JPH02255514A - Powder and granular matter composition - Google Patents
Powder and granular matter compositionInfo
- Publication number
- JPH02255514A JPH02255514A JP7769489A JP7769489A JPH02255514A JP H02255514 A JPH02255514 A JP H02255514A JP 7769489 A JP7769489 A JP 7769489A JP 7769489 A JP7769489 A JP 7769489A JP H02255514 A JPH02255514 A JP H02255514A
- Authority
- JP
- Japan
- Prior art keywords
- potassium
- acid
- potassium nitrate
- nitrite
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims description 13
- 239000000203 mixture Substances 0.000 title claims description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 17
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 235000010289 potassium nitrite Nutrition 0.000 claims abstract description 15
- 239000004304 potassium nitrite Substances 0.000 claims abstract description 15
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 claims description 12
- -1 sulfate ester Chemical class 0.000 claims description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 7
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- XAWNCRQDAFAIHE-UHFFFAOYSA-N methyl naphthalene-1-sulfonate;potassium Chemical compound [K].C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XAWNCRQDAFAIHE-UHFFFAOYSA-N 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- GEHMFBBVXDFUME-UHFFFAOYSA-N 2,3,4-triethylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(CC)C(CC)=C(CC)C(S(O)(=O)=O)=C21 GEHMFBBVXDFUME-UHFFFAOYSA-N 0.000 description 1
- VGKJDEOJZRHTDE-UHFFFAOYSA-N 2,3,4-trimethylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(C)C(C)=C(C)C(S(O)(=O)=O)=C21 VGKJDEOJZRHTDE-UHFFFAOYSA-N 0.000 description 1
- QBVUJLCYWCECLY-UHFFFAOYSA-N 2,3,4-tripropylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(CCC)C(CCC)=C(CCC)C(S(O)(=O)=O)=C21 QBVUJLCYWCECLY-UHFFFAOYSA-N 0.000 description 1
- ZLFUXLIHMADVAL-UHFFFAOYSA-N 2,3-diethylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CC)C(CC)=CC2=C1 ZLFUXLIHMADVAL-UHFFFAOYSA-N 0.000 description 1
- SDRWSOSZWGTKEF-UHFFFAOYSA-N 2,3-dimethylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(C)C(C)=CC2=C1 SDRWSOSZWGTKEF-UHFFFAOYSA-N 0.000 description 1
- XHHIVYOGJCWWCG-UHFFFAOYSA-N 2,3-dipropylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CCC)C(CCC)=CC2=C1 XHHIVYOGJCWWCG-UHFFFAOYSA-N 0.000 description 1
- MGVCHINWHJLXFR-UHFFFAOYSA-N 2-butyl-3-methylnaphthalene-1-sulfonic acid Chemical compound CC=1C(=C(C2=CC=CC=C2C1)S(=O)(=O)O)CCCC MGVCHINWHJLXFR-UHFFFAOYSA-N 0.000 description 1
- BMRVLXHIZWDOOK-UHFFFAOYSA-N 2-butylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CCCC)=CC=C21 BMRVLXHIZWDOOK-UHFFFAOYSA-N 0.000 description 1
- WFYXHHXKFAIEJY-UHFFFAOYSA-N 2-dodecyl-6-hydroxybenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC(O)=C1S(O)(=O)=O WFYXHHXKFAIEJY-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- XCQZVGPEAGYSSA-UHFFFAOYSA-N 2-ethyl-3-methylnaphthalene-1-sulfonic acid Chemical compound CC=1C(=C(C2=CC=CC=C2C1)S(=O)(=O)O)CC XCQZVGPEAGYSSA-UHFFFAOYSA-N 0.000 description 1
- JCRMBLKUFLUWPU-UHFFFAOYSA-N 2-ethylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CC)=CC=C21 JCRMBLKUFLUWPU-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- FWMKPJYJDJSEHR-UHFFFAOYSA-N 2-propylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CCC)=CC=C21 FWMKPJYJDJSEHR-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- WLGDAKIJYPIYLR-UHFFFAOYSA-N octane-1-sulfonic acid Chemical group CCCCCCCCS(O)(=O)=O WLGDAKIJYPIYLR-UHFFFAOYSA-N 0.000 description 1
- UZZYXUGECOQHPU-UHFFFAOYSA-N octyl hydrogen sulfate Chemical compound CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Landscapes
- Glanulating (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は固結が防止された硝酸カリウムまたは亜硝酸カ
リウムの粉粒体組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a granular composition of potassium nitrate or potassium nitrite that is prevented from caking.
