JPH02108508A - Manufacture of extendable and contractible shaft - Google Patents
Manufacture of extendable and contractible shaftInfo
- Publication number
- JPH02108508A JPH02108508A JP26355188A JP26355188A JPH02108508A JP H02108508 A JPH02108508 A JP H02108508A JP 26355188 A JP26355188 A JP 26355188A JP 26355188 A JP26355188 A JP 26355188A JP H02108508 A JPH02108508 A JP H02108508A
- Authority
- JP
- Japan
- Prior art keywords
- resin layer
- shaft
- liquid
- lubricant
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000011347 resin Substances 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000000314 lubricant Substances 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 238000005266 casting Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000013329 compounding Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 5
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 25
- 239000004519 grease Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- -1 trifluoride ethylene tetrafluoride Chemical compound 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 125000003047 N-acetyl group Chemical group 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000003855 acyl compounds Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の目的〕
(産業上の利用分野)
本発明はモノマーキャスティング法にて摺動境界層に樹
脂層を形成する方法に関するもので、自動車用テレスコ
ピックステアリングコラムのメインシャフトの樹脂層の
製造に利用されるものである。[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) The present invention relates to a method of forming a resin layer on a sliding boundary layer by a monomer casting method, and relates to a method for forming a resin layer on a sliding boundary layer by a monomer casting method, and relates to a method for forming a resin layer on a sliding boundary layer using a monomer casting method. It is used in the production of resin layers.
(従来の技術)
本発明に係る従来技術としては特開昭61−18422
2号公報がある。(Prior art) As a prior art related to the present invention, Japanese Patent Application Laid-Open No. 61-18422
There is a No. 2 publication.
このものは、スライドスプライン装置に於て、内周にス
プラインが形成された有底筒状のアウタスプライン部材
とインナスプラインとからなり、アウタスプライン部材
内にインナスプライン部材が伸縮動可能に嵌合され、摺
動面に樹脂膜が被覆され、アウタスプライン部材に対し
てインナスプライン部材が伸縮動する範囲において、長
期に渡って一定の摺動抵抗を得るもので、更に上記スラ
イドスプライン装置を製造する際にアウタスプライン部
材内周に離型剤を塗布し、次にアウタスプライン部材内
にモノマーを注入し、インナスプライン部材を嵌挿し、
クリアランスを介してモノマーの液位を一定位置まで変
位させ、モノマーを重合硬化して製造するものである。This slide spline device consists of an outer spline member having a bottomed cylindrical shape with a spline formed on the inner periphery and an inner spline, and the inner spline member is fitted into the outer spline member so as to be able to expand and contract. , the sliding surface is coated with a resin film to obtain a constant sliding resistance over a long period of time in the range where the inner spline member expands and contracts with respect to the outer spline member, and when manufacturing the slide spline device described above. Apply a mold release agent to the inner circumference of the outer spline member, then inject a monomer into the outer spline member, insert the inner spline member,
It is produced by displacing the liquid level of the monomer to a certain position via a clearance and polymerizing and curing the monomer.
(発明が解決しようとする課題)
しかし前記製造方法は樹脂層の摩擦、摩耗特性を向上す
るために、モノマーキャスティング法により樹脂層形成
後、樹脂摺動面にグリス塗布を実施しているが、下記の
様な問題点がある。(Problems to be Solved by the Invention) However, in the above manufacturing method, in order to improve the friction and wear characteristics of the resin layer, after forming the resin layer by a monomer casting method, grease is applied to the resin sliding surface. There are the following problems.
(1)摺動境界運動中、グリスが徐々に摺動境界部より
漏出し、グリス切れが発生し、その結果スティックスリ
ップの様な引っ掛り感やグリス切れに帰因した樹脂層の
摩耗によりガタ感が発生する。(1) During sliding boundary movement, grease gradually leaks from the sliding boundary, causing a lack of grease, resulting in a stuck-slip feeling and backlash due to abrasion of the resin layer due to the lack of grease. A feeling occurs.
