JPH02276837A - Treatment of porous material - Google Patents
Treatment of porous materialInfo
- Publication number
- JPH02276837A JPH02276837A JP9964989A JP9964989A JPH02276837A JP H02276837 A JPH02276837 A JP H02276837A JP 9964989 A JP9964989 A JP 9964989A JP 9964989 A JP9964989 A JP 9964989A JP H02276837 A JPH02276837 A JP H02276837A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- open cells
- porous body
- gas
- continuous pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011148 porous material Substances 0.000 title claims abstract description 41
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 33
- 239000000057 synthetic resin Substances 0.000 claims abstract description 33
- 239000003595 mist Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 7
- 239000007789 gas Substances 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 6
- 239000007921 spray Substances 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 239000003570 air Substances 0.000 abstract description 2
- 229910052786 argon Inorganic materials 0.000 abstract description 2
- 239000011261 inert gas Substances 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000009423 ventilation Methods 0.000 description 6
- 239000004745 nonwoven fabric Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000001471 micro-filtration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- -1 dolchlorethylene Chemical compound 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Filtering Materials (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はＰ紙、不織布、編織物、焼結体、発泡体等の連
続気孔を有する多孔体の処理方法に関するものであり、
該多孔体は主としてフィルターとして使用される。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for treating porous bodies having open pores such as P paper, nonwoven fabrics, knitted fabrics, sintered bodies, foamed bodies, etc.
The porous body is mainly used as a filter.
Ｐ紙、不織布、編織物、焼結体、発泡体等の連続気孔を
有する多孔体は主としてフィルターとして用いられてい
るが、上記多孔体の連続気孔の孔径は一般には５μ以上
であるが、最近の電子工業等では更に微細な濾過を行な
う必要性が高まり、１μ以下更には０．１μ以下の微細
孔径の連続気孔を有する多孔体が要求されている。しか
しながらこれら多孔体の連続気孔の孔径を小さくするこ
とは極めて困難であった。例えばＦ紙、不織布、編織物
等の繊維材料では使用する繊維の径を小さくすればよい
が、繊維の径を小さくするには限Ｊｆｆがあるし、焼結
体等では焼結体を構成する粒子径を小さくすればよいが
、粒子径を小さくすることにも限度がある。また発泡体
においては連続気孔の径の調節は極めて困難である。し
たがって微細濾過にあっては、止むを得ず価格の非常に
高い特殊な繊維素誘導体やブラスチヴクからなる微細連
続気孔を有する多孔体を使用しているのが現状である０
〔課題を解決するための手段〕
本発明は上記従来の課題を解決するだめの手段として、
連続気孔を有する多孔体に合成樹脂溶液の霧滴を混合し
た気体を送通し、該多孔体の連続気孔の壁面に該合成樹
脂溶液を塗布した後乾燥することによって該連続気孔の
孔径を縮小する多孔体の処理方法を提供するものである
。Porous bodies with open pores such as P paper, nonwoven fabrics, knitted fabrics, sintered bodies, and foamed bodies are mainly used as filters.The pore diameter of the open pores of the above porous bodies is generally 5μ or more, but recently In the electronics industry, etc., there is an increasing need for finer filtration, and porous bodies having continuous pores with micropore diameters of 1 μm or less, and even 0.1 μm or less are required. However, it has been extremely difficult to reduce the diameter of continuous pores in these porous bodies. For example, for fiber materials such as F paper, nonwoven fabrics, and knitted fabrics, the diameter of the fibers used can be reduced, but there is a limit Jff to reducing the diameter of the fibers, and for sintered bodies, etc. It is sufficient to reduce the particle size, but there is a limit to reducing the particle size. Furthermore, in foams, it is extremely difficult to adjust the diameter of continuous pores. Therefore, in microfiltration, it is unavoidable to use a porous body with fine continuous pores made of special cellulose derivatives and blastivuk, which are extremely expensive0 [To solve the problem] [Means for Solving the Problem] The present invention provides the following means for solving the above-mentioned conventional problems.
A gas mixed with mist of a synthetic resin solution is passed through a porous body having continuous pores, and the synthetic resin solution is applied to the walls of the continuous pores of the porous body and then dried to reduce the pore size of the continuous pores. The present invention provides a method for treating a porous body.
