JPH02250814A - First liquid of cold-wave lotion - Google Patents
First liquid of cold-wave lotionInfo
- Publication number
- JPH02250814A JPH02250814A JP7150589A JP7150589A JPH02250814A JP H02250814 A JPH02250814 A JP H02250814A JP 7150589 A JP7150589 A JP 7150589A JP 7150589 A JP7150589 A JP 7150589A JP H02250814 A JPH02250814 A JP H02250814A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- perm
- amino
- protein
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 239000006210 lotion Substances 0.000 title abstract 2
- 229920001184 polypeptide Polymers 0.000 claims abstract description 14
- 102000004196 processed proteins & peptides Human genes 0.000 claims abstract description 14
- 108090000765 processed proteins & peptides Proteins 0.000 claims abstract description 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 239000003531 protein hydrolysate Substances 0.000 claims description 10
- 108010009736 Protein Hydrolysates Proteins 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 abstract description 9
- 102000004169 proteins and genes Human genes 0.000 abstract description 9
- 102000011782 Keratins Human genes 0.000 abstract description 4
- 108010076876 Keratins Proteins 0.000 abstract description 4
- 102000008186 Collagen Human genes 0.000 abstract description 3
- 108010035532 Collagen Proteins 0.000 abstract description 3
- 229920001436 collagen Polymers 0.000 abstract description 3
- 239000002932 luster Substances 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract description 2
- 239000003755 preservative agent Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003700 hair damage Effects 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000003699 hair surface Effects 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000003719 hair strength Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明はパーマ第一液に係り、その目的はパーマネン
トウェーブ処理に使用するパーマ第一液であって、毛髪
の損傷劣化抑制、良好な感触と光沢を付与することがで
きるパーマ第一液の提供にある。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a perm first solution, and its purpose is to provide a perm first solution used in permanent waving, which suppresses hair damage and deterioration and provides a good feel. The purpose of the present invention is to provide a first perm solution that can impart luster and luster.
（従来の技術）
パーマネントウェーブ処理は毛髪主として頭髪にウェー
ブを付与するために行い、通常コールドパーマ処理が主
流でその際使用される薬剤の概要は毛髪のシスチン結合
を切断する還元剤たるパーマ第一液と、ウェーブが付与
された後毛髪のシスチン結合を修復する酸化剤たるパー
マ第二液とからなる。(Prior art) Permanent wave treatment is mainly performed to give waves to the hair, and cold perm treatment is the mainstream. It consists of a perm liquid and a second perm liquid that is an oxidizing agent that repairs cystine bonds in the hair after it has been waved.
（発明が解決しようとする課題）
パーマ第一液処理は、毛髪のタンパク変性や毛髪中のタ
ンパク流出を引き起し易く、その繰り返しによって毛髪
の劣化を招き、延いては枝毛や製電の原因となる。(Problems to be Solved by the Invention) The first liquid perm treatment tends to cause protein denaturation and protein leakage in the hair, and repeated deterioration of the hair leads to split ends and electrical problems. Cause.
しかしながら、頭髪パーマ処理時に同時に毛髪損傷の抑
制や毛髪劣化を抑制できるパーマ第一液は現在のところ
存在せず、その開発が要望されていた。However, there is currently no first perm solution that can simultaneously suppress hair damage and hair deterioration during hair perm treatment, and there has been a demand for the development of such a solution.
（課題を解決するための手段）
以上のような事情に照らしこの発明は、パーマ第一液で
あって、しかも毛髪を損傷することがないパーマ第一液
を創出せんと完成されたもので、即ちこの発明は、タン
パク質加水分解物、ポリペプチド、またはそれらの誘導
体の内から選択される一種以上で平均分子量が２００乃
至４０００である成分と、アミノ変性シリコン（式（１
））とを必須成分としてなるパーマ第一液を提供するこ
とにより上記従来の欠点を悉く解消することに成功した
。(Means for Solving the Problems) In light of the above circumstances, this invention was completed with the aim of creating a first perm solution that does not damage hair. That is, the present invention provides a component having an average molecular weight of 200 to 4000 selected from protein hydrolysates, polypeptides, or derivatives thereof, and an amino-modified silicone (formula (1)
))) By providing a first perm solution containing as an essential component, we have succeeded in eliminating all of the above-mentioned conventional drawbacks.
（以下余白）
ＮＨ−（ＣＨ２’） 、 −ＮＨ＊
但し、Ｘ ： １０〜５００ 、 Ｙ ： １〜３
０、ｎ：ｌ〜１０、ｍ： ｌ〜ｌＯである。(Left below) NH-(CH2'), -NH* However, X: 10-500, Y: 1-3
0, n: 1 to 10, m: 1 to 1O.
