JPH02111863A - Formation of thermally sprayed nickel film with laser under reduced pressure - Google Patents

Formation of thermally sprayed nickel film with laser under reduced pressure

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Publication number
JPH02111863A
JPH02111863A JP63264380A JP26438088A JPH02111863A JP H02111863 A JPH02111863 A JP H02111863A JP 63264380 A JP63264380 A JP 63264380A JP 26438088 A JP26438088 A JP 26438088A JP H02111863 A JPH02111863 A JP H02111863A
Authority
JP
Japan
Prior art keywords
workpiece
nickel
laser
reduced pressure
sprayed coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63264380A
Other languages
Japanese (ja)
Inventor
Nobuaki Otomo
大友 延明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzuki Motor Corp
Original Assignee
Suzuki Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzuki Motor Corp filed Critical Suzuki Motor Corp
Priority to JP63264380A priority Critical patent/JPH02111863A/en
Publication of JPH02111863A publication Critical patent/JPH02111863A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To improve wear resistance and adhesion by heating and melting Ni powder fed onto a body to be treated with a carrier gas at the focus of laser beams and forming a high density thermally sprayed film. CONSTITUTION:A holder 2 with each fixed body 1 to be treated is set in a vacuum vessel 3 and this vessel 3 is evacuated to 1-10Torr pressure. Laser beams 4 of 1-10kW output irradiate and converge on the body 1. Ni powder 5 is fed from a position above the body 1 and melted at the focus 6 of the laser beams 4 and the molten Ni is adhered to the surface of the body 1. The holder 2 is then moved and a thermally sprayed Ni film is formed on the surface of the body 1 and slowly cooled.

Description

【発明の詳細な説明】 a、 産業上の利用分野 本発明は、ニッケル減圧レーザ溶射被膜の作成方法、特
に軸受部分、ベアリング、ピストンリング、カムシャフ
ト等の摺動部材の摺動部の摺動特性と耐摩耗性を向上す
るためにニッケル減圧レーザ溶射被膜を作成する方法に
関する。
Detailed Description of the Invention: a. Field of Industrial Application The present invention relates to a method for producing a nickel reduced pressure laser spray coating, particularly for sliding parts of sliding members such as bearings, bearings, piston rings, camshafts, etc. A method of creating nickel vacuum laser sprayed coatings to improve properties and wear resistance.

b、 従来の技術 材料の表面処理によって摺動特性と耐摩耗性を向上させ
るにはこれまで次の手法が主に用いられている。
b. Conventional technology The following methods have been mainly used to improve the sliding properties and wear resistance of materials through surface treatment.

(1)  プラズマ溶射。(1) Plasma spraying.

(2)  N1−P−BN 、 N1−P−5iC等の
無電解メツキ (3)  イオン注入(N”イオンが主)(4)  プ
ラズマCVD (主にTiN のコーティング)C0発
明が解決しようとする課題 プラズマ溶射被膜は気孔率が高く被膜強度が低い。また
母材との密着強さがあまり大きくならないため高面圧、
又は熱衝撃のある部材には適さない。
(2) Electroless plating of N1-P-BN, N1-P-5iC, etc. (3) Ion implantation (mainly N'' ions) (4) Plasma CVD (mainly TiN coating) The C0 invention attempts to solve the problem Challenges Plasma sprayed coatings have high porosity and low coating strength.Also, because the adhesion strength to the base material is not very strong, high surface pressure,
Or it is not suitable for members that are subject to thermal shock.

特に大気プラズマ溶射では表面酸化が著しく、−船釣に
摺動特性を阻害する。
In particular, atmospheric plasma spraying causes significant surface oxidation, which impairs the sliding properties for boat fishing.

メンキ等は、200〜300’C程度までの使用環境で
あればその耐摩耗性が保障されるがそれ以上では問題が
生ずる。プラズマ溶射被膜より密着強さが低い。
The abrasion resistance of bamboo bran and the like is ensured if used in an environment of about 200 to 300'C, but problems occur above that temperature. Adhesion strength is lower than plasma sprayed coating.

