JPH02247114A - Shampoo composition - Google Patents
Shampoo compositionInfo
- Publication number
- JPH02247114A JPH02247114A JP6800089A JP6800089A JPH02247114A JP H02247114 A JPH02247114 A JP H02247114A JP 6800089 A JP6800089 A JP 6800089A JP 6800089 A JP6800089 A JP 6800089A JP H02247114 A JPH02247114 A JP H02247114A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- fatty acid
- general formula
- expressed
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000002453 shampoo Substances 0.000 title claims abstract description 17
- 150000004665 fatty acids Chemical group 0.000 claims abstract description 27
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 22
- 229930195729 fatty acid Natural products 0.000 claims abstract description 22
- 239000000194 fatty acid Substances 0.000 claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 12
- 229960003237 betaine Drugs 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 230000008719 thickening Effects 0.000 abstract description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- 239000002563 ionic surfactant Substances 0.000 abstract 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 abstract 1
- -1 Cl1-C1 Chemical class 0.000 description 10
- 239000003240 coconut oil Substances 0.000 description 8
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 8
- 235000019864 coconut oil Nutrition 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229960002989 glutamic acid Drugs 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- UWOVWIIOKHRNKU-UHFFFAOYSA-N 2,6-diphenyl-4-(2,4,6-triphenylpyridin-1-ium-1-yl)phenolate Chemical compound [O-]C1=C(C=2C=CC=CC=2)C=C([N+]=2C(=CC(=CC=2C=2C=CC=CC=2)C=2C=CC=CC=2)C=2C=CC=CC=2)C=C1C1=CC=CC=C1 UWOVWIIOKHRNKU-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- GDFAOVXKHJXLEI-VKHMYHEASA-N N-methyl-L-alanine Chemical compound C[NH2+][C@@H](C)C([O-])=O GDFAOVXKHJXLEI-VKHMYHEASA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、頭髪及び皮膚の洗浄に使用されるシャンプー
組成物において従来粘度を付与することの困難であった
陰イオン界面活性剤に粘度を付与することの出来るシャ
ンプー組成物に関する。Detailed Description of the Invention [Industrial Application Field] The present invention provides a method for adding viscosity to anionic surfactants, which has conventionally been difficult to impart in shampoo compositions used for hair and skin cleansing. The present invention relates to a shampoo composition that can be applied.
近年、シャンプーの主剤として使用されるアニオン界面
活性剤には、アミノ酸型のものが多く使用されてきてい
る。また、アミノ酸型陰イオン界面活性剤の増粘方法と
しては、特開昭５８−１８５６９７号公報に脂肪酸ジェ
タノールアミドと水溶性無機塩による方法が提案されて
いる。さらに、特開昭６１−４７９９号公報には、脂肪
酸ジェタノールアミドと脂肪酸アミドアルキルジメチル
アミノ酢酸ベタインによる増粘効果が記載されている。In recent years, amino acid type surfactants have been increasingly used as the main ingredient in shampoos. Furthermore, as a method for thickening amino acid type anionic surfactants, a method using fatty acid jetanolamide and a water-soluble inorganic salt is proposed in JP-A-58-185697. Further, JP-A-61-4799 describes the thickening effect of fatty acid jetanolamide and fatty acid amide alkyldimethylaminoacetic acid betaine.
しかしながら、アミノ酸型活性剤を配合したシャンプー
は増粘が困難で、その増粘には上記の方法によっても充
分ではなく、はとんどのものが低粘度の製品として市販
されている。However, it is difficult to thicken shampoos containing amino acid-type active agents, and even the above-mentioned methods are not sufficient for thickening shampoos, and most shampoos are commercially available as low-viscosity products.
シャンプーの粘度は、手から流れ落ちにくくすると言う
実用面の他、製品の外観を整えると言う意味でも重要で
ある。The viscosity of a shampoo is important not only in terms of making it difficult to run off the hands, but also in terms of improving the appearance of the product.