本発明で用いられる連続気孔を有する多孔体とは、上記
したようにｐ紙、不織布、編織物等の繊維材料、焼結体
のような粒子固結体、無機あるいは有機の発泡体である
。As described above, the porous body having continuous pores used in the present invention includes fiber materials such as paper, nonwoven fabrics, and knitted fabrics, solidified particles such as sintered bodies, and inorganic or organic foams.
本発明で用いられる合成樹脂溶液とはエポキシ樹脂、ウ
レタン樹脂、メラミン樹脂、尿素樹脂、フェノール樹脂
、アクリル樹脂、酢酸ビニル樹脂、スチレン樹脂等の熱
硬化性合成樹脂、熱可塑性合成樹脂のドルオール、キジ
ロール、酢酸エチル、酢酸ブチル、アセトン、メチルエ
チルケトン、メタノール、エタノール、ドルクロルエチ
レン、ｎ−ヘキサン、水等の溶剤の単独または二種以上
の混合溶剤に溶解させた溶液である。上記例示は本発明
を限定するものではなく、本発明においては広範囲な合
成樹脂および溶剤が用いられる。The synthetic resin solutions used in the present invention are thermosetting synthetic resins such as epoxy resins, urethane resins, melamine resins, urea resins, phenol resins, acrylic resins, vinyl acetate resins, and styrene resins, thermoplastic synthetic resins such as drol, It is a solution dissolved in a single solvent or a mixture of two or more of solvents such as quidylol, ethyl acetate, butyl acetate, acetone, methyl ethyl ketone, methanol, ethanol, dolchlorethylene, n-hexane, and water. The above examples are not intended to limit the invention, and a wide range of synthetic resins and solvents may be used in the invention.
上記合成樹脂溶液は通常合成樹脂を１０〜６０重量係程
度含むものであるが、本発明においては上記合成樹脂溶
液の濃度は特に限定されるものではなく、該合成樹脂溶
液の濃度は該溶液が霧滴になり易い粘度を有するように
調節されることが望ましい。The synthetic resin solution usually contains about 10 to 60 parts by weight of synthetic resin, but in the present invention, the concentration of the synthetic resin solution is not particularly limited. It is desirable that the viscosity is adjusted so that the viscosity easily increases.
更に上記合成樹脂溶液には所望により硬化剤、可塑剤、
染料、あるいは目的によって消臭剤、還元剤、酸化剤等
の処理剤を混合して本よい。Furthermore, the synthetic resin solution may contain a curing agent, a plasticizer,
Depending on the purpose, dyes or processing agents such as deodorants, reducing agents, and oxidizing agents may be mixed.
本発明においては連続気孔を有する多孔体に空気、窒素
、アルゴン等の望ましくは不活性な気体を送通し、該気
体にスプレー等により合成樹脂溶液の霧滴を混合する。In the present invention, a preferably inert gas such as air, nitrogen, or argon is passed through a porous body having continuous pores, and mist droplets of a synthetic resin solution are mixed with the gas by spraying or the like.
本発明の作用を第１図〜第３図により説明する。 The operation of the present invention will be explained with reference to FIGS. 1 to 3.
図において（１）は多孔体、（２）は該多孔体（１）の
連続気孔である。該多孔体（１）に第１図に示すように
矢印方向から気体を送通する。該気体に合成樹脂溶液の
液滴（３）を混合すると、該液滴（３）は多孔体（１）
の連続気孔（２）の入口に付着するが、第２図に示すよ
うに気体の送通圧に押されて連続気孔（２）内に泥波し
て該連続気孔（２）の壁面＋２）Ａ（例えばｐ紙であれ
は戸紙を構成するバルブ繊維の周壁面）に液膜（４）を
形成する。その後該乾燥によって液膜（４）の溶剤を除
去すれば、第３図に示すように多孔体（１１の連続気孔
（２）の壁面（２）Ａは合成樹脂層（５）に被覆され、
したがって多孔体（１）の連続気孔（２）の径は縮小さ
れる。In the figure, (1) is a porous body, and (2) is a continuous pore of the porous body (1). Gas is passed through the porous body (1) from the direction of the arrow as shown in FIG. When the droplets (3) of the synthetic resin solution are mixed with the gas, the droplets (3) form the porous body (1).
