JPH02290300A - Method for preventing scale formation in drainpipe and solid chemicals therefor dissolving vessel - Google Patents

Method for preventing scale formation in drainpipe and solid chemicals therefor dissolving vessel

Info

Publication number
JPH02290300A
JPH02290300A JP34118489A JP34118489A JPH02290300A JP H02290300 A JPH02290300 A JP H02290300A JP 34118489 A JP34118489 A JP 34118489A JP 34118489 A JP34118489 A JP 34118489A JP H02290300 A JPH02290300 A JP H02290300A
Authority
JP
Japan
Prior art keywords
main body
water
solid drug
solid
drain pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34118489A
Other languages
Japanese (ja)
Other versions
JPH0688035B2 (en
Inventor
Eiji Takemura
竹村 栄二
Nobuaki Miyakoshi
宮腰 暢章
Norio Kobayashi
則夫 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Soda Co Ltd
Original Assignee
Nippon Soda Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Soda Co Ltd filed Critical Nippon Soda Co Ltd
Priority to JP1341184A priority Critical patent/JPH0688035B2/en
Publication of JPH02290300A publication Critical patent/JPH02290300A/en
Publication of JPH0688035B2 publication Critical patent/JPH0688035B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)

Abstract

PURPOSE:To improve an effect of preventing scale formation by storing solid chemicals made of sublimating material and water-soluble material in a solid chemicals dissolving vessel and arranging the vessel at an inlet of a drainpipe intermittently. CONSTITUTION:A dissolving vessel can be separated into a lid 1 and a main body 2, and solid chemicals A are stored in the main body 2. The main body 2 consists of a main body shell part 2a, a main body taper part 2, and a main body bottom part 2c, and openings 3c, 3d and 3e are arranged at respective parts. Inside and outside projections 4, 5 are arranged at inside and outside walls of the taper part 2b and bottom part 2c of the main body 2 respectively. The inside projections 4 form a clearance between the main body 2 and the solid chemicals A and perform an action of making a contact between the solid chemicals A and flowing water smooth. Water-soluble material in the solid chemicals is dissolved into the flowing water at a steady rate for a long time, therefore, it is possible to prevent adhesion of scale to a drainpipe by using this method.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、排水管のスケール防止方法及びそれに用いる
固形薬剤溶解器に係り、さらに詳しくは、昇華性物′α
と水溶性物質とからなる固形薬剤を、特定の固形薬剤溶
解器に収納して間欠的に流水のある排水管の入り口に設
置し、流水中に固形薬剤中の水溶性の有効成分を効率的
に溶解させ、排水管へのスケールの固着を防止する方法
及びそれに用いる固形薬剤溶解器に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for preventing scaling of drain pipes and a solid drug dissolver used therein.
A solid drug consisting of a solid drug and a water-soluble substance is stored in a specific solid drug dissolver and placed at the entrance of a drain pipe where water flows intermittently. The present invention relates to a method for preventing scale from sticking to a drain pipe by dissolving it in a solid drug, and a solid drug dissolver used therein.

本発明は、各種水洗トイレ、台所、浴室等の間欠的に流
水のある給排水系の排水管へのスケールの固着防止方法
及びそれに用いる固形薬剤溶解器として好適に採用され
る。
INDUSTRIAL APPLICABILITY The present invention is suitably employed as a method for preventing scale from adhering to drain pipes of water supply and drainage systems that have intermittent running water, such as various flush toilets, kitchens, bathrooms, etc., and as a solid drug dissolver used therein.

〔従来の技術〕[Conventional technology]

本発明者等は、昇華性物質と水溶性のスケール防止有効
成分とからなる固形スケール防止剤を提案し(特開昭6
1−021200号公報参照)、直接便器に投入して使
用する男子用小便器用のスケール防止剤として実用に供
している。
The present inventors proposed a solid scale preventive agent consisting of a sublimable substance and a water-soluble scale preventive active ingredient (Japanese Unexamined Patent Publication No. 6
(Refer to Publication No. 1-021200), it has been put to practical use as an anti-scaling agent for men's urinals, which is used by directly pouring it into the toilet bowl.

また小便器用固形スケール防止剤およびこの小使器用固
形スケール防止剤を収納し、小便器排水管入り口に設置
する小使器排水管入り口の目皿(以下『サナJと記す)
形状のプラス千ンク製容器からなる固形スケール防止剤
溶解器が種々市販されている。
In addition, a solid scale preventive agent for urinals and a perforated plate at the entrance of the urinal drain pipe (hereinafter referred to as ``Sana J'') that houses the solid scale preventive agent for urinals and is installed at the entrance of the urinal drain pipe.
There are various types of solid scale inhibitor dissolvers available on the market, each consisting of a plastic container with a different shape.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

前記特開昭61−021200号公報で提案した固形ス
ケール防止剤は、大気中に放置すると昇華性物質が昇華
し、表面に水溶性有効成分の層が形成され、流水と接触
するとその水溶性有効成分層が流水中に溶解し表面が昇
華性物質層で覆われ、溶解がそれ以上は進行せず、再び
大気中に放置すると表面に水溶性有効成分層が形成され
る性質を存する水溶性有効成分の適量を流水中に溶解す
るに適した固形薬剤である。たとえば直接小便器内に投
入して使用した場合は、昇華と尿および洗浄水による溶
解とが交互に行われることにより形状が崩れず、かつ長
期間にわたって適量の有効成分を排水中に?容解させる
ことができる。
In the solid scale inhibitor proposed in JP-A No. 61-021200, when left in the air, sublimable substances sublimate, forming a layer of water-soluble active ingredients on the surface, and when it comes into contact with running water, the water-soluble active ingredients disappear. Water-soluble active ingredients have the property that the ingredient layer dissolves in running water, the surface is covered with a sublimable substance layer, the dissolution does not proceed any further, and a water-soluble active ingredient layer is formed on the surface when left in the air again. It is a solid drug suitable for dissolving appropriate amounts of ingredients in running water. For example, when used directly in a urinal, sublimation and dissolution by urine and washing water occur alternately, so that the shape does not collapse and the appropriate amount of active ingredients are kept in the drain for a long period of time. can be made to understand.