(2)インナースプラインおよびアウタースプラインを
有する構成の2部材の現金嵌合位置にて、その隙間に樹
脂層を形成しているために適正な嵌合位置は1組しかな
く、そのために摺動部材をフリーにしたグリス補給が出
来ない。(2) Since a resin layer is formed in the gap between the two members having an inner spline and an outer spline at the cash fitting position, there is only one set of proper fitting positions, and therefore the sliding member Unable to replenish grease with free.
(3)七ツマーキャスティング法に於て、使用される樹
脂のナイロン6は、吸湿性のために樹脂層の素地金属面
が発錆し易い。(3) In the seven-layer casting method, the resin used, nylon 6, is hygroscopic and the base metal surface of the resin layer tends to rust.
本発明は七ツマーキャスティング法を適用して形成する
樹脂層に於て、摺動フィーリングを向上し、ガタ感の無
いフィーリングを長期間維持する低摩耗な伸縮自在シャ
フトの製造方法を技術的課題とするものである。The present invention is a technical method for manufacturing a low-wear telescopic shaft that improves the sliding feeling and maintains a feeling without rattling over a long period of time using a resin layer formed by applying the seven-point casting method. This is an issue to be addressed.
(課題を解決するための手段)
前記課題を解決するために講じた技術的手段は次のよう
である。すなわち、
アウタシャフト内にインナーシャフトが摺動自在に配設
されてなる伸縮自在シャフトの製造方法に於て、前記両
シャフト間のガタを無くすために、嵌合状態の両シャフ
ト間のスキ間にモノマーキャスティング法を適用して樹
脂層を形成する場合に、加熱溶融状態にある原料モノマ
ーへ、二硫化モリブデン、グラファイト、等無機系滑剤
及びこれら混合物を分散懸濁、又は三弗化エチレン四弗
化エチレン等樹脂パウダーや炭化水素系、脂肪酸化合物
(アミド系、エステル系、アルコール系)及び金属セッ
ケン等有機系滑剤及びこれらの混合物を溶解もしくは分
散させ反応させ、前記樹脂層に均質に又は安定分散に滑
剤を配合して伸縮自在シャフトを製造するものである。(Means for solving the problem) The technical means taken to solve the above problem are as follows. That is, in a method for manufacturing a telescopic shaft in which an inner shaft is slidably disposed within an outer shaft, in order to eliminate play between the two shafts, a space between the two shafts in a fitted state is removed. When forming a resin layer by applying the monomer casting method, inorganic lubricants such as molybdenum disulfide, graphite, and mixtures thereof are dispersed and suspended in the raw material monomer in a heated and molten state, or trifluoride ethylene tetrafluoride is used. Resin powders such as ethylene, hydrocarbons, fatty acid compounds (amides, esters, alcohols), organic lubricants such as metal soaps, and mixtures thereof are dissolved or dispersed and reacted to form a homogeneous or stable dispersion in the resin layer. A retractable shaft is manufactured by adding a lubricant.
(作用)
七ツマーキャスティング法及びそれに使用される原料の
ナイロン千ノマーキャステイグにおいて、ε−カプロク
ラタムを主原料とし、触媒として金属ナトリウム、金属
カリウム、エチルマグネシウムプロミド等アルカリ金属
、アルカリ土類金属及びこられ有機金属化合物、水素化
合物を添加したA液と、同じくε−カプロクラタム又は
物性改善のため、ソフトセグメントを導入した変性ε〜
カプロクラタムを主原料とし、開始剤としてN−アセチ
ルε−カプロクラタム等アシル化合物またはイソシアネ
ート化合物を添加したB液とを等量計量し、混合し、1
40〜170℃で加熱、1〜3分間保持するすることに
より重合を促進しナイロン樹脂を得るもので、これに前
記有機、無機各種の滑剤を添加した樹脂にて樹脂層を形
成したもので、これにより摺動フィーリングを向上した
低摩耗な伸縮自在シャフトを製造するものである。(Function) In the 7-mer casting method and the nylon 1,000-mer casting method used therein, ε-caproculatum is the main raw material, and alkali metals such as metallic sodium, metallic potassium, ethylmagnesium bromide, alkaline earth metals, and These are liquid A to which organometallic compounds and hydrogen compounds have been added, and also ε-caproculatum or modified ε~ to which soft segments have been introduced to improve physical properties.
