JPH0196104A - Cosmetic - Google Patents

Cosmetic

Info

Publication number
JPH0196104A
JPH0196104A JP25441587A JP25441587A JPH0196104A JP H0196104 A JPH0196104 A JP H0196104A JP 25441587 A JP25441587 A JP 25441587A JP 25441587 A JP25441587 A JP 25441587A JP H0196104 A JPH0196104 A JP H0196104A
Authority
JP
Japan
Prior art keywords
cosmetic
skin
foundation
powder
average particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25441587A
Other languages
Japanese (ja)
Inventor
Tadamitsu Uramoto
忠光 浦本
Tadao Nakamura
中村 直生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pola Orbis Holdings Inc
Original Assignee
Pola Chemical Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pola Chemical Industries Inc filed Critical Pola Chemical Industries Inc
Priority to JP25441587A priority Critical patent/JPH0196104A/en
Publication of JPH0196104A publication Critical patent/JPH0196104A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24Phosphorous; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12Face or body powders for grooming, adorning or absorbing
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/412Microsized, i.e. having sizes between 0.1 and 100 microns

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain a cosmetic smoothly spreadable on the skin, having excellent adhesivity and make-up durability and giving unique feeling to the skin, by compounding spherical hydroxyapatite having a specific average particle diameter. CONSTITUTION:The objective cosmetic such as powder foundation, stick foundation and face powder, having excellent and smooth spreadability and uniform adhesivity, giving mild feeling to the skin and providing durable make-up is produced by compounding 0.5-85wt.% of spherical hydroxyapatite having an average particle diameter of 0.1-50mum. The cosmetic may be compounded with oils and fats, waxes, surfactant, antioxidant, perfumery, colorant, powdery pigment, alcohols, antiseptic, water, humectant, etc.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、新規な感触を有する化粧料に関するものであ
り、皮膚上に於いて、のびが滑らかであり、しかも、密
着性と化粧持ちに優れた化粧料を提供せんとするもので
ある。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a cosmetic that has a novel feel, that spreads smoothly on the skin, and that has good adhesion and long-lasting makeup. The aim is to provide excellent cosmetics.

[従来の技術] 従来は、不定形なハイドロキシアパタイトが、使用され
ている。例えば、カラムクロマト用の吸着剤として、蛋
白質、核酸、酵素、ウィルス、その他の高分子化合物の
分析に使用されている。また、水不溶性の微細な白色粉
体の性質とそのコロイド特性を利用して、食品添加物、
歯磨基剤、流動性向上剤、固結防止、分散、懸濁、重合
助剤として使用されている。更に、歯科、生体用材料、
フッ素化アパタイト、新生骨等にも使用されている。例
えば、口腔用組成物としては、特公昭61−36211
号、特公昭55−20759@、特公昭56−7301
4号等が、また、歯磨組成物としては、特公昭56−7
3015号、特公昭55−57514 @等があげられ
る。
[Prior Art] Conventionally, amorphous hydroxyapatite has been used. For example, it is used as an adsorbent for column chromatography to analyze proteins, nucleic acids, enzymes, viruses, and other macromolecular compounds. We also use the properties of water-insoluble fine white powder and its colloidal properties to create food additives,
It is used as a dentifrice base, fluidity improver, anti-caking agent, dispersion, suspension, and polymerization aid. In addition, dental, biological materials,
It is also used for fluorinated apatite, new bone, etc. For example, as an oral composition, Japanese Patent Publication No. 61-36211
No., Special Publication No. 55-20759 @, Special Publication No. 56-7301
No. 4 etc., and as a toothpaste composition, Japanese Patent Publication No. 56-7
No. 3015, Special Publication No. 55-57514 @, etc.

又、化粧料としては、特公昭59−144710号に、
皮膚表面や髪から脂を除去し、脂漏状態を軽減させる方
法が知らされている。
In addition, as a cosmetic, Japanese Patent Publication No. 59-144710 describes
Methods are known to remove oil from the skin surface and hair to reduce seborrhea.

