JPH02177252A - Cell and manufacture thereof - Google Patents

Cell and manufacture thereof

Info

Publication number
JPH02177252A
JPH02177252A JP63334458A JP33445888A JPH02177252A JP H02177252 A JPH02177252 A JP H02177252A JP 63334458 A JP63334458 A JP 63334458A JP 33445888 A JP33445888 A JP 33445888A JP H02177252 A JPH02177252 A JP H02177252A
Authority
JP
Japan
Prior art keywords
resin
ultraviolet
battery
color tone
colorant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63334458A
Other languages
Japanese (ja)
Inventor
Fumio Oo
大尾 文夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP63334458A priority Critical patent/JPH02177252A/en
Publication of JPH02177252A publication Critical patent/JPH02177252A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Sealing Battery Cases Or Jackets (AREA)

Abstract

PURPOSE:To prevent producing a product in which a resin is not thoroughly hardened by filling a resin of ultraviolet ray hardening type that is colored by a colorant by which coloring tone is changed according to ultraviolet irradiation, in a concavity between terminals of positive and negative electrodes of a cell. CONSTITUTION:A ultraviolet ray hardening type resin 1 is arranged in a concavity B that is formed out of an insulating packing 4 by which the resin is insulated between a positive electrode terminal 2 and a negative electrode terminal 3 of a cell, and also by which an internal generating element A is prevented from leaking outside. As the ultraviolet hardening resin 1, a prepolymer that has unsaturated bonding of a principal chain or of a side chain in its molecular structure, or a prepolymer that has unsaturated bonding of the end of the principal chain is used, and by irradiating ultraviolet to these polymers, a radical is generated in the molecular so as to radical-polymerize the polymer and to harden it, as in the case of an unsaturated polyester resin, acryl resin, or epoxy resin. As the colorant, an azo dye that has an azo bonding (-N=N-) in its molecular structure is used, by which color tone is changed by means of ultraviolet irradiation, and the hardening can thus be recognized.

Description

【発明の詳細な説明】 童業上の利用分野 本発明は、電池の端子露出面に紫外線硬化型の樹脂を充
填して構成される電池に関するものである。
DETAILED DESCRIPTION OF THE INVENTION FIELD OF THE INVENTION The present invention relates to a battery constructed by filling an exposed terminal surface of the battery with an ultraviolet curing resin.

従来の技術 従来より、電池の正極端子および負極端子の同一面に露
出する端子間部分には、絶縁性部材を介在させて外部か
らの金属部片の接触による短絡、あるいは結露などによ
る液絡現象の防止が図られていた。特にリチウム電池、
アルカリ電池のような高出力電池である場合、短絡した
時には大電流が流れ、電池自身が発熱して電池封口部分
が変形したり、内蔵電解液が漏出し使用機器を損傷させ
たり、あるいは水分などが両極端子間に介在して液絡状
態になった時、リチウム電池のような3v級の電位を示
す電池にあっては水の電気分解が起こり、端子金属を腐
食させるなどの問題があった。
Conventional technology Conventionally, an insulating material has been interposed between the positive and negative terminals of a battery that are exposed on the same surface to prevent short circuits due to contact with external metal parts or liquid junctions due to condensation. Efforts were made to prevent this. Especially lithium batteries,
When a high-output battery such as an alkaline battery is short-circuited, a large current flows, causing the battery itself to generate heat and deform the battery seal, or cause internal electrolyte to leak and damage the equipment used, or cause moisture etc. When there is a liquid junction between the two electrode terminals, electrolysis of water occurs in batteries such as lithium batteries that exhibit a potential of 3V, causing problems such as corrosion of the terminal metal. .

これらの問題を解決する絶縁性部材としては従来より金
属との密着性、接着性に優れる高分子材料が用いられて
きた。これらの接着剤は溶剤可溶型。
As insulating members to solve these problems, polymeric materials that have excellent adhesion and adhesion to metals have been used. These adhesives are solvent soluble.