しかしながら、この固形スケール防止剤は、便器の清掃
等の際に誤って排水管中に落下し水没した場合、溶解が
進行しなくなり、排水管を詰まらせる原因となる。また
形状の崩れは起きないが便器内に異物が存在するためト
イレ使用者に違和感を泡かせる。これらの問題点を解決
する手段として、適当な容器にこの固形スケール防止剤
を収納し、小便器内に設置することが考えられる。
However, if this solid anti-scaling agent accidentally falls into a drain pipe and is submerged in water during cleaning of a toilet bowl, etc., dissolution will not proceed and this will cause clogging of the drain pipe. In addition, although the toilet bowl does not lose its shape, the presence of foreign matter inside the toilet bowl makes the toilet user feel uncomfortable. As a means to solve these problems, it is conceivable to store the solid scale preventive agent in a suitable container and place it in the urinal.

一方、前記市販のサナ型容器に、前記固形スケール防止
剤を収納しトイレ排水管入り口に設置して使用した場合
は、排水管へ落下することもなく、使用者の違和感もな
くなるが、空気の流通が悪く固形スケール防止剤の昇華
性が抑制され、水溶性有効成分の溶解が遅くなりすぎ充
分なスケール防止効果が得られない。
On the other hand, if the solid scale preventive agent is stored in the commercially available container and installed at the entrance of the toilet drain pipe, it will not fall into the drain pipe and the user will not feel any discomfort, but the air Due to poor distribution, the sublimation of the solid scale inhibitor is suppressed, and the water-soluble active ingredient dissolves too slowly, making it impossible to obtain a sufficient scale prevention effect.

本発明は、前記昇華性物質および水溶性物質からなる固
形薬剤を流水と接触させ、流水中に水溶性有効成分の適
曖を溶解する排水管のスケール防止方法及びそれに用い
る固形薬剤溶解器を提供することをその目的とする。
The present invention provides a method for preventing scaling of a drain pipe, in which a solid drug consisting of a sublimable substance and a water-soluble substance is brought into contact with flowing water, and a quantity of a water-soluble active ingredient is dissolved in the flowing water, and a solid drug dissolver used therein. Its purpose is to.

C諜題を解決するための手段〕 本発明者等は、前記目的を達成すべく鋭意研究した結果
、前記昇華性物質と水溶性物質とからなる固形薬剤を、
特定の固形薬剤溶解器に収納し、間欠的に流水のある排
水管入り口に設置した場合、固形薬剤の昇華速度および
溶解速度と、固形薬剤溶解器の開口部面積との間に相関
関係があることを見出し、本発明を完成した。
Means for Solving Problem C] As a result of intensive research to achieve the above object, the present inventors have developed a solid drug consisting of the above-mentioned sublimable substance and water-soluble substance,
When stored in a specific solid drug dissolver and installed at the entrance of a drain pipe with intermittent running water, there is a correlation between the sublimation rate and dissolution rate of the solid drug and the opening area of the solid drug dissolver. They discovered this and completed the present invention.

本発明は、上蓋1と本体2とからなり、上蓋および本体
に設けた開口部3の面積が上蓋の本体上部分と本体の固
形薬剤Aの収納部表面積の合計の25%以上である固形
薬剤溶解器に昇華性物質と水溶性物質とからなる固形薬
剤を収納し、間欠的に流水のある排水管入り口に設置す
ることを特徴とする排水管のスケール防止方法及びそれ
に用いる固形薬剤溶解器である。
The present invention provides a solid drug comprising a top lid 1 and a main body 2, and the area of the opening 3 provided in the top lid and the main body is 25% or more of the total surface area of the upper part of the main body of the top lid and the storage part of the solid drug A in the main body. A method for preventing scaling of a drain pipe, and a solid drug dissolver used therein, characterized in that a solid drug consisting of a sublimable substance and a water-soluble substance is stored in a dissolver, and the dissolver is installed at the entrance of a drain pipe where water flows intermittently. be.

また前記固形薬剤器が、本体のテーバ一部2bに内部突
起物4および/または外部突起物5を、また本体下部に
設置具6を有することを1.!F敬とする排水管のスケ
ール防止方法及びそれに用いる固形薬剤溶解器である。
1. The solid medicine container has an internal protrusion 4 and/or an external protrusion 5 on the tapered portion 2b of the main body, and an installation tool 6 on the lower part of the main body. ! This is a method for preventing scale in drain pipes and a solid drug dissolver used therein.

本発明を、本発明で使用する固形薬剤溶解器の一実施態
様を示す添付図面(第1図および第2図)にJ5づき詳
細に説明する。
The present invention will be described in detail with reference to the accompanying drawings (FIGS. 1 and 2) showing one embodiment of the solid drug dissolver used in the present invention.

添付第IIAおよび第2図に示すように、固形薬剤C容
解器は、上MIと本体2とに分割できる構造となってお
り、固形薬剤Aは木体2内に収情される。上蓋lおよび
本体2には開口部3が設けられ、上MIは本体上部分1
a(以下「蓋部」という)木体2の外径より張り出した
ひさし部1bとからなり、π部1aには開口部3a,3
bが設けられる。
As shown in attached FIG. IIA and FIG. 2, the solid medicine C container has a structure that can be divided into an upper MI and a main body 2, and the solid medicine A is collected in the wooden body 2. The upper lid l and the main body 2 are provided with an opening 3, and the upper MI is provided with an upper part 1 of the main body.
a (hereinafter referred to as "lid part") consists of an eaves part 1b that overhangs from the outer diameter of the wooden body 2, and the π part 1a has openings 3a, 3.
b is provided.

本体2は、固形薬剤を収納する本体側胴部2a、本体テ
ーパー部2bおよび本体底部2Cからなり、各部分には
開口部3c,3d,3eが設けられる.前記固形薬剤溶
解器において、liI記開口部3の面積の合計は、上誼
lの蓋部1aと本体2の固形薬剤八を収納している部分
(2a,2bおよび20部分)の表11j 4+’fの
合計の25%以上、好ましくは50%以上である。
The main body 2 consists of a main body side body part 2a for storing a solid drug, a main body tapered part 2b, and a main body bottom part 2C, and openings 3c, 3d, and 3e are provided in each part. In the solid medicine dissolver, the total area of the opening 3 of the upper body 1 and the part (2a, 2b and 20 parts) of the main body 2 that accommodates the solid medicine 8 is calculated as shown in Table 11j 4+ 'f is at least 25% of the total, preferably at least 50%.

