JPH0249222B2 - - Google Patents
Info
- Publication number
- JPH0249222B2 JPH0249222B2 JP57200719A JP20071982A JPH0249222B2 JP H0249222 B2 JPH0249222 B2 JP H0249222B2 JP 57200719 A JP57200719 A JP 57200719A JP 20071982 A JP20071982 A JP 20071982A JP H0249222 B2 JPH0249222 B2 JP H0249222B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- synthetic resin
- reinforcing layer
- core
- hard
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003014 reinforcing effect Effects 0.000 claims description 30
- 229920003002 synthetic resin Polymers 0.000 claims description 21
- 239000000057 synthetic resin Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 16
- 229920001169 thermoplastic Polymers 0.000 claims description 16
- 239000004416 thermosoftening plastic Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000004566 building material Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 2
- 239000011162 core material Substances 0.000 description 30
- 239000010410 layer Substances 0.000 description 26
- 229920005989 resin Polymers 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 229920005992 thermoplastic resin Polymers 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000002344 surface layer Substances 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 210000005069 ears Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
本発明は、硬質熱可塑性合成樹脂内に芯材補強
層を埋込収蔵させた建材用素材として好適に使用
される建材用補強硬質合成樹脂成型品の製造方法
に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a reinforced hard synthetic resin molded product for building materials, which is suitably used as a building material material, in which a core reinforcing layer is embedded in a hard thermoplastic synthetic resin. It is.
硬質熱可塑性合成樹脂内に芯材補強層を埋込収
蔵させて、硬質熱可塑性合成樹脂成型品の持つ熱
変形,熱収縮の容易な点や、熱的あるいは構造的
強度が低い点などを改善した合成樹脂成型品とし
ては、芯材補強層に鉄板や、金網を用いた物が既
に公知であるが、このような鉄板や、金網を用い
た物は、製造面,コスト面,使用面から次のよう
な問題点を有している。 A core reinforcing layer is embedded in a hard thermoplastic synthetic resin to improve the ease of thermal deformation and shrinkage, as well as low thermal and structural strength, of hard thermoplastic synthetic resin molded products. Synthetic resin molded products using iron plates or wire mesh as the core reinforcing layer are already known, but products using such iron plates or wire mesh are difficult to manufacture, cost, and use. It has the following problems.
すなわち、熱可塑性合成樹脂に対し、異質の材
料となる鉄板や、金網の補強芯を埋込成形するの
で、補強芯の表面に適当な表面処理を施し、且つ
適当な接着剤を塗着する工程上の煩わしさがあつ
た。 In other words, since reinforcing cores such as iron plates or wire mesh, which are different materials, are embedded into thermoplastic synthetic resin, the process involves applying appropriate surface treatment to the surface of the reinforcing cores and applying an appropriate adhesive. The above annoyances bothered me.
また、補強芯が重いので成型品自体かなりな重
量増となり製造コストも高価であつた。 Furthermore, since the reinforcing core is heavy, the weight of the molded product itself increases considerably and the manufacturing cost is also high.
更に、成型品の切断端面に補強芯が露顕し発錆
を誘発して腐食しやすく、しかも補強芯は熱可塑
性合成樹脂とその該表面のみが接着剤等で密着し
ているだけなので構造的にも層間剥離を生じ易い
などの…問題点を有していた。 Furthermore, the reinforcing core is exposed on the cut end of the molded product, causing rust and corrosion. Moreover, the reinforcing core is structurally unstable because only the thermoplastic synthetic resin and its surface are in close contact with each other with adhesive, etc. However, they also had problems such as easy delamination between layers.
そこで、本発明は上記に鑑みて開発されたも
の、紙質を除く繊維質基材に熱可塑性合成樹脂を
含浸させて成る芯材補強層に、硬質熱可塑性合成
樹脂を複合一体化させて成型したことを特徴とす
る建材用補強硬質合成樹脂成型品の製造方法を提
供することを目的としたもので、これによつて上
記問題点を解決した成型品を得ようとするもので
ある。 Therefore, the present invention was developed in view of the above, and is a core reinforcing layer made by impregnating a fibrous base material other than paper with a thermoplastic synthetic resin, and a hard thermoplastic synthetic resin composite integrally molded. The object of the present invention is to provide a method for producing a reinforced hard synthetic resin molded product for building materials, which is characterized by the following, and thereby to obtain a molded product that solves the above-mentioned problems.
以下に添付図を参照しつつ本発明の望ましい実
施例の製造方法について説明する。 A manufacturing method of a preferred embodiment of the present invention will be described below with reference to the accompanying drawings.