本発明者らは、この増粘しにくいアニオン界面活性剤を
用い、経済的にかつシャンプーに適した粘度を付与する
組成物の開発に研究を重ねた結果、一般式（１）で示さ
れるアミノ酸型陰イオン界面活性剤に優れた粘度特性を
付与する組成を見出し、本発明をなすに至った。As a result of repeated research into the development of an economical composition that imparts a viscosity suitable for shampoo using this anionic surfactant that does not easily thicken, the present inventors found that the amino acid represented by the general formula (1) The present inventors have discovered a composition that imparts excellent viscosity properties to type anionic surfactants, and have accomplished the present invention.
従って、本発明の目的は、アミノ酸型陰イオン界面活性
剤の特性を阻害することなしに、増粘効果が良好なシャ
ンプー組成物を提供することにある。Therefore, an object of the present invention is to provide a shampoo composition that has a good thickening effect without impairing the properties of the amino acid type anionic surfactant.
本発明によれば、下記一般式（１）で表わされる陰イオ
ン界面活性剤３〜１２重量ごと下記一般式（ＩＩ）及び
（ＩＩＩ）で表わされるベタイン型両性界面活性剤の一
種若しくは混合物３〜１２重量２と下記一般式（ＩＶ）
で表わされる脂肪酸ジェタノールアミド１〜６重量％と
下記一般式（Ｖ）で表わされる非イオン界面活性剤１〜
６重量％とを含有することを特徴とするシャンプー組成
物が提供される。According to the present invention, for every 3 to 12 weights of the anionic surfactant represented by the following general formula (1), 3 to 3 to 12 of one kind or a mixture of betaine type amphoteric surfactants represented by the following general formulas (II) and (III) are mixed. 12 weight 2 and the following general formula (IV)
1 to 6% by weight of fatty acid jetanolamide represented by and 1 to 6% by weight of a nonionic surfactant represented by the following general formula (V)
6% by weight.
一般式（Ｉ）
（式中Ｒは炭素数８〜１８の脂肪酸残基）一般式（ＩＩ
）
（式中Ｒは炭素数８〜１８のアルキル基）一般式（ｍ）
（式中Ｒは炭素数８〜１８の脂肪酸残基）一般式（ＩＶ
）
＼
ＣＨ２ＣＨ２０Ｈ
（式中Ｒは炭素数８〜１８の脂肪酸残基）一般式（Ｖ）
ＲＯ（ＣＨ２ＣＨ２０）ｎＨ
（式中Ｒは炭素数８〜１８のアルキル基、ｎは０−１０
である。）
本発明において、第一の必須成分は３〜１２重量２含有
される。前記一般式（Ｉ）で表される化合物としては、
例えばＮ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸のト
リエタノールアミン塩、Ｎ−ラウリン酸アシル−し−グ
ルタミン酸のトリエタノールアミン塩などが挙げられる
。General formula (I) (wherein R is a fatty acid residue having 8 to 18 carbon atoms) General formula (II
) (In the formula, R is an alkyl group having 8 to 18 carbon atoms) General formula (m) (In the formula, R is a fatty acid residue having 8 to 18 carbon atoms) General formula (IV
) \ CH2CH20H (In the formula, R is a fatty acid residue having 8 to 18 carbon atoms) General formula (V) RO(CH2CH20)nH (In the formula, R is an alkyl group having 8 to 18 carbon atoms, n is 0-10
It is. ) In the present invention, the first essential component is contained in an amount of 3 to 12 parts by weight. As the compound represented by the general formula (I),
Examples include triethanolamine salt of N-coconut oil fatty acid acyl-L-glutamic acid and triethanolamine salt of N-laurate acyl-glutamic acid.
