JPH02120382A - Adhesive composition - Google Patents
Adhesive compositionInfo
- Publication number
- JPH02120382A JPH02120382A JP27392888A JP27392888A JPH02120382A JP H02120382 A JPH02120382 A JP H02120382A JP 27392888 A JP27392888 A JP 27392888A JP 27392888 A JP27392888 A JP 27392888A JP H02120382 A JPH02120382 A JP H02120382A
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- parts
- fuel
- adhesive composition
- pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 230000001070 adhesive effect Effects 0.000 title claims description 20
- 239000000853 adhesive Substances 0.000 title claims description 19
- 239000003822 epoxy resin Substances 0.000 claims abstract description 19
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 19
- UUODQIKUTGWMPT-UHFFFAOYSA-N 2-fluoro-5-(trifluoromethyl)pyridine Chemical compound FC1=CC=C(C(F)(F)F)C=N1 UUODQIKUTGWMPT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000000446 fuel Substances 0.000 abstract description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 6
- 239000004593 Epoxy Substances 0.000 abstract description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- 229930185605 Bisphenol Natural products 0.000 abstract description 3
- 150000004982 aromatic amines Chemical class 0.000 abstract description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- 238000005336 cracking Methods 0.000 abstract description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 229920006122 polyamide resin Polymers 0.000 abstract description 2
- 230000008961 swelling Effects 0.000 abstract description 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229920001778 nylon Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- WPYCRFCQABTEKC-UHFFFAOYSA-N Diglycidyl resorcinol ether Chemical compound C1OC1COC(C=1)=CC=CC=1OCC1CO1 WPYCRFCQABTEKC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- -1 imidazole 2MZ amine Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【発明の詳細な説明】
く技術分野ン
本発明はメタノール混入ガソリン、いわゆるガソホール
燃料に接触する部品、例えば燃料フィルター、燃料タン
ク等の接着に使用される接着剤組成物に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an adhesive composition used for bonding parts that come into contact with methanol-containing gasoline, so-called gasohol fuel, such as fuel filters and fuel tanks.
〈従来技術〉
近年、ガソホール燃料（以下、燃料という）が車輛用に
使用されているが、燃料フィルター、燃料タンク等の燃
料に接触する部品にあっては、接着剤に耐燃料性が不足
するなめ、接着層にクラック、膨潤、剥離等の問題が多
発していた。<Prior art> In recent years, gasohol fuel (hereinafter referred to as fuel) has been used for vehicles, but adhesives for parts that come into contact with fuel, such as fuel filters and fuel tanks, lack fuel resistance. Problems such as licking, cracking, swelling, and peeling of the adhesive layer occurred frequently.
また、これら部品には近年、金属製のものに代り、耐衝
撃性、耐熱性、耐油性等に優れ、しかも成形加工が簡便
であることからナイロン族の本のが利用されることが多
くなっている。しかしナイロン族のものは接着が難しい
という問題があり、その解決も求められていた。In addition, in recent years, nylon materials have been increasingly used for these parts instead of metal products because they have excellent impact resistance, heat resistance, oil resistance, etc., and are easy to mold. ing. However, nylon materials have the problem of being difficult to adhere to, and a solution to this problem has been sought.
〈発明の目的〉
本発明は叙上の事情に鑑み検討された結果なされたもの
であり、該燃料に接触しても膨潤、クラック、剥離等の
問題が力く、シかもナイロン製部品に対する接着性能に
すぐれた接着剤組成物を提供せんとするものである。<Object of the Invention> The present invention was developed as a result of studies in view of the above-mentioned circumstances, and the present invention has been developed as a result of studies conducted in view of the above-mentioned circumstances. The object is to provide an adhesive composition with excellent performance.
〈発明の開示〉 本発明の要旨は前記の通りであシ以下詳細に説明する。<Disclosure of invention> The gist of the present invention has been described above and will be explained in detail below.
