HHCI CHs 0CRs C1 CHJ-1-HHCI CHsOCR, C, H.

J-1-HHCI C11s α5ill CH*0CBsJ-1-HB CI CBs 0CRs CBs(OCRs)sJ(-II HCI CB, OCH3 cyclopropyl J-1-HHCN CHs CJs 0CHsJ-1-HHCI CHs CBsF 0CHsJ-1-II HCI CHs 　　　　　CFa　　　　C1゜Table 2 (1ri J-1-HHCI CHs oc, F, CH @J-1-HHCN CHs CHs 0C JsJ(-HHCN CHs 0CHs CF sJ-1-HB CI CI CHs C) Is 　　　　　0CHxC’-CHJ(-HHCI　　　　　CHs　　　　 QC) Is C=CCHsJ(-HHCI CHs 　　　　　　　　　　　　CHxOCHsCHsJ(-HHCI　　　 CHs 0CHzCHzOC) Is table 2 (continued) J(-HHF CHs 0CFIs OCHs table 4 -1-"2"L 'R'T'/T'A HHC1ca, CHIJ-1-B HCI CHs 0CHsJ-1 -HHCI　CHi　　0CJsJ(-HHCI　CHi　0CFJJ- 1-HHCN CHm CHsJ (-B HCN CHs 0CHs J(-HB 0CRs CHs CHsJ-2HHCI CHs CH s J-3-HHCI CHs 0CRsJ (-H5-OCHs CI CH s CHsJ-1-H6-CI CN CHs CHsJ (CHt HH CN CHx CHsJ-1-CHs HC1cH, CH3 I-1-HHF CHs CHi Mugi-mutual” Σ -1-E　RR’/Jijiji Jjiyana　　　　　　Table 6 J E E RR’/R” T’/T” Alk X, YJ-1-HB CI CHI CHI 0CH3J-1-HHCI CL can OCR) IIJ (E HCI CHs CHs 5CHxJ(-HHCI CHs CHs SC!H8J(-HHCI CHs CHs CHsJ-1-HM CI CB, cHn C, H.

J-1-HB CI CHs CJs 0CHsJ-1-HHCI C H, CH, CF, OCR.

J-1-11HCN CHI cH, ocH.

J-I HH0CHs CHs C) Is 0CHiJ-1CHs H CI CHs CHs 0CHsJ-I CH, HHCN CH, CH ,OCH.

J-2-HHCI CH, CH, OCH.

J-3-HHCI CHs C) Is 0C1bJ (H5-OCHs C I CHs CHs 0CHsJ-1-H6-CI CM C)1.　 CB, QC) 13 Table 6 (绖) Ichikami 1" 2" L bi L work Alk XL! -”.

Ichikami-E RR’/R” T’/T” Alk X4 Y 4 ZIJ-1-Ill HCN CHs CHs CHs CHJ-1-HHCI CH3CO 3NJ-1-HHCI CH30CH3CHI CBJ-1-HH CN CHs 0CRs CHs NJ-1-HHC I CY4s 0CHx 0CRs CIJ-1-HB 　　　　　CI　　　CB,　　　OCR,0CHI　　　NJ-1-HH CI CHs CHJ-1-H HCI C)! 3 α: 1 (, CI CIJ-1-HH CI CHI oczas CH3CHJ-1-HHCI CHs CHzOCHs CHs NJ (-HHCI CBz CLOCHs 0CHs CIJ-1-HHCI 　　　　CBs　　　　0CJi　　　QC! MI NJ-I C BJ HHCN CHs 0CHs CHs CI J(-CHs　　HCI　　CHs　　　0CRs　　　CHs CMJ-2-HHCI CHs 0CRs CHs CHJ-3-HB, CI CHs 0CHs CHs CBJ-4-B HCI CE, QC) 1 3 CB8 CEJ-5-B HHCHs 0CHs C11s CMJ-7-HE HCHI OCH 3CHI CH (n ■ 0) J-22-HHHCH, ocas CHa C1 (Rs<Hz) ! Once AdanΣ J E RR’/R” Ding I/Ding” A lk X, Y, ZIJ-12-H3-CHs II CHs 0CRs CHs C1 (Rs <Hs) J-1-II 5-OCHsCl, CHs 0CRs CHs　CIJ(-H6-CI　CN　　CHa　　0CRs　 ells CIJ(-HHF ells 0CHs CHs C11J-7-HHF CHs 0CRs CBs C1 (n□0) J-7-H11CHs CHs 0CRs CBs CH( n=0) J-7-HHCBJ CH2CN 0CHi CHs C E(n・no J-7-HHCFs CHs 0CRs CHs C H (n=o) Table 9 J E E RR”/R” Ding”/T” Alk W X4 Y4 21J(-HHCI CHs S 0CI(s 0CRs CMJ (HHCI CHs S CHs 0CRs NJ-1-HHCI CH3S OCH,0CH3NJ-1-HHCN CH,S OCH,0C HICHJ(CHx HCI CHs S 0CHI 0CHa CHJ(C H2HHCN CHs S 0CRs 0CRs CIJ-2-HHCI CH, S 0CRsOCHICHJ-3-RII CI C113S oc nsocuscaJ-4HHCI CHI S 0CH80CRs CtlJ (-H5-OCRs CI CHs S 0CRs 0CHs CHJ-1- H6-CI CN CH, S OCR, OCH, CIJ-7HHCHs C Hs S 0CHs 0CRs CH (n=0) ! Qianqiang Useful preparations of compounds of formula I may be prepared in conventional manner; they may be prepared as powders, granules, etc. Many of these, including tablets, suspensions, emulsions, aqueous concentrates, concentrated emulsions, etc. Can be applied directly. Spray preparations can be bulked up in a suitable medium, ranging from a few liters to a few hundred It is used with a spray capacity of liter/ha. Highly concentrated compositions are primarily suitable for further preparation. used as an intermediate for When manufactured, the preparation has an active ingredient content of 0.1 to 99% by weight. and a) surfactant from about 0°1 to 20% and b) solid or liquid diluent from about 1 to 20%. Contains 99.9% of at least one species. More specifically, the preparation should contain these ingredients to a greater or lesser extent. It will contain in the proportions shown below: Weight% books Active ingredient　Selected beads　　Surfactant Wettable powder 20-90 0-74 1-10 aqueous suspension 10-50 40-84 1-20 powder 1-25 70-99 0-5 granules and tablets 0.1 -95 5-99.9 0-15 active ingredients and less surfactant or diluent At least one type - 100% by weight Of course, lower or higher amounts of the active ingredients than shown in the table may be used depending on the intended use and physical properties of the compound. A high proportion of surface-active to active ingredients that may be present is sometimes undesirable and This can be achieved by mixing or by mixing in a tank.

A typical solid diluent is described in "Handbo" by Watkins et al. okof　In5ecticide　Dust　Diluents　a nd Carriers”q 2nd edition, Dorland Books. Books%Caldwell1%N, J,), but other solids ie natural and synthetic solids may also be used. Wettable powders and concentrated powders are more adsorbent. A diluent is preferred. Representative liquid diluents and solvents include Marsde n), “5olvents guide”, 2nd edition, Interscience Inc. (Intersience, N, Y,), 1950.

Solubility below 0.1% is suitable for concentrated suspensions: concentrated solutions are preferably stable against phase separation. “McCutcheon’s Deterge nts and Emulsifiers Annual'', Alarela Allured Publ, Corp, N, J, Encyclop, by S. Isely and Wood. edia or 5surface ActiveAgents'', Chemica Chemical Publ, Co, Inc, N, Y, ), 1964 displays surface activity and its recommended uses. all preparations contains small amounts of additives to reduce foaming, caking, corrosion, and microbial growth. May be contained.

Methods for producing such compositions are well known. For liquid formulations, simply mix the components Manufactured by. Finely divided solid compositions can be produced using a hammer mill or fluid energy mill. It is produced by mixing using a mill and usually grinding. Suspending agent is a wet type produced by milling [see, e.g. Littler, U.S. Patent No. 3.060,084]. Granules and tablets are preformed granules containing the active substance. It can be produced by spraying onto a carrier or by agglomeration methods. References, J.E., Bro. Brovning, “Agglomeration”, Ch. EngineeringSl February 4th issue, page 147 (196 7), and Perry, Chemical Engineer 'sHandbook, 5th edition, pp. 8-57, McGr. aw-Hill, N. Y.), 1963.

For further literature on preparation techniques, see e.g. Loux, U.S. Pat. No. 3,235,361, column 6, line 16 to column 7, 1. Line 9 and Examples 10 to 41° R, W, Luckenbaugh ), U.S. Patent No. 3,309,192, column 5, line 43 to column 7, line 62 and implementation. Example 8.12.15.39.41.52.53.58.132.138-140. 162~164.166.167.169~182° H, Gysin and E, Knusl+, US Patent No. 2, No. 891.855, column 3, line 66 to column 5, line 17 and Examples 1 to 4° C, C, Clear Weed Contral as a by Klingman Science” John Wiley & Sons, Inc. Wiley and 5ons, Inc., N, Y,), 1961 , pp. 81-96.

Written by J. D. Fryer and S. A. Evans, 'Weed Control Hnadbook', 5th edition, blackware Le Scientific Publications (Blackwell 5c ientific Publications 0xford), 1968 , pp. 101-103.

In the following examples, all parts are by weight unless otherwise indicated.

2-[[[(4-chloro-6-medoxy-2-pyrimidinyl)amine 1cal [bonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoylchlor Ride 99% trimethyl nonyl polyethylene glycol ether Spray 1% surfactant onto the active ingredient in the mixer and then The mixture was passed through a No. 40 US standard sieve (0.42 mm opening) before packaging. this Concentrates could be further formulated for practical use.

2-[(cyano)(methoxy)methyl]-N-[[(4-methoxy-6-methoxy) 2-pyrimidinyl) aminococarbonyl Dodecylphenol polyethylene glycol ether 2% lignins Sodium silicoaluminate 4% Sodium silicoaluminate Thorium 6% montmorillonite (calcined) 23% Each component was mixed thoroughly. A liquid surfactant is sprayed onto the solid ingredients in a mixer. Add by misting. Essentially everything is 10 when ground in a hammer mill. After reducing the particles to sub-zero micron size, the material is remixed and passed through a No. 50 US standard sieve (open aperture). 0.3 mm) and packaged.

Kansanyu 11 aqueous suspension N-Methoxy-2　-　[[[　(4-methoxy-6dmethyl-1,3.5- ) riazin-2-yl)amino]carbonyl]amino]sulfonylbenzenecar Boximidoyl chloride 40% polyacrylic acid thickener 0.3% dodecylphenol polyethylene glycol ether 0.5% Disodium Phosphate 1% monosodium phosphate 0.5 % polyvinyl alcohol 1.0% water 56.7% Each component is mixed and ground together in a side mill to reduce essentially all particles to size. The diameter was set to 5 microns or less.

Taishin Toyoto oily suspension 2-[[[[(4-chloro-6-medoxy-2-pyrimidinyl)amine 1 carbonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoyl Chloride 25% polyalcohol carboxylic acid ester and Mixture of oil-soluble petroleum sulfonates and oil-soluble petroleum sulfonates 5% xylene Len 70% of each ingredient together and ground in a sand mill to reduce essentially all particles to less than 5 microns. . The product can be used directly, extended with oil or emulsified in water. came.

! Rikkou mutual oily suspension 2-[(cyano)(methoxyimino)methyl]-N-[[(4-methoxy- 6-Methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide 25% polyoxyethylene sorbitol hexaoleate 5% higher aliphatic hydrocarbon oil 70 % Each ingredient is ground together in a sand mill until the solid particles are approximately 5 microns or less. did. The resulting viscous suspension can be applied directly, but is preferably extended with oil or water. It was used after being emulsified in the liquid.

Sad Trap Basjou Honmasa next day! Violet! N-methoxy-2-[[[[(4-methoxy-6-methyl-1,3,5-)ria din-2-yl)amino]carbonyl]amino]sulfonylbenzenecarboxy Midoyl chloride 25% hydrated attapal guide 3% crude calcium lignin sulfonate 20% sodium dihydrogen phosphate 0.5% Water 61 ．． 5% Each ingredient is ground together in a pole or roller mill to give 10% solid particles. reduced to a diameter of less than a micron.

2- [[[[(4-chloro-6-medoxy-2-pyrimidinyl)amino]car [bonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoyl Lolide 40% Dioctyl Sodium Sulfosuccinate 1.5% Sodium Lignosulfonate 3% low viscosity methylcellulose 1.5% Attapal Guide 54 % Mix each component thoroughly and pass through an air mill to reduce the average particle size to 15 microns or less. Mix it again, pass it through a US standard sieve No. 50 (0.3 m opening), and wrap it. equipped.

All compounds of the invention could be formulated in the same way.

x rin! Above Toyotama Wettable powder of Example 16 15% gypsum 69% potassium sulfate 16% Mix each component with a rotary mixer and granulation was achieved by spraying with water. Most of the substances are 1.0 to 0.42 cm ( When the desired range of US standard sieve No. 18-40 is reached, take out the granules and dry them. Dry and sieve.

The material on the sieve was ground to give the desired range of additional material. These granules are active Contains 6% of ingredients.

"Iris" Volume 1 Irrigation powder 2-[(cyano)(methoxyimino)methyl]-N-[[(4-methoxy- 6-Methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide 50% alkylnaphthalene sulfone Low viscosity methylcellulose 2% diatomaceous earth 46% Mix each ingredient and roughly Hammer milled and then air milled to essentially all 10 mic diameter The particles were set to be less than 100 yen. The product was remixed and packaged.

Contrarian! Retired Emperor Buried Danmeshi! N-methoxy-2-[[[(4-methoxy-6-methyl-1,3.5-tria din-2-yl)amine]carbonyl]amino]sulfonylbenzenecarboxy Midoyl chloride 25% anhydrous VL sodium 　　　　　　1O% Crude Calcium Lignosulfonate　　　　　　　　　 5% sodium alkylnaphthalene sulfonate 1 % Calcium/Magnesium Bentonite 59% each ingredient were mixed, hammer milled, and then moistened with approximately 12% water. this mixture It was extruded into a cylindrical shape with a diameter of about 1 to 3 mm, and cut into pellets with a length of 3+ am. . It can be used directly after drying or by grinding the dried pellets into US standard flour. Rui No. 20 (aperture 0.8411II11) was passed through. American standard sieve No. 40 (opening 0.42 sam) The granules remaining on top were packaged for use while the sieved It circulated.

Satohara! Again and again Irrigation powder 2-[[[[(4-chloro-6-medoxy-2-pyrimidinyl)aminoco carbonyl1amino]sulfonyl]-N-methoxybenzenecarboximidoyl Chloride 80% 0% Sodium alkylnaphthalene sulfonate Thorium 2% Sodium Ligninasulfonate 2% synthetic amorphous silica 3% Kaolinite 13 % Each component is thoroughly mixed and passed through a mill such as an air mill or a hammer mill. , an average particle size of 25 microns or less, mix again and pass through a No. 50 US standard sieve (open area). 0, 3 + w) and then packaged.

It smells like a trap! Again 1 ! Emperor Phoenix! strength 2-[(cyano)(methoxyimino)methyl]-N-r[(4-methoxy-6 -Methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide 98.5% silica airgel 0.5% synthetic amorphous silica 1.0% each ingredient was mixed and ground in a hammer mill to ensure that essentially all of the rice The material passed through the national standard sieve No. 50 (openings 0, 3 m+n). This dark Thicknesses could be further compounded in various ways.

Purpose The test results demonstrate that the compounds of the invention are highly active pre- or post-emergent herbicides or Indicates that it is a length regulator. Many of these require complete eradication of all plants. locations such as near fuel storage tanks, ammunition depots, industrial storage areas, parking lots, and outdoors. Extensive pre-emergence and/or It is useful for weed control after germination.

Some of the compounds are used in crops such as rice, wheat, barley, maize, and sorghum. It is useful for selectively controlling weeds in grass, soybeans, and cotton. This compound is also found in plants. useful for modifying the growth of

The application rate of the compounds of the invention is determined by their use as plant growth regulators or herbicides. crop species involved, types of weeds to be controlled, weather and climate, formulations used, application Generally determined by many factors, including method of use, amount of leaves present, etc. In other words, the compound should be applied in an amount of about 0.00 to 1 Okg/ha. child The lower application rate of or for situations where only short-term persistence is required, e.g. for weeding in fallow areas. proposed.

The compounds of this invention can be used in combination with other commercially available herbicides.

Typical sulfonyl elements, triazine, triazole, uracil, urea, mido, diphenyl ether, carbamate, imidazolinone, cineole and vinyl It is of the Pyridium species. Some examples are shown below: Niacrolein Acrolein AMS Ammonium Sulfamate As Asulam Methyl sul 7 anilyl carbamate barban ( barbam) 4-chloro-2-butynyl m-chlorocarbanilate Butylate S-Nityru diisobutyl thiocarbame Codiphosphoric acid Hydroxydimethylarsine oxide CD A A N,N-diallyl-2-chloroacetamide CMA Lucium Methane Arsonate Cycloate te) S-ethyl N-ethylthiocyclohexane cyclohexane (cycluron) ron) 3-cyclooctyl-1,1-dimethylurea dalapone (dola pon) 2.2-dichloropropionic acid DCPA Methyltetrachloroterephthalate dicamba 3+6 -Dichloro-0-anisic acid diphenzoquat 1,2-dimethyl-3,5 -Diphenyl-1 Topira (difenzoquat) Zoliumudino Dinoseb 2-5ee-butyl-4,6-sinitropheno DNOC2-Methyl-4,6-sinitrophenol DSMA Ditrium methane arsonate 7 fenae (2,3 , 6-trichlorophenyl) feruron 1.1- Dimethyl-3-7s nil urea sato fish raw stew fluridone l-methyl-3-phenyl -5-[3-()lifluoromethyl)-phenyl]-4(IH)-pyridinone Fomesafen (2-chlor-4- trifluoromethylphenoxy)-N-methylsulfonyl-2-nitrobenzua Mido 7 Fosamine Ethyl hydrogen (aminocarbonylate) ) Phosphonate glyphosate) N-(phosphonomethyl) Glycine/%O holoxyfop 2-[4-[ [3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]pheno xy]propion Hexafluorate (hemflurate) Potassium hexafluoral Senate hexazinone 3-cyclohexy -6-(dimethylamino)-1-methyl-1,3,5-)riazine-2,4( IH,3H)-dione Imazametabenz 6-(4-isopropyl-4-methyl-5 -oxo-2-imidacillin-2-yl)-m-toluic acid methyl ester and 6-(4-isopropyl-4-methyl-5-oxo-2-imidacylin-2-y )-p-toluic acid methyl ester V transition ± imazapyr (±)-2-[4,5-dihydro-4-methyl-4-(l-methyl ethyl)-5-oxo-IH-imidazol-2-yl]-3-pyridinecarvone acid Iwazaquin 2-(4,5-dihydro -4-Methyl-4-(1-methylethyl)-5-oxo-1H-imidazole 2 -yl)-3-quinolinecarboxylic acid imazotapyr (±)-2-[4,5- Dihydro-4-methyl-4-(l-methylethyl)-5-oxo-IH-imida Sol-2-yl]-5-ethyl-3-pyridinecarboxylic acid iox'ynil 4-hydroxy-3,5- short benzonitrile Improvalin (isopropalin) 2+ 6-sinitro N, N-dipropylcumidine Improvalin (isoprofuron) N-(4-isopropylfuron) phenyl)-N'.

N'-dimethyl element Isouron (Isouron) ethyl)-3-inxazolyl]-N,N-dimethylurea Fukasoni　　　　　　　　　　　　　　　　　chemical name aben) N-[3-(1-ethyl-1-methylpropyl)-5 -isoxazolyl)-2,6-simethoxybenzamide karbutilate tert-butylcarbami Esters of phosphoric acid with 3-(m-hydroxyphenyl)-1,1-dimethylurea lactofen (carboethoxy) )ethyl-5-(2-chloro-4-()lifluoromethyl)phenoxy)-2- Nitropenzoate lenacil 3-cyclohexyl-6,7 -SihydroIH-cyclopentapyrimidine-2,4(3H,5H)-dione Iinuron (3,4-dichlorf) phenyl)-1-methoxy-1-methylurea MAA methane arsonic acid MAMA Monoammonium methane arsonate MCPA [(4-chloro-o-)lyl)oxy]acetic acid MCPB 4-[(4-chlor-0-tolyl) Oxy]butyric acid mecoprop 2 [(4-chlor-0- Toril) Oxy Su Satomi Mefluidide N [(2,4-dimethyl-5- [[(trifluoromethyl)-sulfonyl-1-amino]phenylcoacetamide Metalpropalin N-(2-methyl- 2-propenyl)-2゜6-dinitro-N-propyl-4-(trifluoromethyl) ) Benzene amide Metabenzthiazuron L 3- Dimethyl-3-(2-benzothiazolyl)urea Metam (+++etham) Sodium methyl dithioka -bamate metazole (methazole) 2 (3,4- dichlorophenyl)-4-methyl-1,2,4-oxadiazolidine-3,5- Zeon Metoxuron (methoxuron) N’-(3-chlor-4 -methoxyphenyl)-N,N-dimethylurea metolachlor 2-chlor-N-(2- Ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetate toamide Metribuzin 4-amino-5-tert -butyl-3-(methylthio)-as-)riazin-5(4H)-one Metsulfuron methyl (wtsulfonate) uron methyl) 2-[[(4-methoxy-6-methyl-1,3 ,5-triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic acid Methyl Nisel MH1,2-dihydro-3,6-pyridazinedione Molinate (Illolinate) S-ethyl hexahydro -IH-azepine-1-carbothioate Monolinuron (monol irn:ron) 3-(p-chlor phenyl)-1-methoxy-1-methylurea 7jm7 (monuron) 3- (p-chlorophenyl) -1,1-dimethylurea Monuron TCA 3-Cp-chlorphenyl)-1,1 -Dimethylurea mono (trichloroacetate MSMA) Monosodium methane arsonate napropamide ) 2-(a-naphthoxy)-N,N-diethylpropionamide naptalam (naptalam) N-1-su 7 chill 7 tarami Neburon acid 1-butyl-3-(3, 4-Dichloro7enyl)-1-methylurea Nitralin 4-(methylsulfonyl) -2,6-sinitro N,N-dipropylaniline ! Superintendent Sato Chemical name Nitrofen 2.4-, Chlorphenyl p-nitrophenyl ether Nitrofluorfen 2-chloro-1-( 4-nidoey phenoxy)-4-()lifluoromethyl)benzene Narea (Hexahydro-4,7- Metsundan-5-yl)-1,1-dimethylurea norflurazone (norf Iurazon) 4-chloro-5-(methylamino)-2-(a, a,a-trifluoro-m-tolyl)-3(2)()-pyridazinone oryzalin 3.4-dinitro-N,N- Dipropylsul 7-anilamide Oxadiazon (oxadiazon) 2-tert-butyl- 4-(2,4-dichloro-5-inpropoxyphenyl)△2-1.3.4-o Oxydiazolin-5-one oxyfluor 7xone (oxyf 1uorfen) 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-()rifle (ormethyl)benzene paraauat 1. 1'-dimethyl-4, 4'-biviridinium ion Pebulate S-Probil Butylethylka -vamothioate Chemical name Bendimethalin (pen dimethyl in) N (1-ethylpropyl)-3,4-dimethyl Chil-2,6-cinitrobenzeneamine perfluidon e) l, 1, 1-trifluoro-N-[2-methyl-4 -(Phenylsulfonyl)phenylcomethanesulfonamide Phenmedipham 3-r (methoxyca (rubonyl)aminocophenyl(3-methylphenyl)carbamate picloram 4-amino-3,5,6-to Lichlorpicolinic acid PPG-10135-[2-chloro-4-(trifluoromethyl)-phenoxy ]-2-Nitroacetophenone oxime-〇-acetic acid methyl ester Prodiazine 2-[[4-chlor-6 -(cyclopropylamino)-1,3,5-)riazin-2-ylcoamino]- 2-methylpropanenitrile Profluralin (profluralin) N-(cyclopropyl methyl) -ff, ff.

a-) Rialol-2,6-sinitro N-propyl-p-toluidine Prometon (prometon) 2. 4-bis(isopro and (ruamino)-6-nodoxy-S-triazine V Haruka Trouble Prometryn 2. 4-bis (improvisation) pinogemino)-6-(methylthio)-s-)riazine Pronamide 3. 5-Jiku o Lu N- (1,l-di)f-2-propynyl)benzamide Propachlor 3-Chlor-N-isopro Pilacetanilide Propanil 3', 4'-dichloropro Pionanilide propazine 2-chlor -4,6-bis(isopropylamino)-s-)riazine 7’ Roa 7 Propham Isopropyl carba Prosulfalin nylate (prosulfalin) N-[(4-( diprobinogemino)-3゜5-dinitrophenylcosulfonyl]-S.

S-dimethylsulfilimine Brynachlor 2-chlor-N-(1-methane) Tyl-2-propynyl)acetanilide Pyrazon 5-amino-4-chloro-2 -7enyl-3-(2H)-pyridazinone Quinofopethyl 2-[4-(6-chloro) Luquinoxaline-2-yloxy)phenoxypropanoic acid ethyl ester Secbumeton N-ethyl-6-medoxy -N'-(1-methylpropyl)-1,3,5-triazine-2,4-diamine Chemical name: Setoxydim (setho) xydim) 2-[1-(ethoxyimino)butyl]-5-[2- (Ethylthio)propyl-3-hydroxy-2-cyclohexen-1-one siduron 1-(2-methylcyclohexane) xyl)-3-phenylurea simzine 2-chloro-4,6-bis(E) thylamino)-3-triazine Sulfometuron methyl (sulfometuron methyl) 2- [[[(4,6-dimethyl-2-pyrimidinyl)-aminoco-carbonyl] Amino]sulfonyl]benzoic acid methyl ester TCA Tebutiuron Lichloroacetate (teb uthiuron) N-[5-(1*1-dimethylethyl)- 1,3,4-thiadiazol-2-yl]-N,N'-dimethylurea Terbaci 1 3-tert-butyl- 5-chloro-6-methyluracil Terbuchlor (terbuchlor) N-(butoxymethyl) -2-chloro-N-[2-(1,1-dimethylethyl)-6-methylphenyl] acetamide Terbuthylazine 2-(tart-butylazine) Common name for thylamino)-4-chloro-6-(ethylamino)-3-triazine Chemical name Terbutol 2.6-tert-butyl-p-tolyl methyl carbamate Terbutryn 2-(tert-butyl acetate) Mino)-4-(ethylamino)-6-(methylthio)-s-triazine Thiameturon methyl 3-[[[[(4-methoxy-6-methyl -1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfony thioben carboxylate]-2-thiophenecarboxylic acid methyl ester carb) S-E (4-chlorophenyl)methyl] diethyl carb Mothioate triallate S-(2+ L 3- TriCl sialyl) diisopropyl thiocarbamate Triclovir (triclopyr) [(3,5,6-) dichloro -2-pyridinyl)oxy]acetic acid tridiphane 2-(3,5-dichlor phenyl)-2-(2,2,2-trichloroethyl)oxirane trifluralin 2+ 6-sinitro N , N-dipropyl-4-(trifluoromethyl)benzenamine Souyo What is trimeturon? 　　　　　　-(p-Chlorphenyl-trimethylpseudourea 2, 4-D (2.4-dichlorophenoxy) vinegar Acid 2,4-DB　　　　　　　　　　　　　　　4- c) Vernolate butyrate S-7’lopyl Dipropyl force/cumothioate Xylachlor (revised 1achlor) 2-chlor-N- (2.3 -dimethylphenyl’)-N- (1-methylethyl)acetamide The herbicidal activity of this compound was found in a number of greenhouse tests. The test method and results are as follows. It is as below: Compound table OR 1.

Seikojiku Dan Rainbow XY Su Melting point ('C) I CHs l(　OCH3　　0CH3　CH203　~19213　　H CHn OCHs CH 190-1923 CH3H C Hs cHs CH201-203 decomposition 4 CHs H CI OCRs CM 195-2005 CHs H O CHs CH3 N 189-1916 CH, )l QC) Is QC) 13 N 191-1947 C) 13H 　OC. )II NHCH3 N 180-1868 CH3C N. H OCH, OCH3 CH 203-2079 CH2CH3 H CHs OCHs CH 182-18 610 CIbCHs H CHs CH3 CH 19 1~19611 CHICHI H CI OCH, C H 165-17012 CH2CH3 H CH3 0CH s N 188 ~ 19213 CHxCHx H OCHs OCHs N 178-18214 CH (CHs) H OCH3 0CH3CH 190-19315 C)l(CL) ! ) l C) 11 OCR. CM 190-19216 CH (CHI) 2 H CM) CHs CH 172-17 617 CH (CHI) 2 H CI OCHs CH 155-16018 CH (CHs)z H CH3 0CH, N 176-180 compound table (system) Iku Nenho and gloss x yz Melting point (℃) 19 CH (CH s)z　H　OCHs　　OCRs　　N　178-18320　 CHs CI OCHs OCHs CH 197-20 021 CH) CI C) +3 CHs Cl 15 3-16022 CHs CI CI OCRs Cl 175-18323 CH, CIOCH, cut N 182-184 decomposition 24 cHs CI OCR, O CH3　　　N　　183-187 Birthright So　　　xyz　　Melting point ("C) 25 CH3 0CHs OCHs CH 195 ~ 2002 6 CHs CH3 0CRs CH 178-17927 CH3 cas CHI CH 179-18028 C)1 , CI QC) IS CI (185-22229 CH3 cH, OCRs N 182-18430 ca, O CH. OCHS N 186-18831 CH3CN, oc as　OCRs　CH　163~16732　CHsCHs　CH s OCHs CH 168-17033 CH, CH, CHs CH, CB 161-16334 CHICH, CI OCH. CH 160-16335 CH, CHI CHI O CR, N 180-182 compound table (system) Strong birthright Dan X ヱ　　 Melting point ("C) 36　　CH.C)! QC)1. QC) 1m N 110-120 disassembly t Dan xyz Breasts (Ω main) 37 CI OCRl ocns CH 175-17838 CI CHs OCHs CH 165-17039 CI CH, CH. CH 140-14840 CI CI QC)l, CH 160-16441 CI CHS OCH. N 138-14742 CI OCH3 0CH3 N 165 ~ 16943 0CH30CHI OC H, CH 182-18544 0CH, CHs OCH3 CH 158-16145 0C)l, C)l, CHI C) 1 184-18846 0CH.　　　　CI　　OCHM　 CM 170-17347 0CHx CH3 0CH3 N 143-14748 ocH. OCHs OCHs N 160 ~ 16449 CN OCHS OCR3CH 175 ~17850 CN CH, OCH, CM 169 ~1 7051 CN CHS CH3 CM 175 ~ 1785 2 CN CI OCR3C) + 158-160 compound table ( string) 也茟茀　　　　　　　　　　　　And　Melting point ("C) 53　　　CN　　CH, O CR, N 159-16154 CN OCR, OCH, N 16 8-17055 HOCR, 0CHs CM 167-170 decomposition 56 HOCR, 0CRs CH177-178 decomposition 57 HCHs CHs CM 170-171 decomposition 58 HCI 0CRs C l 166-168 Decomposition 59 B c) Is ocus N 164-165 decomposition 60 Hocu, 0CHs N 167-16 9 decomposition 61 HOCH,OCH3CH184-19262 HCH,O CR, OB 196~20063 HCH@CHs CH1B7~ 19064 HCI 0CRs CH175~17965 HC H30CH3N 166~17066HOCchi 0CRs N 180~ 18567 CI OCH, ocns CH169-17568 CI Cl, OCR, C11202-20469 CI CB, Cl5Cl 180-184 compound table (continued) Living imperial sac and X Yes Melting point (C) 70 CI CI 0CHs CH180-19371 CI CH3ocas N 168-17272 CI 0CHs 0CHs N 182-186 birth control point (C) 73 0 CHs 0CHs CH206~2088 C) Is 0CR s CH204-20675 CHs CH179 ~18276 cloc)! 3 cH197~20177 C H30CHs N 190-19478 0CH, 0CR3N 198-201 Production volume X ヱ 1 1 Supervision cns OCH3CO179-181 decomposition 80 CH30CRs CM 148-163 decomposition compound table (system) Raw Emperor Strong X Y Su Melting point (℃) 81 CM, Cf1s cl 145-160 decomposition 82 CI OCR, CB 140-151 decomposition 83 CH, OC1'lS N 140-150 decomposition 84 00Hs 0CHz 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 1 Supervision X engineering Σ85 0CH, ocns Cl 179-18286 CHs 0CHs CM 176-17987 cH , cH, CH194-1978B CI 0CRs C11 67-17089 CHs 0CRs N 157= 16090 0CRs 0CHs N 173~177 Gourd Δ Japanese crabgrass (Digitaria species), Golden millet (Echinochloacru) s-galli), Setaria faberi, Kara Sumgi (Avena fatua), Bromus 5ec alinus), or downy bromeXBrom us tectorum), velvet leaf (Abutilon theop) hrasti), morning glory (Iponoea species), pensylvanicu+o), sorghum, corn, soybean, sugar Seeds of daikon, cotton, rice, wheat, barley, and Cyp Erus rotundus) are planted and dissolved in a non-toxic solvent to the plants. The seeds were pre-treated with the test compound. At the same time, these crops and weed species are cultivated in the soil. I took treatment. Plant height ranged from 2 to 18 cm at the time of this treatment. . Treated plants and controls were kept in al for 16 days, after which all seeds were compared to controls. The animals were bitten and the response to treatment was assessed visually. The ratings summarized in Table A are 〇 - Damaged. Based on a scale of numbers from 10 to 10 to complete death.

