JPH02296704A - Ozonizer provided with solar battery - Google Patents

Ozonizer provided with solar battery

Info

Publication number
JPH02296704A
JPH02296704A JP1116094A JP11609489A JPH02296704A JP H02296704 A JPH02296704 A JP H02296704A JP 1116094 A JP1116094 A JP 1116094A JP 11609489 A JP11609489 A JP 11609489A JP H02296704 A JPH02296704 A JP H02296704A
Authority
JP
Japan
Prior art keywords
ozone
solar battery
solar cell
power
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1116094A
Other languages
Japanese (ja)
Inventor
Hitoshi Murayama
仁 村山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP1116094A priority Critical patent/JPH02296704A/en
Publication of JPH02296704A publication Critical patent/JPH02296704A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

PURPOSE:To obtain an ozonizer capable of efficiently generating O3 even in an area where there is no power supply equipment by using the power generated by a solar battery and/or an accumulator connected to the solar battery as a power source for driving an O3 generating means. CONSTITUTION:The air as raw gas is introduced 201 into the ozonizer provided with a solar battery and ozonized, and the generated ozone is discharged 202. Meantime, the power from a solar battery 101 is charged into the accumulator 103. A switch 104 is then turned on, the power of the accumulator 103 is converted into AC by an oscillating transistor 106, and a voltage is boosted by a booster transformer 109 and impressed on the electrodes 101 and 111. Consequently, a silent discharge is generated in a discharging gap between a stainless steel pipe 203 for circulating cooling water and a glass tube 204 to generate O3. O3 is easily obtained by this method even in an area where there is no power source equipment such as a commercial power source, provided light energy is available.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、電力供給設備のない未開発地において殺菌、
脱臭、脱色及び医療用に用いる移動可能型の太陽電池付
きオゾン発生装置に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention provides sterilization and
This invention relates to a movable solar cell-equipped ozone generator used for deodorization, decolorization, and medical purposes.

[従来技術及び発明が解決しようとする課題]オゾンは
、殺菌用水処理剤としての他、脱色脱臭用を初めとして
、凝集効果用や、効気性菌の活性向上用から、医療用、
までと極めて広い用途を有するため、近年、オゾン発生
装置の研究が活発に行われている。
[Prior Art and Problems to be Solved by the Invention] Ozone is used not only as a water treatment agent for disinfection, but also for decolorizing and deodorizing, for coagulation effects, for improving the activity of effective bacteria, for medical purposes,
Ozone generators have been extensively researched in recent years because of their extremely wide range of uses.

第3図は従来のオゾン発生装置の代表的な例を示したも
のであり、同図において、301は原料ガス導入口、3
02はオゾン化ガス導出口、3゜3は冷却水循環用ステ
ンレス管、304はガラス管、305は放電電極、30
6は昇圧トランスである。
Figure 3 shows a typical example of a conventional ozone generator. In the figure, 301 is a raw material gas inlet;
02 is an ozonized gas outlet, 3゜3 is a stainless steel tube for cooling water circulation, 304 is a glass tube, 305 is a discharge electrode, 30
6 is a step-up transformer.

空気等の原料ガスは、原料ガス導入口301より導入さ
れ、冷却水循環用ステンレス管303とガラス管304
の間の放電ギャップで起こる無声放電によりオゾンが生
成される。
Raw material gas such as air is introduced from a raw material gas inlet 301, and is passed through a stainless steel pipe 303 and a glass pipe 304 for cooling water circulation.
Ozone is produced by the silent discharge that occurs in the discharge gap between.

印加電圧としては交流、パルス等が用いられるが、近年
では生成効率の向上を目的として、立ち上がりが急峻な
ナノ秒パルスを用いた研究も精力的に行われている。
Alternating current, pulses, etc. are used as the applied voltage, but in recent years, research using nanosecond pulses with a steep rise has been actively conducted with the aim of improving generation efficiency.

また、原料ガス中にAr又はHeを添加することにより
、生成効率を上げようとの試みも成果を挙げている。
Also, attempts to increase the production efficiency by adding Ar or He to the raw material gas have been successful.