硝酸カリウムまたは亜硝酸カリウムの粉粒体は、吸湿性
が高いため貯蔵や輸送の間に固結が起こりやすく、これ
が取り扱い上着しい障害となっている。Powdered materials of potassium nitrate or potassium nitrite have high hygroscopicity and therefore tend to clump during storage and transportation, which poses a serious problem in handling.
従来、このような吸湿性の粉粒体の固結防止方法として
、これらの粉粒体に種々の界面活性剤を配合することが
知られており、例えば、ナ/
フタレンスルホン酸ナトリウムを使用する方法(特開昭
!;、3−/!;29J )等が知られている。Conventionally, as a method of preventing caking of such hygroscopic powders, it has been known to mix various surfactants with these powders. For example, sodium naphthalene sulfonate has been used. A method of doing so (Japanese Patent Application Laid-Open No. 2003-120003; 3-/!; 29J) is known.
しかしながら、これらの界面活性剤による固結防止効果
は十分満足できるとは言えず、より大きい効果を得よう
として多量に用いると着色や品質の低下を招くなどの欠
点がある。However, the anti-caking effect of these surfactants cannot be said to be fully satisfactory, and if a large amount is used in an attempt to obtain a greater effect, there are drawbacks such as coloring and deterioration of quality.
本発明は、着色や品質低下がなく、しかも固結が防止さ
れた工業的価値が大きい硝酸カリウムまたは亜硝酸カリ
ウムの粉粒体組成物を提供するものである。The present invention provides a granular composition of potassium nitrate or potassium nitrite that is free from coloration and quality deterioration and is prevented from caking, and which has great industrial value.
本発明者らは、硝酸カリウムまたは亜硝酸カリウムの粉
粒体の固結防止方法につき鋭意研究を重ねた結果、カリ
ウム塩型の特定の界面活性剤を使用するときは、ナトリ
ウム塩型の界面活性剤に比しアルカリ金属の種類が異な
るのみであるにもかかわらず、極めて優れた固結防止効
果をあげ得ることを見出した。As a result of extensive research into methods for preventing caking of potassium nitrate or potassium nitrite powder, the present inventors found that when using a specific potassium salt type surfactant, a sodium salt type surfactant should be used. It has been found that even though the only difference is in the type of alkali metal, an extremely excellent anti-caking effect can be achieved.
すなわち、本発明の要旨は、硝酸カリウムまたは亜硝酸
カリウムOφ・・に、カリウム塩型のスルホン酸系また
は硫酸エステル系界面活性剤を配合してなる粉粒体組成
物に存する。That is, the gist of the present invention resides in a powder composition formed by blending a potassium salt type sulfonic acid or sulfate ester surfactant with potassium nitrate or potassium nitrite Oφ.
以下、本発明を更に詳細忙説明する。The present invention will be explained in more detail below.
本発明で用いる硝酸カリウムまたは亜硝酸カリウムとし
ては、特に制限はなく種々の製法によって製造されたも
のが対象となる。Potassium nitrate or potassium nitrite used in the present invention is not particularly limited and may be produced by various methods.
カリウム塩型のスルホン酸系または硫酸エステル系界面
活性剤としては、ナフタレンスルホン酸、アルキルナフ
タレンスルホン酸、ベンゼンスルホン酸、アルキルベン
ゼンスルホン酸、アルキルフェノールスルホン酸、アル
キルスルホン酸、上記のスルホン酸のホルマリン縮合物
、アルキル硫酸等のカリウム塩が拳げられるが、特にア
ルキルナフタレンスルホン酸のカリウム塩が好ましい。Potassium salt type sulfonic acid or sulfuric acid ester surfactants include naphthalenesulfonic acid, alkylnaphthalenesulfonic acid, benzenesulfonic acid, alkylbenzenesulfonic acid, alkylphenolsulfonic acid, alkylsulfonic acid, and formalin condensates of the above sulfonic acids. Among them, potassium salts of alkylnaphthalenesulfonic acids and the like are particularly preferred.
