JPH02115688A - Flexible refractory packing material - Google Patents

Flexible refractory packing material

Info

Publication number
JPH02115688A
JPH02115688A JP26607588A JP26607588A JPH02115688A JP H02115688 A JPH02115688 A JP H02115688A JP 26607588 A JP26607588 A JP 26607588A JP 26607588 A JP26607588 A JP 26607588A JP H02115688 A JPH02115688 A JP H02115688A
Authority
JP
Japan
Prior art keywords
pts
packing material
inorganic
sugar liquid
retentivity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP26607588A
Other languages
Japanese (ja)
Other versions
JPH0520472B2 (en
Inventor
Hajime Asami
浅見 肇
Tsutomu Kobashi
小橋 勉
Shintaro Mori
森 眞太郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinagawa Refractories Co Ltd
Original Assignee
Shinagawa Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinagawa Refractories Co Ltd filed Critical Shinagawa Refractories Co Ltd
Priority to JP26607588A priority Critical patent/JPH02115688A/en
Publication of JPH02115688A publication Critical patent/JPH02115688A/en
Publication of JPH0520472B2 publication Critical patent/JPH0520472B2/ja
Granted legal-status Critical Current

Links

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  • Gasket Seals (AREA)
  • Sealing Material Composition (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

PURPOSE:To maintain shape retentivity and moisture retentivity and to obtain a flexible refractory packing material having satisfactory operability by adding specific amount of sugar liquid and hexitol binder to a main material of inorganic refractory powder and inorganic and/or organic fiber. CONSTITUTION:Flexible refractory packing material contains 100 pts.wt. of inorganic refractory powder and inorganic and/or organic fiber as main materials, 5-15 pts.wt. of sugar liquid as binder and 5-30 pts.wt. of hexitol be mixed. The sugar liquid includes one or more of molasses, glucose, honey, etc., in mixture. If the adding amount of the sugar liquid is 5 pts.wt. or less, pressure shrinkage is not sufficient, and airtightness of the packing material is not obtained. If it exceeds 15 pts.wt., the shape retentivity of the material is deteriorated, and machining operability becomes difficult. Hexitol includes one or more of D-sorbite of hexavalent alcohol, D-mannite, dulcite in mixture. If the adding amount is less than 5 pts.wt., the moisture retentivity of the material is deteriorated, the material is cracked, while if it exceeds 30 pts.wt., its shape retentivity is deteriorated, and the structure of the material is embrittled.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は可撓性且つ加圧収縮性を有する耐火1バツキン
グ材に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a fireproof backing material that is flexible and shrinkable under pressure.

〈従来の技術〉 従来、製鋼、造塊工場において溶鋼流を調整するため、
ノズルストッパ一方式、スライドバルブ方式、浸漬ノズ
ル等が使用されている。
<Conventional technology> Conventionally, in order to adjust the flow of molten steel in steel manufacturing and ingot factories,
One-way nozzle stopper type, slide valve type, immersion nozzle, etc. are used.

これら溶鋼流調整耐火構造体は各種耐火部材の組立構造
体として使用されている。
These molten steel flow regulating fireproof structures are used as assembly structures for various fireproof members.

これら耐火部材の接合固定のため、従来より耐火モルタ
ルが使用されている。例えば溶鋼鍋、タンデイツシュ等
においてはスライドバルブ−ノズル間、或はスリーブ−
ストッパーヘッド間、およびストッパー上部と固定押え
れんが、ガス吹込式ストッパーではストッパー金物間に
耐火モルタルを塗布し、接合している。
Refractory mortar has conventionally been used to join and fix these refractory members. For example, in molten steel ladle, tundish, etc., between the slide valve and the nozzle, or between the sleeve and
Refractory mortar is applied between the stopper heads, between the top of the stopper and the fixed presser brick, and between the stopper hardware in the case of gas-blown stoppers.

また本出願人は主原料に結合剤として合成樹脂エマルジ
ョンまたは/およびゴムラテックスを配合した可撓性か
つ、加圧収縮性を有する耐火性パッキングを提案した(
特公昭61−14111号公報)なお、前記可視度とは
ASTM 747に準する試験機で試料形状100 X
 40 X 10nmとし、1分間2kg荷重の可視度
(■)を示す(数値の大きい程可撓度が大である)。ま
た前記加圧収縮率とは、2 kg/dの荷重を掛けた場
合の厚さ寸法の収縮率を言う。
The applicant has also proposed a fire-resistant packing that is flexible and shrinkable under pressure by blending synthetic resin emulsion and/or rubber latex as a binder with the main raw material (
(Japanese Patent Publication No. Sho 61-14111) Note that the above visibility refers to the visibility when the sample shape is 100
40 x 10 nm, and the visibility (■) of a load of 2 kg for 1 minute is shown (the larger the number, the greater the flexibility). Further, the term "pressure shrinkage rate" refers to the shrinkage rate in thickness when a load of 2 kg/d is applied.