However, as shown in Figure 2, it is pushed by the pressure of the gas and flows into the continuous pore (2), causing a wave of water to form on the wall surface of the continuous pore (2) (+2). A liquid film (4) is formed on A (for example, in the case of P paper, the peripheral wall surface of the valve fibers constituting the door paper). After that, when the solvent of the liquid film (4) is removed by drying, the wall surface (2) A of the porous body (11 continuous pores (2)) is covered with the synthetic resin layer (5), as shown in FIG.
Therefore, the diameter of the continuous pores (2) of the porous body (1) is reduced.
合成樹脂層（５）の厚さは気体に対する液滴（３）の混
合量や該液滴（３）を混合した気体の送通量で調節され
得るから連続気孔（２）の孔径を所望の径に縮小するこ
とが出来る。そして多孔体＋１１の連続気孔（２）の孔
径は一般にバラツキがあるけれども、連続気孔（２）の
孔径の大きな本のは気体の通過抵抗が小さいから優先的
に液滴を混合した気体が通過し、その結果孔径の大きな
連続気孔（２）から壁面（２）Ａに液膜（４）が形成さ
れて行く。かくして連続気孔（２）は孔径を縮小される
とともにバラツキが均一化されるのである。The thickness of the synthetic resin layer (5) can be adjusted by adjusting the amount of the droplets (3) mixed with the gas and the amount of gas mixed with the droplets (3), so the diameter of the continuous pores (2) can be adjusted to a desired value. It can be reduced in diameter. Although the pore diameters of the continuous pores (2) in porous body +11 generally vary, the continuous pores (2) with larger pore diameters have a smaller resistance to gas passage, so the gas mixed with the droplets passes through them preferentially. As a result, a liquid film (4) is formed on the wall surface (2) A from the continuous pores (2) with large pore diameters. In this way, the diameter of the continuous pores (2) is reduced and the variation is made uniform.
したがって本発明においては、多孔体の連続気孔の孔径
を合成樹脂層によって所定の径に縮小しかつ均一化する
ことが極めて容易に可能であシ、微細濾過用の多孔質体
を非常に安価に提供出来る。Therefore, in the present invention, it is extremely easy to reduce the pore diameter of the continuous pores of the porous body to a predetermined diameter and make it uniform by using the synthetic resin layer, and the porous body for microfiltration can be manufactured at a very low cost. I can provide it.
また多孔体が合成樹脂層によって補強されかつ耐薬品性
を向上させることも出来る。Further, the porous body can be reinforced with a synthetic resin layer and its chemical resistance can be improved.
本発明を第４図に示す一実施例によって説明すると、０
υはガイド筒であり、該ガイド筒αＤの根端部には送風
機Ｃ１２１が配され、中間にはスプレーガンα鵠が挿着
され、先端部にはクリップ（１４）が取付けられ、該ク
リップ（１４）に多孔体ｔｌ）が支持される。そして該
送風機（Ｉｚを作動させて矢印に示すように空気を該多
孔体（１）に送通し、スプレーガンＯＪより該空気中に
合成樹脂溶液の液滴（３）を混合する。このようにして
多孔体（１）に液滴（３）を混合した空気を送通すると
第１図〜第３図に示すプロセスによって多孔体（１）の
連続気孔（２）の壁面（２）Ａに合成樹脂層（５）が形
成される。合成樹脂層（５）の形成にあたっては常温で
送風のみ行なうか、あるいは加熱して乾燥、あるいは乾
燥硬化させる。The present invention will be explained with reference to an embodiment shown in FIG.
υ is a guide tube, a blower C121 is arranged at the root end of the guide tube αD, a spray gun α is inserted in the middle, and a clip (14) is attached to the tip. 14) supports the porous body tl). Then, operate the blower (Iz) to send air through the porous body (1) as shown by the arrow, and mix the droplets (3) of the synthetic resin solution into the air using the spray gun OJ. When air mixed with droplets (3) is passed through the porous body (1), the droplets (3) are synthesized on the wall surface (2) A of the continuous pores (2) of the porous body (1) through the process shown in Figures 1 to 3. A resin layer (5) is formed.In forming the synthetic resin layer (5), only air is blown at room temperature, or it is dried by heating or dried and hardened.
上記多孔体Ｔ１）としては例えば下記のものが採用され
る。As the above-mentioned porous body T1), for example, the following is employed.