しかし、化粧料分野に球状ハイドロキシアパタイトの使
用は知られていない。
However, the use of spherical hydroxyapatite in the field of cosmetics is unknown.

[発明が解決しようとする問題点] これまで使用されている不定形なハイドロキシアパタイ
トを化粧料、特にメークアップ化粧料に、配合するよう
な場合は、吸着力が強すぎて、伸びの重さ、取れの悪さ
、使用感の悪さが顕著に表われ、その改善が強く望まれ
ていた。
[Problems to be solved by the invention] When the amorphous hydroxyapatite that has been used so far is incorporated into cosmetics, especially makeup cosmetics, the adsorption force is too strong and the spreadability is slow. , poor removal and poor usability were evident, and improvement of these problems was strongly desired.

[問題を解決するための手段] そこで、本発明者は、このような現状に鑑み、上記の問
題点を克服すべく、鋭意研究を行なった結果、皮膚上に
於いて、のびの滑らかさ、更に密着性、つきの均一性に
優れた球状のハイドロキシアパタイトを、化粧料添加剤
に含有せしめることにより、従来にない、独特の優れた
官能特性と密着性、つきの均一性、化粧持ち等の緒特性
とを同時に達成できることをみいだし、本発明を完成す
るに到った。
[Means for Solving the Problem] Therefore, in view of the current situation, the inventor of the present invention conducted intensive research in order to overcome the above problems, and as a result, the inventors found that the smoothness of the skin, Furthermore, by incorporating spherical hydroxyapatite, which has excellent adhesion and uniformity of application, into cosmetic additives, it has unique and excellent organoleptic properties and properties such as adhesion, uniformity of application, and makeup longevity. The present invention has been completed by discovering that it is possible to simultaneously achieve the following.

すなわち、本発明は、平均粒径が0.1〜50μの球状
ハイドロキシアパタイトを0.5〜85重量%配合して
なる化粧料を提供せんとするものである。
That is, the present invention aims to provide a cosmetic composition containing 0.5 to 85% by weight of spherical hydroxyapatite having an average particle size of 0.1 to 50 μm.

本発明を以下に、詳細に説明する。The present invention will be explained in detail below.

まず、本発明の化粧料とは、リキッドファンデーション
、パウダ2フアンデーシヨン、ケーキ状ファンデーショ
ン、スティック状ファンデーション、アンダーメークア
ップ、フェイスパウダー、ボディパウダー、制汗剤、口
紅、頬紅、アイライナー、アイシャドー、アイブローベ
ンシル、日焼は止めクリーム、美白パウダー、乳液、化
粧水等が挙げられる。上記の化粧料でも、とりわけパウ
ダーファンデーション、スティック状ファンデーション
、フェイスパウダー等は、支店に塗り伸ばす時の感触、
特に化粧持ちの効果がもつとも顕著であるので本発明に
於いては好適である。
First, the cosmetics of the present invention include liquid foundation, powder 2 foundation, cake foundation, stick foundation, under makeup, face powder, body powder, antiperspirant, lipstick, blusher, eyeliner, and eye shadow. , eyebrow cream, sunscreen cream, whitening powder, milky lotion, lotion, etc. Among the above cosmetics, especially powder foundation, stick foundation, face powder, etc., the feel when applying and spreading,
In particular, it is suitable for the present invention because it has a remarkable makeup-wearing effect.

