JPH02305900A - Ethanol preparation suitable for washing food processing machine and tool - Google Patents

Ethanol preparation suitable for washing food processing machine and tool

Info

Publication number
JPH02305900A
JPH02305900A JP12664389A JP12664389A JPH02305900A JP H02305900 A JPH02305900 A JP H02305900A JP 12664389 A JP12664389 A JP 12664389A JP 12664389 A JP12664389 A JP 12664389A JP H02305900 A JPH02305900 A JP H02305900A
Authority
JP
Japan
Prior art keywords
ethanol
food processing
present
agent
tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12664389A
Other languages
Japanese (ja)
Other versions
JP2609150B2 (en
Inventor
Shigeo Furuhashi
樹雄 古橋
Kazuo Senna
仙名 和夫
Shuntaro Murayama
俊太郎 村山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KEIYO TOUMITSU YUSO KK
Nippon Kayaku Co Ltd
Original Assignee
KEIYO TOUMITSU YUSO KK
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KEIYO TOUMITSU YUSO KK, Nippon Kayaku Co Ltd filed Critical KEIYO TOUMITSU YUSO KK
Priority to JP1126643A priority Critical patent/JP2609150B2/en
Publication of JPH02305900A publication Critical patent/JPH02305900A/en
Application granted granted Critical
Publication of JP2609150B2 publication Critical patent/JP2609150B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

PURPOSE:To obtain the title ethanol preparation having little corrosiveness to metal and scarcely causing stickiness of machinery, etc., after use by incorporating an organic acid salt or reducing sugar into denatured ethanol. CONSTITUTION:An organic acid salt (e.g. sodium malate) or reducing sugar (e.g. malvit) is incorporated into denatured ethanol preferably modified with a food flavor.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、新規な食品加工段波・器具の洗浄に通したエ
タノール剤に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a novel ethanol agent for cleaning food processing stages and utensils.

〔従来の技術] 従来より、濃度70〜95V/V%のエタノールを食品
加工機械・器具の洗浄に使用することは知られている。
[Prior Art] It has been known to use ethanol at a concentration of 70 to 95 V/V% for cleaning food processing machines and equipment.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、このエタノールは、その構成成分が、エタノー
ルと水であるため、食品加工機械・器具の金属腐食、特
に鉄の腐食が著しく洗浄の目的は達するものの充分に満
足できるものではなかった。
However, since the constituent components of this ethanol are ethanol and water, the metal corrosion of food processing machines and utensils, especially the corrosion of iron, is severe, and although the purpose of cleaning is achieved, it is not completely satisfactory.

本発明は、食品加工機械器具に対する金属腐食が軽微で
かつ洗浄を目的とした新規な食品加工機械器具の洗浄に
通したエタノール剤を提供しようとするものである。
The present invention aims to provide a novel ethanol agent that causes minimal metal corrosion to food processing machinery and equipment and is suitable for cleaning food processing machinery and equipment.

〔課題を解決するための手段〕[Means to solve the problem]

本発明者等は、種々検討した結果、変性エタノールに有
機酸塩又は還元糖を添加することにより、金属に対する
腐食を著しく抑制することを発見し、本発明を完成する
に到ったものである。
As a result of various studies, the present inventors discovered that corrosion of metals can be significantly suppressed by adding organic acid salts or reducing sugars to denatured ethanol, leading to the completion of the present invention. .

すなわち、本発明は変性エタノール中にfi酸塩もしく
は還元糖を含有する食品加工機械器具の洗浄に通したエ
タノール剤に関する。
That is, the present invention relates to an ethanol agent containing fi salt or reducing sugar in denatured ethanol and used for cleaning food processing equipment.

変性エタノールはエタノールに各種変性剤を添加し、飲
用に適さなくしだものである。エタノールとしては合・
成品、醗酵品どちらでもよいが、食品機械器具用洗浄と
しては醗酵品が好ましく、洗浄を目的とした濃度として
は45〜99V/V%が一般的で、好ましくは60〜9
8V/V%、さらに好ましく72〜95V/V%の範囲
が望ましい。このエタノールに添加する変性剤としては
、食品用フレーバーであれば特に制限ないが、蛋白など
の窒素含有化合物を多く含む穀物(例えば大豆など)な
どの醸造食品(例えばみそなど)中の油状成分中に含ま
れる香気性物質をエタノールで抽出した抽出物(以下香
気性抽出物という、)を含むフレーバーが好ましく、例
えば香気性抽出物である醸造回収香を含むフレーバーH
−No、9、フレーバーH−No、IO及び同じ香気性
抽出物であるミソ回収香を含むフレーバーfl−No、
11などのフレーバーがあげられるが、特にフレーバー
H−No、11 が好ましい。又、その添加量は0.1
%以上、好ましくは0.1〜1.5%程度がよい。
Denatured ethanol is made by adding various denaturing agents to ethanol to make it unfit for drinking. As ethanol,
Either a fermented product or a fermented product may be used, but a fermented product is preferable for cleaning food machinery and equipment, and the concentration for cleaning purposes is generally 45 to 99 V/V%, preferably 60 to 9
A range of 8V/V%, more preferably 72 to 95V/V% is desirable. There are no particular restrictions on the denaturant to be added to this ethanol, as long as it is a food flavor, but oily components in brewed foods (such as miso), such as grains (such as soybeans) that contain a large amount of nitrogen-containing compounds such as protein, A flavor containing an extract (hereinafter referred to as an aromatic extract) obtained by extracting an aromatic substance contained in
-No. 9, Flavor H-No. IO and Flavor fl-No containing miso recovery aroma which is the same aromatic extract;
Flavors such as No. 11 can be mentioned, and Flavor H-No. 11 is particularly preferred. Also, the amount added is 0.1
% or more, preferably about 0.1 to 1.5%.