第二の必須成分は３〜１２重量Ｉ重量される。前記一般
式（ＩＩ）で表わされる化合物としては、例えばラウリ
ルジメチルアミノ酢酸ベタイン、オレイルジメチルアミ
ノ酢酸ベタイン、ヤシ油アルキルジメチル酢酸ベタイン
等がある。又前記一般式（ｍ）で表わされる化合物とし
ては、例えばラウロイルアミドプロピルジメチルアミノ
酢酸ベタイン、オレオイルアミドプロピルジメチルアミ
ノ酢酸ベタイン、ヤシ油脂肪酸アミドプロピルジメチル
アミノ酢酸ベタイン等がある。これらは単独に使用する
か、あるいは２種以上を併用する。The second essential ingredient weighs 3 to 12 weight I. Examples of the compound represented by the general formula (II) include lauryldimethylaminoacetic acid betaine, oleyldimethylaminoacetic acid betaine, and coconut oil alkyldimethylacetic acid betaine. Examples of the compound represented by the general formula (m) include lauroylamidopropyldimethylaminoacetic acid betaine, oleoylamidopropyldimethylaminoacetic acid betaine, and coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine. These may be used alone or in combination of two or more.
第三の必須成分は１〜６重量％含有される。前記−般式
（ｒ’／）式で表される化合物としては、例えばラウリ
ル酸ジェタノールアミド、ミリスチン酸ジェ一
タノールアミド、パルミチン酸ジェタノールアミド、ス
テアリン酸ジェタノールアミド、ヤシ油脂肪酸ジェタノ
ールアミド等がある。これらは単独に使用するか、ある
いは２種以上を併用する。The third essential component is contained in an amount of 1 to 6% by weight. Examples of the compound represented by the general formula (r'/) include lauric acid jetanolamide, myristic acid jetanolamide, palmitic acid jetanolamide, stearic acid jetanolamide, and coconut oil fatty acid jetanolamide. etc. These may be used alone or in combination of two or more.
第四の必須成分は１〜６重量％含有される。前記−般式
（Ｖ）で表される化合物としては、例えば天然ラウリル
アルコール、オキソ法合成Ｃ１Ｘ〜ＣｔＳ脂肪族アルコ
ール、チーグラー法合成Ｃ３゜〜１４脂肪族アルコール
、オレイルアルコール、イソステアリルアルコール及び
これらのアルコールの２〜４モルエトキシ化物等がある
。The fourth essential component is contained in an amount of 1 to 6% by weight. Examples of the compound represented by the general formula (V) include natural lauryl alcohol, C1X to CtS aliphatic alcohol synthesized by the oxo method, C3° to 14 aliphatic alcohol synthesized by the Ziegler method, oleyl alcohol, isostearyl alcohol, and these. Examples include 2 to 4 mole ethoxylated alcohols.
第一〜第四の成分の含有量は、それぞれ３〜１２．３〜
１２．１〜６．１〜６重量２であるが、第一の成分と第
二の成分の比は４：６〜６：４、第三の成分と第四の成
分の比は８：２〜２：８で、第一と第二の成分の和をＡ
、第三と第四の和をＢとするとき、ＡとＢの比は５：５
〜７：３であることが望ましい。この比率以外では経済
的な処方のなかで充分な増粘効果が得られない。The content of the first to fourth components is 3 to 12.3, respectively.
12.1-6.1-6 weight 2, but the ratio of the first component to the second component is 4:6 to 6:4, and the ratio of the third component to the fourth component is 8:2 ~2:8, the sum of the first and second components is A
, when the sum of the third and fourth is B, the ratio of A and B is 5:5
It is desirable that the ratio is ~7:3. At ratios other than this, a sufficient thickening effect cannot be obtained in an economical formulation.
また、第四の成分は常温で液状のものが望ましい。これ
は常温で固体のものを用いると低温で析出し、粘度が失
われるからである。Further, the fourth component is preferably liquid at room temperature. This is because if a material that is solid at room temperature is used, it will precipitate at low temperatures and lose its viscosity.
さらに、本発明のシャンプー組成物のＰＨは４．０〜５
．５が好ましい。このＰＩ−１以外では充分な増粘効果
が得られない。Furthermore, the pH of the shampoo composition of the present invention is 4.0 to 5.
．． 5 is preferred. A sufficient thickening effect cannot be obtained with anything other than PI-1.