（発明の構成）
この発明において使用するタンパク質加水分解物、ポリ
ペプチド、またはそれらの誘導体の内から選択される一
種以上で平均分子量が２００乃至４０００である成分は
、還元処理する際に、毛髪に付着吸収されて、化学処理
に依って損傷流出したタンパク質を補い、また毛髪の表
面を保護する作用を有する。(Structure of the Invention) The component selected from protein hydrolysates, polypeptides, and derivatives thereof used in this invention and having an average molecular weight of 200 to 4000 is a component that is used in the hair during reduction treatment. It is adhered and absorbed and has the effect of replenishing proteins damaged and washed out due to chemical treatment and protecting the hair surface.
この発明において使用するタンパク質加水分解物、ポリ
ペプチド、またはそれらの誘導体の内から選択される一
種以上で平均分子量が２００乃至４０００である成分と
は、ケラチン、コラーゲン、シルク等のタンパク質の加
水分解物或いはその誘導体である場合や、これらのタン
パク質の加水分解物から精製したポリペプチド、或いは
これら精製したポリペプチドの誘導体を云う。The component used in this invention, which is one or more selected from protein hydrolysates, polypeptides, and derivatives thereof and has an average molecular weight of 200 to 4,000, refers to hydrolysates of proteins such as keratin, collagen, and silk. or derivatives thereof, polypeptides purified from hydrolysates of these proteins, or derivatives of these purified polypeptides.
タンパク質加水分解物、ポリペプチド、またはそれらの
誘導体は、ケラチン、コラーゲンの加水分解物あるいは
アミノ酸以外のものを含まない純粋のポリペプチド、及
びそれらの誘導体で、分子量が４０００以下で２００以
上の程度のもの、より望ましくは分子量が２００−１０
００程度のものが好ましく使用できる。Protein hydrolysates, polypeptides, or their derivatives are keratin, collagen hydrolysates, or pure polypeptides that do not contain anything other than amino acids, and their derivatives, and have a molecular weight of 4,000 or less and a molecular weight of 200 or more. more preferably a molecular weight of 200-10
00 can be preferably used.
その理由は、分子量が小さいほど毛髪に吸収されやすい
が、分子量２００以下になると吸収されたものが容易に
流出するからであり、また分子量４０００以上のものが
付着した場合はゴワついた感触を与えるからである。The reason for this is that the smaller the molecular weight, the easier it is to be absorbed into the hair, but if the molecular weight is less than 200, the absorbed material will easily flow out, and if the molecular weight is 4000 or more, it will give a stiff feel. It is from.
この発明で使用するアミノ変性シリコンとは化学式（１
）で示されるアミノ酸で変性されたシリコンであって、
分子量が５０００〜１０００００の重合体であるアミノ
変性シリコン樹脂である。The amino-modified silicon used in this invention has the chemical formula (1
) silicon modified with amino acids represented by
It is an amino-modified silicone resin that is a polymer with a molecular weight of 5,000 to 100,000.
このアミノ変性シリコンはアミノ分岐の部分が毛髪に対
する親和力があり毛髪に吸着し易＜、−方シリコン樹脂
の部分が毛髪表面で膜をつくり毛髪を保護する。The amino-branched portion of this amino-modified silicone has an affinity for hair and is easily adsorbed to the hair, while the silicone resin portion forms a film on the hair surface to protect the hair.
ＮＨ−（ＣＨ２）、→Ｈ２
但し、ｘ ：ｌＯ〜５００、Ｙ ：１〜３０１ｎ ：１
〜１０、ｍ： １〜１０である。NH-(CH2), →H2 However, x: 1O~500, Y: 1~301n: 1
~10, m: 1-10.
この発明で使用するアミノ変性シリコンとしてはジメチ
ルシロキサン−γ−（β−アミノエチル）アミノプロピ
ルシロキサン共重合体を好適に使用することができ、こ
れらは通常エマルジョン化されている。As the amino-modified silicone used in this invention, dimethylsiloxane-γ-(β-aminoethyl)aminopropylsiloxane copolymer can be suitably used, and these are usually emulsified.
このようなアミノ変性シリコンは、パーマ第一液中に０
．１〜５重量（１％）配合すればよく、タンパク質加水
分解物は０．１〜１０重量（Ｘ）配合すればよい。Such amino-modified silicone contains 0% in the first perm solution.
