JPH0229385A - Optical information recording medium - Google Patents
Optical information recording mediumInfo
- Publication number
- JPH0229385A JPH0229385A JP63179659A JP17965988A JPH0229385A JP H0229385 A JPH0229385 A JP H0229385A JP 63179659 A JP63179659 A JP 63179659A JP 17965988 A JP17965988 A JP 17965988A JP H0229385 A JPH0229385 A JP H0229385A
- Authority
- JP
- Japan
- Prior art keywords
- recording layer
- recording medium
- layer
- optical information
- recording
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 17
- 239000010410 layer Substances 0.000 claims abstract description 44
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000011241 protective layer Substances 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 3
- 125000003118 aryl group Chemical group 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 150000002367 halogens Chemical class 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- 229910052738 indium Inorganic materials 0.000 claims abstract description 3
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 3
- 239000000758 substrate Substances 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 230000006866 deterioration Effects 0.000 abstract description 4
- 239000003086 colorant Substances 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 6
- LRFVTYWOQMYALW-UHFFFAOYSA-N 9H-xanthine Chemical compound O=C1NC(=O)NC2=C1NC=N2 LRFVTYWOQMYALW-UHFFFAOYSA-N 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- -1 tetrahydrocholine Chemical compound 0.000 description 3
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229940075420 xanthine Drugs 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910021432 inorganic complex Inorganic materials 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical compound C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(II) oxide Inorganic materials [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/249—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
- G11B7/2492—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds neutral compounds
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Indole Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
゛本発明は光記録分野に使用することのできる改善され
た光情報記録媒体に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an improved optical information recording medium that can be used in the optical recording field.
〔従来の技術及び発明が解決しようとする課題〕これま
で、光情報記録媒体として基板上に低融点金属または低
融点金属と誘電体とからなる記録層を設けたものなどが
提案されているが、これらは保存性が悪い１分解能が低
い、記録密度が低い、製造条件が難しくコスト高になる
などの欠点を有する。そこで、最近になって記録層とし
て金属薄膜に代えて有機色素薄膜を使用することが提案
されている。この有機色素薄膜は融点、分解温度が低く
、熱伝導率も低いので高感度、高密度化の可能性がある
こと、また膜形成がコーティングにより可能なため量産
性が高く、低コスト化が期待できるなどの利点がある。[Prior art and problems to be solved by the invention] Until now, optical information recording media have been proposed in which a recording layer made of a low melting point metal or a low melting point metal and a dielectric is provided on a substrate. , these have disadvantages such as poor storage stability, low resolution, low recording density, difficult manufacturing conditions and high cost. Therefore, it has recently been proposed to use an organic dye thin film as the recording layer in place of the metal thin film. This organic dye thin film has a low melting point, low decomposition temperature, and low thermal conductivity, so it has the potential for high sensitivity and high density, and because film formation can be done by coating, it is highly mass-producible and expected to be low cost. There are advantages such as being able to
従来、前記有機色素被膜として、シアニン色素やメロシ
アニン色素等のポリメチン化合物の被膜を用いることは
知られている。しかし、このような色素で構成された記
録層は、熱及び光安定性に劣り、保存性に難点がある上
、再生劣化しやすいという欠点がある。Conventionally, it has been known to use a film of a polymethine compound such as a cyanine dye or a merocyanine dye as the organic dye film. However, recording layers composed of such dyes have poor heat and light stability, have problems with storage stability, and are susceptible to playback deterioration.
本発明は、熱及び光安定性にすぐれ、再生劣化の改善さ
れた記録層を有する光情報記録媒体を提供することを目
的とする。SUMMARY OF THE INVENTION An object of the present invention is to provide an optical information recording medium having a recording layer with excellent thermal and optical stability and improved reproduction deterioration.
上記目的は、光情報記録媒体における記録層中に下記一
般式（１）及び（Ｉｆ）の中から選ばれる化合物の少な
くとも一種を含有させることにより達成される。The above object is achieved by containing at least one compound selected from the following general formulas (1) and (If) in the recording layer of the optical information recording medium.