次に、本発明で用いる平均粒径が0.1〜50μの球状
ハイドロキシアパタイトは、大略以下のようにして作る
。すなわち、ジェットタイプローチーター付きのホモミ
キサーに、あらかじめハイドロキシアパタイト(Ca1
o(PO4>6 (0)−1>2の白色粉末)の4倍伍
のイオン交換水をとり、攪拌しなからハイドロキシアパ
タイトを徐々に添加して、20重量%の均一分散懸濁液
を作る。これを定量ポンプにて回転円盤上に供給し、遠
心法で150±10℃の乾燥室内に噴霧する。乾燥され
た粒子は、サイクロンコレクターで回収する。そして、
分級機を使って、平均粒径が0.1〜50μの球状ハイ
ドロキシアパタイトを分取する。
Next, the spherical hydroxyapatite having an average particle size of 0.1 to 50 μm used in the present invention is produced approximately as follows. That is, hydroxyapatite (Ca1
0 (white powder with PO4>6 (0)-1>2), take 4 times as much ion-exchanged water, and gradually add hydroxyapatite without stirring to form a 20% by weight uniformly dispersed suspension. make. This is supplied onto a rotating disk using a metering pump and sprayed into a drying chamber at 150±10° C. using a centrifugal method. The dried particles are collected in a cyclone collector. and,
Spherical hydroxyapatite having an average particle size of 0.1 to 50 μm is separated using a classifier.

こうして得られる平均粒径が0.1〜50μの球状ハイ
ドロキシアパタイトを配合した化粧料を皮膚上に塗布し
た場合、のびの良いマイルドな使用感触と、滑らかな拡
がり、しかも均一に密着し、長時間の化粧仕上がりの持
続が有り、従来に例のない新規な化粧持ちを達成するこ
とができた。
When a cosmetic containing spherical hydroxyapatite with an average particle size of 0.1 to 50μ obtained in this way is applied to the skin, it has a mild texture that spreads easily, spreads smoothly, and adheres uniformly for a long time. The makeup finish lasted for a long time, and we were able to achieve a new type of makeup longevity that had never been seen before.

一方、球状ハイドロキシアパタイトの粒子径が0.1μ
未満では、のびが重くなり、よれ等も生じ、付きが不均
一となって化粧仕上り上好ましくない。
On the other hand, the particle size of spherical hydroxyapatite is 0.1μ
If it is less than that, it will spread slowly, cause curling, etc., and will not adhere uniformly, which is not desirable for the cosmetic finish.

又、50μを越えると皮膚上での異物感、異和感が生じ
、使用感上好ましくない。
Moreover, if it exceeds 50μ, a foreign body sensation or strange sensation will occur on the skin, which is unfavorable in terms of feeling of use.

こうして得られる球状ハイドロキシアパタイトの配合母
は、化粧料の性質に応じて任意に選択され、リキッドフ
ァンデーションには凡そ0.5〜20重量%、ケーキ状
ファンデーションには凡そ1゜0〜40重量%、パウダ
ーファンデーションには凡そ1.5〜60重量%、フェ
イスパウダーには凡そ1.0〜85重量%、クリームに
は凡そ0.5〜30重量%が適当である。つまり球状ハ
イドロキシアパタイトの配合世は、化粧料全重量にたい
して凡そ0.5〜85重量%が好ましい。
The blending base of the spherical hydroxyapatite obtained in this way is arbitrarily selected depending on the properties of the cosmetic, and is approximately 0.5 to 20% by weight for liquid foundation, approximately 1.0 to 40% by weight for cake foundation, Appropriate amounts are approximately 1.5 to 60% by weight for powder foundations, approximately 1.0 to 85% by weight for face powders, and approximately 0.5 to 30% by weight for creams. In other words, it is preferable that the spherical hydroxyapatite be blended in an amount of about 0.5 to 85% by weight based on the total weight of the cosmetic.