本発明のシャンプー組成物には、以上の必須成分のほか
に水を含むほか、任意成分として下記に示す化合物を適
宜添加使用することが可能である。The shampoo composition of the present invention contains water in addition to the above-mentioned essential components, and may also contain the compounds shown below as optional components.
すなわち、洗浄力及び起泡力改善剤としてのアニオン界
面活性剤、例えばＮ−Ｃｌ１−Ｃ：１．脂肪酸アシルし
一グルタミン酸のナトリウム塩、カリウム塩、Ｃｌ１−
Ｃ１６脂肪酸サルコシンのナトリウム塩、カリウム塩、
アルカノールアミン塩、Ｃｌ１−Ｃ１，脂肪酸メチルア
ラニンのナトリウム塩、カリウム塩、アルカノールアミ
ン塩、Ｃｌ１−Ｃ□６脂肪酸メチルタウリンのナトリウ
ム塩、カリウム塩、Ｃ８〜Ｃｔｓ脂肪酸タウリンのナト
リウム塩、カリウム塩、ポリオキシエチレン（ｎ−１〜
１０）アルキル（ｃ−Ｃ１１１）エーテルカルボン酸の
ナトリウム塩、カリウム塩、アルカノールアミン塩、ポ
リオキシエチレン（ｎ＝１〜４）アルキル（ｃ［１−Ｃ
１１１）エーテルスルホコハク酸二ナトリウム、アルカ
ン（Ｃｘｏ−Ｃｔ、、）スルホン酸ナトリウム、高級ア
ルコール（ｃｍ〜Ｃ□ｌ＋）硫酸エステルのナトリウム
塩、カリウム塩、アルカノールアミン塩、アンモニウム
塩、ポリオキシエチレン（ｎ；２〜１０）アルキル（Ｃ
Ｉｌ〜Ｃ１Ｂ）エーテル硫酸のナトリウム塩、カリウム
塩、アルカノールアミン塩、アンモニウム塩など。感触
改良剤としてのカチオン化ポリマー、動物性及び植物性
油脂成分、エステル類、性能向上剤としての脂肪酸エス
テル型パール光沢剤、キレート剤、紫外線吸収剤、ジン
クピリチオン、ピロクトンオラミン等のフケ防止剤、Ｐ
Ｈ調整剤としての有機酸類、保湿剤及び粘度安定化剤と
してのグリセリン、１．３−ブタンジオール等ポリオー
ル類そのほか香料、着色剤、防腐剤等である。That is, anionic surfactants as detergent and foaming power improvers, such as N-Cl1-C:1. Sodium salt, potassium salt, Cl1- of fatty acid acyl monoglutamic acid
Sodium salt, potassium salt of C16 fatty acid sarcosine,
Alkanolamine salt, Cl1-C1, sodium salt of fatty acid methylalanine, potassium salt, alkanolamine salt, sodium salt of Cl1-C□6 fatty acid methyltaurine, potassium salt, sodium salt of C8-Cts fatty acid taurine, potassium salt, poly Oxyethylene (n-1~
10) Sodium salt, potassium salt, alkanolamine salt of alkyl (c-C111) ether carboxylic acid, polyoxyethylene (n=1-4) alkyl (c[1-C
111) Disodium ether sulfosuccinate, sodium alkane (Cxo-Ct,,) sulfonate, sodium salt, potassium salt, alkanolamine salt, ammonium salt, polyoxyethylene (n ;2-10) alkyl (C
Il-C1B) Sodium salt, potassium salt, alkanolamine salt, ammonium salt, etc. of ether sulfuric acid. Cationized polymers as feel improvers, animal and vegetable oil components, esters, fatty acid ester type pearlescent agents as performance improvers, chelating agents, ultraviolet absorbers, anti-dandruff agents such as zinc pyrithione, piroctone olamine, etc. , P
These include organic acids as H adjusters, glycerin as humectants and viscosity stabilizers, polyols such as 1,3-butanediol, and perfumes, colorants, preservatives, and the like.
