JPH023771B2 - - Google Patents
Info
- Publication number
- JPH023771B2 JPH023771B2 JP5227286A JP5227286A JPH023771B2 JP H023771 B2 JPH023771 B2 JP H023771B2 JP 5227286 A JP5227286 A JP 5227286A JP 5227286 A JP5227286 A JP 5227286A JP H023771 B2 JPH023771 B2 JP H023771B2
- Authority
- JP
- Japan
- Prior art keywords
- agent
- glutathione
- cold wave
- present
- odor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 27
- 108010024636 Glutathione Proteins 0.000 claims description 14
- 229960003180 glutathione Drugs 0.000 claims description 14
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 claims description 4
- 229940075861 ammonium thioglycolate Drugs 0.000 claims description 4
- 239000002075 main ingredient Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 16
- 125000003396 thiol group Chemical class [H]S* 0.000 description 7
- 239000000126 substance Substances 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 230000003700 hair damage Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 229940037001 sodium edetate Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
「産業上の利用分野」
この発明は施術後にメルカプト臭のしないコー
ルドウエーブ第１剤に関する。
「従来の技術」
従来のコールドウエーブ第１剤としては、チオ
グリコール酸アンモニウムおよびアルカリ剤が使
用されており、当該剤に毛髪のケラチン物質誘導
体を配合した方法等も知られている。しかしなが
ら、上記方法ではある程度毛髪の損傷は防止出来
るが、毛髪蛋白ケラチンをチオグリコール酸で還
元することにより発生するメルカプト臭は除去出
来なかつた。又、この特異的な不快臭を除き毛髪
の損傷を防止する目的でシステインパーマも行わ
れているが、ウエーブ形成力が弱く難点があつ
た。
「発明が解決しようとする問題点」
本発明はパーマ施術後にメルカプト臭のしない
新規なコールドウエーブ第１剤を提供することを
技術的課題とする。
「問題点を解決するための手段」
本発明者は（特願昭60−209550号において）従
来のコールドウエーブ第１剤に中性にした糖醗酵
液を添加した、パーマ処理中および後に不快臭の
しないコールドウエーブ第１剤を提案している。
本発明者は前記発明について研究を続行し、糖
醗酵液中に生成された物質を分析調査し、その成
分であるアミノ酸類、有機酸類、ビタミン類、ア
ルコール、アルデヒド、ケトン、グルタチオン、
又は無機塩類をコールドパーマ第１剤に各１％
（重量）添加してメルカプト臭の有無を検査した
結果、グルタチオンに消臭効力のあることを解明
し、本発明を完成させるに至つた。
なお理美容技術者男女10名により行つた上記官
能検査の結果は第１表に示す通りである。
"Industrial Application Field" This invention relates to a cold wave first agent that does not have a mercapto odor after treatment. "Prior Art" As the conventional cold wave first agent, ammonium thioglycolate and an alkaline agent are used, and a method in which a hair keratin substance derivative is blended with the agent is also known. However, although the above method can prevent hair damage to some extent, it cannot remove the mercapto odor generated by reducing the hair protein keratin with thioglycolic acid. In addition, cysteine perm has been performed for the purpose of eliminating this specific unpleasant odor and preventing hair damage, but it has a drawback in that it has a weak wave-forming ability. "Problems to be Solved by the Invention" The technical problem of the present invention is to provide a novel cold wave first agent that does not give off a mercapto odor after a perm treatment. "Means for Solving the Problems" The present inventor (in Japanese Patent Application No. 60-209550) discovered that a neutralized sugar fermentation solution was added to the conventional cold wave first agent, which caused an unpleasant odor during and after the perm treatment. We are proposing a cold wave first agent that does not get wet. The present inventor continued research on the above-mentioned invention, analyzed and investigated the substances produced in the sugar fermentation solution, and determined the components of amino acids, organic acids, vitamins, alcohol, aldehydes, ketones, glutathione,
Or add 1% each of inorganic salts to cold perm first agent.
As a result of adding (weight) and testing for the presence of mercapto odor, it was found that glutathione has a deodorizing effect, leading to the completion of the present invention. The results of the above sensory test conducted by 10 male and female hairdressers are shown in Table 1.