尚、本発明に係わる化粧料には、前述の球状ハイドロキ
シアパタイトの他に、通常化粧料に用いられる添加剤、
例えば、油脂類、ワックス類、界面活性剤、酸化防止剤
、香料、色素、顔料粉体、アルコール類、多価アルコー
ル、防腐剤、薬効成分、紫外線吸収剤、キレート剤、水
、保湿剤、増粘剤等を配合することができる。
In addition to the above-mentioned spherical hydroxyapatite, the cosmetics according to the present invention also contain additives commonly used in cosmetics,
For example, oils and fats, waxes, surfactants, antioxidants, fragrances, pigments, pigment powders, alcohols, polyhydric alcohols, preservatives, medicinal ingredients, ultraviolet absorbers, chelating agents, water, moisturizers, A sticky agent etc. can be added.

[実施例] 次に、本発明の実施例及び比較例について述べる。[Example] Next, examples and comparative examples of the present invention will be described.

尚、例中配合量は重量部である。In addition, the amounts in the examples are parts by weight.

実施例1  パウダーファンデーション(処方) (製法) Aをヘンシェルミキサーに投入混合した後、バルベライ
ザーに移し、粉砕する。
Example 1 Powder foundation (formulation) (manufacturing method) After mixing A into a Henschel mixer, it was transferred to a balberizer and pulverized.

これをヘンシェルミキサーにもどし、攪拌しながらBを
加える。更に、アトマイザ−に移し解砕して製品とする
Return this to the Henschel mixer and add B while stirring. Furthermore, it is transferred to an atomizer and crushed to produce a product.

比較例1 パウダーファンデーション(a)(処方) (製法) 本発明の実施例1の製法を準用し、製品とする。Comparative Example 1 Powder foundation (a) (formulation) (Manufacturing method) The manufacturing method of Example 1 of the present invention is applied mutatis mutandis to produce a product.

比較例2 パウダーファンデーション(b)(処方) (製法) 本発明の実施例1の製法を準用し、製品とする。Comparative Example 2 Powder foundation (b) (formulation) (Manufacturing method) The manufacturing method of Example 1 of the present invention is applied mutatis mutandis to produce a product.

実施例2  フェイスパウダー (処方) (製法) Aをナウターミキサ−にて均−混合後、攪拌しなからB
を加える。
Example 2 Face powder (prescription) (manufacturing method) After uniformly mixing A with a Nauta mixer, without stirring, B
Add.

ブロアーシフターを通して製品とする。The product is passed through a blower shifter.

実施例3  アイライナー (処方) (製法) Aをヘンシェルミキサーに投入し高速混合した後、攪拌
しながらBを加える。
Example 3 Eyeliner (Formulation) (Manufacturing method) After putting A into a Henschel mixer and mixing at high speed, B is added while stirring.

アトマイザ−にて解砕し製品とする。The product is crushed using an atomizer.

実施例4     クリーム (処方) C〔香    料              0.5
(製法) 八を75℃に加熱し、ホモミキサーにて混合する。これ
に75℃の8を加え乳化する。
Example 4 Cream (prescription) C [Fragrance 0.5
(Manufacturing method) Heat 8 to 75°C and mix with a homomixer. Add 8 at 75°C to this and emulsify.

攪拌しながら冷却し、30℃になった時Cを加え製品と
する。
Cool while stirring, and when the temperature reaches 30°C, add C to prepare the product.

[発明の効果] 本発明品が、皮膚上において、のびの滑らかさ、密着性
、つきの均−性及び化粧持ちに優れていることについて
詳述する。
[Effects of the Invention] It will be explained in detail that the product of the present invention is excellent in smoothness of spread, adhesion, uniformity of application, and makeup retention on the skin.

(1)官能評価 く実験方法と結果〉 (試料) ■実施例1 パウダーファンデーション■比較例1 パ
ウダーファンデーション(a)■比較例2 パウダーフ
ァンデーション(b)(評価) 女性専門のパネル20名に、上記各試料の使用テストを
依頼し、のびの滑らかさ、密着性、つきの均一性につい
て10点満点で評価してもらった。
(1) Experimental method and results for sensory evaluation (Sample) ■Example 1 Powder foundation ■Comparative example 1 Powder foundation (a) ■Comparative example 2 Powder foundation (b) (Evaluation) A panel of 20 women specialized in the above We asked them to perform a usage test on each sample and evaluate the smoothness of spread, adhesion, and uniformity of application on a scale of 10 to 10.

