JPH0227353A - Processing method and processing liquid for silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To decrease the staining of an unexposed part and bluing of an exposed part even if the processing by a final processing liquid is shortened by processing the photosensitive material contg. specific compds. by the final processing liquid which is specified in the concn. of a soluble iron salt. CONSTITUTION:The final processing of the photosensitive material contg. >=1 among the compds. expressed by formula I-IV is executed within 30 seconds by the processing liquid contg. >=5X10<-3>mol/l soluble iron salt. In formula, Rf, Rf1-Rf5 denote H, halogen, etc.; (t) denotes 1-3; M denotes action; Rf6, Rf'6 denote H, alkyl, etc.; Rf7, Rf'7 denote hydroxy, alkoxy, etc.; L denotes methine; (n) denotes 0-2; (m), m' denote 0, 1; r denotes 1-3; W denotes O, S; Rf31-Rf34 denote H, alkyl, etc.; l denotes 1, 2: Rf41 denotes an alkyl, aryl; Rf42-denotes a hydroxyl, alkyl, etc., Rf43 denotes 0OZ, etc.; Z denotes H, alkyl; Rf44 denotes H, alkyl, etc. The foaming in a stabilizing tank is suppressed as well according to this method.

Description

[Detailed description of the invention]

[Industrial Application Field] The present invention relates to a processing method and a processing solution for a silver halide color photographic light-sensitive material (hereinafter sometimes referred to as a light-sensitive material). The present invention also relates to a method for processing a photosensitive material that suppresses foaming in a stabilizing tank and enables rapid processing, and a final processing solution for the photosensitive material. [Background of the Invention] Generally, in order to obtain a color image by processing an imagewise exposed light-sensitive material, the generated metallic silver is desilvered after the color development step, and then washed with water, stabilized, or stabilized as an alternative to water washing. A processing step is provided. However, although photosensitive materials are processed on a running basis in automatic processing machines installed at each photo lab, as part of our efforts to improve our services to users, we have decided to process them and return them to users on the same day they are received. In recent years, it has become necessary to return items within a few hours of receiving them, and the development of rapid processing technology is becoming more and more urgent. As a result, the processing time, process, and temperature of the current major color paper photosensitive materials have reached the following levels. That is, for example, the development time for color photographic paper is 8.5 minutes,
The processing temperature is 33°C and the breakdown of processing time is color development 3.5
It consists of three steps: 1.5 minutes of bleach-fixing, and 3.5 minutes of washing.The system technology involved is U.S. Patent 3,582,
No. 322 and OLS 2,160.87
It is disclosed in No. 2, etc. More recently, a rapid color paper processing called Process RA-4 (development time is 3 minutes, processing temperature is 35°
Processing time breakdown for C is 45 seconds for 1 color development, 45 seconds for bleach fixing.
A method (consisting of three steps of 90 seconds and 90 seconds of stability) has also been proposed by Eastman Kodak Company. However, if the processing time is shortened in this way, the whiteness of the unexposed areas of the color paper deteriorates, making it substantially difficult to perform rapid processing. Therefore. In order to improve these problems, a method has been proposed in which a photosensitive material is treated with a stabilizer containing a hardening agent using a specific dye, as shown in JP-A-61-151538, but various studies have been conducted. It has been found that ultra-quick processing in which the stabilization bath is used for 30 seconds or less is not sufficiently effective, and furthermore, the surfactant eluted from the photosensitive material in the stabilization bath causes severe foaming that cannot be ignored. Furthermore, it was found that bluing failures are likely to occur in the exposed area under such conditions. [Object of the Invention] Therefore, the object of the present invention is to improve the whiteness of the color vapor unexposed area even in rapid processing, to prevent bluing from occurring in the exposed area, and to improve the foaming property in the stabilizing tank. The present invention provides a method for processing a photosensitive material and a final processing solution for the photosensitive material. [Structure of the Invention] The processing method of the present invention for achieving the above object is a processing method for a photosensitive material, in which the photosensitive material has the following general formula [AI-I
] to [AI-IV], the concentration of soluble iron salt in the final treatment solution is at least 5 x 10-' mol/state, and the treatment time of the final treatment solution is is within 30 seconds. Further, the processing solution of the present invention that achieves the above object is a final processing solution for processing a photosensitive material.
contains at least one of the compounds represented by the general formulas [AI-I] to [AI-TV], the treatment time of the final treatment liquid is 30 seconds or less, and characterized in that the concentration is at least 5 x 10-3 mol/cross. General formula [AI-: [] Substituted alkoxy group, cyano group, trifluoromethyl group,
-COORfa, -CONHRfa, -NHCORf
,, 7 Mi/group, W1-substituted amino substituted with an alkyl group having 1 to 4 carbon atoms [wherein, Rf, Rf+, Rft,
Rf3. Rf4 and Rf are hydrogen atom, halogen atom, hydroxy group, alkyl group, alkoxy group, -3O
, M group or -NF (represents CIItS03M group, t is 1
0M representing an integer of ~3 represents a cation. General formula [AI-II] (where p and q represent 1 or 2, X is an oxygen atom,
represents a sulfur atom or a -CH2- group; Rf represents a hydrogen atom, an alkyl group or an aryl group; L represents a methine group; n represents 0, 1 or 2; 11 and m' represent 0 or 1; or Rft, which represents a heterocyclic group;
Rfa' is a hydroxy group, an alkoxy group, [in the formula, "represents an integer of 1 to 3, W represents a # element atom and a sulfur atom, shi represents a methine group, Rfffi+~Rf+
i represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group, and at least one is a substituent other than a hydrogen atom. ] General formula [A I-TV
]

[In the formula, 1 represents an integer of 1 or 2, L represents a methine group, and Rf represents an alkyl group, an aryl group, or a heterocyclic group. Rf. is a hydroxy group, an alkyl group, an alkoxy group, a substituted alkoxy group, a cyano group, a trifluoromethyl group, -COORfa, -CONIIRfa, -