しかし、従来のオゾン発生装置においては、原料ガスの
流れの上流側と下流側では、ガスの組成が変化している
にもかかわわらず、該オゾン発生装置内部の放電電極は
、全て同一の電源から電力供給されていたため、ガスの
組成に合わせた放電電圧、投入電力を独立に制御できず
、オゾンの生成効率を充分に高めることはできなかった
However, in conventional ozone generators, even though the gas composition changes on the upstream and downstream sides of the raw material gas flow, the discharge electrodes inside the ozone generator are all connected to the same power source. Because the power was being supplied from the reactor, it was not possible to independently control the discharge voltage and input power according to the gas composition, and it was not possible to sufficiently increase the ozone production efficiency.

また、従来のオゾン発生装置においては、商用電力等の
電力供給設備のない地域での使用は不可能であり、この
ような地域でも使用可能な装置が必要とされていた。
Further, conventional ozone generators cannot be used in areas without power supply facilities such as commercial electric power, and there is a need for an apparatus that can be used in such areas.

[発明の目的] 本発明は、上記従来技術の課題を解決すべく、成された
ものであって、電力供給設備のない地域においても、効
率良くオゾンを生成することを目的としている。
[Object of the Invention] The present invention has been made to solve the problems of the prior art described above, and its purpose is to efficiently generate ozone even in areas without power supply facilities.

[課題を解決するための手段及び作用]本発明は、前記
課題を解決するための手段として、 オゾン発生手段と、太陽電池と、該太陽電池の起電力を
蓄える二次電池とを有し、該二次電池の電力、及び/又
は前記太陽電池の起電力により、前記オゾン発生手段を
駆動して、オゾンを発生することを特徴とする太陽電池
付きオゾン発生装置を提供するものである。
[Means and effects for solving the problem] As a means for solving the problem, the present invention includes an ozone generating means, a solar cell, and a secondary battery that stores the electromotive force of the solar cell. The present invention provides an ozone generator with a solar cell, characterized in that the ozone generating means is driven by the electric power of the secondary battery and/or the electromotive force of the solar cell to generate ozone.

また、前記オゾン発生手段として、原料ガス中で放電す
るための、前記原料ガスの流れ方向に対して、2段以上
に分割された電極を有し、前記各電極に、それぞれ異な
る電圧、電流を印加する手段を有していることを特徴と
する太陽電池付きオゾン発生装置により、上記目的を達
成しようとするものである。
Further, the ozone generating means has an electrode divided into two or more stages with respect to the flow direction of the raw material gas for discharging in the raw material gas, and a different voltage and current are applied to each of the electrodes. It is an object of the present invention to achieve the above object with an ozone generator equipped with a solar cell, which is characterized by having means for applying voltage.

即ち、本発明の太陽電池付きオゾン発生装置はオゾン発
生装置本体と、該オゾン発生装置本体の、例えば上面に
貼り付けられた太陽電池、該太陽電池と接続された二次
電池よりなり、商用電力等を利用しないため、コードレ
スで移動可能である。更に、前記オゾン発生装置の電極
が原料ガスの流れ方向に2段以上に分割されており、各
々に原料ガスの成分に応じた電圧及び電流を印加するこ
とが可能であり、効率的なオゾンの発生を行なえる。
That is, the ozone generator with a solar cell of the present invention consists of an ozone generator main body, a solar cell attached to, for example, the top surface of the ozone generator main body, and a secondary battery connected to the solar cell. Since it does not use any cables, etc., it can be moved without a cord. Furthermore, the electrodes of the ozone generator are divided into two or more stages in the flow direction of the raw material gas, and it is possible to apply a voltage and current depending on the ingredients of the raw material gas to each stage, which enables efficient ozone generation. Can generate.

このような本発明によれば、電力供給設備のない地域に
おいても、光エネルギーさえ得られれば、オゾンを効率
よく発生させることができ、例えば、未開地での飲料水
の殺菌、脱臭等に効果を発揮する。特に、殺菌、脱臭の
必要性の高い夏期には、該太陽電池の出力が太き(なり
、その必要性に十分対応することができる。
According to the present invention, ozone can be efficiently generated even in areas without power supply facilities as long as light energy is obtained, and is effective for sterilizing and deodorizing drinking water in undeveloped areas, for example. demonstrate. In particular, in the summer when the need for sterilization and deodorization is high, the output of the solar cell is high and can sufficiently meet the needs.

また、太陽電池を装置上面に設けることにより、太陽光
を効率よく利用できる。
Furthermore, by providing a solar cell on the top surface of the device, sunlight can be used efficiently.