本発明は、アミノ酸型陰イオン界面活性剤を含むシャン
プー組成物において、ベタイン型両性界面活性剤と脂肪
酸ジェタノールアミドとポリエチレンアルキルエーテル
型非イオン界面活性剤とを配合したことにより、アミノ
酸型陰イオン界面活性剤の特性を損なうことなしに、適
切な粘度を保つ範囲で使用することができ、極めて商品
価値の高いものである。The present invention provides a shampoo composition containing an amino acid type anionic surfactant that contains an amino acid type anionic surfactant by blending a betaine type amphoteric surfactant, a fatty acid jetanolamide, and a polyethylene alkyl ether type nonionic surfactant. It can be used within a range that maintains an appropriate viscosity without impairing the properties of the surfactant, and has extremely high commercial value.
以下、実施例により本発明をさらに詳しく説明する。試
験に使用した物質の略称を以下に示した。Hereinafter, the present invention will be explained in more detail with reference to Examples. The abbreviations of the substances used in the test are shown below.
物 質 名 略 称ヤシ
油脂肪酸−Ｌ−グルタミン酸トリエタノールアミン Ａ
ＧＴ ５ｏｌｕ。Substance Name Abbreviation Coconut oil fatty acid-L-glutamic acid triethanolamine A
GT 5olu.
３０％水溶液
ヤシ油アルキルジメチル酢酸ベタイン３０％水溶液
ＣＤＢ ５ｏｌｕ。30% aqueous solution Coconut oil alkyl dimethyl acetate betaine 30% aqueous solution
CDB 5olu.
ヤシ油脂肪酸アミドプロピルベタイン３０％水溶液
ＣＡＢ ５ｏｌｕ。Coconut oil fatty acid amidopropyl betaine 30% aqueous solution
CAB5olu.
ヤシ油脂肪酸ジェタノールアミド Ｃ
ＤＥポリオキシエチレン（３）アルキルエーテル（Ｃ□
２／Ｃ１４） ＡＬ３実施例Ｉ
ＡＧＴ ５ｏｌｕ、及びＣＤＢ ５ｏｌｕ、を用いて現
下の様に処方し、それぞれの増粘性を試験した。それぞ
れの処方のなかでＣＤＥ及びＡｌ１を変化させ、その影
響をみた。Coconut oil fatty acid jetanolamide C
DE polyoxyethylene (3) alkyl ether (C□
2/C14) AL3 Example I AGT 5olu and CDB 5olu were formulated as shown below, and the thickening properties of each were tested. CDE and Al1 were varied in each formulation and their effects were examined.
ＡＧＴ ５ｏｌｕ。AGT 5olu.
ＡＬ３ ＣＤＢ ＣＤＢ ５ｏｌｕ。AL3 CDB CDB 5olu.
精製水 １−ｇ １−ｈ ２０％ ２０％ Ｙ 残残 （結果）上記処方の粘度を測定した結果を示す。purified water 1-g 1-h 20% 20% Y Residue (Results) The results of measuring the viscosity of the above formulation are shown.
２０℃、Ｂ型ＮＯ１２，１１００ｒｐ、単位ｃｐｓ１−
ｅ １−ｆ １−ｇ １−ｈ １−ｉＰ）１５
．３．
１−ａ １−ｂ １−ｃ １−ｄＸ＝２ ３
２ ５０ ９６ １６０Ｘ＝３ ５０ ８０ １２
０ ２５０Ｙ＝０ ５０ ６４
１１０ １３０Ｙ＝０．５ ５
０ ８０ １４０ ２００Ｙ＝１．０
６０ １２０ １７０ ３９０Ｙ＝１．５
８０ １９０ ３３０ ７２０’
／＝２．０ １２０ ４４０ ６
００ １１６０実施例２
実施例１よりベタイン、脂肪酸アミド、高級アルコール
の３相の系がアニオン界面活性剤の増粘に効果的である
ことが判明したので、さらに優れた混合比率の範囲を調
べる為試験を行った。20℃, B type NO12, 1100rp, unit cps1-
e 1-f 1-g 1-h 1-iP) 15
．． 3. 1-a 1-b 1-c 1-dX=2 3
2 50 96 160X=3 50 80 12
0 250Y=0 50 64
110 130Y=0.5 5
0 80 140 200Y=1.0
60 120 170 390Y=1.5
80 190 330 720'
/=2.0 120 440 6
00 1160 Example 2 From Example 1, it was found that a three-phase system of betaine, fatty acid amide, and higher alcohol is effective in thickening the anionic surfactant, so in order to investigate the range of a more excellent mixing ratio. The test was conducted.
