JPH02252749A - Vinyl chloride resin composition - Google Patents
Vinyl chloride resin compositionInfo
- Publication number
- JPH02252749A JPH02252749A JP7578689A JP7578689A JPH02252749A JP H02252749 A JPH02252749 A JP H02252749A JP 7578689 A JP7578689 A JP 7578689A JP 7578689 A JP7578689 A JP 7578689A JP H02252749 A JPH02252749 A JP H02252749A
- Authority
- JP
- Japan
- Prior art keywords
- moles
- chloride resin
- vinyl chloride
- formula
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000011342 resin composition Substances 0.000 title claims description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 6
- -1 phthalate ester Chemical class 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 20
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 16
- 239000004014 plasticizer Substances 0.000 description 10
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 8
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 6
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 102100034003 FAU ubiquitin-like and ribosomal protein S30 Human genes 0.000 description 1
- 101000732045 Homo sapiens FAU ubiquitin-like and ribosomal protein S30 Proteins 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- PUFGCEQWYLJYNJ-UHFFFAOYSA-N didodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCC PUFGCEQWYLJYNJ-UHFFFAOYSA-N 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は塩化ビニル樹脂組成物に関する。該樹脂組成物
は優れた帯電防止性を有し、帯電防止用成形物（フィル
ム、シート等）用として有用である。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to vinyl chloride resin compositions. The resin composition has excellent antistatic properties and is useful for antistatic molded articles (films, sheets, etc.).
従来の技術
フタル酸エステル（Ｉ）は導電性可塑剤として知られて
いる（特開昭６２−２６５３３８号公報）。BACKGROUND OF THE INVENTION Phthalic acid ester (I) is known as a conductive plasticizer (Japanese Unexamined Patent Publication No. 62-265338).
又、該公報は塩化ビニル樹脂にフタル酸エステル（Ｉ）
と通常の液状可塑剤を配合した樹脂組成物を開示してい
る。通常の液状可塑剤として、例えばジオクチルフタレ
ート、ジデシルフタレート、ジラウリルフタレート等の
フタル酸エステル、トリクレジルホスフェート、トリキ
シレニルホスフェート、モノオクチルジフェニルホスフ
ェート等のリン酸エステル類、エポキシ化大豆油等のエ
ポキシ類、トリオクチルトリメリテート等のトリメリッ
ト類エステル類、二塩基酸ジエステル類、ポリエステル
類等があげられる。Additionally, the publication discloses that phthalate ester (I) is added to vinyl chloride resin.
The patent discloses a resin composition containing a liquid plasticizer and a conventional liquid plasticizer. Examples of common liquid plasticizers include phthalic acid esters such as dioctyl phthalate, didecyl phthalate, and dilauryl phthalate, phosphoric acid esters such as tricresyl phosphate, tricylenyl phosphate, and monooctyldiphenyl phosphate, and epoxidized soybean oil. Examples include epoxies, trimellitic esters such as trioctyl trimellitate, dibasic acid diesters, and polyesters.
しかし、二塩基酸ジエステル類の具体例やその効果につ
いては何ら記載されていない。ジオクチルフタレートが
実施例にあげられているにすぎない。However, no specific examples of dibasic acid diesters or their effects are described. Dioctyl phthalate is only mentioned as an example.
脂肪族二塩基酸エステル（ＩＩ）を可塑剤として単独で
塩化ビニル樹脂に用いると、塩化ビニル樹脂との相溶性
が悪く、成形物の表面にブリードし易い。その為該エス
テル（ＩＩ）は、一般には単独では用いられず、他の可
塑剤と併用される。When aliphatic dibasic acid ester (II) is used alone as a plasticizer in vinyl chloride resin, it has poor compatibility with the vinyl chloride resin and tends to bleed onto the surface of the molded product. Therefore, the ester (II) is generally not used alone, but in combination with other plasticizers.
発明が解決しようとする課題
帯電防止性の優れた成形物を得る為の塩化ビニル樹脂組
成物が求められている。Problems to be Solved by the Invention There is a need for a vinyl chloride resin composition for obtaining molded articles with excellent antistatic properties.