上兼1は、水の排水管への流入を妨げず、かつ固形物の
流入を防止できる構造であれば、その形状に制限はない
。たとえば図面に示す形状以外にも平らな円板、円錐形
、逆円錐形、半円板、四角板、三角板等の形状とするこ
とができる。しかしながら尿、水道水等の高速流水が直
接当たる場所に設置される固形薬剤溶解器にあっては、
流水の飛散を防止できる形状、たとえば球面、円錐形等
であることが望ましい。また小便器、台所等に設置する
溶解器にあっては、違和I8を与えない形状、たとえば
サナR4Q形状、排水口水栓類似形状等であることが望
ましい。上蓋1の開口部3a.3bの平面形状にも制限
はなく、図面に例示した形状以外にも各種任意の平面形
状、たとえば円、四角形、三角形、星形、メノソユ、ス
リノト等とすることができる。また開口部3a,3bの
断面形状にも制限はなく、図面に示す形状以外の任意の
形状とすることができる。図面Gこ記載された上Mlの
ひさし部1bは、特に設けなくてもよく、またより大き
くしてもよい。さらにひさし部ibを、たとえば柔軟な
プラスチック製のスリノトやメッソエ等の流水を排水管
への流入を妨げない+Il造とし、かつ排水管入り口の
周辺部に密着できる構造とする、:とにより排水管への
異物の流入を防止でき、かつ固形薬剤溶解器を設置場所
に安定させることができる。
There is no restriction on the shape of the upper part 1 as long as it has a structure that does not obstruct the flow of water into the drain pipe and prevents the flow of solid matter. For example, in addition to the shape shown in the drawings, the shape may be a flat disk, a cone, an inverted cone, a semicircle, a square plate, a triangular plate, or the like. However, for solid drug dissolvers that are installed in locations that are directly exposed to high-speed flowing water such as urine or tap water,
It is desirable to have a shape that can prevent running water from scattering, such as a spherical or conical shape. Furthermore, for dissolvers installed in urinals, kitchens, etc., it is desirable that they have a shape that does not cause discomfort, such as a Sana R4Q shape or a shape similar to a drain faucet. Opening 3a of upper lid 1. The planar shape of 3b is also not limited, and can be any arbitrary planar shape other than the shapes exemplified in the drawings, such as a circle, square, triangle, star, menosaurus, or surinote. Further, there is no limit to the cross-sectional shape of the openings 3a and 3b, and they can have any shape other than the shape shown in the drawings. The eaves portion 1b of the upper Ml shown in FIG. G may not be particularly provided, or may be made larger. Furthermore, the eaves part ib is made of a flexible plastic material such as Surinoto or Messoe that does not prevent flowing water from flowing into the drain pipe, and has a structure that allows it to fit tightly around the entrance of the drain pipe. It is possible to prevent foreign matter from entering the solid drug dissolver and to stabilize the solid drug dissolver at the installation location.

本体2は、収納した固形薬剤と流水とを接触させ得る構
造であればその形状に制限はなく、図面に例示する以外
にも各種任意の形状、たとえば円柱、四角柱、三角柱、
半球、逆円錐等とすることができる。
The shape of the main body 2 is not limited as long as it has a structure that allows the stored solid drug to come into contact with flowing water, and may have any arbitrary shape other than those illustrated in the drawings, such as a cylinder, a square prism, a triangular prism,
It can be a hemisphere, an inverted cone, etc.

木体2の開口部3c.3d,3eの形状にも制限はなく
、図面に示す形状以外にも各種任意の形状、たとえば円
形、三角形、星形、メッシュ、スリット等とすることが
でき、固形薬剤の排水管への落下を防止し、かつ流水の
流れを妨げない目開きを脊していればよい。具体的には
、31以上、10mm以下の目開きであることが望まし
い。
Opening 3c in wooden body 2. There are no restrictions on the shapes of 3d and 3e, and in addition to the shapes shown in the drawings, they can be of any shape, such as circular, triangular, star-shaped, mesh, slit, etc., to prevent solid drugs from falling into the drain pipe. It is sufficient that the openings are wide enough to prevent the flow of water. Specifically, it is desirable that the opening is 31 or more and 10 mm or less.

また本体2のテーバ一部2bと底部2Cにの内壁には、
内部突起物4、外壁には外部突起物5が好ましく設けら
れる。内部突起物4は、木体2と固形薬剤Aとの間に空
隙をつくり固形薬剤Aと流水の接触をスムーズに行わせ
る働きを有し、外部突起物5は、排水管入り口と木体2
との間に空隙をつくり流水量が多い場合に固形薬剤Aの
溶解に必要な量以外の流水をスムーズに排水管内に導く
働きを有する。
In addition, on the inner wall of the tapered part 2b and bottom part 2C of the main body 2,
An internal protrusion 4 and an external protrusion 5 are preferably provided on the outer wall. The internal protrusions 4 have the function of creating a gap between the wooden body 2 and the solid medicine A to allow smooth contact between the solid medicine A and running water.
It has the function of creating a gap between the drain pipe and the drain pipe to smoothly guide the water other than the amount required for dissolving the solid drug A into the drain pipe when the amount of water flowing is large.

内部突起物4は、本体2内壁と固形薬剤Aとの間に空隙
を形成し、かつその空隙を流水がスムーズに’t&れ得
る任意の形状、たとえば円柱、半円社、:角柱、半球等
の図面に示す以外の形状としてもよい。内部突起物4は
、通常3箇所以上に設ける.レ1面に示すような本体形
状や半球形のような底部程流水路が狭くなる本体形状を
有する固形薬削請解器にあっては、第1図に示す如く底
}11jの突起物の1斯さを上部の突起物高さより品く
することにより、流水と固形藁剤△との接触をスムーズ
に行わせることができる。
The internal protrusion 4 forms a gap between the inner wall of the main body 2 and the solid drug A, and has an arbitrary shape that allows flowing water to flow smoothly through the gap, such as a cylinder, a semicircle, a square cylinder, a hemisphere, etc. It is also possible to have a shape other than that shown in the drawing. Internal protrusions 4 are usually provided at three or more locations. In the case of a solid chemical scraper having a body shape as shown in Figure 1 or a body shape such as a hemispherical shape in which the flow channel becomes narrower toward the bottom, the projections on the bottom 11j as shown in Figure 1 are By making the height higher than the height of the upper protrusion, smooth contact between the running water and the solid straw agent Δ can be achieved.