まづ、雨樋を例にとつた製造プロセスを第1
図,第2図によつて説明すると、基材調整工程(A)
は、芯材補強層11を形成する繊維質基材10を
単独若しくは組み合わせて選出する工程である。 First, let's look at the manufacturing process using rain gutters as an example.
To explain with reference to Fig. 2, the base material preparation process (A)
This is a step of selecting the fibrous base materials 10 that form the core reinforcing layer 11, either singly or in combination.
芯材補強層形成のために使用される繊維質基材
10としては、クラフト紙,洋紙,板紙等の紙質
基材を除く無機有機いずれの繊維でもよく、特に
無機繊維としては、ガラス繊維,カーボン繊維,
石綿繊維,石膏繊維等が、又有機繊維としては、
ポリエステル繊維,ナイロン繊維,ポリビニル繊
維等の単体又はこれらを組合せた不織布,織布,
マツト,ネツト等の加工物が使用でき、更にこれ
らを重合させて多層構造にして厚くすることも可
能である。これらの基材のなかから使用目的に応
じたものが適宜選択される。 The fibrous base material 10 used for forming the core reinforcing layer may be any inorganic or organic fiber other than paper base materials such as kraft paper, Western paper, and paperboard. fiber,
Asbestos fiber, gypsum fiber, etc., and as organic fiber,
Nonwoven fabrics, woven fabrics made of polyester fibers, nylon fibers, polyvinyl fibers, etc. alone or in combination,
Processed products such as mats and nets can be used, and it is also possible to polymerize them to form a multilayer structure and increase the thickness. Among these base materials, one is appropriately selected depending on the purpose of use.
熱可塑性合成樹脂含浸工程(B)は、上記工程(A)に
よつて選択された繊維質基材10を樹脂原料の樹
脂液若しくはエマルジヨン型樹脂液中に含浸する
工程である。 The thermoplastic synthetic resin impregnation step (B) is a step of impregnating the fibrous base material 10 selected in the above step (A) into a resin liquid or an emulsion type resin liquid as a resin raw material.
繊維質基材10に含浸される熱可塑性合成樹脂
12としては酢酸ビニル樹脂,アクリル樹脂,ポ
リビニルアルコール(PVA),ポリ塩化ビニル
(PVC),及びこれらの変形樹脂又はゴム変形樹
脂(例えば、ニトリルクロロプレンゴム)等が好
ましく採用され、溶液型もしくはエマルジヨンタ
イプとして用いられる。 The thermoplastic synthetic resin 12 impregnated into the fibrous base material 10 includes vinyl acetate resin, acrylic resin, polyvinyl alcohol (PVA), polyvinyl chloride (PVC), modified resins thereof, or rubber modified resins (for example, nitrile chloroprene). Rubber) etc. are preferably employed, and are used as a solution type or emulsion type.
エージング工程(C)は、含浸樹脂液を常温下若し
くは加熱下に放置することにより樹脂分を乾燥さ
せる工程である。しかし、この工程(C)に於いて加
熱して樹脂分を幾分軟化させることが後の外表層
を形成する硬質熱可塑性樹脂2を溶着一体化させ
る工程において層間密着性をより良好にする上で
好ましい。 The aging step (C) is a step of drying the resin component by leaving the impregnated resin liquid at room temperature or under heating. However, in this step (C), heating to soften the resin to some extent improves interlayer adhesion in the subsequent step of welding and integrating the hard thermoplastic resin 2 that forms the outer surface layer. It is preferable.
含浸基材繰に出し工程(D)は、例えば第2図の如
く2個のそれぞれの繊維質基材ローラR1,R2か
ら芯材補強層11…を繰り出し、これらをピンチ
ローラR3,R4によつて上下に積層一体とするこ
とによつて実施される。 In the impregnated base material feeding step (D), for example, as shown in FIG. 2, the core reinforcing layer 11 is fed out from two respective fibrous base material rollers R 1 and R 2 , and these are transferred to pinch rollers R 3 , This is carried out by laminating the upper and lower layers together with R4 .
予備成型工程(E)は、芯材補強層11を予備成型
金型RMに送致することにより、例えば雨樋形状
を成型するような場合には、それに応じた形状に
予め成型するものであり、次の金型導入工程(F)で
は、硬質熱可塑性樹脂押出機EXとクロスダイを
組んでいる押出成型Mの成型品の厚みの略中央に
対応する部に対し雨樋の形状に予備成型された芯
材補強層11を連続的に導入する。 In the preforming step (E), the core reinforcing layer 11 is sent to the preforming mold RM to be preformed into a shape corresponding to the shape of a rain gutter, for example, by sending it to the preforming mold RM. In the next mold introduction step (F), a part corresponding to approximately the center of the thickness of the molded product of extrusion molding M, which is assembled with a rigid thermoplastic resin extruder EX and a cross die, is preformed into the shape of a rain gutter. The core reinforcing layer 11 is continuously introduced.
