JPH02263737A - Crystallized glass coated with ceramic by thermal spraying - Google Patents
Crystallized glass coated with ceramic by thermal sprayingInfo
- Publication number
- JPH02263737A JPH02263737A JP8269489A JP8269489A JPH02263737A JP H02263737 A JPH02263737 A JP H02263737A JP 8269489 A JP8269489 A JP 8269489A JP 8269489 A JP8269489 A JP 8269489A JP H02263737 A JPH02263737 A JP H02263737A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- ceramic
- sio2
- crystallized glass
- al2o3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 36
- 239000000919 ceramic Substances 0.000 title claims abstract description 17
- 238000007751 thermal spraying Methods 0.000 title claims description 15
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000011247 coating layer Substances 0.000 claims abstract description 18
- 239000007921 spray Substances 0.000 claims description 9
- 238000005524 ceramic coating Methods 0.000 claims description 5
- 239000000049 pigment Substances 0.000 abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 7
- 230000004907 flux Effects 0.000 abstract description 6
- 238000005507 spraying Methods 0.000 abstract description 6
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 229910052644 β-spodumene Inorganic materials 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000006698 induction Effects 0.000 abstract description 2
- 239000001294 propane Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- 229910052681 coesite Inorganic materials 0.000 abstract 5
- 229910052906 cristobalite Inorganic materials 0.000 abstract 5
- 239000000377 silicon dioxide Substances 0.000 abstract 5
- 229910052682 stishovite Inorganic materials 0.000 abstract 5
- 229910052905 tridymite Inorganic materials 0.000 abstract 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- 229910008556 Li2O—Al2O3—SiO2 Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 229910052914 metal silicate Inorganic materials 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001284373 Spinus Species 0.000 description 1
- ATGLZGGYYRAGGV-UHFFFAOYSA-N [Sb].[Ti].[Cr] Chemical compound [Sb].[Ti].[Cr] ATGLZGGYYRAGGV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- UMUXBDSQTCDPJZ-UHFFFAOYSA-N chromium titanium Chemical compound [Ti].[Cr] UMUXBDSQTCDPJZ-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 229910000174 eucryptite Inorganic materials 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- KHJHBFLMOSTPIC-UHFFFAOYSA-N prop-2-enylidenechromium Chemical compound C(=C)C=[Cr] KHJHBFLMOSTPIC-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- PSUYMGPLEJLSPA-UHFFFAOYSA-N vanadium zirconium Chemical compound [V].[V].[Zr] PSUYMGPLEJLSPA-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/17—Deposition methods from a solid phase
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
この発明は溶射法によるセラミック被覆層を備えた結晶
化ガラスに係り、詳しくは多色・多彩で光沢のある高品
位な被覆層を有するセラミック溶射被覆結晶化ガラスに
関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a crystallized glass having a ceramic coating layer formed by thermal spraying, and more specifically to a ceramic having a multicolored, multicolored, glossy, and high-quality coating layer. Relating to thermal spray coated crystallized glass.
［従来の技術］
従来、結晶化ガラス上にセラミック被覆層を施す方法と
して、塗布材をスクリーン印刷法、転写法、吹き付は法
等で塗布して生の被覆層を形成した後、被覆層を結晶化
ガラスに溶着させて一体化するため焼成していた。[Prior Art] Conventionally, as a method for applying a ceramic coating layer on crystallized glass, a coating material is applied by a screen printing method, a transfer method, a spraying method, etc. to form a raw coating layer, and then the coating layer is applied. was welded to crystallized glass and fired to integrate it.
［発明が解決しようとする課題］
従来の方法では、被塗布材である結晶化ガラスの熱膨張
係数の影響を受けて、多色・多彩で光沢のあ・る高品位
な被覆層を備えることは容易ではなかった。特に、結晶
化ガラスの線膨張係数が２０×１０−７／”Ｃ以下と比
較的小さい場合、光沢を得るためには焼成温度を高める
必要がある。しかしながら、そのために、被塗布材自体
が変形軟化したり、物性が変化したりして高品位の被膜
層をえることは難しかった。[Problem to be solved by the invention] In the conventional method, it is difficult to provide a high-quality coating layer that is multi-colored and glossy due to the influence of the thermal expansion coefficient of the crystallized glass that is the material to be coated. It wasn't easy. In particular, when the coefficient of linear expansion of crystallized glass is relatively small, 20×10-7/"C or less, it is necessary to increase the firing temperature to obtain gloss. However, this causes deformation of the coated material itself. It has been difficult to obtain a high-quality coating layer due to softening and changes in physical properties.