外部突起物5は、本体2外壁とりF.水管B入り口もし
くはその周辺部との間に安定な空隙を形成し、スムーズ
に流水をJ通させ得る形状であれば任意の形状、たとえ
ば円柱、三角柱、四角柱、半球等とすることができる。
The external protrusion 5 is attached to the outer wall of the main body 2 F. It can be of any shape, such as a cylinder, triangular prism, square prism, hemisphere, etc., as long as it forms a stable gap with the water pipe B entrance or its surroundings and allows flowing water to pass through J smoothly.

内部突起物4および外部突起物5は、図面に示す如く本
体2壁面に構造物として設けるが、もしくは本体2壁面
の一部を内部および外部に突出させることにより形成す
る。木体2壁而の一部を突出させた内部突起物4または
外部突起物5においては、それらにも開口部3を設けて
もよい。
The internal protrusion 4 and the external protrusion 5 are provided as structures on the wall surface of the main body 2 as shown in the drawings, or are formed by making a part of the wall surface of the main body 2 protrude inside and outside. An opening 3 may also be provided in the internal protrusion 4 or external protrusion 5 in which a part of the wooden body 2 wall protrudes.

内部突起物4と外部突起物5の高さは、流水雫および流
水中に溶解させる必要存効成分量によって異なる。流水
量が多い場所に設置される固形薬削溶解器においては、
内部および外部突起物45の高さが高く流水をスムーズ
に流す構造が、また流水一が少ない場所に設置される固
形薬剤溶解器においては、それぞれの突起物の閏さが低
く疏水が固形薬剤Aと充分に接触する構造が採用される
。流水惜が少晰で、かつ尚4度の有効成分を溶解させる
必要がある場所に設置する固形藁剤溶解器にあっては、
外部突起物5はなくてもよく、また外部突起物5、内部
突起物4の双方のない構造とすることもできる。
The heights of the internal protrusions 4 and the external protrusions 5 vary depending on the amount of flowing water and the amount of active ingredient required to be dissolved in the flowing water. For solid chemical shavings dissolving machines installed in places with a large amount of water flowing,
In a solid drug dissolver installed in a place where there is little flowing water, the internal and external protrusions 45 have a high height to allow water to flow smoothly. A structure is adopted that allows sufficient contact with the For solid straw dissolving devices installed in locations where there is little running water and it is necessary to dissolve 4 degrees of active ingredients,
The external protrusion 5 may not be provided, or a structure may be provided in which both the external protrusion 5 and the internal protrusion 4 are not provided.

固形薬剤溶解器を、排水管入り口に安定に設置するため
に、図面に示すように設置具6を、本体2底部に設け、
排水管内に挿入して設置する。
In order to stably install the solid drug dissolver at the entrance of the drain pipe, an installation tool 6 is provided at the bottom of the main body 2 as shown in the drawing.
Install by inserting it into the drain pipe.

図面に示す固形薬剤溶解器は、排水管B入り口への設置
を目的とするため、排水管に挿入可能な方式の設置具6
を有するが、設置場所に応じて設置具6は任意の形状、
たとえば3本以上の棒状脚、ゴム製の吸着盤等を採用し
てもよい。
The solid drug dissolver shown in the drawing is intended to be installed at the entrance of drain pipe B, so an installation tool 6 that can be inserted into the drain pipe is used.
However, the installation tool 6 can have any shape depending on the installation location.
For example, three or more rod-like legs, a rubber suction cup, etc. may be used.

特に図面に示す挿入方式の設置具6は、排水管B内に挿
入されることがら、固形薬剤溶解器をfj1水管13入
り口に安定に設置でき、かつ排水の流れを妨げない構造
であればその形状に制限はない。
In particular, since the insertion type installation tool 6 shown in the drawing is inserted into the drain pipe B, it can be installed as long as the solid drug dissolver can be stably installed at the entrance of the fj1 water pipe 13 and has a structure that does not obstruct the flow of waste water. There are no restrictions on the shape.

たとえば円筒、円錐、逆円錐、四角筒、三角筒およびそ
れらに多数の穴を明けた形状、棒状物の先瑞ζこ直交す
る棒を付けた形4ffi,板を直交させた形状等とする
ことができる。
For example, shapes such as cylinders, cones, inverted cones, square tubes, triangular tubes, and shapes with many holes in them, shapes with rods attached perpendicular to the ends of rods, shapes with plates orthogonal, etc. I can do it.

場所に違和感を生じず、かつ排水管内に落下しない大き
さでなくてはならない。
It must be large enough so that it does not create a sense of discomfort in the area and does not fall into the drain pipe.

また固形薬剤溶解器は、既知の各種材質、たとえば各棟
プラスチック、ステンレススチール、砲金、陶磁器等の
材質によって成形、製造できる。
Further, the solid drug dissolver can be molded and manufactured using various known materials, such as plastic, stainless steel, gun metal, and ceramics.

さらにこの固形薬剤溶解器は、2分割構造以上に細分δ
りし得る構造とすることもできる。
Furthermore, this solid drug dissolver has a subdivision δ of more than two-part structure.
It is also possible to have a structure that allows for

本発明において、固形藁剤}容解2gには本体イMj胴
部2a下部に、たとえば柔軟なプラスチック製のメ/ン
ニやスリノト等の流水の排水管への流入を妨げない横造
を有し、かつ排水管B入り口の14辺部に密着させるこ
とのできる鍔を設けることができる。この鍔は、…I述
した同様の構造を有する上漂1のひさし部1bと同様に
、排水管への異物の流入を防止し、かつ固形薬剤溶解器
を設14場所に安定させるはたらきを有する。
In the present invention, the solid straw agent 2g has a horizontal structure at the lower part of the main body 2a, such as a flexible plastic men/menni or surinote, which does not obstruct the flow of running water into the drain pipe. , and a collar that can be brought into close contact with the 14 sides of the drain pipe B entrance can be provided. This collar has the function of preventing foreign matter from flowing into the drain pipe and stabilizing the solid drug dissolver at the installation location, similar to the eaves part 1b of the upper float 1 having a similar structure as described above. .