Nll(:ORf, amino group, substituted amino group substituted with an alkyl group having 1 to 4 carbon atoms, (where p and q represent 1 or 2, X is an oxygen atom,
Represents a cyclic amino group represented by ), which represents a sulfur atom or a -〇〇□- group. Rfa represents a hydrogen atom, an alkyl group, or an aryl group; Rf4:+ represents a Zl group or a Zl group;
3 represents a hydrogen atom or an alkyl group, and z2 and 23 may be the same or different, and bond to each other to form a ring. Rf44 represents a hydrogen atom, an alkyl group, a chlorine atom, or an alkoxy group. 1 In the present invention, the final treatment liquid means a treatment liquid for the final treatment step, and specifically includes a stabilizing liquid, a rinsing liquid, a cleaning liquid, etc. However, a stabilizing liquid is preferable. Next, the general formula [AI-I] to [Al
-1'V] will be described in detail. In [Al-1], Rf, Rf+, Rb,
Rh, Rf, and Rfs are hydrogen atoms; halogen atoms (e.g. chlorine atom, bromine atom, fluorine atom); hydroxy group; alkyl group, preferably an alkyl group having 1 to 4 carbon atoms (
methyl group, ethyl group, propyl group); alkoxy group (e.g. methoxy group, ethoxy group, propoxy group); -3
OJ ; or -NHCH2So, represents an M group. M is a cation, alkali metal atom (e.g. sodium atom, potassium atom); ammonium, organic ammonium a
! (For example, pyridium, piperidinium, triethylammonium, triethanolamine), etc. t represents an integer of 1 to 3. Representative specific examples of the compound represented by the general formula [AI-I] are shown below, but the present invention is not limited thereto. Below is the margin [Example Compounds! 100 NIICIl, SO, NH4 (+-7) HO0 H 1 (0O NH(CHt)ssOJa Ite in the general formula [Al-11], I'lf6.Rf,"
each represents a hydrogen atom, or an optionally substituted alkyl group, aryl group or heterocyclic group
Examples of the aryl group include 4-sulfophenyl group, 4-(sulfomethyl)phenyl group, 4-(δ-sulfobutyl)phenyl group, 3-sulfophenyl group, 2,5-disulfophenyl group, and 3.5-disulfophenyl group. phenyl group, 6,8-disulfo-2-naphthyl group, 4,8-disulfo-2-naphthyl group, 3.5-dicarboxyphenyl group, 4-dicarboxyphenyl group, etc., and this aryl group is a sulfo group, Sulfoalkyl group, carboxy group, alkyl group having 1 to 5 carbon atoms (e.g. methyl group, ethyl group, etc.), halogen atom (
For example, a chlorine atom, a bromine atom, etc.), an alkoxy group having 1 to 4 carbon atoms (for example, a methoxy group, an ethoxy group, etc.), or a phenoxy group. The sulfo group may be bonded to an aryl group via a divalent organic group, such as 4-(4-sulfophenoxy)phenyl group, 4-(2-sulfoethyl)phenyl group, 3-
Examples include (sulfomethylamino)phenyl group and 4-(2-sulfoethoxy)phenyl group. The alkyl groups represented by Rfi, , and Rfa' may be linear, branched, or cyclic, and preferably have 1 to 1 carbon atoms.
Examples of such groups include ethyl group and β-sulfoethyl group. Examples of the heterocyclic group include a 2-(6-sulfo)benzthiazolyl group, a 2-(6-sulfo)benzoxasilyl group, and a halogen atom (e.g., a fluorine atom, a chlorine atom, a bromine atom, etc.), Alkyl groups (e.g. methyl, ethyl, etc.), aryl groups (e.g. phenyl, etc.), carboxyl groups, sulfo groups, hydroxy groups, alkoxy groups (e.g. phenoxy, etc.), aryloxy groups (
For example, it may have a substituent such as a phenyl group. Rfa, Rf,' are each a hydroxy group; carbon number 1-
4 alkoxy group (e.g. methoxy group, ethoxy group, isopropoxy group, n-butyl group); substituted alkoxy group,
For example, an alkoxy group having 1 to 4 carbon atoms substituted with a halogen atom or an alkoxy group having up to 2 carbon atoms (e.g., β-chloroethoxy group, β-methoxyethoxy group); cyano group; trifluoromethyl group; -COORfs; C.O.
NHRfa; -NHCORfa (Rfa represents a hydrogen atom; an alkyl group, preferably an alkoxy group having 1 to 4 carbon atoms; or an aryl group, such as a phenyl group or a naphthyl group, and the alkyl group and aryl group have a sulfo group or ) which may have a carboxy group; amino group;
Substituted amino group substituted with an alkyl group having 1 to 4 carbon atoms (
For example, ethylamino group, dimethylamino group, diethylamino group, di-n-butylamino group); (where p and q represent an integer of 1 to 2, and X represents an oxygen atom, a sulfur atom or a -C1o2- group); , ) represents a cyclic amino group (for example, a morpholino group, a piperidino group, a piperazino group). The methine group represented by is an alkyl group having 1 to 4 carbon atoms (
For example, methyl group, ethyl group, isopropyl group, tert-butyl group, etc.) or aryl group (for example, phenyl group,
tolyl group, etc.). In addition, at least one of the sulfo group, sulfoalkyl group, and carboxy group of the compound is an alkali metal (e.g., sodium, potassium), alkaline earth metal (e.g., calcium, magnesium), ammonium, or an organic base (e.g., diethylamine group, triethylamine group, morpholine group, pyridine group, piperidine group, etc.), n represents 0.1 or 2, l and I' are 0
Or represents 1. Representative specific examples of the compound represented by the general formula [AI-II] are shown below, but the present invention is not limited thereto. [Exemplary Compounds] (II-1) (II-4) (H-2) onK 0IK (■-5) (■-3) (I[-6) 0ONa 0ONa So, N. OsNa (■ (■ (■ So, K (IT-13) o3K (■-14) NHClltSOJa (It-15) OJ o3K NHCHtSOsNa ([l-10) 03K ([[-11) (II-12) 0sNa ( ■ (II-17) (II-18) So, K SO, K 0Ja SO, (n-19) So, K (■ (■ SO, K (■ (■ (■-27) SO, lll+. SO , K So, K SO, NH. (II-22) (II-23) SO, K So, K (It-24) Q (II-28) (n-29) CIl, C1l, So, K Cl1. In the general formula [A I-m] for CIl, So, r represents an integer of 1 to 3, W represents an oxygen atom and a sulfur atom, L represents a methine group, and Rfsr to Rfin are each a hydrogen atom, It represents an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group, and at least one substituent is other than a hydrogen atom. Examples of the alkyl group represented by R "3.~nf:+<" include:
llf listed in the general formula [A I -IT] and R
The alkyl group may be the same as the alkyl group f, ``, and the alkyl group may have a substituent. Examples of the substituent include those introduced into the groups Rfa and Rf, `` in the general formula [Al1I]. Examples of the substituent include the various substituents listed above, but preferably a sulfo group, a carbonyl group, a hydroxy group, an alkoxy group, an alkoxycarbonyl group, a cyano group,
Each group is a sulfonyl group. The aryl group represented by Rh+ to Rfff is preferably a phenyl group, and the substituents introduced into this phenyl group include Rf6 and Rf6′ in the general formula [AI-II].