（１）７紙
（２）ポリエステル不織布
（３）アルミナ焼結体
（４）ポリウレタン発泡体
上記合成樹脂溶液としては例えば下記のものが採用され
る。(1) 7 paper (2) Polyester nonwoven fabric (3) Alumina sintered body (4) Polyurethane foam As the above synthetic resin solution, for example, the following are employed.
（１）エポキシ樹脂 １５重量係硬化剤
５１
ドルオール ２０
（２）メラミン樹脂 ２５重量係硬化剤
０．５１
メタノール ６０
水 １４．５＃
（３）アクリル樹脂栢 １０重量係酢酸エチル
９０ １
＊１；アクリル樹脂：メチルメタクリレートとエチルア
クリレートとの６０：４０重量比の共重合体
（４）スチレン樹脂＊２ １５重量係メチルエチルケ
トン ８５
＊２ ；スチレンとブタジェンとの８０：２０重量比の
共重合体
上記実施例において多孔体（１）を面積１ｄ、孔径６μ
の連続気孔（２）を有するＦ紙＋１）を用い、合成樹脂
溶液をエポキシ樹脂溶液＋１）を用いた場合、本発明の
処理によって７紙（１）の連続気孔の孔径は下表のよう
に縮小される。(1) Epoxy resin 15 weight coefficient hardening agent
51 Dorol 20 (2) Melamine resin 25 Weight coefficient hardening agent
0.51 Methanol 60 Water 14.5 # (3) Acrylic resin 10 weight ratio Ethyl acetate
90 1 *1; Acrylic resin: 60:40 weight ratio copolymer of methyl methacrylate and ethyl acrylate (4) Styrene resin *2 15 weight ratio Methyl ethyl ketone 85 *2; 80:20 weight ratio of styrene and butadiene Copolymer In the above example, the porous body (1) had an area of 1 d and a pore diameter of 6 μm.
When F paper +1) with continuous pores (2) of Reduced.
本発明において多孔体として濾紙を用いる場合には通常
第５図に示すようなサポータ−（２１１を用いる。該サ
ポータ−ｃ１１）は多孔筒体器と該多孔筒体（２ｚの両
端に形成されるフランジＣ２３，（２４１とからなる。When filter paper is used as the porous body in the present invention, a supporter (211) as shown in FIG. It consists of flanges C23 and (241).
該サポータ−＋２１１には第６図に示すようにつづら折
りした７紙（１）が支持され、該サポータ−１２１＋の
多孔筒体■の一端には栓（ハ）が嵌着される。したがっ
て本発明の処理方法は第７図に示すように濾紙（１）を
サポータ−Ｃ＋ｔ＋に支持した状態で実施されてもよい
。As shown in FIG. 6, the supporter +211 supports seven pieces of paper (1) folded in a zigzag manner, and a stopper (c) is fitted into one end of the porous cylinder (2) of the supporter (121+). Therefore, the treatment method of the present invention may be carried out with the filter paper (1) supported on the supporter C+t+ as shown in FIG.
即ち濾紙（１）を支持したサポータ−ｃ２１１を複数個
チャンバーＣ３１１内に収容し、該サポータ−ＣＤの開
口端をチャンバーＣ３１）の支板（ハ）の連絡口（ハ）
にセットして送風ポンプ（至）の吸引側に連絡する吸引
径路（ロ）をチャンバーＣ３１＋の底部に接続し、該送
風ポンプ（至）の吐出側に連絡する送風径路（至）はチ
ャンバーＣ３１１の側面に接続し、該送風径路（至）の
途中には合成樹脂溶液のスプレーガンＧでが挿入される
。That is, a plurality of supports c211 supporting filter paper (1) are housed in a chamber C311, and the open end of the supporter CD is connected to the communication port (c) of the support plate (c) of the chamber C31).
The suction path (B) that connects to the suction side of the ventilation pump (TO) is connected to the bottom of the chamber C31+, and the ventilation path (B) that connects to the discharge side of the ventilation pump (TO) is connected to the A spray gun G for a synthetic resin solution is connected to the side surface, and a spray gun G for a synthetic resin solution is inserted in the middle of the ventilation path.