イオン注入やプラズマ(CVD) は時として優れた摺
動特性をみせるが、大物部品の処理ができないことと、
処理膜厚が1710μ〜1μオーダーと極めて低く耐久
性に欠けるなどの欠点がある。
Ion implantation and plasma (CVD) sometimes show excellent sliding properties, but they cannot process large parts, and
The treated film thickness is extremely low, on the order of 1710 μm to 1 μm, and has drawbacks such as lack of durability.

d、 課題を解決するための手段 上記課題は、被加工物を被加工物支持部材に固定し、被
加工物と被加工物支持部材が収容されている真空容器内
の圧力を1〜10Torrとし、1〜10kwの出力を
有するレーザ光線を、被加工物の上方で集光するように
被加工物の上方から被加工物に照射し、搬送ガスを用い
てニッケル粉末を、ニッケル粉末がレーザ光線の集光点
を通るように、被加工物の上方から供給し、レーザ光線
によって融解したニッケル粉末を被加工物の上面に融着
させ、被加工物支持部材を適宜移動させることにより被
加工物表面にニッケル溶射被膜を形成し、被加工物を徐
冷することを特徴とする、ニッケル減圧レーザ溶射被膜
の作成方法によって解決された。
d. Means for solving the problem The above problem is achieved by fixing the workpiece to a workpiece support member and setting the pressure in the vacuum container in which the workpiece and workpiece support member are housed to 1 to 10 Torr. , a laser beam with an output of 1 to 10 kW is irradiated onto the workpiece from above so as to be focused above the workpiece, and a carrier gas is used to irradiate the nickel powder with the laser beam. The nickel powder is supplied from above the workpiece so as to pass through the focal point of the workpiece, and the nickel powder melted by the laser beam is fused to the upper surface of the workpiece, and the workpiece support member is moved appropriately. The problem was solved by a method for creating a nickel vacuum laser spray coating, which is characterized by forming a nickel spray coating on the surface and slowly cooling the workpiece.

e、 作用 搬送ガスによって送られて来たニッケル粉末はレーザ光
線の集光点において加熱され融解する。
e. The nickel powder carried by the working carrier gas is heated and melted at the focal point of the laser beam.

融解した高温のニッケル粉末は被加工物の表面で固化し
、密度の高い溶射被膜が形成される。
The molten high-temperature nickel powder solidifies on the surface of the workpiece, forming a dense thermal spray coating.

f、 実施例 第1図は本発明に係るニッケル減圧レーザ溶射被膜を作
成する方法を実施する装置の一例の概念図である。
f. Example FIG. 1 is a conceptual diagram of an example of an apparatus for carrying out the method for creating a nickel vacuum laser sprayed coating according to the present invention.

被加工物(Test Piece)は、被加工物支持部
材(Holder)に支持されている。?l!加工物支
持部材は真空容器(Vacuum Chamber)の
中で支持軸(Main 5chaft)により並進移動
可能かつ回転運動可能である。支持軸は往復運動駆動手
段01により往復運動し、回転運動駆動手段D2により
回転運動する。被加工物支持部材はその内部を流れる冷
却水(Cooling Water)によって冷却する
ことができる。
The workpiece (Test Piece) is supported by a workpiece support member (Holder). ? l! The workpiece support member is translationally and rotationally movable within the vacuum chamber by a support shaft. The support shaft is reciprocated by a reciprocating motion drive means 01 and rotated by a rotary motion drive means D2. The workpiece support member can be cooled by cooling water flowing inside the workpiece support member.

真空容器は、ロークリポンプ(Rotary Pump
’)  にヨ/)0.01 Torr程度の真空度に保
たれる。
The vacuum container is a Rotary Pump.
') niyo/) It is maintained at a vacuum level of approximately 0.01 Torr.

