JPH02249622A - Heatproof blow bottle - Google Patents
Heatproof blow bottleInfo
- Publication number
- JPH02249622A JPH02249622A JP1072748A JP7274889A JPH02249622A JP H02249622 A JPH02249622 A JP H02249622A JP 1072748 A JP1072748 A JP 1072748A JP 7274889 A JP7274889 A JP 7274889A JP H02249622 A JPH02249622 A JP H02249622A
- Authority
- JP
- Japan
- Prior art keywords
- polyethylene terephthalate
- terephthalate resin
- layer
- bottle
- superior
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 23
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 22
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 22
- 229920006134 semi-aromatic non-crystalline polyamide resin Polymers 0.000 claims abstract description 9
- 239000002356 single layer Substances 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 125000003118 aryl group Chemical group 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 229920006015 heat resistant resin Polymers 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0223—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by shape
- B65D1/0261—Bottom construction
- B65D1/0276—Bottom construction having a continuous contact surface, e.g. Champagne-type bottom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
- B65D1/0215—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features multilayered
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0223—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by shape
- B65D1/023—Neck construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/26—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at body portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3008—Preforms or parisons made of several components at neck portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3012—Preforms or parisons made of several components at flange portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/302—Preforms or parisons made of several components at bottom portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Laminated Bodies (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、主としてポリエチレンテレフタレー系樹脂か
らなる耐熱ブローボトルに関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a heat-resistant blow bottle mainly made of polyethylene terephthalate resin.
(従来の技術)
従来、ポリエチレンテレフタレート系樹脂からなるブロ
ーボトルは透明性、物理的強度等に優れるため各種飲料
等の用途に広く使われている。(Prior Art) Blow bottles made of polyethylene terephthalate resin have been widely used for various beverages because of their excellent transparency and physical strength.
そしてきびしい密封性を要求される口栓部の耐熱性能を
向上するために
延伸されない口栓部のみを結晶化させて白化させる、
ボトル全体を耐熱性樹脂層を含む多層構造にする、
等の工夫がなされた耐熱ブローボトルが供給されていた
。In order to improve the heat resistance of the spout, which requires tight sealing, we have taken measures such as crystallizing and whitening only the spout that is not stretched, and making the entire bottle a multilayer structure that includes a heat-resistant resin layer. A heat-resistant blow bottle was supplied.
(発明が解決しようとする課題)
上記従来の耐熱ブローボトルは、口栓部を白化したもの
は、加工に手間がかかる上、外観が白く透明性が劣るし
、耐熱性樹脂層を含む多層構造のものは、高価な耐熱性
樹脂を大量に使用するのでコストがかさむという問題が
あった。(Problems to be Solved by the Invention) The above-mentioned conventional heat-resistant blow bottle with a whitened spout requires a lot of processing time, has a white appearance and poor transparency, and has a multilayer structure including a heat-resistant resin layer. The problem with this method is that it is expensive because it uses a large amount of expensive heat-resistant resin.
(課題を解決するための手段) 以下、添付した図面に基づき説明する。(Means for solving problems) The following description will be made based on the attached drawings.
第1図は本発明の耐熱ブローボトルの一例を示す正面断
面図であり、第2図は第1図の耐熱ブローボトルを製造
する装置の一例を示す断面図である。FIG. 1 is a front sectional view showing an example of a heat-resistant blow bottle of the present invention, and FIG. 2 is a sectional view showing an example of an apparatus for manufacturing the heat-resistant blow bottle of FIG. 1.
本発明は、胴体部1がポリエチレンテレフタレ−ト系樹
脂の単層構造を有し、口栓部2が外R3および内層4が
ポリエチレンテレフタレート系樹脂であって中間層5が
半芳香族アモルファスポリアミド樹脂からなる積層構造
を有し、前記胴体部1を配向結晶させたことを特徴とす
る耐熱ブローボトルである。In the present invention, the body part 1 has a single layer structure of polyethylene terephthalate resin, the outer layer 3 and the inner layer 4 of the spout part 2 are polyethylene terephthalate resin, and the intermediate layer 5 is made of semi-aromatic amorphous polyamide. This heat-resistant blow bottle has a laminated structure made of resin, and is characterized in that the body portion 1 is oriented and crystallized.