上記構成において送風ポンプ四を作動させればチャンバ
ーＣ３１１内の空気はサポータ−Ｑυに支持されている
濾紙（１１を通してサポータ−ＣＤ内に流入し吸引径路
ｃ３４）を介して送風ポンプ（至）の吸引側に吸引され
、送風側より吐出されて送風径路（至）を介してチャン
バーＣ３１１に送風される。このように濾紙（１１を通
して空気をチャンバー（３Ｄ１吸引径路（２）、送風ポ
ンプ（至）、送風径路（至）と循環させつ＼送風径路（
至）のスプレーガンｃ３ｎから合成樹脂溶液をスプレー
して合成樹脂溶液の液滴（３）を該空気に混合する。か
くして第１図〜第３図に示すような機構で７紙（１）の
連続気孔（２）の壁面（２）Ａには合成樹脂層（５）が
形成される。In the above configuration, when the blower pump 4 is operated, the air in the chamber C311 flows into the supporter CD through the filter paper (11) supported by the supporter Qυ and is sucked into the blower pump (to) via the suction path c34. The air is sucked to the side, discharged from the ventilation side, and blown into the chamber C311 via the ventilation path (toward). In this way, the air is circulated through the filter paper (11) through the chamber (3D1 suction path (2), the blower pump (to), and the blower path (to)).
A synthetic resin solution is sprayed from the spray gun c3n (to) to mix droplets (3) of the synthetic resin solution into the air. Thus, a synthetic resin layer (5) is formed on the wall surface (2) A of the continuous pores (2) of the seven paper sheets (1) by the mechanism shown in FIGS. 1 to 3.
第１図〜第３図は合成樹脂層形成過程の説明図であり、
第１図は液滴付着状態、第２図は液膜形成状態、第３図
は合成樹脂層形成状態を示し、第４図は本発明に用いら
れる装置の一実施例の説明図、第５図は濾紙サポータ−
の斜視図、第６図は該サポータ−に濾紙を取付けた状態
の斜視図、第７図は濾紙を取付けたサポータ−に本発明
の処理を行なう場合の説明図である。Figures 1 to 3 are explanatory diagrams of the synthetic resin layer forming process,
FIG. 1 shows a droplet adhering state, FIG. 2 shows a liquid film forming state, FIG. 3 shows a synthetic resin layer forming state, FIG. 4 is an explanatory diagram of an embodiment of the apparatus used in the present invention, and FIG. The figure shows the filter paper supporter.
FIG. 6 is a perspective view of the supporter with filter paper attached thereto, and FIG. 7 is an explanatory diagram of the case where the process of the present invention is applied to the supporter with filter paper attached.
Claims (1)
た気体を送通し、該多孔体の連続気孔の壁面に該合成樹
脂溶液を塗布した後乾燥することによって該連続気孔の
孔径を縮小することを特徴とする多孔体の処理方法A gas mixed with mist of a synthetic resin solution is passed through a porous body having continuous pores, and the synthetic resin solution is applied to the walls of the continuous pores of the porous body and then dried to reduce the pore size of the continuous pores. A method for processing a porous body characterized by
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1099649A JPH0660261B2 (en) | 1989-04-18 | 1989-04-18 | Method for treating porous body and apparatus for treating porous body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1099649A JPH0660261B2 (en) | 1989-04-18 | 1989-04-18 | Method for treating porous body and apparatus for treating porous body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02276837A true JPH02276837A (en) | 1990-11-13 |
| JPH0660261B2 JPH0660261B2 (en) | 1994-08-10 |
Family
ID=14252905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1099649A Expired - Lifetime JPH0660261B2 (en) | 1989-04-18 | 1989-04-18 | Method for treating porous body and apparatus for treating porous body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0660261B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015168714A (en) * | 2014-03-05 | 2015-09-28 | 三菱瓦斯化学株式会社 | Resin structure, and prepreg, resin sheet, metal foil-clad laminate, and printed wiring board prepared using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61201078A (en) * | 1985-02-28 | 1986-09-05 | ダイキン工業株式会社 | New impregnated article |
-
1989
- 1989-04-18 JP JP1099649A patent/JPH0660261B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61201078A (en) * | 1985-02-28 | 1986-09-05 | ダイキン工業株式会社 | New impregnated article |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015168714A (en) * | 2014-03-05 | 2015-09-28 | 三菱瓦斯化学株式会社 | Resin structure, and prepreg, resin sheet, metal foil-clad laminate, and printed wiring board prepared using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0660261B2 (en) | 1994-08-10 |
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