有機酸塩としては、有機カルボン酸のナトリウム塩が好
ましく、例えば酢酸ナトリウム、コハク酸ナトリウムな
どの低級(ct ”’cs)脂肪酸カルボン酸のナトリ
ウム塩、フマール酸ナトリウムなどの不飽和カルボン酸
のナトリウム塩、乳酸ナトリウム、リンゴ酸ナトリウム
、クエン酸ナトリウム、酒石酸ナトリウムなどのオキシ
カルボン酸のナトリウム塩、アスパラギン酸ナトリウム
、グルタミン酸ナトリウムなどのモノアミノジカルボン
酸のナトリウム塩などがあげられるが、リンゴ酸のナト
リウム塩が最も好ましい。なお、分子中に2個以上のカ
ルボキシル基の存在する酸の場合、すべてのカルボキシ
ル基がナトリウム塩となっているものが好ましい、これ
らの有機酸塩は単独で使用してもよく、又2種以上併用
してもよい。その使用量は本発明のエタノール剤中有機
カルボン酸塩1種当り約0.001W/匈%〜約5 W
/W%、好ましくは約0.00111/w%〜約I W
/W%、さらに好ましくは約0.005W/W%〜約0
.4賀ハ%程度がよい、又、場合によっては0.001
〜0.14/−%程度使用される。
As the organic acid salt, sodium salts of organic carboxylic acids are preferred, such as sodium salts of lower (ct'''cs) fatty acid carboxylic acids such as sodium acetate and sodium succinate, and sodium salts of unsaturated carboxylic acids such as sodium fumarate. , sodium salts of oxycarboxylic acids such as sodium lactate, sodium malate, sodium citrate, and sodium tartrate, and sodium salts of monoaminodicarboxylic acids such as sodium aspartate and sodium glutamate. Most preferred. In the case of acids with two or more carboxyl groups in the molecule, it is preferred that all the carboxyl groups are sodium salts. These organic acid salts may be used alone, In addition, two or more types may be used in combination.The amount used is about 0.001 W/Hw% to about 5 W per organic carboxylic acid salt in the ethanol agent of the present invention.
/W%, preferably about 0.00111/w% to about IW
/W%, more preferably about 0.005W/W% to about 0
.. About 4% is good, and in some cases 0.001
~0.14/-% is used.

還元糖としては、ソルビット、ソルビット(還元麦芽水
飴)還元オリゴ糖などがあげられるが、−ソルビットが
好ましい。ソルビットは粉末品、液状品の双方が市販さ
れているが、どちらも使用しろる。この還元糖の使用量
は、本発明のエタノール剤中0.001讐/−%〜10
−/讐%、好ましくはO,0OIW/讐%〜5讐/W 
%、さらに好ましくは0.005W/讐%〜1讐/讐%
程度がよい。又、場合によっては0.001〜0.1 
W/W%程度が使用される。
Examples of reducing sugars include sorbitol, sorbitol (reduced malt starch syrup), and reducing oligosaccharides, with -sorbitol being preferred. Sorvit is commercially available in both powder and liquid form, and either can be used. The amount of reducing sugar used is 0.001/-% to 10% in the ethanol agent of the present invention.
-/enemy%, preferably O,0OIW/enemy%~5enemy/W
%, more preferably 0.005 W/en% to 1 en/en%
Good condition. Also, depending on the case, 0.001 to 0.1
About W/W% is used.

本発明のエタノール剤のpHは中性程度から10より低
い程度がよ(好ましくは約pH7−約pH9,5、さら
に好ましくは約pH8−約pH9程度がよい。
The pH of the ethanol agent of the present invention is preferably from neutral to lower than 10 (preferably about pH 7 to about pH 9.5, more preferably about pH 8 to about pH 9).