レーザ光源として、波長10.6μm、出力6kwの赤
外線レーザを発生する炭酸ガスレーザ光源(Co2Ga
s La5er 0scillator)が使用される
。レーザ光源からのレーザ光線は反射鏡(旧rror)
で反射し、KCI!、からなる集光レンズ(KCIl 
−CondenserLens)により集光光束となり
、Zn  SeレンズCZn −3e Lens)を通
って真空容器の中に入り、被加工物の上方38〜40m
の点で集光した後、被加工物の表面を垂直に照射する。
As a laser light source, a carbon dioxide laser light source (Co2Ga
s La5er 0scillator) is used. The laser beam from the laser light source is reflected by a reflecting mirror (formerly RROR).
Reflected and KCI! , a condensing lens (KCIl) consisting of
- Condenser Lens), it becomes a condensed light beam, passes through a Zn Se lens (CZn -3e Lens), enters the vacuum chamber, and travels 38 to 40 meters above the workpiece.
After condensing the light at the point, the surface of the workpiece is irradiated perpendicularly.

なお被加工物への照射角は90″±45°の範囲である
ことが好ましい。
Note that the irradiation angle to the workpiece is preferably in the range of 90''±45°.

粒径25〜40μmのニッケル粉末を、アルゴンガスか
らなる搬送ガス(Carrier Ga5)を用いて、
真空容器内に供給する。ニッケル粉末は、鉛直方向のレ
ーザ光線と共通のノズル(Nozzle)を通って被加
工物の方向に進む。ニッケル粉末はレーザ光線により融
解した状態で被加工物の表面に到達そして固化する。な
おノズルの周辺はウォータジャケント(Water J
acket)内の冷却水によって冷却される。
Nickel powder with a particle size of 25 to 40 μm was processed using a carrier gas (Carrier Ga5) consisting of argon gas.
Supplied into a vacuum container. The nickel powder travels towards the workpiece through a common nozzle with the vertical laser beam. The nickel powder reaches the surface of the workpiece in a molten state by the laser beam and solidifies. The area around the nozzle is Water J.
It is cooled by cooling water in the acket.

往復運動駆動手段1 回転運動駆動手段を用いて被加工
物支持部材を移動させることにより、彼JzU工物を移
動させる。単位時間当りの照射面積が例えば6.5〜7
.5mu+’/seeとなるように、被加工物を1多動
させることにより溶射膜が被加工物の表面に形成される
Reciprocating motion drive means 1 The workpiece is moved by moving the workpiece support member using the rotary motion drive means. For example, the irradiation area per unit time is 6.5 to 7.
.. A sprayed film is formed on the surface of the workpiece by making the workpiece move one time so that the rate is 5 mu+'/see.

被加工物は、支持軸の中を流れる冷却水によって間接的
に冷却され、さらに真空容器の内部をアルゴン雰囲、気
−に保つことにより溶射被膜の形成後約30分間徐冷す
る。
The workpiece is indirectly cooled by cooling water flowing through the support shaft, and the interior of the vacuum container is kept in an argon atmosphere or air, so that the workpiece is slowly cooled for about 30 minutes after the sprayed coating is formed.

第2図は、このようにして得られた溶射被膜の断面写真
である。被膜表面付近は空隙が多く面粗さが大きいこと
がわかる。しかし研摩工程によりこれは十分除去できる
ものである。母材付近の被膜が掻めて稠密であり、大気
プラズマ溶射被膜あるいは減圧プラズマ溶射被膜と全く
異なることが分かる。
FIG. 2 is a cross-sectional photograph of the sprayed coating thus obtained. It can be seen that there are many voids near the coating surface and the surface roughness is large. However, this can be sufficiently removed by a polishing process. It can be seen that the coating near the base material is dense and dense, which is completely different from an atmospheric plasma sprayed coating or a reduced pressure plasma sprayed coating.