【表】【table】
【表】
即ち、本発明はチオグリコール酸アンモニウム
およびアルカリ剤を主成分とするコールドウエー
ブ第１剤に、グルタチオンを添加したことを特徴
とするコールドウエーブ第１剤からなるものであ
る。
グルタチオンの最小有効量算定のために、グル
タチオン１％水溶液を基準とし、10倍希釈による
方法でメルカプト臭の有無の官能検査をした結果
は第２表の通りである。[Table] That is, the present invention consists of a cold wave first agent characterized in that glutathione is added to a cold wave first agent whose main components are ammonium thioglycolate and an alkaline agent. In order to calculate the minimum effective amount of glutathione, a 1% aqueous solution of glutathione was used as the standard, and a sensory test was conducted for the presence or absence of mercapto odor using a 10-fold dilution method.The results are shown in Table 2.
【表】
以上の結果よりグルタチオンは微量でその効力
を発揮し、コールドウエーブ第１剤に対して、
0.001％以上、好適には0.005％以上添加すれば所
期の目的を達成することが判明した。
グルタチオンは動植物に存在するペプチドの一
つであり、生体内である種の酸化還元反応に関与
するものである。そして糖醗酵液および、特に酵
母体内に多く（通常２〜３％）含有さており、通
常前記各物質から抽出して使用される。本発明の
グルタチオンとしては、高純度に精製されたも
の、またはグルタチオンを高濃度に含有する溶液
を使用するのが好適である。
以下実施例をあげて本発明を説明する。
「実施例」
下記組成のコールドウエーブ第１剤で毛髪を室
温で15分間処理後、第２剤（臭素酸ナトリウム
6.5％）で室温で15分間処理後水洗いした。
・ チオグリコール酸アンモニウム（50％）
13.0（％）
・ エデト酸ナトリウム 0.1
・ 強アンモニア水（28％） 1.5
・ グルタチオン 0.005
・ 精製水 85.395
結果はカールは良好であり、毛髪の損傷はな
く、メルカプト臭も感じられなかつた。
「発明の効果」
微量のグルタチオンを添加した本発明のコールド
ウエーブ第１剤を使用することによつて、パーマ
施術中および後の強烈なメルカプト臭を除去する
ことが出来る。グルタチオンは無色透明で呈色や
変色もなく安定であるため、当該物質を添加した
本発明のコールドウエーブ第１剤も又安定であ
り、長期保存に耐えることが出来る。[Table] From the above results, glutathione exerts its effectiveness in small amounts, and has a strong effect on cold wave first agent.
It has been found that the desired purpose can be achieved by adding 0.001% or more, preferably 0.005% or more. Glutathione is one of the peptides present in animals and plants, and is involved in certain redox reactions in vivo. It is contained in a large amount (usually 2 to 3%) in the sugar fermentation liquid and especially in yeast bodies, and is usually used by extracting it from each of the above substances. As the glutathione of the present invention, it is preferable to use highly purified glutathione or a solution containing glutathione at a high concentration. The present invention will be explained below with reference to Examples. "Example" After treating hair with the first cold wave agent of the following composition for 15 minutes at room temperature, the second agent (sodium bromate)
6.5%) for 15 minutes at room temperature and then washed with water.・Ammonium thioglycolate (50%)
13.0 (%) - Sodium edetate 0.1 - Strong ammonia water (28%) 1.5 - Glutathione 0.005 - Purified water 85.395 The results showed good curls, no hair damage, and no mercapto odor. "Effects of the Invention" By using the cold wave first agent of the present invention to which a trace amount of glutathione is added, strong mercapto odor can be removed during and after a perm treatment. Since glutathione is colorless and transparent and stable without coloration or discoloration, the cold wave first agent of the present invention containing this substance is also stable and can withstand long-term storage.
Claims (1)
リ剤を主成分とするコールドウエーブ第１剤に、
グルタチオンを添加したことを特徴とするコール
ドウエーブ第１剤。1. Cold wave first agent containing ammonium thioglycolate and alkaline agent as main ingredients,
A cold wave first agent characterized by the addition of glutathione.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5227286A JPS62209014A (en) | 1986-03-10 | 1986-03-10 | The first cold wave solution containing added glutathion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5227286A JPS62209014A (en) | 1986-03-10 | 1986-03-10 | The first cold wave solution containing added glutathion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62209014A JPS62209014A (en) | 1987-09-14 |
| JPH023771B2 true JPH023771B2 (en) | 1990-01-24 |
Family
ID=12910142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5227286A Granted JPS62209014A (en) | 1986-03-10 | 1986-03-10 | The first cold wave solution containing added glutathion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62209014A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU743667B2 (en) | 1998-02-23 | 2002-01-31 | Swift Beef Company | Method and system for dehairing animals |
-
1986
- 1986-03-10 JP JP5227286A patent/JPS62209014A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62209014A (en) | 1987-09-14 |
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