一般式（Ｉ）ニ
一般式（■）：
（上記式中、■よＣｕ 、 Ｎｉ 、 Ｐｔ 、 Ｐｄ
、 Ｉｎ 、 ＶＯ又はＴｉ、 Ｒ，−Ｒ４及びＲ９
は水素又は置換もしくは未置換のアルキル基、Ｒ１−Ｒ
６は水素、ハロゲン、水酸基、置換もしくは未置換のア
ルキル基、アルコキシ基又はアリール基を表わす、）
本発明の光情報記録媒体は、基本的には基板上に有機色
素からなる記録層を設けることにより構成されるが、必
要に応じて基板と記録層との間に下引き層をあるいは記
録層の上に保護層を設けることができる。また、このよ
うにして構成された一対の記録媒体を記録層を内側にし
て他の基板と空間を介して密封したエアーサンドインチ
構造にしてもよくあるいは保護層を介して接着した密着
サンドインチ（貼合せ）構造にしてもよい。General formula (I) General formula (■): (In the above formula, ■Cu, Ni, Pt, Pd
, In, VO or Ti, R, -R4 and R9
is hydrogen or a substituted or unsubstituted alkyl group, R1-R
6 represents hydrogen, halogen, hydroxyl group, substituted or unsubstituted alkyl group, alkoxy group or aryl group) The optical information recording medium of the present invention basically comprises a recording layer made of an organic dye provided on a substrate. However, if necessary, an undercoat layer may be provided between the substrate and the recording layer, or a protective layer may be provided on the recording layer. Alternatively, the pair of recording media configured in this manner may be formed into an air sandwich structure in which the recording layer is placed inside and sealed with another substrate through a space, or a tight sandwich structure in which the pair of recording media is bonded through a protective layer. It may also be a laminated structure.
次に、本発明の光情報記録媒体を構成する材料および各
層の必要特性について具体的に説明する。Next, the materials constituting the optical information recording medium of the present invention and the necessary characteristics of each layer will be specifically explained.
（１）基板
基板の必要特性としては基板側より記録再生を行う場合
のみ使用レーザー光に対して透明でなりればならず、記
録側から行う場合は透明である必要はない。基板材料と
しては例えばポリエステル。(1) Substrate As a necessary characteristic of the substrate, it must be transparent to the laser beam used only when recording and reproducing is performed from the substrate side, and it does not need to be transparent when recording and reproducing is performed from the recording side. The substrate material is, for example, polyester.
アクリル樹脂、ポリアミド、ポリカーボネート樹脂、ポ
リオレフィン樹脂、フェノール樹脂、エポキシ樹脂、ポ
リイミドなどのプラスチック、ガラス、セラミックある
いは金属などを用いることができる。Plastics such as acrylic resin, polyamide, polycarbonate resin, polyolefin resin, phenol resin, epoxy resin, polyimide, glass, ceramic, or metal can be used.
なお、基板の表面にはアドレス信号などのプレフォーマ
ットや案内溝のプレグルーブが形成されていてもよい。Note that a preformat such as an address signal or a pregroove for a guide groove may be formed on the surface of the substrate.
（２）記録層
記録層はレーザー光の照射により何らかの光学的変化を
生じさせその変化により情報を記録できるもので、その
主成分が前記一般式（Ｉ）及び（ＩＩ）の中から選ばれ
る少なくとも一種の化合物がらなっている。(2) Recording layer The recording layer causes some optical change by irradiation with laser light and can record information by the change, and the main component thereof is at least one selected from the above general formulas (I) and (II). It is made up of a type of compound.
本発明の記録媒体における記録層には、記録特性及び安
定性向上のために、必要に応じ、他の染料、例えば、フ
タロシアニン系、テトラヒドロコリン系、ジオキサジン
系、トリフエッチアジン系、フェナンスレン系、シアニ
ン（メロシアニン）系、アントラキノン（インダンスレ
ン）系、キサンチン系、トリフェニルメタン系、クロコ
ニウム系、ピリリウム系、スクアリリウム系、アズレン
系染料や、金属又は金属化合物、例えば、Ｉｎ、Ｓｎ、
Ｔｅ、Ｂｉ。In order to improve recording characteristics and stability, the recording layer of the recording medium of the present invention may contain other dyes, such as phthalocyanine, tetrahydrocholine, dioxazine, triphetchazine, phenanthrene, cyanine, etc., as necessary. (merocyanine)-based, anthraquinone (indanthrene)-based, xanthine-based, triphenylmethane-based, croconium-based, pyrylium-based, squarylium-based, azulene-based dyes, metals or metal compounds, such as In, Sn,
Te, Bi.