第3図は、このようにして得られた溶射被膜の組織写真
である。結晶粒界と粒内に双晶が認められ粉末が完全溶
融後凝固したことを示す。このような現象は、従来技術
として挙げた他の溶射被膜には全く認められないもので
ある。粉末が完全溶融するほど粉末が高温であるので、
下地母材もそれに応じて昇温する。したがって被膜と母
材の境界が冶金学的に結合し、それゆえ被膜の密着強さ
が高い。
FIG. 3 is a photograph of the structure of the sprayed coating thus obtained. Twin crystals were observed at the grain boundaries and within the grains, indicating that the powder solidified after complete melting. Such a phenomenon is not observed at all in other thermal sprayed coatings mentioned as prior art. The powder is so hot that it completely melts, so
The temperature of the base material also rises accordingly. Therefore, the boundary between the coating and the base material is metallurgically bonded, and therefore the adhesion strength of the coating is high.

第4図は、−液熱硬化性接着剤とユニバーサルジヨイン
トを用いてJIS H8666に基づいて行った各種溶
射被膜の密着強さの試験結果を表わすグラフである。図
の横軸は被膜厚さ(単位μI)を表わし、継軸は密着強
さ(単位kg / aa )を表わす。またAP、LP
、LLは、それぞれ大気プラズマ溶射、減圧プラズマ溶
射、減圧レーザ溶射を表わす。
FIG. 4 is a graph showing the results of a test on the adhesion strength of various thermal spray coatings conducted based on JIS H8666 using a liquid thermosetting adhesive and a universal joint. The horizontal axis of the figure represents the coating thickness (unit: μI), and the joint axis represents the adhesion strength (unit: kg/aa). Also AP, LP
, LL represent atmospheric plasma spraying, reduced pressure plasma spraying, and reduced pressure laser spraying, respectively.

この図は、被膜厚さが大きくなっても密着強さが接着剤
の接着強さよりも大きいことを示す。
This figure shows that the adhesion strength is greater than that of the adhesive even as the coating thickness increases.

第5図は、各種溶射被膜の往復動摩擦試験による摩擦係
数μを表わすグラフである。図の横軸はストローク数N
の10を底とする対数(fogN)、縦軸は摩擦係数μ
を表わす。図中の○は減圧レーザ溶射(アルゴン雰囲気
)、・は減圧レーザ溶射(窒素雰囲気)、△は減圧プラ
ズマ溶射(アルゴン雰囲気)、ムは減圧プラズマ溶射(
窒素雰囲気)、■は大気プラズマ溶射を表わす。なお第
5図の往復動摩擦試験の条件は、使用オイル:モービル
1(SFグレード)1 面圧荷重:50kgf、  ス
トローク速度: 300spm 、摩擦相手材FC25
、当り付は時間2分である。
FIG. 5 is a graph showing the friction coefficient μ of various thermal spray coatings obtained by a reciprocating friction test. The horizontal axis of the figure is the number of strokes N
The base 10 logarithm of (fogN), the vertical axis is the friction coefficient μ
represents. In the figure, ○ indicates reduced pressure laser spraying (argon atmosphere), ・ indicates reduced pressure laser spraying (nitrogen atmosphere), △ indicates reduced pressure plasma spraying (argon atmosphere), and MU indicates reduced pressure plasma spraying (
(nitrogen atmosphere), ■ represents atmospheric plasma spraying. The conditions for the reciprocating friction test in Figure 5 are: oil used: Mobil 1 (SF grade) 1, surface pressure load: 50 kgf, stroke speed: 300 spm, friction partner material FC25.
, the winning time is 2 minutes.

第5図はアルゴン雰囲気中で形成されたニッケルの減圧
レーザ溶射被膜は極めて摩擦係数が低く、繰返し摺動運
動に対して極めて優れた性能を有することを示す。この
摩擦係数の値は、自己潤滑特性に優れているとされてい
るリン青銅のブロック材表面の摩擦係数の値より小さい
値である。
FIG. 5 shows that the reduced pressure laser sprayed coating of nickel formed in an argon atmosphere has an extremely low coefficient of friction and has extremely excellent performance against repeated sliding motions. This value of the friction coefficient is smaller than the value of the friction coefficient of the surface of the phosphor bronze block material, which is said to have excellent self-lubricating properties.