そこで、この発明は溶射法を用いることにより、従来の
問題点を改善した、高品位な被覆層を備えたセラミック
溶射被覆結晶化ガラスの提供を目的とする。Therefore, an object of the present invention is to provide a ceramic spray-coated crystallized glass having a high-quality coating layer, which improves the conventional problems by using a thermal spraying method.
［課題を解決するための手段］
上記目的を達成するため、本発明は被溶射材である結晶
化ガラス（１）上に溶射材であるセラミ・ンクによる被
膜層を備えたことを特徴とするセラミック溶射被覆結晶
化ガラスである。[Means for Solving the Problems] In order to achieve the above object, the present invention is characterized in that a coating layer made of ceramic ink, which is a thermal spraying material, is provided on crystallized glass (1), which is a thermal spraying material. Ceramic spray coated crystallized glass.
また、セラミック被覆層（２）の線膨張係数は結晶化ガ
ラスフ１）の線膨張係数に対して±５０Ｘ１０−フ／℃
の差を備えたことを特徴とするセラミ・ンク溶射被覆結
晶化ガラスである。Furthermore, the linear expansion coefficient of the ceramic coating layer (2) is ±50×10-F/°C with respect to the linear expansion coefficient of the crystallized glass film 1).
Ceramic thermal spray coated crystallized glass is characterized by the following differences:
［作用］
上記のように溶射法のため、被溶射材は比較的低温（約
２００″Ｃ以内）に保持された状態で、すなわち、被溶
射材自体の組織、物性を維持してなされるため、変形軟
化することなく、光沢のある、また付着力のあるセラミ
ック溶射層を形成できる。[Function] As mentioned above, because of the thermal spraying method, the material to be thermally sprayed is kept at a relatively low temperature (within approximately 200"C), that is, the structure and physical properties of the material to be thermally sprayed are maintained. , it is possible to form a glossy and adhesive ceramic sprayed layer without deformation and softening.
さらに、ワンポイントマーク的な層の形成において、被
溶射材全体を加熱する必要なく作業できるという作業性
にも優れている。Furthermore, it has excellent workability in that it is not necessary to heat the entire material to be thermally sprayed when forming a layer like a one-point mark.
また、被溶射材とセラミック被覆層との線膨張係数の上
述の′等辺上になると、両者間の応力差が大きくなり亀
裂、剥離等の欠陥が生じる。Furthermore, when the linear expansion coefficients of the thermal sprayed material and the ceramic coating layer are on the same side as described above, the stress difference between the two becomes large and defects such as cracks and peeling occur.
次に、実施例を説明する。Next, an example will be described.
［実施例］
被溶射材である結晶化ガラスとは
Ｌｉ２０−Ａｌ□Ｏ，−３ｔ（ｈ ［ＴｉＯ２］、Ｌ
ｉ２０−ＡＬｉ２０−ＡＩ２０ ［Ｐ２Ｏ５］、Ｍｇ
Ｏ−Ａ１２０１−８ｉ０２ ［ＴｊＯ□、 ｐ２ｏｇ
ｌ、ＣａＯ−（ＭｇＯ） −Ａｌ２Ｏ２−３ｉ０２
［ｆｌｕｏｒｉｄｅｓ、ｏｘｉｄｅｓｓｕｌｐｈｉｄｅ
ｓ ］、
ＣａＯ−Ｍｇ０３−８ｉ０２ ［ｆｌｕｏｒｉｄｅｓ
コ等の系である。なお、［］は核形成成分を示す。[Example] The crystallized glass that is the material to be thermally sprayed is Li20-Al□O,-3t(h [TiO2], L
i20-ALi20-AI20 [P2O5], Mg
O-A1201-8i02 [TjO□, p2og
l, CaO-(MgO)-Al2O2-3i02
[fluorides, oxidesulfide
s ], CaO-Mg03-8i02 [fluorides
This is a system such as Ko et al. Note that [ ] indicates a nucleation component.
溶射されるセラミックとは被溶射材に付着させる光沢を
付与する役割を持つフラックスと色を付与する役割の顔
料とからなる。The ceramic to be thermally sprayed consists of a flux that is attached to the material to be thermally sprayed and has a role of imparting gloss, and a pigment that has a role of imparting color.