〈発明が解決しようとする課題〉 従来のモルタル工法による接合の問題点は当業者に周知
の如く次のとおりである: l)施工が困難で作業性が悪い。
<Problems to be Solved by the Invention> The problems of joining using the conventional mortar method are as follows, as is well known to those skilled in the art: l) Construction is difficult and workability is poor.

2)耐火モルタルの耐食性及び亀裂の発生によリ、空気
巻込みあるいは漏鋼事故を生じ易い。
2) Due to the corrosion resistance of refractory mortar and the occurrence of cracks, air entrainment or steel leakage accidents are likely to occur.

3)気密性(焼結性)の良い耐火モルタルを使用してい
るため、使用後に耐火モルタルがノズルに焼付き新規に
ノズルを塗着する作業が煩雑である。
3) Since refractory mortar with good airtightness (sinterability) is used, the refractory mortar seizes onto the nozzle after use, making it complicated to apply a new nozzle.

また合成樹脂エマルジョンを結合剤に用いる耐火パッキ
ングは予熱時の分解ガスによって作業環境は悪化する欠
点があり改良が要望されている。
Furthermore, fireproof packing using a synthetic resin emulsion as a binder has the disadvantage that the working environment is deteriorated by decomposition gas during preheating, and improvements are desired.

本発明は上述の背景に基づきなされたものでありその目
的とするところは: 1)施工の作業性が良い 2)気密性が良く 3)使用後の焼付がない 可撓性耐火パッキング材を提供することである。
The present invention has been made based on the above-mentioned background, and its objectives are to: 1) Provide a flexible fireproof packing material that has good workability in construction, 2) has good airtightness, and 3) does not seize after use. It is to be.

く課題を解決するための手段〉 本発明者らは可撓性耐火パッキング材の特性改良を試み
た結果本発明の開発に成功したものであり本発明の構成
は無機耐火物粉末と無機繊維および/または有機繊維の
100重量部を主原料とし、これに結合剤として糖液5
〜15重量部へキシット5〜30重量部を配合してなる
ことを特徴とする可撓性耐火パッキング材にある。
Means for Solving the Problems> The present inventors have succeeded in developing the present invention as a result of attempting to improve the characteristics of flexible fireproof packing materials. / or 100 parts by weight of organic fiber as the main raw material, and 5 parts of sugar solution as a binder.
A flexible fireproof packing material characterized by containing 5 to 30 parts by weight of hexit to 15 parts by weight.

本発明の特徴とするところは結合剤として糖液とへキシ
ットを使用する点にあり、該結合剤の使用により保形性
と保湿性を維持し施工作業性の良好な可撓性耐火パッキ
ング材を得ることができたものである。
The present invention is characterized by the use of sugar solution and hexit as binders, and by using the binders, a flexible fireproof packing material that maintains shape retention and moisture retention and has good workability. This is what I was able to obtain.

本発明において使用される無機耐火物粉末としては、通
常耐火物に使用されるマグネシア、アルミナ、シリカ、
粘土、カーボン等の無機耐火物粉末を使用することがで
きる。
The inorganic refractory powder used in the present invention includes magnesia, alumina, silica, which is usually used for refractories,
Inorganic refractory powders such as clay and carbon can be used.

本発明において使用される繊維原料としては無機繊維を
単独に、あるいは有機繊維を単独にまたは両者を一緒に
使用することができ、無機繊維としてはスラグウール、
石綿、ガラス繊維、セラミックファイバー等を挙げるこ
とができ、有機繊維としては木材パルプ、麻糸、綿くず
、合成繊維、くず等を挙げることが、できる。無機繊維
および有機繊維の長さは10mm未満であることが混練
時の分散上望ましい。
As the fiber raw material used in the present invention, inorganic fibers can be used alone, organic fibers can be used alone, or both can be used together. Examples of inorganic fibers include slag wool,
Examples of the organic fiber include asbestos, glass fiber, and ceramic fiber. Examples of the organic fiber include wood pulp, hemp thread, cotton waste, synthetic fiber, and waste. It is desirable for the length of the inorganic fibers and organic fibers to be less than 10 mm for dispersion during kneading.