ＡＬ３とＣＤＥを次の割合で混合したものを、各種割合
で下記のごとく処方し、その粘度を測定した。A mixture of AL3 and CDE in the following proportions was formulated in various proportions as shown below, and the viscosity thereof was measured.
ＡＬ３．ＣＤＥ混合物
Ａ ＢＣＤＥ Ｆ
ＡＬ３１０８６４２０
ＣＤＥＯ２４６８１０
−ａ
ＡＧＴ ５ｏｌｕ、 １３．３％
ＣＤＢ ５ｏｌｕ、 ２０．０
Ｘ
精製水 残
２−ｂ ２−ｃ ２−ｄ ２−ｅ ２−ｆ
２−ｇ ２−ｈ１３．３％１３．３１１３．３％１３
．３％１３゜３％１０．０％１６．７％２０．０ ２０
．０ ２０．０ ２０．０ ２０．０ ２２．４ １６
．０一 Ｘ−−ＸＸ
残 残 残 残 残 残 残（結果）
次に粘度測定結果を示す。AL3. CDE mixture A BCDE F AL31086420 CDEO246810 -a AGT 5olu, 13.3% CDB 5olu, 20.0 X Purified water Remaining 2-b 2-c 2-d 2-e 2-f
2-g 2-h13.3%13.3113.3%13
．． 3%13゜3%10.0%16.7%20.0 20
．． 0 20.0 20.0 20.0 22.4 16
．． 01 X--XX Residual Residual Residual Residual Residual Residual (Results) Next, the viscosity measurement results are shown.
ＰＨ５，３，２０℃、Ｂ型Ｎ０．２．１１００ｒｐ、単
位ｅｐｓ２−ａ ２−ｂ ２−ｃ ２−ｄ
２−ｅ ２−ｆ ２−ｇ ２−ｈＸ＝
０ ２４ ２４ ２４ ２４ ２４
２４ ２４ ２４ｘ＝３ − −
− ９２ − − ６５ ６
２Ｘ＝４ １０００ ６３２ ５３９ ３２２
２２４ １３８ １８１ １８９Ｘ＝５ ９３
３ ９２０ １２９６ １０８０ ５９６ ４２０
５９２ ６９６Ｘ＝６ ４８３ ５５７ １１
７９ ２０００ １５８７ ８５４ ９０４ ２０
００Ｘ＝７ ４２１ ６０２ １４８８
２１．２０ １３０７ １３９６ ２１４０Ｘ＝８
３８７ ９２８ ２２５６ １４７
２ １１０９ １４６２Ｘ＝９ ３
３２ ６３２ １９１２ ２０００ ６９０ ８
６４実施例３
ベタインとしてＣＡＢ ５ｏｌｕ、を用いて下記のごと
く処方し、その粘度を測定した。PH5, 3, 20℃, B type N0.2.1100rp, unit eps2-a 2-b 2-c 2-d
2-e 2-f 2-g 2-hX=
0 24 24 24 24 24
24 24 24x=3 − −
- 92 - - 65 6
2X=4 1000 632 539 322
224 138 181 189X=5 93
3 920 1296 1080 596 420
592 696X=6 483 557 11
79 2000 1587 854 904 20
00X=7 421 602 1488
21.20 1307 1396 2140X=8
387 928 2256 147
2 1109 1462X=9 3
32 632 1912 2000 690 8
64 Example 3 CAB 5olu was used as betaine and formulated as shown below, and its viscosity was measured.
ＡＧＴ ５ｏｌｕ。AGT 5 olu.
