JPH02243576A - Decorative sheet - Google Patents

Decorative sheet

Info

Publication number
JPH02243576A
JPH02243576A JP6319789A JP6319789A JPH02243576A JP H02243576 A JPH02243576 A JP H02243576A JP 6319789 A JP6319789 A JP 6319789A JP 6319789 A JP6319789 A JP 6319789A JP H02243576 A JPH02243576 A JP H02243576A
Authority
JP
Japan
Prior art keywords
calcium silicate
slurry
carbon fiber
decorative
matrix
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6319789A
Other languages
Japanese (ja)
Inventor
Mitsuru Awata
粟田 満
Yuji Noguchi
勇二 野口
Katsuo Nomura
野村 克夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aica Kogyo Co Ltd
Mitsubishi Kasei Corp
Original Assignee
Aica Kogyo Co Ltd
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aica Kogyo Co Ltd, Mitsubishi Kasei Corp filed Critical Aica Kogyo Co Ltd
Priority to JP6319789A priority Critical patent/JPH02243576A/en
Publication of JPH02243576A publication Critical patent/JPH02243576A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a high-performance decorative sheet free from release between a substrate and decorative layer during use by integrally forming a mica layer on at least either one surface of forming sheet obtained by uniformly dispersing a carbon fiber into a calcium silicate matrix. CONSTITUTION:The decorative sheet being a carbon fiber-containing calcium silicate forming sheet obtained by uniformly dispersing 0.1-20wt.% carbon fiber to a matrix containing calcium silicate as a main ingredient and having a mica layer integrally formed on at least one surface of the forming sheet. A method reacting a calcareous raw material with a silicic raw material by raising temperature of an aqueous slurry, prepared so that a molar ratio of CaO and SiO2 is nearly equal, under pressure at >= 160 deg.C as the above-mentioned production. Solid content concentration of calcium silicate hydrate in the slurry is preferably <=10wt.% and preferably 3-8wt.% especially in consideration of productivity.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は建築材料として使用される珪酸カルシウム系化
粧板に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a calcium silicate decorative board used as a building material.

〔従来の技術〕[Conventional technology]

従来の珪酸カルシウム系化粧板をはじめとする各種化粧
板は珪酸カルシウム板、石綿スレート板、セメントケイ
カル板や石膏ボードの表面に化粧層を貼りつけるかある
いは=母等を吹きつけること等により製造されていた。
Various decorative laminates, including conventional calcium silicate decorative laminates, are manufactured by pasting a decorative layer on the surface of calcium silicate boards, asbestos slate boards, cement silica boards, and plasterboards, or by spraying them with a matrix, etc. was.

〔発明が解決しようとする諜J〕[The espionage that the invention attempts to solve]

しかしながら、かかる従来からの吹きつけ法や接着法等
により設けられた化粧層は、基材である珪酸カルシウム
成形板等との吸湿あるいは吸水量の差もしくは熱膨張率
の違い等の要因により施行後の使用時に基材と化粧層と
が剥離するという課題を有していた。又、更には従来の
化粧板では表面のみに着色することが通常であるため木
口面が出る場合にはその断面で色むら等が生じる等の課
題もあった。
However, the decorative layer provided by the conventional spraying method or adhesive method, etc., may absorb moisture with the base material, such as a calcium silicate molded plate, or may differ in the amount of water absorbed or in the coefficient of thermal expansion. There was a problem in that the base material and the decorative layer peeled off when used. Furthermore, since conventional decorative boards are usually colored only on the surface, there are problems such as color unevenness occurring on the cross section when the end surface is exposed.

〔課題を解決するための手段〕[Means to solve the problem]

そこで、本発明者等はかかる課題を解決するために鋭意
検討を行なった結果、炭素繊維を含有する珪酸カルシウ
ム成形板の表面に雲母層を一体成形的に形成することに
より、上記の課題が解決されることを見い出し、本発明
に到達した。
Therefore, the inventors of the present invention conducted intensive studies to solve these problems, and found that the above problems were solved by integrally forming a mica layer on the surface of a calcium silicate molded plate containing carbon fibers. The inventors have discovered that the present invention is possible.

すなわち、本発明の目的は使用時に基板と化粧層とが剥
離しないような高性能の化粧板を提供することにあり、
又、予めマトリックス材料に顔料等を均一に分散させて
、成形板全体に着色させた化粧板を提供することにある
That is, an object of the present invention is to provide a high-performance decorative board in which the substrate and the decorative layer do not peel off during use.
Another object of the present invention is to provide a decorative board in which the entire molded board is colored by uniformly dispersing a pigment or the like in a matrix material in advance.