[実施例] 以下、本発明の実施例を、図面を用いて具体的に説明す
る。
[Examples] Examples of the present invention will be specifically described below with reference to the drawings.

第1図は、本発明のオゾン発生装置の回路図の一例であ
り、第2図は、第1図の回路図からなる本実施例のオゾ
ン発生装置本体の、部分断面図を含む上面図である。
FIG. 1 is an example of a circuit diagram of the ozone generator of the present invention, and FIG. 2 is a top view including a partial sectional view of the main body of the ozone generator of this embodiment, which is constructed from the circuit diagram of FIG. 1. be.

第1図において、101は太陽電池、102はオゾン発
生装置上流側電極、103は二次電池、104はスイッ
チ、105は過充電防止ツェナーダイオード、106は
発振用トランジスタ、107は抵抗、108はコンデン
サ、109は昇圧トランス、110は逆流防止ダイオー
ド、111はオゾン発生装置下流側電極である。
In FIG. 1, 101 is a solar cell, 102 is an upstream electrode of an ozone generator, 103 is a secondary battery, 104 is a switch, 105 is an overcharge prevention Zener diode, 106 is an oscillation transistor, 107 is a resistor, and 108 is a capacitor. , 109 is a step-up transformer, 110 is a backflow prevention diode, and 111 is a downstream electrode of the ozone generator.

また、第2図において、201は原料ガス導入口、20
2はオゾン化ガス導出口、203は冷却水循環用ステン
レス管、204はガラス管、であり、102は原料ガス
上流用の電極、111は原料ガス下流側の電極、101
は本体の外側に設けられた太陽電池である。
In addition, in FIG. 2, 201 is a raw material gas inlet;
2 is an ozonized gas outlet, 203 is a stainless steel tube for cooling water circulation, 204 is a glass tube, 102 is an electrode for the upstream source gas, 111 is an electrode for the downstream side of the source gas, 101
is a solar cell installed outside the main body.

本実施例では、原料ガスとして空気を用い、原料ガス導
入口201から導入し、内部でオゾン化して、オゾン化
ガス導出口202より放出する。
In this embodiment, air is used as the source gas, introduced through the source gas inlet 201, ozonated inside, and discharged through the ozonized gas outlet 202.

また、第1図において、太陽電池101からの電力は、
二次電池103に充電される。この際、すでに十分に充
電が行われている場合には、過充電防止ツェナーダイオ
ード105によって、二次電池103を保護する。また
、逆流防止ダイオード110により二次電池103から
の逆流による太陽電池の破損を防止する。スイッチ10
4をON状態とすることにより、二次電池103の電力
は、発振用トランジスタ106により、交流に変換され
、昇圧トランス109により、高電圧に昇圧され、各電
極102.111に印加される。これにより、冷却水循
環用ステンレス管203とガラス管204の間の放電ギ
ャップで無声放電が起こり、オゾンが生成される。
In addition, in FIG. 1, the power from the solar cell 101 is
The secondary battery 103 is charged. At this time, if the secondary battery 103 has already been sufficiently charged, the overcharge prevention Zener diode 105 protects the secondary battery 103. Further, the backflow prevention diode 110 prevents damage to the solar cell due to backflow from the secondary battery 103. switch 10
4 is turned on, the power of the secondary battery 103 is converted into alternating current by the oscillation transistor 106, boosted to a high voltage by the step-up transformer 109, and applied to each electrode 102.111. As a result, silent discharge occurs in the discharge gap between the cooling water circulating stainless steel tube 203 and the glass tube 204, and ozone is generated.

本実施例では、放電電極は、原料ガスの流れ方向に対し
て、2段に分割されており、おのおの独立した回路構成
により、電極に対する電圧と電流を制御する構成となっ
ている。
In this embodiment, the discharge electrode is divided into two stages with respect to the flow direction of the source gas, and each stage is configured to control the voltage and current to the electrode by an independent circuit configuration.

また、本実施例では、放電電極に高周波電圧を印加する
構造としたが、これは直流電圧、交流電圧、直流と高周
波あるいは交流の重畳電圧のうち、いずれを用いる構造
としてもよい。
Further, in this embodiment, a structure is adopted in which a high frequency voltage is applied to the discharge electrode, but this may be a structure using any of DC voltage, AC voltage, and a superimposed voltage of DC and high frequency or AC.