あるいは二液型の接着組成物が主なものであるが硬化す
るまでに時間がかかったり、溶剤可溶型のものにあって
は生産ラインの中で溶剤を飛散させる工程が必要となり
、電池製造コストが高くなるものであった。反面紫外線
硬化型の接着組成物は無溶剤型であり、紫外線を照射す
ることにより瞬時に接着硬化する作用を有するため多用
されつつある。
Alternatively, two-component adhesive compositions are the main type, but they take time to harden, and solvent-soluble adhesive compositions require a process to splash the solvent on the production line, making it difficult to manufacture batteries. This resulted in higher costs. On the other hand, UV-curable adhesive compositions are solvent-free and have the effect of instantaneous adhesive curing upon irradiation with UV rays, so they are becoming more widely used.

発明が解決しようとする課題 電池の正、負両極端子の露出部間に紫外線硬化型樹脂を
使用した場合、紫外線硬化型樹脂は紫外線を吸収するこ
とによって瞬時に便化するものであり、特に樹脂自身の
硬化前の色調として透明i生の高いものほど、紫外線を
吸収しやすく従って硬化も速く行なわれる。しかしなが
ら昨今の消費者ニーズとしては外観的にもデザイン性豊
かなものが好まれ、また品質管理の面においても樹脂に
若干の色をつけることによって、電池の両極端子露出部
を完全に紫外線硬化型の樹脂で覆われていることが判定
できるように何らかの着色をするのが有効である。また
、このように着色した紫外線硬化型樹脂に紫外線を照射
することにより硬化させる訳であるが、製造ラインとし
ては照射紫外線を直視することがないよう紫外線照射部
は完全に外部から見えないように遮へいされており、万
一紫外線の光源である水銀ランプの出力が低下したり、
あるいは寿命が尽きていた場合においては、紫外線硬化
型接着剤が完全に硬まっていない状態で生産されるとい
う問題があった。
Problems to be Solved by the Invention When an ultraviolet curable resin is used between the exposed parts of the positive and negative terminals of a battery, the ultraviolet curable resin instantly becomes useful by absorbing ultraviolet rays. The higher the transparency level of the color before curing, the more easily it absorbs ultraviolet rays, and therefore the faster it is cured. However, recent consumer needs favor products with rich designs in terms of appearance, and in terms of quality control, by adding a slight color to the resin, the exposed parts of the battery's terminals can be completely UV-cured. It is effective to apply some kind of coloring so that it can be determined that it is covered with resin. In addition, the colored UV-curable resin is cured by irradiating it with UV rays, but on the production line, the UV irradiation part is completely hidden from view so that the irradiated UV rays cannot be seen directly. It is shielded, so in the unlikely event that the output of the mercury lamp, which is the source of ultraviolet light, decreases,
Alternatively, if the life of the adhesive has expired, there is a problem in that the ultraviolet curable adhesive is produced in a state that has not completely hardened.

課題を解決するための手段 本発明は、・紫外線硬化型樹脂の着色剤として、紫外線
によって鋭敏に色調の変化する発色団を有した着色剤を
使用することならびに工稈内に紫外線硬化型樹脂の色調
の変化を測定する工程を設けることによって前述した問
題点を解決するものである。
Means for Solving the Problems The present invention provides the following features: - The use of a coloring agent having a chromophore whose color tone changes sharply due to ultraviolet rays as the coloring agent for the ultraviolet curable resin, and the use of an ultraviolet curable resin in the culm. The above-mentioned problems are solved by providing a step of measuring changes in color tone.

作用 このように紫外線を照射することにより色調の変化する
着色剤を使用することによって、電池何個に紫外線を照
射されたか否か目視で選別することができ、また比色計
と連動させることによって定期的に紫外線の光源である
水銀ランプの出力の劣化等をデジタル的に管理すること
が可能となるものである。
Function By using a coloring agent that changes color tone when irradiated with ultraviolet rays, it is possible to visually determine how many batteries have been irradiated with ultraviolet rays, and by linking it with a colorimeter. This makes it possible to periodically digitally manage deterioration in the output of a mercury lamp, which is a light source of ultraviolet light.