そしてかかる目的は、珪酸カルシウムを主成分とするマ
トリックスに炭素繊維をO,1〜20重量%均一に分散
せしめた炭素繊維含有珪酸カルシウム成形板であって、
該成形板の少なくとも一方の表面に一体成形にて形成し
た雲母層を有することを特徴とする化粧仮により容易に
達成される。
The purpose is to provide a carbon fiber-containing calcium silicate molded plate in which carbon fibers are uniformly dispersed in a matrix containing calcium silicate in an amount of 1 to 20% by weight.
This can be easily achieved with a decorative temporary having a mica layer integrally formed on at least one surface of the molded plate.

以下、本発明の詳細な説明する。The present invention will be explained in detail below.

本発明で用いる珪酸カルシウムを主成分とするマトリッ
クスは、石灰質原料例えば、生石灰とケイ酸質原料例え
ば珪石とを、水熱合成反応させることにより得られる0
通常、ゾノトライト、トバモライトと呼ばれる結晶質の
ものから、C3HI。
The matrix containing calcium silicate as a main component used in the present invention is obtained by hydrothermally synthesizing a calcareous raw material such as quicklime and a silicate raw material such as silica stone.
C3HI is usually a crystalline material called xonotlite or tobermorite.

C3HI[、さらに非晶質のものまで広範囲に使用しう
る。
C3HI [and even amorphous ones can be used in a wide range of ways.

その製法としては、石灰質原料とケイ酸質原料とをCa
OとSingのモル比がほぼ等しくなるように調整した
水性スラリーを加圧下、160℃以上に昇温しで反応さ
せる方法が採用される0本発明においては、このスラリ
ーをそのまま用いることもできるが、乾燥して粉末にし
たものに水を添加して用いることもできる。該スラリー
中のケイ酸カルシウム水和物の固形分濃度は特に制限は
ないが、10%以下が好ましく、特に生産性を考慮する
と3〜8%が好ましい。
The manufacturing method involves mixing calcareous raw materials and silicic raw materials with Ca
In the present invention, a method is adopted in which an aqueous slurry adjusted so that the molar ratio of O and Sing is almost equal is heated to 160 ° C. or higher under pressure and reacted. In the present invention, this slurry can be used as it is. It can also be used by adding water to a dried powder. The solid content concentration of calcium silicate hydrate in the slurry is not particularly limited, but is preferably 10% or less, and particularly preferably 3 to 8% in consideration of productivity.

又、炭素繊維としては、特に限定されるものではなく、
PAN (ポリアクリロニトリル)系、ピッチ系、レー
ヨン系あるいはフェノール樹脂系炭素繊維等種々のもの
が使用できる。
In addition, carbon fibers are not particularly limited,
Various materials such as PAN (polyacrylonitrile), pitch, rayon, or phenol resin carbon fibers can be used.

又、その形態としては短繊維状が好ましく、その繊維長
は1〜50m、好ましくは5〜30mの短繊維を用いる
のがよい。
Moreover, it is preferable to use short fibers having a fiber length of 1 to 50 m, preferably 5 to 30 m.

m維長が短かすぎると化粧板に対する補強効果が発現し
にクク、繊維長が長すぎるとマトリックススラリー中で
分散し難(、塊状となりやはり補強効果が発現しにくい
ので好ましべない。
If the fiber length is too short, the reinforcing effect on the decorative board will not be expressed, and if the fiber length is too long, it will be difficult to disperse in the matrix slurry (or it will become lumpy, making it difficult to express the reinforcing effect), which is not preferable.

使用する雲母としては白雲母、金雲母、黒雲母、絹雲母
等種々の雲母が使用でき、その粒径等については特に限
定されるものではない。
Various types of mica can be used, such as muscovite, phlogopite, biotite, and sericite, and there are no particular limitations on the particle size.

次に、本発明の化粧板を製造する方法としては、まず上
述した珪酸カルシウムを主成分とするマトリックススラ
リーに雲母を通常5〜10重量%添加混合し、雲母が均
一に分散した混合スラリー(A)を調製する。
Next, as a method for manufacturing the decorative board of the present invention, first, mica is added and mixed in the above-mentioned matrix slurry mainly composed of calcium silicate, usually 5 to 10% by weight, and a mixed slurry in which mica is uniformly dispersed (A ).