Although the various substituents mentioned above can be mentioned as substituents to be introduced into the group, it is desirable to have at least one group among a sulfo group, a carboxy group, and a sulfamoyl group on this aromatic ring. The aralkyl group represented by Rf3I to Rf, is preferably a benzyl group or a phenethyl group, and the substituents introduced therein may be the same as the substituents for the aryl group of Rf, to Rf34 described above. can. Examples of the heterocyclic group represented by Rf:ll'' Rf:14 include a pyridyl group and a pyrimidyl group, and substituents introduced onto this heterocycle include:
The above-mentioned Rf++ to Rf:1. The same substituents for the aryl group can be mentioned. The group represented by Rfi+ to Rfss is preferably an alkyl group or an aryl group, and furthermore, each group such as a carboxy group, a sulfo group, or a sulfamoyl group is present in the molecule of barbylic acid and thiobarbylic acid represented by the general formula [AI-m]. It is desirable to have at least one group, and a symmetric type is preferable. Next, typical examples of the compound represented by the general formula [AI-m] will be shown, but the present invention is not limited thereto. [Exemplary Compound] 5OtNII! So, Nll. zlls C, 11°C411s-n -1ts C, 11°C-1ton-n Cal! 5-n C4+1° General formula [In AI-IVI, the sentence represents an integer of 1 or 2, L represents a methine group, and Rf4□ represents the general formula [AI-
It has the same meaning as Rf and Rf6' in [II], and is preferably an alkyl group or an aryl group, and it is desirable that the aryl group has at least one sulfo group. Rf4. are Rf of the general formula [AI-II], and R
f, all of the substituents shown by = can be introduced, preferably an alkyl group, a carboxy group, an alkoxycarbonyl group,
It is selected from a carbamoyl group, a ureido group, an acylamino group, an imide group, and a cyano group. Z, , Z2 and Z3 represent a hydrogen atom and an alkyl group, respectively, and Z2 and 23 may be the same or different, or may be bonded to each other to form a ring. Examples of the alkyl group represented by zl, Z2, and z3 include methyl group, ethyl group, butyl group, hydroxyalkyl group (e.g., hydroxyethyl group, etc.), alkoxyalkyl group (e.g., β-ethoxyethyl group, etc.), and carboxyalkyl group. (e.g. β-carboxyethyl group, etc.), alkoxycarbonylalkyl group (e.g. β-ethoxycarbonylethyl group, etc.), cyanoalkyl group (e.g. β-diaminoethyl group, etc.), sulfoalkyl group (e.g. β-sulfoethyl group, γ- sulfopropyl group, etc.). Z2 and 23 may be combined with each other to form a 5- or 6-membered ring, and specific examples include a morpholino group, a piperidino group,
Examples include pyrrolidino group. Rf44 represents a hydrogen atom, an alkyl group, a chlorine atom, or an alkoxy group, and examples of the alkyl group include a methoxy group and an ethoxy group. Representative specific examples of the general formula [A I-IVI] are shown below, but the present invention is not limited thereto. [Exemplary Compound CO(II/-2) CHtSOJa 5OsNa SOaK SO,Na Above General Formula [AI-IF, [AI-'IICo, [AI
-m] or [AI-IV] are U.S. Patent No. 3,575,704, U.S. Pat.
．． Specifications of Nos. 510,887 and 3,653,905, JP-A-48-85130, JP-A-49-99620, JP-A-59-111640, JP-A-59-111641,
It can be synthesized by the synthesis method described in each publication of No. 59-170838. In addition, general formulas [AI-IF, [AI-II], [AI
-m] or [AI-IV] may be added directly to the stabilizing solution, or may be added to the pre-bath and allowed to adhere to the photosensitive material. Alternatively, it can be incorporated into the photosensitive material and brought into the stabilizing solution. When contained in a light-sensitive material, it may be contained in any layer of the silver halide emulsion layer or other hydrophilic colloid layer, by dissolving the organic/inorganic alkali salt of the above-mentioned compound of the present invention in water, An aqueous dye solution having an appropriate concentration can be prepared, added to a coating solution, and coated by a known method to be incorporated into a photographic material. The content of these compounds of the present invention is 1 to 800 mg/m' of the surface of the photosensitive material, preferably 2 to 200 mg/rn'. When added to the stabilizing solution, the amount added is o per sentence.
, oos~200+ag is preferable, especially 0.01~5
0+*g is preferred. Among the compounds represented by the above general formulas [AI-I] to [AI-IV], the compound represented by the general formula [AI-II] is more preferable, and two or more of these compounds are used in combination. It's okay to do that. When the compounds represented by the general formulas [AI-I:] to [AI-TV] of the present invention are incorporated into a photosensitive material and eluted into a stabilizing solution, the elution concentration is determined by the photographic sensitization of the stabilizing solution. Of course, it is determined by the amount of replenishment per unit area of the material, but it is also related to the pretreatment before the stabilization treatment, that is, the treatment time and temperature of the color developing solution and bleach-fixing solution. Further, as for the replenishment amount of the processing solution during the In subsequent processing, it is preferable that the replenishment amount for each set of color development step and bleach-fixing step before stabilization treatment is less than If1 per 1 m'' of light-sensitive material, and more preferably 600- The amount of replenishment of the stabilizing solution, which is preferably under stationery, is preferably 2 sentences or less per rn' of photosensitive material, more preferably 1 fL or less, and most preferably 500 cJL or less.In the present invention The stabilizing solution preferably contains a sulfite, and the sulfite may be any organic or inorganic substance as long as it releases sulfite ions, but it is preferably an inorganic salt, and specific preferred compounds may be used. Examples include sodium sulfite, potassium sulfite, ammonium sulfite, ammonium bisulfite, potassium bisulfite, sodium bisulfite, sodium metabisulfite, potassium metabisulfite, ammonium metabisulfite, and hydrosulfide. at least l x 10-' in
It is preferable to add the amount in mole/state,
More preferably, it is added in an amount such that s x to-' mol/l to 10-' mol/l. Although it may be added directly to the stabilizing solution, it is preferable to add it to the stable replenisher. In the present invention, the number of stabilizing tanks may be 2 to 4, but preferably one. Particularly desirable compounds to add to the stabilizer used in the present invention include ammonium compounds. These are supplied by ammonium mounds of various inorganic compounds, specifically ammonium hydroxide, ammonium bromide, ammonium carbonate, ammonium chloride, ammonium hypophosphite, ammonium phosphate, ammonium phosphite, Ammonium fluoride, acidic ammonium fluoride, ammonium fluoroborate, ammonium arsenate, ammonium hydrogen carbonate, ammonium hydrogen fluoride, ammonium hydrogen sulfate, ammonium sulfate, ammonium iodide, ammonium nitrate, ammonium pentaborate, ammonium butyrate, ammonium adipate, Ammonium lauric tricarboxylate, ammonium benzoate, ammonium carbamate, ammonium citric acid, ammonium diethyldithiocarbamate, ammonium formate, ammonium hydrogen malate, ammonium hydrogen oxalate, ammonium phthalate, ammonium hydrogen tartrate, ammonium thiosulfate, ammonium sulfite, ethylenediamine Ammonium tetraacetate, ferric ammonium ethylenediaminetetraacetate, ammonium lactate, ammonium malate, ammonium oxalate, ammonium phthalate, ammonium picrate, ammonium pyrrolidine dithiocarbamate, ammonium salicylate, ammonium succinate, sulfanyl Ammonium acid, ammonium tartrate. These include ammonium thioglycolate, 2,4.6-dolinitrophenolammonium, and the like. These may be for military use or may be used in combination of two or more. The amount of ammonium compound added is 0.0 per stabilizer solution IIL.