この理由は、被膜の酸化がないことと、被膜中の気孔が
少なくかつ被膜が強固であることに因ると考えられる。
The reason for this is thought to be that there is no oxidation of the film, there are few pores in the film, and the film is strong.

第6図は窒素雰囲気中で形成されたニッケル減圧レーザ
溶射被膜のX線回折強度スペクトルである。
FIG. 6 is an X-ray diffraction intensity spectrum of a nickel vacuum laser sprayed coating formed in a nitrogen atmosphere.

第6図は、被膜中にFeが存在し、N+基層中のNiF
e合今になっていることを示す。これが優れた摺動特性
の原因であると考えられる。
Figure 6 shows the presence of Fe in the coating and NiF in the N+ base layer.
e Indicates that it is now in alignment. This is thought to be the cause of the excellent sliding properties.

g、 発明の効果 (i)本発明に係る方法で形成されたニンケル被膜は、
極めて優れた摺動特性を有するので、摺動部材に用いる
と耐摩耗性が著しく向上する。
g. Effects of the invention (i) The nickel coating formed by the method according to the invention has the following properties:
Since it has extremely excellent sliding properties, when used in sliding members, the wear resistance is significantly improved.

(11)耐摩耗性が向上するので、母材下地として低級
汎用材料を使用することができる。
(11) Since the wear resistance is improved, low-grade general-purpose materials can be used as the base material.

(iii )被膜強度が大きく、かつ母材との密着強さ
が大きいので、急冷、急加熱等の熱衝撃に対して強い。
(iii) Since the film has high strength and strong adhesion to the base material, it is resistant to thermal shocks such as rapid cooling and heating.

これ故、過酷な条件のもとにあるタービンエンジンの部
分に応用することが十分に可能である。すなわち高付加
価値の部品に適用することが可能である。
Therefore, it is fully possible to apply it to parts of turbine engines that are under severe conditions. In other words, it can be applied to high value-added parts.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に係るニッケル減圧レーザ溶射被膜を形
成する方法を実施する装置の一例の概念図、第2図は第
1図の装置により得られた溶射被膜の断面写真、第3図
は第1図の装置により得られた溶射被膜の組織写真、第
4図は各種溶射被膜の密着強さの試験結果を表わすグラ
フ、第5図は各種溶射被膜の摩擦係数を表わすグラフ、
第6図は窒素雰囲気中で形成されたニッケルの減圧レー
ザ溶射被膜のX線回折強度スペクトルである。 特許出顎人 鈴木自動車工業株式会社 (ほか2名) 第2図 :゛、゛、゛ ・?ぎ 第3図 手 続 補 正 書 (方式) 事件の表示 昭和63年特許願第264380号 発明の名称 ニッケル減圧レーザ溶射被膜の作成方法3゜ 補正をする者 事件との関係 名称  (208)
Figure 1 is a conceptual diagram of an example of an apparatus for implementing the method of forming a nickel vacuum laser sprayed coating according to the present invention, Figure 2 is a cross-sectional photograph of the sprayed coating obtained by the apparatus shown in Figure 1, and Figure 3 is a Figure 1 is a photograph of the structure of the sprayed coating obtained by the apparatus; Figure 4 is a graph showing the adhesion strength test results of various sprayed coatings; Figure 5 is a graph showing the coefficient of friction of various sprayed coatings;
FIG. 6 is an X-ray diffraction intensity spectrum of a nickel vacuum laser sprayed coating formed in a nitrogen atmosphere. Patent expert Suzuki Jidosha Kogyo Co., Ltd. (and 2 others) Figure 2: ゛, ゛, ゛ ・? Figure 3 Procedural amendment (method) Indication of the case 1985 Patent Application No. 264380 Name of the invention Method for creating nickel vacuum laser sprayed coating 3゜ Person making the amendment Name related to the case (208)