本発明において胴体部1の全厚さにわたって用いられ、
口栓部2の外R3、内層4に用いられるポリエチレンテ
レフタレート系樹脂は、エチレンテレフタレート反復単
位を主体とし、その物性を損わない範囲で他の共重合成
分を少量含有する共重合体であってもよい。In the present invention, it is used throughout the entire thickness of the body part 1,
The polyethylene terephthalate resin used for the outer R3 and inner layer 4 of the spout part 2 is a copolymer mainly composed of ethylene terephthalate repeating units and containing a small amount of other copolymer components within the range that does not impair its physical properties. Good too.
本発明において、口栓部2の中間R5に用いられる半芳
香族アモルファスポリアミド樹脂は、アミン成分をヘキ
サメチレンジアミン等の脂肪族ジアミンとし、酸成分を
イソフタル酸、テレフタル酸、あるいはこれらの混合物
等の芳香族ジカルボン酸として共重合したポリアミドで
ある。In the present invention, the semi-aromatic amorphous polyamide resin used for the middle R5 of the plug portion 2 has an amine component such as an aliphatic diamine such as hexamethylene diamine, and an acid component such as isophthalic acid, terephthalic acid, or a mixture thereof. It is a polyamide copolymerized as an aromatic dicarboxylic acid.
口栓部2は外層3、内層4ともポリエチレンテレフタレ
ート樹脂からなるので透明性、衛生性に優れる。この部
分は延伸されず結晶化により白化しやすいので、透明性
を保つためには結晶化度の程度は密度1.347g/c
m3以下に保つのが好ましい。また、中間R5は耐熱性
、透明性、ポリエチレンテレフタレート系樹脂との相溶
性に優れた半芳香族アモルファスポリアミド樹脂からな
るので、口栓部のポリエチレンテレフタレート系樹脂を
よく補強して耐熱性を高めることができる。Since both the outer layer 3 and the inner layer 4 of the spout portion 2 are made of polyethylene terephthalate resin, it has excellent transparency and hygiene. This part is not stretched and tends to whiten due to crystallization, so in order to maintain transparency, the degree of crystallinity must be 1.347 g/c.
It is preferable to keep it below m3. In addition, the intermediate R5 is made of semi-aromatic amorphous polyamide resin that has excellent heat resistance, transparency, and compatibility with polyethylene terephthalate resin, so the polyethylene terephthalate resin in the spout part can be well reinforced to increase heat resistance. I can do it.
なおこの中間層5は延伸度合の少ない肩部21まで伸ば
してもよい、そしてこの中間M5の厚さとしては、全体
の厚さの5〜90%とするのが好ましい。Note that this intermediate layer 5 may be extended to the shoulder portion 21 where the degree of stretching is low, and the thickness of this intermediate layer M5 is preferably 5 to 90% of the total thickness.
胴体部1はポリエチレンテレフタレート系樹脂の単層構
成なので延伸性に優れ、しかも配向結晶化させているの
で耐熱性に優れている。結晶化の程度を密度が1.37
58/cm3以上になるようにするとさらに耐熱性に優
れる。延伸倍率は面積が6倍以上になるようにすれば、
結晶化度を高めても透明性が良好に保たれるので好まし
い。The body part 1 has a single layer structure of polyethylene terephthalate resin, so it has excellent stretchability, and since it is oriented and crystallized, it has excellent heat resistance. The degree of crystallization is determined by the density of 1.37
If it is set to 58/cm3 or more, the heat resistance will be even better. If the stretching ratio is set so that the area is 6 times or more,
This is preferable because transparency can be maintained well even if the degree of crystallinity is increased.