01 mole to 1.0 mole, preferably 0.0 mole
The range is 0.02 to 2.0 moles. In the present invention, the pl+ of the stabilizer is preferably in the range of 3.0 to 9.5, and further preferably adjusted to pn: 1.5 to 9.0 in order to obtain the desired effect of the present invention. Furthermore, in the present invention, the stabilizing solution has a chemical resistance against iron ions.
- It is preferred for the purposes of the invention to contain a chelating agent with a stability constant of 8 or more. Here, the chelate stability constants are: L, G, 5ille
n.A.E., Martel, “5t
ability Con5tants of M
e-tal-jon Complexes, Th
e (:chemical 5ociety. London (1964), Chabere, S.
K-A, E., Martel+, “Organic S
equestering Agents, Wi! e
y (1959) etc. means a constant generally known. Examples of chelating agents having a chelate stability constant of 8 or more for iron ions that are preferably used in the stabilizing solution include organic carboxylic acid chelating agents, organic acid chelating agents, inorganic phosphoric acid chelating agents, and phosphoroxy compounds. It will be done. Note that the above-mentioned iron ion means ferric ion (Fe3+). Specific examples of compounds of chelating agents having a chelate stability constant of 8 or more with ferric ions include, but are not limited to, the following compounds: ethylenediamine diorthohydroxyphenylacetic acid, Diaminopropanetetraacetic acid, nitrilotriacetic acid, hydroxyethylenediaminetriacetic acid, dihydroxyethylglycine, ethylenediaminediacetic acid, ethylenediaminenipropionic acid, iminodiacetic acid, diethylenetriaminepentaacetic acid, hydroxyethyliminodiacetic acid, diaminopropanoltetraacetic acid, transcyclohexane Diaminetetraacetic acid, glycol ether diaminetetraacetic acid, ethylenediaminetetrakismethylenephosphonic acid, nitrilotrimethylenephosphonic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, 1,1-diphosphonoethane-2-carboxylic acid, 2-phosphonobutane- 1,2,4-tricarboxylic acid, 1-hydroxy-1-phosphonopropane-1,2,:l-tricarboxylic acid, catechol-3,5-diphosphonic acid, sodium pyrophosphate, sodium tetrapolyphosphate, sodium hexametaphosphate Among them, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, nitrilotrimethylenephosphonic acid, and 1-hydroxyethylidene-1 are particularly preferred.
, 1-diphosphonic acid, etc., among which 1-hydroxyethylidene-1,1-diphosphonic acid is most preferably used. The amount of the above chelating agent used is 0.01 to 0.01 per liter of stabilizer.
Good results are obtained with an amount of 50 g, preferably between 0.05 and 20 g. Other commonly known compounds that can be added to the stabilizer include polyvinylpyrrolidone (pvpK-15, Ni-:!0.ni-90), organic acid salts (citric acid, acetic acid, succinic acid, oxalic acid, benzoic acid, etc.), PL+ regulators (phosphates, borates, hydrochloric acid, sulfuric acid, etc.), fungicides (phenol derivatives, catechol derivatives, imidazole derivatives, triazole derivatives, thiabendazole derivatives,
clearing agent halogen compounds, other fungicides known as paper-bulp industry slime control agents), optical brighteners, surfactants, preservatives, +li, Mg,
There are metal salts such as Zn, Ni, AJL, Sn, Ti, lr, etc., and these compounds are necessary to maintain the pH of the stabilizing bath according to the present invention, and also to improve the stability of color photographic images during storage and the prevention of precipitation. To the extent that it does not have a negative impact on the outbreak,
Any compound may be used in any combination. The treatment temperature during the stabilization treatment is preferably in the range of 15°C to 60°C, preferably 20°C to 45°C, and the treatment time is essential in the present invention to be 30 seconds or less, but preferably 30 seconds or less. seconds to 25 seconds, more preferably 4 seconds to 20 seconds
seconds, most preferably 6 seconds to 15 seconds. After the stabilization treatment according to the present invention, there is no need for any water washing treatment, but rinsing with a small amount of water within an extremely short period of time, surface cleaning, etc. can be optionally performed as necessary. Soluble iron salts according to the present invention include inorganic iron salts such as ferric chloride, ferrous chloride, ferric phosphate, ferric bromide, ferric nitrate, and ferrous nitrate; ferric salts, ferric 1-hydroxyethylidene-1,1-diphosphonate, ferrous l-hydroxyethylidene-1,1-diphosphonate, ferrous ethylenediaminetetraacetate, ferric diethylenetriaminepentaacetate, diethylenetriaminepentaacetate vinegar#
ferrous salts, ferric citrate, ferrous citrate, ferric ethylenediaminetetramethylenephosphonate, ferrous ethylenediaminetetramethylenephosphonate, ferric nitrilotrimethylenephosphonate, ferric nitrilotriacetate,
Examples include organic acid iron salts such as ferrous nitrilotriacetate. These organic acid iron salts may be of free acid type, sodium salt, potassium salt, ammonium salt, lithium salt, or alkylammonium salt (triethanolammonium salt, trimethylammonium salt, tetramethylammonium salt, etc.). In the present invention, organic acid iron salts are more preferred as soluble iron salts. These soluble iron salts should be present in the stabilizing solution at least 5 x 10-'
