JPH02129855A - Manufacture of sheet-shaped electrode - Google Patents

Manufacture of sheet-shaped electrode

Info

Publication number
JPH02129855A
JPH02129855A JP63282785A JP28278588A JPH02129855A JP H02129855 A JPH02129855 A JP H02129855A JP 63282785 A JP63282785 A JP 63282785A JP 28278588 A JP28278588 A JP 28278588A JP H02129855 A JPH02129855 A JP H02129855A
Authority
JP
Japan
Prior art keywords
lead plate
current collector
welding
sheet
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63282785A
Other languages
Japanese (ja)
Inventor
Tomoya Murata
村田 知也
Takashi Shimada
隆 嶋田
Yasuhiro Ishiguro
康裕 石黒
Kuniyoshi Nishida
西田 国良
Hiroshi Hamada
浩 浜田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FDK Corp
Original Assignee
FDK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FDK Corp filed Critical FDK Corp
Priority to JP63282785A priority Critical patent/JPH02129855A/en
Publication of JPH02129855A publication Critical patent/JPH02129855A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/536Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/533Electrode connections inside a battery casing characterised by the shape of the leads or tabs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

PURPOSE:To make production easy, to increase discharge performance, and to make lead plate welding control easy by removing a coated positive mix on at least one side of a non-perforated part or part of perforated part extending from the non-perforated part of a metal thin plate, and welding one end of a lead plate to the exposed non-perforated part. CONSTITUTION:A coated positive mix 2 on one side in a specified part of a current collector 1 is removed to expose part of a non-perforated part 1b and part of a perforated part 1a extending from the non-perforated part. The end of a lead plate 3 is placed on the exposed part of the current collector 1 and a pair of welding electrodes of a welder are pressed to the lead plate 3, then the lead plate 3 is spot welded to the current collector to manufacture a sheet- shaped electrode.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 この発明は、シート状電極の製造方法に関し、詳しくは
スパイラル電極構造を有する電池に使用するシート状電
極の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method of manufacturing a sheet-like electrode, and more particularly to a method of manufacturing a sheet-like electrode used in a battery having a spiral electrode structure.

〈従来の技術〉 スパイラル形リチウム電池やニッケルーカドミウム蓄電
池などの電池では、正極と負極とをセパレータを介して
積重したシート状電極体を渦巻状に巻回して作ったスパ
イラル状の発電要素を用い、またこの発電要素を構成す
るスパイラル電極から取り出したリード板を電池缶ある
いは端子板などに電気的に接続する構造が採られる。
<Conventional technology> Batteries such as spiral-shaped lithium batteries and nickel-cadmium storage batteries use spiral-shaped power generation elements made by spirally winding sheet-shaped electrode bodies in which a positive electrode and a negative electrode are stacked with a separator interposed in between. In addition, a structure is adopted in which a lead plate taken out from the spiral electrode constituting the power generation element is electrically connected to a battery can or a terminal plate.

これらの電池に用いる電極、例えばスパイラル形リチウ
ム電池に用いられる正極において、この正極に上記電流
取出し用のリード板を接続する場合、従来は次のような
手順が用いられている。
When connecting the lead plate for taking out the current to the electrode used in these batteries, such as the positive electrode used in a spiral type lithium battery, the following procedure has conventionally been used.

即ち、エクスパンデッドメタル等の全面に孔を形成した
多孔性金属薄板で作った集電体の両面に正極合剤を塗着
し、また乾燥して、集電体に合剤を保持させた帯状体を
作る。次いでこの帯状体をローラなどで圧して正極合剤
を圧縮した後、電池型式に応じた所定寸法に裁断する。
That is, a positive electrode mixture was applied to both sides of a current collector made of a porous thin metal plate with holes formed on the entire surface of expanded metal, etc., and then dried to retain the mixture on the current collector. Make a strip. Next, this strip is pressed with a roller or the like to compress the positive electrode mixture, and then cut into a predetermined size depending on the battery type.