課題を解決するための手段
本発明は塩化ビニル樹脂、下記一般式（Ｉ）で表わされ
るフタル酸エステル（Ｉ）及び一般式（ＩＩ）で表わさ
れる脂肪族二塩基酸エステル（ＩＩ）からなる塩化ビニ
ル樹脂組成物を提供する。Means for Solving the Problems The present invention provides a chlorinated resin comprising a vinyl chloride resin, a phthalate ester (I) represented by the following general formula (I), and an aliphatic dibasic acid ester (II) represented by the general formula (II). A vinyl resin composition is provided.
一般式（Ｉ）
（式中、Ａは炭素数２〜４のアルキレン、Ｒ１及びＲ２
は炭素数２〜１３の直鎮又は分岐アルキルを表わす。ａ
及びｂは１〜６の整数である。）
一般式（Ｉり
〔式中、Ｒ１及びＲ２は炭素数４〜１３の直鎮又は分岐
アルキルを表わすか、又はＲ３が（＾Ｏ）、Ｒ。General formula (I) (wherein A is alkylene having 2 to 4 carbon atoms, R1 and R2
represents a straight or branched alkyl having 2 to 13 carbon atoms. a
and b is an integer from 1 to 6. ) General formula (I [wherein R1 and R2 represent straight or branched alkyl having 4 to 13 carbon atoms, or R3 is (^O), R.
（式中、Ａ％Ｒ，及びａは前記と同義である）で、Ｒ４
がｌ＾０）ｂＬ （式中ＡＳＲ１及びｂは前記と同義で
ある）である。ｎは１〜１２の整数である〕
塩化ビニル樹脂としては平均重合度７００〜４０００の
ものが用いられる。(wherein A%R and a have the same meanings as above), R4
is l^0) bL (wherein ASR1 and b have the same meanings as above). n is an integer of 1 to 12.] As the vinyl chloride resin, one having an average degree of polymerization of 700 to 4000 is used.
式（Ｉ）において、炭素数２〜４のアルキｌノンとして
は例えばエチレン、プロピレン、ブチレン等があげられ
る。炭素数２〜１３の直鎖又は分岐アルキルとしては、
例えばエチル、プロピル、ブチル、ヘキシル、ヘプチル
、オクチル、ノニル、デシル、ドデシル、トリデシル等
があげられる。In formula (I), examples of the alkylonone having 2 to 4 carbon atoms include ethylene, propylene, and butylene. As the straight chain or branched alkyl having 2 to 13 carbon atoms,
Examples include ethyl, propyl, butyl, hexyl, heptyl, octyl, nonyl, decyl, dodecyl, tridecyl, and the like.
式（Ｉ）の化合物としては、例えばエタノールにエチレ
ンオキサイド１〜６モル、プロピレンオキサイド１〜６
モルもしくはブチレンオキサイド１〜６モルを付加させ
た化合物、プロパツールにエチレンオキサイド１〜６モ
ル、プロピレンオキサイド１〜６モル、もしくはブチレ
ンオキサイド１〜６゛モルを付加させた化合物、ブタノ
ールに、エチレンオキサイド１〜６モル、プロピレンオ
キサイド１〜６モル、もしくはブチレンオキサイド１〜
６モルを付加させた化合物、ヘキサノールに、エチレン
オキサイド１〜６モル、プロピレンオキサイド１〜６モ
ル、もしくはブチレンオキサイド１〜６モルを付加させ
た化合物、ヘプタツールに、エチレンオキサイド１〜６
モル、プロピレンオキサイド１〜６モル、もしくはブチ
レンオキサイド１〜６モルを付加させた化合物、オクタ
ツールに、エチレンオキサイド１〜６モル、プロピレン
オキサイド１〜６モル、もしくはブチレンオキサイド１
〜６モルを付加させた化合物、ノナノールに、エチレン
オキサイド１〜６モル、プロピレンオキサイド１〜６モ
ル、もしくはブチレンオキサイド１〜６モルを付加させ
た化合物、デカノールに、エチレンオキサイド１〜６モ
ル、プロピレンオキサイド１〜６モル、もしくはブチレ
ンオキサイド１〜６モルを付加させた化合物、ドデカノ
ールにエチレンオキサイド１〜６モル、プロピレンオキ
サイド１〜６モノへもしくはプチレンオキサイド１〜６
モルを付加させた化合物、トリデカノールに、エチレン
オキサイド１〜６モル、プロピレンオキサイド１〜６モ
ル、もしくはブチレンオキサイド１〜６モルを付加させ
た化合物、またはそれぞれに該当する第２級アルコール
に、該当するアルキレンオキサイドを付加させた化合物
の単独または混合物の、フタル酸ジエステル（置換エス
テルを含む）が挙げられる。As the compound of formula (I), for example, 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide in ethanol,