Equal amounts of solution B containing caproculatum as the main raw material and an acyl compound or isocyanate compound such as N-acetyl ε-caproculatum as an initiator are weighed and mixed.
A nylon resin is obtained by heating at 40 to 170°C and holding for 1 to 3 minutes to accelerate polymerization, and a resin layer is formed with the resin to which various organic and inorganic lubricants are added. As a result, a telescopic shaft with improved sliding feeling and low wear can be manufactured.
(実施例) 以下実施例について説明する。(Example) Examples will be described below.
第1図〜第2図に於て、触媒が添加されたA液貯溜タン
ク1aと、開始剤が添加されたB液貯溜タンクlbと、
それぞれA、B液用のポンプ2 a i2bと混合吐出
部3からなる2液計量部合吐出装置1に於て、A、B液
貯溜タンクla、lbへ各種滑剤を0.1−10重量%
の範囲で添加し、攪拌機4a、4bで混合分散もしくは
溶解状態に調整貯溜する。In FIGS. 1 and 2, a liquid A storage tank 1a to which a catalyst has been added, a liquid B storage tank lb to which an initiator has been added,
In a two-liquid metering unit and discharge device 1 consisting of a pump 2 a i2b and a mixing discharge unit 3 for A and B liquids, 0.1-10% by weight of various lubricants are added to A and B liquid storage tanks la and lb.
The mixture is added in a range of 100 to 100 ml, mixed and dispersed using stirrers 4a and 4b, or adjusted to a dissolved state and stored.
次に前記A、 B液を等量計量し混合した液を、あらか
じめ140〜170℃に予熱した2つの構成部材である
アウタシャフト5とインナーシャフト6の内のアウタシ
ャフト5へ混合吐出部3を介して注入する。Next, equal amounts of the A and B liquids are measured and mixed, and the mixture is fed to the mixing discharge part 3 to the outer shaft 5 of the two structural members, the outer shaft 5 and the inner shaft 6, which are preheated to 140 to 170°C. Inject via.
前記アウターシャフト5ヘインナーシヤフト6をそれぞ
れのスプライン5c、6cを同軸に、且つ位相を合わせ
ながら嵌合させることによりモノマーの液位7の上昇を
伴わせつつ所定の位置迄嵌合し、そのまま140〜17
0℃の加熱炉10内で約3分間保持し反応を促進する。By fitting the outer shaft 5 and the inner shaft 6 with the respective splines 5c and 6c coaxially and in phase with each other, the monomer liquid level 7 is increased and the inner shaft 6 is fitted to a predetermined position. ~17
The mixture is kept in the heating furnace 10 at 0° C. for about 3 minutes to promote the reaction.
この結果嵌合されたアウターシャフト5とインナーシャ
フト6のスキ間8に滑剤が均質に溶解もしくは分散した
樹脂層9が形成され、滑らかなガタ感のない摺動フィー
リングと摩耗の少ない伸縮自在シャフト20が製造でき
るものである。As a result, a resin layer 9 in which the lubricant is homogeneously dissolved or dispersed is formed in the gap 8 between the fitted outer shaft 5 and inner shaft 6, resulting in a smooth sliding feeling without rattling and a telescopic shaft with less wear. 20 can be manufactured.
実施例−1 A、B両成分各1 kgを100℃で溶解したA。Example-1 A prepared by dissolving 1 kg each of both components A and B at 100°C.
B液貯溜タンク内のそれぞれに市販されたステアリン酸
亜鉛を3重量%相当の30gを添加攪拌しつつ半溶融状
態で安定懸濁状態に保持した。30 g of commercially available zinc stearate, equivalent to 3% by weight, was added to each of the liquid B storage tanks and maintained in a stable suspended state in a semi-molten state while stirring.
この調整されたA、B液の等量計量した混合液5 をあ
らかじめ160℃に予熱されたアウターシャフトに注入
、直ちに同しく160℃に予熱されたインナーシャフト
をアウターシャフトに同軸、同位相に最終位置迄嵌合し
、引続き3分間160℃以下に加熱保持し目的の樹脂組
成と伸縮自在シフトを得た。This adjusted mixed solution 5 of A and B in equal amounts is injected into the outer shaft preheated to 160°C, and immediately the inner shaft, which has also been preheated to 160°C, is placed coaxially and in phase with the outer shaft. They were fitted to the desired position, and then heated and held at 160° C. or lower for 3 minutes to obtain the desired resin composition and elastic shift.
