JPH0225168Y2 - - Google Patents
Info
- Publication number
- JPH0225168Y2 JPH0225168Y2 JP1877584U JP1877584U JPH0225168Y2 JP H0225168 Y2 JPH0225168 Y2 JP H0225168Y2 JP 1877584 U JP1877584 U JP 1877584U JP 1877584 U JP1877584 U JP 1877584U JP H0225168 Y2 JPH0225168 Y2 JP H0225168Y2
- Authority
- JP
- Japan
- Prior art keywords
- sample
- slag
- container
- sample container
- metal film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002893 slag Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- -1 and furthermore Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Analysing Materials By The Use Of Radiation (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
Description
【考案の詳細な説明】
本考案は、鉱滓、溶融フラツクス成分の分析の
ために使用する鉱滓試料採取容器に関するもので
ある。なお、本明細書では溶融フラツクスをも含
めて鉱滓と称することにする。[Detailed Description of the Invention] The present invention relates to a slag sample collection container used for analysis of slag and molten flux components. In this specification, the term slag includes molten flux.
従来、例えば高炉滓の成分を分析するには、採
取した試料を蛍光Ｘ線分析装置により分析するの
が一般的であるが、冷却速度が大きいと試料に割
れが入り易く、単に冷却するだけでは満足できる
健全な試料を得ることはなかなか困難であつた。
冷却速度を緩慢にするためにセラミツクスなどの
熱伝導率の悪い材料を試料容器に使用しても、高
炉滓が容器内面に密着して剥離し難くなり、無理
に剥離しても表面状態の極めて悪い試料しか得ら
れなかつた。 Conventionally, for example, in order to analyze the components of blast furnace slag, it is common to analyze the collected sample using a fluorescent X-ray analyzer, but if the cooling rate is too high, cracks tend to appear in the sample, so it is difficult to simply cool it. It was quite difficult to obtain a satisfactory and healthy sample.
Even if a material with poor thermal conductivity such as ceramics is used for the sample container in order to slow the cooling rate, the blast furnace slag will stick to the inner surface of the container and will be difficult to peel off, and even if it is forcibly peeled off, the surface condition will be extremely poor. Only bad samples were obtained.
従つて、通常５〜10Kg程度の高炉滓を汲み取つ
て自然冷却により常温になるまで冷却し、その後
に粗粉砕して除鉄作業を行い、更に100メツシユ
以下に微粉砕し、それを四分法によつて正確に10
グラムの試料に分け、この試料にバインダとして
例えば澱粉、スチレン、スチレンマレイン酸ポリ
マ、ステアリン酸等の結合剤を適量添加混合し、
40〜50トン程度のプレス機械で加圧成型して分析
用試料を調整している。かくすることにより、分
析用試料の表面は滑らかな平担部となり、その表
面に一定の条件で蛍光Ｘ線を照射することがで
き、分析値を求めることができる。 Therefore, usually around 5 to 10 kg of blast furnace slag is scooped out and cooled down to room temperature by natural cooling, then coarsely crushed to remove iron, further finely crushed to less than 100 mesh, and then quartered. exactly 10 by law
Divide into gram samples, add and mix an appropriate amount of a binder such as starch, styrene, styrene maleic acid polymer, stearic acid, etc. to this sample,
Samples for analysis are prepared by pressure molding using a 40 to 50 ton press machine. By doing so, the surface of the sample for analysis becomes a smooth, flat part, and the surface can be irradiated with fluorescent X-rays under certain conditions, allowing analysis values to be determined.
しかし、このような試料の調整は時間がかかる
上に、蛍光Ｘ線分析装置にかけて真空吸引する
と、試料の一部が飛散して分析装置を損傷する等
の問題がある。また粉末の粒度や成型密度を一定
にしないとＸ線測定強度に変化が生じて分析値が
不正確になるし、試料と結合剤の混合比や混合状
態による分析値への影響も無視することはできな
い。 However, such sample preparation takes time, and when the sample is vacuum-suctioned by a fluorescent X-ray analyzer, part of the sample scatters and damages the analyzer. In addition, if the particle size and molding density of the powder are not constant, the X-ray measurement intensity will change and the analytical values will be inaccurate, and the influence of the mixing ratio and mixing state of the sample and binder on the analytical values should also be ignored. I can't.
