JPH0215253A - Transparent diazo photosensitive film - Google Patents
Transparent diazo photosensitive filmInfo
- Publication number
- JPH0215253A JPH0215253A JP16623388A JP16623388A JPH0215253A JP H0215253 A JPH0215253 A JP H0215253A JP 16623388 A JP16623388 A JP 16623388A JP 16623388 A JP16623388 A JP 16623388A JP H0215253 A JPH0215253 A JP H0215253A
- Authority
- JP
- Japan
- Prior art keywords
- film
- transparent
- diazo
- photosensitive film
- lower alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 title claims abstract description 19
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 150000001450 anions Chemical class 0.000 claims abstract 2
- 150000008049 diazo compounds Chemical class 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010408 film Substances 0.000 description 32
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 102220347004 c.89G>A Human genes 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
Description
【発明の詳細な説明】
〔技術分野〕
本発明は、遮光性にすぐれた発色を与える透明性ジアゾ
感光フィルムに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a transparent diazo photosensitive film that provides color development with excellent light blocking properties.
透明フィルム上に遮光性の発色を与えるシアン感光層を
形成した透明性ジアゾ感光フィルムは知られている。こ
のようなフィル１１は、プリン１〜基板作成用、各種印
刷原版作成用のフォ１へマスクに用いられる。A transparent diazo photosensitive film is known in which a cyan photosensitive layer that provides light-shielding coloring is formed on a transparent film. Such a film 11 is used as a mask for the film 1 for producing print 1 to substrates and for producing various printing original plates.
従来、シアン感光材料のうちで比較的良好な遮光性発色
を与えるものとして、以下に示す２種のジアゾ化合物（
ａ）、（ｂ）とカプラー（ｃ）の組合せが知られている
（特開昭６０−１．６５６４５号）。Conventionally, among cyan photosensitive materials, the following two types of diazo compounds (
A combination of a), (b) and coupler (c) is known (Japanese Unexamined Patent Publication No. 1.65645/1982).
（ｂ） ｏ’：Ｎ％、Ｂｒ。(b) o': N%, Br.
しかし、前記した従来の感光材料は、遮光性、感度の点
で未だ満足し得るものではなかった。また、充分な透明
性を有していない等の問題を残していた。However, the conventional photosensitive materials described above are not yet satisfactory in terms of light-shielding properties and sensitivity. In addition, there remain problems such as not having sufficient transparency.
本発明者らは、従来技術に見られる前記問題点を解決す
るために種々研究を重ねた結果、特定のジアゾ化合物に
２種の特定のカプラーを組合せることによりその問題点
を解決し得ることを見出し、本発明を完成するに到った
。The present inventors have conducted various studies to solve the above-mentioned problems found in the prior art, and have discovered that the problems can be solved by combining two specific couplers with a specific diazo compound. They discovered this and completed the present invention.
即ち、本発明によれば、下記一般式で表わされるジアゾ
化合物（１）と、そのカプラーとして、フェニルフェノ
ール（ｎ）及びＮ−（２’−ヒドロキシ低級アルキル）
−β−レゾルシルアミド（ｍ）とを含有する感光層を透
明フィルム上に形成したことを特徴とする透明性ジアゾ
感光フィルムが提供される。That is, according to the present invention, a diazo compound (1) represented by the following general formula, and phenylphenol (n) and N-(2'-hydroxy lower alkyl) as couplers thereof.
A transparent diazo photosensitive film is provided, characterized in that a photosensitive layer containing -β-resorcylamide (m) is formed on a transparent film.
（ｎ） ０（ト。(n) 0 (g.
前記式中、
Ｒ１及びＲ２は低級アルキル基を示し、Ｒ３０Ｈはヒ１
（ロキシ低級アルキル基を示す。低級アルキル基として
は、メチル基、エチル基、プロピル基、ブチル基等が挙
げられる。Ｘはアニオンを示す。アニオンの好ましい具
体例としては、ＰＦイＢＦ、、−ＣＱ’ １／２ＺｎＣ
Ｑ２等が挙げられる。In the above formula, R1 and R2 represent a lower alkyl group, and R30H represents a
(Represents a Roxy lower alkyl group. Examples of the lower alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, etc. CQ' 1/2ZnC
Examples include Q2.