．． 1 to 5 weight (1%) may be blended, and the protein hydrolyzate may be blended in 0.1 to 10 weight (X).
この発明においては、この弁明の目的を損なわない程度
で、通常のパーマ第一液組成である香料、防腐剤、アミ
ン、粘調剤等を添加配合してもよい。In this invention, fragrances, preservatives, amines, viscosity agents, etc., which are the usual compositions of the first permanent perm liquid, may be added to the extent that the purpose of this explanation is not impaired.
以下この発明の実施例及び比較例を示し、この発明の効
果をより一層明確なものとする。Examples and comparative examples of the present invention will be shown below to further clarify the effects of the present invention.
（実施例１〜５及び比較例１〜３）
次の第１表に組成を示すパーマ第一液をそれぞれ調製し
た。(Examples 1 to 5 and Comparative Examples 1 to 3) Perm first liquids whose compositions are shown in Table 1 below were prepared.
（以下余白）
実
施
例（第１表−１）
（数字は重量部、残部は精製水、香料等）※アンモニア
水（２８％）によりｐＨ９，０に調整した。(The following is a blank space) Examples (Table 1-1) (The numbers are parts by weight, the remainder is purified water, perfume, etc.) *The pH was adjusted to 9.0 with aqueous ammonia (28%).
※タンパク質加水分解物としては、加水分解ケラチン（
平均分子量４００）液である■酸相化成製ブロモイスＷ
Ｋを純分換算して使用した。*As a protein hydrolyzate, hydrolyzed keratin (
Bromois W manufactured by Acid Phase Chemicals, which is a liquid with an average molecular weight of 400
K was converted into pure content and used.
※アミノ変性シリコンとしては、そのエマルジョン溶液
であるトーレシリコン■製アモジメチコーンエマルジョ
ン（８Ｍ８７０２Ｃ）を純分換算して使用した。*As the amino-modified silicone, its emulsion solution, Amodimethicone Emulsion (8M8702C) manufactured by Toray Silicone ■, was used in terms of purity.
※比較例１〜３のパーマ第一液は、タンパク質加水分解
物、アミノ変性シリコン以外の配合組成物は実施例１〜
５と同一配合組成とした。*The perm first solution of Comparative Examples 1 to 3 is a protein hydrolyzate, and the blended compositions other than amino-modified silicone are those of Examples 1 to 3.
The composition was the same as that of No. 5.
（試験例１）
４０人（各群５人）の化粧年令の女性（１８オ〜６０才
）に実施例１〜５及び比較例１〜３で得たパーマ第一液
をそれぞれ使用して、通常のパーマ処理との相異を問診
で調べた。(Test Example 1) The first perm solution obtained in Examples 1 to 5 and Comparative Examples 1 to 3 was applied to 40 women (18 to 60 years old) of makeup age (5 in each group). We investigated the differences from regular perm treatment through interviews.
尚、パーマ第二液としては、臭素酸ナトリウム５ｘ液を
使用した。Note that a 5x sodium bromate solution was used as the second perm solution.
結果は、Ｏ・・・いつもより良い、Δ・・・いつもと変
わらない、×・・・いつもより悪い、の王道りに評価し
た。尚、試験は次の項目について行った。The results were rated according to the standard: O: better than usual, Δ: same as usual, ×: worse than usual. The test was conducted on the following items.
■・・・毛髪のツヤ、■・・・毛髪のしなやかさ、の毛
触り
結果を下記第２表にまとめて示す。The hair texture results of ■...hair gloss and ■...hair suppleness are summarized in Table 2 below.
実 施 例（第２表−１）（人）
コシ等
（注）実施例５のパーマ第１液はギルビー法による測定
の結果ウェーブ効率が若干おちた。Examples (Table 2-1) (person) Kosi, etc. (Note) The wave efficiency of the first perm solution of Example 5 was slightly decreased as a result of measurement by the Gilby method.
比較例３で得たパーマ第一液で上記処理を５回反復した
試験（Ｂ）とをそれぞれ行った。A test (B) was conducted in which the above treatment was repeated five times using the first perm solution obtained in Comparative Example 3.
各々の処理後の毛髪、処理前の毛髪をそれぞれランダム
に毛束から毛を抜取り、レオメータ−に供してその２ａ
ｎの長さの毛髪を切断するに要する重さを測定した。結
果は１０本の平均値を採った。Hair after each treatment and hair before treatment are randomly extracted from the hair bundles and subjected to a rheometer.
The weight required to cut hair of length n was measured. The results were the average value of 10 samples.