延伸度合が少なく、耐熱性の劣る底部6も、口栓部と同
様このm層構造として熱による変形を防止してもよい。The bottom portion 6, which has a low degree of stretching and poor heat resistance, may also have this m-layer structure to prevent deformation due to heat, similar to the spout portion.
本発明の耐熱ブローボトルを製造するなめには、まず第
2図に示すような射出成形装置により、試験管状のパリ
ソンをつくり、これを延伸ブロー成形してから熱処理す
ることにより、胴体部1を配向結晶化させて、たとえば
結晶化度を密度1.375g/cm3以上にすればよい
。To manufacture the heat-resistant blow bottle of the present invention, first, a test tube-shaped parison is made using an injection molding apparatus as shown in FIG. Oriented crystallization may be performed to, for example, make the degree of crystallinity to a density of 1.375 g/cm 3 or more.
すなわち、割型7とコア型71にかこまれたキャビティ
ー中に射出ノズル8から、まずポリエチレンテレフタレ
ート系樹脂11を引続き半芳香族アモルファスポリアミ
ド樹脂51を共射出して口栓部2のたとえば3層の積層
構造を形成し、続いて半芳香族アモルファスポリアミド
樹脂51を止めてポリエチレンテレフタレート系樹脂1
1のみを射出して胴体部1の単層構造を形成する。さら
に、再び、半芳香族アモルファスポリアミド樹脂51を
共射出して底部6の3屑の積層構造を形成する。That is, first, a polyethylene terephthalate resin 11 and then a semi-aromatic amorphous polyamide resin 51 are co-injected from an injection nozzle 8 into a cavity surrounded by a split mold 7 and a core mold 71 to form, for example, three layers of the spout part 2. Then, the semi-aromatic amorphous polyamide resin 51 is stopped and the polyethylene terephthalate resin 1 is formed.
1 is injected to form a single layer structure of the body part 1. Furthermore, the semi-aromatic amorphous polyamide resin 51 is again co-injected to form the laminate structure of the three pieces of the bottom part 6.
こうして得られたパリソンをブロー成形装置に移し、ポ
リエチレンテレフタレート系樹脂の結晶化温度以上、1
40℃以下に加熱された加熱型中で面積倍率6〜14倍
にブロー延伸して所定時間保持して熱処理し、型を冷却
したり、ボトル内部に冷媒を吹き込んだりして冷却して
本発明の耐熱ブローボトルが得られる。The parison thus obtained was transferred to a blow molding machine, and heated for 1 hour above the crystallization temperature of the polyethylene terephthalate resin.
The present invention is carried out by blow-stretching to an area magnification of 6 to 14 times in a heating mold heated to 40°C or less, holding it for a predetermined period of time for heat treatment, and cooling the mold or by blowing a refrigerant into the bottle. A heat-resistant blow bottle is obtained.
また得られたパリソンを、ポリエチレンテレフタレート
系樹脂の結晶化温度以上、融点−20度以下に加熱され
た加熱型中で面積倍率6〜14倍にブロー延伸して所定
時間保持して熱処理し得られた中間体を、加熱型に対す
る内容積の割合が75〜115%である最終型内に移し
て再延伸することにより冷却を最終型で効率よく行なっ
て本発明の耐熱ブローボトルが得られる。Further, the obtained parison is blow-stretched to an area magnification of 6 to 14 times in a heating mold heated to a temperature above the crystallization temperature of the polyethylene terephthalate resin and below the melting point of -20 degrees, and is heat-treated by holding the parison for a predetermined time. The obtained intermediate is transferred into a final mold having an internal volume ratio of 75 to 115% with respect to the heating mold and re-stretched, thereby efficiently cooling the final mold to obtain the heat-resistant blow bottle of the present invention.