本発明において使用されるエポキシ樹脂はエポキシ当量
１４０〜２００のエポキシ樹脂が使用される。中でもビ
スフェノールＡ、ハロゲン化ビスフェノールＡ１カテコ
ール、クレゾール々どのような多価フェノールのポリグ
リシジルエーテル、グリセリンのような多価アルコール
のポリグリシジルエーテル、ポリカルボン酸とエビクロ
ルヒドリンから得られるポリグリシジルエステル、ノボ
２ツク型フエノール樹脂とエピクロルヒドリンとを反応
させて得られるエポキシノボラック、シクロヘキセンオ
キシド系の環状脂肪族エポキシなどが好ましい。The epoxy resin used in the present invention has an epoxy equivalent of 140 to 200. Among them, polyglycidyl ethers of polyhydric phenols such as bisphenol A, halogenated bisphenol A1 catechol, and cresol, polyglycidyl ethers of polyhydric alcohols such as glycerin, polyglycidyl esters obtained from polycarboxylic acids and shrimp chlorohydrin, Preferable examples include epoxy novolac obtained by reacting a novolac type phenol resin and epichlorohydrin, and a cycloaliphatic epoxy based on cyclohexene oxide.
該エポキシ樹脂の硬化剤としては脂肪族アミン、芳香族
アミン、ポリアミドアミンならびにポリアミド樹脂等が
該エポキシ樹脂ｉ ｏ ｏ’ｉ量部（七２１下車に部と
いう）に対し１０〜１００部が配合されるＯ
次に該エポキシ樹脂の粘度調節、ならびに耐燃料性、接
着性等を付与する目的で、レゾルシノールジグリシジル
エーテルが該エポキシ樹脂１００部に対し５〜６０部配
合される。５部以下ではナイロン等被着体に対する密着
性が劣り、６０部以上では耐燃料性が劣り好ましくない
。一般にエポキシ樹脂の粘度調節、ならびに流動性の向
上させるために反応性希釈剤が使用される。しかし、反
応性希釈剤が配合されると一般に耐油性、耐熱性、接着
力等、性能が大幅に低下するが該レゾルシノールジグリ
シジルエーテルが使用された場合には性能の低下が認め
られない。As a curing agent for the epoxy resin, 10 to 100 parts of aliphatic amine, aromatic amine, polyamide amine, polyamide resin, etc. are blended with respect to the amount of parts of the epoxy resin (referred to as parts for getting off at 721). Next, 5 to 60 parts of resorcinol diglycidyl ether is added to 100 parts of the epoxy resin for the purpose of controlling the viscosity of the epoxy resin and imparting fuel resistance, adhesive properties, etc. If the amount is less than 5 parts, the adhesion to adherends such as nylon will be poor, and if it is more than 60 parts, the fuel resistance will be poor. Reactive diluents are generally used to control the viscosity of epoxy resins and to improve fluidity. However, when a reactive diluent is blended, properties such as oil resistance, heat resistance, and adhesive strength are generally significantly reduced, but when the resorcinol diglycidyl ether is used, no reduction in performance is observed.
なお、流動性の調節、チクソ性の付与、硬化収縮の抑制
等のために炭酸カルシニウム、アルミナ、二酸化硅素等
の充填剤が適宜配合される。Note that fillers such as calcium carbonate, alumina, silicon dioxide, etc. are appropriately blended to adjust fluidity, impart thixotropy, suppress curing shrinkage, and the like.
次に実施例によシ更に本発明を説明する。Next, the present invention will be further explained with reference to examples.
実施例１
ビスフェノール凰エポキシ樹脂（商品名工ピコ−）８０
７、油化シェルエポキシ会社製）８０部、レゾルシノー
ルグリシジルエーテル（商品名ヘロキシＷＣ６９、ウイ
ルミントン社製）２０部にボηアミドアミン（商品名ト
ーマイド２９０Ｃ，富士化成工業会社製）４０部、重質
炭酸カルシ−ラム（商品名ホワイトンＳＢ、白石カルシ
ュラム社製）５０部を混合し、実施例１の接着剤組成物
を得た０
実施例２
フェノールノボラック型エボギシ樹脂（商品名エピコー
ト１５２、油化シェルエポキシ社！！り８０部、レゾル
シノールジグリシジルエーテル（商品名ヘロキシＷＣ６
９、ウイルミントン社製）２０部、テトラエチレンペン
タミン（東洋ソーダ社製）１４部を混合し、実施例２の
接着剤組成物を得た。Example 1 Bisphenol epoxy resin (trade name: Pico) 80
7. 80 parts (manufactured by Yuka Shell Epoxy Company), 20 parts of resorcinol glycidyl ether (trade name: Heroxy WC69, manufactured by Wilmington Co., Ltd.), 40 parts of polyamide amine (trade name: Tomide 290C, manufactured by Fuji Kasei Kogyo Co., Ltd.), and heavy carbonic acid. The adhesive composition of Example 1 was obtained by mixing 50 parts of Calciram (trade name Whiten SB, manufactured by Shiraishi Calcilum Co., Ltd.). 80 parts of Epoxy Co., Ltd., resorcinol diglycidyl ether (trade name: Heloxy WC6)
9 (manufactured by Wilmington Co., Ltd.) and 14 parts of tetraethylenepentamine (manufactured by Toyo Soda Co., Ltd.) were mixed to obtain the adhesive composition of Example 2.