しかして、芯材補強層11の導入と伴行して押
出機EXより外表層を形成することとなる硬質熱
可塑性樹脂2を加熱溶融させて上記芯材補強層1
1と略等速にて押出されるのである〔工程(G)〕。 Accompanied by the introduction of the core reinforcing layer 11, the hard thermoplastic resin 2 that will form the outer surface layer is heated and melted by an extruder EX to form the core reinforcing layer 1.
1 [Step (G)].
外表層を形成する硬質熱可塑性合成樹脂2とし
ては、PVC,アクリル樹脂,ポリカーボネート
及びこれらの変性樹脂等が採用され、耐候性,耐
摩耗性,剪断,引張強度,衝撃強度,及び上記熱
可塑性合成樹脂12との相溶性を考慮して、ある
いはまた成型品の表面に要求される性質等に応じ
て、前掲の硬質熱可塑性合成樹脂2の単層若しく
は2種以上の樹脂を重合させた複数層に形成する
ことができる。 As the hard thermoplastic synthetic resin 2 forming the outer surface layer, PVC, acrylic resin, polycarbonate, modified resins thereof, etc. are used, and the thermoplastic synthetic resin 2 has excellent weather resistance, abrasion resistance, shear strength, tensile strength, impact strength, and the above-mentioned thermoplastic synthetic resin. Considering the compatibility with the resin 12 or depending on the properties required for the surface of the molded product, a single layer of the above-mentioned hard thermoplastic synthetic resin 2 or multiple layers made by polymerizing two or more resins may be used. can be formed into
そして外表層を形成する熱可塑性樹脂2が例え
ば硬質塩化ビニル樹脂の場合は約180〜200℃の溶
融温度に保持すれば、芯材補強層11を形成する
熱可塑性樹脂12も軟化され、両樹脂2,12が
溶着一体とされ最終工程(H)を経て本発明による硬
質成型品Pが得られる。 If the thermoplastic resin 2 forming the outer surface layer is, for example, a hard vinyl chloride resin, by holding it at a melting temperature of about 180 to 200°C, the thermoplastic resin 12 forming the core reinforcing layer 11 will also be softened, and both resins will be softened. 2 and 12 are welded together, and through the final step (H), a hard molded product P according to the present invention is obtained.
かくして得られた硬質成型品Pとしての雨樋G
は、第3図に示されるようなもので、この硬質成
型品Pはその構造を微視的に分析すれば、芯材補
強層11内の繊維質基材10を構成する繊維素子
の各々が第4図に示されるように含浸固化された
熱可塑性樹脂12によつて丁度担持されたような
状態になつており、しかも各々の繊維素子の間に
深く入り込んで固化した熱可塑性樹脂12が外表
層の被覆された硬質熱可塑性樹脂2と溶着一体化
されて結合強度の極めて大きい構造体となつてい
る。 Rain gutter G as the thus obtained hard molded product P
is as shown in FIG. 3, and if the structure of this hard molded product P is microscopically analyzed, each of the fiber elements constituting the fibrous base material 10 in the core reinforcing layer 11 is As shown in FIG. 4, it is in a state where it is supported by the thermoplastic resin 12 that has been impregnated and solidified, and the thermoplastic resin 12 that has penetrated deeply between each fiber element and solidified is outside. It is welded and integrated with the hard thermoplastic resin 2 coated on the surface layer to form a structure with extremely high bonding strength.
したがつて、本製造方法によつて得られる硬質
成型品Pは芯材補強層11が外表層を形成する硬
質熱可塑性樹脂2の熱による長手方向,幅方向の
伸びや同方向の収縮を可及的に防止し、曲げ強
度,剪断強度を補強し、同時に芯材補強層11
と、合成樹脂外表層との両者層間の界面の接着性
を良好にして層間剥離の生じにくいという特徴を
有するのである。さらに繊維質基材10を補強芯
として用いているので、鉄板,金網を用いたのに
比べて軽量であり、かつ安価であるなどの利点に
加え切断端面より芯材が露顕しても発錆を誘発し
ないので耐久性にも優れたものとなるのである。 Therefore, in the hard molded product P obtained by this manufacturing method, the core reinforcing layer 11 allows the hard thermoplastic resin 2 forming the outer surface layer to elongate in the longitudinal direction and the width direction and to shrink in the same direction due to heat. The core reinforcing layer 11
It is characterized by good adhesion at the interface between the two layers and the synthetic resin outer surface layer, making it difficult for interlayer peeling to occur. Furthermore, since the fibrous base material 10 is used as a reinforcing core, it is lighter and cheaper than iron plates or wire meshes, and in addition, rust does not occur even if the core material is exposed from the cut end surface. Since it does not induce this, it has excellent durability.