更に、分析精度を高くしたい場合には、微粉砕
した試料の0.5グラムを正確に秤量して、これに
Na2B4O7（ホウ砂）を５グラム添加して白金ルツ
ボ中で約1000度Ｃに加熱溶融して分析試料にする
ことが行われている。しかしこの場合でも、試料
に含有されている微量元素のナトリウムの分析は
不能であり、微量のカリウム、亜鉛等が希釈され
るために、分析精度が必ずしも十分でない。 Furthermore, if you want to increase the accuracy of your analysis, you can accurately weigh 0.5 grams of the finely ground sample and add it to the sample.
A sample for analysis is prepared by adding 5 grams of Na 2 B 4 O 7 (borax) and heating and melting it in a platinum crucible at about 1000 degrees Celsius. However, even in this case, it is impossible to analyze the trace element sodium contained in the sample, and trace amounts of potassium, zinc, etc. are diluted, so the analysis accuracy is not necessarily sufficient.
このように、従来の試料調製方法では分析精度
に問題があると共に、調製時間も労力も相当に大
きく、それに要するコストは相当に高価となる。 As described above, conventional sample preparation methods have problems with analytical precision, require considerable preparation time and labor, and are considerably expensive.
本考案の目的は、上述の問題を改善するため、
溶融状態の鉱滓をそのまま試料容器に注入して、
それを冷却するだけで蛍光Ｘ線用の分析試料が容
易に得られる鉱滓試料採取容器を提供することに
あり、その要旨は、熱伝導率が低くかつ多孔質の
材料により凹型に成型した試料容器の内面に、高
温の鉱滓と反応し難い性質の金属膜を試料容器の
多孔性を損わないようにコーテイングしたことを
特徴とするものである。 The purpose of this invention is to improve the above-mentioned problems.
Pour the molten slag directly into the sample container,
The purpose is to provide a slag sample collection container from which an analysis sample for fluorescent X-rays can be easily obtained by simply cooling the slag sample container. The inner surface of the sample container is coated with a metal film that does not easily react with high-temperature slag so as not to impair the porosity of the sample container.
第１図は本考案に係る鉱滓試料採取容器の１実
施例を示すものであり、例えば高さＨ＝15〜20
mm、開口の内径D1＝32〜35mm、底部の内径D2＝
31〜34mm程度の凹状の容器であり、試料容器１は
熱伝導率の低い材料で作られていると共に、凝固
時に鉱滓から発生するガスを放散するために多孔
質の材料で作られている。 FIG. 1 shows an embodiment of the slag sample collection container according to the present invention, for example, the height H=15 to 20.
mm, inner diameter of opening D1=32~35mm, inner diameter of bottom D2=
The sample container 1 is a concave container with a diameter of about 31 to 34 mm, and is made of a material with low thermal conductivity, and is also made of a porous material to dissipate gas generated from the slag during solidification.
試料容器１は例えばセラミツクスや鋳物用砂型
を単一又は混合したものにフエノールレジン等の
粘着剤を添加して凹型に加熱成型したものが用い
られるが、耐高温性を有し、溶融滓と反応せずに
しかも高い通気性を有することが必要である。 The sample container 1 is, for example, made of ceramics or a foundry sand mold, either singly or in a mixture, with an adhesive such as phenol resin added and heated and molded into a concave shape. It is necessary to have high air permeability without any air pollution.
この試料容器１の内面には、高温の鉱滓と反応
し難い性質を有する例えばクロム、ニツケル、
金、白金等が蒸着或いはスパツタリングなどによ
り極めて薄い金属膜２として通気性を損わずにコ
ーテイングされている。第１図の場合は試料容器
１の内面に直接金属膜２をコーテイングした例で
あるが、第２図に示す実施例は試料容器１の内面
に予め黒鉛層３を形成してから、金属膜２をコー
テイングした場合を示している。 The inner surface of the sample container 1 is coated with materials such as chromium, nickel, etc., which have properties that do not easily react with high-temperature slag.
Gold, platinum, etc. are coated as an extremely thin metal film 2 by vapor deposition or sputtering without impairing air permeability. In the case of FIG. 1, the metal film 2 is directly coated on the inner surface of the sample container 1, but in the embodiment shown in FIG. 2 is coated.