又、別個に上記の珪酸カルシウムを主成分とするマトリ
ックススラリーに上述した炭素繊維を通常0.1〜20
重量%、好ましくは1〜10重景%重量様にして添加混
合し、炭素繊維が均一に分散した混合スラリーCB)を
調製する。尚、その際上記の混合スラリー(A)に対し
て炭素繊維又はガラス繊維を混合しておいてもよい。
Separately, the above-mentioned carbon fibers are added to the above-mentioned matrix slurry mainly composed of calcium silicate, usually in an amount of 0.1 to 20%.
They are added and mixed in a proportion by weight, preferably 1 to 10 weight percent, to prepare a mixed slurry CB) in which carbon fibers are uniformly dispersed. Incidentally, at that time, carbon fibers or glass fibers may be mixed in the above-mentioned mixed slurry (A).

その後、加圧脱水成形機の成形金型にまず上記の混合ス
ラリー(A)を投入し、次いで混合スラリー(B)を混
合スラリー(A)と混合しない様に徐々に投入して加圧
脱水成形を行なう、その際、雲母層の厚みは最終形態で
ある化粧板において2〜5tmとするのが好ましい。
After that, the above mixed slurry (A) is first put into the mold of the pressure dehydration molding machine, and then the mixed slurry (B) is gradually put in so as not to mix with the mixed slurry (A), and the pressure dehydration molding is performed. In this case, the thickness of the mica layer is preferably 2 to 5 tm in the final form of the decorative board.

この加圧脱水成形は常法の濾水成形方法により行なわれ
るが、雲母層が一体成形に形成するように行なわなけれ
ばならない、又、基板の両面に雲母層を形成する場合に
は、混合スラリー(A)を再度上述した混合スラリー(
B)の投入後に同様にして、徐々に投入し、混合スラリ
ーCB)の層に対してその両面に混合スラリー(A )
の層を設けるようにした後、加圧脱水成形を行なうこと
により得ることができる。
This pressurized dehydration molding is carried out by a conventional drainage molding method, but it must be carried out so that the mica layer is integrally formed.Also, when forming mica layers on both sides of the substrate, a mixed slurry must be used. (A) is the mixed slurry described above again (
After adding B), gradually add the mixed slurry (A) to both sides of the layer of mixed slurry CB).
It can be obtained by forming a layer and then performing pressure dehydration molding.

この様にして得られた成形板を100〜180℃、好ま
しくは105〜150℃の温度で乾燥あるいは再びオー
トクレーブ養生後乾燥することにより本発明の化粧板が
得られる。得られる化粧板の比重としては0.3〜1.
0g/adが好ましい。
The decorative board of the present invention can be obtained by drying the molded board thus obtained at a temperature of 100 to 180°C, preferably 105 to 150°C, or drying it again after curing in an autoclave. The specific gravity of the decorative board obtained is 0.3 to 1.
0 g/ad is preferred.

尚、必要に応じて、炭素繊維あるいは雲母を珪酸カルシ
ウムを主成分とするマトリックススラリーに添加混合す
る際にSBRラテックス、特にカルボキシル化SBRラ
テックスを同時に添加配合してもよい。
If necessary, SBR latex, particularly carboxylated SBR latex, may be added and blended at the same time when carbon fibers or mica are added and mixed into the matrix slurry containing calcium silicate as a main component.

該ラテックスを添加することにより、成形物の強度と粘
り強さ(靭性)及び加工性を向上させることができるが
、その添加量は、ケイ酸カルシウム水和物100重量部
に対し、固形分換算で2〜25重量部添加するのが好ま
しい、この添加量を増加すると得られる成形物の強度が
向上するが、一方、不燃性の低下、カサ比重の増加及び
コストの上昇などの問題が生ずる。
By adding the latex, it is possible to improve the strength, tenacity (toughness) and processability of the molded product, but the amount added is 100 parts by weight of calcium silicate hydrate in terms of solid content. It is preferable to add 2 to 25 parts by weight.Increasing the amount added improves the strength of the molded product obtained, but on the other hand, problems such as a decrease in nonflammability, an increase in bulk specific gravity, and an increase in cost occur.

又、表層にある雲母との色調を考慮の上、成形時の混合
スラリー(A)及び/又は(B)に顔料を添加して着色
してもよい。
Further, in consideration of the color tone with mica in the surface layer, a pigment may be added to the mixed slurry (A) and/or (B) for coloring during molding.