無機繊維は常温時および中間温度の強度を与える作用が
あるが、該パッキング材の耐食性を低下させるのでその
添加量は30重量部以下とするのが好ましい。
Inorganic fibers have the effect of imparting strength at room and intermediate temperatures, but since they reduce the corrosion resistance of the packing material, the amount added is preferably 30 parts by weight or less.

有機繊維は常温時の強度およびパッキング材に保形性を
与え使用時の燃焼によって気孔が増加し、断熱性を向上
する作用がある。その添加量は5重量部以下が好ましく
5重量部を超えると使用時の燃焼によって気孔を作り気
密性が低下し、また組織が脆弱化する等の欠点が生ずる
Organic fibers provide strength at room temperature and shape retention to the packing material, and when used, burn up to increase pores and improve heat insulation. The amount added is preferably 5 parts by weight or less, and if it exceeds 5 parts by weight, pores are formed due to combustion during use, resulting in a decrease in airtightness and weakening of the structure.

結合剤として使用する糖液としては糖密、水あめ、ハチ
ミツ等を1種または2種以上を混合して使用することが
できる。その添加量は目標の保形性、加圧収縮性によっ
て主原料100重量部に対して5〜15重量部である。
As the sugar solution used as a binder, molasses, starch syrup, honey, etc. can be used alone or in combination of two or more. The amount added is 5 to 15 parts by weight based on 100 parts by weight of the main raw material, depending on the target shape retention and pressure shrinkability.

糖液の添加量は多いほど可塑性が増加し可撓性を増すが
、5重量部未満の時は加圧収縮性が充分でなく、該パッ
キング材の気密性が得られない。
The larger the amount of sugar solution added, the greater the plasticity and flexibility, but if it is less than 5 parts by weight, the shrinkability under pressure will not be sufficient and the packing material will not be airtight.

また15重量部を超えるとパッキング材の保形性が悪く
、施工作業も困難となる。またもう1種の結合剤として
使用するヘキシットとしては六価アルコールのD−ソル
ビット、D−マンニット、ズルシット等を1種または2
種以上を混合して使用す部である5重量部未満ではパッ
キング材の保湿性が悪く亀裂が発生することもある。ま
た30重量部を越えるとパッキング材の保形性が悪くそ
して施工後昇温、受鋼時に結合剤消失によるパッキング
材組織が脆弱化する等の欠点が発生する。
Moreover, if it exceeds 15 parts by weight, the shape retention of the packing material will be poor and construction work will be difficult. As another type of hexite used as a binder, one or two hexahydric alcohols such as D-sorbitol, D-mannitol, and dulcitol are used.
If the amount used is less than 5 parts by weight, the packing material may have poor moisture retention properties and cracks may occur. If the amount exceeds 30 parts by weight, the packing material will have poor shape retention, and the structure of the packing material will become brittle due to temperature rise after construction and loss of binder during steel receiving.

なおヘキシットは水溶液として添加することもできる。Note that hexite can also be added as an aqueous solution.

また高温の強度を保持させるために小量の無機質の結合
剤、例えば水ガラス、硼酸塩、リン酸塩等を併用するこ
とも可能である。
It is also possible to use a small amount of an inorganic binder, such as water glass, borate, phosphate, etc., in order to maintain the strength at high temperatures.

本発明の可撓性耐火パッキング材は上記配合物を通常の
オ、−ガー成形あるいは所定形状の枠に練土を入れロー
ラーによって練土表面を整形するローラー成形等によっ
て得られる。
The flexible fire-resistant packing material of the present invention can be obtained by molding the above-mentioned compound by conventional o-ger molding, or by roller molding in which clay is placed in a frame of a predetermined shape and the surface of the clay is shaped with a roller.

可撓性耐火パッキング材の厚さは2〜20mmが好適で
ある。
The thickness of the flexible fireproof packing material is preferably 2 to 20 mm.

加圧収縮性は装着圧力および熱応力に対し、10〜80
%が望ましい、しかしながら使用現場の耐火物の形状、
サイズその他の操業条件に応じて適宜選定しうるちので
ある。
Pressure shrinkage is 10 to 80 against mounting pressure and thermal stress.
% is desirable, however, the shape of the refractory at the site of use,
The material is selected as appropriate depending on the size and other operating conditions.