その後、第3図(A)の通り、帯状体の所定部位におい
て、上端から下端までの間の集電体表裏面の正極合剤1
7を一定幅でかき取るなどして除去し、集電体18の表
面を露出させる。その後、第3図(B)の通り、この露
出面に電流取出し用のリード板19を位置させ、また一
対の溶接電極をそれぞれ表裏から押し当て、リード板1
9を正極集電体18に溶接する。
Thereafter, as shown in FIG. 3(A), at a predetermined portion of the strip, the positive electrode mixture 1 is applied to the front and back surfaces of the current collector between the upper end and the lower end.
7 is removed by scraping off a certain width to expose the surface of the current collector 18. Thereafter, as shown in FIG. 3(B), a lead plate 19 for taking out the current is placed on this exposed surface, and a pair of welding electrodes are pressed against each other from the front and back sides of the lead plate 19.
9 is welded to the positive electrode current collector 18.

更に、このままでは発電要素巻回時ないし巻回後におい
てリード板19の露出部などがセパレータを突き破って
負極とショートする危険性があるため、通常はリード板
及び集電体露出部分並びにその周辺部分を覆うように耐
電解液性の絶縁テープ20(保護テープ)を表裏面から
貼り付け、最後に真空乾燥して水分を完全に除去する。
Furthermore, if this continues, there is a risk that the exposed parts of the lead plate 19 will break through the separator and short-circuit with the negative electrode during or after winding the power generation element, so normally the exposed parts of the lead plate, current collector, and their surrounding areas are An electrolyte-resistant insulating tape 20 (protective tape) is applied from the front and back sides so as to cover it, and finally, the moisture is completely removed by vacuum drying.

〈発明が解決しようとする課題〉 しかしながら、上記した従来の製造方法では、電極の上
端から下端まで一定の幅で合剤をかき取っていることか
ら、電極のこのかき取られた部分は放電に寄与せず、そ
の分放電容量上の損失となる。保護テープを貼着する構
造とした場合はこのテープを貼着した部分にある合剤も
反応に関与せず、この度合いがより大きい。
<Problems to be Solved by the Invention> However, in the conventional manufacturing method described above, the mixture is scraped off in a constant width from the upper end to the lower end of the electrode, so this scraped part of the electrode is not susceptible to discharge. There is no contribution, and this results in a corresponding loss in discharge capacity. In the case of a structure in which a protective tape is attached, the mixture in the area where the tape is attached also does not participate in the reaction, and the degree of this reaction is greater.

また、リード板を上記溶接部分において確実に溶接する
必要上、集電体上の合剤を完全に除去しなければならな
いが、集電体の表面が多孔性で凹凸があるためこの除去
作業が容易でないという問題があった。
In addition, in order to reliably weld the lead plate at the welding part, it is necessary to completely remove the mixture on the current collector, but this removal work is difficult because the surface of the current collector is porous and uneven. The problem was that it wasn't easy.

この他、上記のように集電体の多孔部分においてリード
体を溶接する際、溶接用電極がこの孔に入ることがあり
、この場合電極の加圧力の関係などから溶接時にスパー
クが起こること等があり、このため溶接不良が発生し易
く、溶接の管理が難しく、また溶接電極の摩耗が加速さ
れる等の問題がある。
In addition, when welding the lead in the porous part of the current collector as mentioned above, the welding electrode may enter the hole, and in this case, sparks may occur during welding due to the pressure applied by the electrode. Therefore, there are problems such as welding defects are likely to occur, welding is difficult to manage, and wear of the welding electrode is accelerated.

以上の問題に鑑み、この発明は、製造容易で電池の放電
性能向上を図ることができ、またリード板溶接時の管理
容易化が行える、シート状電極の製造方法を提供するこ
とを目的とする。
In view of the above problems, it is an object of the present invention to provide a method for manufacturing a sheet-like electrode that is easy to manufacture, can improve the discharge performance of a battery, and can be easily managed during lead plate welding. .

く課題を解決するための手段〉 この発明のシート状電極の製造方法は、金属薄板に多数
の孔を穿設し且つ少なくとも幅方向片側に非穿設部を有
する帯状のパンチドメタルで作った集電体の両面に合剤
を塗着し、また電流取出し用のリード板を取付けてなる
シート状電極の製造方法であって、前記非穿設部、ある
いはこの非穿設部とこれに続く穿設部の一部に塗着され
た合剤の少なくとも片面側を除去し、またこの除去部分
に露出した前記非穿設部に前記リード板の端部を溶接す
ることを要旨とするものである。
Means for Solving the Problems> The method for manufacturing a sheet-like electrode of the present invention is to produce a sheet-like electrode made of a band-like punched metal having a large number of holes perforated in a thin metal plate and having a non-perforated portion on at least one side in the width direction. A method for manufacturing a sheet-like electrode comprising applying a mixture to both sides of a current collector and attaching a lead plate for taking out a current, the method comprising: the non-perforated portion, or the non-perforated portion and the following. The gist is to remove at least one side of the mixture applied to a part of the perforated part, and to weld the end of the lead plate to the non-perforated part exposed in this removed part. be.