本発明において、固形薬剤溶解器の大きさは、設置場所
、使用目的等によりWなるが、設置した本発明において
、固形薬剤1容解器に収納される固形薬剤は、昇華性物
質と水溶性物質とがらなる固形薬剤である。この固形薬
剤において、昇華性物質とは、常温において昇華減少し
得る既知の物質であり、たとえばバラジクロルヘンゼン
、ナフタリン等であり、水溶性物質とは、水に溶解しが
つ常温で固体の既知物質である。各種の水溶性有効成分
は、その単独もしくは他の水溶性物質と共に昇華性物質
と混合、成形される。
In the present invention, the size of the solid drug dissolver varies depending on the installation location, purpose of use, etc. However, in the present invention, the solid drug stored in one solid drug dissolver is a sublimable substance and a water-soluble substance. It is a solid drug consisting of a substance. In this solid drug, sublimable substances are known substances that can sublimate and decrease at room temperature, such as balajichlorhenzene, naphthalene, etc., and water-soluble substances are substances that are soluble in water and solid at room temperature. It is a known substance. Various water-soluble active ingredients are mixed with a sublimable substance alone or together with other water-soluble substances, and then molded.

固形薬剤の形状は、固形薬剤溶解器に収納可能な形状で
あれば任意であるが、球状、偏平球状、円板状等である
ことが望ましい。
The shape of the solid drug may be arbitrary as long as it can be stored in the solid drug dissolver, but it is preferably spherical, oblate spherical, disc-shaped, or the like.

本発明において、固形薬剤溶解器は、固形薬剤を収容し
、小便器、浴場、台所等の排水管入り口、家庭用水洗ト
イレのロータンク+洗部、水洗1〜イレ洗浄水流水路、
洗面所蛇口落下部等の間欠的Cこ流水に接触する場所お
よび水洗トイレのハイタンク注水口等の流水と大気に同
時に接触している場所に設置して使用する。
In the present invention, the solid drug dissolver accommodates a solid drug, and can be used at the entrance of a drain pipe in a urinal, a bathroom, a kitchen, etc., the low tank + flush section of a household flush toilet, flush 1 to flush water flow channels,
It is installed and used in places that come into contact with intermittent running water, such as the falling part of a washroom faucet, and in places that come into contact with running water and the atmosphere at the same time, such as the high tank water inlet of a flush toilet.

〔作   用] 本発明において、111T記詳述した固形薬剤溶解器に
、昇華性物質と水溶性物質とからなる固形薬剤を収柄し
、間欠的に流水のある個所、たとえば男子トイレ等にナ
サに代えて設置することにより、固形薬剤中の昇華性物
質の昇華速度が安定化し、かつ水溶性物質が長期間安定
した速度で流水中にl容解する。
[Function] In the present invention, a solid drug consisting of a sublimable substance and a water-soluble substance is collected in the solid drug dissolver described in detail in 111T, and placed in a place where there is intermittent running water, such as a men's restroom. By installing the sublimation agent instead, the sublimation rate of the sublimable substance in the solid drug is stabilized, and the water-soluble substance is dissolved in flowing water at a stable rate for a long period of time.

昇華性物質と水溶性′#J質との均一混合物からなる固
形薬剤は、大気と接触すると昇華性物質が昇華し表面に
水溶性物質層が形成され、水溶性物質層がI1なると昇
華がlrll制される。形成された水溶性物質層は、流
水と接触することにより溶解除去され、固形薬剤の表面
は昇華性物質Il!jで覆われイ容解が抑制される。昇
華性物質の昇華は、固形薬剤の表1hjから均一に行わ
れ、かつ昇華性物質が昇華して形成された水(容性物質
層はポーラスであり少槽の水でも容易にt容解する。ま
た固形薬剤に均一に水が接触しない状態でも形状が崩れ
ることなくl容解する。さらに長!リ1間流水との接触
がない場合には騨華が抑制され、多晴の流水と接触する
場合には溶解が抑制されることから、有効成分が長期間
にわたって安定に流水中に溶解する。
When a solid drug consisting of a homogeneous mixture of a sublimable substance and a water-soluble substance comes into contact with the atmosphere, the sublimable substance sublimates and a water-soluble substance layer is formed on the surface, and when the water-soluble substance layer becomes I1, the sublimation stops lrll. be controlled. The formed water-soluble substance layer is dissolved and removed by contact with running water, and the surface of the solid drug is covered with the sublimable substance Il! It is covered with j and the i-acceptance is suppressed. The sublimation of the sublimable substance is performed uniformly as shown in Table 1hj of the solid drug, and the sublimable substance is sublimated into water (the sublimable substance layer is porous and easily dissolved in water in a small tank). In addition, even if the solid drug does not come into uniform contact with water, it will dissolve without losing its shape.Furthermore, if there is no contact with running water for a long period of time, stagnation will be suppressed, and the solid drug will not come in contact with running water. In this case, dissolution is suppressed, so that the active ingredient is stably dissolved in running water for a long period of time.

小便器、台所、浴場等において、排水管に詰まりを生し
るのは少量の徘水が高濃度の汚染成分を含む場合であり
、多量かつ低4度の汚染成分を含む排水の場合には打1
水管の詰まりは起きにくい。
In urinals, kitchens, bathrooms, etc., drain pipes become clogged when a small amount of floating water contains highly concentrated pollutants. Hit 1
Clogged water pipes are unlikely to occur.

昇華性物質と水溶性物質とからなる固形薬剤は、間欠的
に流水中に水溶性物質を溶解させる用途、特に小便器、
台所、浴場等の排水管の詰まり防止剤として優れた性状
を存している。
Solid medicines consisting of sublimable substances and water-soluble substances are used in applications where water-soluble substances are intermittently dissolved in running water, especially in urinals,
It has excellent properties as an anti-clog agent for drain pipes in kitchens, bathrooms, etc.