上記界面活性剤におけるアルキルナフタレンスルホン酸
としては、炭素数/−20、好ましくは1〜乙のアルキ
ル基を有し、総炭素数がl/〜20のものが好んで用い
られる。アルキル基の具体例としては、メチル基、エチ
ル基、n−プロピル基、i−プロピル基、n−ブチル基
、i−ブチル基、ヘキシル基等があケラれ、アルキル基
の数は特に制限はないが通常7〜3個のものがよ(使用
される。As the alkylnaphthalene sulfonic acid in the above-mentioned surfactant, one having an alkyl group of 1 to 20 carbon atoms, preferably 1 to 20 carbon atoms, and a total of 1 to 20 carbon atoms is preferably used. Specific examples of alkyl groups include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, i-butyl group, hexyl group, etc., and there are no particular restrictions on the number of alkyl groups. No, but usually 7 to 3 are used.
アルキルナフタレンスルホン酸の具体例としては、メチ
ルナフタレンスルホン酸、エチルナフタレンスルホン酸
、プロピルナフタレンスルホン酸、ブチルナフタレンス
ルホン酸のようなモノアルキルナフタレンスルホン酸、
ジメチルナフタレンスルホン酸、ジエチルナフタレンス
ルホン酸、ジプロピルナフタレンスルホン酸、ジブチル
ナフタレンスルホン酸のよ5なジアルキルナフタレンス
ルホン酸、トリメチルナフタレンスルホン酸、トリエチ
ルナフタレンスルホン酸、トリプロピルナフタレンスル
ホン酸、トリブチルナフタレンスルホン酸のようなトリ
アルキルナフタレンスルホン酸、メチルエチルナフタレ
ンスルホン酸、メチルブチルナフタレンスルホン酸のよ
うな混合アルキルナフタレンスルホン酸等が拳げられる
。Specific examples of alkylnaphthalenesulfonic acids include monoalkylnaphthalenesulfonic acids such as methylnaphthalenesulfonic acid, ethylnaphthalenesulfonic acid, propylnaphthalenesulfonic acid, and butylnaphthalenesulfonic acid;
Dialkylnaphthalenesulfonic acids such as dimethylnaphthalenesulfonic acid, diethylnaphthalenesulfonic acid, dipropylnaphthalenesulfonic acid, dibutylnaphthalenesulfonic acid, trimethylnaphthalenesulfonic acid, triethylnaphthalenesulfonic acid, tripropylnaphthalenesulfonic acid, tributylnaphthalenesulfonic acid Mixed alkylnaphthalene sulfonic acids such as trialkylnaphthalene sulfonic acid, methylethylnaphthalene sulfonic acid, methylbutylnaphthalene sulfonic acid, etc. are mentioned.
アルキルベンゼンスルホン酸及ヒアルキルフェノールス
ルホン酸としては、炭素数l〜20゜好ましくは10〜
/gのアルキル基を有し、総炭素数が/A〜30のもの
が好んで用いられる。The alkylbenzenesulfonic acid and hyalkylphenolsulfonic acid have a carbon number of l to 20°, preferably 10 to
Those having an alkyl group of /g and a total number of carbon atoms of /A to 30 are preferably used.
アルキル基の具体例としては、デシル基、ドデシル基、
ヘキサデシル基、オクタデシル基等が挙げられ、アルキ
ル基の数は特忙制限はないが通常7〜3個のものがよ(
使用される。アルキルベンゼンスルホン酸の代表例とし
ては、ドデシルベンゼンスルホン酸力、アルキルフェノ
ールスルホン酸としては、ドデシルフェノールスルホン
酸が挙げられる。Specific examples of alkyl groups include decyl group, dodecyl group,
Examples include hexadecyl group, octadecyl group, etc. The number of alkyl groups is not particularly limited, but it is usually 7 to 3.
used. Typical examples of alkylbenzenesulfonic acids include dodecylbenzenesulfonic acid, and examples of alkylphenolsulfonic acids include dodecylphenolsulfonic acid.