第３表に結果を示す。Table 3 shows the results.
第 ３ 表 （ｇ）
（試験例２）
前記実施例３で得たパーマ第一液及び前記試験例１で使
用したパーマ第二液を使用して次の髪の強度試験を行っ
た。Table 3 (g) (Test Example 2) The following hair strength test was conducted using the first perm liquid obtained in Example 3 and the second perm liquid used in Test Example 1.
Ｌｏａｎの長さで１ｇの毛束を、パーマ処理してその後
、４０℃の温水で水洗して、乾燥した。A 1 g long hair bundle was permed, washed with 40° C. warm water, and dried.
ニの処理を連続して５回反復した試験（Ａ）と、（発明
の効果）
以上詳述した如く、この発明に係るパーマ第一液は、タ
ンパク質加水分解物、ポリペプチド、ポリペプチド誘導
体の内から選択される一種以上で平均分子量が２００乃
至４０００である成分と、アミノ変性シリコン（式（１
））とを必須成分としてなるパーマ第一液であるから、
パーマネントウェーブ処理に使用することにより、毛髪
の損傷劣化抑制、良好な感触と光沢を付与することがで
きるという効果を奏する。Test (A) in which the treatment (d) was repeated five times in succession and (Effects of the invention) As detailed above, the first perm solution according to the present invention contains protein hydrolysates, polypeptides, and polypeptide derivatives. One or more components selected from the following and having an average molecular weight of 200 to 4000, and an amino-modified silicone (formula (1)
)) as the essential ingredients,
When used in permanent wave treatment, it has the effect of suppressing hair damage and deterioration and imparting good texture and gloss.
ＮＨ−（ＣＨ，）ａｔ −Ｎｌ２
但し、ｘ：１０〜５００、Ｙ：１〜３０、ｎ：１〜１０
、ｍ： １〜１０である。NH-(CH,)at-Nl2 However, x: 10-500, Y: 1-30, n: 1-10
, m: 1-10.
Claims (3)
れらの誘導体の内から選択される一種以上で平均分子量
が２００乃至４０００である成分と、アミノ変性シリコ
ン（式（１））とを必須成分としてなるパーマ第一液。 ▲数式、化学式、表等があります▼（１） 但し、Ｘ：１０〜５００、Ｙ：１〜３０、ｎ：１〜１０
、ｍ：１〜１０である。(1) Consisting of one or more components selected from protein hydrolysates, polypeptides, or derivatives thereof and having an average molecular weight of 200 to 4,000, and amino-modified silicone (formula (1)) as essential components. Perm first solution. ▲There are mathematical formulas, chemical formulas, tables, etc.▼(1) However, X: 10-500, Y: 1-30, n: 1-10
, m: 1-10.
れらの誘導体の内から選択される一種以上で平均分子量
が２００乃至４０００である成分が０．１〜１０重量％
配合されてなる請求項第（１）項記載のパーマ第一液。(2) 0.1 to 10% by weight of one or more components selected from protein hydrolysates, polypeptides, or derivatives thereof with an average molecular weight of 200 to 4000;
The first perm liquid according to claim (1).
されてなる請求項第（１）項記載のパーマ第一液。(3) The first perm liquid according to claim (1), which contains 0.1 to 5.0% by weight of amino-modified silicone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7150589A JPH02250814A (en) | 1989-03-23 | 1989-03-23 | First liquid of cold-wave lotion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7150589A JPH02250814A (en) | 1989-03-23 | 1989-03-23 | First liquid of cold-wave lotion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02250814A true JPH02250814A (en) | 1990-10-08 |
Family
ID=13462608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7150589A Pending JPH02250814A (en) | 1989-03-23 | 1989-03-23 | First liquid of cold-wave lotion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02250814A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1247518A1 (en) * | 2001-04-06 | 2002-10-09 | L'oreal | Permanent hair-waving process using aminosilicones |
| KR100460197B1 (en) * | 1997-10-08 | 2005-08-17 | 사랑새화장품주식회사 | Composition of the first liquid of permanent wave lotion |
| KR100678646B1 (en) * | 2005-01-14 | 2007-02-02 | 주식회사 일진코스메틱 | Permanent wave composition and method for permanent wave using it |
| JP2007084491A (en) * | 2005-09-22 | 2007-04-05 | Takara Belmont Co Ltd | Method for permanent waving treatment and permanent waving composition |
| WO2014000951A3 (en) * | 2012-06-29 | 2014-07-10 | Henkel Ag & Co. Kgaa | Method for chemical smoothing of human hairs ii |
| WO2014000952A3 (en) * | 2012-06-29 | 2014-07-10 | Henkel Ag & Co. Kgaa | Method for chemical smoothing of human hairs i |