mol or a compound to which 1 to 6 mol of butylene oxide is added, a compound to which 1 to 6 mol of ethylene oxide, 1 to 6 mol of propylene oxide, or 1 to 6 mmol of butylene oxide is added to propatool, ethylene oxide to butanol. 1 to 6 moles, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide
A compound in which 6 moles of ethylene oxide is added to hexanol, a compound in which 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide is added to heptatool, 1 to 6 moles of ethylene oxide to heptatool.
1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide to octatool, a compound to which 1 to 6 moles of propylene oxide or 1 to 6 moles of butylene oxide has been added.
Compounds with ~6 moles added to nonanol, 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide to nonanol, 1 to 6 moles of ethylene oxide, propylene to decanol A compound obtained by adding 1 to 6 moles of oxide or 1 to 6 moles of butylene oxide to dodecanol, 1 to 6 moles of ethylene oxide to dodecanol, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide.
1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide to tridecanol, or corresponding secondary alcohols. Examples include phthalic acid diesters (including substituted esters), singly or as a mixture of compounds to which alkylene oxide is added.
式（ＩＩ）にふいて炭素数４〜１３の直鎮又は分岐アル
キルとしては、例えばブチル、ヘキシル、ヘプチル、オ
クチル、ノニル、デシル、ドデシル、トリデシル等があ
げられる。Examples of the straight or branched alkyl having 4 to 13 carbon atoms in formula (II) include butyl, hexyl, heptyl, octyl, nonyl, decyl, dodecyl, tridecyl, and the like.
式（ＩＩ）の化合物としては、例えばブタノール、ヘキ
サノール、ヘプタツール、オクタツール、ノナノール、
デカノール、ドデカノール、もしくはトリデカノールま
たはそれぞれに該当する第２級アルコールの単独または
混合物のアジピン酸ジエステル（［換エステルを含む）
、ブタノールに、エチレンオキサイド１〜６モル、プロ
ピレンオキサイド１〜６モル、もしくはブチレンオキサ
イド１〜６モルを付加させた化合物、へ、キサノールに
、エチレンオキサイド１〜６モル、プロピレンオキサイ
ド１〜６モル、もしくはブチレンオキサイド１〜６モル
を付加させた化合物、ヘプタツールに、エチレンオキサ
イド１〜６モル、プロピレンオキサイド１〜６モル、も
しくはブチレンオキサイド１〜６モルを付加させた化合
物、オクタツールに、エチレンオキサイド１〜６モル、
プロピレンオキサイド１〜６モル、もしくはブチレンオ
キサイド１〜６モルを付加させた化合物、ノナノールに
、エチレンオキサイド１〜６モル、プロピレンオキサイ
ド１〜６モル、もしくはブチレンオキサイド１〜６モル
を付加させた化合物、デカノールに、エチレンオキサイ
ド１〜６モル、プロピレンオキサイド１〜６モル、もし
くはブチレンオキサイド１〜６モルを付加させた化合物
、ドデカノールに、エチレンオキサイド１〜６モル、プ
ロピレンオキサイド１〜６モル、もしくはブチレンオキ
サイド１〜６モルを付加させた化合物、トリデカノール
に、エチレンオキサイド１〜６モル、プロピレンオキサ
イド１〜６モル、もしくはブチレンオキサイド１〜６モ
ルを付加させた化合物、またはそれぞれに該当する第２
級アルコールに、該当するアルキレンオキサイドを付加
させた化合物の単独または混合物の、アジピン酸、アゼ
ライン酸、セバシン酸等のジエステル（置換エステルを
含む）が挙げられる。Examples of the compound of formula (II) include butanol, hexanol, heptatool, octatool, nonanol,
Adipic acid diesters (including conversion esters) of decanol, dodecanol, or tridecanol or their corresponding secondary alcohols, singly or in mixtures.