The symbol following this number has the following meaning: C sanctification/corruption Theory B: sunburn D-Deciduous leaves E-Germination inhibition G-san growth delay Effect on H-formation U-Abnormal pigmentation X-lateral bud stimulation S=-pigment deficiency 6Y-Abscessed bud or flower Table A Compound 1 Compound 2 Rate - kg/ha O,050,010,05 (101 after germination 7ta 9C9C9C5C, 9G Morning Glory IOCIOCIOc IOC Onamomi 9C9CIOCIOc Hamasuge 9C9C9C3C,8 G crabgrass 0 0 3G 3G O dogbi D9C9C9C3C, 9H Oat 60 20 5C, 906G wheat 7G 6G 5C, 9G 7C tow% (7 ko’y 9G 2C, 9G 5U, 9G 3C19G soybean 9C9C9C9C rice 9C5C, 9G 5C, 9G 30.7C%O stiffness 60 50 4C, 9G 4C, 9G Tin i Nochiyahi + 90 7G 4C, 9G 5C, 9c sugar beet 9CIOC9C velvet leaf 10c 9CI OC5C, 9G oh x 7 = +o gusa 2C, 7G 30 5 C, 9G 7G barley 80 6G 4 C, 9H2C, 7C Table A Compound 1 Compound 2 Ratio-kg/ha 0.05 0.01 0.05 0.01 before germination Cotton 9G 2G 3C, 8G O morning glory 98 2C, 4G 3C, 8G O Onamomi 2C, 702C, 7G 3C, 4H-ha Mass game 9G 3G 9G 5G Cucumber 2G 0 5G O Inuvie 8H609H3H oat 2C, 6G 3G 3C, 5G 2C, 3G wheat 8G 50 3C, 8G 5G corn 20. 9H2C, 6G 3C, 8H3C, 6H soybean 3G, 9H4H3C, 7H3C, 6B rice 9G 60 9H2G sorghum 3C, 8103C, 9Fl 7 B Suzume no Chiyahiki 3C, 8050805G Sugar beet 9G 9G 3C, 9G 9G Velvet Leaf 9G 7G 4C, 9G 3H Great Elephant 8G 0 9H3G barley 8G 6G 8G 2C, 7C Table A Compound 3 Compound 4 Rate-kg/ha O,050,010-050,01 after germination Cotton 9C5C, 9G 9C4C, 9H Morning Glory 　　　　　　IOc　　　　2C,7G　　　　　IOCIOc Onamomi　 IOCIOCIOc IOC Hamasuge 9C905C, 9G Mehishiba 6G 5G 3G O Inubi 1 9C5C, 9H3C, 986H Color Sumgi 4C, 904C, 906G O wheat 5C, 909G 5G O corn 8U, 9C40, 9G 8H3H, 4C.

Soybean 9C9C5c, 9G 3c, 5c rice 6C, 9G 6C, 9G 3C, 8G 5G Moo:+ shi9C6C, 9G 81 2C, 8G Suzume no Chiyahiki 9 C5C, 9G 9G 5G sugar beet core 9C5C , 9G IOc 9C Velvet Leaf 1 0CIOC9G Giant Greentail 4C,905G 5G O barley 5C, 9G 90 6G 　　2G Table A Compound 3 Compound 4 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 9G 5H3C, 7G 7G morning glory 9G 9G 9G Onamomi 9G 3C, 5H3C, 6H3C, 8G Hamasuge IoE 5g IoE 8g Mehio Shiba 　 　 　 5G 　 　 　 2G 　 　 9H2C3C,7HO Oat 2C,8G 3C,7 02C, 3G O wheat 3C, 9H2C, 8G 20 2G corn 90 4C, 803C, 7 82C, 2G soybean 9H3C, 7H3C, 4G Oi 9H907G Sorghum IOE 9H3C, 9G 2C, 7G Suzume no Chiyahiki 98 7G 7G O sugar beet 9G 8G 3C, 9G 3C, 9G Velvet Leaf 90 8H9G 8H Giant Greentail 98 3G 7G O barley 9G 9 0 3C, 7G 2G Table A Compound 5 Compound 6 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 9C4C, 9G 5C, 905C, 9G Asaga O IOc 5C, 9G 5C, 9G 5C, 9G Onamomi IOCl0C-5C, 9G 3H, 6G Hamasuge 4C, 90802C, 2G O Mehishiba o　　　o　　　　o　　.

Dogfish o, o o.

Oat 0 0 0 0 Q wheat 00 0Q Tumo O Koshi 3C, 9g 3 H3C, 8HO soybean 5C, 9G 5C, 9G 5C, 9G 5C, 9G rice oo o .

Sorghum 2G 0 2G O sparrow Nochahiki oo o.

Sugar beet 10CIOC10C9C velvet leaf 5C, 9H9C5C, 9H Giant foxtail oo o.

Barley 0 0 0 Table A Compound 5 Compound 6 Ratio-kg/ha 0005 0.01 0-05 0-01 before germination Cotton 8H4G 3C, 702G morning glory 　　　　　9G80　　　9G　　　　3C, 7G Onamomi　　　　 811 5G 2G puff 8 game 　　　　0　　　0　　　0　　　　　　　　　　　　　　　　　　　　0　 o.

Oats o.

Wheat o.

Corn 7G 2G 3C, 8G 2 G soybean 4C, 8H3C, 5G 3C, 7H3C, 3 H rice 2G 0 0 Mookoshi 3C, 5G 0 0 2G 5 G 0 0 Sugar beet 5C, 9G 70 5C, 908G Velpet Leaf 80 60 2C, 502G Great Elephant 2G O00 Barley 　　　　　　　　　　　　　　　OO0 Table A Compound 7 Compound 8 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 4C, 9G 4C, 9G 5C, 9G 9C morning glory 90 5C, 9G IOc 2C, 6G Onamomi 5C, 9G II IO CIOc Hamasuge 3C, 903C, 505C, 904C, 9G Mehishiba 2G o

IJ Barnyard grass 3C, 8H3G 9C3C, 91 (oats) 2G 0 40 2G wheat 0 　　　　0　　　　2G　　　　　Qt? % Rokoshi 4C99G 3C , 803C, 6H2C, 4G soybean 3C, 804C, 909 C4C,9G rice 3C,706G 4C,90 3C, 5G mosshi 70 2C, 2G 4C, 8 H3C, 7G Sugar Dairy: ln! QCIOc IOCIOc velvet Litori 5C, 9G 4C, 8HIOc 9C Oenoco Logsa 3G 0 3C, 702G barley 2C, 2G 0 3C, 803G Downy Blow/, 0 0 0 3C, 802C, 3G Table A Compound 7 Compound 8 Rate-kg/ha O,050,010-050,01 before germination Cotton 5G 30 7G O Asa Gao 9G IC2C, 5H7G Onamomi 3G Ic 3C, 8H3C, 5H Hamasuge 0 0 0 10E Mehishiba 2C, 4002C, 3G　　　　　　　　　　　　　3C,7G　　　0　 3C, 4G O oat 3G 2G 2C, 5G 2G wheat 0 0 0 3G O corn 9G 3C, 6G 3C, 9H2C, 2G soybean 3C, 9H7H8H3C, 7H rice 8G 5G 80 2 C, 4G sorghum 3C, 8H3G 8H2C, 2G Sugar beet 5C, 908H907G velvet leaf 2 C, 8G 3H8H3C, 5) 1 Giant foxtail grass 0 0 2C, 4G O barley 2C, 2G Ic 　　　　OO Downey Brohm　　30　　　2G　　　　9H 2C, 5G Table A Compound 9 Compound 10 Rate - kg/ha O, 050, 010, 050, 01 after germination 7ta 5C, 9G 6G 4C, 9G 2G Asaga, i IOC IOC 3C, 6G IC, IH O Na%mi IOC9C9C4C,9G Hamasuge 5C, 904C, 9G 4C, 9G 2C , 5G Mehishiba 0 0 0 3G Oi Nuvier 4C, 983C, 7G 2C, 2G Oka Ras wheat 2C, 3003C, 5G O wheat 2G 0 3C, 5G O corn 3C, 883C, fiG 3C, 703C, 6G soybean IOC3C, 8H4C, 904C, 9G rice 3C, 9 G 7G 7G 2C, 4G sorghum 3C, 903C, 8H3C, 7G 2C, 4G Sugar beet 9 C3C, 7G 4C, 909G Velvet Leaf 9C5C, 9 G　　　　　　　　　　　　　　　　　　　　　　3C, 703C, 7G 0 2G O barley 2C, 5G 2C , 203C, 502C, 4G Downey Brohm 4C, 8G 3C, 4G 3C, 702C, 4G Table A Compound 9 Compound 10 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton Ic 70 2G O Asa Gao 9G 3C, 387G 2G Onamomi 9H3C, 7H8H, 3C, 5H Hamasuge IOE 　　　　　　　　　　　　　　　　　3G　　　　　　　　　　　　　　　　　3C,3G 　　　　　　　　　　　　　　　　3G　　　　　　　　　　　　　　　　　　3C,7H2 06GO oat 2C, 50304G O wheat 4G 0 2G O corn 3C, 9G 3C, 5G 3C, 9G 3C, 5H die 3C, 8H3C, 7G 98 3C, 6H BH5c 7H3G sorghum 3C, 9H3C, 5G 9H2C, 3G Sugar beet 8 G80 9G 9G Velvet Leaf 8H3C, 60703H Giant foxtail grass 40 20 2G O Downy - Blohm 3C, 8G 50 6G 2C, 5G Table A Compound 11 Compound 12 Rate - kB/ha O,050,010-050,01 before germination Cotton 9H3C, 8G IcIc 5C, 9G Morning Glory IOC9CIOCIOC Onamomi 9C9CIOc IOC Hamasuge IOo 5 C, 903C, 7G 4G Mehishiba 3 to 0 0 0 Dogfish 2C, 5G 2H00 Crow Wheat 0 0 0 Wheat 0 0 0 0 Corn 3C, 4 (, 203C, 6G O soybean 4G IH9C4C, 9G Ne 2c, 5g IC 0 Moroko 3C, 7G 2C, 4G 2G 2G service Radish IOo 3C, 8G IOCIOC Berube Leaf IOc 5C, 9) 1 9C5C, 9 Sawfish 2G 0 0 0 Barley 0 Downey Brohm 3C, 7G O00 Table A Compound 1 Compound 12 Rate - kg/ha O,050,010,050,01 before germination Cotton 30 30 4C, 906G morning glory 5G 40 9G Onamomi 3C, 4H3C, 518H3C, 5H Hamasuge IOE 0 0 0 Mechisiba 20c, 5g 　　　　　　　　　　　　　0　　0　　　0　　　0　0 Crow Wheat 2G OOO wheat 0 0 0 0 Corn 2C, 5G 0 0 3C, 703C, 3G soybeans 0 0 98 3C, 8G rice 7G 4G 0 0 sorghum 7G 0 7G O Sugar beet 9G 8G 5C, 9G 5C, 9G Velvet Leaf 58 3C, 58783C, 5G Giant Greentail 2G 2G OO Barley 1c Downey Brohm 3 0 2G 0 3G Table A Compound 13 Compound 14 Rate-kg/ha 0.05 0.01 0.05 0.01 before germination Cotton 5C, 9G 4C, 9G 7G 7G morning glory IOc IOC3C, 8G 5G, 9 G Onamomi IOc 5C,9G 4C,904 C, 9H Hayasuge 9C03C, 9G 4C, 9 to Mehishiba 0 0 0 0 Golden millet 0 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 0 4G 0 wheat 0 0 2 G O corn 2C, 3G O403G soybean 5C, 9G 4C, 903C, 9G 4C, 9G Ne IC 0 4g '2g Moro Kosi 0 0 2G 3G O Sparrow Yahiki 8GO sugar beet 10c 9C3C, 7H4G velvet leaf 9C3C, 864C, 9G 2C, 8G Giant Elephant 0 0 3C, 7G O barley 2G O3G Oda Unnie Blohm 00 Table A Compound 13 Compound 14 Rate - kg/ha O, 050,010,050,01 after germination Cotton 7H2C, 5G OO morning glory 9G 3C, 3G 0 Onamomi 7H3C, 3G 2HO Hamasuge 7G 0 0 0 Mehishiba 0 dogfish oo o.

Oat 0 0 0 3G O wheat 　　　　　oo　　　　　o.

Corn 2C, 40000 soybeans 4C, 8 03C, 8HOO rice 0 0 0 4G’ 0 sorghum 0 0 0 0 sorghum Firefly 00 Sugar beet 5C, 9 05C, 9G 3G O Velvet Leaf 8G 2C, 3000 giant foxtail grass 0 0 0 0 0 Wheat 0 0 0 Downey Brohm Oo Table A Compound 15 Compound 16 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 9H7G 7G 5G Morning Glory 　　　　　　　IOc　　　　5C, 9H3C, 8H2C, 5G Onamomi 5C, 9G 4C, 9H3C, 9H3C, 6H Hamasuge 8g 3g 0 0 Mehisiba 0 0 2G 0 7G 31 2C, 5G O oat 6G 20 7G O wheat 3G 0 0 2G O corn 3CL7G 2G 3c, 3c 1c soybean 5C, 9G 3C, 683C, 5G 2C, 3H rice 50 4G 3C, 5G O sorghum 3C, 40203G O Sparrow 5G 50 0 Sugar beet 3C, 5G 50 2G O velvet leaf 4C, 902H5G O oe Sawfish 3 to 2G 5 (1; 0 Oh Wheat 5G 0 40 0 Table A Compound 15 Compound 16 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 0 0 0 2G O Morning Glory 81 0 1HO Onamomi 7 H2C, 3HIHO Hamasuge 0 8G OO Mehishiba 　　　　　oo　　　　o.

Golden millet 2c o o.

Oat 5G 2c 6G Oko Wheat 4Q 20 5G O corn Rokoshi 3C, 7G 2C, 3G 3C, 7G O dive 3C, 7H2G 0 0 Rice 6G 20 3G O Sorghum 2C, 5G 2G 0 0 Sparrow 7 G 3G 5G O Sugar beet 4H 4G 70 2G Velvet Leaf 0 0 0 0 Giant Enoco Log Sa 2G O00 Barley 6 to 0 4G 0 Table A Compound 17 Compound 18 Ratio - kg/ha O,050,010,050,01 After germination Cotton 6G 4G 4C,8G 3 C,7H Morning glory 3C,8H2H9C3C,9H Onion 4C,9H3C , 8H9C3G, 9H Hamusuge 2 G 0 0 0 Rock grass 0 0 0 0 Golden millet 4G 5G OO Oat 0 0 0 0 Wheat 0 0 0 0 Corn 0 0 2HO dive 2G IH2C, 8 H3C, 6H Rice 2C, 3G 0 0' 0 Sorghum 0 0 0 0 sparrow Yahiki 0 0 0 0 Sugar beet 4G 0 5C, 9G 4C, 8G Velvet leaf 7 G 0 4C, 9H 8G Giant hackberry 0 0 0 0 Barley 0 0 0 0 Table A Compound 17 Compound 18 Proportion - kg/ha O,050 ,010,050,01 Cotton before germination 2G 0 3G O Asaga O Q O7G O Onamomi 2 to 0 8HO Hamasuge 0 0 0 0 Mehishiba 0 0 0 0i Nuvier 0 0 0 0 Oat 0 0 0 0 Wheat 0 0 0 0 Corn 2C, 5G 0 2C, 5 G O Dive 0 0 3 C, 7 G O Rice 2G 0 0 0 Moro Koshi 0 0 0 0 Sparrow beet 0 0 0 0 Sugar beet 5G O8G O Velvet leaf 0 0 3G O Giant foxtail 0 0 0 0 Barley 0 0 0 0 Table A Compound 19 Compound 20 Ratio - kg/ha O,050,010, 050,01 After germination Cotton 3C, 803G 9C5C, 9G Asaga No. 4C, 9G 4C, 8HIOCIOC Gi 0 0 80 2G Corn 0 0 4U, 9 3C, 8G Soybean 3C, 8G 3C, 5H9C9C Rice 0 0 3C, 80 5G Sorghum 0 20 9C 3C, 9G Sparrow Nochiyahiki 0 0 5C, 902C, 7G Sugar Cane A 4C, 9G 3C, 8HIOCIOc Velvet leaf 3C, 8H 3C, 7HIOc 8G Giant foxtail 0 0 3G, 6G 2G Barley 0 0 3C, 6G 3G Table A Compound 19 Compound 20 Ratio - kg/ha O, 050,010,050, 01 Before germination Cotton 2G 0 3G O Asa Gao 3C, 411209G 2G Onamomi 2C, 2H03C, 8)! 5G Pork mulch 0 0 9G 8G Crabgrass 0 0 3G O Golden millet 0 0 0 0 Oat 0 0 3G O Wheat 0 0 3C, 5G O Corn 0 0 3C, 9G 2C, 5G Soybean 3C, 3H2C, 2H3C, 4HO Rice 0 0 3C, 8G O Sorghum 0 0 3C, 9G 2G Sparrow beet 0 0 7G O Sugar beet 7G 511 90 7G Velvet leaf 20.2H05C, 9G 3H Giant hackberry 0 0 2G O Barley 0 0 3C, 7G 2C Table A Compound 21 Compound 2 2 percentage -kg/ha O,050,010-050,01 After germination Cotton IOC3C, 609C5G Morning glory IOC3C, 7810c 3C, 8G Onion IOc 3C, 8HIOc 2C, 9G Hamusuge 5 C, 90908G O Crabgrass 4G O02 G Goldeneye 5C, 9G 2C, 8HIC, 5H2G Crow Wheat 2C,7G 50 3G O Wheat 9G 3G 0 0 Corn 3C,902C,7H2C,7H2G Soybean 90 9C6C,902C,6G Rice 80 5G 20 2G Sorghum 5C,9G 90 9G 2C,8M Sparrow 4C,9G 9G 60 6G Sugar beet 5C,9G IOC9C3C,7G Velvet leaf IOc 9G 90 2C,7G Giant hackberry 8G 4G 2G O Barley 9G 6G 4G 0 Table A Compound 21 Compound 22 Ratio - kg/ha o, os 0-01 0.05 0 .01 Pre-germination Cotton IC06G O Morning glory 50 50 90 4G Onamomi 3C, 7H3C, 718G 6G Hamusuge 10E 3G 10E O Kingfisher 2G 0 0 - Goldeneye 4G O00 Kara Soybean 2C, 5G 0 0 0 Wheat 3C, 9G 0 0 0 Corn 9G 2C, 8G 2G O Soybean 911 1c, 4G 0 0 Rice 5C, 8H 203G O Sorghum 9m1 2C, 7112C, 8G Japanese radish 9G 9 G 3C,9G O Velvet leaf 3G O8G O Red foxtail 70 6G 5 0 4G Barley 9 (1; 4G IC,500Table A Compound 23 Compound 24 Ratio-kg/ha o,os O,010,050, 01 After germination Cotton 4C, 9G 4C, 905C, 9G Oa Sagao 5C, 9H3C, 7G 5C, 9H3C, 4G O Namomi 3C, 9H2C, 402C, 7G Ic, 3G Hama Sedge 3G 3G 0 0 Crabgrass 0 2G 0 0 Golden millet 9C4C, 8H3C, 9H3C, 71 Oat 8G ' 2C, 3G 2C, 6G 2G Wheat 5 G 30 2G O Corn 3c, J c 3C, 7112C, 8G 3c, 4c Soybean 6 C , 9G 4C, 9G 4C, 9G 3C, 8G rice 4G 20 2G O sorghum 6C, 9G 3C, 803C, 9G 8G sparrow 5 C, 9G 8 to 3C, 9G 8G sugar beet 5C, 9G 3C, 609C 5C, 9G velvet leaf 3C , 8G - Giant foxtail 6G 30 6G O barley 0 0 2G 0lf Table A Compound 23 Compound 24 Ratio - kg/ha O,050,010,050,01 Before germination Cotton 8G 0 2G O cotton Gao 9G 2C, 6G 2C, 4G IC, 5G Onagumomi 9G 6G 2C, 6G 5G Hamusuge 8G 0 5G 2G Crabgrass 4G 2G 3G Golden millet 4G 0 0 0 Oat 0 0 0 0 Wheat 2G 0 0 0 Corn 4C, 7H01c O dive 4 C, 8) 1 0 2C, 2G O rice 5C, 8H02C, 4G O sorghum 4C, 883C, 7H4C, 9G 3C, 5 with sparrow Ki 4G 0 0 0 Sugar beet 5C, 9G 3c, 8c 4C, 9 4G Velvet Leaf 2C, 4G 0 2C, 3G 2C; Sa 3C, 8H 20703G Barley 2C, 40204 G 0 Table A Compound 25 Compound 26 Rate - kg/ha O, 050, 050, 01 After germination Cotton IOc 9C3C, 7G Asaga, t IOCIOc 4C, 8G Ona% Mi 9CIOC 5C, 9G Hamasuge 9C9C2C. 2C, 784C, 9G 2C, 9G Sparrow 6C, 9 09C 4C, 9G Sugar beet IOc IOc 9C Velvet leaf 10c IOC 5C, 9G Big oak Logsa 4C, 8G 5C, 9G 3C, 8G Barley 3G 3C, 903C, 9G Table A Compound 25 Compound 26 Ratio - kg/ha O, 050, 050, 01 Before germination Cotton 90 9H2C, 7G Morning glory 9G 9H8G Onion 7G 9H 3C , 7H Hamasuge 50 9G Mehishiba 50 4G O Dogfish 8H9H9H Ka Rath wheat 3G 3c, 8G 3c, 8c Wheat 60 80 2C, 5G Corn 8H2C, 9G 3C, 7B Soybean 9H 4C, 8H 3C, 4H Rice 80 3C, 9G 8G Moro Koshi 9G 2C, 9G 3C, 9G Sparrow Yahiki 9 2C, 908G Sugar beet 8G 9G 9G Velvet leaf 9G 9G 3C, 8H Giant hackberry sc '9u 8 B Barley 90 802C, 8G Table A Compound 27 Compound 28 Proportion - kg/ha O,050,010,050, 01 After germination Cotton 4c, 9c 6G 9C2C, 7G Morning Glory 90 3C, 7G IOC 9C Onomimi IOc 4C, 9G IOc 9C Porkworm 5C, 9G: 4C, 9G 9C 9C Black-and-white grass 7G 40 2G O Dogweed 9C4C, 9H3C, 8H5H Karasum Gi 6C, 9G 2C, 906 G O wheat 5C, 9G 3C, 905G O corn 7U, 9C3C, 903C, 8H5) 1 die 9C9C4C, 882B Rice 9C5 C, 903C, 8G 2G Sorghum 4C, 9G 4C, 9G 4C, 9G 3C, 7G Sparrow 9C5C, 9G 5C, 908G Sugar beet 9CIOc 9CIOc Velvet Leaf 9C8G9C7G Giant Elephant Sa 5C,903C,8G 4G O Barley 5C ,902C,9G 3C,702G Table A Compound 27 Compound 28 Rate-kg/ha O,050,010,050,01 Before germination Cotton 90 7G 5G 7G A Sagao 90 5G 9H8G Onagiri 9H7G 9H8B Red-bellied grass IOE 9G 9G 40 Kingfisher 5G O00 Golden millet 9H8H7HO Oat 2C, 803C, 504G O Wheat 3C, 9H7 G 5G O Corn 2C, 9G 2 C, 9G 3C, 7G 2G soybean 9H8800 Rice 9H9H8) 1 3G Sorghum 9HIOH3C,8HO Suzume Nochahiki 9H817H2G Sugar Ikon 90 70 9C7G velvet leaf 9G 88 4C, 9G 80 Giant foxtail 9H3H2G O barley 90 8G 2C, 6G 0Table A Compound 29 Compound 30 Ratio - kg/ha O,050,010,050,01 After germination Cotton 9C5C, 9G 9C5C, 9G Morning Glory 5C, 9G 5C, 9G 9C9C Onion IOc 9CIOC5C, 9G Red-eye 2C, 6G 3G 9C4C, 7G Crabgrass 6G 0 0 0 Golden millet 0 0 21 0 Oat 0 0 0 0 Wheat 0 0 0 0 Corn 5 U, 9H6H3C, 8HO dive 5C, 9 to 4 C, 9G 5C, 9G 5C, 9G rice 2C, 2G O00 sorghum 4C, 90402G O Sparrow 6G 0 0 0 Sugar porgy Con 9C9CIOC9C Velvet Leaf - 10C4C, 90 Oninophroga sc o o.

Barley 0 0 Table A Compound 29 Compound 30 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 9G 50 3C, 805G Asa Gao 90 9G 9G 5G Onamo Mi 91 71 3C, 7HIC Hamasuge IOE 0 0 0 Mehishiba 0 0 0 0 Dogfish 2G 0 0 0 Oat 0 0 0 0 wheat 0 0 0 corn 80 3C, 603C, 8H7G soybean 91 2C, 7G 91 3C, 5G rice 2 G 0 2G O sorghum 2C, 8 G 0 3G O Sparrow 30 0 0 0 Sugar beet 4C, 908H4C, 9 03C, 8G Velpet Leaf 5C, 907B 5C, 90 3C, 7G Giant Elephant Grass 0 0 0 0 Barley 3C02C0 Table A Compound 31 Compound 32 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 9C9G 3C, 903C, 9G Asaga O IOC30,8G IOc IOc Onamomi IOc 4C, 9G 90 4C, 9G Massage 9C9C9C Mehishiba 5G 0 2G 5G dog! 4C, 9H3C, 5G 4C, 9H8H Oat 0 0 0 3C, 7G 2C, 3G wheat 2G 0 0 7G 3G door % o Koshi 3C, 8G 30 3C , 9H3C, 8G soybean 4C, 9G 3C, 803C, 9G 3C, 6H rice 3C, 9G 70 3C, 9G 8G 70 Koshi 3C, 9G 3C, 709G 3C, 9G Sparrow i9-'rhi* 4C, 9 to 7G 3C, 9 5G sugar beetle: I> IOC 2C, 8 9 C3C, 8G velvet tree y IOc 5C, 9G I Oc 5C, 9G oh! / :l Ogusa 3C, 6003C , 702G barley 2C, 2G 0 9 to 9 7G My A Table Compound 31 Compound 32 Rate - kg/ha O,050,010,050,01 before germination Cotton 2G 8G 7G Morning glory 2C, 3H08H3G, 5G Onamomi 8H2C, 3H9H3C, 7H Hamasuge IOE O IOE　　　　　　　　　　　　　　0　　　0　　　　　2C, 5G　　　　　　　　　　　　　　　　3H09H6G Oat　　　 0 0 0 3C, 8G 3G wheat 0 　　　　0　　　　8H3G corn　　　　　4G　　　0 98 2C, 8G soybeans 3C, 7H2C, 3G 3C, 7H3C, 6G rice 3C, 8H6G 9H8G sorghum 9H2C, 503C, 903C, 9G Sparrow 7G 30 9H7G Sugar Daiko 3H8G 8G 3H Velvet Leaf 3G 0 0 7HO Giant Foxtail 2C, 4G 0 barley 5G 0 0 9G BG Table A Compound 33 Compound 34 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 3C, 9G 2C, 9G 4C, 9G 2C, 9G morning glory IOC4C, 9G 9C3C, 8 G Onamomi 9C3C, 9HIOC4C, 9G Hamasuge 90 9C3C, 80 Mechiba 3C, 7g 　　　　　　　3C, 7G　　　O Golden millet 9H7H3C, 8H2C, 3G Oats 3C,702COO Wheat 90 4G 2G O corn 3C, 9H 3C, 7G 3G O soybean 3C, 9G 8H2HO rice 5C, 908G 70 2C, 4G sorghum 2C, 9G 3C, 802C, 8G 2G Suzume no Chiyahiki 5C, 908G 8G O Sugar beet IOC3C, 8G 3C, 903C, 8G Rubetsu Leaf 5C, 908G 9C3C, 8G Giant Elephant Log f 3C, 6G 20 3C, 7G Ic Ohm Gi 2C, 9G 8G O0 Table A Compound 33 Compound 34 Rate-kg/ha　　　　　　　　　　　　　　　　　O,010,050,01 shot Memae Cotton 7G 0 2G O Asaga O 2C, 2G 0 7HIH Onamomi 　　　　　　　　2C, 2H8H2C, 5G Ha? X game 8G 　　　　　　　　　　　　10E　　　　　　　　　　　　　　　　　　　2C,4G　 4G OO Inubi x 9H3C, 5G 2G O oat 7G Ic 0 0 Wheat 80 2G 0 0 Wheat 0 corn 2C, 903C, 4G 2G 0 soybean 2C, 8H3C, 6G oO rice 9H 7G 8H5G Mookoshi 9H2C, 8H2C, 504G Sparrow/Chia Hiki 3C, 9H3C, 7G 5G O sugar beet 80 70 8G 3H Perpetu Leaf OO5G 　　　　IH Giant Greentail　　　　4G　　　　2G　 　 0 0 Barley 9G 8G 3G 0 Table A Compound 35 Compound 36 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 5C, 9G 4C, 905C, 904C, 9G Asaga r IOC9C5C, 905C, 9G Onamomi IOo 9C909C Hamasuge 0 0 crabgrass 0 0 0 goldeneye 0 0 0 0 Oats 0 0 0 0 wheat 0 0 0 0 0 Corn 4G 0 2G O soybean 4C, 9050, 9G 5C, 9G 4C, 9G ne 0 0 0 sorghum 2G 0 2G O Suzume no Chahiki 0 0 0 0 0 .

Sugar beet 9C4C, 9G IOo 9G velvet leaf 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 0 0 Barley 0 0 0 Table A Compound 35 Compound 36 11 go-kg/ha O,050,010,050,01 before germination Cotton 2C, 9G 3G 9G 3 G Morning Glory 9G 3H9G 3G Onamomi 9H3C, 509H3C, 6H Hamasuge IOE 0 0 4G 0 0 0 2G 0 Golden flea 2G O oats 0 0 0 0 .

Wheat o.

Corn cy Koshi 2C, 5G 3C, 5G 2C, 3G 2C, 2G soybean 8H3C, 5G 3C, 8H3C, 7G Nen 0 0 2g O % Rokoshi 5 G 4G 2C, 202G Suzume no Chiyahiki 0 　0　　　0　　.