A concentration of mol/l is used, preferably in the range from 8 x IO to 150 x 10 mol/l, more preferably in the range from 12 x 10 to 100 x 10' mol/l. In addition, these soluble iron salts according to the present invention may be added to the stabilizing solution (tank solution) by adding them to the stabilizing solution replenisher, or they may be eluted from the photosensitive material in the stabilizing solution (stabilizing solution). It may be added to the stabilizing solution (tank solution), or it may be added to the stabilizing solution (tank solution) by roughly adhering it to the photosensitive material to be processed from the pre-bath. In order to efficiently achieve the object of the present invention, it is particularly preferable to use a magenta coupler represented by the following general formula [M-I] in the photosensitive material to be processed. General formula [M-I] In the formula, Z represents a nonmetallic atom group necessary to form a nitrogen-containing heterocycle, the ring formed by Z may have a substituent, and X is a hydrogen atom. or represents a group that can be separated by reaction with an oxidized product of a color developing agent, and R represents a hydrogen atom or a substituent. There are no particular restrictions on the substituents represented, but typical examples include alkyl, aryl, anilino, acylamino, sulfonamide, alkylthio, arylthio, alkenyl, and cycloalkyl, but in addition, halogen Atoms and cycloalkenyl, alkynyl, heterocycle, sulfonyl, sulfinyl, phosphonyl, acyl, carbamoyl, sulfamoyl, cyano, alkoxy, aryloxy, heterocycleoxy, siloxy, acyloxy, carbamoyloxy, amino, alkylamino, imide, ureido, sulfonyl Also included are famoylamino, alkoxycarbonylamino, aryloxycarbonylamino, alkoxycarbonyl, aryloxycarbonyl, and heterocyclic thio groups, as well as spiro compound residues, bridged hydrocarbon compound residues, and the like. The alkyl group represented by R preferably has 1 to 32 carbon atoms, and may be linear or branched. The aryl group represented by R is preferably a phenyl group. Examples of the acylamino group represented by R include an alkylcarbonylamino group and an arylcarbonylamino group. Examples of the sulfonamide group represented by R include an alkylsulfonylamino group and an arylsulfonylamino group. Examples of the alkyl component and aryl component in the alkylthio group and arylthio group represented by R include the alkyl group and aryl group represented by R above. The alkenyl group represented by R preferably has 2 to 32 carbon atoms, and the cycloalkyl group preferably has 3 to 2 carbon atoms, particularly 5 to 7 carbon atoms, and the alkenyl group may be linear or branched. The cycloalkenyl group represented by R has 3 to 3 carbon atoms.
12, especially those of 5 to 7 are preferred. Examples of the sulfonyl group represented by R include an alkylsulfonyl group and an arylsulfonyl group; examples of the sulfinyl group include an alkylsulfinyl group and an arylsulfinyl group; examples of the phosphonyl group include an alkylphosphonyl group. Alkoxyphosphonyl group, aryloxyphosphonyl group, arylphosphonyl group, etc.; Acyl group includes alkylcarbonyl group, arylcarbonyl group, etc.; carbamoyl group includes alkylcarbamoyl group, arylcarbamoyl group, etc.; sulfamoyl group includes alkylsulfa group; moyl group,
Niacyloxy groups such as arylsulfamoyl groups include alkylcarbonyloxy groups, arylcarbonyloxy groups, etc.; carbamoyloxy groups include alkylcarbamoyloxy groups, arylcarbamoyloxy groups, etc.; ureido groups include alkylureido groups, arylureido groups, etc. ; Examples of the sulfamoylamino group include an alkylsulfamoylamino group and an arylsulfamoylamino group; Preferably the heterocyclic group is a 5- to 7-membered group, specifically a 2-furyl group and a 2-thienyl group. , 2-pyrimidinyl group, 2-benzothiazolyl group, etc.: The heterocyclic oxy group preferably has a 5- to 7-membered heterocycle, for example, 3,
4,5.6-tetrahydrobilanyl-2-oxy group, 1
-Phenyltetrazole-5-oxy group, etc.; The heterocyclic thio group is preferably a 5- to 7-membered heterocyclic thio group, such as 2-pyridylthio group, 2-benzothiazolylthio group, 2.4-diphenoxy-1 , 3,5-triazole-6 monothio group, etc.; Siloxy groups include trimethylsiloxy group, triethylsiloxy group, dimethylbutylsiloxy group, etc.; Imide groups include succinimide group, 3-heptadecylsuccinimide group, phthalimide group. group, glutarimide group, etc.; spiro compound residues include spiro[:1.3]heptan-1-yl; bridged hydrocarbon compound residues include bicyclo[2,2,1
1 hebutan-1-yl, tricyclo[3,3°1.11
- 71-decane-1-yl, 7,7-dimethyl-bicyclo[2,2,11-hebutan-1-yl, etc. are mentioned. Examples of groups that can be released by reaction with the oxidized product of the color developing agent represented by , alkoxycarbonyloxy, aryloxycarbonyl, alkyloxalyloxy, alkoxyoxalyloxy, alkylthio, arylthio, heterocyclicthio, alkyloxycarbonylthio, acylamino, sulfonamide, nitrogen-containing heterocycle bonded by N atom, alkyloxy carbonylthiamino, aryloxycarbonylamino, carboxyl, (R8' is the same as the above R, Z' is the same as the above Z, R2' and R3' are a hydrogen atom, an aryl group, an alkyl group, or a heterocyclic group) ) and the like, but preferably a halogen atom, particularly a chlorine atom. Examples of the nitrogen-containing heterocycle formed by 2 or 2' include a pyrazole ring, an imidazole ring, a triazole ring, or a tetrazole ring, and examples of the substituents that the ring may have include those described for R above. can be mentioned. More specifically, what is represented by the general formula [M-I] is represented by, for example, the following general formulas [M-II] to [M-■]. In the following margins, the general formula [M-II] to the general formula [M-■], R1-R6 and X. have the same meaning as the above R. Also, preferred among the general formulas [M-1] are those represented by the following general formula [M-VIA]. General formula [M-W] In the formula, R3, X and Zl have the same meanings as R, X and Z in general formula [M-I]. Among the magenta couplers represented by the general formula [M-II eco general formula [M-■], particularly preferred ones are those represented by the general formula [M-■].