実施例 次て本発明の詳細な説明する。第1図は紫外線硬化型樹
脂1を、電池の正極端子2と負極端子30間にこれを絶
縁しかつ内蔵発電要素人を外部に漏出するのを防止する
絶縁バッキング4で形成されるくぼみBに配した電池の
要部断面を示す。
EXAMPLES The present invention will now be described in detail. Figure 1 shows an ultraviolet curable resin 1 placed between a positive terminal 2 and a negative terminal 30 of a battery in a recess B formed by an insulating backing 4 that insulates the resin and prevents the built-in power generating element from leaking outside. A cross-section of the main parts of the installed battery is shown.

ここでの紫外線硬化型樹脂1としては1分子構造上、主
鎖または側鎖に不飽和結合をもつブレポリ7−1主鎖の
末端に不飽和結合を持つプレポリマーが使用され、これ
らのポリマーに紫外線を照射することによって分子内に
ラジカル基を発生させてポリマーをラジカル重合させ硬
化させるものであり、例えば不飽和ポリエステル樹脂、
アクリμ樹脂、エポキシ樹脂等である。また本発明によ
る着色剤としては、その分子構造が分子内にアゾ結合(
−N=N−)を有するアゾ系染料、又は分子内にメチン
結合(−C;H=)を有するメチン系染料を樹脂に対し
0.2〜0.8重量%添加することによって、紫外線の
光量、単位としてはミ+)ジュール/スケアーセンチメ
ー)/しくmJ/L−4)の変化に敏感に、その色調を
変化させることができ、目視でも紫外線が照射されたも
のか、そうでないものかを充分判別できるものである。
As the UV curable resin 1 here, a prepolymer having an unsaturated bond at the end of the main chain of Brepoly 7-1, which has an unsaturated bond in the main chain or side chain due to its single molecule structure, is used. By irradiating ultraviolet rays, radical groups are generated within the molecule to radically polymerize and harden the polymer. For example, unsaturated polyester resin,
Acrylic μ resin, epoxy resin, etc. Furthermore, the colorant according to the present invention has an azo bond (
By adding 0.2 to 0.8% by weight of an azo dye having -N=N-) or a methine dye having a methine bond (-C;H=) in the molecule to the resin, UV rays can be removed. The color tone can be changed sensitively to changes in the amount of light (unit: mJ/L-4), and it is possible to visually tell whether it has been irradiated with ultraviolet rays or not. It is possible to sufficiently determine whether

アゾ系染料は、前述したようにその分子構造中にアゾ結
合(−N=l(−)を発色団として持つ染料であり具体
的物質としては、例えばB ismarck : Br
own G 、 G hromeBlueB 、 Pr
ocian Yellow R5等がある。メチン系染
料は分子中にメチン結合(−CH=)を持つ染料であシ
、具体的物質としては、Ce1litonFast  
Yellow  7G  、Pinacyanol  
、Cyan土neBlue 、ムm1no Napht
hol Brown 3G等がある。
As mentioned above, an azo dye is a dye having an azo bond (-N=l(-) as a chromophore in its molecular structure, and specific substances include, for example, Bismarck: Br
own G, G hromeBlueB, Pr
There are ocean yellow R5, etc. Methine dyes are dyes with a methine bond (-CH=) in the molecule, and specific substances include Ce1litonFast.
Yellow 7G, Pinacyanol
, Cyan Sat neBlue , Mu m1no Napht
There are hol Brown 3G, etc.

次に第2図は本発明の有効性を実険的に証明したもので
ある。つまり1本発明の染料を用いた場合に紫外線の光
量〔111J/、1i〕を変化させた時の色調の変化を
グラフ化したものであり、横軸に紫外線の光量CIIJ
/、J ] 、縦軸には紫外線硬化型樹脂の硬化前の色
調と、硬化後の色調を比色計で測定し、下式に示す計算
式での色調の変化率の絶対値を示したものである。
Next, FIG. 2 shows practical proof of the effectiveness of the present invention. In other words, it is a graph of the change in color tone when the amount of ultraviolet light [111 J/, 1i] is changed when the dye of the present invention is used, and the horizontal axis shows the amount of ultraviolet light CIIJ.
/, J ], The vertical axis shows the color tone before curing and the color tone after curing of the ultraviolet curable resin, measured with a colorimeter, and shows the absolute value of the rate of change in color tone according to the formula shown below. It is something.