また、第2図ではオゾン発生装置本体の誘電体として、
ガラス管を用いたが、これに特定されるものではない。
In addition, in Figure 2, as the dielectric of the ozone generator main body,
Although a glass tube was used, the present invention is not limited to this.

また、オゾン発生装置本体としては、いずれの形のオゾ
ン発生装置を用いてもよい。
Furthermore, any type of ozone generator may be used as the ozone generator main body.

以下、実施例の装置を用いて本発明を更に具体的に説明
する。
Hereinafter, the present invention will be explained in more detail using apparatuses according to embodiments.

第1図及び第2図に示した装置を用い、原料ガスとして
空気を用いてオゾンを生成した。
Using the apparatus shown in FIGS. 1 and 2, ozone was generated using air as a raw material gas.

印加電圧としては、上流側電極5kV一定とし、下流側
電極は1kV〜7kVの範囲で1kV間隔で変化させ、
オゾン生成効率の変化を測定した。
The applied voltage was constant at 5 kV for the upstream electrode, and varied at 1 kV intervals in the range of 1 kV to 7 kV for the downstream electrode.
Changes in ozone production efficiency were measured.

第4図は測定結果であり、下流側電極の印加電圧を3k
Vとしたときに、最も高いオゾン生成効率が得られた。
Figure 4 shows the measurement results, and the voltage applied to the downstream electrode was 3k.
When V, the highest ozone generation efficiency was obtained.

このことは、オゾン発生電極を、原料ガスの流れの方向
に多段に分割し、それぞれ独立に、変化する原料ガスの
組成に応じた印加電圧を設定することにより、オゾンの
生成効率を高め得ることを示すものである。
This means that the ozone generation efficiency can be increased by dividing the ozone generation electrode into multiple stages in the direction of the flow of the raw material gas and independently setting the applied voltage according to the changing composition of the raw material gas. This shows that.

尚、本発明のオゾン発生装置は、本実施例に限定される
ことはなく、例えば、多段に分割した電極に対して、一
つの回路構成とし、昇圧トランスの出力側を複数設ける
ことによって、それぞれ、異なる電圧を取り出す構造と
してもよい。
Note that the ozone generator of the present invention is not limited to this embodiment. For example, the ozone generator of the present invention is not limited to this embodiment. For example, by using one circuit configuration for electrodes divided into multiple stages and providing a plurality of output sides of step-up transformers, each , a structure may be used to extract different voltages.

また、多数の太陽電池を直列に接続することにより、高
電圧電源とし、直接、電極に印加することによっても、
構造の簡単なオゾン発生装置とすることかできる。
In addition, by connecting a large number of solar cells in series, a high voltage power source can be created, and by directly applying it to the electrodes,
It can be used as an ozone generator with a simple structure.

また、太陽電池は、装置本体に直接取り付けなくても良
く、より受光条件の良い場所に、分離して設置しても、
本発明は同様の効果を得ることが可能である。
In addition, the solar cells do not have to be attached directly to the main body of the device, and can be installed separately in a location with better light reception conditions.
The present invention can achieve similar effects.

[発明の効果〕 以上説明したように、 オゾン発生手段と、太陽電池と、該太陽電池と接続され
た二次電池とからなり、前記オゾン発生手段の駆動電源
として、太陽電池の発生電力及び/又は前記二次電池の
電力を使用することによって、商用電源等の電源設備の
ない場所等でも、光エネルギーさえ得られれば、使用可
能となる効果がある。これは、例えば、未開地等におけ
る飲料水のオゾンによる殺菌等が容易に可能となるとい
うことである。
[Effects of the Invention] As explained above, it is composed of an ozone generating means, a solar cell, and a secondary battery connected to the solar cell, and as a driving power source for the ozone generating means, the power generated by the solar cell and/or Alternatively, by using the power of the secondary battery, it can be used even in places where there is no power supply equipment such as a commercial power source, as long as light energy can be obtained. This means that, for example, it becomes possible to easily sterilize drinking water with ozone in undeveloped areas and the like.