ＡＱ、Ｓｅ、Ｔｅａ、 、ＳｎＯ，Ａｓ、Ｃｄ等を混合
分散させてもよく、また積層してもよい。AQ, Se, Tea, SnO, As, Cd, etc. may be mixed and dispersed, or may be laminated.
また記録層には、窩分子材料、あるいは上記−般式で表
わされる化合物より長波長域に吸収能を有する有機化合
物（アミニウム、イモニウム、ジイモニウム系化合物等
）又は無機錯体化合物（ビスジチオジケトン系、ビスフ
エニルジチオール系錯体等）などの低分子化合物を混合
分散させてもよい。さらに記録層には、その他、保存安
定剤（金属錯体、フェノール系化合物）、分散剤、難燃
剤、滑剤、可塑剤等を含有させることができる。記録層
の膜厚は１００人〜１０μ■、好ましくは２００人〜２
ｐｓである。記録層の形成方法としては、蒸着、ＣＶＤ
法。In addition, the recording layer may contain a cavity molecular material, an organic compound (aminium, immonium, diimonium compounds, etc.) or an inorganic complex compound (bisdithiodiketone type, A low molecular weight compound such as a bisphenyldithiol complex (such as a bisphenyldithiol complex) may be mixed and dispersed. Furthermore, the recording layer may also contain storage stabilizers (metal complexes, phenolic compounds), dispersants, flame retardants, lubricants, plasticizers, and the like. The thickness of the recording layer is 100 μm to 10 μm, preferably 200 μm to 2 μm.
It is ps. Methods for forming the recording layer include vapor deposition and CVD.
Law.
スパッター法の他、溶剤塗工法、例えば、浸漬コーティ
ング、スプレーコーティング、スピナーコーティング、
ブレードコーティング、ローラコーティング、カーテン
コーティング等を用いることができる。In addition to sputtering, solvent coating methods such as dip coating, spray coating, spinner coating,
Blade coating, roller coating, curtain coating, etc. can be used.
（３）下引き層
下引き層は（ａ）接着性の向上、（ｂ）水又はガスなど
のバリヤー、（ｃ）記録層の保存安定性の向上及び（ｄ
）反射率の向上、（ｅ）溶剤からの基板の保護、（ｆ）
プレグルーブの形成などを目的として使用される。（ａ
）の目的に対しては高分子材料、例えば、アイオノマー
樹脂、ポリアミド樹脂、ビニル系樹脂、天然樹脂、天然
高分子、シリコーン、液状ゴムなどの種々の高分子物質
及びシランカップリング剤などを用いることができ、（
ｂ）及び（ｃ）の目的に対しては上記高分子材料以外に
無機化合物、例えば、Ｓｉｎ、 、ＭｇＦ、 、Ｓｉｎ
、Ｔｉｅ、 、ＺｎＯ，ＴｉＮ、ＳｉＮなど、金属また
は半金属、例えば、Ｚｎ、Ｃｕ、Ｓ、Ｎｉ、Ｃｒ、Ｇｅ
、５ｅｔＡｕ、Ａｇ、Ａｌ１などを用いることができる
。また、（ｄ）の目的に対しては金属、例えば、ＡＱ、
Ａｇ等や、金属光沢を有する有機薄膜、例えば、メチン
染料、キサンチン系染料等を用いることができ、（ｅ）
及び（ｆ）の目的に対しては、紫外線硬化樹脂、熱硬化
樹脂、熱可塑性樹脂等を用いることができる。(3) Undercoat layer The undercoat layer (a) improves adhesion, (b) serves as a barrier against water or gas, (c) improves storage stability of the recording layer, and (d)
) improvement of reflectance, (e) protection of the substrate from solvents, (f)
Used for purposes such as forming pre-grooves. (a
), various polymeric substances such as ionomer resins, polyamide resins, vinyl resins, natural resins, natural polymers, silicones, liquid rubbers, and silane coupling agents may be used. is done, (
For the purposes of b) and (c), inorganic compounds such as Sin, MgF, Sin
, Tie, , ZnO, TiN, SiN, etc., metals or metalloids, such as Zn, Cu, S, Ni, Cr, Ge
, 5etAu, Ag, Al1, etc. can be used. Also, for the purpose of (d), metals such as AQ,
Ag or the like, an organic thin film having metallic luster, for example, methine dye, xanthine dye, etc. can be used, and (e)
For the purpose of (f) and (f), ultraviolet curing resins, thermosetting resins, thermoplastic resins, etc. can be used.