計算式 なお、本実験に際し、紫外線硬化型樹脂としては不飽和
ポリエステル、アクリy樹脂、エポキシ樹脂の3種項そ
れぞれに1着色材として本発明のアゾ系、メチン系染料
を比較用として分子の主体構造がアントラキノン系、ア
クリジン系、アジン系。
Calculation formulas In this experiment, the UV-curable resins used were one for each of three types: unsaturated polyester, acrylic resin, and epoxy resin.The azo and methine dyes of the present invention were used as colorants for comparison, and the main molecules were The structure is anthraquinone, acridine, and azine.

ジフェニルメタン系、インジゴ系、フタロシアニン系、
スチ2やベン系、トリフェニルメタン系染料をそれぞれ
用い、添加量としては、紫外線硬化型樹脂に対し0.3
重量%添加し、紫外線はv600〔mJ/c(〕で30
秒間照射させたものである。結果としてはそれぞれの場
合いずれも第2図に示すような傾向を示した。なお第2
図中の比較用サンプルとしてはインジゴ系、スチルベン
系染料の場合を示し念。紫外線硬化型樹脂としてはアク
リル樹脂を用いた場合の結果を示す。
diphenylmethane type, indigo type, phthalocyanine type,
The amount of addition is 0.3% per ultraviolet curable resin.
Added by weight%, UV rays were 30 at v600 [mJ/c (])
It was irradiated for seconds. The results showed a tendency as shown in FIG. 2 in each case. Furthermore, the second
The comparative samples in the figure are indigo and stilbene dyes. The results are shown when acrylic resin was used as the ultraviolet curable resin.

発明の効果 以上、第2図に示す実験結果から明らかなように本発明
によるアゾ系、メチン系の染料を用いたものは紫外線の
光電の変化に鋭敏に反応し、万一紫外、!lの光源であ
る水銀ランプの出力が低下した場合などは、その色調の
変化を目視、あるいは比色計等によって管理する工程を
設けることにより樹脂の未硬化品の生産を未然に防止で
き、電池表面に未硬化の樹脂が付着したり、生産ライン
を未硬化の樹脂で汚染することがなくなり、品質管理上
、ならびに生産管理上極めて有効な電池製造法を提供で
きるものである。
In addition to the effects of the invention, as is clear from the experimental results shown in Figure 2, the dyes using azo and methine dyes according to the present invention respond sensitively to changes in photoelectricity of ultraviolet light, and even if ultraviolet light,! If the output of the mercury lamp, which is the light source of the battery, decreases, by setting up a process to monitor the change in color tone visually or using a colorimeter, etc., it is possible to prevent the production of uncured resin products. This eliminates the possibility of uncured resin adhering to the surface or contaminating the production line with uncured resin, making it possible to provide a battery manufacturing method that is extremely effective in terms of quality control and production control.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の着色材を用いた紫外線硬化型樹脂を電
池端子間のくぼみ部分に充填した電池の要部断面図、第
2図は本発明の発色剤の色調の変化率を比較したグラフ
である。 1・・・・・・紫外線硬化型樹脂、2・・・・・・正極
端子、3・・・・・・負極端子、4・・・・・・絶縁バ
ッキング、ム・・・・・・発電要素、B・・・・・・く
ぼみ。
Figure 1 is a cross-sectional view of the main parts of a battery in which the recesses between the battery terminals are filled with an ultraviolet curable resin using the coloring agent of the present invention, and Figure 2 is a comparison of the rate of change in color tone of the coloring agent of the present invention. It is a graph. 1...UV curing resin, 2...Positive terminal, 3...Negative terminal, 4...Insulating backing, Mu...Power generation Element, B...Indentation.