M-H] is a magenta coupler. The ring formed by 2 in general formula [M-1] and the substituent that the ring formed by Z8 in general formula [M-Vll may have, and the general formula [M-Tl] to general formula [M -V! The general formula [M
-V:, ] is preferable. General formula [M-IX] -I'l' -SO□-R2 In the formula, R1 represents an alkylene group, and R2 represents an alkyl group, a cycloalkyl group, or an aryl group. The alkylene group represented by R' preferably has 2 or more carbon atoms in the straight chain portion, more preferably 3 to 6 carbon atoms, and it does not matter whether it is straight chain or branched. The alkyl group represented by R2 is preferably a 5- to 6-membered one. In addition, when used for positive image formation, the substituent R on the heterocycle
and R, most preferably the following general formula [M-X
It is represented by l. General formula [M-Xl R,, -C- In the formula, R9, RIG and R11 each have the same meaning as R above. Moreover, two of the above R9+R1° and R11, for example, R
9 and RIO may be bonded to form a saturated or unsaturated ring (e.g., cycloalkane, cycloalkene, heterocycle), and R11 may be bonded to the chain ring to form a bridged hydrocarbon compound residue. You can. Preferred specific examples of the above magenta couplers include compounds 1 to 77 described on pages 15 to 31 of Japanese Patent Application No. 62-220060. The amount of the magenta coupler used in the present invention is generally from 0.05 to 1 mole of silver in the photosensitive silver halide emulsion layer.
It is 2.0 mol. In the present invention, in addition to the above magenta coupler, each 1 JDI
R compounds, yellow couplers, cyan couplers, etc. are preferably used. The photosensitive material used in the present invention may contain various other photographic additives. For example, antifoggants, stabilizers, ultraviolet absorbers, and color stain prevention agents described in Research Disclosure No. 17643. agents, optical brighteners, color image fading inhibitors, antistatic agents, hardeners, surfactants, plasticizers. Wetting agents and the like can be used. In the light-sensitive material used in the present invention, the hydrophilic colloid used to prepare the emulsion is preferably gelatin, and other examples include derivative gelatin, graft polymers of gelatin and other polymers, and proteins such as albumin and casein. , cellulose derivatives such as hydroxyethyl cellulose derivatives and carboxymethyl cellulose, starch derivatives, single or copolymer synthetic hydrophilic polymers such as polyvinyl alcohol, polyvinylimidazole, and polyacrylamide. Supports for the photosensitive material used in the present invention include baryta paper, polyethylene-coated paper, polypropylene synthetic paper, transparent supports with a reflective layer, such as glass plates, polyester films such as cellulose acetate, cellulose nitrate, and polyethylene terephthalate. , a polyamide film, a polycarbonate film, a polystyrene film, etc., and may also be an ordinary transparent support, and these supports are appropriately selected depending on the intended use of the photosensitive material. Coating of the silver halide emulsion layer and other photographic constituent layers used in the present invention includes dipping coating, air doctor coating, and curtain coating. Various coating methods can be used, such as hopper coating. Also, U.S. Patent Nos. 2,751,791 and 2,941.
It is also possible to use a simultaneous coating method of two or more layers by the method described in No. 898. In the present invention, the coating position of each emulsion layer can be determined arbitrarily. For example, in the case of a full-color photosensitive material for photographic paper, the blue-sensitive silver halide emulsion layer,
It is preferable to arrange a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer. Each of these photosensitive silver halide emulsion layers may consist of two or more layers. In the photosensitive material of the present invention, it is optional to provide an intermediate layer with an appropriate thickness depending on the purpose, and a filter layer,
Contains various layers such as an anti-curl layer, a protective layer, and an anti-halation layer! & can be used in appropriate combination as a layer. Hydrophilic colloids that can be used in the emulsion layer as described above can be used as a binder in these constituent layers, and can also be contained in the emulsion layer as described above. Various photographic additives can be included. In the method for processing a photosensitive material of the present invention, if the photosensitive material contains a coupler in the photosensitive material and is processed by the so-called internal development method, color vapor, color negative film, color positive film, and slide color can be used. It can be applied to any photosensitive material such as reversal film, color reversal film for movies, color reversal film for TV, and reversal color vapor. [Effects of the Invention] According to the present invention, even in rapid processing, the whiteness of the color vapor unexposed area is good, no bluing occurs in the exposed area, and the foaming property in the stabilizing tank is improved. A material processing method and a final processing solution for the photosensitive material are provided. [Example] Hereinafter, the present invention will be explained in more detail with reference to Examples.
However, the embodiments of the present invention are not limited to these. Example 1 A photosensitive material was prepared by sequentially coating the following layers on a polyethylene coated paper support from the support side. Note that polyethylene coated paper has an average molecular weight of 10
6.5% by weight of anatase titanium oxide was added to a mixture of 200 parts by weight of polyethylene with an average molecular weight of 0,000 and a density of 0.95 and 20 fJ m parts of polyethylene with an average molecular weight of 2,000 and a density of 0.80, and extrusion coating was performed. The surface of high-quality paper with a weight of 165 g/rn' was coated with a thickness of 0.
A coating layer having a thickness of 0.035+*m was formed, and a coating layer with a thickness of 0.040 mm was provided on the back surface only by polyethylene. The polyethylene-coated surface of this support was pretreated by corona discharge, and then the following layers were sequentially applied. First layer: A blue-sensitive silver halide emulsion layer consisting of a silver chlorobromide emulsion containing 0.5 mol % of silver bromide. The emulsion contains 340 g of gelatin per mol of silver halide, and the following per mol of silver halide The sensitizing dye [m] was sensitized using 2.4X 10-4 mole (using isopropyl alcohol as the solvent) and dissolved and dispersed in dibutyl phthalate.