昇華性物質と水溶性物質とからなる固形薬剤を、開口部
面積が木体2および蓋部1aの表面積の2594未満で
ある固形’V ff’t i8解器に収納した場合、d
.争性物笹の昇華が抑制され流水と接触しても水冷性の
有効成分が微小噴しか溶解せず、必要噴の有効成分を流
水中に溶解させることが困難となる。
When a solid drug consisting of a sublimable substance and a water-soluble substance is stored in a solid 'Vff't i8 disintegrator whose opening area is less than 2594 of the surface area of the wooden body 2 and the lid part 1a, d
.. The sublimation of the competitive bamboo is suppressed, and even when it comes into contact with running water, the water-cooling active ingredient dissolves in only a small amount, making it difficult to dissolve the necessary amount of the active ingredient in the running water.

本発明においては、固形薬剤溶解器の開口部面積を本体
2および,π部1aの表面積の25%以−jことしたこ
とにより、昇華性物質の茎気を充分拡敗させることがで
き、昇華性物質と水冷性物質とからなる固形薬剤の有効
成分を流水中に有効に溶解させることができる。
In the present invention, by setting the opening area of the solid drug dissolver to 25% or more of the surface area of the main body 2 and the π section 1a, the stems of the sublimable substance can be sufficiently spread, and the sublimation The active ingredient of a solid drug consisting of a water-cooling substance and a water-cooling substance can be effectively dissolved in running water.

固形薬剤の溶解速度は、この開口面積によって異なり、
気温が高く固形薬剤の昇華速度および溶解速度が速くな
る夏期には、25%以上の範囲内で開口部面積を小さく
し1華性物質の昇華を抑制することにより溶解を抑制し
、気i1’r.Lが低く固形薬剤の昇華速度および溶解
速度が遅くなる冬1り1には、固形薬剤溶解器の開口部
面積を大きくし、昇華および溶解を促進させることがで
き、年間を通して均一な薬剤溶解址が得られる。
The dissolution rate of solid drugs depends on this opening area,
In summer, when the temperature is high and the sublimation rate and dissolution rate of solid drugs are high, dissolution is suppressed by reducing the opening area within a range of 25% or more and suppressing the sublimation of 1-color substances. r. In winter, when L is low and the sublimation rate and dissolution rate of solid drugs are slow, the opening area of the solid drug dissolver can be increased to promote sublimation and dissolution, resulting in a uniform drug dissolution site throughout the year. is obtained.

〔実 施 例〕〔Example〕

本発明を、実施例によりさらに詳細に説明する。 The present invention will be explained in more detail by way of examples.

ただし、本発明の範囲は、下記実施例により何ら限定さ
れるものではない。
However, the scope of the present invention is not limited in any way by the following examples.

(+1  固形薬剤溶解器 (A−1). (A−2).  (C−1) および(
C−2)固形薬剤溶解容器として、添付第1図、第2図
に示す構造を有し、ト惹lと本体2の開口部3の面積の
合計が、上謎1の本体上部分と本体2の固形薬剤収納部
の表面積の合計の60%である固形薬斉h容解器(^−
1)および30%である (^−2)、ならびに比較用
として上蓋1と本体2の開口部3の面積の合計が、上M
1の本体上部分と本体2の固形薬剤収納部の表面積の合
計の10%である固形剰剤溶解器(C−1)および12
%である市阪の固形薬剤溶解器(C−2)を’la備し
た。
(+1 Solid drug dissolver (A-1). (A-2). (C-1) and (
C-2) As a solid drug dissolution container, it has the structure shown in the attached Figures 1 and 2, and the total area of the opening 3 of the main body 2 and the top part of the main body 1 is the same as that of the upper part of the main body 1. The solid drug storage container (^-
1) and 30% (^-2), and for comparison, the total area of the opening 3 of the upper lid 1 and the main body 2 is
A solid surplus drug dissolver (C-1) and a solid drug dissolver (C-1), which is 10% of the total surface area of the upper part of the main body 1 and the solid drug storage part of the main body 2;
It was equipped with a solid drug dissolver (C-2) manufactured by Ichisaka.

(2)固形薬剤の溶解試験 パラジク口ルヘンゼン粉末50%とスルファミン酸粉末
50%(重@基Y$)のlPt台品を加圧成形した直径
45闘、重量60gの円仮伏固形薬剤を、前記固形薬剤
溶解器(A−1). (A−2), (C−1)および
(C−2)に収納し、それぞれを壁掛けストール形小便
器の排水管を腐食防止剤入り塩酸でm帰した後、排水管
入り口に設置した。小便器は1回42の洗浄水で30分
間に1回自動洗浄を行いつつ、通常どおりに使用した。
(2) Dissolution test of solid drug A rounded solid drug with a diameter of 45 cm and a weight of 60 g was prepared by pressure molding an lPt product containing 50% Parajik Luhensen powder and 50% sulfamic acid powder (heavy @ group Y $). The solid drug dissolver (A-1). (A-2), (C-1) and (C-2), each of which was installed at the entrance of the drain pipe after soaking the drain pipe of a wall-mounted stall-type urinal with hydrochloric acid containing a corrosion inhibitor. The urinal was used as usual, with automatic cleaning performed once every 30 minutes using 42 washes of water each time.

30日後に固形薬剤の溶解量を測定すると共に、排水管
入り口部の汚れを観察した。
After 30 days, the amount of dissolved solid drug was measured and the stain at the entrance of the drain pipe was observed.

試験結果を、固形薬剤を使用しなかったブランクの結果
と共に、第1表中に示す。
The test results are shown in Table 1 along with the results of a blank in which no solid drug was used.

第1表中、便器tηれは、固形薬剤を設置して30日後
の排水管入り口部の状態を下記の3段階で表示した。
In Table 1, the condition of the drain pipe entrance 30 days after the installation of the solid medicine was expressed in the following three levels.

O:汚れなし Δ;少し汚れ ×:lηれまた固形薬剤
の溶解率は、下記弐により算出した。
O: No stain Δ: Slight stain ×: lη Moreover, the dissolution rate of the solid drug was calculated according to 2 below.