Claims (3)

【特許請求の範囲】[Claims] (1)電池の正極端子および負極端子の同一面に露出す
る端部の間に形成されたくぼみ部分に、紫外線を照射す
ることによって色調が変化する着色剤で着色された紫外
線硬化型の樹脂を充填した電池。
(1) A UV-curable resin colored with a coloring agent that changes color when exposed to ultraviolet light is applied to the depression formed between the ends of the battery's positive and negative terminals that are exposed on the same side. Filled battery.
(2)着色剤が、アゾ系染料又はメチン系染料である特
許請求の範囲第1項記載の電池。
(2) The battery according to claim 1, wherein the colorant is an azo dye or a methine dye.
(3)電池の正極端子および負極端子の同一面に露出す
る端部の間に形成されたくぼみ部分に紫外線によって色
調の変化する着色剤を含んだ紫外線硬化型樹脂を充填す
る電池の製造法であって、紫外線の照射前の色調と、照
射後の色調の変化を測定する工程を有した電池の製造法
(3) A battery manufacturing method in which a recess formed between the ends of the battery's positive and negative terminals exposed on the same side is filled with an ultraviolet curable resin containing a colorant whose color tone changes with ultraviolet light. A method for manufacturing a battery that includes a step of measuring the color tone before irradiation with ultraviolet rays and the change in color tone after irradiation.
JP63334458A 1988-12-28 1988-12-28 Cell and manufacture thereof Pending JPH02177252A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63334458A JPH02177252A (en) 1988-12-28 1988-12-28 Cell and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63334458A JPH02177252A (en) 1988-12-28 1988-12-28 Cell and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH02177252A true JPH02177252A (en) 1990-07-10

Family

ID=18277612

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63334458A Pending JPH02177252A (en) 1988-12-28 1988-12-28 Cell and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH02177252A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0824276A1 (en) * 1996-08-14 1998-02-18 Three Bond Co., Ltd. Visible-light or near-infrared-light curing resin for battery-insulating seal
US6146789A (en) * 1996-08-15 2000-11-14 Three Bond Co., Ltd. Battery having a visible-light or near-infrared-light curing resin as an insulating seal

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56159055A (en) * 1980-05-13 1981-12-08 Yuasa Battery Co Ltd Battery
JPS60123538A (en) * 1983-12-08 1985-07-02 Showa Highpolymer Co Ltd Ultraviolet-curable prepreg

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56159055A (en) * 1980-05-13 1981-12-08 Yuasa Battery Co Ltd Battery
JPS60123538A (en) * 1983-12-08 1985-07-02 Showa Highpolymer Co Ltd Ultraviolet-curable prepreg

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0824276A1 (en) * 1996-08-14 1998-02-18 Three Bond Co., Ltd. Visible-light or near-infrared-light curing resin for battery-insulating seal
US6146789A (en) * 1996-08-15 2000-11-14 Three Bond Co., Ltd. Battery having a visible-light or near-infrared-light curing resin as an insulating seal

Similar Documents

Publication Publication Date Title
US4822536A (en) Method of encapsulating an electronic component with a synthetic resin
PT882086E (en) Composition exhibiting improved fluorescent response
KR960702119A (en) Partially polymerized resins
TWI447159B (en) A photohardenable resin composition having shading and adhesion, and a hardened product thereof
JPS6217729A (en) Production of cell for sealing liquid crystal
TW200530327A (en) Light shielding sealing agent for liquid crystal display element, vertical conducting material, and liquid crystal display element
US3808073A (en) Method of assembling plastic apparatus
JPH02177252A (en) Cell and manufacture thereof
US4494825A (en) Fill port seal with first and second photosensitizers
JPH0431823A (en) Patterned light control material and production thereof
KR100774421B1 (en) Process for producing electrophoretic display device
JPS6129821A (en) Liquid crystal display element
CN110452586A (en) A kind of preparation method of electrochromism film
JPS59113422A (en) Total solid-state electrochromic display
JPS6141129A (en) Method for producing electrochromic apparatus
JPH0322347A (en) Manufacture of battery
EP0116584B1 (en) Thermochromic composition
JPS6289930A (en) Production of liquid crystal cell
CN107608179A (en) For the color blocking material of color membrane substrates and the preparation method of color membrane substrates color blocking pattern
JPH01246396A (en) Formation of electrically conductive film
JPH0127539B2 (en)
JPH0793131B2 (en) Battery
JP4493906B2 (en) Liquid crystal display device and manufacturing method thereof
CN210090882U (en) Electrochromic glass
KR950033597A (en) Manufacturing method of color filter and liquid crystal display