ＣＡＢ ５ｏｌｕ。CAB 5olu.
ＣＤＢ
ＡＬ−３
精製水
３−ａ ３−ｂ ３−ｃ ３−ｄ１
３．３％ １３．３％ １３．３％ １３．３％２０．
０ ２０．０ ２０．０ ２０．００．０
１．８ ２．４ ３．００．０ １．２
１．６ ２．０残 残 残 残
−ｅ
１３．３％
２０．０
３．６
２．４
残
（結果）次に粘度測定結果を示す。CDB AL-3 Purified water 3-a 3-b 3-c 3-d1
3.3% 13.3% 13.3% 13.3%20.
0 20.0 20.0 20.00.0
1.8 2.4 3.00.0 1.2
1.6 2.0 Residue Residue Residue Residue -e 13.3% 20.0 3.6 2.4 Residue (Results) Next, the viscosity measurement results are shown.
Ｐ１１５．３．２０℃、Ｂ型Ｎｏ、２．１１００ｒｐ、
単位ｃｐｓ３−ａ ３−ｂ ３−ｃ ３−ｄ
３−ｅ２９ ３１７ ２．５３２ １２．１６０
１８．８８０実施例４
下記処方にて、ｐＨの変化による粘度の変化を測定した
。ｐＨは水酸化ナトリウム、クエン酸により調整した。P115.3.20℃, B type No.2.1100rp,
Unit cps3-a 3-b 3-c 3-d
3-e29 317 2.532 12.160
18.880 Example 4 Changes in viscosity due to changes in pH were measured using the following formulation. pH was adjusted with sodium hydroxide and citric acid.
４−ａ ４−ｂ １３．３％ １３．３％ ２０．０ ２０．０ ２．４ １．６ 残 ＡＧＴ ５ｏｌｕ。4-a 4-b 13.3% 13.3% 20.0 20.0 2.4 1.6 Residue AGT 5olu.
ＣＤＢ ５ｏｌｕ。CDB 5olu.
ＣＡＢ ５ｏｌｕ。CAB 5 olu.
ＡＬ−３１，８ ＣＤＥ １．２ 精製水 残 （結果）次に粘度測定結果を示す。AL-31,8 CDE 1.2 Purified water remainder (Results) Next, the viscosity measurement results are shown.
２０℃、Ｂ型Ｎｏ、２＋１１００ｒｐ、単位ｃｐｓＰＨ
３，９４，９５，４５，７６，０７，２４−ａの粘度
９３６ ２１９２０ ３６６ １５６ ３８ ２４ＰＨ
４，０４，９５，３６，１７，１
４−ｂの粘度 １５６ ２４６０ ３５０ ５０ ３２
以上の試験結果より、アミノ酸型陰イオン界面活性剤を
含むシャンプーにおいて、ベタイン型両性界面活性剤と
脂肪酸ジェタノールアミドとポリオキシエチレンアルキ
ルエーテル型非イオン界面活性剤を併用した系が優れた
増粘性を示すことがわかる。20℃, B type No., 2+1100rp, unit cpsPH
Viscosity of 3,94,95,45,76,07,24-a
936 21920 366 156 38 24PH
4,04,95,36,17,1 4-b viscosity 156 2460 350 50 32
From the above test results, in shampoos containing amino acid-type anionic surfactants, systems that use a combination of betaine-type amphoteric surfactants, fatty acid jetanolamide, and polyoxyethylene alkyl ether-type nonionic surfactants have excellent thickening properties. It can be seen that this shows that
Claims (1)
性剤３〜１２重量％と下記一般式（II）及び（III）で
表わされるベタイン型両性界面活性剤の一種若しくは混
合物３〜１２重量％と下記一般式（IV）で表わされる脂
肪酸ジエタノールアミド１〜６重量％と下記一般式（Ｖ
）で表わされる非イオン界面活性剤１〜６重量％とを含
有することを特徴とするシャンプー組成物。 一般式（ I ） ▲数式、化学式、表等があります▼ （式中Ｒは炭素数８〜１８の脂肪酸残基） 一般式（II） ▲数式、化学式、表等があります▼ （式中Ｒは炭素数８〜１８のアルキル基） 一般式（III） ▲数式、化学式、表等があります▼ （式中Ｒは炭素数８〜１８の脂肪酸残基） 一般式（IV） ▲数式、化学式、表等があります▼ （式中Ｒは炭素数８〜１８の脂肪酸残基） 一般式（Ｖ） ▲数式、化学式、表等があります▼ （式中Ｒは炭素数８〜１８のアルキル基、ｎは０〜１０
である。）(1) 3 to 12% by weight of an anionic surfactant represented by the following general formula (I) and 3 to 12% by weight of one or a mixture of betaine type amphoteric surfactants represented by the following general formulas (II) and (III) % and 1 to 6% by weight of fatty acid diethanolamide represented by the following general formula (IV) and the following general formula (V