設;6“時の 固形薬剤車量 30[1後の 固形薬剤】ji @ 溶解率一 × 1 0 0 設i6“時の固形薬剤11℃ν 第 ■ 表 〔発明の効果〕 FiiT記第1表中に示したように、上蓋と本体に十分
な大きさの開口部を有する固形薬剤溶解器に、昇華性物
買であるパラジク口ルヘンゼンおよび水溶j生物質であ
るスルファミン酸からなる固形薬剤を収納し、トイレ排
水管入り口に設置することにより、スルファミン酸が長
時間にわたり効果的に尿または洗浄水に溶解し小便器排
水管の汚れを防止する。一方、開口部而槓が不足する比
較例の固形桑削溶解器を使用した場合には、薬剤溶解速
度が遅く、その結果小便器排水管のtクれが認められる
Amount of solid drug truck at setting 6": 30 [solid drug after 1] ji @ Dissolution rate 1 x 1 0 0 Solid drug at setting i6": 11°C ν Table ■ [Effects of the invention] FiiT Table 1 As shown in the figure, a solid drug consisting of a sublimable substance, parasitic acid, and a water-soluble biological substance, sulfamic acid, is stored in a solid drug dissolver having a sufficiently large opening in the top lid and main body. By installing it at the entrance of the toilet drain pipe, sulfamic acid effectively dissolves in urine or flush water over a long period of time, preventing the urinal drain pipe from becoming dirty. On the other hand, when the solid mulberry shavings dissolver of the comparative example, which lacks the opening part, is used, the drug dissolution rate is slow, and as a result, the urinal drain pipe is observed to be bent.

吏施例においては、パラジクロルヘンゼンとスルファミ
ン酸からなる固形薬剤収納し、小便器排水管入り口に設
置した場合の例を示したが、1!li′l形薬剤溶解器
に他の昇(自)性物質および水溶性物竹からなる固形薬
剤を収納し、台所、浴場等の間欠的に流水と接触する場
所に設置した場合においても、固形薬剤を長期間にわた
り効果的に溶解し、その排水管のスケール固着を防止す
ることができる。
In the example, we have shown an example in which a solid drug consisting of paradichlorohenzene and sulfamic acid is stored and installed at the entrance of the urinal drain pipe, but 1! Even if a Li'l-type drug dissolver is used to store solid drugs made of other ascending substances and water-soluble materials, and is installed in a place where it comes into contact with running water intermittently, such as in a kitchen or bathroom, the solid It is possible to effectively dissolve chemicals over a long period of time and prevent scale from sticking to drain pipes.

本発明は、昇華性物質および水溶性物官からなる固形薬
剤を固形薬剤溶解器に収.納し、使用場所に安定に設置
し、かつ長期間にわたり効果的に流水中に薬剤を溶解さ
せることにより、排水管へのスケール固着を防止する方
法及びそれに用いる固形薬剤溶解器を提供するものであ
り、その産業的意義および公衆衛生的意義は極めて大き
い。
In the present invention, a solid drug consisting of a sublimable substance and a water-soluble substance is stored in a solid drug dissolver. The present invention provides a method for preventing scale from sticking to drain pipes by storing and stably installing the drug in the place of use, and effectively dissolving the drug in flowing water over a long period of time, and a solid drug dissolver used therein. It has great industrial and public health significance.

【図面の簡単な説明】[Brief explanation of drawings]

第1図,二本発明で使用する固形薬剤溶解器の一実施a
様を示す断面図。 第2図:第1図の斜視図。 (使用符号〕 1 :上盈     Ia;惹部 1b;ひさし部   2 :本体 2a;側胴部    2b.テーバ一部2c;底部  
   3 −開口部 3a,3b:上惹開口部 3c.3d,3e:木体開口部 4 :内部突起物  5 :外部突起物6 ;設置具 A 、固形薬剤   B −排水管
Figures 1 and 2: An implementation of the solid drug dissolver used in the present invention a
FIG. Figure 2: Perspective view of Figure 1. (Code used) 1: Upper roof Ia; Attachment part 1b; Eaves part 2: Main body 2a; Side body part 2b. Taber part 2c; Bottom part
3 - Openings 3a, 3b: Upper opening 3c. 3d, 3e: Wood opening 4: Internal protrusion 5: External protrusion 6; Installation tool A, solid drug B - Drain pipe

Claims (6)

【特許請求の範囲】[Claims] (1)上蓋1と本体2とからなり、上蓋および本体に設
けた開口部3の面積が上蓋の本体上部分と本体の固形薬
剤Aの収納部表面積の合計の25%以上である固形薬剤
溶解器に昇華性物質と水溶性物質とからなる固形薬剤を
収納し、間欠的に流水のある排水管入り口に設置するこ
とを特徴とする排水管のスケール防止方法
(1) Consisting of a top lid 1 and a main body 2, the area of the opening 3 provided in the top lid and the main body is 25% or more of the total surface area of the upper part of the main body of the top lid and the solid drug A storage part of the main body. A method for preventing scale in a drain pipe, characterized by storing a solid chemical consisting of a sublimable substance and a water-soluble substance in a container, and installing the container at the entrance of a drain pipe where water flows intermittently.
(2)請求項第(1)項において、固形薬剤溶解器が、
本体のテーパー部2bに内部突起物4および/または外
部突起物5を有することを特徴とする排水管のスケール
防止方法
(2) In claim (1), the solid drug dissolver comprises:
A method for preventing scaling of a drain pipe characterized by having an internal protrusion 4 and/or an external protrusion 5 on the tapered part 2b of the main body
(3)請求項第(1)項または第(2)項において、固
形薬剤溶解器において、本体下部に設置具6を有するこ
とを特徴とする排水管のスケール防止方法
(3) A method for preventing scale in a drain pipe according to claim (1) or (2), characterized in that the solid drug dissolver has an installation tool 6 at the bottom of the main body.
(4)上蓋1と本体2とからなり、上蓋および本体に設
けた開口部3の面積が上蓋の本体上部分と本体の固形薬
剤Aの収納部表面積の合計の25%以上であり、内部に
昇華性物質と水溶性物質とからなる固形薬剤を収納し間
欠的に流水のある場所に設置することを特徴とする固形
薬剤溶解器
(4) Consisting of a top lid 1 and a main body 2, the area of the opening 3 provided in the top lid and the main body is 25% or more of the total surface area of the upper part of the main body of the top lid and the solid medicine A storage part of the main body, and A solid drug dissolver that stores a solid drug consisting of a sublimable substance and a water-soluble substance and is installed in a place where there is intermittent running water.
(5)請求項第(4)項に記載の固形薬剤溶解器におい
て、本体のテーパー部2bに内部突起物4および/また
は外部突起物5を設けたことを特徴とする固形薬剤溶解
(5) The solid drug dissolver according to claim (4), characterized in that an internal protrusion 4 and/or an external protrusion 5 are provided on the tapered portion 2b of the main body.
(6)請求項第(4)項または第(5)項に記載の固形
薬剤溶解器において、本体下部に設置具6を設けたこと
を特徴とする固形薬剤溶解器
(6) The solid drug dissolver according to claim (4) or (5), characterized in that an installation tool 6 is provided at the bottom of the main body.
JP1341184A 1989-12-28 1989-12-28 Drain pipe scale prevention method and solid drug dissolver used therefor Expired - Lifetime JPH0688035B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1341184A JPH0688035B2 (en) 1989-12-28 1989-12-28 Drain pipe scale prevention method and solid drug dissolver used therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1341184A JPH0688035B2 (en) 1989-12-28 1989-12-28 Drain pipe scale prevention method and solid drug dissolver used therefor