本発明のアルコール剤にはさらに界面活性剤などの洗浄
補助成分を添加してもよい。界面活性剤としては、例え
ばポリグリセリンの脂肪酸エステルが好ましく、特にポ
リグリセリンのラウレートが好ましい、ポリグリセリン
としては重合度2〜15程度のものが好ましい。その使
用量は本発明のエタノール剤中0〜10讐ハ%、好まし
くはO〜5−/−%、さらに好ましくはO〜IW/−%
程度である。又、場合によっては0.1%以下で使用さ
れる。
A cleaning aid component such as a surfactant may be further added to the alcoholic agent of the present invention. As the surfactant, for example, fatty acid ester of polyglycerin is preferable, and laurate of polyglycerin is particularly preferable. As the polyglycerin, one having a degree of polymerization of about 2 to 15 is preferable. The amount used is 0 to 10%, preferably O to 5-/-%, more preferably O to IW/-% in the ethanol agent of the present invention.
That's about it. In some cases, it is used at 0.1% or less.

なお、金属腐食を押さえるという観点から本発明のアル
コール剤中には有機酸、無機酸などのフリーの酸が実質
的に含まない。
In addition, from the viewpoint of suppressing metal corrosion, the alcohol agent of the present invention does not substantially contain free acids such as organic acids and inorganic acids.

本発明のエタノール剤を製造するには、例えばエタノー
ルに変性剤を添加した後、1種又は2種以上の有機カル
ボン酸の塩及び/又は還元糖、さらに所望により洗浄補
助成分を添加溶解すればよい。
In order to produce the ethanol agent of the present invention, for example, after adding a denaturing agent to ethanol, one or more salts of organic carboxylic acids and/or reducing sugars, and if desired, cleaning auxiliary ingredients are added and dissolved. good.

本発明のエタノール剤の使い方は、本発明のエタノール
剤を機械器具に噴霧洗浄したり、本発明のエタノール剤
を含浸させたダスターで拭いたり、機械器具自体を、本
発明のエタノール剤中にじかに漬けるなど一般的な方法
でよい。
The ethanol agent of the present invention can be used by spraying and cleaning machinery and equipment with the ethanol agent of the present invention, wiping with a duster impregnated with the ethanol agent of the present invention, or directly immersing the machinery and equipment themselves into the ethanol agent of the present invention. You can use common methods such as pickling.

〔作用〕[Effect]

次に本発明のエタノール剤の作用を実験例により説明す
る。
Next, the effect of the ethanol agent of the present invention will be explained using experimental examples.

実験例1 フレーバーH−No、 11を0.5%添加したエタノ
ール濃度75V/V%の変性アルコールに後記表1記載
の各添加剤を添加溶解した本発明のエタノール剤を各5
0dづつ、直径2.51の試験管にいれ、その中に、日
本テ反トバネル工業社製のテストピース5PCG−5B
  (鉄)をいれて、密栓し、室温20°Cに放置し、
金属の腐食度合いを肉眼的に観察した。
Experimental Example 1 Five ethanol agents of the present invention were added and dissolved in denatured alcohol with an ethanol concentration of 75 V/V% to which 0.5% Flavor H-No. 11 was added and each additive listed in Table 1 below was added and dissolved.
0d each in a test tube with a diameter of 2.51, and in it, test piece 5PCG-5B manufactured by Nihon Tebanel Kogyo Co., Ltd.
(iron), seal it tightly, and leave it at room temperature 20°C.
The degree of metal corrosion was visually observed.

なお、対照として未変性エタノールを75V/V%にし
たものを用いた。又、金属の腐食の度合いは−(腐食な
し)、±(わずかの腐食を認める)、+(表面の171
0程度に腐食を認める)十+(表面の175程度に腐食
を認める) 、+++(表面の174程度に腐食を認め
る) ++++ (表面の1/3程度に腐食を認める)
の5段階で表示した。
As a control, undenatured ethanol was used at 75 V/V%. In addition, the degree of corrosion of metal is - (no corrosion), ± (slight corrosion observed), + (171 on the surface).
Corrosion is observed on about 0) 10+ (Corrosion is observed on about 175 of the surface), +++ (Corrosion is observed on about 174 of the surface) +++++ (Corrosion is observed on about 1/3 of the surface)
Displayed in 5 levels.

結果を表1に示す。The results are shown in Table 1.

表−1 この結果から本発明のエタノール剤の鉄に対する腐食性
は極めて低いことが明らかとなった。特にリンゴ酸ナト
リウム添加区では腐食が全く認められず、腐食性におい
て極めてすぐれていることがわかる。
Table 1 The results revealed that the ethanol agent of the present invention has extremely low corrosivity to iron. In particular, no corrosion was observed in the area to which sodium malate was added, indicating that the area had excellent corrosion resistance.