フラックスとして、
β−ｅｕｃｒｉｐｔｉｔｅ（ＬｉＡＩＳｉＯ，ｓ） 、
β−ｓｐｏｄｕｍｅｎｅ（ＬｉＡＩＳｉ２０６） 、
ｓｉ、１ｉｃａ ｇｌａｓｓ、 ｃｏｒｄｉｅｒｉ
ｔｅ（ＭｇＡｌ□５ｔ５０＋ｓ） 、ｂｅｒ５’１（Ａ
ＩＪｅｓＳｔ６０＋ｓ） 、ＢａＴｊＳｉ３０ｇ 、Ｆ
ｅ２Ｔ＋０５ 、Ａｌ２ＴｉＯ５等の材料は低膨張の被
溶射材に適している。As a flux, β-eucryptite (LiAISiO,s),
β-spodumene (LiAISi206),
si, 1ica glass, cordieri
te(MgAl□5t50+s), ber5'1(A
IJesSt60+s), BaTjSi30g, F
Materials such as e2T+05 and Al2TiO5 are suitable for low expansion materials to be thermally sprayed.
また、そのほかとしては、
ＴｉＯ２−５ｊ０２系ガラス、Ｃｕ２０−ＡＣｕ２０−
ＡＩ２０系ガラス、ＰｂＯ−Ｂ２０３−５ｉ０２ 系
ガラス、リン酸ジルコニル（Ｚｒ２Ｐ２０ｇ ）等であ
る。In addition, TiO2-5j02 glass, Cu20-ACu20-
These include AI20 type glass, PbO-B203-5i02 type glass, zirconyl phosphate (Zr2P20g), and the like.
顔料はクロムアルミナピンク、紅柄等のコランダム型、
クロムアンチモンチタン黄、バナジウム式黄等のルチル
型、バナジウムジルコニウム黄等の蛍石型、海碧、クロ
ムアルミナピンク等のスピネル型、クロム錫ピンク等の
ペロブスカイト型等の酸化物よりなるもの、さらに、ヒ
ワ等のガーネット、クロムチタンピンク等のスフエーン
、バナジウム青等のジルコン等の珪酸塩鉱物からなるも
のである。Pigments are corundum type such as chrome alumina pink, red pattern, etc.
Those made of oxides such as rutile type such as chromium antimony titanium yellow and vanadium yellow, fluorite type such as vanadium zirconium yellow, spinel type such as sea blue and chromium alumina pink, and perovskite type such as chrome tin pink; It consists of silicate minerals such as garnet such as siskin, suphene such as chromium titanium pink, and zircon such as vanadium blue.
なお、上述の溶射材はフラックスと顔料との混合物、合
成物またはガラスの何れであってもよい。Note that the above-mentioned thermal spraying material may be a mixture of flux and pigment, a composite, or glass.
溶射法としては、酸素とアセチレンまたは酸素とプロパ
ンなどのガス熱源を使用するガス溶射法とアークやプラ
ズマや高周波誘導など熱源を使用する電気溶射法を用い
ることができる。As the thermal spraying method, a gas thermal spraying method using a gas heat source such as oxygen and acetylene or oxygen and propane, and an electric thermal spraying method using a heat source such as arc, plasma, or high frequency induction can be used.
被ｐＩＡ層の厚みは１００μｌ以下で、２０〜５０μｍ
が好適である。The thickness of the pIA layer is 100 μl or less, and is 20 to 50 μm.
is suitable.
［具体例１］ 結晶化ガラスはネオセラムＮ−０（商品名）を用いた。[Specific example 1] Neoceram N-0 (trade name) was used as crystallized glass.
この線膨張係数は３０〜３８０°Ｃで−３〜−５×１、
０−７ ／ ’Ｃである。This linear expansion coefficient is -3 to -5×1 at 30 to 380°C,
0-7/'C.