顔料としては特に限定されるものではなく、たとえば、
ベンガラ、酸化マンガン、クロム緑、コバルト緑、コバ
ルト青等、無機質成形板の着色に使用できるものであれ
ばよく、その添加量も所望に応じて添加混合すればよい
Pigments are not particularly limited; for example,
Any material that can be used for coloring an inorganic molded plate may be used, such as red iron oxide, manganese oxide, chromium green, cobalt green, cobalt blue, etc., and the amount thereof may be added and mixed as desired.

更に、本発明の化粧板に撥水性が要求される場合には、
無機質成形体に使用される撥水剤を添加してもよい。
Furthermore, when the decorative board of the present invention is required to have water repellency,
A water repellent used for inorganic molded bodies may be added.

本発明の化粧板は、マトリックスが針状結晶や板状結晶
の集合体である多孔質珪酸カルシウムであるため、吸湿
、脱湿の作用がある。また、炭素繊維を補強材としてい
るため、吸湿によっても強度低下はなく、また透湿抵抗
が1〜3h−m・璽層Hg/gである。
Since the matrix of the decorative board of the present invention is porous calcium silicate, which is an aggregate of needle-like crystals or plate-like crystals, it has moisture absorption and dehumidification effects. In addition, since carbon fiber is used as a reinforcing material, the strength does not decrease even when moisture is absorbed, and the moisture permeation resistance is 1 to 3 h-m/Place Hg/g.

このため、吸湿・脱湿のはげしい場所での使用が可能で
あり、いわゆる呼吸する建材として使用できる。
Therefore, it can be used in places where moisture absorption and dehumidification are severe, and it can be used as a so-called breathing building material.

〔実施例〕〔Example〕

以下本発明を実施例により本発明を説明する。 The present invention will be explained below with reference to Examples.

実施例1 粉末珪石と石灰とを原料として高圧下水熱反応を行い、
ジノトラストスラリーを得た。このスラリーに石炭ピン
チ系炭素繊維(ダイアリード0)を6部添加混合した。
Example 1 A hydrothermal reaction under high pressure was carried out using powdered silica stone and lime as raw materials,
Obtained Gino Trust Slurry. To this slurry, 6 parts of coal pinch type carbon fiber (Dialead 0) was added and mixed.

この混合スラリーにカルボキシル変性したSBRラテッ
クス2部とブラウン顔料(バイエル“無機顔料645T
”)を3部し着色スラリーを得た。
Two parts of carboxyl-modified SBR latex and a brown pigment (Bayer “Inorganic Pigment 645T”) were added to this mixed slurry.
”) to obtain a colored slurry.

このスラリーの1/8に金雲母(山口雲母工業所″NC
Cl332”)を0.7.5部添加し混合した。
1/8 of this slurry was added to phlogopite (Yamaguchi Mica Industrial Co., Ltd.
0.7.5 parts of Cl332'') was added and mixed.

この雲母添加スラリーを濾水金型にまず投入しその後、
残りの7/8のスラリーを投入した後加圧成形を行った
。成形体を120℃で8時間乾燥し、220X220X
16tmの成形体を得た。この成形体は片面に金雲母が
点在しており、また、切断面も全てブラウンであり、化
粧板として使用できる。
This mica-added slurry is first poured into a drainage mold, and then
After adding the remaining 7/8 of the slurry, pressure molding was performed. The molded body was dried at 120°C for 8 hours, and 220X220X
A molded body of 16 tm was obtained. This molded product has phlogopite dotted on one side, and all cut surfaces are brown, so it can be used as a decorative board.

この雲母入り成形体をASTM  E−96に準じて透
湿抵抗を測定したところ3 h−rrr −rm Hg
/gであり、テスト後も雲母がはがれることはなかった
The moisture permeability resistance of this mica-containing molded body was measured according to ASTM E-96, and it was found to be 3 h-rrr-rm Hg.
/g, and the mica did not peel off even after the test.

〔発明の効果〕〔Effect of the invention〕

本発明の化粧仮によれば、表面層が一体成形された雲母
により化粧化されており、また多孔質珪酸カルシウム板
のため、吸湿・脱湿作用があるため、結露を生じること
もない、また板全体を着色化することも可能であるため
、施工現場での切断においても木口処理することもなく
使用できる。
According to the cosmetic temporary of the present invention, the surface layer is decorated with integrally molded mica, and since it is a porous calcium silicate plate, it has moisture absorption and dehumidification properties, so it does not cause dew condensation. Since the entire piece can be colored, it can be used for cutting at construction sites without the need for edge treatment.