（４）保護層
保護層は、（ａ）記録層をその傷、ホコリ、汚れ等から
保護する、（ｂ）記録層の保存安定性の向上、（ｃ）反
射率の向上等を目的として使用される。これらの目的に
対しては、前記下引き層に示した材料を用いることがで
きる。(4) Protective layer The protective layer is used for the purposes of (a) protecting the recording layer from scratches, dust, dirt, etc., (b) improving storage stability of the recording layer, and (c) improving reflectance. be done. For these purposes, the materials listed above for the undercoat layer can be used.
本発明において、前記下引き層及び保護層には、記録層
の場合と同様に、安定剤、分散剤、難燃剤、滑剤、帯電
防止剤、界面活性剤、可塑剤等を含有させることができ
る。さらに下引き層や保護層に対しても、前記一般式で
表わされる化合物を含有させることができる。In the present invention, the undercoat layer and the protective layer may contain stabilizers, dispersants, flame retardants, lubricants, antistatic agents, surfactants, plasticizers, etc., as in the case of the recording layer. . Furthermore, the undercoat layer and the protective layer can also contain a compound represented by the above general formula.
次に本発明で用いるのに好ましい化合物の具体例を示す
。Next, specific examples of compounds preferable for use in the present invention will be shown.
前記一般式（１）及び一般式（ＩＩ）で表わされる化合
物例をそれぞれ表−１及び表−２に示す。Examples of compounds represented by the general formula (1) and general formula (II) are shown in Table 1 and Table 2, respectively.
以下に実施例をあげて本発明をさらに説明するが、本発
明はこれら実施例のみに限定されるものではない。The present invention will be further explained below with reference to Examples, but the present invention is not limited to these Examples.
（実施例１）
厚さ１．２閣のポリメチルメタクリレート（ＰＭＭＡ）
板（直径１３０ｍ）上にアクリル系フォトポリマーによ
り深さ９００人、半値幅０．４４、ピッチ１．６声のら
線状の案内溝を設けた基板上に、前記化合物＆８の１，
２−ジクロルエタン溶液をスピナー塗布して厚さ１５０
０人の記録層を形成し、記録媒体を得た。(Example 1) Polymethyl methacrylate (PMMA) with a thickness of 1.2 cm
The above compound &8 1,
Apply 2-dichloroethane solution with a spinner to a thickness of 150 mm.
A recording layer of 0 people was formed to obtain a recording medium.
（実施例２）
実施例１の基板上に、前記化合物ＮＱ８と下記化合物（
１）を１＝１の重量比で混合した１、２−ジクロルエタ
ン溶液をスピナー塗布して厚さ１０００人の記録層を形
成し、記録媒体を得た。(Example 2) On the substrate of Example 1, the compound NQ8 and the following compound (
A 1,2-dichloroethane solution containing 1) mixed at a weight ratio of 1=1 was coated with a spinner to form a recording layer with a thickness of 1000 layers to obtain a recording medium.
（実施例３）
実施例１の基板上に厚さ１００人のＴｏ蒸着膜を設けさ
らにその上に前記化合物Ｎａ８の１，２−ジクロルエタ
ン溶液をスピナー塗布して厚さ８００人の記録層を形成
し、記録媒体を得た。(Example 3) A To vapor-deposited film with a thickness of 100 nm was provided on the substrate of Example 1, and a 1,2-dichloroethane solution of the compound Na8 was applied using a spinner to form a recording layer with a thickness of 800 nm. and obtained a recording medium.
