JPH02157725A - Liquid crystal element - Google Patents

Abstract

PURPOSE:To obtain the liquid crystal element which has a stable memory characteristic at the time of multiplex driving and has a good contrast by subjecting the silane coupling agent treated layers formed on electrodes to a rubbing treatment thereby executing a uniaxial orientation treatment. CONSTITUTION:SiO2 is deposited by evaporation as an insulating layer on the surfaces of substrates 1 which are sputtered with, for example, indium tin oxide ITO, as the transparent electrodes 2, then an amino silane soln. is applied thereon by using a spinner and is calcined. The calcined coating is subjected to the rubbing treatment. The resulted substrates are assembled via a spacer 4 to attain about 2mum cell thickness. The liquid crystal material 5 is injected between these substrates. The AC electric field of 15 Hertz and 25V is thereafter applied to this element to unify the orientation of the liquid crystal. The liquid crystal element which has the stable memory characteristic at the time of multiplex driving and has the good contrast is obtd. in this way.

Description

DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a liquid crystal element using a ferroelectric liquid crystal composition.

[Background Art] In recent years, liquid crystal displays have come to be widely used as display elements due to their characteristics such as thinness, light weight, and low power consumption. However, most of these display elements are TN type display elements using nematic liquid crystals, and their response is still slow in application fields requiring high multiplexing, and improvements are needed. Under these circumstances, chiral smectic liquid crystals having optically active sites are attracting attention.

The chiral smectic C phase (hereinafter referred to as "SmC" phase) of this chiral smectic liquid crystal exhibits ferroelectricity,
Because of the large coupling force between the spontaneous polarization (hereinafter referred to as Ps) and the electric field, it is possible to exhibit high-speed response that cannot be achieved with a TN type liquid crystal display element. Furthermore, it is known that the SmC'' phase exhibits memory properties in sufficiently thin cells by appropriately controlling the orientation (Clarke et al.

Applied Physics Letters, 36. 89
9.1980) Development is progressing for high-speed shutters and high multiplex display devices.

As factors governing the response speed of ferroelectric liquid crystals, Ps,
Possible factors include the viscosity of the liquid crystal and the orientation of the liquid crystal within the cell. −
A typical liquid crystal composition exhibits a smectic A phase (hereinafter referred to as SmA phase) at a temperature above the SmC' phase.A ferroelectric liquid crystal composition with such a phase series exhibits a smectic A phase (hereinafter referred to as SmA phase) at a temperature above the SmC' phase. As the PS gradually increases, -1 for boat fishing.
0 to 30 nc/cm2. However, the response speed of liquid crystal gradually slows down to 100 to 300 μs at room temperature. This is thought to be because the viscosity of the liquid crystal increases as the temperature decreases. In addition, regarding other liquid crystal compounds, Onishi et al. (National Technical Report* VO
L33. Nol, Feb. 1987) showed that a large P of 220 nc/c rrf
Liquid crystal compounds having s are also known. The response speed of this compound is very fast at 20 μs. That is, high-speed response of liquid crystal can be easily achieved by increasing Ps, but in liquid crystal compounds with large Ps, substituents such as C1, Coo, OCH3, ON, etc. are located near the asymmetric carbon site. In many cases, the viscosity in the bulk state is expected to be quite large, judging from the molecular skeleton.

[Problem to be solved by the invention] However, as Ps is increased in order to increase the speed of response of the liquid crystal, the interaction between the liquid crystal and the substrate surface increases, and the alignment of the liquid crystal within the cell becomes more likely to be disturbed. . FIGS. 2 to 4 schematically show the switching process of a ferroelectric liquid crystal cell. In the figure, 11 is a substrate, 12 is an alignment film, 13 is a C director, 14 is spontaneous polarization, and 15 is the direction and size of a dipole on the surface of the substrate in contact with the liquid crystal.

FIG. 4 shows a case where the dipoles on the substrate surface have the same orientation and size. As shown in (b) and (c), when an electric field is applied, the spontaneous polarization 14 is oriented in the direction of the electric field, but when no electric field is applied, the spontaneous polarization 14 is oriented as shown in (a).
The interaction between the base member and the dipole 15 on the substrate surface is large, and a twisted state is likely to occur near one of the substrate surfaces.

FIG. 3 shows a case where the orientation of the dipole on the surface of the substrate is different. (b) and (c) show a bistable state depending on the direction when an electric field is applied as in FIG. 4. However, in the absence of an electric field, as shown in (a), the spontaneous polarization 14 is oriented due to the influence of the dipoles 15 on both substrate surfaces, and one of the bistable states becomes extremely stable, resulting in a one-sided memory state.

FIG. 2 shows a case where the dipoles on the surface of the substrate have the same direction but different sizes. When an electric field is applied, a bistable state is shown depending on the direction of the electric field as shown in (b) and (c), but when no electric field is applied, a spontaneous state 8i occurs due to the influence of the dipole 15 on the substrate surface.
14 is oriented, resulting in a one-sided memory state with remaining twist as shown in a).