(発明の効果)
以上説明したように、本発明は胴体部がポリエチレンテ
レフタレート系樹脂の単層構造を有し、口栓部が外層お
よび内層がポリエチレンテレフタレート系樹脂であって
中間層が半芳香族アモルファスポリアミド樹脂からなる
積層構造を有し、前記胴体部を配向結晶化したことを特
徴とする耐熱ブローボトルであるので、特に密封性を要
求される口栓部の耐熱性が優れ、口栓部から胴体部に至
るまで透明性に優れた耐熱ブローボトルが得られるとい
う効果を有する。(Effects of the Invention) As explained above, in the present invention, the body part has a single layer structure of polyethylene terephthalate resin, the outer layer and the inner layer of the spout part are made of polyethylene terephthalate resin, and the middle layer is semi-aromatic. This heat-resistant blow bottle has a laminated structure made of amorphous polyamide resin, and is characterized by having the body portion oriented and crystallized, so the spout portion, which requires particularly tight sealing, has excellent heat resistance. This has the effect that a heat-resistant blow bottle with excellent transparency from the to the body can be obtained.
第1図は本発明の耐熱ブローボトルの一例を示す正面断
面図であり、第2図は第1図の耐熱ブローボトルを製造
する装置の一例を示す断面図である。
1・・・・・・胴体部 2・・・・・・口栓部3
・・・・・・外層 4・・・・・・内層5・・・・
・・中間層FIG. 1 is a front sectional view showing an example of a heat-resistant blow bottle of the present invention, and FIG. 2 is a sectional view showing an example of an apparatus for manufacturing the heat-resistant blow bottle of FIG. 1. 1... Body part 2... Spout part 3
...Outer layer 4...Inner layer 5...
・Middle class
Claims (1)
を有し、口栓部が外層および内層がポリエチレンテレフ
タレート系樹脂であって中間層が半芳香族アモルファス
ポリアミド樹脂からなる積層構造を有し、前記胴体部を
配向結晶させたことを特徴とする耐熱ブローボトル。The body has a single-layer structure made of polyethylene terephthalate resin, the spout has a laminated structure in which an outer layer and an inner layer are made of polyethylene terephthalate resin, and an intermediate layer is made of semi-aromatic amorphous polyamide resin, A heat-resistant blow bottle characterized by oriented crystals.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7274889A JP2730157B2 (en) | 1989-03-24 | 1989-03-24 | Heat resistant blow bottle |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7274889A JP2730157B2 (en) | 1989-03-24 | 1989-03-24 | Heat resistant blow bottle |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02249622A true JPH02249622A (en) | 1990-10-05 |
JP2730157B2 JP2730157B2 (en) | 1998-03-25 |
Family
ID=13498286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7274889A Expired - Lifetime JP2730157B2 (en) | 1989-03-24 | 1989-03-24 | Heat resistant blow bottle |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2730157B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0699996A (en) * | 1992-09-22 | 1994-04-12 | Toyo Seikan Kaisha Ltd | Chemical resistant squeezing container |
JP2008094454A (en) * | 2006-10-13 | 2008-04-24 | Dainippon Printing Co Ltd | Plastic container with gas barrier layer |
EP2698321A1 (en) * | 2012-08-16 | 2014-02-19 | INOTECH Kunststofftechnik GmbH | Preform used for the production of a container, and container to hold a food product |
-
1989
- 1989-03-24 JP JP7274889A patent/JP2730157B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0699996A (en) * | 1992-09-22 | 1994-04-12 | Toyo Seikan Kaisha Ltd | Chemical resistant squeezing container |
JP2008094454A (en) * | 2006-10-13 | 2008-04-24 | Dainippon Printing Co Ltd | Plastic container with gas barrier layer |
EP2698321A1 (en) * | 2012-08-16 | 2014-02-19 | INOTECH Kunststofftechnik GmbH | Preform used for the production of a container, and container to hold a food product |
Also Published As
Publication number | Publication date |
---|---|
JP2730157B2 (en) | 1998-03-25 |
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