アルキルスルホン酸としては、炭素数2〜20、好まし
くは6〜/−のものが挙げられ、代表例としては、オク
チルスルホン酸である。Examples of the alkyl sulfonic acid include those having 2 to 20 carbon atoms, preferably 6 to 10 carbon atoms, and a typical example is octylsulfonic acid.
また、アルキル硫酸としては、炭素数コル20好ましく
は6〜12のものが誉げられ、代表例としては、オクチ
ル硫酸、−一エチルヘキシル硫酸等が挙げられる。Further, as the alkyl sulfuric acid, those having a carbon number of 20, preferably 6 to 12 are preferred, and representative examples include octyl sulfuric acid, -monoethylhexyl sulfuric acid, and the like.
これらカリウム塩型のスルホン酸系または硫酸エステル
系界面活性剤は、単独でも、混合して使用してもよい。These potassium salt type sulfonic acid or sulfate ester surfactants may be used alone or in combination.
本発明の粉粒体組成物の調製方法は、成分が均一に配合
できる方法である限り特に限定されるものではない。例
えば、原料の硝酸カリウムまたは亜硝酸カリウムの溶液
に上記界面活性剤を添加後、結晶析出により粉粒体組成
物を得る方法、結晶析出中の硝酸カリウムまたは亜硝酸
カリウムのスラリー中に添加、結晶析出により粉粒体組
成物を得る方法、粉状または粒状の硝酸カリウムまたは
亜硝酸カリウムに直接スプレーする方法等が挙げられる
。また、対象とする硝酸カリウムまたは亜硝酸カリウム
としてカリウム分を過剰に含有させたものを用い、これ
に遊離酸の形の上記のようなスルホン酸または硫酸エス
テルを配合してカリウム塩を形成させてもよい。The method for preparing the powder composition of the present invention is not particularly limited as long as the ingredients can be mixed uniformly. For example, after adding the above-mentioned surfactant to a solution of potassium nitrate or potassium nitrite as a raw material, a powder composition is obtained by crystallization. Examples include a method of obtaining a body composition, a method of directly spraying powdered or granular potassium nitrate or potassium nitrite, and the like. Alternatively, potassium nitrate or potassium nitrite containing an excessive amount of potassium may be used, and the above-mentioned sulfonic acid or sulfuric acid ester in the form of a free acid may be blended with this to form a potassium salt. .
上記界面活性剤の使用量は、硝酸カリウムまたは亜硝酸
カリウムの使用目的、保存条件、輸送条件等によっても
異なるが、通常硝酸カリウムまたは亜硝酸カリウムに対
してo、o o s〜o、 r重量%、好ましくは0.
0 / −0,2重量%である。この量があまりに少な
いと本発明の効果が期待できなくなる。逆にあまりに多
く用いてもそれによる特段の効果は期待できず、経済的
に不利であるばかりか品質上好ましくない結果を招く恐
れがある。The amount of the surfactant used varies depending on the purpose of use of potassium nitrate or potassium nitrite, storage conditions, transportation conditions, etc., but is usually o, o o s to o, r wt %, preferably from o, o o s to o, r weight % based on potassium nitrate or potassium nitrite. 0.
0/-0.2% by weight. If this amount is too small, the effects of the present invention cannot be expected. On the other hand, if too much is used, no particular effect can be expected, and it is not only economically disadvantageous but also may lead to unfavorable results in terms of quality.
伺、粉粒体の粒径は特に限定されないが、火薬、ガラス
原料、熱媒体等の工業用としては、平均粒径が数十〜数
百μm程度のものが好適に使用される。Although the particle size of the powder is not particularly limited, for industrial applications such as explosives, raw materials for glass, and heating media, those having an average particle size of about several tens to several hundreds of μm are preferably used.