, a compound obtained by adding 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide to butanol; Or a compound to which 1 to 6 moles of butylene oxide is added, a compound to which 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide is added to heptatool, a compound to which 1 to 6 moles of butylene oxide is added to heptatool, and ethylene oxide to octatool. 1 to 6 moles,
A compound to which 1 to 6 moles of propylene oxide or 1 to 6 moles of butylene oxide is added; a compound to which 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide is added to nonanol; A compound in which 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or 1 to 6 moles of butylene oxide is added to decanol, 1 to 6 moles of ethylene oxide, 1 to 6 moles of propylene oxide, or butylene oxide to dodecanol. A compound to which 1 to 6 mol of ethylene oxide, 1 to 6 mol of propylene oxide, or 1 to 6 mol of butylene oxide is added to tridecanol, or a second compound corresponding to each of them.
Examples include diesters (including substituted esters) of adipic acid, azelaic acid, sebacic acid, etc., which are compounds obtained by adding the corresponding alkylene oxide to an alcohol.
塩化ビニル樹脂に対するフタル酸エステル（Ｉ）と脂肪
族二塩基酸エステル（ＩＩＩ）との配合割合は塩化ビニ
ル樹脂１００重量部に対して（■）＋（ＩＩ）が２０〜
７０重量部である。The blending ratio of phthalate ester (I) and aliphatic dibasic acid ester (III) to vinyl chloride resin is (■) + (II) from 20 to 100 parts by weight of vinyl chloride resin.
It is 70 parts by weight.
又、（Ｉ）／ （ＩＩ）の重量比は５０／ｌ〜１１５０
゜好ましくは５０１５〜２５１５０である。Also, the weight ratio of (I)/(II) is 50/l to 1150
° Preferably it is 5015-25150.
本発明のビニル樹脂組成物は、さらに必要に応じて、公
知の安定剤（例えば、ステアリン酸亜鉛、ステアリン酸
バリウム）、酸化防止剤（例えば、ビスフェノールＡ）
、難燃性物質（例えば、トリクレジルホスフェート、オ
クチルジフェニルホスフェート等のリン酸エステル可塑
剤、石膏）が添加されていてもよい。The vinyl resin composition of the present invention may further contain known stabilizers (e.g., zinc stearate, barium stearate), antioxidants (e.g., bisphenol A), as necessary.
, flame retardant substances (for example, phosphate ester plasticizers such as tricresyl phosphate and octyldiphenyl phosphate, and gypsum) may be added.
本発明の塩化ビニル樹脂組成物をミキシングロール、押
し出し機等により混練し、さらに必要に応じて造粒し、
フィルム、シート用材料を得ることができる。The vinyl chloride resin composition of the present invention is kneaded using a mixing roll, an extruder, etc., and further granulated if necessary,
Materials for films and sheets can be obtained.
以下に実施例を示す。Examples are shown below.
実施例１〜４
塩化ビニル樹脂（平均重合度１０００）１００重量部と
可塑剤〔プラサイザーＭ−１００（協和発酵）に第１表
に示す可塑剤を２Ｑｗｔ％混合したもの〕５０重量部と
安定剤〔ステアリン酸亜鉛ニステアリン酸バリウム（Ｉ
： １ｗ／ｗ）３３重量部とを混合した。その後、混練
（ロール温度 １５５℃、７分間）とプレス（温度１６
５℃、７分間）により厚さ１０１１１１の試験用シート
を或ルした。Examples 1 to 4 100 parts by weight of vinyl chloride resin (average degree of polymerization 1000), 50 parts by weight of plasticizer [Plasizer M-100 (Kyowa Hakko) mixed with 2Qwt% of the plasticizer shown in Table 1], and stabilizer [Zinc stearate Barium stearate (I)
: 1 w/w) and 33 parts by weight were mixed. After that, kneading (roll temperature 155℃, 7 minutes) and pressing (temperature 16℃)
A test sheet having a thickness of 101111 mm was prepared by heating at 5° C. for 7 minutes.