) A shampoo composition comprising 1 to 6% by weight of a nonionic surfactant represented by: General formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R is a fatty acid residue with 8 to 18 carbon atoms) General formula (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R is (alkyl group having 8 to 18 carbon atoms) General formula (III) ▲Mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R is a fatty acid residue having 8 to 18 carbon atoms) General formula (IV) ▲Mathematical formulas, chemical formulas, tables, etc. etc. ▼ (In the formula, R is a fatty acid residue with 8 to 18 carbon atoms) General formula (V) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (In the formula, R is an alkyl group with 8 to 18 carbon atoms, n is 0-10
It is. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6800089A JPH02247114A (en) | 1989-03-20 | 1989-03-20 | Shampoo composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6800089A JPH02247114A (en) | 1989-03-20 | 1989-03-20 | Shampoo composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02247114A true JPH02247114A (en) | 1990-10-02 |
Family
ID=13361187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6800089A Pending JPH02247114A (en) | 1989-03-20 | 1989-03-20 | Shampoo composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02247114A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2477913A (en) * | 2010-02-11 | 2011-08-24 | Pangaea Lab Ltd | A hair building solid agent with electrostatic effects |
-
1989
- 1989-03-20 JP JP6800089A patent/JPH02247114A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2477913A (en) * | 2010-02-11 | 2011-08-24 | Pangaea Lab Ltd | A hair building solid agent with electrostatic effects |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0150323B1 (en) | Shampoo composition | |
| EP0004755B1 (en) | Liquid detergent cleansing compositions having low ocular and skin irritation | |
| EP1221474B1 (en) | Detergent composition | |
| JPH05201853A (en) | Abstergent composition | |
| US4526710A (en) | Liquid detergent composition | |
| US3723357A (en) | Liquid detergent compositions | |
| EP0612518A1 (en) | Cosmetic composition containing a phosphate surfactant and a co-surfactant | |
| JP4173962B2 (en) | Detergent composition with pearly luster and pearly luster concentrate with good dispersibility | |
| JPH02247114A (en) | Shampoo composition | |
| USRE30641E (en) | Low irritating detergent compositions | |
| US20020187917A1 (en) | High-foaming non-anionic surfactant compositions | |
| CN114921296A (en) | Soap-based self-thickening cleansing compositions | |
| JP2537060B2 (en) | Skin cleanser composition | |
| JP4345144B2 (en) | Cleaning composition | |
| JPH02212598A (en) | Liquid detergent composition | |
| JPH08134494A (en) | Detergent composition | |
| JP4931287B2 (en) | Liquid detergent composition | |
| JP4982018B2 (en) | Cleaning composition | |
| JPH0542998B2 (en) | ||
| US3888798A (en) | Liquid detergent composition | |
| US4824604A (en) | Detergent composition | |
| JPS5918440B2 (en) | cleaning composition | |
| JP3473092B2 (en) | Detergent composition | |
| JPH0548800B2 (en) | ||
| EP0322741A2 (en) | Low irritant detergent composition |