このように形成した試料容器１に溶融状態の鉱
滓を注型してそのまま冷却すると、第３図に示す
ような形状を有する試料４が得られるが、試料容
器１の内面には高温の鉱滓と反応し難い金属膜２
があるため、試料４は試料容器から簡単に剥離で
きるし、試料４の分析面５はガラス表面状の極め
て滑らかな面になつているので、そのまま蛍光Ｘ
線分析装置へかけることができる。この点につい
ては金属膜２を設けない試料容器で採取した試料
が、容器と試料との境界層で殆ど剥離できないと
いう事実からもその効果が実証される。また、得
られた試料４は結合剤も混入されていず、更にナ
トリウム、カリウム等の微量含有元素が全く希釈
されていないから、従来の場合に比較して高い分
析精度が得られる。 If molten slag is poured into the sample container 1 formed in this way and then cooled, a sample 4 having the shape shown in FIG. 3 will be obtained. Metal film that is difficult to react 2
Because of this, the sample 4 can be easily peeled off from the sample container, and the analysis surface 5 of the sample 4 has an extremely smooth glass surface, so it can be directly exposed to fluorescent X.
It can be applied to a line analyzer. Regarding this point, its effectiveness is also demonstrated by the fact that a sample collected using a sample container without the metal film 2 can hardly be separated at the boundary layer between the container and the sample. In addition, the obtained sample 4 does not contain any binder, and furthermore, trace elements such as sodium and potassium are not diluted at all, so that higher analysis accuracy can be obtained than in the conventional case.
なお、本考案に係る鉱滓試料採取容器は、高炉
滓や製鋼滓のみだけでなく、熔銑予備処理滓、炉
外精錬滓、タンデツシユ内鉱滓、連続鋳造鋳型内
鉱滓等の試料調製にも利用できることは勿論であ
る。 The slag sample collection container according to the present invention can be used not only for blast furnace slag and steelmaking slag, but also for sample preparation of hot metal pretreatment slag, out-of-furnace smelting slag, slag in a tundish, slag in a continuous casting mold, etc. Of course.
上述したように本考案に係る鉱滓試料採取容器
は、試料容器内に金属膜をコーテイングするなど
して、溶融鉱滓を注型して冷却させるだけで健全
な試料が得られるので、分析精度が向上するのみ
ならず、従来大変な手数と時間を必要とした試料
調製を1/10程度の短時間で簡易に行うことがで
き、それに要するコストも大幅に切下げることが
可能である。 As mentioned above, the slag sample collection container according to the present invention improves analysis accuracy because a healthy sample can be obtained by simply casting molten slag and cooling it by coating the sample container with a metal film. In addition, sample preparation, which conventionally required a great deal of effort and time, can be easily performed in about 1/10th the time, and the costs required can be significantly reduced.
図面は本考案に係る鉱滓試料採取容器の実施例
を示し、第１図、第２図はその断面図、第３図は
得られた試料の斜視図である。
符号１は試料容器、２は金属膜、３は黒鉛層、
４は試料、５は分析面である。
The drawings show an embodiment of the slag sample collection container according to the present invention, and FIGS. 1 and 2 are sectional views thereof, and FIG. 3 is a perspective view of the obtained sample. 1 is a sample container, 2 is a metal film, 3 is a graphite layer,
4 is a sample, and 5 is an analysis surface.
Claims (1)
に成型した試料容器の内面に、高温の鉱滓と反
応し難い性質の金属膜を試料容器の多孔性を損
わないようにコーテイングしたことを特徴とす
る鉱滓試料採取容器。 ２ 前記試料容器の内面と前記金属膜との間に黒
鉛層を介在した実用新案登録請求の範囲第１項
に記載の鉱滓試料採取容器。[Claims for Utility Model Registration] 1. On the inner surface of a sample container formed into a concave shape using a porous material with low thermal conductivity, a metal film that does not easily react with high-temperature slag is placed on the inner surface of the sample container to reduce the porosity of the sample container. A slag sample collection container characterized by being coated to prevent the occurrence of slag. 2. The slag sample collection container according to claim 1, wherein a graphite layer is interposed between the inner surface of the sample container and the metal film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1877584U JPS60131856U (en) | 1984-02-13 | 1984-02-13 | Mine slag sample collection container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1877584U JPS60131856U (en) | 1984-02-13 | 1984-02-13 | Mine slag sample collection container |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60131856U JPS60131856U (en) | 1985-09-03 |
| JPH0225168Y2 true JPH0225168Y2 (en) | 1990-07-11 |
Family
ID=30507724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1877584U Granted JPS60131856U (en) | 1984-02-13 | 1984-02-13 | Mine slag sample collection container |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60131856U (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4009167A1 (en) * | 1990-03-22 | 1991-09-26 | Electro Nite | SAMPLER FOR METAL MELTING |
-
1984
- 1984-02-13 JP JP1877584U patent/JPS60131856U/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60131856U (en) | 1985-09-03 |
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