本発明において、ジアゾ化合物（１）とカップラー（■
）、（ｍ）の使用割合は、ジアゾ化合物１モルに対し、
全カプラー［（Ｕ ）＋ （ｍ ）〕ｏ０ｇ〜２．０モ
ル、好ましくは１．２〜１．６モルである。また、全カ
プラーに対し、カプラー（ＩＩ）の使用割合は、１〜１
５モル％、好ましくは３〜７モル２及びカプラー（ｍ）
の使用割合は、８５〜９９モル％、好ましくは９３〜９
７モルぶである。In the present invention, the diazo compound (1) and the coupler (■
), (m) are used in proportions of 1 mole of diazo compound,
Total coupler [(U)+(m)]o0 g to 2.0 mol, preferably 1.2 to 1.6 mol. In addition, the ratio of coupler (II) used to all couplers is 1 to 1.
5 mol %, preferably 3 to 7 mol 2 and coupler (m)
The usage ratio of is 85 to 99 mol%, preferably 93 to 9
It is 7 molebu.
本発明のジアゾ感光フィルムは、透明性を有する支持体
フィルム上に、前記ジアゾ化合物とカプラーを含む塗布
液を塗布乾燥することによって製造される。支持体フィ
ルムとしては、例えば、ポリエステルフィルムや、ポリ
アミドフィルム、ポリ塩化ビニルフィルム、ポリプロピ
レンフィルム等のプラスチックフィルムの他、トレーシ
ングペーパ、セルローストリアセテートフィルム等が挙
げられる。The diazo photosensitive film of the present invention is produced by coating and drying a coating solution containing the diazo compound and coupler on a transparent support film. Examples of the support film include plastic films such as polyester film, polyamide film, polyvinyl chloride film, and polypropylene film, as well as tracing paper and cellulose triacetate film.
塗布液には、ジアゾ化合物及びカプラーを支持体フィル
ム上に結着させるためのバインダーが添加されるが、こ
のバインダーとしては、例えば、ポリビニルアルコール
、ポリビニルブチラール、ニトロセルロース、カルボキ
シメチルセルロース等の各種の高分子物質が用いられる
。塗布液に用いる溶剤としては、慣用のもの、例えば、
水、アルコール、メチルエチルケトン、エチルセロソル
ブ、ジメチルホルムアミド等が挙げられる。A binder for binding the diazo compound and the coupler onto the support film is added to the coating solution, and examples of this binder include various polymers such as polyvinyl alcohol, polyvinyl butyral, nitrocellulose, and carboxymethyl cellulose. Molecular substances are used. As the solvent used in the coating solution, conventional solvents such as
Examples include water, alcohol, methyl ethyl ketone, ethyl cellosolve, dimethyl formamide, and the like.
また、塗布液には、慣用の補助成分、例えば、安定化剤
として、クエン酸、酒石酸、スルホサリチル酸、ｐ−ト
ルエンスルホン酸等、酸化防止剤として、チオ尿素、ジ
フェニルチオ尿素等を添加し得る他、紫外線吸収剤、染
料、界面活性剤、帯電防止剤、マット化剤等を添加する
ことができる。The coating solution may also contain conventional auxiliary components such as citric acid, tartaric acid, sulfosalicylic acid, p-toluenesulfonic acid, etc. as stabilizers, and thiourea, diphenylthiourea, etc. as antioxidants. In addition, ultraviolet absorbers, dyes, surfactants, antistatic agents, matting agents, etc. can be added.