Contains 200 mg/m' of di-butylhydroquinone and 2.1 x 10-' moles of [Y-1] of the following structure as a yellow coupler per mole of silver halide, silver amount 2
It is coated at a concentration of 90 mg/m'. 2nd layer: 290 g/g of di-tert-octylhydroquinone dissolved and dispersed in dibutyl phthalate, 2-(2'-hydroxy-3",5"-di-butylphenyl)benzo as a UV absorber; Triazole, 2-(2''-hydroxy-5'-t-butylphenyl)benzotriazole, 2-(2'-hydroxy-3'-t-butyl-5'
-methylphenyl)-5-chloroupenzotriazole and 2-(2'-hydroxy-3'',5'-di-t-
butylphenyl)-5-chloro-benzotriazole mixture (1:1:1:l) 200mg/
Gelatin 2000ag/r in gelatin layer containing m'
It is coated to be RF. Third layer: A green-sensitive silver halide emulsion layer consisting of a silver chlorobromide emulsion containing 0.4 mol% of silver bromide. The emulsion contains 460 g of gelatin per mol of silver halide, and the following per mol of silver halide: Structure of sensitizing dye [I] 2. [M-1] with the following structure as 2,5-di-t-butyl octatroquinone and magenta coupler sensitized using 10-' mole of Sx and dissolved in a solvent consisting of 2 parts of dibutyl phthalate and tricresyl phosphate. per mole of silver halide 1.
It contains 5×10-' moles and is coated to give a silver content of 240 B/rn'. In addition, as an antioxidant, 2,
2.4-)-dumethyl-6-lauryloxy-7-t-
0.30 mol of octylchroman was added per mol of coupler. 4th layer: 30 mg/m' of di-t-octylhydroquinone dissolved and dispersed in didioctyl phthalate and 2-(2'-hydroxy-3',5'-di-t-butylphenyl)benzotriazole as an ultraviolet absorber. , 2-(2'-hydroxyl 5'-t-butylphenyl)benzotriazole, 2-(2'-hydroxyl-3'-t-butyl-5'
A mixture of (2:1.5:1 .5: 2) 500
The gelatin layer contains 1900 mg/rn' of gelatin. Fifth layer: A red-sensitive silver halide emulsion layer consisting of a silver chlorobromide emulsion containing 0.4 mol % of silver bromide, the emulsion containing 500 g of gelatin per mol of silver halide; 150 g of 2,5-di-butylhydroquinone sensitized using 2.5 x 10-' mol of sensitizing dye [IT] having the following structure and dissolved and dispersed in dibutyl phthalate.
/rn' and a cyan coupler with the following structure [C-1
] per mole of silver halide, and was coated to give a silver amount of 29 hg/m'. Sixth layer: This is a gelatin layer, and gelatin is coated at a concentration of 1000 mg/rn'. The silver halide emulsions used in each light-sensitive emulsion layer (layers 1, 3, and 5) were prepared by the method described in Japanese Patent Publication No. 7772/1983, and were prepared using sodium thiosulfate pentahydrate. Chemically sensitized and stabilized with 4-hydroxy-6-
Methyl-1,3,3a,7-titrazaindene (2.5 g per mole of silver halide), bis(vinylsulfonylmethyl)ether (1 g per 1 g of gelatin) as a hardening agent.
0 mg) and saponin as a coating aid. In addition, the second layer contains the exemplified compound general formula [Al
-1] to [Al-ff co and the following comparative compounds [Al-1
], [Al-21 was added at 15 B/rn'. Sensitizing dye [L] Sensitizing dye [II] Sensitizing color* [IIT-[Y-1] [Al-1] [M-1] [Al-2-C(2 [C-1] CCHtj"' r 5OJa After exposing the color vapor produced by the above method, processing was performed using the following processing steps and processing solution. Processing steps (1 tank each) (1) Color development 38°C 20 seconds (2
) Bleach fixing at 35°C for 20 seconds (3) Stable at 35°C Listed in Table 1 (4)
Drying 60℃~80℃ 30 seconds [Color development tank solution] Benzyl alcohol 2g diethylene glycol 10g potassium bromide
0.01g potassium chloride
2.3 g potassium sulfite (50% solution) 0.5 m color developing agent (3-methyl-4-amino-N-ethyl-N-(β-methanesulfonamidoethyl)-aniline sulfate 5.0 g diethylhydroxylamine (85%) 5.0g triethanolamine 10.0g potassium carbonate
30g Ethylenediaminetetraacetic acid sodium salt 2.0g Fluorescent brightener (PK manufactured by Nippon Soda Co., Ltd.)
-Cone) 2. (Add 1g of water to make one sentence,
Adjusted to pl 10.15 with potassium hydroxide or sulfuric acid. [Color developer replenisher] Benzyl alcohol diethylene glycol Potassium chloride Potassium sulfite (50% solution) Color developer (3-methyl-4-amino-N-ethyl-
N-(β-methanesulfonamidoethyl)-aniline sulfate 8.0g diethylhydroxylamine (85%)
7.0g triethanolamine 1
0.0g potassium carbonate 30g
Ethylenediaminetetraacetic acid Lithium acetate j;l 2.0g
Fluorescent brightener (PK-(:one) manufactured by Nippon Soda Co., Ltd.) 2.
Add 5g water and 1! 1 and adjusted to 91110.40 with potassium hydroxide or sulfuric acid. g 0g 3.0g 1.5 pyogenes [Bleach-fix tank solution and replenisher] Diethylenetriaminepentaacetic acid ferric ammonium salt 65.0g Diethylenetriamiminoacetic acid 3.0g Ammonium thiosulfate (70% solution) 100.0*MS-Amino 1,3.4-thiadiazole-2-thiol
0.5g ammonium sulfite (40
% solution) 27.5m and adjust to 16.50 with ammonia water or glacial acetic acid, and add water to bring the total volume to 1.
Set to 1. [Stable tank fluid and replenisher] Ortho-phenylphenol 1.0 g 5-chloro-2-methyl-4-inthiazolin-3-one 2-methyl-4-isothiazolin-3-one ethylene glycol tinovar 5FP (manufactured by Ciba Geigy) 0.02g 0.02g], Og 2g l-hydroxyethylidene-1,1-diphosphonic acid (60% aqueous solution) 3.0g BiC, (45% aqueous solution) MgSO4・711.0 0.65g 0.2g PVP ( Polyvinylpyrrolidone) 1.0g
Soluble iron salts (listed in Table 1) Listed in Table 1 Ammonia water (ammonium hydroxide 25% aqueous solution) 2.5g Nitrilotriacetic acid trisodium salt 1.5g Make up to 1 sentence with water, and adjust to pH 7.5 with ammonia water and sulfuric acid. For each color vapor sample after treatment, the spectral reflection density at 420 nm of the white unexposed area was measured using a photodensitometer. Furthermore, bluing in the exposed area was visually observed. The results are shown in Table 1. In the table, IIEDP4e is l-hydroxyethylidene-1
, 1-diphosphonate, EDTA4e is ferric ammonium ethylenediaminetetraacetate, DTPA-Fe is ferric ammonium diethylenetriaminepentaacetate, Gi
t-Fe is ferric ammonium citrate, NT^Fe
means ferric ammonium nitriloacetate. Furthermore, in Table 5, the mark ○ means that no bluing is observed, the mark Δ means that some occurrence of bluing is observed, and the mark X means that bluing is observed to the extent that it reduces the product value. Furthermore, the more x marks there are, the more significant the degree of damage is. From Table 1, it can be seen that when the soluble iron salt of the present invention is used at a specific concentration in the stabilizing solution and the processing time is within 30 seconds, the general formulas [A I -I ] to [Al-1'V ] When using the compound represented by the formula, even during rapid processing for the first time, staining in unexposed areas is good, whiteness is good, and bluing in exposed areas is also good. It can be seen that if even one of these conditions is absent, none of these effects can be obtained. Example 2 A running process was performed using the color vapor prepared in Example 1 and Percentage 1. In the running process, the automatic processor is filled with the above color developing tank liquid, as well as the bleach-fixing tank liquid and the stabilizing tank liquid, and the above color developing replenisher is added every 3 minutes while processing the color vapor sample. The bleach-fix replenisher and stable replenisher were replenished through a metering pump. The amount of replenishment to the color development tank is 1m of color vapor.