シートの体積固有抵抗はＪＩＳ Ｋ−６’７２３に準
拠して測定した。The volume resistivity of the sheet was measured in accordance with JIS K-6'723.
その結果を第１表に示す。The results are shown in Table 1.
第 １
表
手続補正書（自発）
１、事件の表示
平成１年特許願第７５７８６号
表から明らかな様に、実施例の塩化ビニル樹脂組成物は
比較例のそれに比べて帯電防止性がすぐれている。Table 1 Procedural amendment (voluntary) 1. Indication of the case As is clear from the table of Patent Application No. 75786 of 1999, the vinyl chloride resin composition of the example has superior antistatic properties compared to that of the comparative example. There is.
発明の効果
本発明の塩化ビニル樹脂組成物は優れた帯電防止性を有
する。Effects of the Invention The vinyl chloride resin composition of the present invention has excellent antistatic properties.
事件との関係 特許出願人
郵便番号 １００
住所 東京都千代田区大手町−丁目６番１号名称協和油
化株式会社
明細書の特許請求の範囲の欄及び発明の詳細な説明の欄
５、補正の内容
１）特許請求の範囲
「別紙の通り」
２）明細書第３頁９行
「リフト類エステル類」を「リフト酸エステル類」に訂
正する。Relationship to the case Patent applicant postal code 100 Address 6-1 Otemachi-chome, Chiyoda-ku, Tokyo Name Kyowa Yuka Co., Ltd. Claims column and detailed description of the invention column 5 of the specification, amendments Contents 1) Claims “as per attached sheet” 2) Correct “lift esters” to “lift acid esters” on page 3, line 9 of the specification.
３）同書第９頁下より７〜６行の「さらに必要に応じて
」の後に「汎用の可塑剤（例えば、ジオクチルフタレー
ト、ジイソノニルフタレート）」を加入する。3) From the bottom of page 9 of the same book, add "general-purpose plasticizers (for example, dioctyl phthalate, diisononyl phthalate)" after "further as necessary" in lines 7-6.
４）同書第９頁１１行
ｒ２０〜７０重量部」を「１０〜１００重量部」に訂正
する。4) On page 9, line 11 of the same book, ``20 to 70 parts by weight'' is corrected to ``10 to 100 parts by weight.''
特許請求の範囲
１、塩化ビニル樹脂、下記一般式（Ｉ）で表わされるフ
タル酸エステル（Ｉ）及び一般式（Ｉ［）で表わされる
脂肪族二塩基酸エステル（ＩＩ）からなる塩化ビニル樹
脂組成物。Claim 1: A vinyl chloride resin composition comprising a vinyl chloride resin, a phthalate ester (I) represented by the following general formula (I), and an aliphatic dibasic acid ester (II) represented by the general formula (I[). thing.
一般式（Ｉ）
（式中、Ａは炭素数２〜４のアルキレン、Ｒ３及びＲ３
は炭素数２〜１３の直鎖又は分岐アルキルを表わす。ａ
及びｂは１〜６の整数である。）一般式（ＩＩ）
Ｃ式中、Ｒ５及びＲ１は炭素数４〜Ｉ３の直鎮又は分岐
アルキルを表わすか、又はＲ５が（八〇）、Ｒ。General formula (I) (wherein A is alkylene having 2 to 4 carbon atoms, R3 and R3
represents a straight chain or branched alkyl having 2 to 13 carbon atoms. a
and b is an integer from 1 to 6. ) General formula (II) In formula C, R5 and R1 represent straight or branched alkyl having 4 to I3 carbon atoms, or R5 is (80), R.