実施例３
ビスフェノールＡ型エポキシ樹脂（商品名エピコート８
２８、油化シェルエポキシ社＆り８０部、レゾルシノー
ルジグリシジルエーテル（商品名ヘロキシ６９、ウイル
ミントン社製）２０部、グー性イミダゾール２ＭＺアミ
ン（四国化成工業社製）５部、無水珪酸微粉末（商品名
アエロジル２００゜日本アエロジル社＆）１部を混合し
て実施例３の接着剤組成物とした。Example 3 Bisphenol A type epoxy resin (trade name Epicote 8
28, 80 parts of Yuka Shell Epoxy Co., Ltd., 20 parts of resorcinol diglycidyl ether (trade name: Heroxy 69, manufactured by Wilmington Co., Ltd.), 5 parts of gooey imidazole 2MZ amine (manufactured by Shikoku Kasei Kogyo Co., Ltd.), silicic anhydride fine powder ( The adhesive composition of Example 3 was prepared by mixing 1 part of Aerosil 200 (trade name) by Nippon Aerosil Co., Ltd.
比較例１
ビスフェノールＦ型エポキシ樹脂（商品名エピコート８
０７、油化シェルエポキシ社製）にポリアミドアミン（
商品名トーマイド２９０ Ｃ，富士化成工業社製）４０
部、重質炭酸カルシニウム（商品名ホワイトンＳＢ、白
石カルシュウム社製）５０部を混合し比較例１の接着剤
組成物とした０比較例２
フェノールノボラック型エポキシ樹＃（商品名エピコー
ト１５２、油化シェルエポキシ社製）１００部、テトラ
エチレンペンタミン（東洋ソーダ社製）１４部を混合し
て比較例２の接着剤組成物とした。Comparative Example 1 Bisphenol F type epoxy resin (trade name Epicote 8
07, polyamide amine (manufactured by Yuka Shell Epoxy Co., Ltd.)
Product name Tomide 290 C, manufactured by Fuji Kasei Kogyo Co., Ltd.) 40
Comparative Example 2 Phenol novolac type epoxy resin # (trade name Epicote 152, oil An adhesive composition of Comparative Example 2 was prepared by mixing 100 parts of (manufactured by Shell Epoxy Co., Ltd.) and 14 parts of tetraethylenepentamine (manufactured by Toyo Soda Co., Ltd.).
比較例３
ビスフェノールＡｍエポキシ樹脂（商品名エピコート８
２８、油化シェルエポキシ社製）１００部、変性イミダ
ゾール２ＭＺアジ／（四国化成社１ｎ）５部、無水珪酸
微粉末（商品名アエロジル２００、日本アエロジル社製
）１部を混合して比較例３の接着剤組成物を得た。Comparative Example 3 Bisphenol Am epoxy resin (trade name Epicote 8
Comparative Example 3 was prepared by mixing 100 parts of 28, manufactured by Yuka Shell Epoxy Co., Ltd., 5 parts of modified imidazole 2MZ aji/(Shikoku Kasei Co., Ltd. 1n), and 1 part of silicic anhydride fine powder (trade name Aerosil 200, manufactured by Nippon Aerosil Co., Ltd.). An adhesive composition was obtained.
各接着剤組成物の各種特性を測定した結果は表の通りで
あった。The results of measuring various properties of each adhesive composition are shown in the table.
仄験秤伽法 ・引張剪断液ｉａ力＜ｋｙｆ／ｃｉ） 被ノ８体としてナイロン（ナイロン １ｏｏｘａ。experience weighing law ・Tensile shear liquid ia force <kyf/ci) Nylon (nylon 1ooxa) as the 8 subjects.