この伸縮自在シャフトはスティックスリップの少ない滑
らかな摺動フィーリングを示すと共に、7.5万回の摺
動テスト後においてもガタ感を感じない低摩耗量であっ
た。This telescopic shaft exhibited a smooth sliding feeling with little stick-slip, and had a low amount of wear with no looseness even after 75,000 sliding tests.
実施例−2
原料粘度の高いB液貯溜タンク内のみ低分子量4弗化エ
チレン(ダイキン社製ルブロン2ミクロンパウダー)を
5重量%になる様に50g添加し、沈降しない様に攪拌
を続けた。以下実施例1と同手順で目的の組成の樹脂層
を有する伸縮自在シャフトを得た、摩擦摩耗特性も実施
例1と同様な良好な結果が得られた。Example 2 50 g of low molecular weight tetrafluoroethylene (Daikin Lubron 2 micron powder) was added to the liquid B storage tank, which has a high raw material viscosity, to give a concentration of 5% by weight, and stirring was continued to prevent sedimentation. The same procedure as in Example 1 was followed to obtain a telescoping shaft having a resin layer having the desired composition, and the same good results in friction and wear characteristics as in Example 1 were obtained.
(比較例)
実施例1と同じ手順でまったく滑剤を添加していない樹
脂層からなる伸縮自在シャフトを製造した、その特性は
スティックスリップ状の引っ掛り感が発生し、7.5万
個のテスト後は摩耗による有感ガタが発生した。(Comparative example) A telescopic shaft made of a resin layer without any lubricant was manufactured using the same procedure as in Example 1. The characteristic was that a stick-slip-like catching feeling occurred, and 75,000 pieces were tested. After that, there was a noticeable rattling due to wear.
本発明は次の効果を有する。すなわち、(1)滑剤が樹
脂層全体もしくは表層に均一に存在するために、滑らか
な摺動フィーリング及び低摩耗等潤滑効果が永続する。The present invention has the following effects. That is, (1) since the lubricant exists uniformly in the entire resin layer or the surface layer, the lubricating effect such as a smooth sliding feeling and low wear is maintained.
(2)モノマー原料中に一括して滑剤か投入出来るため
、従来の様に成形品一体毎にグリス塗布する必要がなく
、塗布設備も不要となる。(2) Since the lubricant can be added to the monomer raw material all at once, there is no need to apply grease to each molded product as in the past, and no application equipment is required.
(3)樹脂層に均一に溶存もしくは分散した滑剤により
樹脂層の吸湿性が改善され、同時に滑剤の錆抑制効果に
より樹脂層素地金属面の発錆がなくなる。(3) The lubricant uniformly dissolved or dispersed in the resin layer improves the hygroscopicity of the resin layer, and at the same time, the rust-inhibiting effect of the lubricant eliminates rust on the base metal surface of the resin layer.
第1図は滑剤が添加貯溜された貯溜タンクと、原料を計
量混合吐出する装置の説明図、第2図は滑剤を含有する
樹脂組成からなる伸縮自在シャフトを加熱雰囲気内で製
造する工程の説明図、第3図は第2図の要部の拡大説明
図である。
5・・・アウタシャフト。
6・・・インナーシャフト。
8・・・スキ間。
9・・・樹脂層。Fig. 1 is an explanatory diagram of a storage tank in which lubricant is added and stored, and a device for measuring, mixing and discharging raw materials, and Fig. 2 is an explanatory diagram of the process of manufacturing a retractable shaft made of a resin composition containing lubricant in a heated atmosphere. 3 are enlarged explanatory views of the main parts of FIG. 2. 5... Outer shaft. 6... Inner shaft. 8...Suki. 9...Resin layer.