（式中、Ａ％Ｒ９及びａは前記と同義である）で、Ｒ４
が（八〇）ｂＲ２（式中Ａ、Ｒ２及びｂは前記と同義で
ある）である。ｎは１〜１２の整数である〕
２、塩化ビニル樹脂１００重量部に対して（■）＋（Ｉ
Ｉ）が１０〜１００重量部で、かつ（■）／（ＩＩ）の
重量比が５０７１〜１１５ｏとなるように配合した塩化
ビニル樹脂組成物。(wherein A%R9 and a have the same meanings as above), and R4
is (80) bR2 (in the formula, A, R2 and b have the same meanings as above). n is an integer from 1 to 12] 2. (■) + (I
A vinyl chloride resin composition containing 10 to 100 parts by weight of I) and a weight ratio of (■)/(II) of 5071 to 115o.
Claims (1)
フタル酸エステル（ I ）及び一般式（II）で表わされ
る脂肪族二塩基酸エステル（II）からなる塩化ビニル樹
脂組成物。 一般式（ I ） ▲数式、化学式、表等があります▼（ I ） （式中、Ａは炭素数２〜４のアルキレン、Ｒ＿１及びＲ
＿２は炭素数２〜１３の直鎖又は分岐アルキルを表わす
。ａ及びｂは１〜６の整数である。） 一般式（II） ▲数式、化学式、表等があります▼ 〔式中、Ｒ＿３及びＲ＿４は炭素数４〜１３の直鎖又は
分岐アルキルを表わすか、又はＲ＿３が（ＡＯ）＿ａＲ
＿１（式中、Ａ、Ｒ＿１及びａは前記と同義である）で
、Ｒ＿４が（ＡＯ）＿ｂＲ＿２（式中Ａ、Ｒ＿２及びｂ
は前記と同義である）である。ｎは１〜１２の整数であ
る〕 ２、塩化ビニル樹脂１００重量部に対して（ I ）＋（
II）が２０〜７０重量部で、かつ（ I ）／（II）の重
量比が５０／１〜１／５０となるように配合した塩化ビ
ニル樹脂組成物。[Claims] 1. Vinyl chloride resin, a vinyl chloride resin consisting of a phthalate ester (I) represented by the following general formula (I) and an aliphatic dibasic acid ester (II) represented by the general formula (II) Composition. General formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) (In the formula, A is alkylene with 2 to 4 carbon atoms, R_1 and R
_2 represents a straight chain or branched alkyl having 2 to 13 carbon atoms. a and b are integers from 1 to 6. ) General formula (II) ▲ Numerical formulas, chemical formulas, tables, etc.
_1 (in the formula, A, R_1 and a have the same meanings as above), and R_4 is (AO)_bR_2 (in the formula, A, R_2 and b
is the same as above). n is an integer from 1 to 12] 2. (I) + (with respect to 100 parts by weight of vinyl chloride resin)
A vinyl chloride resin composition containing 20 to 70 parts by weight of II) and a weight ratio of (I)/(II) of 50/1 to 1/50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7578689A JPH02252749A (en) | 1989-03-28 | 1989-03-28 | Vinyl chloride resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7578689A JPH02252749A (en) | 1989-03-28 | 1989-03-28 | Vinyl chloride resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02252749A true JPH02252749A (en) | 1990-10-11 |
Family
ID=13586245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7578689A Pending JPH02252749A (en) | 1989-03-28 | 1989-03-28 | Vinyl chloride resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02252749A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60181142A (en) * | 1984-02-29 | 1985-09-14 | New Japan Chem Co Ltd | Novel plasticizer |
| JPS63117067A (en) * | 1986-11-05 | 1988-05-21 | Masami Sakamoto | Subsidiary material composition for resin and resin composition |
-
1989
- 1989-03-28 JP JP7578689A patent/JPH02252749A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60181142A (en) * | 1984-02-29 | 1985-09-14 | New Japan Chem Co Ltd | Novel plasticizer |
| JPS63117067A (en) * | 1986-11-05 | 1988-05-21 | Masami Sakamoto | Subsidiary material composition for resin and resin composition |
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