く作用〉 上記のように少なくとも片側に非穿設部を有するパンチ
ドメタルで作った集電体を用い、またこの集電体の非穿
設部、あるいはこの非穿設部とこれに続く穿設部の一部
に塗着された合剤の少なくとも片面側を除去するように
することで、合剤の除去面積が可及的に小さくなり、こ
の結果放電容量の増加が図れる。
As described above, a current collector made of punched metal with a non-perforated portion on at least one side is used, and the non-perforated portion of this current collector, or this non-perforated portion and the subsequent perforated portion are used. By removing at least one side of the mixture applied to a part of the installation part, the area from which the mixture is removed is made as small as possible, and as a result, the discharge capacity can be increased.

また、リード板の溶接に際しては、集電体端部の非穿設
部ないしこれに続く穿設部の一部における合剤を除去す
るのみでよく、このため合剤のかき取りが容易かつ確実
に行え、結果としてリード板溶接作業が著しく簡略化す
る。
In addition, when welding the lead plate, it is only necessary to remove the mixture from the non-perforated part of the end of the current collector or a part of the perforated part following this, making it easy and reliable to scrape off the mixture. As a result, the lead plate welding work is significantly simplified.

更に、集電体の非穿設部においてリード板の溶接を行う
ようにしたので、溶接の管理が容易となり、リード板の
溶接強度が安定し、信頼性向上が図れる。
Furthermore, since the lead plate is welded in the non-perforated portion of the current collector, welding can be easily managed, the welding strength of the lead plate can be stabilized, and reliability can be improved.

〈実施例〉 次に、実施例を説明する。<Example> Next, an example will be described.

第1図(A)において、チタンやステンレスで作った厚
さ0.05mm、幅が24mm程度のバチトメタルから
なる帯状の集電体1の中央から両端にかけての部分は、
直径1.5mm程度の多数の孔が形成された穿設部1a
となっている。またこのシート状集電体1の両側には、
幅2 mm程度の帯状の非穿設部lbがそれぞれ形成さ
れている。
In FIG. 1(A), the part from the center to both ends of the band-shaped current collector 1 made of titanium or stainless steel and made of batite metal with a thickness of 0.05 mm and a width of about 24 mm is as follows.
Perforated part 1a in which many holes with a diameter of about 1.5 mm are formed.
It becomes. Moreover, on both sides of this sheet-like current collector 1,
A band-shaped non-perforated portion lb having a width of about 2 mm is formed respectively.

そして、上記のシート状集電体1の両面に、二酸化マン
ガンを主成分とする正極合剤2をそれぞれ塗着し、乾燥
し、更にローラ等によりプレスして圧縮し、また所定の
長さ(約220mm)に裁断して、第1図(B)のよう
なシート状体を作った。
Then, a positive electrode mixture 2 containing manganese dioxide as a main component is applied to both sides of the sheet-like current collector 1, dried, and compressed by pressing with a roller or the like. A sheet-like body as shown in FIG. 1(B) was made by cutting the sample into pieces of about 220 mm).

次いで、上記のシート状体の片面において、集電体1の
所定部位(図中右端から 107.5〜112 、5 
+n+eの位置)の上縁部分に位置する幅5m。
Next, on one side of the sheet-like body, a predetermined portion of the current collector 1 (from the right end in the figure 107.5 to 112, 5
+n+e position) width 5m located at the upper edge part.

高さ2〜5 mmの部分に塗着された正極合剤2を除去
して、非穿設部tb並びにこれに続く穿設部1aの一部
を第1図(C)の通り露出させた。
The positive electrode mixture 2 coated on the 2 to 5 mm height portion was removed to expose the non-pierced portion tb and a portion of the perforated portion 1a following this as shown in Fig. 1(C). .

その後、集電体1の上記露出部上に、幅3mm。Then, on the exposed part of the current collector 1, a width of 3 mm was applied.