×２ν１）を用いて接着面積３０Ｘ３０ｇｄ、接着剤厚
さ２麿とし試験片を作成した。（接着面アセトン脱脂）
・重量変化率（ΔＷ％）、体積変化率（Δ■チ）接着剤
組成物を注型して直径５０朋、厚さ３鰭の円板とし１４
０℃、３０分間で硬化させ試験片を作成する。該試験片
を冷却管付き１０１フラスコ中のＦｕｅｌＣ（イソオク
タン／トルエン＝ １／ｌ ）８５％、メタノール１５
チ（容量）の混合液６１に浸漬しフラスコを６０℃水槽
に入れて経時浸漬後の引張剪断強度、重量変化率（ΔＷ
％）、体積変化率（６７％）を測定した。×2v1), a test piece was prepared with an adhesive area of 30×30 gd and an adhesive thickness of 2 mm. (Adhesive surface acetone degreasing) Weight change rate (ΔW%), volume change rate (Δ■chi) Cast the adhesive composition to form a disk with a diameter of 50 mm and a thickness of 3 fins.14
A test piece is prepared by curing at 0°C for 30 minutes. The test piece was placed in a 101 flask equipped with a cooling tube in 85% Fuel C (isooctane/toluene = 1/l) and 15% methanol.
The flask was immersed in a mixed solution 61 (volume) of
%) and volume change rate (67%) were measured.
〈発明の効果〉
本発明になる接着剤組成物はエポキシ樹脂にレゾルシノ
ールグリシジルエーテルが適量配合されてなるものであ
るため、メタノール混入ガソリンに接触しても重量、体
積の変化が極めて少く、・燃料タンク、燃料フィルター
等の部品の接着組立に使用されても燃料モレ等の問題が
生じない。<Effects of the Invention> Since the adhesive composition of the present invention is made by blending an appropriate amount of resorcinol glycidyl ether with an epoxy resin, there is extremely little change in weight and volume even when it comes into contact with methanol-containing gasoline. Even when used for adhesive assembly of parts such as tanks and fuel filters, problems such as fuel leakage do not occur.
また近年、使用の多くなっているナイロン製部品に対し
てすぐれた接着性を持ち耐久性の接着組立部品を提供す
ることができる。Furthermore, it is possible to provide a durable adhesive assembly that has excellent adhesion to nylon parts, which have been increasingly used in recent years.
Claims (1)
硬化剤１０〜１００重量部ならびにレゾルシノールジグ
リシジルエーテル５〜６０重量部が配合されることを特
徴とする接着剤組成物(1) An adhesive composition characterized in that 10 to 100 parts by weight of an epoxy resin curing agent and 5 to 60 parts by weight of resorcinol diglycidyl ether are blended with 100 parts by weight of epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27392888A JPH02120382A (en) | 1988-10-28 | 1988-10-28 | Adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27392888A JPH02120382A (en) | 1988-10-28 | 1988-10-28 | Adhesive composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02120382A true JPH02120382A (en) | 1990-05-08 |
| JPH0585589B2 JPH0585589B2 (en) | 1993-12-08 |
Family
ID=17534527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27392888A Granted JPH02120382A (en) | 1988-10-28 | 1988-10-28 | Adhesive composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02120382A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003018699A3 (en) * | 2001-08-23 | 2003-09-04 | Dow Global Technologies Inc | Fuel tanks |
| JP2014511424A (en) * | 2011-03-07 | 2014-05-15 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | Cargo tank coating |
| WO2023063000A1 (en) * | 2021-10-14 | 2023-04-20 | 三菱瓦斯化学株式会社 | Epoxy resin composition, cured product thereof, prepreg, fiber-reinforced composite material, and high-pressure gas container |
-
1988
- 1988-10-28 JP JP27392888A patent/JPH02120382A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003018699A3 (en) * | 2001-08-23 | 2003-09-04 | Dow Global Technologies Inc | Fuel tanks |
| JP2014511424A (en) * | 2011-03-07 | 2014-05-15 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | Cargo tank coating |
| WO2023063000A1 (en) * | 2021-10-14 | 2023-04-20 | 三菱瓦斯化学株式会社 | Epoxy resin composition, cured product thereof, prepreg, fiber-reinforced composite material, and high-pressure gas container |
| JP7279868B1 (en) * | 2021-10-14 | 2023-05-23 | 三菱瓦斯化学株式会社 | Epoxy resin composition and its cured product, prepreg, fiber-reinforced composite material, high-pressure gas container |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0585589B2 (en) | 1993-12-08 |
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