Claims (1)
され、樹脂層を有する伸縮自在シャフトの製造方法に於
て、前記両シャフト間のガタを無くするために、嵌合状
態の両シャフト間のスキ間にモノマーキャスティング法
を適用して前記樹脂層を形成する場合に加熱溶融状態に
ある原料モノマーへ無機系滑剤及び有機系滑剤を分散さ
せつつ反応させ、前記樹脂層に均質に又は安定分散に滑
剤を配合して樹脂層を形成した伸縮自在シャフトの製造
方法。In a method for manufacturing a telescopic shaft in which an inner shaft is slidably disposed within an outer shaft and has a resin layer, in order to eliminate play between the two shafts, a gap between the two shafts in a fitted state is removed. When forming the resin layer by applying the monomer casting method, the inorganic lubricant and the organic lubricant are reacted while being dispersed in the raw material monomer in a heated molten state, and the lubricant is uniformly or stably dispersed in the resin layer. A method for manufacturing a telescopic shaft in which a resin layer is formed by compounding.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26355188A JPH02108508A (en) | 1988-10-19 | 1988-10-19 | Manufacture of extendable and contractible shaft |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26355188A JPH02108508A (en) | 1988-10-19 | 1988-10-19 | Manufacture of extendable and contractible shaft |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02108508A true JPH02108508A (en) | 1990-04-20 |
Family
ID=17391118
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26355188A Pending JPH02108508A (en) | 1988-10-19 | 1988-10-19 | Manufacture of extendable and contractible shaft |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02108508A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9604268B2 (en) | 2012-05-25 | 2017-03-28 | Bahoshan Iron & Steel Co., Ltd. | Cold state metal plate strip surface treatment system and treatment method of the same |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62195048A (en) * | 1986-02-21 | 1987-08-27 | Mitsubishi Heavy Ind Ltd | Cast molded resin sliding material |
JPS6360713A (en) * | 1986-09-02 | 1988-03-16 | Toyota Motor Corp | Manufacture of spline |
-
1988
- 1988-10-19 JP JP26355188A patent/JPH02108508A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62195048A (en) * | 1986-02-21 | 1987-08-27 | Mitsubishi Heavy Ind Ltd | Cast molded resin sliding material |
JPS6360713A (en) * | 1986-09-02 | 1988-03-16 | Toyota Motor Corp | Manufacture of spline |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9604268B2 (en) | 2012-05-25 | 2017-03-28 | Bahoshan Iron & Steel Co., Ltd. | Cold state metal plate strip surface treatment system and treatment method of the same |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3908038A (en) | Thermoplastic molding compositions | |
JPH04236300A (en) | Powdery lubricant for plunger device | |
US4051096A (en) | Resin composition | |
US3252905A (en) | Polyamide bearings | |
JPH02108508A (en) | Manufacture of extendable and contractible shaft | |
JP5634211B2 (en) | Phenolic resin molding material and sliding member | |
US4465799A (en) | Low friction slide lining composition and a method of producing the slide lining composition | |
US4326999A (en) | Lubricant and release agent for molded rubber articles | |
US2394567A (en) | Lubricating grease composition | |
DE3784384T2 (en) | POLYMERIZATION OF CYCLOOLEFINES BY METATHESIS. | |
CN107245237B (en) | chemical corrosion resistant PC composition and preparation method thereof | |
US2706715A (en) | Grease composition | |
JP2983778B2 (en) | Lubricant composition for ball joints | |
US3826785A (en) | Anionic lactam polymerization process using an o-c-n containing activator | |
CN103619937A (en) | Compositions having reduced frictional coefficient, method of manufacture thereof and articles comprising the same | |
US2525177A (en) | Vinyl resin compositions and molds produced therefrom | |
JP2002031213A (en) | Synthetic resin-made gear | |
Berg | Process development for the reactive injection moulding of caprolactam intermediates | |
SU1237683A1 (en) | Antifriction composition | |
US12023732B2 (en) | Iron-based mixed powder and method for manufacturing the same | |
SU1054069A1 (en) | Counter-adhesion coating for moulds | |
JPH05178970A (en) | Use of chlorinated polymer for raising the heat distortion temperature and glass transition temperature of dicyclopentadiene polymer | |
JP2018159124A (en) | Anticorrosive composition | |
US2326748A (en) | Polymerized insulating compound | |
JPS6020962A (en) | Production of resin molding having excellent resistance to friction and wear |