None of these orientations are suitable for multiplex driving of ferroelectric liquid crystals using bistable memory.

In this way, the larger Ps is made for the purpose of increasing the response speed, the more easily the twisted state or one-sided memory state is assumed as described above.

On the other hand, the magnitude of Ps also affects the optical characteristics of the liquid crystal element when a driving waveform is applied to the liquid crystal element.

According to our detailed experiments, the threshold characteristic of the liquid crystal element is P
It was found that it changes depending on the size of s.

That is, when a voltage pulse as shown in FIG. 5 is applied, the threshold of the liquid crystal when changing from the first stable state of the ferroelectric liquid crystal to the second stable state as shown in FIG. The threshold value of the liquid crystal when changing from the second stable state to the first stable state is different, and when a multiplex drive waveform is applied, the contrast of the liquid crystal element decreases. To describe the influence of Ps on this hysteresis phenomenon, it has been found that the larger Ps is, the greater the hysteresis becomes.

The present invention is intended to solve the above problems, and its purpose is to provide a liquid crystal element that has stable memory properties and good contrast during multiplex driving.

[Means for solving the problem] As a result of detailed research, we found that there is an optimal value for the magnitude of spontaneous polarization of ferroelectric liquid crystals.

That is, the liquid crystal element of the present invention includes (1) a liquid crystal cell formed by sandwiching a ferroelectric liquid crystal between two sets of substrates having electrodes, and a layer treated with a silane coupling agent such as aminosilane formed on at least one electrode; It is characterized in that it is subjected to rubbing treatment to perform uniaxial alignment treatment, injected with ferroelectric liquid crystal, and then further applied with an alternating electric field to change the alignment state.

(2) The above liquid crystal device is characterized in that at least one of each component of the ferroelectric liquid crystal is a liquid crystal compound exhibiting a smectic C phase.

(3) The absolute value of the spontaneous polarization of the ferroelectric liquid crystal is O over the entire temperature range in which it exhibits a ferroelectric liquid crystal phase.
, Inc/cn (~40 nc/cm).

(4) The absolute value of the spontaneous polarization of the ferroelectric liquid crystal is 0 over the entire temperature range in which it exhibits a ferroelectric liquid crystal phase.
．． It is characterized by being in the range of 1 nc/c to 20 nc/c rri.

(5) The ferroelectric liquid crystal is characterized in that it exhibits a chiral smectic C phase.

The liquid crystal element used in the present invention can use a polarizing plate if necessary.

As the electrode used in the present invention, a transparent electrode such as indium tin oxide or a metal vapor deposited film such as aluminum or gold can be used.

Substrates used in the present invention include glass, transparent plastic substrates, or glass at least one of which is opaque;
Plastic, metal, etc. can be used.

An insulating layer such as SiO2 can be provided on the electrode used in the present invention, if necessary.

As the liquid crystal used in the present invention, ferroelectric smectic liquid crystals such as pyrimidine type, pyrazine type, biphenyl type, ester type, pyridine type, diester type, azo type, Schiff type, and tolan type can be used. Also, other liquid crystal materials may be used.

The ferroelectric liquid crystal phase of the ferroelectric smectic liquid crystal used in the present invention is preferably the SmC'' phase, but other chiral smectic phases can also be used.

The value of Ps of the ferroelectric liquid crystal used in the present invention is 0.1 to
40 nc/cm2 is desirable, more preferably 0.1
~20 nc/c i.

In the rubbing direction of the present invention, the angle formed by the upper substrate and the lower substrate can be changed as necessary. Only one substrate may be rubbed.

The silane coupling agent used in the present invention is preferably aminosilane, but silane coupling agents such as vinylsilane and chlorosilane can also be used.

The peak value of the alternating electric field applied in the present invention is 15V to 40V.
is desirable, but can be made higher or lower as needed.

The frequency of the alternating electric field applied in the present invention is a frequency at which the ferroelectric liquid crystal sufficiently responds, and is preferably from 1 hertz to 100 hertz, but it can be made higher or lower as necessary.

As described above, the present invention is not limited to liquid crystal materials or alignment methods, and can be applied to various manufacturing processes. EXAMPLES The present invention will be explained in more detail with reference to Examples below.

[Example] (Example 1) The liquid crystal composition used in this example is shown below.

1) CsH+v@◎0CaH+s
25χ2)CsHn@◎0C6HI3
25χ3)CeH+4COO◎◎C5Hu
15χ4) CBHI? ◎◎Coo◎Cs
H++ 15χ The PsO value of the liquid crystal composition of this example was 14 nc/cbo.

SiO2 was deposited as an insulating layer on the surface of a substrate on which ITO (indium tin oxide) was sputtered as a transparent electrode, and an aminosilane solution was applied using a spinner.

It was baked at 150°C for 30 minutes and rubbed. The obtained substrate is separated by about 2 μm through a spacer as shown in Figure 1.
The liquid crystal composition was injected into two chambers so that the cell thickness was . Thereafter, an alternating electric field of 15 h/25 V was applied to adjust the orientation of the liquid crystal. This liquid crystal element is 1/64 d
When driven by multiplex, the memory property was good and the contrast was 15.