（実施例４，５．６）
実施例１の基板上に、前記化合物Ｍａｌ、２．２２をそ
れぞれ真空度１０−’Ｔｏｒｒ下で真空蒸着して厚さ１
０００人の記録層を形成し、記録媒体を得た。(Example 4, 5.6) On the substrate of Example 1, the compounds Mal and 2.22 were vacuum-deposited under a vacuum degree of 10-'Torr to a thickness of 1.
A recording layer of 000 people was formed to obtain a recording medium.
（実施例７，８）
実施例１の基板と同様の形状を持つ射出成形ポリカーボ
ネート基板上に、前記化合物ＮＱ １５．１８をそれぞ
れ実施例４と同様に真空蒸着して記録層を形成し、記録
媒体を得た。(Examples 7 and 8) On an injection molded polycarbonate substrate having the same shape as the substrate of Example 1, the compound NQ 15.18 was vacuum deposited in the same manner as in Example 4 to form a recording layer. Got the medium.
（実施例９）
実施例４において、前記化合物ＮＱＩの代わりに前記化
合物弘１と下記化合物（ＩＩＩ）の共蒸着（１：１）物
を記録層とした以外は同様にして記録媒体を得た。(Example 9) A recording medium was obtained in the same manner as in Example 4 except that the recording layer was co-deposited (1:1) of the compound Hiroshi 1 and the following compound (III) instead of the compound NQI. .
ト“
（比較例１）
実施例１において、前記化合物＆８の代わりに下記化合
物（ＩＩＩ）を用いた以外は同様にして記録媒体前記の
ようにして得た各記録媒体に、波長７９０ｎｍの半導体
レーザー光を基板側より記録周波数５Ｍ１（ｚ、線速２
．１ｍ／ｓｅｅ、記録パワー３ 、５ｍＶで情報を書込
み、再生し、その再生波形のスペクトル解析（スキャニ
ングフィルター、バンド幅３０ＫＨｚ）を行い、Ｃ／Ｎ
を測定した。さらに、この同じ記録媒体に繰返し再生試
験の代用試験として、タングステン光８００００ルクス
下で２０時間放置後、同様の測定を行った。(Comparative Example 1) A recording medium was prepared in the same manner as in Example 1 except that the following compound (III) was used instead of the compound &8. Each recording medium obtained as described above was heated with a semiconductor laser having a wavelength of 790 nm. Recording frequency 5M1 (z, linear velocity 2
．． Information was written and reproduced at 1 m/see and recording power of 3.5 mV, and the spectrum analysis of the reproduced waveform (scanning filter, bandwidth 30 KHz) was performed to determine the C/N.
was measured. Furthermore, as a substitute test for the repeated playback test, the same recording medium was left under 80,000 lux of tungsten light for 20 hours, and then similar measurements were performed.
以上の測定結果を次表に示す。The above measurement results are shown in the table below.
表−３
〔発明の効果〕
上述のようにして構成された本発明の光情報記録媒体は
、半導体レーザー等の長波長光による記録再生が可能で
、熱安定性及び光安定性の向上したもので、保存性にす
ぐれかつ再生劣化の少いものである。さらに、良好な形
状でビットが形成でき、高いＣ／Ｎを得ることができる
。Table 3 [Effects of the Invention] The optical information recording medium of the present invention configured as described above is capable of recording and reproducing using long wavelength light such as a semiconductor laser, and has improved thermal stability and optical stability. It has excellent storage stability and little deterioration during reproduction. Furthermore, a bit can be formed in a good shape and a high C/N can be obtained.