以下、実施例によって本発明を具体的に説明するが、本
発明はその要旨をこえない限り以下の実施例に限定され
るものではない。EXAMPLES The present invention will be specifically explained below with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof.
実施例/−Aおよび比較例1〜7
平均粒径300μmの硝酸カリウム忙下記第1表に示す
カリウム塩型の界面活性剤の70%水溶液をスプレーし
て混合し、70℃で5時間乾燥して水分がO,OS%の
硝酸カリウムの粉粒体組成物を得た。Example/-A and Comparative Examples 1 to 7 Potassium nitrate particles having an average particle size of 300 μm were sprayed and mixed with a 70% aqueous solution of a potassium salt type surfactant shown in Table 1 below, and dried at 70° C. for 5 hours. A powder composition of potassium nitrate having a moisture content of O and OS% was obtained.
このものの固結度は第1表に示す通りであった。The degree of consolidation of this product was as shown in Table 1.
比較として、ナトリウム塩型の界面活性剤を使用した場
合および界面活性剤を用いなかった場合の粉粒体組成物
の固結度を第1表に併記した。For comparison, Table 1 also shows the degree of caking of powder compositions when a sodium salt type surfactant was used and when no surfactant was used.
なお、固結度の測定は、実施例及び比較例で得られた各
粉粒体組成物300fiをポリエチレン製の袋に入れ、
これを型に入れて7.!r kgの荷重をかけ、7日/
回のサイクルで30℃とq。In addition, the degree of caking was measured by placing each powder composition 300fi obtained in Examples and Comparative Examples in a polyethylene bag,
Put this into a mold 7. ! Applying a load of r kg, 7 days/
30℃ and q for 2 cycles.
℃の間で温度を上下させなから10日間保持して得られ
た、? (711X 90mm×J Om (高さ)の
試料如ついて行った。Obtained by holding the temperature for 10 days without raising or lowering the temperature between ? (A sample of 711 x 90 mm x J Om (height) was followed.
針入率は、該試料にsocmの高さから長さ/45(H
H1重さ/ ?、 j 9の針を落下させ、針の進入し
た長さを
進入長さ(冨1) / j O(冨@)Xioo(%)
で示した。針入率は大きい程固結度が小さいことを示す
。The penetration rate is calculated from the height of socm to the length/45 (H
H1 weight/? , j 9 needle is dropped, and the length of the needle's entry is the entry length (maximum 1) / j O (maximum @) Xioo (%)
It was shown in The higher the penetration rate, the lower the degree of consolidation.
また、固塊率は、該試料を高さ!rOcmの位置から落
下させ、落下物を目開き3nの篩にかけ、篩上に残った
試料の割合を示した。固塊率は小さい程固結度が小さい
ことを示す。In addition, the solidification rate is the height of the sample! The sample was dropped from a position of rOcm, the fallen material was passed through a sieve with an opening of 3n, and the percentage of the sample remaining on the sieve was shown. The smaller the solidification rate, the lower the degree of solidification.
第1表
〔発明の効果〕
本発明の粉粒体組成物は固結することがなく、界面活性
剤の使用量が少ないので品質が優れている。Table 1 [Effects of the Invention] The powder composition of the present invention does not clump and has excellent quality because the amount of surfactant used is small.
Claims (1)
塩型のスルホン酸系または硫酸エステル系界面活性剤を
配合してなる粉粒体組成物。(1) A powder composition comprising potassium nitrate or potassium nitrite mixed with a potassium salt type sulfonic acid or sulfate ester surfactant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7769489A JPH0761848B2 (en) | 1989-03-29 | 1989-03-29 | Powder composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7769489A JPH0761848B2 (en) | 1989-03-29 | 1989-03-29 | Powder composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02255514A true JPH02255514A (en) | 1990-10-16 |
JPH0761848B2 JPH0761848B2 (en) | 1995-07-05 |
Family
ID=13641001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7769489A Expired - Fee Related JPH0761848B2 (en) | 1989-03-29 | 1989-03-29 | Powder composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0761848B2 (en) |
-
1989
- 1989-03-29 JP JP7769489A patent/JPH0761848B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0761848B2 (en) | 1995-07-05 |
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