(Example 2) The liquid crystal composition used in this example is shown below.

1) CvH+s@@0CaH+a
25χ2) CsHts@◎0CvH+s
25χ3)C8H17◎Coo◎◎CsHo
15χ4) C8H17G@Coo◎C5H
o152 The PS value of the liquid crystal composition of this example was 13 n c / c i.

A substrate prepared in the same manner as in Example 1 was assembled with a spacer interposed therebetween so that the cell thickness was approximately 2 μm.

Thereafter, the above liquid crystal composition was injected. Thereafter, an alternating electric field of 15 h/25 V was applied to adjust the orientation of the liquid crystal. When this liquid crystal element was driven at 1/64 duty multiplex, it had good memory properties and a contrast of 18.

(Example 3) The liquid crystal composition used in this example is shown below.

2) CsH+e@@octH+s 5z 3) CeH+v@Coo◎◎C5Hu
152 The Ps value of the liquid crystal composition of this example is 15 nc/c
It was m.

A substrate prepared in the same manner as in Example 1 was assembled with a spacer interposed therebetween so that the cell thickness was approximately 2 μm.

Thereafter, the above liquid crystal composition was injected. Then 15 hertz,
An alternating electric field of 25 V was applied to align the liquid crystal. When this liquid crystal element was driven at 1/64 duty multiplex, the memory property was good and the contrast was 15.

(Example 4) 1) CsHn@@ocaH+a 25
$2) C*H+o C3H1325χ3)C8
HI? ◎Coo◎◎CsH 15χ
lCH3 The Ps value of the liquid crystal composition of this example was 16 nc/c.

A substrate prepared in the same manner as in Example 1 was assembled with a spacer interposed therebetween so that the cell thickness was approximately 2 μm. Thereafter, the above liquid crystal composition was injected. Thereafter, an alternating electric field of 15 Hz and 25 V was applied to align the liquid crystal. This liquid crystal element is 1/
When driven with a 64 duty multi-breeding system, the memory performance was good and the contrast was 1 day.

Although the embodiments have been described above, the present invention is not limited to the above-mentioned embodiments, but similar effects can be obtained with a wide variety of other liquid crystal materials, alignment materials, alignment methods, etc. Furthermore, this liquid crystal element can be applied to liquid crystal televisions, liquid crystal displays, liquid crystal shutters, and the like.

[Effects of the Invention] As described above, according to the present invention, it is possible to provide a liquid crystal element that has stable memory properties and good contrast during multiplex driving.

[Brief explanation of the drawing]

FIG. 1 is a diagram schematically showing a liquid crystal element of the present invention. Figures 2 (al to (C)) are diagrams schematically showing the orientation states of ferroelectric liquid crystals. Figures 3 (a) to (C) are diagrams schematically showing the orientation states of ferroelectric liquid crystals. FIG. 4(a) to (C) are diagrams schematically showing the alignment state of ferroelectric liquid crystal. FIG. 5 is a diagram showing the applied voltage pulse during threshold measurement. FIG. 6 is a diagram showing the optical response of the liquid crystal when a voltage pulse is applied during threshold measurement. 1. Substrate 2, electrode 3° alignment film 4 varnish spacer 5 , Liquid crystal 11; Substrate 12: Alignment film 13: C director 14: Spontaneous polarization 15: Direction and size of the dipole on the surface of the substrate in contact with the liquid crystal Name) Nato - Juhiki H (αri first' wo (C)

Claims (5)

[Claims] (1) In a liquid crystal cell in which a ferroelectric liquid crystal is sandwiched between two sets of substrates having electrodes, a layer treated with a silane coupling agent such as aminosilane formed on at least one electrode is subjected to a rubbing treatment to achieve uniaxial alignment. A liquid crystal element characterized in that it undergoes processing, injects ferroelectric liquid crystal, and then further applies an alternating electric field to change its alignment state. (2) The liquid crystal device according to claim 1, wherein at least one kind of each component of the ferroelectric liquid crystal is a liquid crystal compound exhibiting a smectic C phase. (3) The absolute value of the spontaneous polarization of the ferroelectric liquid crystal is 0 over the entire temperature range in which the ferroelectric liquid crystal phase is exhibited.
．． 3. The liquid crystal element according to claim 1, wherein the liquid crystal element is in the range of 1 nc/cm^2 to 40 nc/cm^2. (4) The absolute value of the spontaneous polarization of the ferroelectric liquid crystal is 0 over the entire temperature range in which it exhibits a ferroelectric liquid crystal phase.
．． The liquid crystal element according to claim 1 or 2, characterized in that the liquid crystal element is in the range of 1 nc/cm^2 to 20 nc/cm^2. (5) The liquid crystal device according to any one of claims 1 to 3, wherein the ferroelectric liquid crystal exhibits a chiral smectic C phase.