また、オゾン発生手段として、原料ガスの流れ方向に対
して2段以上に分割された電極を有し、各々の電極に対
し、原料ガスの成分に応じた最適の電圧、電流を印加す
ることによって、従来の一つの電極によるオゾン発生装
置に比較して、効率良くオゾンを生成することができる
In addition, as an ozone generation means, it has an electrode divided into two or more stages in the flow direction of the raw material gas, and by applying the optimal voltage and current to each electrode according to the ingredients of the raw material gas. , it is possible to generate ozone more efficiently than the conventional ozone generator using one electrode.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例の回路図の一例。 第2図は本発明の実施例の部分断面図を含む外観図。 第3図は従来のオゾン発生装置の部分断面図を含む外観
図。 第4図は本実施例の装置で得られたオゾン生成効率と印
加電圧との関係を表すグラフである。 106゜ 107゜ 108゜ 109゜ 110゜ ill。 20 l。 202゜ 203゜ 204゜ 305゜ 306゜ トランジスタ 抵抗 コンデンサ 昇圧トランス 逆流防止ダイオード オゾン発生装置下流側電極 301、原料ガス導入口 オゾン化ガス導出口 303、冷却水循環用ステンレス管 304、ガラス管 放電電極 昇圧トランス
FIG. 1 is an example of a circuit diagram of an embodiment of the present invention. FIG. 2 is an external view including a partial sectional view of an embodiment of the present invention. FIG. 3 is an external view including a partial sectional view of a conventional ozone generator. FIG. 4 is a graph showing the relationship between ozone production efficiency and applied voltage obtained with the apparatus of this example. 106°107°108°109°110°ill. 20 l. 202゜203゜204゜305゜306゜Transistor resistance capacitor step-up transformer backflow prevention diode ozone generator downstream electrode 301, raw material gas inlet ozonized gas outlet 303, stainless steel tube for cooling water circulation 304, glass tube discharge electrode step-up transformer

Claims (2)

【特許請求の範囲】[Claims] (1)オゾン発生手段と、太陽電池と、該太陽電池の起
電力を蓄える二次電池とを有し、該二次電池の電力、及
び/又は前記太陽電池の起電力により、前記オゾン発生
手段を駆動して、オゾンを発生することを特徴とする太
陽電池付きオゾン発生装置
(1) The ozone generating means includes an ozone generating means, a solar cell, and a secondary battery that stores the electromotive force of the solar cell, and the ozone generating means uses the electric power of the secondary battery and/or the electromotive force of the solar cell. An ozone generator with a solar cell, characterized in that it generates ozone by driving a
(2)前記オゾン発生手段として、原料ガスを放電する
ための、該原料ガスの流れ方向に対して、2段以上に分
割された電極を有し、前記各電極に、それぞれ異なる電
圧、電流を印加する手段を有することを特徴とする請求
項1に記載の太陽電池付きオゾン発生装置。
(2) The ozone generating means has an electrode divided into two or more stages with respect to the flow direction of the raw material gas for discharging the raw material gas, and a different voltage and current are applied to each of the electrodes. 2. The ozone generator with a solar cell according to claim 1, further comprising means for applying energy.
JP1116094A 1989-05-11 1989-05-11 Ozonizer provided with solar battery Pending JPH02296704A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1116094A JPH02296704A (en) 1989-05-11 1989-05-11 Ozonizer provided with solar battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1116094A JPH02296704A (en) 1989-05-11 1989-05-11 Ozonizer provided with solar battery

Publications (1)

Publication Number Publication Date
JPH02296704A true JPH02296704A (en) 1990-12-07

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ID=14678560

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1116094A Pending JPH02296704A (en) 1989-05-11 1989-05-11 Ozonizer provided with solar battery

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Country Link
JP (1) JPH02296704A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001073908A1 (en) * 1998-12-10 2001-10-04 Motouchi, Kyoko Ionizer
US6769420B1 (en) 1998-12-10 2004-08-03 Satoko Fujiwara Ionizer
US7224567B2 (en) 2001-11-16 2007-05-29 Kazuo Motouchi Structural arrangements for ion generator to promote ionization efficiency

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001073908A1 (en) * 1998-12-10 2001-10-04 Motouchi, Kyoko Ionizer
US6769420B1 (en) 1998-12-10 2004-08-03 Satoko Fujiwara Ionizer
EP1189319A1 (en) * 2000-03-27 2002-03-20 Motouchi, Kyoko Ionizer
EP1189319A4 (en) * 2000-03-27 2008-05-14 Motouchi Kyoko Ionizer
US7224567B2 (en) 2001-11-16 2007-05-29 Kazuo Motouchi Structural arrangements for ion generator to promote ionization efficiency

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