Sugar beet 3C, 904C, 9G 5C, 903C, 8G Velvet leaf 5C, 9G 0 3C, 7H2G Grass 0 0 0 0 Barley Ic 4G 0 0 Table A Compound 37 Compound 38 Rate - kg/ha O, 050, 010, 050, 01 After germination Cotton 5C, 909C9C5C, 9G Morning glory IOCIOc 9CIOc Onna fir IOCIO C9C3C, 8G Japanese sedge 2 C, 9G 4C. 9G 3C, 9H3C, 61 (soybean 9C9C5C, 904C, 9G rice 5C, 9G 9C7G 5G Moro Koshi 5C, 9G 6C, 9G 4C, 8G 3 C, 7G Sparrow Chiyahiki 6C, 903C, 9G 4C, 9G 3C, 9G Sugar beet 9C5C, 9G 5C, 904 C, 9H Velvet Leaf 10c IOCIOC9C Oeno Cologa 9C4C, 9G 3C, 9G 4C, 8G Barley 3C, 9G 2C, 902C, 503G Table A Compound 37 Compound 38 Ratio - kg/ha O, 050, 010, 050, 01 Before germination Cotton 9G 80 4G Oa Sagao 9G 40 4G Oonamo Mi 811 10E 0 0 Pork grass IOE 0 4G O Crabgrass 4G 2G 2G O Golden millet 9H3G 3G O Oat 3C, 803C, 6G 0 0 Wheat 4C, 9H6 G 0 0 Corn 3C, 9H2C, 502 G O Soybean 3C, 7H3C, 702 C, 2G O Rice 101 91 2G O Sorghum 4C, 9G 2C, 8G 3G O Sparrow 4C, 91303G O Sugar beet 5C, 9G 4C, 807G O Bellpet Leaf 5C, 9G 4C, 9G 2HO Giant hackberry 4C, 8H 3C, 7000 Barley 9G 8G 3G 0Table A Compound 39 Compound 40 111 go-kg/ha 0005 0.01 0.05 0.01 After germination Cotton 9C5C, 909C5C, 9G Morning glory IOc 4C, 9G IOC 9C Onagiri 9C4C, 9G IOo 9C Lotus grass 2C, 9G 90 4C, 9G 9G Mehishiba 3C, 70 504G O 9C5C, 9G 9C5C, 9G Oat 4C, 9G 9G 2c, 9c 3c, 7c Wheat 5C, 9G 8G 9G 8G) '> % Rokoshi 3C, 7G 2 G 3C, 8H 3C, 7H Soybean 5C, 905C, 905C, 9G 2C, 7G Rice 9C4C, 9G 5C, 9G 2C, 7G% Lokoshi 5C, 904C, 9G 5 C, 904C, 9G Sparrow/f'r Hi* 6C, 9G 90 5C, 9G 3C, 9G Sugar beet 9C4C, 9H9C9C Berhet !J -710c 9CIOc 4C,8H Oh!/ :l Cll Sasa 9C4C,904C,907G Barley 3C,90703C,8G 4G Table A Compound 39 Compound 40 Ratio-kg/ha o,os O,010,050,01 shot Before bud cotton 9G 70 4C, 9G 9G Morning glory 9G 8H9G 9G Onamia 9H3C, 5H8H3C, 6H Hamusuge 9G IOE IOE 9G Crabgrass 6G 2G 6G 3G Golden millet 9H3C, 5G 9H3G Oat 4G, 8H3C, 403C , 6G 2C, 2G wheat 3C, 9) 1 7G 8H8G corn 2C, 6G 5G 3C, 8G 5G soybean 9H9H8H3C, 7G rice 9HIOH9H9H sorghum 3C, 9H4C, 9H3C, 9H3C, 9H Sparrow 8H5G 3C, 8H4G sugar beet 4C, 907G 5C, 9 G 8G velvet leaf 4C, 8H3C, 7H4C , 8H3G Green foxtail 30.8H3C, 703C, 6030 Barley 9H3C, 8H8G 3C, 7G Table A Compound 41 Compound 42 Ratio - kg/ha O, 050, 010, 050, 01 After germination Cotton 4C, 903C, 504C, 903C , 8H Morning Glory 5C, 9G 3C, 9G IOC4C, 9G Onamo Mi 4C, 902C, 7G 4C, 9G 3C, 7G Hamasuge 50 4G 3C, 8G O Crab grass 4G 2G 3C, 7G 3 C, 5G Golden millet 5C, 9G 5C, 9G 4C, 904C, 9G Oat 4C, 9G 2C, 8G 4C, 9G 3C, 8G wheat 3C, 7G 8G 50.90 5C, 9G corn 4C, 903C, 9G 5C, 904C, 9G soybean 5C, 9G 3C, 8H9C3C, 8G rice 5C, 904C, 9G 5C, 9G 4C, 9G sorghum 5C, 9G 4C, 8H4C, 9G 4C, 9G Sparrow 5C, 90 3C, 904C, 9G 3C, 9G Sugar beet 9C3c, 7 G 9c 5c, 9c Velvet leaf 3C, 7H2G 4C, 8H4G Giant hackberry 5C, 9G 4C, 9G 90 4G , 9G barley 8G 70 4C,908G Table A Compound 41 Compound 42 Proportion - kg/ha O,050,010,050,01 Before germination Cotton 60 2G 3C,7G 2G Morning glory 9G O9G 2C Onomimium 20 0 2C,702G Japanese sedge 0 05g OMihi shiba 2g 05g {2c otobie 2C to 2c, 7G 0 4C, 8H4G carrassmugi 3C, 7G 2C, 7G 3C, 7H2C, 2G 609H5g ウ ロ 609H5g ウ ロ ロ ロ ９ ９ ９ ９ ０ ０ ０ ０. 7H / 2C Rice IOE 6G IOH9H Sorghum 4C, 9H3C, 8H3C, 9H3C, 3G Sparrow 40 0 3C, 606G Sugar beet 70 2H3C, 904G Velvet leaf 2G 0 3G IH Giant hackberry 3C, 705G 4 C, 8H:T; Wheat 9H3C, 8G 98 2C, 4G Table A Compound 43 Compound 44 Ratio - kg/ha O, 050, 010, 050, 01 After germination Cotton 5C, 9G 5C, 9G 4C, 9G 4C, 9G Morning glory 9CIOCIOC9C Onamia IOC4C, 8HIOc 4C, 9G Hamusuge 4C , 9G 4C, 9G 9G crabgrass 9C5G 2C, 6G 2G dog bean 9 C9C5C, 903C, 9G oat 4C, 9G 2C, 9G 3C, 903G, 7G wheat 9C909G 9G corn o Koshi 9C' 4C, 9G 4C, 9H3C, 6H soybean 6 C ,906C,9G 6C,9G 3C,8G Rice 6C,9G 6C,9G 9 C9C-v-1:I:l 9C4C,9G 4C,9G 4C,9H Sugar bean:17 9C9C9C9C Velvet leaf 10 c IOc IOc 5C ,9H oh x 7 :l ro Grass 9C5C, 9G 9C5C, 9G Barley 5C, 903C, 903C, 903C, 7G Table A Compound 43 Compound 44 Ratio -18/ha O, 050, 010, 050, 01 Before germination Cotton 9 9G 5G 2G Morning glory 9H919G 5G Onomimi 9H8H2C, 7H3C, 6H Hamusuge IOE IOE IOE O Kingfisher 7G 3G 2G O Golden millet 9H914C, 7HJH Power 5' Cedar 4C, 8G 3C, 7G 3C, 602 C, 3G Wheat 9H819H7H Corn C1 Koshi 10B 91 4C, 9 G 3C, 7G Soybean 9 H9H91 (4C, 7H rice IOE IOHIOH 3C, 6H% o Koshi98 4C, 9H5C, 9H3C, 8H Sparrow Chiyahiki IOE 9H9) 1 8H sugar beet 90 9G 3C, 9G 9G velvet tree y 4C, 9G 4C, 9G 4C, 8H 3C, 6H Big Enochrolog? 3C,803C,8G 3C,8H5H Barley 3C,9G 90 9G BH Table A Compound 45 Compound 46 Ratio - kg/ha o, os O, 010,050,01 shot After bud Cotton 3C, 909G 9C9G Morning glory 9C5C, 9G 6C, 9G 5C, 9G Onomimi 9C4C, 9G IOc 3C, 9G Pomfret 90 90 903C, 9G Crabgrass 3G 20 40 3G Inubini x 4C, 9G 4C, 8H9C9B Oat 3C, 7G 7G 3C , 9G 6G wheat 90 8G 90 6G corn o=+shi 2G 0 2C, 3G O soybean 2C, 6G 2C, 3H2C, 6G 4H Rice 9C9C9C 4C, 9G Sparrow beet 5c, 9c 3c, 8G 5C, 9G 3C, 9G Sugar beet 9C4C , 8H6C, 9G 9C Hell Het! J-75C, 9H4C, 882C, 704C, 8H Oe Sawflower 9C3C, 705C, 9G 3C, 8G Barley 9G 3C, 60904G Table A Compound 45 Compound 46 Ratio - ks/ha o, os O, 010,050,01 Before germination Cotton 2C0502G Morning glory 3C, 8H 3G 9G 811 Onomimi 8H2C ， 2 H9H8B Pork grass IOE 9G 9G IOE crabgrass 2G 0 0 0 Golden millet 3C, 7H2H4C, 8H21 Oat 2C, 3002C, 502G Wheat 5G 0 8H3G Corn 3C, 7004C, 7G 4 G Soybean 2C, 5004C, 8H2C, 5 G rice 4C, 8H09H' 911 Sorghum 3C, 9113C, 3 to 5C, 9H3C, 811 Sparrow beet 8 H03C, 6G 6G Sugar beet 90 8G 9G 8G Velpet leaf 4C, 7H2C, 4H4C, 7H2C, 5H Os/:Io grass 51 61 7H7 H Barley 3C ,8H09G 81 Table A Compound 47 Compound 48 Rate = kg/ha o, os O, 010,050,01 shot After bud cotton 6G 0 6G O Asaga O 4C, 882C, 2G 4C, 8HO Onamomi 3C, 5H02C, 3HIc Hamusuge 4G O Kingfisher 2G 0 2C, 402G Goldeneye 3C, 4H03C, 6HO Crow Wheat 2C,6G 0 2C,6G 2G Com Gi 4C, 9G 30 9G 80 tow Moct = + 3C1'9G 0 3C, 902C, 4G die 0 0 ICO Rice 3C, 9G 3C, 9G 4C; 9G 3C, 9G Sorghum 3C, 7H03C, 7G 2G Sparrow-4 C, 90609G 7G Sugar beet 3C, 6H 3H3C, 6H 3H Perpetu Leaf 0 0 2CO Giant Greenberry Logsa 2C,6G 2C3C,8G O Barley 9G 0 9G 0Table A Compound 47 Compound 48 Rate-kg/ha O,050,010,050,01 Before germination Cotton 0 0 0 0Morning glory 4G 0 2G O Onna fir 2G 0 4G O Hamusuge 0 0 0 0 Mehishiba 4G 0 2G O Golden Grass 0 0 0 0 Ka Rath wheat 0 0 0 0 Wheat 0 0 0 0 Corn 3C, 6G 0 2G, 6G IC, 2G Soybean 0 0 0 0 Rice 2C, 5G 0 4G 2G Sorghum 2C, 3G 0 0 0 Sparrow 0 0 0 0 Sugar Ikon 20 2G 0 0 Velvet leaf 5G 28 2G O Giant foxtail 4G 0 3C, 7H3G Barley 0 0 0 0Table A Compound 49 Compound 50 Ratio = kg/ha O,050,010,050,01 After germination Cotton 9CIOCIOC3C, 9 Morning Glory IOCIOC9C9C Onagiri IOc IOC3C, 7H2C, 4H Red-eye 4C, 9G 7G Crabgrass 5G 0 2G Golden Millet 9C5C, 9G 3C, 7H3C, 5B Oat 9G 50 4G 2G Wheat 9G 50 70 7G Corn 5 0. 9G 4C, 904C, 8HIc , 3G soybean 9C 9C3C, 8H5H Rice 5C, 9G 5C, 903C , 602C, 3G Sorghum 4C, 9G 4C, 9G 3C, 7G 4G Sparrow 9C, 903C, 705 G Sugar beet 9C9C9C3C, 8H Velvet leaf 100 IO C9C3C, 7G giant foxtail 9C4C,9 G 3G,7G 2C,5G Barley 2C,7G O00 Table A Compound 49 Compound 50 Rate-kg/ha O,050,010,050,01 Before germination Cotton 5C,9G 7G 0 0 Asa Gao 9G 8G 4G Oonamo Mi 9HIC, IH00 Hamasuge IOE IOE 0 0 Mehishiba 5G 0 0 0 Golden millet 9H000 Oat 3C, 6G 2G 0 0 Com Gi 7G 0 0 0 Corn 4C, 9G 3C, 7C3G O Soybean 9H3C, 7G 0 0 Rice 9H6G 2G O Sorghum 3C, 9G 2C ,5G 3G O Sparrow 4C, 8G O00 Sugar beet 5C, 9G 7G 3G O Velvet leaf 4C ,9G 28 1CO Oe Sawgrass 4C, 9H3G 2G O Barley 2C, 803C, 7G 0 0 Table A Compound 51 Compound 52 Rate - kg/ha O, 050, 010, 050, 01 After germination '79 5C, 9G 3C, 904C, 9G 4C, 9G Morning glory 9C4C, 9G IOo 5C, 9G Onamomi 5C, 9 to 4C, 9G 9C4C, 9G Hamasuge 9G 2C, 9G 4C, 9G 3C, 5 to Mehishiba 2C, 2 to 0 2C, 2G O Dogfish 4C, 9G 3C, 8H5C, 9G 4C, 9G Oats 90 8G 2C, 702G Wheat 902C, 90803G Corn 2C, 9H 6G 4C, 9H 3C, 8G Soybeans 5C, 904C, 905C, 9G 3C, 7B Rice 5C, 9G 3C, 605C, 902C, 3C% O: I 4C, 904C, 8G 5C, 904C, 9G Sparrow 5C, 9G 80 5C, 9G 7G Sugar beet 9C4C, 9G 90 9C Velvet Leaf 9C3C, 8HIOC9C Logsa 4C,903C,9G 3C,706G Barley 8G 60 6G 3G Den A Table Compound 51 Compound 52 Ratio - kg/ha O,050,010,050,01 Before germination Cotton 90 3C,503G,70 3C,4G A Sagao 90 2H9C3C, 3 and Onagiri 7H2C9HO Red-bellied grass IOE 3C, 5G IOE 3G Crabgrass 2C000 Golden millet 3C, 8C03C, 8H3G Oat 3C, 7G3C, 4C2C, 3G O Wheat 3C, 817G 5G O Corn 3C, 983 C, 804C, 9) 1 2G Soybean 9H4C, 8G 4C, 8H3C, 6G Rice 9H3C, 404C, 9 2C, 7G Sorghum 3C, 983C, 7G 5G, 9G 40.8G Sparrow 90 803G, 8H6 G Sugar beet 3C, 9G 3C, 6) 1 4C, 9G 3C, 7G velvet leaf 3C, 5H2C, 302C, 28o Green foxtail 3C, 7G 2C, 5G 3G, 81 (2G o Barley 9G 2G 4C, 802C, 3G Table A Compound 53 Compound 54 Rate - kg/ha 0005 0.01 0.05 0.01 After germination Cotton 3C, 4G 2C, 3G 3C, 7H3C Morning glory 4C, 9G IC, 2G 2C ,2Hlc,lH Onion 2C,3G IH2C,3G O Golden millet 3C,6H2C,3H3C,7HO Oat 3G 0 3G O Wheat 9C6G 9C6G Corn 3C,70203C,782G Soybean 2C,4G O3C,5H2H Rice 5G 0 2C,5G O Sorghum 3C , 5003C, 7G 2G Sparrow Chiyahiki 90 50 4C, 903G Sugar beet 4C, 9G IC 3C, 7HIH Beveled Leaf 0 0 0 0 Oe Sawfish 2C, 6G 0 3G, 7G 2G Oh Wheat 6G 30 3C, 802C, 5G Table A Compound 53 Compound 54 Proportion - kg/ha 0-05 0.01 0-05 0.01 Before germination Cotton 2C, 21 (000 Morning glory 2C, 2HO00 Japanese fir tree 11 0 0 0 Ha Massage 0 0 0 0 Crab grass 0 0 0 0 Golden millet 0 0 0 0 Oat 0 0 0 0 Wheat 0 0 0 0 Corn 3 G 0 2G O soybean oo o.

Rice 3G 0 0 sorghum 2G, 2G 0 2G 2G Hiki QQ 00 Sugar beet 3H2G 2G O Velvet Leaf 0 0 0 0 Giant foxtail grass 0 0 0 0 0 Barley 0 0 0 Table A Compound 55 Compound 56 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 5C, 9 to 5C, 9G IOc 9C morning glory lOc 2C, 7G 9C2C , 4G Onamomi IOc 9CIOc 5C, 9G Hamasuge IOc 9C6C,9G 3C,8 G Mehishiba 4C, 9G 30 4G 2 G dogfish 9C9C9H3C, 9H Oats 3C, 8G 3G 9G 3 C, 6G wheat 8G 0 80 3 G Tomoro) 5C, 9G 3C, 9H5C, 9G 3C , 9H soybean 9C5C, 9G 9C5C, 9G rice 9C3C, 8G 9C2C, 5G Sorghum 90 3C, 8G 3C, 8H3C, 7G Sparrow 9-Yahi* 9C2C, 805C, 907G sugar beet 1ocloc9c9c Velvet Leaf 10c 9C9C9C Oe/:lOgusa 4C, 9G 3C, 703C, 8G 3G, 7G barley 5G 0 5G 0 Table A Compound 55 Compound 56 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 8G 3 to 2G Oa Sagao 9G 0 1c, lHO Onamomi 3C, 7H02CO Hamasuge IOE 0 9G O3G 　　　　　　　　　　　　　　　　2C,8H4G　　　　　3C,8H 2G oats 3C, 602G 3C, 5G I C wheat 5G (16G O corn 5C, 9G 3C, 704G, 9HIc soybean 3C, 8H2C, 3H2C, 481c rice 98 8H982G sorghum 9G 60 2C, 7G O Sparrow 80 3G 70 3G sugar beet 90 90 4G, 9G 8G Velvet Leaf 4C, 9G 5H3C, 5HO Oeno Korokusa 9H307G O barley 6G 0 2G, 6G 0 Table A Compound 57 Compound 58 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 3C, 9H3C, 7H4G, 8G 6G Asaga O 2C, 2G 0 10C3C, 7H Onamomi 　　　　　　9Clc, 3)! 3C, 7H4H Ha? Sedge 4C, 9G 30 5C, 9G 3C, 70 Mehishiba 3G 30 2G O goldeneye 3C, 7H3C, 4H3C, 8H2H oat 9C , 5G 0 0 wheat 8G 40 　　　　　　　0　　0h　’7　Moo　:)　C3C,8H3G　　　　 3C, 7H2C, 5G soybean 5C, 9G 4C, 9G 3C, 7H4H rice 9C3C, 802C, 7G 2G Sorghum 4C, 9G 3C, 9) 1 4C, 9 03C, 8B Sparrow Chiyahiki 6C, 904C, 904G O Sugar beet 9C5C, 9f:, 9C5C, 9G velvet Toleaf 9C3C, 8H3C, 9G IC, 2H Oninoccus 2C, 302G 20.6G O barley 　　　oo　　　　o.

Table A Compound 57 Compound 58 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 5G 2G 8G 3 G morning glory 0 3G 2C, 6G O Onamomi Ic Ic 9G 8G 8G 　　　　　　0　　0　　　　　　0　　　　　　　　　　　　　　　　3G　 0 7G O oat 2C, 7G 0 0 0 wheat 0 sc 　　　　o　　　.

Corn 3G 0 2C, 3G Oda is 0 0 0 1G 1G 6G 0 5G 0 sorghum 40 0 30.7G O Sparrow 2C, 6G O00 Sugar beet 9G 2G 9G 7G Velvet Leaf 3C, 5H02C, 3G 　　　　　　O. Gi 　　　　　　2G　　　　　0　　　　　　2G　　　　　0Table A Compound 59 Compound 60 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 2C, 3G 0 5G OA Sagao 3C, 8G IH3C, 8HIc, IH Onamomi 3C, 8H2G 3C, 8H2H Hamasuge 0 0 30 4G Mehishiba o 　　　　0　　　　　2　　　　　0　　　　　　　　　　　　　3C,8 H2H4C, 8H2C, 4H oat 90 5G 8G O wheat 40 0 5 G O corn 3C, 9H3C, 6H5C, 9G 4G soybean 4C, 9H4H3C, 804H rice 9C5C, 9G 50.9G 5C, 9G sorghum 4C, 9H3C, 6G 30.9G 3C, 7H Sparrow Chiyahiki 2C, 7G 6G 4G 4G Sato Daikon 9C3C, 5G 5C, 9H2C, 6G Velvet Tri -F 2C, 5G O2C, 7020 Giant Elephant 0 0 0 3G O barley 0 　　　　　　　　0Table A Compound 59 Compound 60 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton o.

Morning glory 0 0 0 Onamomi 0 0 0 0 Hamasuge 0 IOE 0 0 0 0 Mehishiba 0 0 0 0 0 Golden millet 0 0 0 Oat 　 　 　 0 0 0 0 0 wheat 0 0 wheat 0 0 0 Corn 0 Ic 2C, 2G O Dive OOICO Rice 3C, 6G 0 5G Omo Rokoshi 3G 0 2C, 5G O tin Menochahiki 0 0 0 0 Sugar beet 70 2G 2HO Velvet Leaf 0 0 0 0 0 giant red foxtail GI 0 0 Table A Compound 61 Compound 62 Rate - kg/ha O, 050,010,050,01 after germination Cotton IOc IOCIOC9C Morning Glory 9CIOCIOc IOC Onamomi IOc IOc IOc IOc Hamasuge IOc IOCIOc IOcMehishit< 2C, 5G sc, 9c 3G goldenrod 9H4C, 8H9C5C, 9H oats 0 0 0 60 2G wheat 0 06g 2g 2g Tou % O: L 3C, 6G 3G 5C, 9G 3C, 9H soybean 4C, 9G 5C, 909C5C, 9G rice 3C,703G 4C,9(1; 3C,7GmoO:l 3C, 8G 6G 4C, 9G 4C, 9G Suzume no Chia Hiki 3C, 7G to 5 9C8G sugar beet 10C 10C1OC1Oc Velvet Leaf IOc IOc I Oc　　　　IOc　　　　　　3C,6G　　20　　　　 5C, 9G 5G barley 2C, 4G O8G 7G Table A Compound 61 Compound 62 Rate - kg/ha O,050,010,050,01 before germination Cotton 90 6G 9 to 8G a Sagao 9G 5G 9G 6G Namomi 7H2C, 2G 9H3C, 6B Hamasuge IoE 8g IoE 3G Mehii Shiba 3C, 7G 0 3C, 803C, 6G goldenrod 8HIC9H7B oat 2G 0 3C, 702C, 3G wheat 2G O8G 5G corn 3C, 6003C, 9H3C, 7G da is 4C, 9H5, 3C, 9H3C, 8H rice 8H08G, 3C, 7G sorghum 8 to 0 3C, 9H3C, 8 to Sparrow 4C , 9G 2G 5C, 808G sugar beet 90 80 5C, 9G 4C, 9G Velpet Leaf 4 C,8G　　　30　　　4C,9G　　70 Giant foxtail 3G 0 3C, 806G barley 3C, 7 G 0 3C, 9G 3C, 7G Table A Compound 63 Compound 64 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton IOc IOCIOc 5C, 9G a Saga t IOc 9CIOCIOc Onamomi IOc IOCIOc IOc Hamasuge 9C9CIOc IOC Mehishiba 4C, 805C, 9G 2G 9C9C3C, 804G Ras wheat 3C, 8G 5G 0 0 wheat 80 5G 0 0) t% C 1:l　shiIOc　’ 9G OO dive 9C5C, 904C, 902C, 7G rice 5C, 9G 4C, 9 to 30 0 sorghum 9C9C3 C, 705G Suzume no Chiyahiki 9C5C, 905G O Keto 9 Daikon IOCIOC9CIOc Velvet Leaf IOc IOc 9C3C, 8G Giant foxtail 5C, 9G 4C, 8G 5G O barley 9G 8G 2G 0.Table A Compound 63 Compound 64 Rate-kg/ha O,050,010-050,01 before germination Cotton 9G 90 9G 9G a Sagao 9G 9G 9G 9G Namomi 9H9H3C, 5H7G Hamasuge IO E IOE 9G Mehishiba 8 G 3C, 7G 2C, 5G O Golden millet 9H9H’ 2C, 5G 2G Oat 3C, 7 03G 0 0 wheat 8H5G 0 0 corn 90 3C, 903C, 7G O soybean 9H3C, 8H3C, 5G 3G rice 　　　　　　　　8G　　　2C,602C,'5G　　　　O Sorghum 10) 1 3C, 9H3C, 7G 4G Suzume Nochia Hiki 9) 1 9G 0 0 sugar beet 909G 5C, 909G Velvet Leaf 9G 9G 8G 5G 5G 5G 0 0 barley 9G 3C, 8G 61:, 0 Table A Compound 65 Compound 66 Rate - kg/ha O, 050, 010, 050, 01 after germination '79 10c 5C, 9G IOc 5C, 9G Asaga# IOC9C9CIOC Onamomi IOc 9CIOc IOc Hamasuge 5C, 9G 0 5C, 8G 3G Mehishiba 4C, 8G 0 0 Inubi!　　　　　　　 3C, 6G 0 5C, 903C, 5H Oat 0 0 0 3G O wheat 2G 0 0 0 Corn 3C, 7H3C; 2 C, 7G O soybean 9C5C, 9G 9C9C Rice 0 0 0 Sorghum 4C, 902G 5G O Suzume no Chahiki 0 0 0 0 Sugar beet 10C10C10c9c Berhetsu Toleaf 10C9C9C9C Giant Foxtail 3G 0 0 0 Barley 5G O2G 　　　　　　　Table A Compound 65 Compound 66 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 9G 9G 9G 8G Morning glory 9G 9G 90 9G Namomi 9H889H7H Hamasuge IOE 3G 3G 3C, 803 G 2G 0 Goldeneye 5G 0 5G O oat 0 0 0 0 0 wheat 0 0 0 corn 3C, 703C, 6G 3C, 703C, 7G soybean 9G 4C, 8G 98 3C, 7H rice 0 0 0 sorghum 8 0 5G 50 3C, 4G Sparrow Chiyahiki 0 0 0 0 Sugar beet 9G 5C, 905C, 905C, 9G Velvet Leaf 5C, 9G 5G 　　　　　　　4C, 8G　　　　40 Giant Foxtail　　　　　3C, 5G0　　 3G O Barley 2G O00 Table A Compound 67 Compound 68 Rate - kg/ha O, 050, 010, 05 (after LOI germination Cotton 5C, 9G 2C, 805C, 903C, 8G Morning glory 5C, 9H3G 3C, 7G 3C, 3B Onamomi IOc 9CIOc 5C, 9 G Hamasuge 6C, 9G 9C9C9C Mehishiba 　　　　　　　　　　　0　　　　0　　　0　　　　　　　　　　　　3H2G　 　　　　　　　　　　　　　　　　　　　0　　　0　　　0　　　0　0 Wheat 0 0 0 0 Corn O O4G 3G soybean 5C, 9G 5C, 9G 4C, 9G 3C, 8G rice 0 0 0 0 sorghum 0 0 3C,602 G Suzume no Chiyahiki 3G O00 Sugar beet 9 CIOC9C3C, 7G Velvet Leaf 5C, 903C, 709C3 C, 80 Giant Foxtail Q Q Q 3G O Barley 2G 0 30 0 Table A Compound 67 Compound 68 Rate - kg/ha O,050,010,050,01 before germination Cotton 2G 0 2G O Asaga O Onamomi 0 0 0 2G 3C, 5H2C3C, 5H2C, 3G Hamasuge IO E 0 0 0 Mehishiba 0 0 3G O oats 0 0 0 0 0 wheat 　　　　　oo　　　　　o.

Corn 0 0 0 3G, 6G O-die 3C, 5H2C, 2H3C, 3HIH rice 0 0 0 5G 0 sorghum 0 3C, 6G O Sparrow 0 3G O sugar beet 80 50 　　　　　　　　　　　　　　　　　　　4G Velvet Leaf　　　　　4H04HO Logsa 0 0 0 0 Barley 0 0 2G 0 Table A Compound 69 Compound 70 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 5C, 9G 3C, 8G 7G 5G morning glory IC010C3C, 7G Onamomi IOc 5C, 9G 9C3C, 7G Hamasuge 3C, 8G 5C, 905C, 904C, 8G Mehishiba 4G 0 0 0 Golden flea 0 0 0 0 Oat 0 0 0 0 Wheat 0 0 0 Corn 3G 000 soybean 4C, 902C, 8G 2C, 310 rice 20 2G 0 0 sorghum 40 2G 0 0 Sparrow beet 0 0 0 0 Sugar beet 4C, 903C, 6G 3C, 8G 7G Velvet Leaf 3C, 902C, 5G 4C, 8G 5G Giant Greentail 0 0 0 0 Barley 0 0 0 　　　　　0Table A Compound 69 Compound 70 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 30 0 0 Morning Glory 0 0 0 0 Onamomi 3C, 5G OICO Hamasuge sc.

Fish grass 0 0 0 Golden millet 0 0 0 0 Oats 0 0 0 0 0 0 wheat 0 0 0 tow Sorghum 2G 0 2G O soybean 3C, 4H02HO rice 4G 0 0 sorghum 7G 0 0 Sugar beet 3H03G O Velvet tree F 0 2G 0 Barley 2G OO O Table A Compound 71 Compound 72 Ratio - kg/ha o, os 0101 0.05 0.01 after germination Cotton 4C, 9G 6G 4C, 905G Morning glory 5C, 9G 3C, 7G 4C, 9G 4C, 8G Onamomi IOo 9C9C2C, 6G da Is 4C, 9G 4C, 9G 5C, 909G Radish 5C, 9G 5C, 9G 9C4C, 8G Rupet Leaf 5C, 903C, 503C, 807G Table A Compound 71 Compound 72 1R total-kg/ha O,050,010,050,01 before germination Cotton 6G0 0 Morning Glory 3G0 6G 2G Onamomi 3C, 5G 3) 1 2CO Hamasuge 0 0 0 o.

Dogfish oo o.

Oats 0 0 0 0 Wheat 　　oo　　　　　o.

Corn 2G 0 0 soybeans 3C, 6G 3C, 3H3C, 7H3C, 3H rice 0 Moro Kano 0 0 0 0 0 0 0 0 Suzume no Chiyahiki 0 0 0 0 0 0 Sugar dai: l　　　5C, 9G　　4C,903C,8G　　3C,5H Velvet Leaf 2G 0 0 Oenoco Logsa 0 0 0 0 0 Barley oo o.

Table A Compound 73 Compound 74 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 9C3C, 7H3C, 705G Morning Glory 5C, 9G 7G 4C, 9H2C, 3H Onamomi 9CIOCIOc 3C, 9G Hamasuge 4C , 903C, 8G 3C, 6G O oat oo o.

Wheat 0 0 0 2G O corn 4C, 9G 7H3C, 8H3G soybean 4C, 9G 3C, 8H4C, 9H5H rice 4G 0 0 0 0 mo koshi 4G C, 3G O Suzume no Chahiki 3C, 603C, 603C, 6G O? )’7 Thailand: l/ IOC3C, 7H3C, 9G 3C, 7G velvet leaf 9C3C, 7G 3C, 7G 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 0 0 0 barley oo o.

Table A Compound 73 Compound 74 Rate - kg/ha O,050,010,050,01 before germination Cotton 0 0 Morning Glory 3H000 Onamomi 5HOIHO Hamasuge 5G 0 0 0 0 Mehishiba 0 0 0 0　　　　　　　　　　　　　　2H000 Oat 2G 0 0 0 wheat 2G 0 0 0 corn 2C, 7G O00 soybean 3C, 6H01c O rice 6G 0 0 mo Rokoshi 3G 0 2CO Suzume no Chahiki 7G 0 0 0 Sugar beet 9G 3H700 Velvet Leaf 71 0 11 0 Oyeno Kogusa 0 0 0 0 0 Oomugi 　　　　　　　　　　　　　　　O00 Table A Compound 77 Compound 78 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton 2G 0 7G O Asa Gao 38 0 2C, 3HO Onamomi 3C, 8H04C, 8HO Hamasuge oo o.

Mehishiba 　　　　　oo　　　　o.

Golden millet 0 0 0 0 oats 0 0 0 0 wheat oo o.

Corn 0 0 0 soybean IH03HO rice 3G 0 4 G Nochahiki 0 0 0 0 Sugar beet 5 H03C, 7H2G velvet leaf 0 0 0 0 Oenokorogsa 0 0 0 0 0 Barley 0 0 0 0 0 practice All Compound 77 Compound 78 Rate - kg/ha O, 050, 010, 050-01 before germination Cotton 0 0 Morning Glory 0 0 0 0 Onamomi 0 0 0 Hamasuge 0 0 0 0 0 crabgrass 0 0 0 dogfish 0 0 0 0 Oats 0 0 0 0 0 0 wheat 0 0 0 tow Sorghum 0 0 0 Soybean 0 0 0 0 0 rice 0 0 0 0 0 Moro Kano 0 0 0 0 Sparrow Chiyahiki 0 0 0 0 Sato Daifun 2H 05G O Velvet Leaf 0 0 0 0 O Oenokorogsa 0 0 0 0 0 Barley 0 0 0 0 0 Compound 79 Compound 80 Rate - kg/ha O, 050, 010, 050, 01 after germination Cotton IOC909C9C Morning Glory IOc IOCIOc 5C, 9G Onamomi IOc IOc 9C5C, 9G Hamasuge 5C, 9G 9C8G Mehishiba 5C, 903C, 703 C, 8G IC dogfish 9C9C9C3C, 911 Crow Wheat 3C, 9G 9G 3C, 8G 3C, 8G wheat 5C, 9G 5C, 903C, 9G 9 G corn 9C40, 9G 3C, 7G 5G die zu 9C9C5C, 9G 5C, 9H rice 9C9C9C3C, 8G sorghum IOc 4C, 903C, 9G 4C, 9G Suzume no Chiyahiki 6C, 905C, 9 G IOo 2C, 9G sugar beet 9C9CIOc 5C, 9G velvet leaf 9CIOc 9C4C, 8 H-oh! / :l ell Sasa IOC9C9C4C, 8G barley 9C5C, 902C, 907G Table A Compound 79 Compound 80 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 9C3C, 9G 3C, 818G Morning Glory IOC9H5C, 902C, 5H Onamomi 9H8 H9H2C, 2H Hamasuge IOE IOE 9 G　　　　　　　　　　　　　　　　　　3c, 7c　　3c, 8c　　 81 0 Golden millet 9H3C, 703C, 7G 3C, 7G oat 4C, 803C, 7G 30.7G 2C, 2G com Gi IOH2C, 8G 2C, 906G corn IOH2C, 903C, 7H3G soybean 9H9H9 H3C, 6H rice IOE 9G IOH 4G MoH:l 5C, 9G 3C, 9G 5C, 9G 3C, 7H Suzume no Chiyahiki 98 80 3C, 8G 7 G sugar beet 90 4C, 9G 5C, 907G Rubet Leaf 4C, 9G 4c, 9G 3C, 9HIC C Onigata 9H3C, 8G 3C, 703G Barley 9H9G 3C, 9G 2C, 5G Table A Compound 81 Compound 82 II combined-kg/ha o, os O,010-050,01 After germination Cotton 5C, 9G 5C, 9G 5C, 905C ,9G Asagat IOCIOc IOCIOc Onamo Mi 5C, 9H4C, 9G IOC9C Hamasuge 6C, 902C, 9G IOC5C, 9G Mehishiba 3C, 7G 3C, 605C, 803C, 7G Inubi!　　　　　　 9C4C, 7H9C4C, 9G oat 6C, 902C, 804C, 906G wheat 9G 90 9 G 9G corn o, o o 　　　　.