このように、本発明の製造方法によれば、鉄板
や金網等を用いることがなく塗布工程が不要であ
るうえに、芯材補強層に含浸させた熱可塑性合成
樹脂と硬質熱可塑性合成樹脂との溶着一体化がな
されるので両者間の接着性が良好となる。さら
に、芯材補強層を予備成型した後に硬質熱可塑性
合成樹脂を複合一体化させるので、一体化後に成
型品形状に合致した形状に成型する必要がなく、
両者は完全に密着一体化して種々の形状の成型品
であつても層間剥離を生じない建材用成型品を得
ることができるのである。 As described above, according to the manufacturing method of the present invention, there is no need to use iron plates, wire mesh, etc., and there is no need for a coating process. Since the two are welded and integrated, the adhesion between the two is good. Furthermore, since the hard thermoplastic synthetic resin is compositely integrated after the core reinforcing layer is preformed, there is no need to mold it into a shape that matches the shape of the molded product after the integration.
The two are completely integrated in close contact with each other, making it possible to obtain molded products for building materials that do not cause delamination even when molded products have various shapes.
上記実施例は、雨樋を例にとつて製造方法を説
明したが、例示以外のパイプ,アングル,波板,
その他の建材用品の場合も同様に製造できること
はいうまでもなく、特にパイプ等の成型品にあつ
ては外表層の熱可塑性樹脂はその外周面にのみ被
覆形成させる方法を採用してもよい。 In the above embodiment, the manufacturing method was explained using a rain gutter as an example, but other pipes, angles, corrugated plates, etc.
It goes without saying that other building materials can also be produced in the same way, and especially for molded products such as pipes, a method may be adopted in which the thermoplastic resin of the outer surface layer is coated only on the outer peripheral surface.
また、上記実施例では押出成型法を例に採つた
が、芯材補強層に硬質熱可塑性樹脂層を複合一体
化させる方法として押出,ラミネート,プレス,
浸漬等の工程も可能であつて得ようとする成型品
の形状,大きさ,等によりその成型品の特徴が生
かせる成型法が適宜採択できるものである。 In addition, although the extrusion molding method was used as an example in the above embodiment, extrusion, lamination, pressing,
Processes such as dipping are also possible, and a molding method that takes advantage of the characteristics of the molded product depending on the shape, size, etc. of the molded product to be obtained can be selected as appropriate.
最後に、本発明で雨樋を製造する場合を例にと
つて詳述する。 Finally, a case in which a rain gutter is manufactured using the present invention will be described in detail as an example.
実施例 1
(a) 芯材補強層として、厚み0.2mmのガラス繊維
マツト塩化ビニルのエマルジヨン中に含浸させ
エージングさせたものを3枚重合させた後120
〜160℃にて予備成型を行つた。Example 1 (a) As a core material reinforcing layer, three sheets of glass fiber mats with a thickness of 0.2 mm were impregnated in vinyl chloride emulsion and aged, and after polymerization 120
Preforming was performed at ~160°C.
(b) しかる後、かくして得られた突曲する耳部を
有した略半円筒状の芯材補強層を通常の雨樋成
型用クロスダイの中に緩やかな速度で連続的に
導入して塩化ビニル樹脂を180〜200℃の溶融温
度に保持して押出被覆し、外表層を突曲する耳
部を有した略半円筒状の芯材補強層の両面にそ
れぞれ厚みが1.3mmで、その中央部に厚み0.6mm
の芯材補強層が得られた。(b) After that, the core material reinforcing layer having a substantially semi-cylindrical shape with protruding ears thus obtained is continuously introduced at a gentle speed into a normal cross die for molding rain gutters to form vinyl chloride. The resin is extruded and coated at a melting temperature of 180 to 200°C, and the outer surface layer is coated with a roughly semi-cylindrical core reinforcing layer with a thickness of 1.3 mm on both sides and having ears that protrude. thickness 0.6mm
A core reinforcing layer was obtained.