溶射材はフラックスにβ−ｅｕｃｒｉｐｔｉｔ、ｅ（Ｌ
ｉＡＩＳｉＯ４）９０重量％と顔料にＣｏｏ−Ａｌ□０
．系の海碧１０重量％からなるガラス化物で、平均粒径
５μｍの微粉末を用いてガス溶射して紫色被膜層を得た
。また、上記・の顔料のほかは同じ条件で、顔料は（Ｆ
ｅ、Ｃｏ）（）（Ｆｅ、Ｃｒ）２０ｇで黒色被覆層を、
バナジウム青で青色被膜層を得た。Thermal spraying material is flux β-eucriptit, e(L
iAISiO4) 90% by weight and Coo-Al□0 as pigment
．． A purple coating layer was obtained by gas spraying using a vitrified product consisting of 10% by weight of sea blue and a fine powder with an average particle size of 5 μm. In addition, under the same conditions except for the above pigment, the pigment was (F
e, Co) () (Fe, Cr) 20g to form a black coating layer,
A blue coating layer was obtained with vanadium blue.
［具体例２］
結晶化ガラスはネオセラムＮ−１１（商品名）を用いた
。この線ｆｆ＆を張係数は３０〜３８０℃で８〜９×１
．０−’／”Ｃである。[Specific Example 2] Neoceram N-11 (trade name) was used as crystallized glass. The tensile modulus of this line ff& is 8-9 x 1 at 30-380℃
．． 0-'/''C.
溶射材はフラックスにβ−ｓｐｏｄｕｍｅｎｅ ８５重
量％と顔料に酸化チタン１５重量％からなる混合物で、
平均粒径７μｍの微粉末を用いてガス溶射して白色被膜
層を得た。The thermal spraying material is a mixture of 85% by weight of β-spodumene as a flux and 15% by weight of titanium oxide as a pigment.
A white coating layer was obtained by gas spraying using fine powder with an average particle size of 7 μm.
［発明の効果］
本発明は、以上の説明のように、溶射法を用いて、結晶
化ガラス上に高品位なセラミック溶射被膜を備えたセラ
ミック溶射被覆結晶化ガラスを提供できる効果がある。[Effects of the Invention] As described above, the present invention has the effect of being able to provide a ceramic spray-coated crystallized glass having a high-quality ceramic spray coating on the crystallized glass using a thermal spraying method.
第１図は、本発明の一実施例のセラミック溶射被覆結晶
化ガラスの断面図である。FIG. 1 is a sectional view of a ceramic spray-coated crystallized glass according to an embodiment of the present invention.
Claims (1)
るセラミックによる被膜層を備えたことを特徴とするセ
ラミック溶射被覆結晶化ガラス。 ２、セラミック被覆層（２）の線膨張係数は結晶化ガラ
ス（１）の線膨張係数に対して±５０×１０＾−＾７／
℃の差を備えたことを特徴とする請求項１記載のセラミ
ック溶射被覆結晶化ガラス。[Scope of Claims] 1. A ceramic spray-coated crystallized glass, characterized in that a coating layer made of ceramic, which is a thermal spraying material, is provided on a crystallized glass (1), which is a thermal spraying material. 2. The linear expansion coefficient of the ceramic coating layer (2) is ±50×10^-^7/ with respect to the linear expansion coefficient of the crystallized glass (1).
The ceramic spray coated crystallized glass according to claim 1, characterized in that the ceramic spray coated crystallized glass has a difference in temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8269489A JPH02263737A (en) | 1989-03-31 | 1989-03-31 | Crystallized glass coated with ceramic by thermal spraying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8269489A JPH02263737A (en) | 1989-03-31 | 1989-03-31 | Crystallized glass coated with ceramic by thermal spraying |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02263737A true JPH02263737A (en) | 1990-10-26 |
Family
ID=13781520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8269489A Pending JPH02263737A (en) | 1989-03-31 | 1989-03-31 | Crystallized glass coated with ceramic by thermal spraying |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02263737A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997020783A1 (en) * | 1995-12-06 | 1997-06-12 | Philips Electronics N.V. | Method of manufacturing a glass substrate coated with a metal oxide and a glass substrate for an electronic display |
| KR100445669B1 (en) * | 2001-03-24 | 2004-08-21 | 조철환 | The ceramic coating method of quartz surface |
-
1989
- 1989-03-31 JP JP8269489A patent/JPH02263737A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997020783A1 (en) * | 1995-12-06 | 1997-06-12 | Philips Electronics N.V. | Method of manufacturing a glass substrate coated with a metal oxide and a glass substrate for an electronic display |
| KR100445669B1 (en) * | 2001-03-24 | 2004-08-21 | 조철환 | The ceramic coating method of quartz surface |
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