Dive 9C5C, 9G 4C, 8H2C, 7H rice 9C5C, 9G 9C5C, 9C% o Koshi 5C, 9G 9G 9C5C, 9G Suzume no Chiyahiki 4C, 9G 3C, 7G 5C, 9 to 8G+)? Tycon 9C4C, 9G IOc 4C, 9H Berhet Leaf 9C4C, 9H4 C, 902C, 8G Oh! /:) Ogusa 5C, 9 to 3C, 809 C5C, 9G Barley 8G 6G3C, 9G 8 G Table A Compound 81 Compound 82 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 9G 3C, 78909G morning glory 9H3C, 4H9G 2C, 8H Onamomi 9 H3G, 7H9H8H Hamasuge IOE 9G IOE 9G Mehishiba 9H5G 8HO Golden millet 3C, 8HIC9H2C, 3G oat 4C, 7G 3C, 5G 3C, 5G IC wheat 2C, 9H6G 8G O corn 2C, 3G 0 3G 0 soybean 98 4C, 7H4C, 8H3C, 6) 1 rice I OE 3C, 7G IOE 91 (Sorghum) 5C, 9G 3C, 8G 4C, 9c 4C, 9G Sparrow Nochiyahiki 9H3C, 8H9H8G Sugar beet 4C, 9 G 3C, 7H9G 8G Velvet Leaf 5C, 903 G, 7H4C, 7H’3C, 5H Giant foxtail 9H2C, 3G3C , 3G 3 and barley 4C, 80202C, 902C, 5 G Table A Compound 83 Compound 84 Ratio = kg/ha O,050-010,050,01 after germination '7 Evening 3C, 9H8H4C, 9G 2C, 3H Morning Glory IOC3C, 8H4C, 905C, 9G Onamomi 5C, 903C, 8H4C, 9 03C, 7H Hamasuge 2G 0 2C, 50 4G Mehishiba 4C, 8H3G 5C, 9G 2 C, 3G dog x 5C, 904C, 9G 9C4C, 9G oats 3C, 9G 3C, 7G 50.90 3C, 7G wheat 2C, 9G 2C, 902C, 9 G 9G corn 40.9G 30.9G 9 C40,9G soybean 5C,9G 3C,8H5C,9H 4C, 8G rice 9C5C, 9G 9C9C Moo:+ し9C4C, 9G 9C4C, 9G Sparrow 5-Yahi* 6C, 9G 70 9C9C sugar beet 9C3C, 7HIOc 5C, 9G velvet leaf 3C, 7H3C, 4H3C, 7H2H Oninoccus 5C, 9G 3C, 8G 6C, 9G 3C, 8G barley 4C, 9G 8G 5C , 9G 8G Table A Compound 83 Compound 84 Rate - kg/ha O, 050, 010, 050, 01 before germination Cotton 3G O2C, 3G O morning glory 9G 0 2G, 6H4G Onamomi 3C, 3HIc 2C, 2HO Hamasuge 0 0 0 0 0 Mehishiba 3G 0 3G 3C, 7H03C, 5G O Oats 7G 0 3C, 4G O Wheat 7G O7G O corn 3C, 9G 2C, 5G 2C, 9G 2G soybean 4C, 8H2C, 5G 3C, 783G rice IOE 6GIOHO sorghum 3C, 9G 3C, 8G 4C, 9G 3C, 9G Suzume no Chiyahiki 8G 0 8G O sugar beet 2C, 4H02C, 404G Velvet Leaf IC000 O. barley 2C, 70206G O barley 40.8G 3G 2C, 9G 3G test B Reach! Hesitation Sassafras in three large pots (diameter 25cm, depth 12.5cm) raS) Filled with sandy loam soil. In one pot is Cyperus r. otundus) tuber, crabgrass (Digitaria sanguinali) s), Cassia obtusifolia, Datura Sagao (Datura stramonium), Velvet leaf (Abut ilon theophrasti), Chenopodium al. bum), rice (Oryzas 5ativa), and teaweed (Sid a.5pinosa) was planted. In the second pot, there is a green φ foxtail ( green foxtail), (Setaria viridis), Onamo Xantium pensylvanicum, morning glory (Ipomo) ea hederacea), cotton (Gossypium hirsutum) , Johnson grass (Sorghu+++ halepense), dogfish x ( Echinochloa crus-galli), corn (Zea m. ays), soybean (Glycine maz), and giant foxtail (Set aria faberi). The third pot contains wheat (Triticum). aestivum), barley (Hordeum vulgare), Polygonum convolvulus, Polygonum convolvulus Bromus 5ecalinus) or Downey Bromus (Bromus tectorum), sugar beet (Beta vulgaris), crow Wheat (Avena fatua), Chickweed (Stellaria media) or field violet (Viola a) rvensis), blackglass (Alopec urus myosuroides), and Brassica na pus) was planted. The plants were allowed to grow for about 14 days and then treated with a solvent that was non-toxic to the plants. The dissolved compound was sprayed after germination.

Before germination Fill three inner pots (diameter 25cm, depth 12.5cm) with satsafras sandy loam soil. Filled. In one pot, there are tubers of porphyry, crabgrass, sicklebot, and chouse. I planted morning glory, velvet leaf, white locust, rice, and teaweed.

In the second pot there are green foxtails, Japanese fir, morning glories, wasps and johns. Planted songgrass, goldeneye, corn, soybeans, and red foxtail. . In the third pot, add wheat, barley, corn buckwheat, sycamore or daun. – brome, sugar beet, oat, chickweed or field violet I planted blackgrass, blackgrass, and rapeseed. In three pots, use a solvent that is non-toxic to plants. The dissolved compound was pre-emergent sprayed.

Treated plants and controls were kept in the greenhouse for approximately 24 days, then all plants were replaced with controls. The response of the plants was evaluated visually.

Response ratings are based on a scale of 0 to 100. 〇-No effect here, 10 again 0-52 indicates extermination. A dash (-) response means no test was performed. do.

Response ratings are shown in Table B.

Table B Compound 1 Ratio = g/ha 62 16 4 1 After germination Giant foxtail 30 0 0 0 herhe tsu) ! J-710010010050 Sugar beet 10 0 100 100 100 Mehishiba 3 0 0 0 0 Teaweed 90 70 50 30 Japanese morning glory 100 10 0 70 50 Rice 60 50 30 0 Onamomi 100 100 80 40 Cotton 100 100 80 30 Soybean 100 100 100 100 Golden millet 70 60 50 3 0 Oat 0000 Morning glory 100 100 100 50 Wheat 3 0 0 0 0 Siclepot 100 100 100 40 Jiyeonson grass 70 60 50 30 Hamasuge 100 100 100 50 corn 70 50 30 0 0 Yaserinpa 100 100 80 30 Brazuku glass 90 80 70 50 Arana 100 100 100 100 Omggi 50 30 30 Guri Foxtail 50 30 0 0 Sparrow Hiki 60 50 30 0 Shiroza 30 0 70 50 Chickweed 100 90 80 50 Table B Compound 1 Proportion - g/ha 250 62 16 4 Before germination Giant foxtail 70 50 30 0 Velvet Toleaf 100 90 80 70 Sugar dai: 2 /　　　　　　　100 100 100 100 Mehishiba 60 30 0 0 Teiweed 90 80 70 60 Morning Glory 90 80 70 60 Rice 100 80 50 30 Onamomi 9 0 80 70 60 Cotton 90 60 30 0 Soybean 90 70 0 0 Inupi! 100 90 60 30 Oat 90 60 30 0 Morning glory 90 80 70 60 Wheat 80 50 30 0 Siclepo Tsudo 100 70 50 30 Jiyeon Sungura 80 50 30 0 Japanese musume 100 100 70 30 Corn 60 30 0 0 Wild buckwheat 1 00 90 Bo 6G Black grass 10 0 90 70 50 Canola 100 90 80 50 Barley 70 50 30 0 Green foxtail 90 60 30 0 Suzume no Chiyahiki 90 80 70 5 0 Shiroza 100 90 80 70 boxes Be 100 95 90 80 Table B Compound 2 Proportion - g/ha 62 16 4 1 After germination Velvet leaf 10010 o 10050 Sugar beet 10 0 90 60 Seaweed 30 20 0 0 Teiweed 90 70 30 30 Stunning morning glory 100 100 90 70 rice 90 50 40 40 onamomi 100 100 70 50 wata 100 90 60 50 da Is 100 100 100 90 dogs Biet 100 100 50 Oat 80 70 40 20 Morning glory 10 0 100 70 50 Wheat 90 70 40 40 Siclebots 100 10 0 Johnson Grass 100 80 40 40 Hamusuge 100 100 60 50 Corn 90 80 5G Yasei Soba 100 100 40 40 Blackgrass 90 90 70 60 rape -100100 60 barley 80 70 50 30 gr Foxtail 80 70 40 20 Sparrow Hiki 90 70 50 20 Shiroza 100 90 50 50 Chickweed 100 90 40 0 Table 8 Compound 2 Proportion - g/ha 62 16 4 1 Before germination Giant hackweed 100 90 40 20 Verbe Tutle leaf 100 90 70 Sugar beet 100 100 90 40 Mehishiba 70 40 0 0 Tei 9 Eid 90 70 30 Morning glory 100 80 40 Rice 100 90 80 40 Onion fir 80 70 50 30 Cotton 100 70 50 3 0 soybean 90 80 60 50 dogfish D 100 100 90 40 Oat 80 50 30 0 Morning glory 100 80 60 Wheat 90 60 30 0 Siclepot 8040 Jyo Japanese grass 100 100 80 80 Japanese horseradish 100 40 30 Corn 100 50 40 20 Wild buckwheat 100 100 80 30 Black grass 10 0 90 40 10 Oilseed rape 100 100 70 30 Barley 70 70 40 30 Green Foxtail 100 80 40 10 Sparrow 100 90 70 40 Shiroza 100 100 100 60 Chickweed 100 90 80 20 Table B Compound 3 Proportion - g7ha 62 16 4 1 After germination Velvet Leaf 100100806゜Sugar Daikon 100 100 80 50 Mehishiba 50 40. 20 0 Teiweed 90 70 50 40 Japanese morning glory 100 90 80 50 Rice 90 80 80 50 Onagumomi 100 100 100 Cotton 100 90 80 30 Soybean 100 100 100 100 Golden millet 100 100 90 50 Oats 100 100 70 40 Morning glory 100 90 70 40 Wheat 100 100 80 50 Sicle Pot 100 100 Jeongson Grass 100 100 80 40 Persimmon 100 100 7 0 50 Corn 100 100 . 90 50 Yasei Soba 100 100 70 30 Black Grass 100 90 80 70 A Burana 100 100 100 70 Oh Wheat 90 80 70 40 green wheat Foxtail 70 70 40 20 Sparrow 90 90 70 40 Whiteweed 100 90 70 40 Chickweed 10 0 80 50 30 Table B Compound 3 Rate - g/ha 62 16 4 1 Before germination Giant foxtail 100 90 70 20 Berbe Tutle Leaf 100 100 90 30 Sugar Dairy Con 100 100 100 90 Mehishiba 80 70 40 40 Teiweed 90 80 40 20 Morning Glory 100 100 80 60 Rice 100 100 90 90 Onamomi 9 0 80 80 70 Cotton 100 90 80 50 Soybeans 90 8 0 70 60 Golden millet 100 100 90 40 Oats 90 80 70 60 Morning Glory 100 70 50 40 Wheat 90 80 70 30 Shiku Reported 90 80 50 0 Jiyoung Song Ras 100 100 90 40 Japanese horseradish 100 100 80 30 Corn 100 100 70 50 Wild buckwheat 100 100 80 80 Black grass 100 90 90 70 Brassica 10 0 100 100 100 Barley 9 0 80 70 60 Green Foxtail 100 80 60 0 Sparrowtail 100 90 80 70 Shiroza 100 100 100 90 Chickweed 90 90 80 70 Table B Compound 4 Proportion - g/ha 62 16 4 1 After germination Velvet leaf 100 100 60 30 Sat Japanese radish 100 100 Japanese radish 20 0 0 0 Teiweed 80 40 20 0 Japanese radish 100 100 80 50 rice 50 40 20 10 Onamomi 100 100 100 50 Cotton 90 80 5 0 0 Soybean 100 50 20 0 Golden Millet 70 30 0 0 Ka Rasmugi 30 0 0 0 Morning glory 100 100 80 20 Wheat 50 20 10 0 Siclepot 90 90 40 0 John's grass 70 60 20 20 Perilla 100 100 70 50 Corn 50 40 20 0 Wild buckwheat 100 100 90 Blackgrass 70 40 20 Brassica 100 100 100 100 Barley 50 40 20 0 Green Foxtail 40 20 10 0 Tin 80 50 20 0 Shiroza 100 100 Chickweed 9050 Table 8 Compound 4 Proportion - g/ha 250 62 16 4 Before germination Giant chickweed 90 80 60 30 Verbe Tsutorif 100 100 80 70 Sato 9 ties Con1001009o80 Mehishiba 70 60 40 0 Tee Weed 90 90 70 30 Chiyosenasa Gao 100 100 80 70 Rice 100 100 100 70 Onamomi 90 90 80 70 Cotton 100 90 60 40 Soybean 8 0 70 50 40 Inubi L 100 100 70 50 Oats 70 7 0 20 0 Asagaa* 100 100 90 70 Wheat 50 30 2 0 10 Siclepot 100 100 80 Ji Jonsson Grass 100 90 70 50 Japanese Red Grass 100 100 90 80 Corn 100 60 40 40 Yasei Soba 100 100 90 60 Black Grass 100 90 80 40 Canola 100 1 00 100 90 Barley 80 70 40 10 Green Foxtail 90 80 50 30 Sparrowtail 90 70 4 0 Shiroza 100 100 100 90 Chickweed 90 80 50 Table B Compound 5 Ratio - g/ha 62 16 4 1 After germination Velvet leaf 100 100 60 0 Sat Japanese radish 100 100 80 40 Japanese radish 20 0 0 0 Teiweed 90 60 20 Japanese morning glory 100 100 80 30 Rice 1 0 0 0 0 Onamia 100 100 100 40 cotton 90 80 80 30 soybean 100 100 100 90 Golden millet 0000 Oat 0000 Morning glory 100 100 60 40 Wheat 30 30 20 10 Sicle Pot 100 90 2 0 Johnson Grass 20 0 0 0 Hama Carex 100 100 40 30 Corn Koshi 30 20 0 0 Wild buckwheat 90 90 60 30 Black grass 40 20 20 0 Brassica 100 100 90 60 Barley 1 0 0 0 0 Green foxtail 10 0 0 0 Sparrow ooo.

Shiroza 100 100 100 70ha Kobe 90 80 70 30 Table B Compound 5 Proportion - g/ha 250 62 16 4 Before germination Giant foxtail 90 40 10 0 Berbe Tutle Leaf 100 100 80 40 Sugar Bee -:1> 100 100 100 100 Mehi Shiva 80 40 20 0 Teiwi 90 80 50 40 Morning Glory 100 70 50 Rice 90 40 40 0 Onion 90 80 70 40 Cotton 100 90 60 30 Soybean 90 9 0 80 60 Dog Bee! 100 70 40 30 Oat 40 10 0 0 Morning glory 100 100 90 40 Wheat 10 0 0 0 Gulbotsud 100 90 90 60 Jiyeonseo Japanese grass 90 80 50 30 Corn grass 100 90 70 Corn 90 50 50 10 Wild buckwheat 100 100 100 80 Black grass 90 80 50 20 Canola 10 0 100 1 00 20 Barley 40 30 10 0 Green Foxtail 90 40 20 0 Sparrowtail 60 40 20 20 Shiroza 100 100 10 0 90 Chickweed 100 90 80 60 Table B Compound 6 Proportion - g/ha 250 62 16 4 After germination Berberatory y 100 100 90 40 sa Radish 100 100 100 mehshi Ba 10 0 0 0 Do 90 60 40 30 Morning Glory 90 90 60 40 Rice 10 0 0 0 Onomimi 1 00 100 80 40 Cotton 90 80 80 20 Soybean 100 100 100 100 Golden millet 40 2 0 0 0 Oat 10 0 0 0 Morning glory 100 100 90 80 Wheat 10 0 0 0 Sicklepot 100 90 80 Jeongsong Grass S 0 0 0 0 Hamusuge 100 100 40 30 Corn 50 10 Yasei Soba 100 100 60 40 Black Grass 50 30 20 0 Abu Lana 100 90 Barley 0 0 0 0 Green Foxtay Le 0 0 0 0 Sparrow grass 30 0 0 0 Shiroza 100 1 00 100 100 Chickweed 100 90 60 Table 8 Compound 6 Ratio - g/ha 250 62 16 4 Before germination Giant foxtail 60 20 10 0 velvet Toleaf 100 100 60 40 Sugar Daiko 100 100 100 80 crabgrass 50 30 0 0 teaweed 80 70 60 30 morning glory 90 80 40 40 rice 6 0 40 20 0 Japanese fir 90 70 50 50 cotton 100 10 0 70 20 Soybean 90 80 70 50 Golden millet 100 90 40 20 Oat 10 0 0 0a Sagao 100 90 90 50 Wheat 10 0 0 0 Shikurubotsudo 100 80 50 Jiyeonson Grass 50 50 30 20 Red-eye 90 90 40 30 Corn 100 40 30 10 Yasei Soba 100 100 100 70 black grass 80 70 30 0 rape 100 100 90 30 barley 20 0 0 0 g Lean Foxtail 60 20 0 0 Sparrow Yahiki 50 30 10 0 Shiroza 100 100 100 80 Chickweed 100 100 90 60 Table B Compound 7 Ratio - g/ha 250 62 16 4 After germination Giant foxtail 50 30 20 0 Berbe Tree leaf 100 100 90 80 sugar radish 100 100 100 100 meshi Ba 30 20 0 0 Teiwi Do 90 90 80 50 Morning Glory 100 100 90 90 Rice 100 100 50 10 Onomimi 90 40 20 0 Cotton 90 80 80 70 Soybean 100 100 100 90 Golden millet 90 70 50 10 Oat 50 40 30 20 Morning glory 100 100 90 85 Wheat 0 0 0 0 Siclebots 100 100 100 80 Jiyongson Grass 60 40 30 0 Hamusuge 0 0 0 0 Corn 90 80 80 40 Yaseimpa 100 100 100 100 Blackgrass 70 50 30 20 Brassica 90 90 50 30 Barley 10 0 0 0 Green Foxtail 80 50 20 0 Shiroza 100 100 10 0 90 Chickweed 100 90 80 60 Downey Brome 60 40 20 0Table B Compound 7 Proportion - g /ha 250 62 16 Before germination Giant foxtail 70 40 20 Velvet Tree leaf 100 90 80 Sugar beet 100 100 100 Mehishiba 80 70 30 Teiweed 100 90 90 Stingray 100 50 30 Rice 100 90 80 Onion 80 3 0 0 cotton 100 90 80 soybean 100 100 70 i Nubie 100 80 70 Oats 70 40 30 Morning Glory 100 100 100 Wheat 1000 Shikurupotsu 100 70 Jiyeonso Grass 50 50 30 Corn 100 100 60 Wild buckwheat 100 100 100 Black grass 70 50 40 Canola 90 90 60 Barley 30 20 10 Green grass Foxtail 90 80 40 Shiroza 100 - 100 90ha Kobe 90 80 60 Downey Bro 90 60 30 Table B Compound 8 Rate-ag/ha 250 62 16 4 shots After bud Physalis 90 40 20 Verbe Tree leaf 100 100 100 100 sugar radish 100 100 100 100 mehshi Ba 70 40 40 30 twi Do 100 100 90 40 Chiyosenasaga O 100 100 90 70 Rice 50 40 30 10 Onamomi 100 100 100 100 Cotton 100 100 100 90 Soybean 100 100 100 90 Golden millet 100 100 100 30 Oat 7 0 5 () 30 0 Morning glory 100 100 90 40Wheat 50 30 0 0Siclebots 100 100 90 80Jeonson Grass 90 80 40 0Horsegrass 100 100 10 0 100Corn 50 40 30 10 Yasei Soba 100 100 100 90 Black Grass 90 70 50 30 A Burana 100 100 100 100 o Barley 30 0 0 0 Green Foxtail 100 80 50 30 Shiroza 100 100 90 80 Hafbe 100 100 80 50 Downy Brome 90 70 60 50 Table 8 Compound 8 Rate - g/ha 250 62 16 4 Germination Previous Giant Elephant 90 80 70 60 velvet Tree leaf 90 70 50 30 Sugar beet 100 100 90 80 Crabweed 70 50 30 0 Teiweed 90 70 50 30 Teaweed 7 0 60 50 30 Rice 100 90 70 30 Onion 90 7 0 50 30 cotton 70 50 30 0 soybean 90 80 60 30 Golden millet 90 80 50 3 0 Oat 50 40 30 0 Morning moth O 90 80 60 30 Wheat 50 30 20 0 Shikurubotsudo 100 100 70 50 Jyongson Grass 70 50 30 0 Red-and-white mullet 100 100 100 30 Corn 90 60 0 0 Wild buckwheat 100　 100 90 70 Black grass 80 7 0 60 50 Brassica 100 100 100 90 Barley 50 30 2 0 0 Green Foxtail 90 70 50 30 Shiroza 100 90 80 60 Ha Kobe 100 100 90 60 Downey Brome 90 70 50 30 Table B Compound 9 Rate = g/ha 250 62 16 4 After germination Giant foxtail 70 50 40 30 Berbe Tsutorif 100 100 100 80 sugar Ikon 100 100 90 60 Mehishiba 50 50 40 0 Teiweed 100 100 90 40 Morning Glory 100 100 90 80 Rice 90 80 40 0 Onamomi 1 00 100 100 90 cotton 10 0 100 90 60 soybean 100 100 90 60 Golden millet 100 100 70 50 Oat 70 50 30 0 Morning glory 100 100 100 90 Wheat 60 30 0 0 Sicle Pot 90 90 50 20 Jiyeonson Grass 90 80 60 30 Hamas Ge 100 100 100 40 Tomoro Kosi 100 100 70 20 Yasei Soba 100 100 10G 100 Black Kug Russ 90 80 70 60 Brassica 100 100 100 100 Barley 60 30 0 0 Green Foxtay Le 100 100 70 20 Shiloza 100 100 90 50 Chickweed 10 0 100 90 60 Downey Brome 100 70 50 30 Table 8 Compound 11 Rate - g/ha, 250 62 16 Before germination Sawfish 80 70 50 Velvet Tree leaf 90 70 50 Sugar beet 100 100 100 Seaweed 3000 Teaweed 90 70 50 Stunning morning glory 90 70 60i Ne 100 90 70 Onamo Mi 90 80 70 Cotton 70 30 0 Soybean 3000 Golden millet 80 50 30 Oat 4000 Morning glory 90 80 60 Wheat 0 0 0 Siclepot 50 30 0 Johnson grass 50 30 0 Hama Sedge 100 90 60 Corn 3000 Wild buckwheat 100 100 100 Blackgrass 90 60 30 Brassica 100 100 100 Barley 0 0 0 Green Foxtail 80 50 30 Whiteberry 100 90 70 Chickweed 9 0 80 70 Downey Brome 70 50 30 Table B Compound 12 Rate - g/ha 62 16 4 1 Post-germination Giant Yellowtail 0 0 0 0 Velvet Tree Fu 100 100 90 60 sugar beet 100 100 100 90 crabgrass 40 20 0 0 teaweed 90 60 40 20 morning glory 1 00 100 90 80 rice 10 0 0 0 Onamomi 100 100 100 100 cotton 100 90 70 50 soybeans 100 100 　　　100 90 dogfish ooo.

Oats 30 20 0 Morning glory 100 90 70 50 wheat 　　　　　　20　　　0　　　0　　　　　　　　　　 100 80 40 20 Jiyeonson Glass ooooo.

Hamasuge 100 50 30 0 Tomo Rokoshi 40 20 0 Yasei Soba 　　　　　　100　　100　　100　　90 Black Glass 50 40 20 0 rape 100 100 100 90 barley 　　　ooo.