また、炭素繊維を補強材として使用しているため、軽量
・高強度の板であり、完全不燃の珪酸カルシウムをマト
リックスとしているため、大版で薄い不燃化粧板となる
In addition, since carbon fiber is used as a reinforcing material, the board is lightweight and has high strength.Since the matrix is completely non-combustible calcium silicate, it can be made into a large and thin non-combustible decorative board.

このように、本発明の化粧板は意匠性があり、不燃、高
強度の呼吸する化粧板として、各種内装材として使用で
きる。
As described above, the decorative board of the present invention has good design, is nonflammable, has high strength, and can be used as a breathable decorative board for various interior materials.

Claims (2)

【特許請求の範囲】[Claims] (1)珪酸カルシウムを主成分とするマトリックスに炭
素繊維を0.1〜20重量%均一に分散せしめた炭素繊
維含有珪酸カルシウム成形板であって、該成形板の少な
くとも一方の表面に一体成形にて形成した雲母層を有す
ることを特徴とする化粧板。
(1) A carbon fiber-containing calcium silicate molded plate in which 0.1 to 20% by weight of carbon fibers are uniformly dispersed in a matrix mainly composed of calcium silicate, the molded plate having an integrally formed plate on at least one surface of the molded plate. A decorative board characterized by having a mica layer formed by
(2)珪酸カルシウムを主成分とするマトリックスが顔
料を均一に分散させたものである請求項1記載の化粧板
(2) The decorative board according to claim 1, wherein the matrix containing calcium silicate as a main component has a pigment uniformly dispersed therein.
JP6319789A 1989-03-15 1989-03-15 Decorative sheet Pending JPH02243576A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6319789A JPH02243576A (en) 1989-03-15 1989-03-15 Decorative sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6319789A JPH02243576A (en) 1989-03-15 1989-03-15 Decorative sheet

Publications (1)

Publication Number Publication Date
JPH02243576A true JPH02243576A (en) 1990-09-27

Family

ID=13222252

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6319789A Pending JPH02243576A (en) 1989-03-15 1989-03-15 Decorative sheet

Country Status (1)

Country Link
JP (1) JPH02243576A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018079630A (en) * 2016-11-17 2018-05-24 株式会社イノアックコーポレーション Carbon fiber composite decorative plate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018079630A (en) * 2016-11-17 2018-05-24 株式会社イノアックコーポレーション Carbon fiber composite decorative plate

Similar Documents

Publication Publication Date Title
US5858083A (en) Cementitious gypsum-containing binders and compositions and materials made therefrom
US5685903A (en) Cementitious gypsum-containing compositions and materials made therefrom
JP3025906B2 (en) Gypsum-containing cementitious composition and production material therefrom
US5718759A (en) Cementitious gypsum-containing compositions and materials made therefrom
CN105272097A (en) Novel magnesian cementing material and preparation method for magnesian cementing plate prepared from novel magnesian cementing material
US6406535B1 (en) Material for constructional finished wallboard
MX2007014740A (en) Natural aluminosilicate composites and aggregates synthesized in alkaline environment and their manufacturing process.
CA2645402A1 (en) Cement-based fire door core
CN110423075A (en) A kind of heat-insulating decorative composite board finishing material and preparation method thereof
US6171655B1 (en) Method of preparing constructional finished wallboard
JPH02243576A (en) Decorative sheet
JPH03112842A (en) Production of fiber cement board
JP5162067B2 (en) Calcium silicate hydrate slurry
JP4213405B2 (en) Fiber-containing gypsum board and manufacturing method thereof
KR20010019471A (en) A Gypsumboard Containing Loess and Method for Preparing the Same
JP6166965B2 (en) Method for producing moisture-conditioning building material and method for producing moisture-conditioning building material
JP2002308669A (en) (calcium silicate)-silica composite formed body
JP2515197B2 (en) Calcium silicate refractory coated board and its manufacturing method
KR100455472B1 (en) Calcium silicate board and method of manufacturing same
JPS62176949A (en) Calcium silicate gypsum composite body
JPH0569787B2 (en)
JP2758449B2 (en) Fire-resistant hardened asbestos-free gypsum body and method for producing the same
JP2601781B2 (en) Cement fiberboard
CN116677156A (en) Composite heat-insulating wall brick and preparation method thereof
CA2192733C (en) Cementitious gypsum-containing compositions and materials made therefore