長さ15+nm、厚さ 0.1mmのリード板3の端部
を位置させ、またこのリード板3の上から一対の溶接電
極を押し当て、リード板3を集電体1に抵抗スポット溶
接して、第1図(1))に示した通りの、シート状電極
を作製した。
The end of a lead plate 3 with a length of 15+ nm and a thickness of 0.1 mm was positioned, and a pair of welding electrodes was pressed onto the lead plate 3 to resistance spot weld the lead plate 3 to the current collector 1. A sheet-like electrode as shown in FIG. 1 (1)) was prepared.

尚、上記シート状体の両面において、同様な正極合剤除
去により集電体1の非穿設部1b並びにこれに続く穿設
部1aの一部を露出させ、次いでこの露出部の片面側に
位置させたリード板の端部に溶接電極の一方を、また溶
接電極の他方は露出部の他面側に押し当て、抵抗スポッ
ト溶接によりリード板端部を集電体に溶接するようにし
ても良い。また、溶接方法も抵抗溶接に限定されず、例
えばレーザ溶接などを適宜に用いることが出来る。更に
リード板の溶接部分に耐電解液性の絶縁テープを貼着さ
せてこの部分を保護するようにしても良い。また、合剤
除去部位を非穿設部1bのみとしてもよい。
Incidentally, on both sides of the sheet-like body, the non-perforated part 1b of the current collector 1 and a part of the perforated part 1a following this are exposed by removing the positive electrode mixture in the same manner, and then on one side of this exposed part. One of the welding electrodes is pressed against the end of the positioned lead plate, and the other welding electrode is pressed against the other side of the exposed part, and the end of the lead plate is welded to the current collector by resistance spot welding. good. Furthermore, the welding method is not limited to resistance welding, and for example, laser welding or the like can be used as appropriate. Furthermore, an electrolyte-resistant insulating tape may be attached to the welded portion of the lead plate to protect this portion. Alternatively, the mixture removal portion may be limited to the non-perforated portion 1b.

以上のようにして得たシート状電極を正極とし、また負
極にはリチウムシートを用い、更にこれら正極と負極と
をセパレータを介して積重し、この積重体を渦巻状に巻
回してスパイラル状の発電要素を作った。
The sheet-shaped electrode obtained as described above is used as a positive electrode, and a lithium sheet is used as a negative electrode.The positive electrode and negative electrode are stacked with a separator in between, and this stack is spirally wound to form a spiral. The power generation element was created.

そして、第2図の通り、有底円筒状の電池缶4の内部に
、底部に絶縁板5を介して上記で得た発電要素6を収納
し、また負極7から取り出したリード板8を電池缶底部
に、正極りから導出したリード板3は電池缶開口部に載
置した封口板10にそれぞれ溶接するなどして、直径1
7順。
Then, as shown in FIG. 2, the power generating element 6 obtained above is housed inside a bottomed cylindrical battery can 4 with an insulating plate 5 interposed at the bottom, and a lead plate 8 taken out from the negative electrode 7 is placed inside the battery can. At the bottom of the can, the lead plates 3 led out from the positive electrode are welded to the sealing plate 10 placed in the opening of the battery can.
7th order.

高さ33 、5 +nn+のリチウム電池(本発明品)
を作製した。図中11は絶縁ガスケット、12は端子板
、18はセパレータ、14は外装フィルムである。
Lithium battery with a height of 33.5 +nn+ (product of the present invention)
was created. In the figure, 11 is an insulating gasket, 12 is a terminal board, 18 is a separator, and 14 is an exterior film.

また、上記のパンチドメタルに代えてエキスパンデッド
メタルを集電体に用い、また第3図(A)〜(C)のよ
うにしてリード板を溶接して作った正極を使用した他は
同様にして、直径17mm。
In addition, an expanded metal was used as the current collector instead of the punched metal described above, and a positive electrode made by welding a lead plate as shown in Fig. 3 (A) to (C) was used. Similarly, the diameter is 17mm.

高さ33.5mmのリチウム電池(比較品)を作製した
A lithium battery (comparative product) with a height of 33.5 mm was produced.

そして、これら2つの電池を、環境温度20〜20℃の
範囲において、900mAの電流で3秒間放電した後2
7秒間休止するいうサイクルで終止電圧1,5Vまで続
けるというパルス放電試験を行った所、上記環境温度全
域に亘って、本発明品では比較品に比べ5〜10%放電
性能の向上が確認された。
After discharging these two batteries with a current of 900 mA for 3 seconds at an environmental temperature of 20 to 20°C,
When a pulse discharge test was conducted in which the cycle was paused for 7 seconds and continued up to a final voltage of 1.5V, it was confirmed that the product of the present invention had a 5 to 10% improvement in discharge performance compared to the comparative product over the above environmental temperature range. Ta.