Clean Foxtail 20 0 0 Shiroza 100 60 40 20 Chickweed 　　　　100　100　　90　　85 Downey Prome 　 　 0 0 0 0 Table B Compound 12 Rate - g/ha 250 62 16 before germination Giant foxtail grass 50 20 0 velvet Leaf 100 90 90 sugar beet 　　　　100　　　100　　　　100 Mehishiba　　　　　 　　　　　　　　　　　　　　　30　　　　　　　30 teweed　　　　　　 100 80 80 Japanese morning glory 100 90 90 rice 80 50 20 Onamomi 100 100 90 cotton 100 90 90 soybeans 100 100 90 Golden millet 40 30 0 oat 3000 morning glories 100 100 100 wheat 0 0 　　　　　　　　　　　　　100　　　90　　　7 0 Jiyeon Song Glass 40 20 0 Hamasuge 50 30 0 corn 100 40 30 100 100 100 Black Glass 60 40 0 rapeseed 100 100 100 barley 2000 gr Foxtail 70 50 20 Shiroza 100 100 90 Chickweed 90 85 70 Downey Brohm 5 0 30 0 Table B Compound 13 Rate - g/ha 250 62 16 4 Germination rear Giant foxtail grass 0 0 0 velvet tree 100 100 100 90 sugar daiko 100 100 100 90 mehshiba 0 0 0 0 Tee Weed 　100　　80　　60　　　40 Morning Glory　　　　1 00 100 90 90 rice 10 0 0 0 Onamomi 100 100 100 80 cotton 90 90 80 70 soybeans 100 100 100 100 Inibie 30 10 0 0 oats 20 0 0 0 oats 0 morning glory 100 100 100 90 wheat 10 0 0 0 shiku Lubotsudo 100 100 90 70 Jiyeonseo Glasses 0 0 0 0 0 Hamasuge 100 40 20 0 corn 40 20 0 0 Yaseinba 10 0 100 90 80 Black Glass 20 0 0 0 Brassica 100 10 0 100 100 barley 0 0 0 0 0 Green Foxtail 20 0 0 0 0 Shiroza 100 100 80 60 Chickweed 100 100 90 80 Downy ・Blohm 40 20 0 Table 8 Compound 13 Rate - g/ha 250 62 16 before germination Giant foxtail grass 50 20 0 velvet Leaf 100 90 90 sugar beet 　　　　100　　　100　　　　100 Mehishiba　　　　　 　　　　　　　　　　　　20　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 1009090 Japanese morning glory 100 90 80 rice 70 40 10 rice Namomi 100 90 80 cotton 100 80 soybeans 80 goldeneye 40 20 0 Oats 40 20 0 Morning Glory 100 100 90 wheat 0 0 0 sicle pot 100 70 50 Jiyeon Song Glass 40 20 0 Hamasuge 100 50 corn 1 00 70 30 Yasei Sopa 100 100 100 Black Glass 30 20 0 rapeseed 100 100 100 barley 0 0 0 Green Foxtail 50 30 0 Shiroza 100 100 90 Hafbe 90 Downey Brohm 90 Downey Brohm 60 30 0 Table B Compound 20 Ratio - g/ha 62 16 4 1 after germination Velvet leaf 100 100 80 70 sa Radish radish 100 100 100 60 Mehi Shiba 10 0 0 0 80 60 40 10 Japanese morning glory 100 80 40 0 rice 40 40 30 10 Onamomi 100 100 100 80 cotton 50 4Q soybean 100 　　　　　100　　100 Goldenfish　　　　　　　　　　　90　　　50　 50 20 oats 10 0 0 0 morning glory 100 100 80 40 wheat 40 40 20 10 shiku Lubotsudo 100 90 50 20 Jiyeonson Glass 100 60 40 20 Hamasuge 100 50 50 30 corn 10 0 90 70 20 Yasei Soba 100 80 40 0 Black Glass 80 70 60 0 rapeseed 100 100 100 70 barley 60 60 30 10 Green, 7 Onk Tail 30 10 0 Sparrow Chiyahiki 80 70 30 Shiroza 90 70 60 0 Chickweed 100 100 80 40 Table B Compound 20 Rate = g/ha 250 62 16 4 Germination Before Giant foxtail grass 80 40 20 10 velvet Toleaf 100 100 70 20 sugar daiko 100 100 80 80 Mehishiba 50 300 0 Taise Weed 　　　　90　　80　　40　　　　　　　　　　　　　　　　　　　 90 90 80 50 rice 90 70 60 40 Onamomi 90 8 0 70 60 cotton 70 60 50 40 soybeans 80 70 20 20 Golden millet 100 100 50 30 Oats 20 0 0 Asa Gao 100 90 90 50 Fumugi 70 40 10 0 sicle pots 　　　　100　　90　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 100 90 80 50 Hamasuge 90 70 60 50 corn 80 70 10 10 Yasei Soba 100 10G 80 40 Black Glass 90 90 40 20 rapeseed 100 100 90 40 barley 50 30 30 20 green, 7 oxtail 80 40 30 10 Suzume no Chiyahiki 90 80 70 40 Shiroza 100 100 100 90 Chickweed 100 100 90 60 Table B Compound 23 Ratio - g/h3 62 16 4 1 after germination Velvet leaf 90 40 30 20 sugar Radish 100 90 7G Mehishiba 　　　　　20　　　0　　　0　　　　　　　　　　　　　　　　　　　　　　 　1000 Morning Glory　　　　　　　　　70　　　30　　 0 rice 40 10 10 0 ona Fir 90 80 50 20 cotton 30 20 0 0 soybeans 　　　　　100　　90　　50　　　20 Goldeneye 90 80 40 0 Oats 70 60 30 0 morning glory 100 70 40 0 wheat 50 30 30 0 cycle potsdo 30 Zeyon -songrass 100 40 30 20 Hamasuge 30 30 20 0 corn 100 70 30 0 Yasei Soba 80 60 0 0 Black Glass 70 3 0 30 0 rapeseed 100 90 70 40 Barley 40 30 20 10 Green Foxtail 20 0 0 0 Suzume no Chiyahiki 80 40 0 Shiroza 100 100 40 0 Chickweed 　 　 　 　 70 　 60 　 　 　 　 0Table 8 Compound 23 Ratio-g/ha 250 62 16 4 Before germination Giant foxtail grass 100 80 30 0 velvet Tree leaf 100 80 60 40 sugar daiko 100 90 70 50 Mehishiba 90 80 30 0 Teeweed 　　　50 Japanese morning glory 90 40 30 rice 100 100 90 40 Onamomi 80 60 60 40 cotton 90 70 40 0 soybeans 　　　　　90　　80　　60　　20 Goldenfish　　　　　　　 100 50 30 0 Oats 60 20 20 0 morning glory 100 70 60 30 wheat 70 30 20 10 Cycle Potsdo 80 Jiyon Songrass 100 100 90 30 Hamasuge 　　　　80　　70　　. 70 30 corn 50 30 0 Yasei Soba 1 00 100 60. 30 blank glasses 100 100 20 0 rapeseed 100 100 50 0 Barley 70 50 30 20 Green Foxtail 100 80 30 0 Sparrow Chiyahiki 100 50 10 0 Shiroza 100 100 90 40 Chickweed 90 70 40 Table B Compound 25 Rate - g/ha 62 16 4 1 germination rear Giant foxtail grass 30 0 0 velvet Tree leaf 100 90 60 30 sugar daisies Con 100 100 100 90 Mehishiba 30 0 0 　　　　70　　50　　30　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 100 90 70 50 rice 80 60 30 0 Onamomi 80 70 50 30 cotton 100 8 0 60 30 soybeans 100 100 90 50 Golden millet 70 50 30 0 oats 50 30 0 0 oats 0 morning glory 100 100 90 40 Wheat 40 20 0 0 Shikurupotsu Do 100 100 90 Jiyoung song Russ 70 50 30 0 Hayasuge 100 100 50 30 corn 　　　　　70　　60　　50　　　30 Yasei Soba　　　　　　　 90 70 50 30 blank glass 90 80 70 50 rapeseed 100 1 00 100 100 Barley 50 30 0 Green Foxtail 50 30 0 0 Sparrow Chiyahiki 90 70 50 30 Shiroza 90 80 70 60 Ha Kobe 100 90 70 50 Table B Compound 25 Ratio "g/ha" 62 16 4 1 before germination Giant foxtail grass 100 60 30 0 velvet Tree Leaf 100 60 30 0 Sugar Daiko 100 100 90 70 mehshiba 60 30 0 　　　　　　60　　30　　　0　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 80 60 50 30 rice 90 60 0 0 Onamomi 60 5 0 40 30 cotton 0 0 0 0 0 soybeans 60 0 0 0 Golden millet 60 30 0 0 Karasum Gi 60 30 0 0 Society 90 70 50 30 Humgi 40 0 0 0 Shikurubotsud 1 00 90 30 0 Jiyeonson Glass 70 50 30 0 Hamasuge 90 50 30 0 corn 0 0 0 0 Yasei Soba 90 70 50 30 bucks Rack grass 90 70 50 30 rape 100 90 70 30 Barley 60 30 0 Green Foxte Rule 70-50 30 0 Suzume no Chiyahiki 70 30 0 0 Shiroza 100 100 100 100 Chickweed 100 9 0 70 50 Table B Compound 26 Ratio - ag/ha 62 16 4 1 shot After bud Velvet leaf 100 100 50 20 sa Radish radish 100 90 80 60 radish 70 30 20 20 Teeweed 　　　　　　70　　50　　　40 Morning Glory　　　　1 00 90 80 30 rice 90 80 70 40 Onamomi 100 1 00 70 40 cotton 100 90 40 40 soybeans 100 100 100 60 Golden millet 100 90 8 0 40 oats 80 70 40 20 morning glory 100 100 80 30 Wheat 90 70 30 20 wheat Tsudo 100 100 80 20 Jiyoung songs Russ 90 80 50 40 Hamasuge 100 100 70 40 corn 100 100 90 70 Yasei Sopa 100 50 30 Black Glass 9 0 80 70 50 Brassica 100 100 90 80 Barley 80 70 50 30 Green Foxtail 90 80 3 0 0 Sparrow Chiyahiki 90 80 70 70 Shiroza 90 80 60 60 box Table B 90 50 Compound 26 Ratio = g/ha 62 16 4 1 before germination Giant foxtail grass 100 90 60 20 velvet Tree leaf 100 80 0 sugar beet 　　　　　　100　　90　　90　　　70 Mehishiba　　　　 　　　　90　　50　　50　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 　 100 70 30 0 Stingray morning glory 1 00 90 80 40 rice 100 90 80 40 Onamomi 90 80 50 30 cotton 90 50 30 0 soybeans 80 60 20 0 Inubini 100 100 90 30 oats 80 70 50 20 a Sagao 100 90 50 50 wheat 80 50 20 10 sicle pots 100 100 80 30 Jiyeonson Glass 90 40 30 Hamasuge 100 50 30 10 corn 100 90 70 50 Yasei Soba 100 90 80 30 Black Glass 100 100 100 40 Brassica 70 50 30 20 barley 100 90 50 1 0 Green Foxtail 100 90 80 60 Tin Menochiyahiki 100 100 90 90 Shiroza 　　　　　　　　　100　　90　　80　　40ノ\cope Table B Compound 27 Ratio - g/ha 62 16 4 1 after germination Velvet leaf 100 90 70 70 sa Red sea bream: 100 100 50 seaweed 　　　　　60　　60　　20　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 　 10 0 100 40 0 rice 100 100 70 60 Onamomi 100 100 70 40 Golden millet 100 100 90 4 0 Oats 80 70 60 20 Asaga o 90 80 70 40 wheat 　　　　　　　　80　　70　　70　　　30 sicle pots 100 100 40ji5i 7’/’/g 57.　　　　　100　　100　　80　　60/%? X game 　　　　　　100　　100　　90　　40 corn 100 100 80 50 Yasei Soba 90 70 40 black glass 100 90 80 70 Brassica 10 0 100 90 70 Barley 90 60 60 3G Green Foxtail 90 80 40 0 Sparrow Chiyahiki 90 90 9 0 70 Shiroza 80 70 40 0 Chickweed 100 90 20 Table B Compound 27 Ratio = g/ha 62 16 4 1 before germination Giant foxtail grass 100 80 70 30 velvet Tree leaf 90 90 80 30 sugar daiko 100 90 90 70 Mehishiba 　　　　　80　　40　　20　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 　 90 80 50 morning glories 90 80 70 40 rice 1 00 90 60 Onamomi 90 80 70 60 cotton 90 70 5 0 40 soybeans 80 60 50 20 dogfish 100 90 70 40 ka Rasmugi 80 70 60 10 Morning Glory 　 　 　 　 　 80 　 70 　 　 　 40 wheat 100 80 60 10 sickle bottles 100 80 40 10 Jiyeonson Glass 100 90 80 60 Hamasuge 10 0 80 70 20 corn 100 100 70 40 Yasei Soba 100 8 0 70 60 Black Glass 100 100 70 40 rapeseed 100 100 80 40 Barley 80 70 40 20 Green Foxtail 100 80 60 20 Sparrow Chiyahiki 100 90 90 60 Shiroza 　　　　　　　　　100　　100　　90　　70 Huffbe 　　　　　　　90　　90　　80　　30 Table B Compound 28 Rate - g/ha 62 1g 4 1 germination rear Velvet Leaf 100 90 40 0 Sato Radish 100 90 80 70 Mehishiba 20 0 0 Q O teaweed 　　　　　　　　60　　　30　　20　　　　0. 100 80 80 rice 80 50 20 10 Onamomi 100 100 70 30 cotton 80 80 50 3G soybeans 80 70 2 0 20 Goldenflies 70 40 10 0 oats 40 10 morning glories 100 100 70 20 wheat 　　　　　40　　30　　30　　　　　　　　　　　　　　　　　 100 70 20 Jiyeonson Glass 6 0″:53030 Hamasuge 100 100 3 0 20 corn 50 30 20 0 Yasei Soba 100 80 60 40 Blackgrass 70 60 40 0 Brassica -1001009070 Barley 1 0 10 0 0 Green Foxtail 40 30 0 0 Sparrow Chiyahiki 90 70 40 0 Shiroza 70 40 30 Chickweed 4000 Table 8 Compound 28 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 40 20 0 0 velvet Toleaf 100 90 70 30 sugar beet 　　　　　　100　　100　　70　　70 Mehishiba　　 60 20 0 0 Taise Weed 　　　　　80　　80　　70　　　30 Morning Glory　　　　　 100 90 80 50 rice 10 0 90 70 20 Onamomi 90 80 70 50 cotton 90 70 50 20 soybeans 70 50 4 0 20 Dogfish 100 90 70 40 oats 30 20 0 0 a Sagao 100 90 70 40 wheat 　　　　　　　　　40　　20　　10　　0　　　　　　　 　　　　　　90　　30　　30 Jyeonson Glass　　　　　9 0 90 40 20 Hamasuge 100 90 40 0 corn 90 40 10 0 Yasei Soba 100 90 80 40 Black Glass 80 40 10 rapeseed 100 100 90 5 0 barley 40 20 10 10 gr Foxtail 50 40 10 0 Sparrow Ki 90 70 50 10 Shiroza 100 90 90 70 Chickweed 90 80 70 Table 30 B Compound 29 Rate - g/ha 62 16 4 1 germination rear Teeweed 90 80 20 20 Morning glory 100 100 90 30 rice 10 0 0 0 Onamomi 100 100 90 40 cotton 　　　　90　　90　　70　　20 soybeans 100 100 100 80 Morning Glory 100 100 80 40 wheat 1 0 10 10 0 Shikurubotsudo 100 100 100 20 corn 90 50 10 0 Yasei Soba 100 50 blank glasses 90 80 70 20 Brassica 100 100 100 70 Barley 20 10 0 0 Green Foxtail 40 0 0 0 Suzume no Chiyahiki 30 0 0 0 Shiroza 100 100 90 80 Chickweed 100 100 80 30 Table B Compound 29 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 80 70 20 0 velvet Tsutorif 100 100 90 50 sugar daisies Con 100 100 100 70 Mehishiba 70 60 30 20 Teeweed 　　　　　100　　80　　70　　　　　30 Morning Glory　 100 90 80 60 rice 90 40 10 0 Onamomi 90 90 80 60 cotton 100 100 90 70 soybeans 100 1 00 80 60 Goldeneye 90 70 30 oats 20 0 0 0 morning glory 100 100 100 90 Wheat 0 0 0 Shikurubo Tsudo 100 100 90 Jiyeonson Glass 80 70 0 Hamasuge 1 00 90 40 20 corn 100 50 20 10 Yasei Soba 100 1 00 90 70 Black Glass 90 80 70 40 Brassica 100 100 1 00 40 barley 50 20 0 0 Green-Foxtail 80 60 0 0 s Zumenochiyahiki 80 50 30 20 Shiroza 100 100 100 90 Chickweed 100 90 80 70 Table B Compound 30 Ratio - g/ha 62 16 4 1 after germination Velvet Leaf 100 100 70 40 Sat Udaikon 100 100 90 60 Mehishiba 　　　　　　　　　　　　　　　　　　　　　　 80 　　　60　　40　　10 St. morning glory 　　　　　　　　100　　8 0 50 20 rice 0 0 0 0 0 Onamomi 100 100 50 30 cotton 90 80 50 30 Soybeans 100 100 100 80 Nuvier 30 to 0 0 crow Wheat 30 10 0 Morning glory 100 90 80 30 wheat 　　　　　20　　20　　10　　　10 Sicle Bots　　　　　　 100 100 Jiyeon Song Glass 0 0 0 Hamasuge 100 40 20 20 Tomo Rokosi 40 30 10 0 Yasei Soba 100 90 50 black glass 3000 rapeseed 100 100 80 70 barley 20 10 0 0 Green Foxtail 0 0 0 Sparrow Nochiyahiki 20 0 0 Shiroza 100 90 70 50 Chickweed 　　　　100　　100　　90Table 3 Compound 30 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 40 20 0 0 velvet Toleaf 100 100 90 70 sugar bee Con 100 100 100 70 Mehishiba 70 20 00 Taise Weed 　　　　　90　　80　　70　　　50 Stunning Morning Glory　　 100 90 80 20 rice 50 10 0 0 Onamomi 90 80 70 50 cotton 100 1 00 80 40 soybeans 90 80 70 50 Golden millet 100 80 50 0 oats 30 0 0 0 0 morning glory 100 100 100 0 humugi 10 0 0 cycles Botsudo 100 90 Jiyeonson Glass 7 0 40 0 0 Hamasuge 90 50 30 corn 90 20 10 Yasei Sopa 100 100 90 70 Black Glass 70 40 30 0 Brassica 100 100 100 40 Barley 20 0 0 0 green Foxtail 40 10 0 0 Sparrow 40 10 10 0 Shiroza 100 100 80 80 Chickweed 1 00 90 80 Table B Compound 31 Ratio = g/ha 250 62 16 4 after germination Giant foxtail grass 50 40 30 0 velvet Tree leaf 100 100 70 60 sugar dai Con 100 100 100 70 Mehishiba 0 0 0 0 Tee Weed 70 50 30 0 Japanese morning glory 10 0 90 80 50 rice 50 40 30 0 Onamomi 100 90 80 70 cotton 70 50 40 30 soybeans 100 90 80 60 Golden millet 80 70 50 30 Oat 60 30 0 G Asaga o 100 80 60 30 wheat 　　　　　　　　50　　30　　　0　　　　　　　　　　　　　 　　　　　90　　70　　60　　30 Jyeonson Grass　　　　　 70 50 30 0 Hamasuge 90 70 50 30 corn 0 0 0 0 Wild buckwheat 100 100 1 00 70 Black Glass 100 90 70 50 rapeseed 100 100 100 100 barley 40 30 20 0 Green Foxtail 50 40 30 0 Shiroza 100 100 70 50 Chickweed 100 100 70 50 Downey Brohm 70 30 0 Table 8 Compound 32 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 90 60 30 0 velvet Tree leaf 90 80 70 50 sugar beet 　　　　　　100　　100　　100　　90 Mehishiba　　 　　　　　　80　　50　　30　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　〇 　　　　90　　80　　70　　　40 Morning Glory　　　　　 100 100 90 70 rice 1 00 100 90 70 Onamomi 90 80 70 60 cotton 90 80 60 30 soybeans 90 70 50 0 Golden millet 100 95 90 85 Oats 90 80 70 5 0 morning glory 100 90 80 70 com Gi 90 70 50 30 sicle pots 100 100 80 30 Jiyeonson glass 100 90 85 80 Hamasuge 100 100 80 30 corn 100 100 90 50 Yasei Soba 100 90 80 70 Black Glass 100 95 90 85 rape 100 100 100 100 barley 90 7 0 60 50 Green Foxtail 90 60 30 0 Shiroza 100 100 90 70 Chickweed 100 95 90 8 5 Downey Brohm 100 100 100 90 Table B Compound 34 Rate - g/ha 250 62 16 4 Germination rear Giant foxtail grass 50 30 0 berbe Tree leaf 100 100 90 60 sugar dai Con 100 90 70 60 Mehishiba 50 300 0 Taise Weed 　　　　　　80　　70　　50　　　30 Morning Glory　　　　 100 100 80 60 rice 7 0 50 30 0 Onamomi 100 100 90 70 Dogfish 80 50 30 0 oats 30 0 0 oats 0 0 morning glory 100 100 90 60 Wheat 0000 Sicle Pots 100 100 100 50 Jiyeonson Glass 70 50 30 0 Hamasuge 10 0 90 60 30 corn 30 0 0 0 Yasei Soba 100 10 0 100 80 Black Glass 70 50 30 0 Brassica 100 100 1 00 100 Barley 50 30 0 0 green, 7 oxtail 50 30 0 0 Shiroza 100 70 50 30 Chickweed 80 50 30 0 Downey Brohm 100 80 70 60 Table B Compound 34 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 30 0 0 velvet Tree Leaf 90 80 70 60 Sugar Daiko 100 100 90 70 mehshiba 0 tee weed 　　　　95　　90　　70　　　　　　　　　　　　　　　　　　　　 100 90 80 70 rice 100 90 60 30 Onamomi 90 80 60 30 cotton 70 50 30 0 soybeans 0 0 0 0 0 dogfish 50 30 0 0 Kara Sumgi 60 30 0 Morning Glory 90 80 50 30 wheat 　　　　30　　　0　　　0　　　　　　　　　　　　　　 70 50 30 0 Jiyeonson Glass 70 60 50 30 Hamasuge 100 90 70 0 corn 80 30 0 0 Yasei Soba 80 70 60 50 Black Glass 90 70 50 3 0 rapeseed 100 100 100 90 Barley 60 30 0 0 green ・Foxtail 30 0 0 0 Shiroza 100 90 80 70 Chickweed 90 70 50 30 Downey Brohm 90 80 70 60 Table B Compound 35 Rate - g/ha 250 62 16 4 Germination rear Giant foxtail grass 30 0 0 velvet Tsutorif 100 100 100 90 sugar Icon 100 100 100 100 Mehishiba 　 　 　 　 　 　 0 0 0 0 　　　　　　100　　90　　80　　　70 Morning Glory　　　 100 100 100 90 rice 30 0 0 0 Onamomi 10 0 100 100 100 cotton 1 00 90 80 70 soybeans 100 100 100 80 Goldeneye 60 0 0 0 oats 30 0 0 0 Morning glory 100 100 9 5 90 wheat 0 0 0 0 0 Kurupotsudo 100 100 Jiyeonson Glass 70 50 0 0 Hamasuge 6 0 30 0 0 corn 60 30 0 0 Yasei Soba 100 10 0 100 100 Black Glass 100 90 70 50 rapeseed 100 100 100 100 barley 0 0 0 0 green foxtail 50 30 0 0 shi Rosa 100 100 90 70 Chickweed 100 100 100 100 Downy Bro Room 70 30 0 Table 8 Compound 35 Rate - g/ha 250 62 16 before germination Giant foxtail grass 50 30 0 velvet Lee y 100 100 90 sugar beet 　　　　　　100　　　100　　　　100 Mehishiba　　 50 300 Tey Weed 　　90　　　80　　　60 Stingray morning glory 　　　　100 100 90 rice 50 30 0 Onamomi 95 90 85 cotton 100 70 60 soybeans 100 90 80 Nuvier 50 30 0 Oats 0 morning glory 0 morning glory 100 100 90 wheat 0　　　0　　　　　　　　　　　　　　　90　　 80 60 Jiyeonson Glass 50 30 0 Hamasuge 70 60 50 Corn 100 90 80 ya Seisoba 10010090 Black Glass 80 70 60 Brassica 100 100 100 barley 3000 grams Leanne Foxte, -le 50 30 0 Shiroza 100 100 90 Chickweed 　　　　100　　100　　　100 Downey Brohm 70 50 30 Table B Compound 36 Rate - g/ha 250 62 16 4 Germination rear Giant foxtail grass 30 20 0 0 Herhe ” / To!J -71001009580 Sugar beet 100 100 100 80 mehshiba 50 20 0 0 Teeweed 100 80 80 　　　　　　　　　　　　　　　　100　　100　　90　 70 rice 　 　 　 　 　 30 　 10 　 0 0 0 Namomi 100 100 100 100 wa 90 90 80 70 soybeans 　　　　　　　　100　　100　　90　　90 Golden millet 70 40 20 0 oats 30 20 0 0 G Morning Glory 100 100 100 85 wheat 10 0 0 0 sicle pot 100 ．． 100 100 70 Jiyeonson Glass 20 0 0 0 Hamasuge 100 9 0 60 30 corn 60 20 0 0 Yasei Soba 100 100 1 00 80 Black Glass 40 30 20 0 rapeseed 100 100 100 100 barley 20 0 0 0 Green Foxtail 40 10 0 Shiroza 90 70 70 40 Chickweed 100 100 100 100 Downey Boom 40 20 0 0 Table B Compound 36 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 40 40 30 20 velvet Tree leaf 100 90 40 20 sugar daiko 100 100 90 90 Mehishiba 　　　　　　40　　20　　20　　　　　　　　　　　　　　　 　　　　　　100　　100　　50　　　50 Morning Glory　　 90 80 30 20 rice 60 40 0 0 Onamomi 100 100 70 30 wata 100 100 30 10 soybeans 100 10 0 20 0 Golden flea 30 20 20 0 Oats 20 0 0 0 morning glory 100 100 80 2 0 wheat 0 0 wheat 100 100 60 30 Jiyeonson Glass 40 30 20 0 Hamasuge 90 20 0 0 corn 0 corn 50 50 30 30 Yasei Soba 100 100 100 90 Black Glass 70 40 40 20 rapeseed 100 1 00 100 90 Barley 20 0 0 0 Green Foxtail 40 30 0 0 Shiroza 95 90 80 4 0 Chickweed 100 90 70 7G downy - Blohm 60 30 20 20 Table B Compound 37 Rate - g/ha 62 16 4 1 germination rear Giant foxtail grass 90 70 60 20 velvet Tsutorif 100 100 90 50 sugar icon 100 100 100 90 mehshiba 70 70 20 0 Teeweed 　　　　100　　60　　50　　　　G. 100 90 80 60 rice 100 100 80 40 Onamomi 100 100 70 20 cotton 1 00 90 80 30 soybeans 100 100 90 20 goldeneyes 100 100 100 90 oats 100 1 00 70 40 Morning Glory 100 100 100 50 wheat 100 100 90 80 Sicle Bots 100 90 5 0 30 Jiyeon Song Glass 100 100 90 60 Hamasuge 100 90 0 0 0 corn 100 100 90 0 ya Seisoba 100 100 90 80 Bratu Kuglas 100 100 70 40 Brassica 100 100 100 90 barley 100 70 40 0 Green Fock Stale 100 90 80 20 Shiroza 100 100 90 50 Chickweed 100 100 80 70 Downey Brohm 100 90 80 30 Table 8 Compound 37 Ratio - g/ha 62 16 4 1 before germination Giant foxtail grass 100 90 40 0 velvet Tree Leaf 100 90 30 0 Sugar Daiko 100 100 90 60 Mehishiba 90 70 0 0 Taise Weed 　　　　　100　　90　　50　　　50 Morning Glory　　　 100 100 50 50 rice 100 100 70 30 Onamomi 10 0 90 80 60 cotton 100 100 80 30 soybeans 90 90 100 100 40 20 oats so so o.

Morning glory 100 100 30 0 com Gi 　　　　　　　　　90　　90　　　80　　　50 Jiyeonson Glass 90 80 50 20 Hamasuge 100 90 90 30 corn 1 00 100 20 0 Yasei Soba 100 100 100 100 Black Glass 80 70 50 30 rapeseed 100 100 100 20 Barley 90 90 20 0 Green Foxteful 100 100 50 50 Shiroza 100 100 8 0 50 Chickweed 100 100 50 50 Downey Brohm 100 90 40 0th B table Compound 38 Ratio - g/h Yu 62 16 4 1 after germination Giant foxtail grass 60 50 30 0 velvet Toleaf 100 90 60 40 sugar beets 90 80 70 60 mehshiba 　　　　0　　0　　　0　　　　　　　　　　　　　　80 70 50 20 Japanese morning glory 100 90 80 60 rice 60 40 20 0 Onamomi 80 30 0 0 cotton 90 70 30 20 soybeans 90 80 70 50 Nuhi-70505040 Oats 80 70 40 0 Morning glory 90 70 70 60 Humgi 　　　　　　90　　90　　70　　　40 sicle pots　 　　　　ooo.

Johnson Glass 60 50 40 30 Hamas Game Kosi 90 40 20 0 Yasei Soba 70 50 30 30 blank glass 90 80 70 50 rapeseed 90 80 80 70 barley 50 40 30 0 Green Foxtail 40 20 　　　　　　　　　　　　0　　　　　　　　　　　100　　70　 70 40 Chickweed 80 60 50 50 Downey Brohm 80 60 50 0th B table Compound 38 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail grass 0 0 0 velvet tree F 40 30 0 0 sugar beet 　　　　　50　　30　　20　　　　　　　　　　　　　　　　 0 0 0 0 Teeweed 40 40 so o 　　o　　　.

Rice 30 20 0 0 Onamo Mi, so, so, o.

Wata　　　　　　　　ooo.

Soybean 0 0 Golden millet 30 20 0 0 oats 50 30 30 0 Morning Glory so o o.

Wheat 30 0 0 ciclepo Tsudo so so.

Johnson grass 30 0 0 Hamasuge 0 0 Corn 0 Corn 0 0 0 0 Yasei Soba 　　　　　　50　　50 Black Glass　　　　　　　　30　　2 0 20 0 rapeseed 40 30 30 0 Barley 0 0 0 0 0 Green Foxtail 40 -20 0 0 Sparrow Chiyahiki so so.

Chickweed 100 30 0 0 Downy Bu ROHM 40 20 0 Table B Compound 39 Rate - g/ha 62 16 4 1 germination rear Giant foxtail grass 95 50 20 0 velvet Tree leaf 100 80 60 50 sugar daiko 100 100 90 50 mehshiba 50 200 0 0 Taise Weed 　　　　90　　90　　50　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 100 90 70 40 rice 1 00 70 40 20 Onamomi 90 70 30 20 cotton 90 7 0 30 0 soybeans 100 90 80 30 Goldeneye 100 100 6 0 50 oats 90 90 50 40 morning glory 100 90 70 20 pieces Wheat 90 90 80 50 sicles Do 80 50 30 0 100 70 60 40 Hamasuge 100 100 100 40 corn 40 20 0 0 Yasei Soba 100 80 50 20 Black Glass 100 100 70 50 rapeseed 100 100 100 70 Barley 90 7 0 30 20 Green Foxtail 100 70 40 0 Shiroza 100 50 50 0 chickweed 100 100 60 4 0 Downey Brohm 90 80 40 20 Table 8 Compound 39 Ratio = g/ha 62 16 4 1 before germination Giant foxtail grass 100 30 30 0 velvet tree y 90 80 50 30 sugar dai Con 100 80 50 0 Mehishiba 　　　　　　70　　30　　30　　　　　　　　　　　　　　　　　　　　　　 　　　　　60　　40　　　0　　　　　　　　　　　　　　　　　　　0. 60 50 30 30 rice 8 0 40 40 0 Onamomi 80 30 30 0 watts 100 1 00 30 0 soybeans 100 90 30 0 Goldenflies 100 100 0 oats 70 20 0 0 asa Gao 100 0 0 0 wheat 　　　　　　　　　70　　20　　　　0　　　0　　　　　　 0 Jiyeonson Glass 90 70 20 0 Hamasuge 100 100 50 50 corn 4 0 20 0 0 Yasei Soba 100 100 100 90 Black Glass 70 30 0 0 Brassica 100 80 50 0 Barley 90 30 30 0 Green Foxtail 100 80 40 40 Shiroza 90 50 30 0 boxes Downey Brohm 70 0 0 Downey Brohm 100 40 0 Table B Compound 40 Ratio - g/ha 62 16 4 1 after germination Giant foxtail grass 100 40 20 0 velvet Tree leaf 100 90 40 0 sugar daiko 100 90 80 30 Mehishiba 40 200 0 Taise Weed 　　　　　80　　50　　20　　　0　　　　　　　　　　　　　　 100 100 80 50 rice 9 0 80 30 0 Onamomi 100 50 20 0 cotton 90 50 20 0 soybeans 80 80 20 20 dogbini 100 90 70 4G oat 90 70 30 0a Sagao 100 100 50 0 wheat 　　　　　　　　　90　　90　　50　　40 Siclepot 0 Jiyeonson Glass 100 80 70 40 Hamasuge 100 80 20 0 corn 80 30 0 0 Yasei Soba 100 100 50 20 blank glasses 100 90 50 30 Brassica 100 100 100 80 barley 80 50 40 20 Green Foxtail 90 70 20 0 Shiroza 100 100 70 7 0 Chickweed 100 70 20 0 Downy ・Prohm 90 70 30 0 Table B Compound 40 Ratio - g/ha 62 16 4 1 before germination Giant foxtail grass 60 60 0 berbe Tsutorif 100 50 40 0 sugar Icon 100 100 50 50 mehshiba 100 70 60 40 Teeweed 　　　　　　80　　70　　30　　　　30 Stunning morning glory　　 90 30 0 0 rice 1 00 100 30 20 Onamomi 90 80 40 0 cotton 100 80 50 0 soybeans 90 60 0 0 Dogfish 100 100 3 0 20 oats 90 60 30 0 morning glory 100 70 70 0 Wheat 50 30 0 0 cycles Tsudo 　　　　　　　　80　　80　　　70　　　30 Jiyeon Sungura 90 90 50 20 Hamasuge 　　　　　　　90　　70　　20 corn 40 30 0 0 Yasei Soba 100 100 100 100 Black Glass 90 50 0 0 rapeseed 100 100 70 40 Barley 70 50 0 0 Green Foxtail 90 90 40 30 Shiroza 100 90 80 30 Chickweed 70 70 0 Downey Prohm 90 80 40 40 Table B Compound 41 Rate = g/ha 250 62 16 4 Germination rear Giant foxtail grass 100 80 50 20 velvet Tsutreef 90 60 40 0 sugar dai Con 100 100 80 30 Mehishiba 　　　　　　　70　　60　　40　　　20 teeweed 　　　　　50　　20　　　0　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　0 90 90 80 70 rice 10 0 100 90 40 Onamomi 80 50 20 0 cotton 60 5 0 0 soybeans 100 90 80 30 Golden millet 100 100 9 0 60 Oats 100 100 90 80 morning glory 100 100 50 0 wheat 　　　　　　　　　　　　100　　　100　　　90　　90 Shikurubotsudo 80 30 0 0 Jiyon Songgrass 100 100 80 40 Hamasuge 40 0 0 0 corn 100 100 80 70 Yasei Soba 100 40 30 0 black glass 100 100 90 80 Brassica 100 90 90 80 Barley 90 60 60 30 Green Foxtail 100 90 50 50 Shiroza 90 80 40 0 Chickweed 100 80 70 50 Downey Brohm 100 100 90 80・Table B Compound 41 Rate - g/ha 250 62 16 4 Germination Before Giant foxtail 100 100 90 40 bells Betstreef 100 40 40 40 Sugar Dai Con 100 90 0 0 Mehishiba 　　　　　　100　　70　　　0　　　　　　　　　　　0　 　　　　　80　　50　　30　　　　　　　　　　　　　　　　　　　　　　 100 80 30 0 rice 10 0 100 60 40 Onamomi 90 70 40 0 cotton 100 90 30 0 soybeans 100 100 20 dogfish 100 100 50 0 oats so so so o oats .

Morning Glory 100 90 20 0 Wheat 100 20 0 0 Sicle Pot 90 80 30 30 John's Grass 100 90 70 40 Red-eye 20 0 0 0 Corn 100 90 '40 0 Wild buckwheat 1 00 100 100 100 blank glass 1 00 70 50 40 rapeseed 100 60 30 20 Barley 100 8 0 0 0 Green Foxtail 100 100 90 50 Shiroza 80 70 70 30 Chickweed 90 90 0 0 Dow Nie Blohm 100 100 90 30 Table B Compound 42 Rate - g/ha 250 62 16 4 Post-germination Giant foxtail 100 50 40 0 be Lubetsu Leaf 70' 40 20 0sa Radish 100 100 100 70 Mehi Shiba 90 20 20 0 Tea weed 30 20 0 0 Japanese morning glory 100 90 80 30 Rice 100 100 90 40 Japanese oak 80 20 0 0 Cotton 80 30 30 0 Soybean 100 70 60 0 Golden millet 100 100 80 60 Oat 100 100 100 90 Morning glory 90 90 80 20 Wheat 100 100 90 80 Sicle Pot 80 30 0 0 Jeongson Grass 10 0 100 70 40 Hamusuge 90 50 50 30 Corn 100 100 60 30 Yasei Soba 100 90 50 0 Black Grass 100 100 80 80 Brassica 100 1 00 90 70 Barley 100 10 0 80 30 Green Foxtail 100 50 40 0 Shiroza 100 80 50 30 Chickweed 100 90 7 0 50 Downey Brome 100 100 90 80 Table B Compound 42 Proportion - g/ ha 250 62 16 4 Before germination Giant foxtail 100 90 70 0be Lubetsu Leaf 70 50 30 0 sato Udaikon 100 100 50 30 Mehishi Ba 100 90 50 50 Tee Weed 50 50 50 0 Japanese morning glory 100 90 50 0 Rice 100 100 70 50 Onion 90 90 30 0 Cotton 80 80 30 0 Soybean 100 70 0 Golden millet 100 100 100 30 Oats 9 0 80 40 20 Morning glories 100 100 50 θ wheat 100 100 20 0 Sicle Pot 100 80 40 0 Jyongson Grass 100 90 50 30 Japanese Red Grass 100 50 30 0 Corn 100 40 30 0 Yasei Soba 100 10 0 100 100 Black Grass 90 9 0 70 40 Brassica 80 80 70 20 Barley 90 90 50 30 Green Foxtail 100 -100 90 30 Shiroza 100 70 70 70 Chickweed 100 70 0 0 Downey brome 100 100 80 40 Table B Compound 43 Rate - g/ha 62 16 4 1 After germination Giant foxtail 100 100 60 to 40 4 to 7 )! J-71001009090 Sugar Dai-2in 100 100 100 100 crabgrass 90 40 20 0 teaweed 100 80 70 20 morning glory 100 90 80 70 rice 100 100 90 70 onion 100 80 30 0 cotton 100 90 80 60 die 100 100 80 30 Inubij-1001 0010080 Oat 100 100 100 90 a Sagao 100 100 80 50 com Gi 100 100 90 90 cycles Potsudo 100 80 50 0 Jiyeon-seo Ning grass 100 100 80 60 Japanese horseradish 90 90 40 0 Corn 100 1 00 80 80 Wild buckwheat 100 10 0 100 50 Black grass 100 100 90 50 Brassica 100 100 100 90 Barley 100 100 90 8 0 Green Foxtail 100 100 70 40 Shiroza 100 100 70 70ha Kobe 100 100 90 80 Downey Prohm 100 100 80 40 Table 8 Compound 43 Rate - g/ha 62 16 4 1 shot In front of the bud, Giant foxtail 100 100 70 60 be Lubetsu Leaf 100 100 90 70 Sat Udaikon 100 100 100 80 Mehishi Ba 90 90 80 50 Eid 100 100 80 50 Morning Glory 100 90 80 0 Rice 100 100 100 40 Onamomi 100 100 70 0 Cotton 100 100 100 90 soybean 100 100 60 50 dogfish 100 100 80 40 oat 90 80 60 60 morning glory 100 100 50 0=wheat 100 90 1 80 40 Shikurupotsudo 100 100 90 70 Japanese grass 90 90 70 70 Japanese horseradish 1 00 100 80 40 Corn 10 0 100 0 0 Wild buckwheat 100 100 100 100 Blank glass 90 80 70 50 Brassica 100 100 100 40 Barley 100 90 70 0 Green 7 Oxtail 100 10 0 100 30 Shiroza 100 100 90 0 Chickweed 100 90 50 Downey Brome 100 10 0 9 0 70 Table B Compound 49 Rate - g/ha 62 16 4 1 After germination Giant foxtail 100 100 50 20 be Rubet Leaf 100 100 60 0sa Radish 100 100 100 90 Mehi Shiba 100 50 40 0 Tea Weed 100 90 40 10 Chiyouse Morning glory 100 100 90 40 Rice 90 70 20 0 Japanese fir 100 80 70 50 Cotton 100 90 90 50 Soybean 100 90 70 60 Golden millet 100 100 60 40 Oat 80 70 50 40 Morning glory 100 100 90 50 Wheat 50 50 40 30 Siclepot 100 60 50 0 Jiyeonson Grass 1 00 90 80 60 Japanese Red Bean Grass 0 0 0 0 Corn 100 80 30 30 Yasei Soba 100 100 90 70 Blank Grass 70 70 60 50 Brassica 100 100 100 90 Barley 80 70 6 0 20 Green Foxtail 100 100 60 50 Shiroza 100 90 90 60 Chickweed 100 90 80 70 Downy Prome 80 70 60 40 Table B Compound 49 Rate - g/ha 62 16 4 1 day before germination 90 80 80 70 Bells Bet Leaf 90 80 50 40 Sato Udaikon 90 80 60 30 Mehishiba 100 100 90 50 Teiui code 100 90 70 40 Sagao 90 60 40 20 Rice 100 90 60 20 Onion 90 80 70 Cotton 70 40 40 Soybean 90 40 10 0 Golden millet 10 0 90 40 30 Oat 60 40 40 30 Morning glory 100 90 40 40 Wheat 70 2 0 0 0 sicle pot 100 90 40 jiyon Songgrass 100 90 40 0 Hamasuge 90 80 3G Tomo Rokoshi 70 60 20 0 Yaseiso Ba 100 90 80 50 Black Kug Russ 90 70 40 0Brassica 100 90 20 0Barley 80 30 20 0Green Fox Tail 100 90 70 40 Shiroza 100 100 100 80 Chickweed 100 100 90 70 Downy Prome 90 40 20 0Table B Compound 52 Rate-g/ha 62 16 4 1 shot After budding Giant foxtail 50 30 0 0 berbe Tsutorif 100 70 40 30 sugar Ikon 100 100 100 70 Mehishiba 0 0 0 0 Teiweed 80 40 30 20 Morning glory 100 100 90 80 Rice 0 0 0 0 Onion fir 80 60 50 30 Cotton 100 7 0 30 0 Soybeans 100 90 50 0 Golden millet 90 80 70 60 Oats 70 50 30 0 Morning Glory 90 70 6 0 0 Wheat 70 50 30 0 Sicle Pot 30 0 0 0 Johnson Grass 90 80 70 50 Ha Masuge 50 30 0 G Tow Sorghum 20 10 0 0 Yanaiso Ba 100 90 80 70 Black Kug Russ ゛ 100 100 80 50 Brassica 100 100 90 80 Barley 50 30 0 0 Green Fox Tail 0 0 0 0 Shiroza 10 0 100 70 50 Chickweed 10 0 90 70 30 Downey-Brom 70 50 30 0 Table 8 Compound 52 Proportion - g /ha 250 62 16 4 Before germination Giant foxtail 90 70 50 30 be Rubet Leaf 70 50 30 0 Sato Radish 95 90 80 70 Mehishiba 95 90 85 80 Teiwi Do 90 70 50 0 Chiyosenasaga O 90 70 50 30 Rice 100 90 60 30 Japanese fir 70 50 30 0 Cotton 70 50 20 0 Soybean 60 30 0 0 Golden millet 100 100 80 50 Oat 4 0 30 0 0 Morning glory 80 50 30 2 0 Wheat 80 30 0 0 Sicle Pot 90 7 0 50 30 Jeongson Grass 90 80 70 50 Japanese Musume 100 100 50 30 Corn 100 80 30 0 Yasei Soba 100 95 90 80 Black Grass 100 90 8 0 70 Brassica 100 100 90 60 Oh Wheat 80 70 50 30 Green Foxtail 100 90 80 50 Sparrow 100 100 90 8 0 Chickweed 100 90 60 30 Downy - Brohm 90 80 50 30 Table B Compound 55 Proportion - g/ha 250 62 16 4 After germination Giant foxtail 70 30 0 0 Bell Betutleaf 100 100 100 80 Sugar Die: In 100 100 100 100 Mehishiba 40 30 0 0 Teiweed 90 70 60 50 Morning Glory 100 100 70 50 Rice 70 60 50 30 Onamomi 1 00 100 80 60 cotton 8 0 70 50 40 soybeans 100 100 100 100 Inubie 90 70 60 50 Karamugi 70 60 50 50 30 Sochao 100 90 60 30 Komugi 50 30 0 0 0 0 0 Cycle Potsdo 100 100 100 100 70 Jiyeonson Grass 90 60 30 0 Japanese Musume 100 100 1 00 80 Corn 100 80 7 0 60 Yasei Soba 100 100 100 100 Black Glass 100 100 80 70 Abra Na 100 100 100 100 ohm Gi 60 30 0 0 Green F Foxtail 80 50 30 0 Sparrowtail 100 100 70 50 Shiroza 90 70 50 30 Hafbe 100 100 70 50 Table B Compound 55 Rate - g/ha 250 62 16 4 Before germination 100 100 70 30 be Rubet Leaf 100 90 60 30 Sat Udaikon 100 100 100 100 Mehi Shiba 70 50 30 0 Tee Weed 90 80 70 50 Chimney Morning Glory 95 90 60 40 Rice 100 100 70 30 Onion 90 80 30 0 Cotton 90 80 70 60 Soybean 100 90 60 0 Golden Millet 1 00 100 80 40 Oat 90 70 50 30 Morning glory 100 90 60 50 Wheat 70 50 30 0 Siclepot 9 0 80 50 30 Jiyeonson Grass 90 80 70 30 Hamasuge 100 100 70 50 Corn 100 90 30 0 Wild buckwheat 90 8 0 70 50 Blackgrass 90 80 70 60 Canola 100 100 60 30 Barley 50 30 0 0 Green Foxtail 100 90 6 0 30 Sparrow 100 70 60 50 Shiroza 100 100 100 90 Chickweed 100 90 80 60 Table B Compound 56 Proportion - g/ha 250 62 16 4 Post-germination Giant foxtail o o o.