'Win! , 80 mu, the amount of replenishment to the bleach-fixing tank is 2201 mJ of bleach-fixing replenisher per 1 m'', and the amount of replenishing to the stabilizing tank is 2511 mJ of stable replenisher per lrn'.
1 replenished. However, the stabilizing solution used was that of Example 1, Experiment No. 1-1, and the stabilizing tank treatment time was as shown in Table 2: <10 seconds, 20 seconds,
30 seconds, 40 seconds and 60 seconds were used, respectively. Furthermore, the AI dyes (anti-irradiation dyes) in the photosensitive material were those listed in Table 2, and the other conditions were the same as in Example 1. The running process was carried out continuously until the amount of stable replenisher liquid replenished into the stable tank liquid became three times the volume of the stable tank liquid. The soluble iron salt concentration in the stable tank liquid at the end of the running process was 22×10 −3 mol/state. At the end of the running process, the stain (420 nm) of the unexposed area of the treated color vapor was measured, and the bluing of the exposed area and the foaming properties of the stabilizer were observed. The results are summarized in Table 2. The descriptions in the table correspond to Table 1 of Example 1. Further, in the foaming property, - means that foaming is hardly observed, and + means that foaming is slightly observed. Furthermore, the higher the number, the more significant the degree. From Table 2, it can be seen that when using the AI dye according to the present invention within 30 seconds of processing time of the stabilizer, all of the unexposed area staining, exposed area bluing, and stabilizer foaming properties are good. Karu. Example 3 The magenta couplers used in Example 1 were as follows M-2 to M
The experiment of Example 1 was carried out by replacing each sample with -11 and keeping the others the same. As a result, the stain density (+2
0 ns) was improved by 20-30%. [M-2] [M-3] [M-4] [M-5] [M-61 [M-71 [M-81 ll 5 Csll+, (t) [M-9] [M-10] [ M-11]

Claims (1)

[Scope of Claims] 1. In a method for processing a silver halide color photographic light-sensitive material, the silver halide color photographic light-sensitive material is a compound represented by the following general formulas [A I-I] to [A I-IV]. containing at least one, the concentration of the soluble iron salt in the final treatment liquid is at least 5 x 10^-^3 mol/l, and the treatment time of the final treatment liquid is within 30 seconds. A method for processing silver halide color photographic materials. General formula [A I - I] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [In the formula, Rf, Rf_1, Rf_2, Rf_3, Rf_
4 and Rf_5 are hydrogen atoms, halogen atoms, hydroxy groups, alkyl groups, alkoxy groups, -SO_3M groups, or -
Represents NHCH_2SO_3M group. t represents an integer of 1 to 3. M represents a cation. General formula [AI-II] ▲ Numerical formulas, chemical formulas, tables, etc.
, Rf_7′ are a hydroxy group, an alkoxy group,
Substituted alkoxy group, cyano group, trifluoromethyl group, -
COORf_6, -CONHRf_6, -NHCORf
_6 amino group, substituted amino group substituted with an alkyl group having 1 to 4 carbon atoms, or ▲mathematical formula, chemical formula, table, etc.▼ (where p and q represent 1 or 2, X is an oxygen atom,
Represents a sulfur atom or -CH_2- group. ) represents a cyclic amino group. Rf_6 represents a hydrogen atom, an alkyl group, or an aryl group. L represents a methine group. n is 0, 1
Or represents 2. m and m' represent 0 or 1. ] General formula [A I-III] ▲Mathematical formulas, chemical formulas, tables, etc.▼ [In the formula, r represents an integer from 1 to 3, W represents an oxygen atom and a sulfur atom, L represents a methine group, Rf_3_1~R
f_3_4 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group, and at least one
One or more are substituents other than hydrogen atoms. ] General formula [A
I-IV] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [In the formula, l represents an integer of 1 or 2, L represents a methine group, and Rf_4_1 represents an alkyl group, an aryl group, or a heterocyclic group. Rf_4_2 is a hydroxy group, an alkyl group, an alkoxy group, a substituted alkoxy group, a cyano group, a trifluoromethyl group, -COORf_8, -CONHRf_8
, -NHCORf_8, amino group, substituted amino group substituted with an alkyl group having 1 to 4 carbon atoms. Or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (Here, p and q represent 1 or 2, X is an oxygen atom,
Represents a sulfur atom or -CH_2- group. ) represents a cyclic amino group. Rf_8 represents a hydrogen atom, an alkyl group, or an aryl group. Rf_4_3 represents -OZ_1 group and Rf_4_3 represents -OZ_1 group or ▲mathematical formula, chemical formula, table, etc.▼ group, Z_1, Z_2 and Z_3 represent a hydrogen atom or an alkyl group, and Z_2 and Z_3 may be the same or different. , can also be combined with each other to form a ring. Rf_4_4 represents a hydrogen atom, an alkyl group, a chlorine atom, or an alkoxy group. ] 2. In the final processing solution for processing the silver halide color photographic light-sensitive material, the silver halide color photographic light-sensitive material contains at least one of the compounds represented by the general formulas [A I-I] to [A I-IV]. The treatment time of the final treatment liquid is within 30 seconds, and the concentration of soluble iron salt in the final treatment liquid is at least 5 x 10^-^3 mol/l. Final processing solution for silver halide color photographic materials.