又、本発明品の場合、いずれのエタノール剤を使用して
もベトつきは少なく、又、いずれのエタノール剤で洗浄
した器具を使用して食品を製造しても、風味への影響は
認められなかった。
In addition, in the case of the product of the present invention, there is little stickiness no matter which ethanol agent is used, and no effect on flavor is observed even if food is manufactured using utensils cleaned with either ethanol agent. There wasn't.

〔発明の効果〕〔Effect of the invention〕

以上から明らかなように本発明のエタノール剤は、金属
に対する腐食作用は極めて小さく、使用後の機械等のベ
トつきも少なく、又、食品にその残渣が付着した場合で
も風味を損なわないという優れた効果を発揮するもので
、食品加工機械・器具の洗浄剤として好適である。
As is clear from the above, the ethanol agent of the present invention has an extremely low corrosive effect on metals, is less sticky to machines after use, and has excellent properties such as not impairing flavor even if its residue adheres to food. It is highly effective and is suitable as a cleaning agent for food processing machinery and equipment.

〔実施例] 95%未変性エタノールに下記表2記載のフレーバー等
を添加し、その復水で希釈し、濃度75−95010%
のエタノール剤を得た。なお、フレーバーは0.5%、
その他の成分は0.01%添加した。
[Example] Flavors listed in Table 2 below were added to 95% undenatured ethanol, diluted with condensed water, and the concentration was 75-95010%.
An ethanol agent was obtained. In addition, flavor is 0.5%,
Other components were added in an amount of 0.01%.

Claims (1)

【特許請求の範囲】[Claims] 1、変性エタノール中に有機酸塩もしくは還元糖を含有
する食品加工機械・器具の洗浄に通したエタノール剤
1. Ethanol agent used for cleaning food processing machinery and equipment containing organic acid salts or reducing sugars in denatured ethanol
JP1126643A 1989-05-22 1989-05-22 Ethanol agent suitable for cleaning food processing machinery and equipment Expired - Lifetime JP2609150B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1126643A JP2609150B2 (en) 1989-05-22 1989-05-22 Ethanol agent suitable for cleaning food processing machinery and equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1126643A JP2609150B2 (en) 1989-05-22 1989-05-22 Ethanol agent suitable for cleaning food processing machinery and equipment

Publications (2)

Publication Number Publication Date
JPH02305900A true JPH02305900A (en) 1990-12-19
JP2609150B2 JP2609150B2 (en) 1997-05-14

Family

ID=14940280

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1126643A Expired - Lifetime JP2609150B2 (en) 1989-05-22 1989-05-22 Ethanol agent suitable for cleaning food processing machinery and equipment

Country Status (1)

Country Link
JP (1) JP2609150B2 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5743668A (en) * 1980-08-28 1982-03-11 Asahi Denka Kogyo Kk Preservative for food
JPS5758876A (en) * 1980-09-26 1982-04-08 Ueno Seiyaku Kk Germicide for food, raw ingredient of food, and device for processing food, and its use
JPS58121204A (en) * 1982-01-13 1983-07-19 Nippon Shinyaku Co Ltd Antiseptic composition
JPS5938391A (en) * 1982-08-27 1984-03-02 Dai Ichi Kogyo Seiyaku Co Ltd Alkali rust remover composition
JPS59133377A (en) * 1983-01-18 1984-07-31 Katayama Chem Works Co Ltd Anticorrosive for metal
JPS59205484A (en) * 1983-04-13 1984-11-21 ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト Corrosion controlling liquid
JPS59222588A (en) * 1983-05-31 1984-12-14 Nippon Nohyaku Co Ltd Water treating agent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5743668A (en) * 1980-08-28 1982-03-11 Asahi Denka Kogyo Kk Preservative for food
JPS5758876A (en) * 1980-09-26 1982-04-08 Ueno Seiyaku Kk Germicide for food, raw ingredient of food, and device for processing food, and its use
JPS58121204A (en) * 1982-01-13 1983-07-19 Nippon Shinyaku Co Ltd Antiseptic composition
JPS5938391A (en) * 1982-08-27 1984-03-02 Dai Ichi Kogyo Seiyaku Co Ltd Alkali rust remover composition
JPS59133377A (en) * 1983-01-18 1984-07-31 Katayama Chem Works Co Ltd Anticorrosive for metal
JPS59205484A (en) * 1983-04-13 1984-11-21 ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト Corrosion controlling liquid
JPS59222588A (en) * 1983-05-31 1984-12-14 Nippon Nohyaku Co Ltd Water treating agent

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Publication number Publication date
JP2609150B2 (en) 1997-05-14

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