Velvet Leaf 100 100 80 40sa Radish 100 100 100 100 me Hyshiba 0 0 0 0 Teiweed 70 50 30 0 Japanese morning glory 100 100 90 70 Rice 50 30 0 0 Onion 100 100 100 80 Cotton 70 60 50 0 Soybean 100 100 90 70 Golden millet 0 0 0 0 Oat 0 0 0 0 Morning glory 100 100 100 60 wheat 0 0 0 0 shiku Report 100 90 80 60 Jiyon Song Grass 0 0 0 0 Hamusuge 100 100 100 70 Corn 0 0 0 0 Yasei Soba 100 100 100 90 Black Grass 50 30 0 0 Brassica 100 1 00 100 100 Barley 30 0 0 0 Green Foxtail 0 0 0 0 Sparrow-throat 30 0 0 0 Shi Rosa 90 80 70 50 Chickweed 100 80 70 60 Table 8 Compound 56 Proportion - g/ha 250 62 16 4 Before germination Giant hackberry 0 0 0 0 Velvet tree Fu 90 70 50 30 sugar beet 100 100 100 100 crabgrass 0 0 0 0 teaweed 8 0 60 50 30 morning glory 60 50 40 30 rice 60 30 0 0 90 60 30 0 cotton 70 50 30 0 soybean 100 9 0 30 0 Golden millet 30 0 0 0 Oat 30 0 0 0 Morning glory 90 80 70 50 Wheat 0 0 0 0 Sicklepo Tsudo 100 70 50 30 Jyonson Grass 60 0 0 0 Japanese Musume 100 100 0 0 Corn 0 0 0 0 Yasei Soba 10 0 90 80 50 Black Grass 70 50 30 0 Brassica 100 100 80 40 Barley 0 0 0 0 Green Foxtail 0 0 0 0 Sparrow 30 0 0 0 White The 100 100 90 70 Chickweed 90 80 70 60 Table B Compound 61 Rate - g/ha 62 16 4 1 After germination Giant foxtail 100 50 30 10 be Rubet Leaf 100 100 100 90 Sat Udaikon 100 100 100 100 Mehi Shiva 50 30 0 0 Teiu Eid 100 90 50 40 Chiyosen Morning glory 100 100 90 80 Rice 80 50 40 30 Onagumomi 100 100 80 40 Cotton 100 100 90 70 Soybean 100 100 100 100 Dog Hi-10040 200 Oat 50 20 0 0 Asaga O 100 100 90 90 Wheat 40 20 10 0 Shikulpot 100 100 100 90 Jiyeon Song Gras 100 40 30/%7 Sedge 100 100 100 100 Corn 90 80 70 40 Wild buckwheat 100 100 100 100 Blank grass 90 90 50 10 Brassica 100 100 100 100 Barley 50 30 10 0 Clean Foxtail 50 40 30 20 Shiroza 100 90 90 70 Chickweed 10 0 100 100 Downey Brome 100 8 0 50 30 Table B Compound 61 Rate - g/ha 250 62 16 4 Before germination Giant foxtail 40 30 0 0 Bell Bettleaf 90 90 80 40 Sugar da Icon 100 100 90 70 Mehishiba 90 80 70 30 Teiwi 100 90 90 60 Gao 100 90 50 Rice 80 80 50 20 Onion 80 80 60 Cotton 90 90 40 20 Soybean 90 70 40 10 Golden millet 100 9 0 60 30 Oat 70 70 60 30 Morning glory 100 100 9 0 30 Wheat 40 20 10 0 Ukulpot 100 90 9 0 60 Jiyeonson Grass 80 40 30 10 Yellow-bellied Grass 90 80 3 0 Corn 60 50 30 20 Yasei Soba 100 90 90 80 Bu Rackgrass 80 70 40 30 Abra Na 100 100 100 90 Barley 80 50 30 0 Green wheat Foxtail 80 80 60 0 Shiroza 100 100 90 80 Chickweed 100 100 100 10G Downy Brome 90 80 40 40 Table B Compound 62 Rate = g/ha 62 16 4 1 After germination Green foxtail grass 90 90 50 40he Ruhet! J-710010010090 Sugar beet 1 00 100 100 100 Mehishiba 70 40 30 20 Teiweed 10 0 100 90 50 Stilica 100 100 100 90 rice 90 60 50 40 Onamomi 100 100 100 80 cotton 100 100 100 60 soybeans 100 1 00 100 100 dogfish! 100 100 100 70 Oats 80 6 0 40 10 Morning Glory 100 10 0 100 90 Wheat 50 40 20 0 Shikurubotsu 100 100 70 50 Jiban Song Gras X 100 100 90 70 Hamasuge 100 100 100 90 corn o==+shi100 100 100 70 Yasei soba 100 100 100 80 bu Rack grass 100 90 60 30ab Lana 100 100 100 100 oh Wheat 80 70 30 30 Green Foxtail 100 100 80 50 Shiroza 100 90 80 70 Chickweed 100 100 100 100 Downy Plow Mu100 100 80 70 Table 8 Compound 62 Proportion - g/ha 250 62 16 4 Before germination Giant foxtail 100 60 50 20 Rubet Leaf 100 90 60 40 Sat Udaikon 100 100 90 80 Mehishi Ba 100 90 70 40 tea Eid 100 90 90 70 Japanese morning glory Morning glory 100 100 90 70 Rice 100 80 70 20 Onion 90 80 70 40 Cotton 90 90 50 30 Soybean 90 70 50 20 Golden millet 100 90 60 20 Crow Wheat 80 70 60 20 Morning glory 100 100 90 70 Wheat 90 70 60 30 Sicle Pot 100 100 90 40 Jyongson Grass 100 90 40 Japanese Musume 90 80 70 70 Corn 100 90 50 0 Yasei Soba 100 9 0 80 80 Black Grass 100 90 70 30 Brassica 100　100　 100 90 Barley 90 90 70 60 Green Foxtail 100 100 90 30 Shiroza 100 100 10 0 90 Chickweed 100 100 100 100 Downey brome 100 90 80 70 Table B Compound 63 Rate = g/ha 62 16 4 1 After germination Giant foxtail 100 90 40 20 be Rubet Leaf 100 100 100 90 Sat Udaikon 100 100 100 100 Mehi Shiva 100 70 40 20 Tei -Weed 100 100 100 70 Chiyo Morning Glory 100 100 90 80 Rice 100 90 70 40 Onamomi 100 100 100 70 Cotton 100 100 90 60 Soybean 100 100 100 100 Golden millet 100 100 100 90 Oat 100 70 60 30 Morning glory 100 100 90 40 Wheat 100 70 30 0 Siclepot 100 100 80 40 Jyongson Grass 100 100 90 70 Perilla 100 100 '100 40 Corn 100 100 90 80 Yaseimba 100 100 ] 00 100 Black Grass 100 100 70 20 Brassica 100 100 100 100 Barley 80 70 60 40 Green Fox Tail 100 100 90 40 Shiroza 1 00 90 70 60 Chickweed 100 100 100 90 Downey Brohm 100 100 80 80 Table B Compound 63 Proportion - g/ha 62 16 4 1 Before germination Giant foxtail 50 40 0 0 Bell Betutleaf 80 80 60 40 Sugar Ikon 90 80 80 70 Crabweed 100 80 70 30 Teiweed 90 90 80 30 Japanese morning glory 90 80 50 20 Rice 90 50 40 20 Japanese fir 90 80 70 20 Cotton 90 60 40 30 Soybean 80 60 20 1 0 Golden millet 1 00 100 40 10 Oat 6 0 50 50 10 Morning Glory 100 90 70 30 Wheat 80 70 40 20 Sicle Pot 100 90 80 40 John's Grass 90 60 30 0 Red Spotted Grass 90 3 0 0 Corn 90 50 20 10 Yasei Soba 90 90 80 Black Grass 100 50 4 0 20 Brassica 100 90 90 80 Barley 90 80 40 30 Green Foxtail 100 90 30 0 Shiroza 100 100 100 7 0 Hafbe 100 90 40 Downey Brome 100 100 90 60 Table B Compounds 64 Rate - g/ha 62 16 4 1 After germination Green foxtail grass 50 10 0 0 berbe Tsutorif 100 100 90 50 sugar Ikon 100 100 100 90 Mehishiba 10 0 0 0 Teiweed 100 90 70 Japanese morning glory 100 100 100 90 Rice 30 20 10 0 Onamomi 100 100 100 40 Cotton 90 90 70 40 Soybean 100 100 70 50 Golden Millet 90 50 30 10 Oat 40 0 0 0 morning glory 100 100 100 60 Wheat 20 0 0 0 Sicle Pot 100 70 50 0 John's Grass 90 60 40 20 Red Spotted Root 100 100 10 0 60 Corn 30 10 0 0 Wild Soba 100 100 100 100 Blackgrass 40 30 20 0 Brassica 100 100 100 100 Barley 30 10 0 0 Green Foxtail 70 50 20 Shiroza 90 70 60 50 Chickweed 100 100 90 90 Downy Blow Mu 40 30 30 0 Table 8 Compound 64 Proportion - g/ha 250 62 16 4 Before germination Giant foxtail 40 0 0 0 Berbe Tsutorif 90 90 80 40 sugar Ikon 100 90 90 90 Crabweed 100 80 40 Teaweed 90 90 80 40 Morning Glory 100 90 80 50 Rice 90 70 30 10 Onion 90 70 70 30 Cotton 90 80 0 Soybean 50 30 20 10 Golden Grass 8 0 40 20 0 Oats 201 O Morning glory 100 90 90 80 Wheat 30 20 10 0 Shiku Rupotsudo 100 80 60 Jeongson Grass 60 50 40 20 Japanese Musume 100 100 90 40 Corn 70 20 10 0 Yasei Soba 100 90 80 80 Black Grass 70 60 30 0 Brassica 100 100 90 90 Barley 30 20 10 Green Foxtail 90 40 20 0 Shiroza 100 100 100 70 Chickweed 100 10 0 100 90 Downey Prome 90 80 30 10 Table B Compound 65 Rate - g/ha 250 62 16 4 shots After budding 100 90 20 0be Rubet Leaf 100 100 100 90 Sat Udaikon 100 100 100 100 Mehi Shiva 60 40 0 0 Teiu Eid 100 100 100 50 Japanese morning glory 100 100 100 100 Rice 40 30 10 0 Onamomi 100 100 100 100 Cotton 100 100 90 70 Soybean 100 100 100 100 Golden millet 90 70 40 10 Oat 30 10 10 0 Morning glory 100 100 100 100 wheat 10 10 0 0 Shikurupotsudo 100 100 100 70 Jiyeonson Grass 60 50 30 0 Hamasuge 100 30 0 Corn 100 100 90 50 Yasei Soba 100 100 100 100 Black grass 90 80 30 0 Brassica 100 100 100 100 Barley 40 20 10 0 Green Foxtail 100 9 0 70 20 Shiroza 100 100 80 50 Chickweed 100 100 100 100 Downey Brome 100 100 40 0 Table B Compound 65 Rate - g/ha 250 62 16 4 Before germination Giant foxtail 90 80 20 Berbe Tree Leaf 100 90 70 40 Sugar Radish 100 100 100 90 Mehishiba 90 90 60 30 Teiui code 100 100 90 20 Sagao 100 100 90 40 Rice 70 40 10 0 Onion 90 90 80 70 Cotton 90 80 70 20 Soybean 100 90 50 20 Golden millet 90 80 30 0 Oat 50 40 30 30 Morning glory 1 00 100 90 90 Wheat 10 0 00 Sicle Pot 100 100 90 80 Jiyeonson Grass 30 2 0 10 0 Lotus Grass 80 70 40 0 Corn 100 80 30 10 Yasei Soba 100 100 100 90 Blackgrass 80 80 40 Brassica 100 100 9080 Barley 60 40 20 0 Green Fox Tail 100 90 50 40 Shiroza 100 90 50 40 Chickweed 100 100 100 80 Downey Brome 70 40 30 30 Table B Compound 66 Rate - g/ha 250 62 16 4 After germination Giant foxtail 100 40 0 0 bell Betutleaf 100 100 100 90 Sat Udai: l/ 100 100 100 100 Mehishiba 10 0 0 0 Tei Weed 100 100 80 50 Chiyouse Morning Glory 100 100 100 80 Rice 40 20 10 0 Onomimi 100 100 100 80 Cotton 100 100 90 40 Soybean 100 100 100 100 dogs! 100 80 30 0 Oat 10 10 0 0 Morning glory 100 100 100 100 Wheat o o o.

Sicle pod 100 100 90 40ji Jonsson Grass 40 10 0 Hamasuge 1oo6o4o3゜Corn 100 80 70 10 Yasei Soba 100 100 100 100 Black Glass 60 20 0 rapeseed 100 100 100 100 barley 30 10 0 0 0 Green Foxtail 70 50 30 0 Shiroza 100 100 100 70 boxes Be 100 100 100 100 Downy ・Blohm 70 10 0 Table 8 Compound 66 Ratio - g/ha 250 62 16 4 Before germination Giant foxtail grass 40 20 0 berbe Tsutorif 100 90 90 30 sugar icon 100 100 100 90 mehshiba 　　　　　　　　　90　　　80　　　30　　　0TEY Do 100 90 70 Japanese morning glory 90 80 40 0 rice 70 60 0 0 Onamomi 90 80 80 30 cotton 90 90 50 10 soybeans 90 　　　　90　　　30　　　20 Golden millet 90　　　　40　　　0　 0 oats 40 30 20 1 0 morning glory 100 100 90 70 Wheat 10 0 0 Shikurubo Tsudo 100 90 50 40 Jiyeon Sung Glass 20 20 0 0 Hamasuge 80 50 0 corn 100 80 20 10 Yasei Soba 100 100 100 90 Black Glass 60 30 20 0 rapeseed 100 90 90 80 barley 30 10 0 0 Green Foxtail 10 0 90 30 0 Shiroza 100 90 90 30 Chickweed 100 100 90 90 Downey Brohm 40 2 0 0 0 Table B Compound 67 Giant Foxtail 10 0 0 Q Bell Bet Leaf 100 100 100 80 Sato Radish 100 100 100 radish Ba Do 100 70 70 60 Gao 100 100 80 70i4 60 40 10 0 Onamomi 　　　　　! 00 100 100 90 Morning Glory 100 90 70 30 wheat o o o.

Sicle pod 100 90 80 40ji Jonsson Glass 40 30 30 0 Hamas Ge　　　　　　　　100　　100　　100　　80 Tomoro Kosi 40 10 0 0 Yasei Soba 100 100 100 100 blank graph 50 30 20 0 rapeseed 　　　　　100　　100　　100　　100 Barley 20 0 0 Green Foxte Rule 30 0 0 0 Shiroza 1 00 70 50 20 Chickweed 100 100 100 40 Downey Brohm 50 40 20 0 Table B Compound 67 Ratio - g/ha 250 62 16 before germination Giant foxtail grass 0 0 0 velvet tree-y 90 70 50 sugar beet 100 90 80 mehshiba 40 10 0 Teiweed 80 70 2 0 morning glory 70 60 40 rice 60 50 30 Onamomi 80 70 30 cotton 30 20 0 soybeans 20 10 10 goldeneyes 30 10 0 carasms Gi 40 30 20 morning glory 40 40 0 Humgi 100 0 sicle pound 80 70 30 Jiyeonson Glass 60 20 0 Hamasuge 90 90 40 corn 1000 Yasei Soba 100 90 80 Black Grass 100 40 0 rapeseed 100 100 90 barley 20 0 Green Foxtail 000 Shiroza 　　　　　90　　　90　　　80 hafbe　　　　　　10 0 100 80 Downey Brohm 20 0 　　Table B Compound 68 Ratio - g/ha 250 62 16 4 After germination Giant foxtail grass 50 30 0 0 hell Hettree 71oolooooloo9゜Sugar taikon 1oo1oolooo1o.

Mehishiba 30 30 0 0 tay -weed 100 90 50 40 Senasaga No. 100 100 100 70 rice 60 50 40 0 Onamomi 100 100 80 40 cotton 100 90 70 40 soybeans 100 100 100 30 Golden millet 100 8 0 40 0 Oats 50 30 0 0 Asaga No. 100 90 70 30 wheat 　　　　　　　　　　20　　10　　　0　　　0 　　　　　　　　　60　　60　　　　　50　　40 90 50 20 0 Hamasuge 　 　 　 90 　 80 　 　 70 corn 80 50 30 Yaseinpa 100 100 90 70 Black Glass 80 70 50 20 Brassica 100 100 100 100 barley 30 10 0 Green Foxtail 60 40 20 0 Shiroza 100 100 70 60 Chickweed 100 1 00 100 90 Downey Brohm 80 70 70 30 Table 8 Compound 68 Ratio - g/ha 250 62 26 before germination Giant foxtail grass 2000 velvet tree y 50 4G Sat9 Daikon 90 90 8 0 mehshiba 40 20 0 tewe Do 90 70 30 Japanese morning glory 80 70 40 rice 60 40 30 Onamomi 90 50 0 cotton 5000 soybeans 20 10 10 goldenfish 50 20 0 Oats 60 50 4 0 morning glory 80 70 40 wheat 40 10 0 sicle pots 400 Jiyeonson Glass 4000 Hamasuge 80 70 30 corn 90 20 10 Yasei Soba 100 90 80 black glass 70 50 30 Brassica 100 90 90 Barley 60 30 20 Green Foxtail 4000 Shiroza 90 80 70 ha Kobe 100 90 90 Downey Brohm 　　　　70　　30　　　0Table B Compound 73 Rate - g/ha 62 16 4 1 germination rear Giant foxtail grass.

Velvet leaf 90 70 50 30 Sugar beet 90 70 50 30 me Hyshiba 30 0 0 0 Eid 50 30 0 0 Gao 70 50 30 0 rice 0QQQ Onamomi 90 70 50 30 cotton 70 50 30 0 soybeans 80 60 30 0 Golden millet o o 　　　　.

Oats 0000 Morning Glory 80 70 50 30 wheat o oo.

Shikurupotsudo 50 30 0 0 Nnnng glass ooo.

Hamasuge 60 30 0 0 toe Sorghum 50 40 30 20 yase Isoba 80 70 50 30 Bratu Kuglas 0000 Brassica 100 80 50 30 barley 000 0 Green Foxtail 0000 Shiroza 0000 Chickweed 0000 Downey Prome 50 30 0 0 Table B Compound 73 Ratio - g/ha 250 62 16 4 Before germination Giant foxtail grass 50 30 0 berbe Tree leaf 90 70 50 30 sugar daisies Con 90 70 50 30 Mehishiba 60 30 0 　　　　　70　　　50　　　30　　　　0. 80 50 30 0 rice 60 30 0 0 Onamomi 70 50 30 0 cotton 40 20 0 0 soybeans 50 　　　　30　　　0　　　0　　　　　　　　　　　　　　　50　 30 0 0 oat oat 　　　　o　　.

Morning glory 70 50 30 0 ko Wheat 0 0 Shikurupot 70 30 0 0 Jiyeonson Glass 30 0 0 0 Hamasuge 80 50 30 0 corn 30 0 0 0 Yasei Soba 90 70 50 30 Black Glass 60 30 0 0 C rapeseed rape 70 50 30 0 Barley 0 0 0 (Green Foxtail 60 30 0 C sparrow C Shiroza 90 70 50 3C Gourd Tan Corn and sorghum herbicide testing was conducted on pre-emergence and post-emergence evaluations of the following species: included.

Crops Corn Corn Zea ff1ays Jiyeonson Grass Digital ia sanguinalis puff 8 games Onamomi Hachimono "Hiroyu 4 End I omoea hederacea hellhetley 7 and others Aim for 3 fish and 3 ribs.■ Willow knotweed. 1L Post-germination plants were grown in satsafras soil. corn and dive It was grown in a separate container with a diameter of 25 cm. Sorghum and seven grass weed species are divided into two Four species per container were grown in containers with a diameter of 18c+n.

Seven broad-leaved weed species were also grown in two 18 cm diameter containers, with four and three species per container. and let it grow. One additional corn plant was planted in a container 18 cm in diameter. Ta. The soil surface of this further container of corn was exposed to the test compound only through the leaves. It was coated with the adsorbent perlite before the spray treatment to get into the plants. Plants depend on seeds The test compound was grown for 10-21 days and then dissolved in a solvent that is non-toxic to the plants. Spray after germination.

a! Roasted Fertilize! ; Pre-germinated plants were grown in Tama silt/loam soil. these plants The soil surface is covered with perlite; except for corn plants, the soil surface is covered with perlite; It was as described. On the day of planting or the next day, add a solvent that is non-toxic to the plants. The test compound dissolved in the solution was sprayed.

Hual value Treated plants and controls were kept in the greenhouse for 2-4 weeks. Visual plant response assessment is Performed on a percentage scale from 0 to 100 compared to the illuminated object. Here 0 - indicates no damage, and 100 - indicates death. Response evaluations are shown in Table 0.

Table 0 Compound 36 Ratio - g/ha 125 64 32 16 8 4 2 After germination Corn 40 20 0 0 0 0 0 da is 100 100 100 100 95 75 55 green fox Tail o ooo.

Giant foxtail grass o o o o ooo.

Fall Panicum o o ooo.

Omega-shiba ooo ooo.

Johnson Glass 35 0 0 0 0 Moro Kosi 25000000 Murasaki Hamusuge 70 40 0 0 0 0 0 Velvet Leaf 100 10 0 95 70 65 35 0 Onamomi 100 1 00 100 100 95 70 50 Lady Yanagitade 100 100 100 85 65 40 25 Shiroza 100 95 85 70 60 30 0 Akanea Obiyu 10 0 100 100 100 85 60 35 Ivy morning glory 1 00 100 100 100 90 65 45 Japanese morning glory 100 100 100 95 75 45 30 Perlite treatment 25 0 0 0 0 0 0 0 Corn Table 0 Compound 36 Ratio - g/ha 250 125 64 32 16 Before germination Corn 40 20 0 0 0 soybeans 80 55 20 0 0 Green Fo Cocktail 300,000 Giant Elephant 20,000 0 Fol Panicum 200000 Omegahiba 200,000 golden fowl 40 20 0 0 0 Jiyeonson Glass 90 75 60 30 0 sorghum 45 35 30 0 0 mura Sakihamasuge 90 75 40 30 0 Velvet Trief 100 70 55 30 0 Onamomi 95 80 50 20 0 Lady Willow Polygonum 100 100 80 50 25 Shiroza 100 100 75 55 35 Akanea Obiyu 100 100 95 60 40 Ivy Morning Glory 　　　　95　　90　　60　35　　0 St. morning glory　　 100 80 50 25 0 Table C Compound 56 Rate - g/ha 125 64 32 16 Germination rear Corn 85 75 65 50 soybeans 100 100 100 100 Green Leaf Foxtail 40 25 0 0 Giant foxtail 40 25 0 0 Fall Panicum 45 　　25　　　0　　　0　　　　　　　　　　　　　　　　　　0 0 0 0 dogfish 100 90 65 35 Jonsson Grass 70 65 60 40 Sorghum 90 85 70 50 Murasaki Hamusuge 100 100 70 35 Velvet Leaf 100 90 55 35 Onamomi 100 80 65 35 Lady Yanagitade 95 85 60 45 Shiroza 55 25 0 0 Akanea Obiyu 100 100 95 65 Ivy Morning Glory 50 20 0 0 Morning Glory 100 100 90 60 Para Light treatment 70 60 55 40 corn Table 6 Compound 56 Rate - g/ha 250 125 64 before germination Corn 000 soybeans 40 　　　　　　　　　　　　G Green Foxtail　　2000 Big Enocolog Sa　　　　　　　　　　　　　　　　　　　　　　　　　　　000 　　　　　　　　　　　　　　0　　0　　　　　　　　　　　　　　0　 0 0 Jiyeonson Grass 55 25 0 Sorghum 　　　　　　　　0　　0　　0　　　　　　　　0　 0 0 velvet leaf 0 0 0 Onamomi 2 0 0 Shiroza 40 30 0 Akaneao Biyu 60 35 0 Ivy Morning Glory 　　　　0　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　3000 Test D L diameter 15c + 11 containing Satusa 7 rum sandy loam soil (pH 6,8; 1% OM) Three or four types of weeds were planted per pot. Cotton was planted separately in pots of the same size. germination 12-16 days after the subsequent planting, i.e. when the plants are at the 2-3 leaf stage (5.5 cm tall) ~12 cm). Pre-emergence planting was done the day before treatment.

The compound is dissolved in a suitable plant-non-toxic solvent and sprayed at 37412/ha, then Plant responses were visually evaluated on a percentage scale after 3 weeks of growth in a greenhouse. Ta. Here, 0 indicates no damage and 100 indicates plant death. The following species were evaluated:

potted Common name: Latin name: am) cotton ( Coker315) Gossypium hirsutu m 2 dogs s Echinochlo a crus-galli 1 Bamiyuda grass Cyno don dactylon 1 broad leaf signal grass B rachiaria platyphylla 1 crabgrass 　　　　　　　　　　-1 Fol Pani Cam Panicum dichotomiflora+ 1 Goose glass Eleusin 1ndica 1 Jiyeon Song Glass Sor Hum Halepense 　　　　　　　　　　　(yperus rotundus) 3 Onamomi Xantium pens ylvanicum 3 Ivy Su+7 @Morning Glory Ipomoe a hederacea 3 Shiroza C henopodium album Aobi: L Ama ranthus retroflexus prickly fern 5i da 5pinosa purse lane Portulaca o leracea sicklebots Ca5sia obtusif olia willow knotweed Po1y onum ersica ris velvet leaf Abutilon theophras ti Hozuki Physalis betero hy The results are shown in Table 1.

1 Table 90 Compound 28 1 Ratio-Mg/ha 125 64 32 16 83 Before germination l 90 90 80 50 203 100 100 100 90 801 Shiroza so so 　　　　o　　　o　　

Velvet leaf 98 90 80 70 70 puri Tree fern 60 60 50 40 20 ciclepo Tsudo 30 30 30 0 0 Onamomi 　　　　　　　90　　90　　90　　90　60CMN Purseley 80 70 60 60 30 Ivy Morning Glory 90 90 70 0 0 Goose glass 30 20 0 0 0 Bermew Douglas 30 20 0 0 0 Dogfish 80 7 0 60 30 20 Jiyeonson Glass 50 40 0 0 0 Fallanicum so so so 　so　　　o　　.

Omnibus japonica 20 20 0 0 0 broadleaf Gunarglas o o o.

Murasaki Hamasuge 100 100 70 70 50 Rede E. Yanagitae 90 90 80 80 80 Broomstick 70 60 60 50 30 Yue Yandan A 16cm diameter Airlite plastic pot was partially filled with Tama silt loam soil. The soil was saturated with water. Japanese and Indian rice seedlings at 2.0-2.5 leaf stage was transplanted to % of the pot. In other months of the pot, Alisma triv. ale), Scrippus (ScripusXScripus paludosus) ), CyperusXCyparus esculentus, and Seedlings or sprouted tubers of Sagittaria spp. were transplanted. Residue Seeds of Echinochloa crus-galli in a pot. The budded tubers of Eleocharis were planted. all these weeds is a major rice weed or weed species important to rice. 3 to 4 days after planting, Raise the water level to 3 cm (approximately 1200 mC/pot) and maintain this level throughout the test; . Within 24 hours of raising the water after formulating the compound in a solvent that is non-toxic to plants Compound treatment was applied directly to rice fields. The pots were kept in a greenhouse. Application rate and treatment? Table 2 summarizes the evaluation of plant responses carried out 21 days later.

Table 2 Compound 1 Rate - g/ha 16 8 4 2 Golden millet 40 20 0 0 caltrops 55 30 0 0 Omodaka 90 85 0 0 sills 50 30 0 0 saji Omodaka 95 90 0 0 Rice Japonica 65 30 10 0 Rice Indica 20 0 0 0 Table E Compound 5 Ratio - g/ha 125 64 32 16 8 Inuhi - 200,000 Water chestnut 20 20 0 0 0 omodaka 90 80 65 0 0 sills o o.

Yellow Rikan Massage 30 0 0 0 0 Sagio Moda Ka 85 70 65 0 0 Rice Japonica 20 0 0 0 0 0 Rice Indica 20 0 0 0 Table E Compound 8 Ratio - g/ha 125 64 32 16 8 Golden millet 80 75 50 0 0 water chestnut 95 90 90 80 70 silps 100 100 100 100 95 Yellow Hamasuge 90 85 80 70 0 Sajio Modaka 100 100 98 95 90 Rice Japonica 75 60 50 40 30 Rice Indica 30 25 20 0 0 Table E Compound 11 Ratio - g/ha 125 64 32 16 8 Golden millet 40 30 0 0 0 water chestnut 　 　 　 　 　 　 90 90 85 75 70 sillp x 100 95 90 85 75 Yellow ・Hamasuge 75 40 0 0 0 Sagio Modaka 98 95 95 80 0 Rice Japonica 60 50 40 20 0 Rice Indica 20 20 20 20 0 Table E Compound 12 Ratio "g/ha" 64 32 16 8 4 Nuvier o o o.

Caltrops 60 60 30 0 0 Silp S o o o.

Yellow Hamasuge o o o.

Sagio Modaka o o o.

Rice japonica o o o.

Rice Indica o o o.

Table 2 Compound 13 Ratio = g/ha 64 32 16 8 4i Nuvier o o o.

Caltrops 70 0 0 0 0 sills o o o.

Yellow Hamasuge o o o.

Sagio Modaka o o o.

Rice japonica o o o.

Rice Indica o o o.

Table 2 Compound 29 Ratio - g/ha 250 125 64 32 16 8 4 Golden millet 80 60 50 50 0 0 0CMN Omodaka 95 90 85 80 0 - -Rice japonica 25 20 15 10 0 0 0 Indica 30 25 20 10 0 0 0 Table E Compound 30 Ratio - g/ha 125 64 32 16 8 Golden millet 20 20 0 0 0 water chestnut o o o.