(結果) 表−1から明らかなように、本発明品は比較例1に比し
てのびの滑らかさとつきの均一性が、比較例2に比して
密着性が優れていることがわかる。
(Results) As is clear from Table 1, the product of the present invention is superior to Comparative Example 1 in smoothness of spread and uniformity of application, and superior to Comparative Example 2 in adhesion.

(2)化粧持ちの評価 く実験方法と結果〉 (試料) ■実施例1 パウダーファンデーション■比較例1 パ
ウダーファンデーション(a)(測定方法) 室温30〜35°C1湿度75〜90%の室内にて、被
検者10名に各試料を半顔塗布してもらい、1時間、2
時間、4時間後の化粧くずれについて、肉眼判定した。
(2) Experimental method and results for evaluating makeup durability> (Sample) ■Example 1 Powder foundation ■Comparative example 1 Powder foundation (a) (Measurement method) Indoors at room temperature 30-35°C and humidity 75-90% , 10 subjects were asked to apply each sample on half of their faces for 1 hour and 2 hours.
The fading of the makeup after 4 hours was visually determined.

(評価) 化粧くずれ な   や    あ   か   非い      
  る   な   常あ     りあ にあ る          る    る (結果) 表−2 表−2から明らかなように、本発明品はなかなか化粧く
ずれせずに化粧持ちがよいが、比較対照量は化粧くずれ
がおこり易く化粧持ちがよくないことがわかる。
(Evaluation) Makeup doesn't come off.
Results Table 2 As is clear from Table 2, the product of the present invention does not easily cause makeup to come off and has a long makeup life, but the comparison product tends to cause makeup to come off easily. I can see that it doesn't last well.

Claims (1)

【特許請求の範囲】[Claims] 平均粒径が0.1〜50μの球状ハイドロキシアパタイ
トを0.5〜85重量%配合してなる化粧料。
A cosmetic containing 0.5 to 85% by weight of spherical hydroxyapatite with an average particle size of 0.1 to 50μ.
JP25441587A 1987-10-08 1987-10-08 Cosmetic Pending JPH0196104A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25441587A JPH0196104A (en) 1987-10-08 1987-10-08 Cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25441587A JPH0196104A (en) 1987-10-08 1987-10-08 Cosmetic

Publications (1)

Publication Number Publication Date
JPH0196104A true JPH0196104A (en) 1989-04-14

Family

ID=17264658

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25441587A Pending JPH0196104A (en) 1987-10-08 1987-10-08 Cosmetic

Country Status (1)

Country Link
JP (1) JPH0196104A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6096324A (en) * 1995-06-13 2000-08-01 Laboratory Skin Care Methods of delivering materials into the skin, and compositions used therein
US6579516B1 (en) 1995-06-13 2003-06-17 Zahra Mansouri Methods of delivering materials into the skin, and compositions used therein

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6096324A (en) * 1995-06-13 2000-08-01 Laboratory Skin Care Methods of delivering materials into the skin, and compositions used therein
US6099849A (en) * 1995-06-13 2000-08-08 Mansouri; Zari Skin care moisturizers and cleansers
US6120782A (en) * 1995-06-13 2000-09-19 Mansouri; Zari Methods of delivering materials into the skin, and compositions used therein
US6579516B1 (en) 1995-06-13 2003-06-17 Zahra Mansouri Methods of delivering materials into the skin, and compositions used therein
US7655250B2 (en) 1995-06-13 2010-02-02 Laboratory Skin Care, Inc. Topical formulations comprising ceramic hydroxyapatite particles
US7771753B2 (en) 1995-06-13 2010-08-10 Laboratory Skin Care, Inc. Topical formulations comprising ceramic hydroxyapatite particles

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