Publications (2)

Publication Number Publication Date
JPH02290300A true JPH02290300A (en) 1990-11-30
JPH0688035B2 JPH0688035B2 (en) 1994-11-09

Family

ID=18344008

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1341184A Expired - Lifetime JPH0688035B2 (en) 1989-12-28 1989-12-28 Drain pipe scale prevention method and solid drug dissolver used therefor

Country Status (1)

Country Link
JP (1) JPH0688035B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205746A (en) * 2018-10-24 2019-01-15 中科协创环境科技江苏有限公司 It is a kind of for handling the filter device of coal chemical industry high-concentration sewage
JP2021080653A (en) * 2019-11-14 2021-05-27 株式会社エスエイチユー Drain part medicine holder

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB897733A (en) * 1958-08-05 1962-05-30 Brook Chemicals Ltd Improvements in or relating to disinfecting and deodorising compositions
FR1501248A (en) * 1965-11-19 1967-11-10 Agent for cleaning the basin of water closets and urinals with water washing and container for this agent
US3597772A (en) * 1968-12-13 1971-08-10 Chemtrust Ind Corp Lavatory sanitation bodies
JPS5011347U (en) * 1973-05-25 1975-02-05
JPS51745U (en) * 1974-06-18 1976-01-06
JPS5623431U (en) * 1979-07-30 1981-03-03
JPS57168668A (en) * 1981-04-10 1982-10-18 Mutsuo Endou Washing anti-stain aromatic agent
JPS5984072U (en) * 1982-11-27 1984-06-06 矢後 直義 Decorative containers for toilets
JPS6121200A (en) * 1984-07-10 1986-01-29 日本曹達株式会社 Scale preventing agent and prevention
JPS6285575U (en) * 1985-11-13 1987-06-01

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB897733A (en) * 1958-08-05 1962-05-30 Brook Chemicals Ltd Improvements in or relating to disinfecting and deodorising compositions
FR1501248A (en) * 1965-11-19 1967-11-10 Agent for cleaning the basin of water closets and urinals with water washing and container for this agent
US3597772A (en) * 1968-12-13 1971-08-10 Chemtrust Ind Corp Lavatory sanitation bodies
JPS5011347U (en) * 1973-05-25 1975-02-05
JPS51745U (en) * 1974-06-18 1976-01-06
JPS5623431U (en) * 1979-07-30 1981-03-03
JPS57168668A (en) * 1981-04-10 1982-10-18 Mutsuo Endou Washing anti-stain aromatic agent
JPS5984072U (en) * 1982-11-27 1984-06-06 矢後 直義 Decorative containers for toilets
JPS6121200A (en) * 1984-07-10 1986-01-29 日本曹達株式会社 Scale preventing agent and prevention
JPS6285575U (en) * 1985-11-13 1987-06-01

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205746A (en) * 2018-10-24 2019-01-15 中科协创环境科技江苏有限公司 It is a kind of for handling the filter device of coal chemical industry high-concentration sewage
CN109205746B (en) * 2018-10-24 2024-02-06 中科协创环境科技江苏有限公司 A filter equipment for handling coal industry high concentration sewage
JP2021080653A (en) * 2019-11-14 2021-05-27 株式会社エスエイチユー Drain part medicine holder

Also Published As

Publication number Publication date
JPH0688035B2 (en) 1994-11-09

Similar Documents

Publication Publication Date Title
US5336424A (en) Improved urinal block composition
US7921479B2 (en) Water-conserving urinal block and holder
WO2012135910A1 (en) A urinal deodoriser cartridge
JP2931255B2 (en) How to prevent scale on toilet drainpipe
AU2017261534A1 (en) Urinal Mat
US5759574A (en) Tel-tale-tablets
JPH02290300A (en) Method for preventing scale formation in drainpipe and solid chemicals therefor dissolving vessel
JPH0137011Y2 (en)
JPH1121973A (en) Removing tool of dirt and offensive odor of toilet seat
JP2784904B2 (en) Scale inhibitor for toilet drainpipe
JP3775507B2 (en) Drug supply tool for flush toilet
CN2257838Y (en) Slowly-released device of automatic cleaning agent for flushing toilet
JP4647826B2 (en) Detachable trap in the trap removable toilet
JP2928772B2 (en) Prevention method of scale sticking of toilet drain pipe
JP3164126B2 (en) Solid chemical dissolver for aquarium
JP2506198Y2 (en) Chemical holding device for drain of urinal
CN208346943U (en) A kind of stainless steel glass trough urinal
KR102582634B1 (en) Medicines for removing and preventing urinary stones
JPH0431335Y2 (en)
JPH0529268Y2 (en)
US20240183141A1 (en) Universal self cleaning system for toilets and methods thereof
JPH0213579Y2 (en)
JPH02225733A (en) Drug injection device for flush toilet stool
JPH03223386A (en) Method for stainproofing and deodorizing toilet bowl
JPS5930075Y2 (en) Aromatic toilet cleaner

Legal Events

Date Code Title Description
EXPY Cancellation because of completion of term