本発明のジアゾ感光フィルムは、通常のジアゾ感光フィ
ルムと同様にして露光及び現像を行うことによりフィル
ム表面に発色画像又は透明画像を形成することができる
。即ち、露光には水銀灯を用いることができるし、現像
にはアンモニアガス等のアルカリ剤を用いることができ
る。このような露光及び現像により得られるフィルム上
の画像は陽画であって露光部が透明で、非露光部が色素
部（着色部）となる。従って、透明画像を得るには、透
明画像を有するネガフィルムを用いて、露光及び現像を
行えばよい。The diazo photosensitive film of the present invention can form a colored image or a transparent image on the film surface by performing exposure and development in the same manner as a normal diazo photosensitive film. That is, a mercury lamp can be used for exposure, and an alkaline agent such as ammonia gas can be used for development. The image on the film obtained by such exposure and development is a positive image in which the exposed areas are transparent and the non-exposed areas are pigmented areas (colored areas). Therefore, in order to obtain a transparent image, exposure and development may be performed using a negative film having a transparent image.
本発明のジアゾ感光フィルムに用いられるジアゾ化合物
（１）とカプラー（ＩＩ）、（ＩＩＩ）との組合せは、
反応性′にすぐれるとともに、光分解性にもすぐれたも
ので、短時間での露光及び現像により、高色素濃度の非
露光部と透明性の良い露光部を与える。The combination of diazo compound (1) and couplers (II) and (III) used in the diazo photosensitive film of the present invention is as follows:
It has excellent reactivity and photodegradability, and can provide unexposed areas with high dye density and exposed areas with good transparency by exposure and development in a short time.
そして、この場合の非露光部に形成され色素画像は、遮
光性にすぐれたもので、紫外部の光（波長３５０〜４４
０ｎｍ）の透過を効果的に遮断する。In this case, the dye image formed in the non-exposed area has excellent light-shielding properties, and has ultraviolet light (wavelengths of 350 to 44
0 nm).
本発明のジアゾ感光フィルムは、前記のように、それに
用いるジアゾ化合物とカプラーは反応性にすぐれかつ遮
光性にすぐれた色素を与えるため、支持体フィルム上に
形成させるジアゾ感光層は薄膜のもので十分であり、経
済的である。例えば、ジアゾ感光層の厚みは１０μｍ以
下、通常、７〜８μｍ（Ｋ燥塗布量：０．０５〜０ 、
０９ｇ／ ａＫ ）である。As mentioned above, in the diazo photosensitive film of the present invention, the diazo compound and coupler used therein provide a dye with excellent reactivity and light blocking properties, so the diazo photosensitive layer formed on the support film is a thin film. Sufficient and economical. For example, the thickness of the diazo photosensitive layer is 10 μm or less, usually 7 to 8 μm (K dry coating amount: 0.05 to 0,
09g/aK).
また、本発明のジアゾ感光フィルムは、その生保存性に
おいてもすぐれたものである。Furthermore, the diazo photosensitive film of the present invention has excellent shelf life.
次に本発明を実施例によりさらに詳細に説明する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例］− 下記成分組成の塗布液を常法により調製した。Example】- A coating solution having the following component composition was prepared by a conventional method.
（塗布液）
（１）メチルエチルケトン（ＭＥＫ） １．６５
重量部（２）メチルセロソルブ １６５（
３）合成シリカ ０．７２（５）塩化
ビニル／酢酸ビニル共重合体１５．０３
（６）アクリル酸メチルエステル １６．７（７）塩化
亜鉛 １．２（８）塩化第二スズ
（９）スルホサリチル酸
（１０）酒石酸
（１１）チオ尿素
（１３）フェニルフェノール
７０．６
（１６）フッ素界面活性剤（１０％ＭＥＫ溶液） １
５ ｎ次に、前記塗布液をポリエチレンテレフタレート
フィルム（厚さ：１７５μｍ）上に塗布乾燥してジアゾ
感光フィルムを作製した。(Coating liquid) (1) Methyl ethyl ketone (MEK) 1.65
Part by weight (2) Methyl cellosolve 165 (
3) Synthetic silica 0.72 (5) Vinyl chloride/vinyl acetate copolymer 15.03 (6) Acrylic acid methyl ester 16.7 (7) Zinc chloride 1.2 (8) Stannic chloride (9) Sulfo Salicylic acid (10) Tartaric acid (11) Thiourea (13) Phenylphenol 70.6 (16) Fluorine surfactant (10% MEK solution) 1
5n Next, the coating solution was applied onto a polyethylene terephthalate film (thickness: 175 μm) and dried to prepare a diazo photosensitive film.