Omodaka 60 0 0 0 Ine Ja Ponica 30 0 0 0 0 Rice Indica 20 0 0 0 Table E Compound 56 Ratio - g/ha 125 64 32 16 8 Golden millet 80 30 0 0 0 water chestnut 95 85 75 0 0 Omodaka 90 90 70 0 0 sills 100 98 - 0 0 Yellow Hamasuge 40 0 0 0 0 Sagio Modaka 100 90 100 80 40 Rice Japonica 60 20 1 0 0 0 0 Rice Indica 50 20 10 　　　　　0Table 5 Compound 61 Ratio = g/ha 64 32 16 8 4i Nuvier 70 50 0 0 0 caltrops 　 　 　 　 80 　 80 　 0 　 0 0 sills 100 100 80 40 0 Yellow Hamasuge 100 90 80 75 70 Sagio Modaka 100 100 100 95 90 Rice Japonica 5 5 45 30 0 0 Rice Indica 20 10 10 0 0 Table E Compound 64 Ratio - g/ha 64 32 16 8 4i Nubini 65 60 30 0 0 caltrops 　　　　　　　　　90　　90　　　70　　70　-Silps 100 100 85 70 0 Yellow Hama Sedge 95 90 50 40 0 Sagio Modaka 100 100 85 0 0 Rice Japonica ° 50 40 30 10 10 Rice Indica 25 20 10 10 10 Exam F In the post-emergence tank of the test, crop and weed seeds were grown in satsafras sandy loam soil (organic matter 1%) and applied 1 to 3 weeks later. The plants are thus at the point of treatment. It existed as a young plant. Additionally, for post-emergence testing, plants were grown in commercially potted pots. It was grown in a 50:50 mixture of mixture and satsafras soil. To the pre-germinated tank Plant in Tama silt loam soil (3% organic matter) on the day before or on the day of treatment. I did it for The appropriate planting depth is 9 sorghum and 3 to 4 sorghum. c + a; Morning glory, Onamomi, and Hamasuge - 2.5-3 cm; Velvet tree Fu, cyclobod, and Sesbania - 20111; all other species - 0,5 cm Met.

test compound. non-toxic to plants at the concentrations required to obtain the desired application rate. Dissolved/suspended in a clear solvent. This solution or suspension is then applied to the soil by spraying it on 7 leaves. Newly planted into young plants (post-germination tank): Soil surface of container (pre-germination tank) applied to. This application was carried out using an automatic sprayer with a spray capacity of 374Q/ha. t;. Immediately after treatment, the containers are transferred to the greenhouse and, in the case of test post-emergence tanks, the plants are Water as needed, being careful not to get the leaves wet.

The following species were used in the test.

When applied after germination Plant species Scientific name Approximate growth stage Grass weed: Dogfish Echinochloa crus-galli 　　　2-3 leaf Oe/　:l　ell　Sasa　　　5etaria faberi i 2-3 leaf green/-7 oxtail 5ataria vi ridis 2-311 Jiyeonson Glass Sorghum halepense 2-3 leaves Fall Panicum um dichotomiflorum 2-38 purple ++ 7% ma Carex Cyperus rotundus 5-6 leaf signal ・Glass Brachiaria platy hylla 2 -3 leaf meshiba Di 1taria san uinalis 2-3 velvet leaf Abutilon theo hr asti 2-3 leaf Datura Stra moniu+++ 1-2 true leaf hemp sesbania 5esba nia exaltata 1st true leaf sicle pot C@ 551@01) tusifolia 1st True Leaf Onamomi Xantium pensylvanicu+m Second true leaf ivy -Leaf morning glory I oa+oea hederacea l-2 True leaf hartade Yanagitade Po1y onu+l1ersicaris 　　　　　　　3-4 leaves Aobiyu A+naranthuS retroflexus 4-58 Shiroza Chenopodium album 4-511 Teeweed 5ida 5pinosa 2-31 Seiyou Black Nightshade 5olanu+a tycanthu+a Second True Leaf Soybean (Williams) Kai Mukani WmX 1 Tricotyledons Approximately 2 and 4 weeks after treatment on the post-emergent and pre-emergent cisterna, respectively, the southern We conducted a plant response evaluation at the end of the day. Evaluation is done on a percentage scale from 0 to 100. Ta. Here is a plant response rating of 0 - no damage and 100 - plant death. Summarize in table.

Table F Compound 28 Ratio g/ha 250 125 64 32 　　　16 Before germination Soybeans 40 0 0 0 0 Corn 20 10 10 0 0 Velvet Leaf 60 50 40 20 0 Chiyosenagao 70 70 40 0 0 sicle pots 40 20 0 0 0 0 Hemp Sesbania 40 20 0 0 0 0 Onamomi 75 50 30 0 0 Ivy-Morning Glory 50 50 30 0 0 Madder Aobiyu 95 90 75 60 30 Shiroza 100 80 60 50 40 Prickly Fern 40 20 0 0 　　　　　　　　　　　　　　　　50　　　20　　0　　　0 　　　　　　　　　　　　　20　　　0　　0　　0　 　　　Green Foxtail　　o　　ooo.

Johnson Glass 30 0 0 0 0 Huo Le Panicum 40 20 0 0 0 ome Hishiba ooooo.

Broad leaf signal grass ooo.

A? fki/%? 2 games 80 70 60 40 20 Lady Yanagitade 85 75 60 40 20 Black Nightshade 75 50 30 0 0 Table 1 Compound 34 Ratio g/ha 125 64 32 16 8 4 After germination Soybeans 20 0 0 0 0 0 Corn 40 30 0 0 0 0 Velvet leaf 80 70 50 40 30 20 Chiyosenagao 80 60 50 40 30 20 sicle pots 50 30 0 0 0 0 Hemp Sesbania 98 90 70 40 20 0 Onamomi 100 100 70 6 0 50 40 Ivy morning glory 100 100 1 00 100 70 50 Akanea Obiyu 98 9 0 80 70 40 20 Shiroza 50 30 20 0 0 0 Brickley Fern 　o　　　o　　oo.

Golden millet 50 40 30 0 0 0 Giant foxtail grass 30 0 0 0 0 0 0 Green Foxtail 30 0 0 0 0 Jiyeon Song grass 50 30 0 0 0 0 four Le Vanicum 30 0 0 0 0 0 Omega o o o.

Broad leaf signal grass 50 30 0 0 0 0 0 Murasaki Hamasuge 80 70 60 50 0 0 Black Nightshade 95 85 80 20 0 0 Exam G I planted the following seeds.

Name Rfm-11111 1 large cone Black grass, stage ■Alopecurus myosuroides 14.0 Shiroza, common species Chenopodium al bum CO catchweed bed Stroke 0 Gallium aparine 9 ．． 0 Russian Thistle 5 Alsoa Kali 6.0 Black Nightshade, Oriental Solanum nigrum 2.0 Gumbinazuna TH1ASPI ARVENSE 2.5 Ivy Leaf Stag Beetle Veronica he deraefolia 5. Q field stag beetle.

Common species Veronica persica 6 ．． 0 field pansy Viola arvensis After 1.52 days, a second series based on the following species was planted.

Name Genus Species Size cm) Blackgrass, 1st stage Alopecurus + nyosuroide s 6.0 oats, stage ■ Avena fatua 　　　　　　　22.0 Sugar dai: I7　　　　　　　　Beta vulga ris 8.0 Brassic a napus 13.0 Koc hia 5 coparia 5.0 Chamomile, odorless species Matricaria 1nodora 4. Q1 year older Chigotuna Gi Poa annua 7.0 Yasei Soba Polygonum convolvulus 7.0 Seven days after the first planting, a third pot was prepared with the next seed.

Name Genus Species Size cm) Diinted Gordgrass Aegilops cylindrica 12.0 Oats, Stage I Avena fatua 15.0 All post-emergent plantings should be kept in the greenhouse until herbicide application. Let it grow I;. Pre-emergence treatments are applied in the same manner as described for post-emergence treatments. This was prepared immediately before herbicide application. Application of herbicides requires first applying the technical substance to the plant. Dilute in a non-toxic solvent and spray onto plants and soil surfaces using a belt sprayer. All were performed by applying six components.

After treatment, all components were removed to a greenhouse where they were kept at a temperature of 19°C at night and 30°C during drying. , 16 hours of sunlight, and 45 to 80% relative humidity for 21 days. At this time Using a visual scale with dots of 0 representing no inhibition and 100 representing complete inhibition. All species were evaluated. The test results are summarized in Table G.

Table G Compound 1 Ratio g/ha 32 16 8 4 2 Before germination Whole wheat 30 10 0 0 0 0 Fuyu wheat 30 20 0 0 0 0 Haru Barley 60 60 40 2 0 0 Fuyu barley 80 40 30 10 0 Oats 20 10 0 0 0 Downey Brohm 20 20 0 0 0 0 Suzume no Chiyahiki 20 10 10 0 0 Blank glass 80 60 60 30 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　90　　90　　50 40 20-older ryegrass 20 10 0 0 0 0 Joynt Goatgelas oooooo.

Green 7 Oxtail 100 50 20 10 0 rapeseed 100 100 100 90 70 Kisetsuchiweed Bed Straw 80 70 50 40 20 Yasei Soba 70 70 70 60 40 Kotia 6 0 60 40 20 0 Chamomile 90 90 8 () 70 30 Black Nightshade 70 60 60 40 30 Field Stag Beetle 50 50 40 30 0 Ivy Stag Beetle 　　　　100　　90　　80　　60　　30 Sugar Dai:) 100 100 100 90 80 Shiroza 　　　　　　100　　90　　80　　80　　　60 Gunbai shepherd's purse 100 100 80 70 40 field Violet 100 90 90 70 50th 0 table Compound 1 Ratio g/ha 32 16 8 4 2 After germination Whole wheat 20 － 0 0 0 0 Fuyu wheat 10 0 0 0 0 0 hull barley 10 0 0 0 0 0 Fuyu Barley 30 20 10 10 　　　　　　　　　　　　　　　　　　　　　　　　oooo.

Oat stage 2　　　　　　　oooo.

Downey Brohm 30 30 10 0 0 Suzume no Chiyahiki 40 30 30 0 0 Black Glass 50 40 20 20 0 Black Grass Stage 2 40 40 3 0 30 0-Early Strawberry Tsunagi oooo.

- Older Rye Grass 10 0 0 0 0 0 Joynt Goatgelas oooooo.

Green Foxtail 　　　oooo.

Brassica 100 100 100 100 100 Kisetsuchiweed Bed Straw 90 60 40 20 0 Yasei Soba 70 60 40 40 20 Futia 70 40 30 20 0 Chamomile 90 80 70 60 40 Black Nightshade 60 50 50 40 30 field stag beetle U　　　　　oooo.

Ivy Stag Beetle 60 30 0 0 0 0 sugar dace = 7 100 100 100 10 0 100 Shiroza 20 10 0 0 1 00 90 40 field violet 60 40 20 0 0! sac Compound 5 Ratio 9/ha 64 32 16 8 4 Before germination Harukomugi 　　　　　　　　　　　　000007 Yukomugi 　　　　　　00000Haru Barley　　　　　　　　　　00000 7 Jubarley 10 0 0 0 0 0 Oat 00000 Downey Prome 　　　　　　00000 Sparrow Sparrow 　　　　　　　　　00000 Black Glass 30 10 0 0 0 - Handmade Strawberry Nagi 40 10 0 0 0-Older Rye Grass 30 10 0 0 0 Joint Goat Geras 20 20 0 0 0 Green 7 Onk Tail 10 0 0 0 0 0 Brassica 80 80 70 　　　　40　　　20 Kisetsuchiweed Bed Straw　　70　　60　 40 0 0 Yasei Soba 90 7 0 50 30 0 Kotia 20 0 0 0 0 0 Chamomile 70 50 30 0 0 Black Nightshade 40 10 0 0 0 Field Stag Beetle 30 30 0 0 0 Ivy Stag Beetle 100 80 70 40 10 sugar beet 100 100 100 90 90 Shiroza 　　　　　　　　　80　　70　40　　20　　0gunbai Shepherd’s purse 70 20 10 0 0f field pie, tre) 100 100 90 8 0　　　40Table G Compound 5 Ratio g/ha 64 32 16 8 4 After germination Hull wheat ooooo.

7 Yukomugi　　　　　　　　　　　oooo.

Haru barley 　　　　　　　　　　　　　　　　　　　　　oooo.

Fuyu barley 　　　　　　　　　　oooo.

Oats 　　　　　　　　　　oooo.

Oat second stage 10 0 0 0 0 Downey Prohm 　　　　　　　oooo.

Suzume no chahiki 　　　　　　　　oooo.

Black Glass　　　　　　　　　oooo.

Black grass second stage 30 20 0 0 0 0-Early Strawberry Tsunagi o, o .

-Older Rye Grass　　　　　　　　　　　　oooo.

Joynt Goatgelas oooooo.

Green Foxtail 30 0 0 0 0 Brassica 100 100 100 90 　　　　　80　　　　　　10　　　10　　0　　0　 0 0 Yanaisoba 80 80 60 40 30 Kotia 90 80 60 40 10 chamomiles too 80 70 50 30 Black Nightshade 70 60 30 20 0 Field Stag Beetle 20 0 0 0 0 Ivy Stag Beetle 　　　　　　oooo.

Sugar beet 100 100 100 70 ．． 70 Shiroza 80 80 70 　70　　40　　　　　　　　　　　　　　　100　　90 90 60 20 Field Violet 30 20 0 0 Table G Compound 6 Ratio e/ba 125 64 32 　16 Before germination Halic wheat 10 0 0 0 7 Yukomugi 0 0 o Hull Barley 10 0 0 0 07 yu Barley 10 0 0 0.

Oats 20 0 0 0 Downey Brohm -10000 Sparrow 　　　　　ooo.

Black Glass 40 10 10 0 - Hand raw strawberry eel 30 30 20 0 - Older ryegrass 20 20 0 0 Joynt Goatgelas 10 0 0 0 0 Green Foxtail 20 0 0 0 0 rapeseed 100 100 100 80 Kisetsuchiweed Bed Straw 90 90 30 20 Yasei Soba 100 100 90 70 Kotia 50 50 30 0 Chamomile Modoki 90 40 30 10 Black Night Shade 90 80 60 10 Field Stag Beetle 40 30 20 0 Ivy Stag Beetle 100 100 60 3G sugar carp:’/ 100 100 100 100 Shiroza 10G 90 100 00 80 50 field violet 100 100 90 70 Table 0 Compound 6 Ratio g/ha 125 64 32 16 after germination Whole wheat ooo.

Fuyukomugi 0 0 0 0 Haruo Wheat 0 0 Fuyu barley 0 0 0 0 Oat 　　　　　　　　　　　0　　　0　　　　　　　　　　　　　　　　　　 0 0 0 0 Downey Brohm 1 0 0 0 0 0 Suzume no Chiyahiki 0 0 0 0 Black Glass 0 0 0 0 Blank glass 2nd stage 0 0 0 0 0-Hisei Ichigo Tsunagi 0 0 0 0 0 0-Early Rye Grass 0 0 0 Jyoi Nto Gortogelas ooo.

Green Foxtail 20 20 0 0 Brassica 100 100 100 100 Kisetsuchiweed Bed Straw 80 70 30 20 Yasei Soba 100 100. 90 80 Kotia 70 50 40 　　　　　　　　　　　　　　　100　　100　　8 0 60 Black Nightshade 80 70 6 0 40 Field Stag Beetle 10 0 0 0 0 Ivy Stag Beetle 70 60 4 0 0 Sugar beet 100 100 100 100 Shiroza 100 100 　　　　　　　　　　60　　　　　　　　　　　　　　100　　8 0 70 50 field violet 90 6 0 20 0! Wheat Compound 8 Ratio 9/ha 125 64 32 16 8 4 Before germination Whole wheat 20 10 0 0 0 0 0 Fuyu wheat 20 20 10 0 0 0 Hull Barley 30 10 0 0 0 0 Fuyu barley 50 50 20 1 0 0 0 Oats 20 10 0 0 0 0 Downey Prome 50 30 1 0 0 0 0 Sparrow Chiyahiki 80 50 30 10 0 0 Black Glass 80 80 70 50 20 10 - Hand raw strawberry eel 70 70 60 50 40 40 - Plain ryegrass 20 10 0 0 0 0 Joint Goat Geras 20 10 0 0 Q O Green Fox Tail 90 70 70 30 0 0 Brassica 　 　 　 　 　 100 100 90 90 80 70 kise Aardvark Bedstraw 90 70 40 40 20 0 Yasei Soba 90 80 70 50 10 0 Kotia 50 20 20 0 0 0 Chamomile Modoki 80 80 70 70 60 40 Black Nightshade 70 7 0 60 50 30 20 Field Stag Beetle 60 50 50 40 40 30 Ivy Stag Beetle 70 50 40 20 0 0 Sugar beets 90 80 80 80 70 60 Shiroza 100 90 90 80 70 50g Mbaina Zuna 100 100 100 90 80 70 Field Violet 70 70 60 6 0 50 40 boxes Compound 8 Ratio g/ha 125 64 32 16 8 4 After germination Whole wheat 20 10 10 0 0 0 Fuyu wheat 10 10 0 0 0 0 Hull Barley 20 10 10 0 0 0 Fuyu Barley 60 30 30 10 10 0 Oats 10 10 0 0 0 0 Q Oats 2nd stage 10 10 0 0 0 0 Downey Brohm 20 10 0 0 0 0 Sparrow Chiyahiki 50 5 0 50 30 20 10 Black Glass 70 70 50 40 20 10 Black Grass 2nd Stage 　　　　　　80　70　60　　50　20　　0-Hirao Strawberry Tsunagi 　　　　　　　20　20　10　　10　　0　　0-Horizontal ryegrass 20 10 0 0 0 0 joint go Togeras 40 40 20 20 10 0 Glee Foxtail 70 70 50 30 20 0 rapeseed 100 100 100 100 1 00 100 Kisetsuchiweed Bed Straw 90 70 60 50 30 20 Yasei Soba 70 70 40 40 30 20 Kotia 70 40 30 30 10 0 Chamomile 100 100 100 100 90 90 Black Nightshade 60 50 40 30 30 0 field hoe Gatasou 20 0 0 0 0 Ivy Kuwaga Tasou 60 30 10 0 0 0 Sugar Daiko 100 100 100 90 90 60 Shiro The 70 70 40 40 20 20 Goombai shepherds 100 100 100 10 0 100 100 Field Violet 30 10 0 0 0 0 Table G Compound 9 Ratio g/ha 64 32 16 9 4 2 Before germination Whole wheat 30 20 10 0 0 0 Fuyu wheat 30 10 0 0 0 0 Hull barley 50 40 30 10 0 0 Fuyu Barley 50 50 20 10 0 0 Oats 30 20 10 0 0 0 Downey Brohm 40 40 20 10 0 0 Suzume no Chiyahiki 60 50 30 20 10 0 Black Glass 90 90 80 70 70 40-Early strawberry eel 70 70 60 40 30 10-Early Ryegrass 30 10 10 0 0 0 joint Goat Geras 20 20 10 0 0 0 Glee Foxtail 60 60 60 40 30 0 rapeseed 100 100 100 90 90 80 Kisetsuchiweed Bed Straw 70 70 50 40 40 20 Yasei Soba 90 9 0 80 70 50 40 Kotia 40 0 0 0 0 0 Chamomile 90 90 90 80 60 40 Black Nightshade 　　　　　50　50　50　50　　30　　20field quaga Tasou 50 50 40 30 30 20 Ivy ・Stag Beetle 40 30 0 0 0 0 Sato Radish 100 90 90 90 80 70 Shiroza 100 90 80 80 60 40 Goombai shepherd 100 100 10 0 90 90 70 Field Violet 70 50 40 40 20 0 cold Compound 9 Ratio e/ha 64 32 16 8 4 2 After germination Whole wheat ooooooo.

Fuyu wheat ooooooo.

Haru barley 20 10 0 0 0 0 0 Ayu barley 40 30 20 10 0 0 Oats 20 0 0 0 0 0　　　　　　　　　　　　　　　　　　　　oooooo.

Downey Brohm 20 10 0 0 0 0 Suzume no Chiyahiki 30 10 0 0 0 0 0 Black Glass 60 60 50 40 20 0 Black Grass Stage 2 70 60 50 20 0 0-Early Strawberry Tsunagi 60 50 3 0 10 0 0-Early ryegrass ooooooo.

Joynt Goatgelas 50 50 30 10 0 0 Green Foxtail 40 40 20 10 0 0 Brassica 100 100 100 100 100 90 Kisetsuchiweed Bed Straw 70 4 0 30 10 0 0 Yasei Soba 60 60 40 20 0 0 Kotia 60 40 20 0 0 0 Chamomile 100 100 90 80 70 70 Black Night Shae De 50 50 40 30 10 0 field Stag beetle 20 10 0 0 0 0 Ivy Stag Beetle 30 0 0 0 0 Sugar Dai Con Rosa 70 70 60 20 0 0 Gunbai Nazuna 100 100 100 100 1 00 100 Field Violet 40 10 0 0 0 0 Table G Compound 11 Ratio e/ha 125 64 32 16 8 4 Before germination Harukomugi　　　　　　　　　　　　0000007 Yukomugi 10 0 0 0 0 Hull barley 10 0 0 0 0 Fuyu barley 20 20 10 10 0 0 Oats 10 0 0 Downey Plow M Ki 　　　　　　　20　20　20　10　　0　　0black Gu5s 80 70 60 40 30 20-Early strawberry eel 70 60 50 50 30 20-Early Lygra S 40 20 10 0 0 0 joint ・Goat Geras 30 10 10 0 0 0 Gris Foxtail 70 70 50 30 20 0 rapeseed 100 100 100 100 90 90 Kisetsuchiweed Bedstraw 90 70 7 0 50 50 10 Yasei Soba 100 1 00 100 90 90 40 Kotia 30 20 20 0 0 0 Chamomile 100 100 90 70 40 10 Black Night Shae Do 60 60 50 40 40 20 field ・Stag beetle 70 70 70 50 40 30 Ivy Stag Beetle 100 70 50 40 2 0 0 Sugar beet 100 100 90 90 90 90 Shiro The 90 90 80 70 70 50 Gunbai shepherd's purse 100 100 100 90 80 60 Field Violet 80 50 4 0 40 30 Table 10 G Compound 11 Ratio g/ha 125 64 32 16 8 4 After germination Whole wheat 10 10 0 0 0 0 07 Yukomugi 20 10 10 0 0 0 Hull Barley 20 10 0 0 0 07 Yubarley 20 10 10 0 　0　　0 Oats　　　　　　　　　　　oooooo.

Oats second stage　　　　　　　oooooo.

Downey Brohm ooooo.

Suzume no chahiki 　 　 　 　 oooooo.

Black Glass 10 0 0 0 0 0 0 Black grass second stage 30 20 20 0 0 0-Early Strawberry Tsunagi 20 20 10 0 0 0-Early Ryegrass 20 0 0 0 0 0 0 Joint Goat Geras 20 10 0 0 0 0 Green Foxtail 40 20 0 0 0 0 Brassica 100 100 100 100 100 100 Kisatsuchiweed Bedstraw 80 50 50 40 40 20 Yasei Soha 1oolooo705o301Oko Cheer 60 50 30 10 0 0 Chamomile Modoki 100 80 70 50 40 20 Black Nightshade 70 70 60 50 50 40 Field Stag Beetle 30 3 0 30 20 10 0 Ivy Stag Beetle 8 0 70 20 10 0 0? )'7 Thailand: 27 100 100 100 80 60 60 Shiroza 　　　　70　70　70　50　20　　20 Goombai shepherd 　　　　　　　100　100　100　　90　100　40 feel Violet 50 30 10 0 0 0th G table Compound 12 Ratio g/ha 125 64 32 16 8 4 Before germination Whole wheat 30 10 0 0 0 0 Fuyu wheat ooooooo.

Haru barley 10 0 0 0 0 0 0 Fuyu barley 20 10 0 0 0 0 0 Oats 20 10 0 0 0 0 Downey Brohm 10 0 0 0 0 0 0 Suzume no Chiyahiki 30 10 0 0 0 0 Black Glass 40 30 30 10 0 0-Early Strawberry Tsunagi 50 50 30 20 0 0-Early ryegrass 40 10 0 0 0 0 Joint Goat Geras 40 10 0 0 0 0 Green Foxtail 40 10 0 0 0 0 Artex Abra f 100 1 00 90 80 80 50 Kisetsuchiweed Bed Straw 70 60 50 50 30 10 Yasei Soba 100 100 100 100 90 6Q Kotia 80 50 50 30 20 20 kamitsu Remoto* 100 90 90 70 70 40 Plaque Night Shade 80 80 70 70 60 50 Field Stag Beetle 90 90 8 0 80 40 30 Ivy - 7'7 Rattle 80 80 70 40 20 10s 14 die=+n100 100 100 100 100 90 Shiroza 100 90 9 0 80 80 60 Goombai shepherd 100 100 90 80 30 20 Field Violet 1 00 90 90 Bo 50 φ! Tatemae Compound 12 Ratio 9/ha 125 64 32 16 8 4 After germination Whole wheat 10 0 0 0 0 0 0 Fuyu wheat 20 10 0 0 0 0 0 hull barley 10 0 0 0 0 0 0 Fuyu Barley 10 0 0 0 0 0 0 oats ooooo.

Oats second stage　　　　　　　oooooo.

Downey Prohm ooooooo.

Sparrow Sparrow 30 0 0 0 0 0 0 Black Glass 20 10 0 0 0 0 Black Glass 2nd Stage 30 10 0 0 0 0 0-Early Strawberry Tsunagi 30 10 0 0 0 0-Senyu Ryegrass 20 0 0 0 0 0 0 Joint Goat Geras 3 (1100000 Green Leaf) Foxtail 40 20 20 0 0 0 Artek Brassica 100 100 100 100 100 90 Kisetsuchiweed Bed Straw 90 80 80 50 50 40 Yasei Soba 90 90 90. 80 80 70 Futia 70 70 60 40 20 10 Chamomile 9 0 70 60 40 20 0 Black Nightshade 70 70 50 40 20 20 field stag beetle C 50 50 20 20 10 0 Ivy Mulberry Gatasou 60 20 0 0 0 0 Sugar daiko 100 100 100 100 100 90 Rosa 70 70 60 60 30 　　　　　10　　　　　　　　　　　100　100　100　1 00 100 80 field violet 50 50 50 40 10 10 Table G Compound 13 Ratio g/ha 125 64 32 16 8 4 Before germination Pa Jp’: 2”gi 0000007 Yukomugi 10 0 0 0 0 Hull barley 10 10 0 0 0 Fuyu barley 10 0 0 0 0 Oats 10 10 0 Downey Bro Room ooooo.

Suzume no chahiki 　 　 　 　 　 oooooo.

Black Glass 30 0 0 0 0 0 0 - Senju Ichigo Nagi 30 20 0 0 0 0 0-Senyu ryegrass 10 10 0 Q 0 0 Joint Goat Geras 20 10 0 0 0 0 Green Foxtail 50 10 0 0 0 0 Artex Brassica 100 100 90 90 80 70 Kisetsuchiweed Bedstraw 100 60 60 50 50 20 Yasei Soba 9 0 90 90 90 70 60 Kotia 70 40 40 30 20 0 Chamomile 90 90 70 30 20 0 Black Night Shade 90 70 70 - 30 20 Fee Ludo Stag Beetle 40 40 30 30 10 0 Ivy Stag Beetle 100 60 30 0 0 0 Sugar dai:) 7 100 100 100 1 00 90 90 Shiroza 90 90 90 90 70 60 Goombai shepherd's purse 90 80 80 70 70 40 field violet 90 90 70 60 50 40! bag Compound 13 Ratio g/ha 125 64 32 16 8 4 After germination Whole wheat ooooooo.

Fuyu wheat ooooooo.

Hull barley ooooooo.

7 Yubarley ooooooo.

Oats ooooooo.

Oats second stage　　　　　　　oooooo.

Downey Brohm ooooo.

Suzume no chahiki 　 　 　 　 oooooo.

Black Glass　　　　　　　　oooooo.

Black Grass Stage 2　　　　　oooooo.

- Senshu Ichigo Tsunagi　　　　　　　　oooooo.

- Senshu ryegrass　　　　　　　　　　oooooo.

Joint Goat Geras 200000-0 Green Fock Stale 　　　　20　0　　0　　0　　　0　　0 Artex Abra 100 100 100 100 100 80 kisetsuchi Weed Bedstraw 90 90 70 60 50 3 0 Yasei Sopa 70 70 50 40 2 0 0 Kotia 80 50 40 2 0 0 0 Chamomile 100 100 8 0 70 40 30 Black Nightshade 80 60 50 50 40 30 Field Stag Beetle 20 0 0 0 0 0 Ivy Stag Beetle 　oooooo.

Satogui = ln 100 100 100 100 100 90 Shiroza 90 90 90 90 30 0g Mbaina Zuna 100 100 100 100 8 0 60 field violet 10 0 0 0 0 0 Table G Compound 29 Ratio g/ha 125 64 32 16 8 4 Before germination Whole wheat 10 0 0 0 0 0 0 7 Yukomugi 20 0 0 0 0 0 0 Haru barley 30 10 0 0 0 0 Fuyu Barley 30 20 10 10 0 0 Oats 40 10 0 0 0 0 Downey Brohm 30 20 0 0 0 0 Sparrow Sparrow 40 20 20 0 0 0 Black Glass 90 90 60 40 10 0 - Senju Ichigo Nagi 80 80 60 50 2 0 10-Senyu Rye Grass 50 40 20 10 10 0 Jiyo Into Gotogelas 50 30 10 0 0 0 Green Foxtail 90 70 50 40 2 0 0 Brassica 100 100 90 9 0 90 90 Kisetsuchiweed Bedstraw 90 80 60 50 30 0 Yasei Soba 100 1 00 100 90 60 30 Kotia 50 50 50 40 10 0 Chamomile Modoki 100 90 60 50 30 10 black nights Aid 60 50 50 40 20 0 feel Stag beetle 90 90 70 60 40 2 0 Ivy Stag Beetle 100 90 90 70 40 20 Sato Dynia 100 100 100 100 90 90 Shiroza 100 9 0 90 60 30 10 Gumpaina Zuna 100 80 70 50 20 0 Field Violet 　　　　100　100　90　90　　80　60! Dan! Compound 29 Ratio y/ha 125 64 32 16 B 4 After germination Bulk wheat ooooooo.

Fuyu wheat 10 0 0 0 0 0 Haru barley 10 0 0 0 0 0 0 7 Jubarley 10 10 0 0 0 0 0 oats ooooo.

Oat stage 2　　　　　oooooo.

Downey Brohm 40 0 0 0 0 0 Suzume no Chiyahiki 　　　　　　oooooo.

Black Glass 50 40 20 10 Q Q Black Glass 2nd stage 70 50 40 3 0 20 0 - Older Strawberry Nagi 30 10 0 　　　　　0　　0　　　　　　　　　　　　　　　　oooooo.

Joynt Goatgelas 20 10 0 0 0 0 Green Foxtail 50 50 40 30 20 0 rape 100 100 100 100 100 100 kisetsuchi Weed Bedstraw 70 50 50 30 10 0 Yasei Soba 100 100 80 60 5 0 40 Kotia 100 100 90 90 80 50 Chamomile Motoi 100 1 00 100 90 90 70 Black Nightshade 70 40 40 30 30 10 Field Stag Beetle 　 　 　 50 50 30 20 0 0 Ivy Stag Beetle C 60 60 50 30 10 0 Sugar daiko 100 100 100 100 100 100 series Rosa 80 70 70 60 40 10 Gunbai shepherd's purse 100 100 80 7 0 60 50 Field Violet 90 90 70 50 30 0 Table G Compound 31 Ratio g/ha 125 64 32 16 8 Before germination Bulk wheat 40 30 10 0 07 Yukomugi 40 20 IQ OQ Hull Barley 50 40 30 20 10 barley 60 40 30 20 10 oats 50 30 20 0 0 Downey Prome 6 0 40 40 20 0 Suzume no Chiyahiki 70 70 50 40 20 black glass 　　　　　　80　　80　　70　　　60　　40-Chisei Strawberry Tuna Gi 　　　　　　　　　70　　60　　50　　40　　20-Handleig Last 40 30 30 20 10 Into Gotogelas 30 20 20 10 0 Green Foxtail 100 80 50 30 20 Brassica 100 100 10 0 100 90 Kisetsuchiweed Bedstraw 80 80 60 50 30 Yasei Soba 90 80 80 70 40 Kotia 70 50 40 20 0 Chamomile 　　　　100　　100　　90　　90　80 Black Knight Code 70 70 50 40 20 fields ・Stag beetle 90 90 80 70 50 a Ivy Stag Beetle 100 80 80 50 30 sugar beets 100 90 90 8 0 70 Shiroza 100 90 80 80 60 Goombai shepherd's purse 90 90 80 80 60 field violet 100 1 00 80 60 30 Table G Compound 31 Ratio g/ha 125 64 32 16 8 After germination Bulk wheat o.

Fuyufumugi 10 0 0 0 0 0 hull barley 10 0 0 0 0 0 Fuyu Barley 20 10 0 0 0 oats 20 0 0 0 0 power rasmugi 2nd stage 20 10 0 0 Downey Brohm 0 o Downey Brohm o.

Sparrow Sparrow 30 30 20 0 0 Black Glass 80 80 70 50 30 Black Grass 2nd Stage 80 70 7 0 40 20-Chisei Ichigo Tsunagi 10 10 　　　　　　0　　　　　　　　　　　　　　　　　　　10 0　　0　　0　　　0　　　　　　　　　　　30　 10 0 0 0 Green Foxtail 60 60 30 20 07 5s 100 100 100 100 80 Kisetsuchi 9 Eid Bed Straw 80 60 40 40 20 Yasei Sopa 100 100 90 80 60 Kotia 70 40 30 10 0 Chamomile Moto+ 100 100 80 60 40 Black Night Shae Do 50 30 20 20 10 field Qin Stag Beetle 20 10 0 0 0 Ivy Stag beetle o.

Sato'F Thailand: 1n 100 90 70 60 40 Shiroza 40 30 10 0 0 gunba Inaz + 100 100 100 80 60 field violet 30 0 0 0 　　　　Table G Compound 35 Ratio s/ha 125 64 32 16 8 4 Before germination Bulk wheat 10 0 0 0 0 1 0 fuyu wheat ooooooo.