特許出願人 株式会社 リ コ − 代理人弁理士 池浦敏明（ほか１名）Patent applicant Rico Co., Ltd. Representative patent attorney: Toshiaki Ikeura (and one other person)
Claims (1)
さらに必要に応じて保護層を設けてなる光情報記録媒体
において、前記記録層中に、下記一般式（ I ）及び（
II）の中から選ばれる化合物の少なくとも一種を含有さ
せたことを特徴とする光情報記録媒体。 一般式（ I ）： ▲数式、化学式、表等があります▼ 一般式（II）： ▲数式、化学式、表等があります▼ （上記式中、ＭはＣｕ、Ｎｉ、Ｐｔ、Ｐｄ、Ｉｎ、Ｖ０
又はＴｉ、Ｒ＿１〜Ｒ＿４及びＲ＿９は水素又は置換も
しくは未置換のアルキル基、Ｒ＿５〜Ｒ＿８は水素、ハ
ロゲン、水酸基、置換もしくは未置換のアルキル基、ア
ルコキシ基又はアリール基を表わす。）(1) In an optical information recording medium in which a recording layer is provided directly or via an undercoat layer on a substrate and further provided with a protective layer as necessary, the following general formulas (I) and (
An optical information recording medium containing at least one compound selected from II). General formula (I): ▲There are mathematical formulas, chemical formulas, tables, etc.▼ General formula (II): ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the above formula, M is Cu, Ni, Pt, Pd, In, V0
Or Ti, R_1 to R_4 and R_9 represent hydrogen or a substituted or unsubstituted alkyl group, and R_5 to R_8 represent hydrogen, halogen, hydroxyl group, substituted or unsubstituted alkyl group, alkoxy group or aryl group. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63179659A JP2605116B2 (en) | 1988-07-19 | 1988-07-19 | Optical information recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63179659A JP2605116B2 (en) | 1988-07-19 | 1988-07-19 | Optical information recording medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0229385A true JPH0229385A (en) | 1990-01-31 |
| JP2605116B2 JP2605116B2 (en) | 1997-04-30 |
Family
ID=16069639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63179659A Expired - Lifetime JP2605116B2 (en) | 1988-07-19 | 1988-07-19 | Optical information recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2605116B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0822546A2 (en) * | 1996-07-12 | 1998-02-04 | Ciba SC Holding AG | Storage medium with large capacity |
| JPH1086517A (en) * | 1996-09-19 | 1998-04-07 | Konica Corp | Optical recording medium employing metal complex methine coloring matter and recording method |
| JPH1134500A (en) * | 1997-07-16 | 1999-02-09 | Tdk Corp | Optical recording medium using metal-complex type dye |
| KR100750705B1 (en) * | 2004-07-30 | 2007-08-22 | 다이요 유덴 가부시키가이샤 | Optical information recording medium and method of manufacturing |
| CN111841636A (en) * | 2020-06-23 | 2020-10-30 | 泰州九润环保科技有限公司 | Application of metalloporphyrin-mesoporous organic silicon oxide composite material in photocatalytic degradation of organic pollutants |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103554398B (en) * | 2013-10-30 | 2015-07-08 | 华东师范大学 | Preparation method of metal porphyrin-phenolic aldehyde resin |
-
1988
- 1988-07-19 JP JP63179659A patent/JP2605116B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0822546A2 (en) * | 1996-07-12 | 1998-02-04 | Ciba SC Holding AG | Storage medium with large capacity |
| EP0822546A3 (en) * | 1996-07-12 | 1998-04-22 | Ciba SC Holding AG | Storage medium with large capacity |
| JPH1086517A (en) * | 1996-09-19 | 1998-04-07 | Konica Corp | Optical recording medium employing metal complex methine coloring matter and recording method |
| JPH1134500A (en) * | 1997-07-16 | 1999-02-09 | Tdk Corp | Optical recording medium using metal-complex type dye |
| KR100750705B1 (en) * | 2004-07-30 | 2007-08-22 | 다이요 유덴 가부시키가이샤 | Optical information recording medium and method of manufacturing |
| CN111841636A (en) * | 2020-06-23 | 2020-10-30 | 泰州九润环保科技有限公司 | Application of metalloporphyrin-mesoporous organic silicon oxide composite material in photocatalytic degradation of organic pollutants |
| CN111841636B (en) * | 2020-06-23 | 2021-09-03 | 泰州九润环保科技有限公司 | Application of metalloporphyrin-mesoporous organic silicon oxide composite material in photocatalytic degradation of organic pollutants |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2605116B2 (en) | 1997-04-30 |
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