以」二で得られたジアゾ感光フィルムについて、以下の
ようにしてその試験を行った。The diazo photosensitive film obtained above was tested in the following manner.
（発色性）
試料フィルム」二にネガフィルムを置き、水銀灯により
露光し、アンモニア現像を行った。得られたフィルム上
の発色濃度及び地肌濃度をマクベス濃度計（ＴＤ−５０
４使用）により測定した。(Color development) A negative film was placed on the second sample film, exposed to light using a mercury lamp, and developed with ammonia. The color density and background density on the obtained film were measured using a Macbeth densitometer (TD-50).
4).
その結果、すぐれた紫外光の遮光性と可視光の透過性を
有する発色が得られた。As a result, a color with excellent ultraviolet light blocking properties and visible light transmittance was obtained.
（生保存性）
試料フィルムを、５０℃、湿度８０％ＲＨの暗室に１週
間保存した後、発色性を上記と同様の方法によって試験
を行なった結果、大きな変化は認められず、良好な生保
存性を示した。(Raw storage stability) After storing the sample film in a dark room at 50°C and 80% RH for one week, the color development was tested using the same method as above. As a result, no major changes were observed, indicating that the film had good storage stability. It showed storage stability.
（耐光性）
発色性の項目で作成した試料サンプルを用いて、フェー
ドメーター（３ｋｔ＋水銀灯）を使用し２０〜３０時間
露光し強制的劣化を試みたが、発色・黄ばみ等に大きな
変化は認められなかった。(Light resistance) Using the sample prepared in the color development section, we exposed it to light for 20 to 30 hours using a fade meter (3kt + mercury lamp) to attempt forced deterioration, but no major changes in color development, yellowing, etc. were observed. There wasn't.
特許出願人 ソ マ −ル株式会社 代 理 人 弁理士 池浦敏明（ばか１名）手 続 補 正 書 平成元年 ２月 １７日Patent applicant: Seoul Co., Ltd. Representative patent attorney: Toshiaki Ikeura (one idiot) Continued Supplementary Positive book 1989 February 17th
Claims (1)
ンを示す） で表わされるジアゾ化合物と、フェニルフェノールと、
Ｎ−（２′−ヒドロキシル低級アルキル）−β−レゾル
シルアミドとを含有する感光層を透明フィルム上に形成
したことを特徴とする透明性ジアゾ感光フィルム。(1) A diazo compound represented by the general formula ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (In the formula, R^1 and R^2 are lower alkyl groups, and X represents an anion);
A transparent diazo photosensitive film characterized in that a photosensitive layer containing N-(2'-hydroxyl lower alkyl)-β-resorcylamide is formed on a transparent film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16623388A JPH0215253A (en) | 1988-07-04 | 1988-07-04 | Transparent diazo photosensitive film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16623388A JPH0215253A (en) | 1988-07-04 | 1988-07-04 | Transparent diazo photosensitive film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0215253A true JPH0215253A (en) | 1990-01-18 |
| JPH0476461B2 JPH0476461B2 (en) | 1992-12-03 |
Family
ID=15827579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16623388A Granted JPH0215253A (en) | 1988-07-04 | 1988-07-04 | Transparent diazo photosensitive film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0215253A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4702433B2 (en) | 2008-11-07 | 2011-06-15 | 富士ゼロックス株式会社 | Developer recovery apparatus and image forming apparatus using the same |
-
1988
- 1988-07-04 JP JP16623388A patent/JPH0215253A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0476461B2 (en) | 1992-12-03 |
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