Haru barley 30 10 0 0 0 07 Yubarley 40 20 20 20 0 0 oats 20 10 0 0 0 0 Downey Prome 20 10 10 0 0 0 Sparrow Chiyahiki 40 40 30 20 0 0 Black Glass 80 70 4 0 20 0 0-Hirao Ichikotsunagi 60 60 50 50 40 30 - Plain ryegrass 40 40 30 20 20 0 Joint Goat Geras 30 30 10 0 0 0 Green 7 Oxtail 50 50 30 10 0 07/U+ 100 100 100 100 100 90 kisetsuchiui de bedstrow 80 80 70 70 50 50 yase Isoba 100 90 90 70 50 30:l? 7 80 80 50 4 0 20 0 Chamomile Modoki 1OO10080705o30 Black Night Shade 70 60 50 40 20 0 fee Ludo Ri7 Kata/Tsu 100 90 90 90 80 70 Ivy -F7 Kata'/'7 100 100 100 100 100 90”l’>f icon 100 100 100 100 100 100 Shiro The 100 90 80 80 60 50 Kunhainasuna 1o09o909o8070 Field Violet 1001 oo80705o20 Table 0 Compound 35 Ratio g/ha 125 64 32 16 　　　g　　　　4 After germination Whole wheat 10 0 0 0 0 0 0 Fuyu wheat 20 10 0 0 0 0 Haru barley 20 10 0 0 0 0 07 Yubarley 10 0 0 0 0 0 0 oats ooooo.

Oats second stage　　　　　　　oooooo.

Downey Brohm ooooooo.

Suzume no chahiki ooooooo.

Black Glass 70 60 40 20 0 0 blank glass second stage 70 50 50 30 10 0-Handmade Strawberry Tsunagi 20 10 10 0 0 0 - Older Rye Grass 20 20 2 0 0 0 0 Joint Goat Geras 20 to OOOO Clean Foxtail 20 0 0 0 0 0 rapeseed 100 100 100 100 100 90 Kisetsuchiweed Bed Straw 90 80 70 50 30 10 Yasei Soba 100 10 0 80 60 30 20 Kotia 70 70 50 30 10 0 Chamomile 100 100 90 80 70 50 Black Night Shae Do 40 30 10 0 0 0 field hoe Gatasou 70 50 40 20 0 0 Ivy Stag beetle 50 30 2θ 0 0 0 Sugar beetle Con 100 100 100 100 90 70 Shiroza 70 40 30 10 0 0 Kunhainasuna 1001o0100806050 Field Violet 60 50 40 20 0 0! And blue Compound 36 Ratio g/ha 125 64 32 16 11 Before germination Hull wheat ooooo.

Fuyu wheat 20 10 0 0 0 Haru Barley 10 10 0 0 0 Fuyu barley 30 20 10 10 0 Oats 30 10 0 0 0 Downey Brohm 20 0 0 0 0 Sparrow Chiyahiki 20 2 0 10 0 0 blank glass 40 40 30 30 20-Chisei Ichigo Nagi 50 50 40 40 20-older ryegrass 40 20 10 0 0 Joint Goat Geras 　　　　　　20　　20　　0　　　0　　　0 Green・7 Otsuk Stale 30 20 10 0 0 Brassica 100 100 100 100 100 ki Setsuweed Bedstraw 90 80 80 60 50 Yayisoba 90 90 9 0 80 70 Kotia 70 7 0 50 30 20 Chamomile 1 00 100 90 90 70 Black Nightshade 　　　　　80　　80　　70　　50　　50 Field Kuga Tasou 70 70 60 60 50 Ivy ・Stag beetle 100 100 80 60 4 0 sugar beet 100 100 100 10 0 90 Shiroza 90 80 8 0 60 50 Goombaina Zuna 100 1 00 90 80 60 field violet 100 100 90 70 50asG table Compound 36 Ratio g/ha 125 64 32 16 8 After germination Whole wheat o.

7 Yukomugi o o o o .

Hull barley o.

7 Jubarley o.

Oats o o o.

Oat second stage 20 0 0 0 0 0 Downey Brohm .

Sparrow-no-chahiki o o o.

Black Glass 30 20 0 Q O Black Glass 2nd stage 30 20 10 0 0 - Handmade Strawberry Tsunagi 10 0 0 0 0 0-Older Rye Grass o o.

Joynt Goatgelas o o o .

Green Foxtail o o o.

Brassica 100 100 100 100 80 Kisetsuchiweed Bed Straw 70 60 40 20 0 Yaseisopa 100 100 90 70 50 Kotia 50 40 30 10 Q Chamomile Modoki 1 00 90 80 70 40 Black Nightshade 70 40 20 10 0 field stag beetle C o o o.

Ivy stag beetle o o o.

Sugar beet 100 100 90 90 60 Shiroza 20 0 0 0 0 0 Gunbai Nazuna 100 100 9 0 90 70 Field Violet 10 0 0 Table G Compound 55 Ratio g/ha 125 64 32 16 8 4 Before germination Whole wheat o-ooo.

Fuyu wheat ooooooo.

Haru barley 10 10 0 0 0 0 0 Fuyu Barley 30 20 10 0 0 0 oats 30 10 0 0 0 0 Downey Brohm 30 10 0 0 0 0 Sparrow Chiyahiki 40 40 20 10 0 0 Black Glass 60 60 6 0 40 20 10-Handmade Strawberry Tsunagi 60 60 50 30 0 0-Older ryegrass 60 50 50 30 0 0 Joint Goat Geras 10 0 0 0 0 0 Green 7 Oxtail 60 60 30 20 0 0 Brassica 100 100 100 100 70 70 Dostraw 80 60 60 50 40 10 Yasei Soba 100 100 90 70 70 40 Cotia 90 80 70 50 3 0 t.

Chamomile modoki 100 90 70 70 6 0 20 Black Nightshade 70 70 50 50 0 0 Field Stag Beetle 80 80 8 0 70 50 30 Ivy-F'7 7 rattles 100 90 80 80 60 40 Sugar dai: 100 100 100 100 9 0 80 Shiroza 90 90 90 80　　70　　60　　　　　　　　　　　　100　90 80 60 10 0 field &/<i:t 7 to 100 100 90 70 60 20 Table 0 Compound 55 Ratio e/ha 125 64 32 16 8 4 After germination Whole wheat ooooooo.

Fuyu wheat ooooooo.

Haru barley 10 0 0 0 0 0 0 Fuyu barley ooooooo.

Oats ooooo.

Oat second stage 10 0 0 0 0 0 da Unnie Blohm ooooo.

Suzume no chahiki ooooooo.

Black Glass 100 60 60 30 10 0 Black Grass Stage 2 90 70 40 1 0 - 0 - Early strawberry eel 20 20 20 　0　　0　　0-Older Rye Grass　　　　　　　oooooo.

Joynt Goatgelas 10 0 0 0 0 0 Green Foxtail 20 10 0 0 0 0 rapeseed 100 100 100 100 1 00 100 Kisetsuchiweed Bed Straw 60 60 60 40 40 10 Yasei Soba 100 90 90 90 70 60 Kotia 10 0 100 80 80 70 50 Chamomile Moto* 　　　100　100　100　’80　　80　60 Black Nightshi Aid 70 70 50 10 0 0 Russian birthmark Mi -100100-100100 Field Ku 100 100 100 100 60 40 eyes Bee Stag Beetle 100 100 100 60 40 0 Sugar Dairy: 17 100 100 100 100 100 100 Shiroza 100 100 8 0 60 40 20 Goombai shepherds 90 90 80 60 40 30 Field Violet 100 100 90 90 50 30! And! Compound 56 Ratio g/ha 125 64 322 germination Previous Rukomugi 60 40 207 Yukom Gi　　　　　　　　　　　　　　　　30　　　　20 Hull Barley 0 Fuyu Barley 20 10 0 Fuyu Barley 0 oats 40 20 0 oats 20 20 0 Downey Brohm 　　　　　　　　　　　　70　　　　40 Sparrow 80 80 50 black glass 　　　　　　　　　　60　　　　　50-Handmade Strawberry Tsunagi　　　　　　　 70 60 40-older ryegrass 20 0 0 Q Joint Goat Geras 1 0 0 0 Q Green Foxtail 60 50 30 rapeseed 100 　100　　　90 Kisetsuchiweed Bed Straw　　60　 50 40 Yasei Soba 80 80 40 Kotia 60 30 20 chamomiles 80 7 0 70 Black Nightshade 100 10 0 100 Russian Thistle 100 0 100 Field Stag Beetle 70 40 30 Ivy Stag Beetle 70 60 20 sugar beet 100 90 90 Shiroza 90 70 70 Gunbai shepherd's purse 90 90 8 0 Field Violet 20 0 0! And Gi Compound 56 Ratio */ha 125 64 32 After germination Whole wheat 30 10 10f Yukomugi 30 10 10 Haruo Barley 10 10 Fuyuoo Wheat 20 10 10 oats 　　　　　　　　　　　　　　　　　　　　　　10　　　　20 power rasmugi No. 2 steps 40 10 Downy Blow MU　　　　　　　　60　　　60　　　　　20 Sparrow 90 70 40 black glass 　　　　　　　　90　　　70　　　　60 Black Glass 2nd stage 　　　　　90　　　　60　　　　　　30-Handmade Strawberry Tsunagi 　　　　　50　　　　0　　　20-Older Ryegrass　　　　　　 2000 Joint Goat Geras 70 30 10 Green Foxtail 20 0 0 0 rapeseed 100 100 0 Kisetsuchiweed Bed Straw 80 40 20 Wild buckwheat 60 40 20 kochia 904020 Chamomile Modoki 90 90 60 Black Nightshade 0 Russian thistle 10 0 100 100 Field Stag Beetle 50 40 10 Ivy Stag Beetle 60 　　　　　　　　　　　　10 Sugar daisies: l:/　　　　　　　　10 0 100 100 Shiroza 60 　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　100 100 90 field violet 0 0 0 0 mouse 9! Compound 61 Ratio y/ba 32 16 8 4 2 Before germination Whole wheat 20 10 0 0 0 Fuyu wheat 40 30 10 0 0 Hull barley 40 30 10 0 0 Fuyu Barley 20 10 0 0 0 oats 0 oats 　　　　　　　　o.

Downey Brohm 30 10 0 0 0 0 Suzume no Chiyahiki 80 60 60 40 20 Black Glass 20 20 2 0 10 0-Early strawberry eel 30 20 20 10 0-Older Ryegrass 30 30 20 0 0 Joint Goat Geras 30 30 10 0 0 Green Foxtail 70 40 20 0 0 rapeseed 　　　　100　100　100　100　90Kisetsuchiweed ・Bed straw 100 80 60 50 40 Ba 80 80 70. 60 60 Cotia 70 50 30 0 0 Chamomile Modoki 100 100 100 90 80 Black Nightshade 70 60 50 50 30 Russian thistle 60 30 20 0 0 Field Stag Beetle 70 60 50 50 40 Ivy Stag Beetle 70 50 30 0 0 sugar doce) 7 100 90 90 90 90 Shiroza 　　　　　　90　　90　　80　　　80　　70 Gunbai shepherds 　　　　　　　　100　　90　　80　　70　60 Fee Ludo Violet 80 60 60 50 4 0Table 0 Compound 61 Ratio y/ha 32 16 8 4 2 After germination Whole wheat o.

Fuyu wheat 10 10 0 0 0 Hull Barley o.

Fuyu barley 20 20 10 0 0 oats 　 　 　 o 　 　 　 o.

Oats second stage o o o.

Downey Brohm 10 0 0 0 0 0 Suzume no Chiyahiki 30 10 0 0 0 0 Black Glass o.

Black grass second stage 30 30 0 0 0 0 - Handmade Strawberry Tsunagi o o o o .

-Hand-raw ryegrass o o.

Joynt Goatgelas o o o .

Green Foxtail 20 20 10 0 0 rapeseed 100 100 100 100 90 Kisetsuchiweed Bed Straw 80 80 50 10 0 Yasei Sopa 60 6 0 30 0 0 Kotia 70 60 60 50 30 Chamomile 1 00 100 100 100 70 Black Nightshade 30 10 0 0 0 Field Stag Beetle 0 Ivy Stag Beetle C 30 30 20 0 0 sugar beet 　 　 　 　 　 　 100 100 100 100 90 Shiroza 20 10 0 0 0 Nhainasuna 1001001001001o0 Field Violet 20 20 10 0 0 Table G Compound 62 Ratio 9/ha 8 4 2 2 1 Before germination Halic wheat 10 0 0 0 Fuyu wheat 20 10 0 0 Ha Barley 40 40 30 0f Yubarley 10 0 0 0 ka Rasmugi 0 Downy Brohm 0 0 0 0 Suzume no Chiyahiki 30 10 0 0 blank glass 　　　　　　　　　10　　10　　　　0　　　　0-Handmade Strawberry Tsunagi 　　　　　　　　　30　　10　　　　0　　　　0-Hand-raw ryegrass 30 10 0 Joint Goat Geras 20 10 0 Green Fo Cocktail 40 10 0 0 Brassica 　 　 　 　 　 　 100 　 100 　 100 　 90 kisetsu Weed Bedstraw 20 20 0 0 Yaseiso Pa 70 70 60 40 = Cheer 60 20 10 0 Minremo Doki 100 90 80 70 Blank Nightshade 70 40 30 10 Ronyaa Zami 　 　 　 　 　 80 　 80 　 50 　 40 feel Stag Beetle 70 60 30 20 Ivy ・Stag beetle 70 30 10 0 sugar Icon 100 100 70 70 Shiroza 90 90 80 70 Gunba Inazuna 100 90 60 60 ft Old Violet 50 40 20 20! And ! Compound 62 Ratio g/ha 8 4 2 2 1 After germination Whole wheat 40 30 10 0 Fuyu wheat 30 10 0 0 Haru barley 40 20 0 0 Fuyu barley 30 10 0 0 Oat oats 0 0 0 0 rasm Gi second stage 20 10 0 Downey Prome 0 0 0 Sparrow 50 40 0 Black Glass 0 0 0 0 Black Grass Stage 2 　　　　　40　　10　　　　0　　　　　0-Handmade Strawberry Tsunagi 30 20 0 00 -Healing riglass 100 0 0 Zyointh Gote Gerus 　 　 　 20 　 20 　 0 0 Green Foxtail 20 20 0 0 rapeseed 　　　　100　　100　　100　　90 Kisetsuchi Weed Bed Dostrow 50 30 0 0 Yasei Sopa 　　　　　　60　　30　. 20 0 Kotia 　　　　　　70　　40　　40　　　10 Chamomile 　　　　　　80　　80　　60　　60 Black Nightshade 0 field stag beetle C 30 10 0 0 sugar beet 100 100 90 90 Shiroza 20 0 0 0 Kunhiusna 1OO loo9050 Field Violet 60 10 0 0 Table G Compound 64 Ratio g/ha 125 64 32 16 8 4 2 1 Before germination Whole wheat 50 30 10 0 0 0 0 0 0 Fuyu wheat 40 20 20 10 0 0 0 0 Hull barley 60 60 50 20 0 0 0 0 07 Yubarley 70 60 6 0 50 30 0 0 0 Oat 30 20 10 0 0 0 0 0 Downey Brohm 30 10 10 0 0 0 0 0 Sparrow 80 60 50 30 10 0 0 0 Black Glass 　　　　　　　　50 30 10 0 0 0 0 0 0-early Raw strawberry eel 70 60 30 30 10 0 0 0-Hand-raw ryegrass 70 40 40 30 10 10 0 0 Joint Goat Geras 40 30 30 0 0 0 0 0 Green Foxtail 100 80 6 0 40 30 0 0 0 Brassica 100 100 100 100 100 100 100 90 Kisetsuchiweed・ Bed straw 100 100 100 90 70 60 40 40 Yase Isoba 100 90 90 80 70 70 60 50 Kotia 90 80 80 70 70 6 0 40 20 Chamomile 100 100 90 9 0 90 80 70 60 Black Nightshade 80 80 70 60 60 50 30 20 Russian thistle 1 00 90 80 50 50 20 0 0 Field Stag Beetle 100 90 80 70 70 60 40 10 Ivy Kuwaga Tasou 100 90 90 80 60 60 30 10 Sato Radish 100 100 100 100 100 90 90 80 Shiroza 100 100 100 8 0 80 70 70 30 Gunhainaz + 100 1 00 100 90 80 80 70 30 Field Violet 90 80 70 70 60 40 20 0 Table G Compound 64 Ratio */ha 125 63 32 16 B 4 2 1 After germination Harutsumugi ooooooooo.

7yu==+7. GI 20 10 0 0 0 0 0 0 Hull barley 10 10 0 0 0 0 0 0 Fuyu barley ooooooo o.

Oats 　　　　　　　oooooooo.

Oat stage 2　　　　　oooooooo.

Downey Blue el-A 10 0 0 0 0 0 0 0 0 Sparrow Chiyahiki 30 20 0 0 0 0 0 0 Black Kug 5th 20 10 0 0 0 0 0 0 0 Black Grass Stage 2 20 0 0 0 0 0 0 0 0-Early Strawberry Tsunagi 20 10 0 0 0 0 0 0 - Early ryegrass ooooo oo.

Joynt Goatgelas 40 10 0 0 0 0 0 0 Green Foxtail 30 30 10 0 0 0 0 0 Brassica 100 100 10 0 100 90 90 90 70 Kisetsuchiweed Bedstraw 10 0 100 70 70 50 20 0 0 Kotia 80 80 60 60 50 40 30 20 Chamomile 100 100 100 70 50 30 20 0 bra Tsuknightshade 40 30 20 20 10 0 0 0 Field Stag Beetle 20 20 0 0 0 0 0 0 0 Ivy Stag Beetle 100 80 40 20 0 0 0 0 Sugar beet 100 100 100 100 10 0 100 90 70 Shiroza 70402020 0 0 0 0 Gunbai shepherd 100 100 1 00 100 100 100 100 20 field-/<Iore7) 　　　　30　10　0　　0　　0　　0　　　0　　0! Compound 65 Ratio e, 7 ha 125 64 32 16 g’ 4 2’ 1 before germination Harutsumugi 10 0 0 0 0 0 0 0 G Fuyu wheat 20 10 0 0 0 0 0 0 Hull barley 70 50 30 20 0 0 0 0 Fuyu barley 70 60 3 0 30 0 0 0 0 Oats 20 20 10 0 0 0 0 0 Downey But'-A 50 20 10 0 0 0 0 Suzume no Chiyahiki 60 40 30 0 0 0 0 Black Grass S 90 90 80 80 40 40 0 0- Early strawberry eel 60 60 50 40 40 20 10 0-Early Ryegrass 60 50 50 40 40 2 0 10 0 Joint Boat Gras x 50 40 30 3 0 20 10 0 0 Green-7 Oxtail 90 80 80 4 0 30 10 0 0 Brassica 100 10 0 100 90 90 80 80 80 Kisetsuchiweed Ped 7 100 100 90 80 80 60 60 60 Yaseinba 100 90 90 90 80 70 70 60 Kotia 90 80 80 60 60 40 30 10 Chamomile modoki 100 100 100 90 90 7 0 70 60 Black Nightshade 80 80 70 70 60 50 20 10 Russian thistle 90 90 90 70 70 60 60 40 Field Stag Beetle 10 0 90 80 80 80 70 60 30 Ivy Stag Beetle 100 90 90 70 70 50 40 30 Sugar dai: 17 100 100 100 100 100 100 80 80 Shiroza 100 100 90 90 80 6 0 60 40 Goombai shepherd 100 100 100 90 90 90 40 30 Field Violet 1001ooloO1 ooloo907o4゜Table G Compound 65 Rate e/km 125 64 32 16 8 4 2 1 After germination Harutsumugi ooooooooo.

7 Yukomugi　　　　　　　　　oooooooo.

Haru barley 10 10 0 0 0 0 0 0 0 Fuyu Barley 20 10 0 0 0 0 0 0 oats 0 oats

Oat stage 2　　　　　oooooooo.

Downey Brohm ooooooo.

Sparrow Sparrow 20 10 0 0 0 0 0 0 0 Black Glass 40 20 0 0 0 0 0 0 Black Grass Stage 2 80 60 60 50 10 0 0 0-Early Strawberry Tsunagi 40 30 1 0 0 0 0 0 0 - Early ryegrass 20 20 20 0 0 0 0 0 Joint Goat Geras o ooooooo.

Green Foxtail 40 30 0 0 0 0 0 0 Abu? 100 100 100 100 100 100 90 5 0 Kisetsuchiweed Bedstraw 90 90 80 80 30 10 0 0 Yasei Soba 90 80 80 70 30 10 0 0=++7 100 100 9 0 70 60 60 40 0 Chamomile + 10 0 100 100 100 90 90 60 20 Black Nightshade 80 40 40 40 10 0 0 0 field ku Vagatasou 80 60 50 30 10 0 0 0 Ivy - Stag beetle 80 50 50 30 0 0 0 0 0 sugar beet: l: / 100 100 100 100 100 90 90 70 Shiroza 50 30 20 10 0 0 0 0 Gunbainaz + 1 00 100 100 100 100 100 80 20 Field Buy Olette 80 50 50 40 20 0 0 0 Table G compound group Ratio y/ba 125 64 32 16 8 4 2 Before germination Harutsumugi 10 10 0 0 0 0 　　　　　　　　　　　　　　　　　　　　　　　oooooooo.

Haru barley 30 0 0 0 0 0 0 0 Fuyu Barley 30 20 20 10 10 0 0 power? X wheat 20 20 10 10 10 10 10 Downey P-A 40 10 0 0 0 0 0 Suzume no Chiyahiki 20 1 0 0 0 0 0 0 Black Glass 5 0 40 30 30 30 20 20-Early strawberry eel 40 40 30 30 20 10 10-Early ryegrass 30 20 20 10 10 10 0 Joint goat woodpecker S 10 10 0 0 0 0 Green - 7 Ots Coustel 60 50 30 20 20 10 0 Brassica 　　　　　100　100　100　100　70　70　60 Eid Bedstraw 90 90 90 90 70 50 40 Yase Isopa 90 90 90 80 60 50 30 Cotia 50 50 20 10 10 0 0 Chamomile Modoki 90 90 90 80 80 70 70 Black Nightshade 70 50 40 30 30 30 30 Russian thistle 10 0 0 0 0 0 0 Field Stag Beetle 60 6 0 50 50 50 40 40 I.P. stag beetle 9 0 70 70 70 70 70 0 sugar dai”/ 100 100 100 90 90 90 70 Shiroza 　　　　　100 90 90 40 40 30 20 Goombai shepherd 80 80 80 70 60 40 30 feel 100 100 90 90 60 60 30 stars! Compound 66 Ratio #/ha 125 64 32 16 8 4 2 After germination Whole wheat 10 0 0 0 0 0 0 　　　　　　　　　　　　　　　　　　　　　　　oooooooo.

Haru barley 30 20 10 10 10 10 10 Fuyu Barley 10 10 10 0 0 0 0 oats 0 oats

Oat second stage 10 10 0 0 0 0 0 0 Downey Brohm ooooooo.

Sparrow Sparrow 10 10 0 0 0 0 0 0 Black Glass 30 30 10 10 10 10 10 Black grass second stage 20 20 10 0 0 0 0 - Older Strawberry Tsunagi 10 10 10 10 0 0 0 - Older Rye Grass 10 10 0 0 0 0 0 Joint Goat Geras 20 20 10 0 0 0 0 Green Foxtail 40 30 10 0 0 0 0 Brassica 100 100 100 90 90 70 50 Kisetsuchiweed・ Bed straw 100 100 100 60 50 30 10 Yaseiso Ba 90 80 80 60 50 50 10 pieces Cheer 60 60 40 40 40 20 0 Chamomile Modoki 90 90 80 80 70 60 50 Black Nightshade 80 50 50 20 10 10 10 Russian thistle 50 50 50 50 50 30 0 Field Stag Beetle ooooooo .

Ivy Stag Beetle 70 60 60 50 40 40 20 sugar beets 100 100 100 100 90 90 60 Shiroza 60 40 40 0 0 0 0 0 Goumpaina Zuna 90 90 90 80 80 20 20 Field Violet 80 40 0 0 0 0 0 International Search Report international search report US 88024S9 SA　23559

Claims (25)

[Claims] 1. formula ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ In the formula, J is ▲There are mathematical formulas, chemical formulas, tables, etc.▼J-1▲There are mathematical formulas, chemical formulas, tables, etc.▼J -2▲There are mathematical formulas, chemical formulas, tables, etc.▼J-3▲There are mathematical formulas, chemical formulas, tables, etc. ▼J-4▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼J-5▲ Contains mathematical formulas, chemical formulas, tables, etc. ▼J-6▲There are mathematical formulas, chemical formulas, tables, etc.▼J-7▲There are mathematical formulas, chemical formulas, tables, etc. Yes ▼J-8▲ There are mathematical formulas, chemical formulas, tables, etc. ▼J-9▲ Mathematical formulas, chemical formulas, tables, etc. ▼J-10▲There are mathematical formulas, chemical formulas, tables, etc.▼J-11▲Mathical formulas, chemical formulas, etc. There are scientific formulas, tables, etc. ▼J-12 and ▲There are mathematical formulas, chemical formulas, tables, etc. ▼L-1 selected from 0; E is a single bond or -CH2-; Q1 is -C(T1)=N-O-Alk; T1 is CN, F, Cl, Br, S CN, N3, C1-C2 alkoxy, C1-C2 thioalkyl, NH (C1-C2 2 alkyl), N(C1-C2 alkyl)2, N(OCH3)CH3 and ▲Formula , chemical formula, table, etc. (select from ▼ or 4) Re; Alk is optionally a C1-C3 atom substituted with CN, OCH3, SCH3 or halogen. and CH2CH=CH2; Q2 is -C(T2)=N-O- Alk; T2 is H; optionally substituted with CN, OCH3, SCH3 or halogen; C1-C3 alkyl; cyclopropyl: F; Cl; Br; CN; SCN; N 3; N3; C1-C2 alkoxy; C1-C2 thioalkyl; NH(C1-C2 alkyl); N(C1-C2 alkyl)2; N(OCH3)( Selected from CH3 and ▲There are mathematical formulas, chemical formulas, tables, etc.▼ or 4; R1 is H, C1-C3 alkyl, C1-C3 haloalkyl, halogen, CN, nitro, C1 ~C2 alkoxy, C1-C3 haloalkoxy, C1-C2 alkylthio, C1 ~C3 alkylsulfinyl, C1-C3 alkylsulfonyl, SCF2H, N H2, NHCH3, N(CH3)2 or one C1-C2 alkoxy, C1- C2 haloalkoxy, SH, SCH3, C1-C2 a substituted with CN or OH Selected from Lukil; R2 is H, F, Cl, Br, C1-C2 alkyl, C1-C2 haloalkyl or selected from C1-C2 alkoxy; R3 is H, C1-C3 alkyl, C1-C 2-haloalkyl, C3-C4 alkenyl, C3-C4 alkynyl, CH2CN, selected from phenyl and phenyl substituted with F, Cl, CH3 or OCH3 ;n is 0 or 1; R is H or CH3; W is O or S; A is ▲There are mathematical formulas, chemical formulas, tables, etc.▼A-1▲There are mathematical formulas, chemical formulas, tables, etc.▼A -2▲There are mathematical formulas, chemical formulas, tables, etc.▼A-3▲There are mathematical formulas, chemical formulas, tables, etc. ▼A-4▲There are mathematical formulas, chemical formulas, tables, etc.▼A-5▲There are mathematical formulas, chemical formulas, tables, etc. Selected from ▼A-6 and ▲Mathematical formulas, chemical formulas, tables, etc.▼A-7; H, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 haloalkyl, C1-C4 haloalkylthio, C1-C4 alkylthio E, halogen, C2-C5 alkoxyalkyl, C2-C5 alkoxyalkoxy C, amino, C1-C3 alkylamino, di(C1-C3 alkyl)amino, or is selected from C3-C5 cycloalkyl; Y is H, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 haloalkoxy C, C1-C4 haloalkylthio, C1-C4 alkylthio, C2-C5 alco xyalkyl, C2-C5 alkoxyalkoxy, amino, C1-C3 alkyl Amino, di(C1-C3 alkyl)amino, C3-C4 alkenyloxy, C3 ~C4 alkynyloxy, C2-C5 alkylthioalkyl, C1-C4 haloar C2-C4 alkynyl, azide, cyano, C2-C5 alkyl sulfyl Nylalkyl, C2-C5 alkynylsulfonylalkyl, CH2OH, ▲Formula , chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas , tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ and N(OCH3)CH selected from 3; m is 2 or 3; L1 and L2 are independently O or S; Ra is H or C1-C3 alkyl ; Rb and Rc are independently C1-C3 alkyl; Z is CH or N; Z1 is CH or N; Y1 is O or CH2; X1 is CH3, OCH3, OC2H5 or OCF2H; X2 is CH3, C 2H5 or CH2CF3; Y2 is OCH3, OC2H5, SCH3, SC 2H5, CH3 or CH2CH3; X3 is CH3 or OCH3; Y3 is H or CH3; X4 is CH3, OCH3, OC2H5, CH2OCH3 or Cl; and Y4 is CH3, OCH3, OC2H5 or Cl; provided that i) X is Cl, F, When Br or I, Z is CH and Y is OCH3, OC2H5, N(OCH 3) CH2, NHCH3, N(CH3)2 or OCF2H; ii) When X or Y is C1 haloalkoxy, Z is CH; iii) X4 and and Y4 are not Cl at the same time; iv) When W is S, R is H and A is A-1; Yes, and Y is CH3, OCH3, OC2H5, CH2OCH3, C2H5, CF3, SCH3, OCH2CH=CH2, OCH2C≡CH, OCH2CH2 OCH3, CH(OCH3)2 or 1,3-dioxolan-2-yl; v) When the total number of carbon atoms in X and Y is greater than 4, the number of carbon atoms in Q1 or Q2 is equal to 4. Squid or smaller; vi) When J is J-6, J-7, J-8 or J-9 and A is A-7 , Z1 is CH; and vii) J is J-6, J-7, J-8 or J-9; , A is A-1, and X and Y are haloalkoxy or haloalkyl group , T2 is F, Cl, Br, CN, SCN, N3, C1~C2 alco xy, C1-C2 thioalkyl, NH (C1-C2 alkyl), N(C1-C2 Alkyl)2, N(OCH3)CH3 or ▲There are mathematical formulas, chemical formulas, tables, etc.▼or is 4]. 2. E is a single bond; and W is O, A compound according to claim 1. 3. E is CH2 or J is J-6; and W is O; A compound according to claim 1. 4. R1 is H, F, Cl, Br, CH2CN, CH3, OCH3, SCH3 or selected from OCF2H; R2 is selected from H, F, Cl, Br or CH3; R3 is H, C1-C3 alkyl; selected from phenyl, CH2CF3 and CH2CH=CH2; X is C1-C2 alkyl, C1-C2 alkoxy, Cl, F, Br, I, OCF 2H, CH2F, CF3, OCH2CH2F, OCH2CHF2, OCH2CF 3, selected from CH2Cl and CH2Br; Y is H, C1-C2 alkyl, C 1-C2 alkoxy, CH2OCH3, CH2OCH2CH3, NHCH3, N (OCH3)CH3, N(CH3)2, CF3, SCH3, OCH2CH=CH 2, OCH2C≡CH, OCH2CH2OCH3, CH2SCH3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼▲Mathematical formulas, There are chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼OCF2H, OC selected from F2Br, SCF2H, cyclopropyl, C≡CH or C≡CCH3 and Rb and Rc are C1-C2 alkyl, according to claim 3. Compound. 5. A is A-1; n is 0; X is selected from CH3, OCH3, OCH2CH3, C1 or OCF2H; do Y is CH3, OCH3, C2H5, CH2OCH3, NHCH3, CH(OCH 3) A compound according to claim 4 selected from 2 and cyclopropyl. 6. R is H; T1 is selected from CN, Cl and C1-C2 alkoxy; and T2 is H, C From 1-C3 alkyl, cyclopropyl, Cl, CN and C1-C2 alkoxy selected, A compound according to claim 5. 7. The compound according to claim 6, wherein J is J-1 to J-5 and J-7 to J-13. Compound. 8. 8. The compound according to claim 7, wherein J is J-1. 9. The compound according to claim 7, wherein J is J-2. 10. 8. The compound according to claim 7, wherein J is J-3. 11. 8. A compound according to claim 7, wherein J is J-4. 12. 8. A compound according to claim 7, wherein J is J-5. 13. 8. A compound according to claim 7, wherein J is J-7. 14. 8. A compound according to claim 7, wherein J is J-8. 15. 8. A compound according to claim 7, wherein J is J-9. 16. 8. The compound according to claim 7, wherein J is J-10. 17. 8. The compound according to claim 7, wherein J is J-11. 18. 8. A compound according to claim 7, wherein J is J-12. 19. 8. The compound according to claim 7, wherein J is J-13. 20.2-[[[(4-chloro-6-methoxy-2-pyrimidinyl)amino] carbonyl]amino]sulfonyl]-N-methoxybenzenecarboximidoyl 9. The compound according to claim 8, which is a chloride. 21.2-[(cyano)(methoxyimino)methyl]-N-[[(4-methoxy -6-methyl-2-pyrimidinyl)amino]carbonyl]benzenesulfonamide 9. The compound according to claim 8, which is 22. N-methoxy-2-[[[[(4-methoxy-6-methyl-1,3,5- triazin-2-yl)amino]carbonyl]amino]sulfonylbenzenecar 9. The compound according to claim 8, which is boximidoyl chloride. 23. Compounds according to any one of claims 1 to 22 and agriculturally suitable A herbicidal composition comprising a carrier. 24. A compound according to claim 1, an agriculturally suitable carrier, and a compatible organic compound. A herbicide composition comprising a pest herbicide. 25. A herbicidally effective amount of the compound according to any one of claims 1 to 22, A method for controlling weeds comprising application to a weed growing area before or after germination. .