〈発明の効果〉 以上のように、この発明によれば、シート状電極の製造
の容易化が図れ、またリード板の溶接の信頼性が高まる
他、製造されたシート状電極を用いて構成される電池に
おける放電性能の向上が図れる等の効果を奏し、その産
業上の利用価値は大きい。
<Effects of the Invention> As described above, according to the present invention, it is possible to facilitate the manufacture of a sheet-like electrode, improve the reliability of welding a lead plate, and also improve the reliability of welding a lead plate. It is effective in improving the discharge performance of batteries, and has great industrial value.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(A)〜(D)は実施例におけるシート状電極の
製造方法を示した説明図、第2図はこのシート状電極を
用いて構成される電池の断面図、第3図(A)〜(C)
は従来例の説明図である。 1.18・・・集電体、2,17・・・正極合剤、3,
8゜19・・・リード板、4・・・電池缶、6・・・発
電要素、7・・・負極、9・・・正極。 特許出願人  富士電気化学株式会社 代  理  人 尾  股 イ丁 雄 第 麿 図 b 一一一欠「−璽■ 第 図
Figures 1 (A) to (D) are explanatory diagrams showing the manufacturing method of the sheet-shaped electrode in the example, Figure 2 is a cross-sectional view of a battery constructed using this sheet-shaped electrode, and Figure 3 (A )~(C)
is an explanatory diagram of a conventional example. 1.18... Current collector, 2,17... Positive electrode mixture, 3,
8゜19...Lead plate, 4...Battery can, 6...Power generation element, 7...Negative electrode, 9...Positive electrode. Patent Applicant: Fuji Electrochemical Co., Ltd. Representative: Hito Mata I Choo No.b 111 Missing “-Seal■ Fig.

Claims (1)

【特許請求の範囲】[Claims] 1、金属薄板に多数の孔を穿設し且つ少なくとも幅方向
片側に非穿設部を有する帯状のパンチドメタルで作った
集電体の両面に合剤を塗着し、また電流取出し用のリー
ド板を取付けてなるシート状電極の製造方法であって、
前記非穿設部、あるいはこの非穿設部とこれに続く穿設
部の一部に塗着された合剤の少なくとも片面側を除去し
、またこの除去部分に露出した前記非穿設部に前記リー
ド板の端部を溶接することを特徴とするシート状電極の
製造方法。
1. Apply a mixture to both sides of a current collector made of band-shaped punched metal with a large number of holes drilled in a thin metal plate and a non-perforated part on at least one side in the width direction. A method for manufacturing a sheet-like electrode with a lead plate attached,
At least one side of the mixture applied to the non-drilled part, or this non-drilled part and a part of the drilled part following this, is removed, and the non-drilled part exposed to this removed part is A method of manufacturing a sheet-like electrode, comprising welding the ends of the lead plate.
JP63282785A 1988-11-09 1988-11-09 Manufacture of sheet-shaped electrode Pending JPH02129855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63282785A JPH02129855A (en) 1988-11-09 1988-11-09 Manufacture of sheet-shaped electrode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63282785A JPH02129855A (en) 1988-11-09 1988-11-09 Manufacture of sheet-shaped electrode

Publications (1)

Publication Number Publication Date
JPH02129855A true JPH02129855A (en) 1990-05-17

Family

ID=17657051

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63282785A Pending JPH02129855A (en) 1988-11-09 1988-11-09 Manufacture of sheet-shaped electrode

Country Status (1)

Country Link
JP (1) JPH02129855A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113328211A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 High-energy-density lithium primary battery negative plate and preparation method thereof
CN113328210A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 Lithium metal negative plate of lithium battery and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5224522B2 (en) * 1973-04-03 1977-07-01

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5224522B2 (en) * 1973-04-03 1977-07-01

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113328211A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 High-energy-density lithium primary battery negative plate and preparation method thereof
CN113328210A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 Lithium metal negative plate of lithium battery and preparation method thereof
CN113328211B (en) * 2021-05-27 2022-09-27 贵州梅岭电源有限公司 High-energy-density lithium primary battery negative plate and preparation method thereof
CN113328210B (en) * 2021-05-27 2022-09-27 贵州梅岭电源有限公司 Lithium metal negative plate of lithium battery and preparation method thereof

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