可撓性耐火パッキング材はそのまま耐火物間の接合部に
嵌合して使用しうるが、離形祇、ポリエチレン、ビニー
ルを貼付して保管、組立、作業性を向上させることがで
きる。
The flexible fireproof packing material can be used as it is by fitting into joints between refractories, but it can also be pasted with removable material, polyethylene, or vinyl to improve storage, assembly, and workability.

以下に実施例を挙げて本発明の可撓性耐火ツマ・ンキン
グ材を更に説明する。
The flexible fireproof knob and binding material of the present invention will be further explained below with reference to Examples.

1隻Mよ 下記第1表に記載する配合物をノ\イスピードミキサー
で混練した練土をローラー成形しツマ・ンキング材を得
た。得られたパ・ンキング材・の緒特性を第1表に併記
する。第1表から明らかな如く、比較品1は加工収縮性
、可撓性は本発明品に近似のものであるが、保湿性が悪
く、比較品2は保湿性は良好であるが、加圧収縮性、可
撓性が劣る。
1 ship M The mixture shown in Table 1 below was kneaded using a noisy speed mixer, and the clay was roller-molded to obtain a tsuma-king material. The properties of the obtained punching material and cord are also listed in Table 1. As is clear from Table 1, Comparative Product 1 has processing shrinkage and flexibility similar to the product of the present invention, but its moisture retention is poor, and Comparative Product 2 has good moisture retention, but under pressure Poor contractility and flexibility.

傘2 : ASTM 747に準する試験機で試料形状
100X40X1−とし1分間2 kg/cfflの可
撓度Il/Imを示す。
Umbrella 2: Using a testing machine conforming to ASTM 747, the sample shape was 100 x 40 x 1- and exhibited a flexibility Il/Im of 2 kg/cffl for 1 minute.

実JL[津1 タンデイツシュノズルと浸漬ノズルの間に150φ×7
0φX8m/mの本発明品2を使用したが嵌合施工性も
良くさらに予熱時の悪臭もなくエアーシールも良好であ
った。
Real JL [Tsu 1 150φ x 7 between tandate nozzle and immersion nozzle
Inventive product 2 of 0 φ x 8 m/m was used, and the fit and workability was good, and there was no bad odor during preheating, and the air seal was also good.

〈発明の効果〉 本発明の可撓性耐火パッキング材は従来の耐火パッキン
グ材に比べ ・保形性、保湿性も良く保管中にキレッ発生がなく良好
な施工作業性を保持できる。
<Effects of the Invention> Compared to conventional fireproof packing materials, the flexible fireproof packing material of the present invention has better shape retention and moisture retention properties, and can maintain good construction workability without causing sharpness during storage.

・予熱時の分解ガスによる悪臭がない。・There is no bad odor caused by decomposed gas during preheating.

・保形性については、長期間の保管が確保できる。- Regarding shape retention, long-term storage can be ensured.

・シール性が良好で、使用後の焼付がなく簡単に処理が
できる。
・Good sealing properties, no burning after use, and easy disposal.

Claims (1)

【特許請求の範囲】[Claims] 無機耐火物粉末と無機繊維および/または有機繊維の1
00重量部を主原料としこれに結合剤として糖液5〜1
5重量部、ヘキシット5〜30重量部を添加してなるこ
とを特徴とする可撓性耐火パッキング材
Inorganic refractory powder and inorganic fiber and/or organic fiber 1
00 parts by weight as the main raw material and 5 to 1 parts of sugar solution as a binder.
A flexible fireproof packing material characterized by adding 5 parts by weight and 5 to 30 parts by weight of hexite.
JP26607588A 1988-10-24 1988-10-24 Flexible refractory packing material Granted JPH02115688A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26607588A JPH02115688A (en) 1988-10-24 1988-10-24 Flexible refractory packing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26607588A JPH02115688A (en) 1988-10-24 1988-10-24 Flexible refractory packing material

Publications (2)

Publication Number Publication Date
JPH02115688A true JPH02115688A (en) 1990-04-27
JPH0520472B2 JPH0520472B2 (en) 1993-03-19

Family

ID=17426005

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26607588A Granted JPH02115688A (en) 1988-10-24 1988-10-24 Flexible refractory packing material

Country Status (1)

Country Link
JP (1) JPH02115688A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014006991A1 (en) * 2012-07-06 2014-01-09 日本碍子株式会社 Mortar

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014006991A1 (en) * 2012-07-06 2014-01-09 日本碍子株式会社 Mortar

Also Published As

Publication number Publication date
JPH0520472B2 (en) 1993-03-19

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