Claims (2)

【特許請求の範囲】[Claims] (1)被加工物を被加工物支持部材に固定し、被加工物
と被加工物支持部材が収容されている真空容器内の圧力
を1〜10Torrとし、1〜10kwの出力を有する
レーザ光線を、被加工物の上方で集光するように被加工
物の上方から被加工物に照射し、搬送ガスを用いてニッ
ケル粉末を、ニッケル粉末がレーザ光線の集光点を通る
ように、被加工物の上方から供給し、レーザ光線によっ
て融解したニッケル粉末を被加工物の上面に融着させ、
被加工物支持部材を適宜移動させることにより被加工物
表面にニッケル溶射被膜を形成し、被加工物を徐冷する
ことを特徴とする、ニッケル減圧レーザ溶射被膜の作成
方法。
(1) A laser beam having an output of 1 to 10 kW, with the workpiece fixed to the workpiece support member and the pressure inside the vacuum container in which the workpiece and the workpiece support member are housed to be 1 to 10 Torr. is irradiated onto the workpiece from above the workpiece so that the light is focused above the workpiece, and the nickel powder is irradiated onto the workpiece using a carrier gas so that the nickel powder passes through the convergence point of the laser beam. The nickel powder is supplied from above the workpiece and melted by a laser beam, and is fused to the top surface of the workpiece.
A method for creating a nickel vacuum laser sprayed coating, which comprises forming a nickel sprayed coating on the surface of a workpiece by appropriately moving a workpiece support member, and slowly cooling the workpiece.
(2)特許請求の範囲第1項記載のニッケル減圧レーザ
溶射被膜の作成方法で形成された溶射被膜を有する物。
(2) An object having a sprayed coating formed by the method for producing a nickel vacuum laser sprayed coating as set forth in claim 1.
JP63264380A 1988-10-20 1988-10-20 Formation of thermally sprayed nickel film with laser under reduced pressure Pending JPH02111863A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63264380A JPH02111863A (en) 1988-10-20 1988-10-20 Formation of thermally sprayed nickel film with laser under reduced pressure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63264380A JPH02111863A (en) 1988-10-20 1988-10-20 Formation of thermally sprayed nickel film with laser under reduced pressure

Publications (1)

Publication Number Publication Date
JPH02111863A true JPH02111863A (en) 1990-04-24

Family

ID=17402349

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63264380A Pending JPH02111863A (en) 1988-10-20 1988-10-20 Formation of thermally sprayed nickel film with laser under reduced pressure

Country Status (1)

Country Link
JP (1) JPH02111863A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5449536A (en) * 1992-12-18 1995-09-12 United Technologies Corporation Method for the application of coatings of oxide dispersion strengthened metals by laser powder injection
WO2014025244A1 (en) * 2012-08-07 2014-02-13 Torims Toms Apparatus and method for repair and renovation of crankshaft journal surfaces in-situ by means of laser cladding
US20150069025A1 (en) * 2013-09-10 2015-03-12 Caterpillar, Inc. Machine component cladding strategy

Citations (3)

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Publication number Priority date Publication date Assignee Title
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JPS61163258A (en) * 1985-01-11 1986-07-23 Shinagawa Refract Co Ltd Laser thermal spraying method
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US5449536A (en) * 1992-12-18 1995-09-12 United Technologies Corporation Method for the application of coatings of oxide dispersion strengthened metals by laser powder injection
WO2014025244A1 (en) * 2012-08-07 2014-02-13 Torims Toms Apparatus and method for repair and renovation of crankshaft journal surfaces in-situ by means of laser cladding
US20150069025A1 (en) * 2013-09-10 2015-03-12 Caterpillar, Inc. Machine component cladding strategy
US9555503B2 (en) * 2013-09-10 2017-01-31 Caterpillar Inc. Machine component cladding strategy

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