| EP2687265A3 (en) * | 2012-05-29 | 2014-12-17 | Henkel AG&Co. KGAA | Method for reshaping fibres containing keratin |
| EP2594256A3 (en) * | 2011-09-02 | 2015-08-12 | Henkel AG&Co. KGAA | Pre-treatment agent for keratinous fibres |
-
1989
- 1989-03-23 JP JP7150589A patent/JPH02250814A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100460197B1 (en) * | 1997-10-08 | 2005-08-17 | 사랑새화장품주식회사 | Composition of the first liquid of permanent wave lotion |
| EP1247518A1 (en) * | 2001-04-06 | 2002-10-09 | L'oreal | Permanent hair-waving process using aminosilicones |
| FR2823110A1 (en) * | 2001-04-06 | 2002-10-11 | Oreal | PROCESS FOR PERMANENT DEFORMATION OF HAIR USING AMINO SILICONES |
| KR100678646B1 (en) * | 2005-01-14 | 2007-02-02 | 주식회사 일진코스메틱 | Permanent wave composition and method for permanent wave using it |
| JP2007084491A (en) * | 2005-09-22 | 2007-04-05 | Takara Belmont Co Ltd | Method for permanent waving treatment and permanent waving composition |
| EP2594256A3 (en) * | 2011-09-02 | 2015-08-12 | Henkel AG&Co. KGAA | Pre-treatment agent for keratinous fibres |
| EP2687265A3 (en) * | 2012-05-29 | 2014-12-17 | Henkel AG&Co. KGAA | Method for reshaping fibres containing keratin |
| WO2014000951A3 (en) * | 2012-06-29 | 2014-07-10 | Henkel Ag & Co. Kgaa | Method for chemical smoothing of human hairs ii |
| WO2014000952A3 (en) * | 2012-06-29 | 2014-07-10 | Henkel Ag & Co. Kgaa | Method for chemical smoothing of human hairs i |
| US9421160B2 (en) | 2012-06-29 | 2016-08-23 | Henkel Ag & Co. Kgaa | Method for chemical smoothing of human hairs |
| EP2866773B1 (en) | 2012-06-29 | 2017-08-09 | Henkel AG & Co. KGaA | Method for chemical smoothing of human hairs ii |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6740317B1 (en) | Hair care compositions and improved hair quality | |
| BR0204982A (en) | Cosmetic compositions containing at least one amino silicone and a conditioning agent, use of a composition, use of at least one amino silicone and treatment process, and enhancement of the remaining effects of the conditioning effects of a cosmetic composition | |
| JP2011502171A (en) | Keratin derivative and method for producing the same | |
| EP0699431A1 (en) | Base material for cosmetics and uses of the same | |
| WO2012140725A1 (en) | Cosmetic base material, and cosmetic containing said cosmetic base material | |
| JP2005008632A (en) | Hair treatment composition and hair after-treatment composition containing alkylguanidine compound as activator, used for protecting hair from damage caused by chemical treatment and restoring hair already damaged | |
| US6123934A (en) | Hair cosmetic composition | |
| JPH02250814A (en) | First liquid of cold-wave lotion | |
| JP2011088828A (en) | Cosmetic base and cosmetic containing the cosmetic base | |
| JP2000302648A (en) | Hair cosmetic | |
| JP2000302647A (en) | Hair treatment | |
| JPH0585921A (en) | Hair treating agent | |
| JP2009161519A (en) | Cosmetic base material and hair cosmetic | |
| JPH02212410A (en) | Composition agent for conditioning alkali-treated hair | |
| JP4824507B2 (en) | Straight perm agent | |
| JP3270776B2 (en) | Hair cosmetics | |
| KR101989888B1 (en) | A hair care composition for repairing a damaged hair containing a cystine-silicon copolymer and a hair dye comprising the same | |
| KR100523371B1 (en) | Hair cosmetic compositions including rhodiola radics cortex extract for protection of hair and repair of hair damage | |
| JPH10120533A (en) | Hair treatment composition of two-agent type | |
| JPS59101414A (en) | Hair-protecting cosmetic composition | |
| JP2010215540A (en) | Straight hair-forming cosmetic | |
| JP3446977B2 (en) | Hair dye | |
| JP5243024B2 (en) | Hair cosmetics | |
| JPH08157340A (en) | Hair cosmetic | |
| JP3979496B2 (en) | Hair protectant |