かくして得られた雨樋は、形状の塩化ビニル樹
脂製の雨樋に比べて熱による伸縮,変形も少な
く、又切断面において金属板内蔵の雨樋のように
発錆を誘発することも無く保形性の良好なもので
あつた。 The rain gutter thus obtained is less likely to expand, contract, or deform due to heat than a rain gutter made of vinyl chloride resin, and it can be easily maintained without causing rust on the cut surface, unlike rain gutters with built-in metal plates. It had good shape.
第1図は、本発明の製造プロセスを示す工程
図,第2図は、同上の工程図の概略装置図,第3
図は、本発明によつて得られた雨樋の縦断面斜視
図,第4図は、第3図に示された雨樋に於ける芯
材補強層の模式拡大図。
(符号の説明)、10は繊維質基材、11は芯
材補強層、12は熱可塑性樹脂(芯材補強層成型
材)、2は硬質熱可塑性樹脂(外表層成型材)、G
は雨樋、Pは成型品である。
Figure 1 is a process diagram showing the manufacturing process of the present invention, Figure 2 is a schematic equipment diagram of the same process diagram, and Figure 3 is a schematic diagram of the same process diagram.
4 is a vertical cross-sectional perspective view of a rain gutter obtained according to the present invention, and FIG. 4 is a schematic enlarged view of a core reinforcing layer in the rain gutter shown in FIG. 3. (Explanation of symbols), 10 is a fibrous base material, 11 is a core reinforcing layer, 12 is a thermoplastic resin (core reinforcing layer molding material), 2 is a hard thermoplastic resin (outer surface layer molding material), G
is a rain gutter, and P is a molded product.
Claims (1)
含浸させて成る芯材補強層を予備成型し、熱可塑
性合成樹脂を複合一体化させて成ることを特徴と
する建材用補強硬質合成樹脂成型品の製造方法。1. Reinforced hard synthetic resin molding for building materials, characterized by pre-molding a core reinforcing layer made by impregnating a fibrous base material other than paper with a thermoplastic synthetic resin, and integrating the thermoplastic synthetic resin into a composite. method of manufacturing the product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20071982A JPS5989148A (en) | 1982-11-15 | 1982-11-15 | Reinforcing synthetic resin shape for building material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20071982A JPS5989148A (en) | 1982-11-15 | 1982-11-15 | Reinforcing synthetic resin shape for building material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5989148A JPS5989148A (en) | 1984-05-23 |
JPH0249222B2 true JPH0249222B2 (en) | 1990-10-29 |
Family
ID=16429062
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP20071982A Granted JPS5989148A (en) | 1982-11-15 | 1982-11-15 | Reinforcing synthetic resin shape for building material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5989148A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI69878C (en) * | 1984-06-12 | 1986-05-26 | Tikkurilan Vaeritehtaat Oy | WASTE MATERIALS WITHOUT WASHING TEXTILES OELASTISK TEXTIL FOERFARANDE FOER TILLVERKNING AV DENSAMMA OCH AV DENSAMMA BIDAT ELEMENT |
JPH0822566B2 (en) * | 1989-02-14 | 1996-03-06 | 積水化学工業株式会社 | Method for manufacturing long composite molded body |
JPH07112701B2 (en) * | 1989-02-23 | 1995-12-06 | 積水化学工業株式会社 | Method for manufacturing long composite molded body |
JPH03158219A (en) * | 1989-11-16 | 1991-07-08 | Sekisui Chem Co Ltd | Manufacture of composite tube |
JP2533662B2 (en) * | 1989-12-08 | 1996-09-11 | 積水化学工業株式会社 | Manufacturing method of eaves gutter |
JP2584880B2 (en) * | 1990-02-26 | 1997-02-26 | 積水化学工業株式会社 | Manufacturing method of Kakuken gutter |
JPH07110514B2 (en) * | 1990-06-25 | 1995-11-29 | 積水化学工業株式会社 | Manufacturing method of core reinforced resin eaves gutter |
JPH04201535A (en) * | 1990-11-30 | 1992-07-22 | Sekisui Chem Co Ltd | Manufacture of fiber composite gutter |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5788477A (en) * | 1980-11-21 | 1982-06-02 | Ricoh Co Ltd | Recording body exchanging method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58526Y2 (en) * | 1979-10-18 | 1983-01-06 | ロンシール工業株式会社 | Roof finishing material for railway vehicles |
-
1982
- 1982-11-15 JP JP20071982A patent/JPS5989148A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5788477A (en) * | 1980-11-21 | 1982-06-02 | Ricoh Co Ltd | Recording body exchanging method |
Also Published As
Publication number | Publication date |
---|---|
JPS5989148A (en) | 1984-05-23 |
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